CN110551559A - medium-speed wire processing fluid and preparation method thereof - Google Patents

medium-speed wire processing fluid and preparation method thereof Download PDF

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Publication number
CN110551559A
CN110551559A CN201910768213.1A CN201910768213A CN110551559A CN 110551559 A CN110551559 A CN 110551559A CN 201910768213 A CN201910768213 A CN 201910768213A CN 110551559 A CN110551559 A CN 110551559A
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China
Prior art keywords
medium
regulator
speed wire
wire processing
wire
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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CN201910768213.1A
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Chinese (zh)
Inventor
周统智
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Suzhou Renguang Intelligent Technology Co Ltd
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Suzhou Renguang Intelligent Technology Co Ltd
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Priority to CN201910768213.1A priority Critical patent/CN110551559A/en
Publication of CN110551559A publication Critical patent/CN110551559A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00Lubricating compositions containing more than 10% water
    • C10M173/02Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/281Esters of (cyclo)aliphatic monocarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)

Abstract

the invention relates to the technical field of wire cut electrical discharge machining, in particular to a medium-speed wire-moving machining liquid and a preparation method thereof. The wire-moving processing liquid comprises the following components in percentage by mass: 10-15% of spark discharge regulator, 5-15% of pH regulator, 4-8% of lubricant, 10-20% of antirust agent, 6-10% of chip removal detergent and the balance of deionized water. In the wire-moving processing liquid, the spark discharge regulator is alkyl glycoside polyoxyethylene ether which has better degradability, so that the wire-moving processing liquid has better degradability; the antirust agent is a mixture of benzotriazole and tolyltriazole in a mixing ratio of 1:1, so that the antirust agent can have better antirust property at lower concentration and higher concentration; the pH regulator is HY-95, which has less environmental pollution and can avoid harm to worker's health.

Description

Medium-speed wire processing fluid and preparation method thereof
Technical Field
the invention relates to the technical field of preparation of medium-speed wire processing liquid, in particular to medium-speed wire processing liquid and a preparation method thereof.
Background
the electric discharge machining is a method of machining a workpiece in a certain medium by an electroerosion action of pulse discharge between a tool electrode and a workpiece electrode. The wire cut electric discharge machine belongs to a unique independent machine tool in China, adopts a multiple reciprocating cutting processing technology, adopts large-current rapid cutting for the first time, and adopts speed-limiting cutting during the second and third times of trimming cutting, so that the cutting efficiency and the surface quality of the machine tool are greatly improved. Three stages (1) five, sixty years and even two series of water-based and oil-based combined use periods started before in the development of the linear cutting processing fluid, basically water and common mineral oil such as kerosene, transformer oil and the like are used. (2) In the seventies to eighty, special oil for electric spark machining is produced, namely, a proper amount of additive is added into proper mineral oil, and the oil contains more aromatic hydrocarbon. (3) From eighty to ninety years, with the increasing environmental protection requirements, machine tools are upgraded and replaced, and synthetic and mixed linear cutting machining liquid begins to appear.
The medium-speed wire belongs to one of wire cut electrical discharge machining. The medium-speed wire processing is different from a common metal cutting process and belongs to electric discharge processing, so that the medium-speed wire processing liquid has the working functions of cooling, chip removal, lubrication, rust prevention and the like, and simultaneously is used as an electric discharge medium to directly participate in the processing process.
at present, the spark discharge regulator in the existing wire-moving working fluid has no good biodegradability, so that the existing wire-moving working fluid has great pollution to the environment and great harm to the health of workers, and the antirust property can be changed along with the concentration of the wire-moving working fluid.
Therefore, there is a need to provide a new technical solution to overcome the above-mentioned drawbacks.
disclosure of Invention
The invention aims to provide a medium-speed wire processing liquid and a preparation method thereof, which can effectively solve the technical problems.
in order to achieve the purpose of the invention, the following technical scheme is adopted:
The medium-speed wire processing liquid comprises the following components in percentage by mass:
wherein the spark discharge regulator is alkyl glycoside polyoxyethylene ether; the pH regulator is HY-95; the antirust agent is a mixture of benzotriazole and tolyltriazole.
Further: the mixing ratio of the benzotriazole to the methylbenzotriazole is 1: 1.
further: the chip removal detergent is dodecyl dimethyl betaine or fatty alcohol-polyoxyethylene ether.
further: the lubricant is ethoxylated fatty acid methyl ester and its derivative.
A preparation method of a medium-speed wire processing liquid comprises the following steps:
step S1: weighing the spark discharge regulator, the pH regulator, the lubricant, the antirust agent, the chip removal detergent and the deionized water in percentage by mass;
Step S2: mixing the pH regulator, the lubricant and the antirust agent with the deionized water, and stirring for 20-30 minutes;
Step S3: and (4) adding the spark discharge regulator and the chip removal detergent into the mixture obtained in the step S2, regulating the temperature to 35 ℃, stirring for 5-15 minutes at the temperature, cooling and standing to obtain the medium-speed wire-moving machining liquid.
Compared with the prior art, the invention has the following beneficial effects:
1. The wire-moving working fluid and the spark discharge regulator are alkyl glycoside polyoxyethylene ether which has better degradability, so that the wire-moving working fluid has better degradability.
2. According to the wire-moving processing liquid, the antirust agent is a mixture of benzotriazole and methyl benzotriazole according to the mixing ratio of 1:1, so that the wire-moving processing liquid can have good antirust property at both lower concentration and higher concentration.
3. According to the silk-running processing liquid, the pH regulator is HY-95, so that the pollution to the environment is small on one hand, and the harm to the health of workers can be avoided on the other hand.
Detailed Description
The wire-moving processing fluid and the preparation method thereof are clearly and completely explained below. The specific techniques or conditions are not indicated in the examples, and are performed according to the techniques or conditions described in the literature in the field or according to the product specification. The reagents or instruments used are not indicated by manufacturers, and are all conventional products commercially available, wherein the pH regulator HY-95 is obtained from Beijing Maier chemical engineering Co. It is to be understood that the embodiments described are only some of the embodiments of the invention, and not all of them.
example 1:
The medium-speed wire processing liquid comprises the following components in percentage by mass:
wherein the antirust agent is benzotriazole and tolyltriazole which are mixed according to the mass percentage ratio of 1: 1.
A preparation method of a medium-speed wire processing liquid comprises the following steps:
Step S1: weighing the spark discharge regulator, the pH regulator, the lubricant, the antirust agent, the chip removal detergent and the deionized water in percentage by mass;
Step S2: mixing the pH regulator, the lubricant and the antirust agent with the deionized water, and stirring for 20 minutes;
step S3: and (4) adding the spark discharge regulator and the chip removal detergent into the mixture obtained in the step S2, regulating the temperature to 35 ℃, stirring for 5 minutes at the temperature, cooling and standing to obtain the medium-speed wire-moving machining liquid.
Example 2:
The medium-speed wire processing liquid comprises the following components in percentage by mass:
Wherein the antirust agent is benzotriazole and tolyltriazole which are mixed according to the mass percentage ratio of 1: 1.
The preparation method of the medium-speed wire-moving processing liquid comprises the following steps:
step S1: weighing the spark discharge regulator, the pH regulator, the lubricant, the antirust agent, the chip removal detergent and the deionized water in percentage by mass;
Step S2: mixing the pH regulator, the lubricant and the antirust agent with the deionized water, and stirring for 25 minutes;
Step S3: and (4) adding the spark discharge regulator and the chip removal detergent into the mixture obtained in the step S2, regulating the temperature to 35 ℃, stirring for 10 minutes at the temperature, cooling and standing to obtain the medium-speed wire-moving machining liquid.
example 3:
The medium-speed wire processing liquid comprises the following components in percentage by mass:
Wherein the antirust agent is benzotriazole and tolyltriazole which are mixed according to the mass percentage ratio of 1: 1.
A preparation method of a medium-speed wire processing liquid comprises the following steps:
step S1: weighing the spark discharge regulator, the pH regulator, the lubricant, the antirust agent, the chip removal detergent and the deionized water in percentage by mass;
Step S2: mixing the pH regulator, the lubricant and the antirust agent with the deionized water, and stirring for 30 minutes;
step S3: and (4) adding the spark discharge regulator and the chip removal detergent into the mixture obtained in the step S2, regulating the temperature to 35 ℃, stirring for 15 minutes at the temperature, cooling and standing to obtain the medium-speed wire-moving machining liquid.
Example 4:
the medium-speed wire processing liquid comprises the following components in percentage by mass:
Wherein the antirust agent is benzotriazole and tolyltriazole which are mixed according to the mass percentage ratio of 1: 1.
A preparation method of a medium-speed wire processing liquid comprises the following steps:
Step S1: weighing the spark discharge regulator, the pH regulator, the lubricant, the antirust agent, the chip removal detergent and the deionized water in percentage by mass;
Step S2: mixing the pH regulator, the lubricant and the antirust agent with the deionized water, and stirring for 30 minutes;
Step S3: and (4) adding the spark discharge regulator and the chip removal detergent into the mixture obtained in the step S2, regulating the temperature to 35 ℃, stirring for 15 minutes at the temperature, cooling and standing to obtain the medium-speed wire-moving machining liquid.
comparative use of examples 1 to 4 gave the following use results:
The invention has the following beneficial effects:
1. according to the wire-moving processing liquid, the antirust agent is a mixture of benzotriazole and methyl benzotriazole according to the mixing ratio of 1:1, so that the wire-moving processing liquid can have good antirust property at both lower concentration and higher concentration.
2. The wire-moving working fluid and the spark discharge regulator are alkyl glycoside polyoxyethylene ether which has better degradability, so that the wire-moving working fluid has better degradability.
3. the silk-running processing liquid of the invention, the pH regulator is HY-95, on one hand, the pollution to the environment is small, and on the other hand, the harm to the health of workers can be avoided
It will be understood that modifications and variations can be made by persons skilled in the art in light of the above teachings and all such modifications and variations are intended to be included within the scope of the invention as defined in the appended claims.

Claims (5)

1. a medium-speed wire processing liquid is characterized in that: comprises the following components in percentage by mass:
the spark discharge regulator is alkyl glycoside polyoxyethylene ether, the pH regulator is HY-95, and the antirust agent is a mixture of benzotriazole and methyl benzotriazole.
2. the medium-speed wire processing fluid as claimed in claim 1, wherein: the mixing ratio of the benzotriazole to the methylbenzotriazole is 1:1 in percentage by mass.
3. the medium-speed wire processing fluid as claimed in claim 1, wherein: the chip removal detergent is dodecyl dimethyl betaine or fatty alcohol-polyoxyethylene ether.
4. the medium-speed wire processing fluid as claimed in claim 1, wherein: the lubricant is ethoxylated fatty acid methyl ester and its derivative.
5. a preparation method of a medium-speed wire processing liquid is characterized by comprising the following steps: the method comprises the following steps:
Step S1: preparing raw materials of the medium speed wire processing fluid according to claim 1, namely weighing the spark discharge modifier, the pH modifier, the lubricant, the rust inhibitor, the chip removal detergent and the deionized water in percentage by mass;
Step S2: mixing the pH regulator, the lubricant and the antirust agent with the deionized water, and stirring for 20-30 minutes to obtain a mixture;
Step S3: and (4) adding the spark discharge regulator and the chip removal detergent into the mixture obtained in the step S2, stirring for 5-15 minutes at 35 ℃, cooling and standing to obtain the medium-speed wire-moving machining liquid.
CN201910768213.1A 2019-08-20 2019-08-20 medium-speed wire processing fluid and preparation method thereof Pending CN110551559A (en)

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Application Number Priority Date Filing Date Title
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2193224A (en) * 1986-05-27 1988-02-03 Grace W R & Co Fuel oil additives
CN104673470A (en) * 2013-11-27 2015-06-03 刘现梅 Medium-speed wire cutting working fluid
CN105820866A (en) * 2016-04-20 2016-08-03 广州科卢斯流体科技有限公司 Medium-speed wire-cut electrical discharge machining (MS-WEDM) total-synthesis wire-cut processing fluid
CN106675746A (en) * 2017-01-09 2017-05-17 哈尔滨理工大学 Mechanical electro-spark wire-electrode cutting fluid and preparation method thereof
CN105623812B (en) * 2016-01-29 2017-07-07 广州工大科技有限公司 Wire Wire-cut Electrical Discharge Machining liquid and preparation method thereof in alcohol radical

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2193224A (en) * 1986-05-27 1988-02-03 Grace W R & Co Fuel oil additives
CN104673470A (en) * 2013-11-27 2015-06-03 刘现梅 Medium-speed wire cutting working fluid
CN105623812B (en) * 2016-01-29 2017-07-07 广州工大科技有限公司 Wire Wire-cut Electrical Discharge Machining liquid and preparation method thereof in alcohol radical
CN105820866A (en) * 2016-04-20 2016-08-03 广州科卢斯流体科技有限公司 Medium-speed wire-cut electrical discharge machining (MS-WEDM) total-synthesis wire-cut processing fluid
CN106675746A (en) * 2017-01-09 2017-05-17 哈尔滨理工大学 Mechanical electro-spark wire-electrode cutting fluid and preparation method thereof

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Application publication date: 20191210