CN110526580A - A kind of bronze glaze and preparation method thereof - Google Patents

A kind of bronze glaze and preparation method thereof Download PDF

Info

Publication number
CN110526580A
CN110526580A CN201910935678.1A CN201910935678A CN110526580A CN 110526580 A CN110526580 A CN 110526580A CN 201910935678 A CN201910935678 A CN 201910935678A CN 110526580 A CN110526580 A CN 110526580A
Authority
CN
China
Prior art keywords
glaze
bronze
green body
glazing
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201910935678.1A
Other languages
Chinese (zh)
Other versions
CN110526580B (en
Inventor
夏寸草
熊开波
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of Shanghai for Science and Technology
Original Assignee
Shanghai School Of Visual Arts
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai School Of Visual Arts filed Critical Shanghai School Of Visual Arts
Priority to CN201910935678.1A priority Critical patent/CN110526580B/en
Publication of CN110526580A publication Critical patent/CN110526580A/en
Application granted granted Critical
Publication of CN110526580B publication Critical patent/CN110526580B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Glass Compositions (AREA)

Abstract

The invention discloses a kind of bronze glaze, include following component: potassium feldspar 45-49%, calcite 10-13%, barium carbonate 15-19%, kaolin 15-17%, aluminium oxide 2-3%, copper carbonate 3-4% as mass fraction;The present invention discloses a kind of preparation methods of bronze glaze, include the following steps: step 1, weigh various raw materials in proportion, and after grinding plus water mixes, and cross sieve and obtain the glaze slip of uniform and smooth;Step 2, different glazing method and thickness are selected according to green body size, thickness;Step 3, glazing green body is packed into kiln, is fired under oxidizing atmosphere by following heating curve, keep the temperature natural cooling of ceasing fire after twenty minutes.The beneficial effects of the present invention are the formula and preparation method for the bronze glaze that the present invention is announced can steadily reach glaze colours effect bronzy.Its chromaticness is simple and unsophisticated, thick and heavy, elegant, has dignified sense of history, extremely strong artistic expression and higher artistic value.

Description

A kind of bronze glaze and preparation method thereof
Technical field
The present invention relates to ceramic glaze colours technical fields more particularly to a kind of bronze glaze and preparation method thereof.
Background technique
Bronze ware is the principal mode of quotient, all period culture, is the important carrier of Chinese civilization, is successive dynasties ceramic art The model for practising and imitating.Successive dynasties ceramic art only learns the moulding of bronze ware mostly, but the ware of bronze glaze seldom occurs.
Using copper as colorant in traditional ceramics glaze, various red effects are burnt out in a reducing atmosphere mostly, it is common Have: the rose-red of an ancient unit of weight kiln, red, under-glaze red of holding a memorial ceremony for for wood-fired kiln etc..And the present invention is used under modern electrical kiln oxidizing atmosphere Copper carbonate is colorant, burns out dumb light, simple and unsophisticated bronze ware.Ancient times generally use the firings such as bavin, coal, carbon, with Development in science and technology and modern society focus on environmental protection, electrical kiln extensive utilization at present.In the widely applied overall background of modern electrical kiln, it is desirable that Ceramic technology is constantly brought forth new ideas on the basis of tradition, is suitble to scientific experiment technique study ceramic glaze and formula various new Type, the modernization firing mechanism of energy-saving and environmental protection.
Summary of the invention
1. the technical issues that need to address
The present invention needs the technical issues of final result to be, provides a kind of based on the unmanned working path rule in agricultural machinery crop field The algorithm drawn is debugged with the method for scientific experiment, is expanded utilization of the copper in ceramic glaze, is enriched ceramic glaze chromaticity kind.
2. technical solution
A kind of bronze glaze, includes following component, by mass percentage: potassium feldspar 45-49%, calcite 10-13%, carbon Sour barium 15-19%, kaolin 15-17%, aluminium oxide 2-3%, copper carbonate 3-4%.
It preferably, include following component, by mass percentage: potassium feldspar 48.4%, calcite 11.6%, barium carbonate 17.2%, kaolin 15.4%, aluminium oxide 3.0%, copper carbonate 4.4%.
The present invention discloses a kind of preparation methods of bronze glaze, include the following steps:
Step 1, various raw materials are weighed in proportion, and after grinding plus water mixes, and crosses 200 mesh standard sieve nets after evenly mixing and obtains The glaze slip of uniform and smooth;
Step 2, different glazing method and thickness are selected according to green body size, thickness, wherein selection glazing by sufflation method, Selection leaching glaze method.
Step 3, glazing green body is packed into kiln, is fired under oxidizing atmosphere by following heating curve, ceased fire after keeping the temperature 20min Natural cooling.
Preferably, the step 2 includes the following steps:
Step 2.1, different glazing methods is selected according to green body size, thickness, adjusts the ratio of bronze glaze and water;
Step 2.2, green body is small and thick selection glaze method, and the mass ratio of glaze and water is 1:1;
Step 2.3, the big and thin selection glazing by sufflation method of green body, and the mass ratio of glaze and water is 1:0.6.
Preferably, from room temperature to 560 DEG C the time 210 minutes, DEG C time 120 minutes from 560 DEG C to 900, then 900 DEG C of left sides Right heat preservation 10 minutes, DEG C time 240 minutes from 900 DEG C to 1260.
Preferably, the holding temperature of the step 4 is 1260 DEG C.
Preferably, the screen over-size of crossing in the step 1 is no more than 0.5%.
3. beneficial effect
In conclusion the beneficial effects of the present invention are: the electricity modernized is debugged and utilized with the method for scientific experiment The bronze glaze of kiln plant invention, is a kind of glaze colours with unique artistic effect, can greatly improve the artistic value of works and glad Reward value.Modernization electrical kiln equipment is largely used in various regions, and the present invention can widely, reproducibility promote the use of.
Specific embodiment
The present invention will be further described combined with specific embodiments below, but the present invention should not be limited by the examples.
Embodiment:
100 jin of bronze glaze, it is made of following raw materials according: 48.4 jin of potassium feldspar, 11.6 jin of calcite, and barium carbonate 17.2 Jin, 15.4 jin of kaolin, 3.0 jin of aluminium oxide, 4.4 jin of copper carbonate.
Above-mentioned bronze glaze and preparation method thereof the following steps are included:
Then plus water step 1, various raw materials are weighed in 100 jin of bronze glaze formula ratio quality, is first screened and is ground, Mixing crosses 200 mesh standard sieve nets after mixing and obtains fine and smooth glaze slip, and the surplus of sieving is no more than 0.5%.
Step 2, different glazing method and thickness are selected according to green body size, thickness.Big and thin green body selects glazing by sufflation Glaze method is soaked in method, the small and thick selection of green body.According to the difference of glazing method, the ratio of bronze glaze and water is adjusted.Glaze method: The mass ratio of glaze and water is 1:1, and glazing by sufflation method: the mass ratio of glaze and water is 1:0.6.
Preferably, glaze layer thickness control is between 0.8-1.5mm.
Step 3, the glazing green body dried is packed into kiln, is fired under oxidizing atmosphere by following heating curve.From room temperature to 560 DEG C the time 210 minutes, 560 DEG C -900 DEG C the time 120 minutes, 900 DEG C or so keep the temperature 10 minutes, 900 DEG C -1260 DEG C when Between 240 minutes, 1260 DEG C keep the temperature 20 minutes, natural cooling of ceasing fire later.180 DEG C or less, which are dropped to, in kiln temperature opens wicket again, Obtain the bronze glaze.
The effect of bronze glaze each component:
Potassium feldspar, chemical formula K2O·Al2O3·6SiO2, usually also referred to as orthoclase, color are white, red, milky, density For 2.54-2.57g/cm3, hardness 6.Ceramic glaze is mainly made by feldspar, quartz and raw clay, and wherein feldspar content is reachable 10-35%.Potassium feldspar is mainly used in ceramic batch and glaze.Feldspar can play the work of non-plastic raw material to potassium feldspar before firing With, it reduces the dry of green body and shrinks and deform, improvement drying property, shortening drying time.It can be used as flux reduction in firing Firing temperature promotes quartz and kaolin melting, and diffuses into one another the formation for permeating and accelerating mullite in the liquid phase.In this hair Bright middle utilization is Pingjiang River potassium feldspar.
Calcite, chemical formula CaCO3, it is a kind of calcium carbonate mineral, chemical composition CaO accounts for 56.03%, CO243.97% is accounted for, Often contain Mn and Fe, contains Sr sometimes.The color of calcite changes because the impurity wherein contained is different, but general is mostly white or nothing Color.Its main function is to reduce glaze melting temperature, increases the glossiness of glaze colours and glaze is prevented to be cracked and accumulate.
Barium carbonate, chemical formula BaCO3, inorganic compound, molecular weight 197.35, hexagon micro crystal, white powder.Have Very strong toxicity is stored in the storehouse of shady and cool ventilation, package encapsulation.It should separately store with acids, edible chemical, never mix Storage.
Kaolin, chemical formula Al203·2Si02·2H20, it is a kind of nonmetallic clay mineral, in pure white fine and smooth, mollisol Shape has the physicochemical properties such as good plasticity and fire resistance.Because white and fine and smooth, also known as white clouds are native.Kaolin has Certain plasticity, adhesiveness.The good caking property of glaze, suspension and binding ability are assigned in glaze.
Aluminium oxide, chemical formula Al2O3, alias corundum, alumina.It is a kind of compound of high rigidity, the white for being insoluble in water is solid Body, it is odorless, tasteless, matter is extremely hard, 2050 DEG C of fusing point.Hermetically drying is needed to save.
Copper carbonate, chemical formula CuCO3 are the carbonate of copper, are cyan powders shape solid, are the colour formers of bronze glaze.
Although the present invention has been disclosed in the preferred embodiment as above, it is not intended to limit the invention, any to be familiar with this The people of technology can do various changes and modification, therefore protection of the invention without departing from the spirit and scope of the present invention Range should subject to the definition of the claims.

Claims (7)

1. a kind of bronze glaze, which is characterized in that include following component, by mass percentage: potassium feldspar 45-49%, calcite 10-13%, barium carbonate 15-19%, kaolin 15-17%, aluminium oxide 2-3%, copper carbonate 3-4%.
2. a kind of bronze glaze according to claim 1, which is characterized in that include following component, by mass percentage: potassium Feldspar 48.4%, calcite 11.6%, barium carbonate 17.2%, kaolin 15.4%, aluminium oxide 3.0%, copper carbonate 4.4%.
3. a kind of utilize bronze glaze preparation method described in claim 1-2 any one, which is characterized in that including walking as follows It is rapid:
Step 1, various raw materials are weighed in proportion, and after grinding plus water mixes, and crosses 200 mesh standard sieve nets after evenly mixing and obtains uniformly Fine and smooth glaze slip;
Step 2, different glazing method and thickness are selected according to green body size, thickness, wherein selection glazing by sufflation method, selection Soak glaze method.
Step 3, glazing green body is packed into kiln, is fired under oxidizing atmosphere by following heating curve, nature of ceasing fire after heat preservation 20min It is cooling.
4. a kind of bronze glaze preparation method according to claim 3, which is characterized in that the step 2 includes the following steps:
Step 2.1, different glazing methods is selected according to green body size, thickness, adjusts the ratio of bronze glaze and water;
Step 2.2, green body is small and thick selection glaze method, and the mass ratio of glaze and water is 1:1;
Step 2.3, the big and thin selection glazing by sufflation method of green body, and the mass ratio of glaze and water is 1:0.6.
5. according to a kind of bronze glaze preparation method as claimed in claim 3, which is characterized in that the heating curve in the step 4 are as follows: From room temperature to 560 DEG C the time 210 minutes, DEG C time 120 minutes from 560 DEG C to 900, then 900 DEG C or so keep the temperature 10 minutes, from 900 DEG C to 1260 DEG C the time 240 minutes.
6. according to a kind of bronze glaze preparation method described in claim 5, which is characterized in that the heating curve in the step 4 are as follows: The holding temperature of the step 4 is 1260 DEG C.
7. according to a kind of bronze glaze preparation method as claimed in claim 3, which is characterized in that cross screen over-size not in the step 1 More than 0.5%.
CN201910935678.1A 2019-09-29 2019-09-29 Bronze glaze and preparation method thereof Active CN110526580B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910935678.1A CN110526580B (en) 2019-09-29 2019-09-29 Bronze glaze and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910935678.1A CN110526580B (en) 2019-09-29 2019-09-29 Bronze glaze and preparation method thereof

Publications (2)

Publication Number Publication Date
CN110526580A true CN110526580A (en) 2019-12-03
CN110526580B CN110526580B (en) 2022-04-19

Family

ID=68670969

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910935678.1A Active CN110526580B (en) 2019-09-29 2019-09-29 Bronze glaze and preparation method thereof

Country Status (1)

Country Link
CN (1) CN110526580B (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19749858C1 (en) * 1997-11-11 1999-04-22 Siemens Matsushita Components Reduction stable low dielectric constant ceramic material for co-firing with copper electrodes
CN103304274A (en) * 2013-06-08 2013-09-18 浙江工业大学之江学院工业研究院 Bronze green crystalline glaze and firing method thereof
CN106430977A (en) * 2016-08-31 2017-02-22 厦门万仟堂艺术品有限公司 Light greenish blue matte glaze for pottery product and preparation method of light greenish blue matte glaze
CN109231825A (en) * 2018-09-13 2019-01-18 湖南高峰陶瓷制造有限公司 Bronze unglazed furnace transmutation glaze and preparation method thereof
CN109942188A (en) * 2019-04-16 2019-06-28 福建省德化问瓷阁陶瓷有限公司 A kind of green temmoku glaze ceramics of matt and its manufacture craft

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19749858C1 (en) * 1997-11-11 1999-04-22 Siemens Matsushita Components Reduction stable low dielectric constant ceramic material for co-firing with copper electrodes
CN103304274A (en) * 2013-06-08 2013-09-18 浙江工业大学之江学院工业研究院 Bronze green crystalline glaze and firing method thereof
CN106430977A (en) * 2016-08-31 2017-02-22 厦门万仟堂艺术品有限公司 Light greenish blue matte glaze for pottery product and preparation method of light greenish blue matte glaze
CN109231825A (en) * 2018-09-13 2019-01-18 湖南高峰陶瓷制造有限公司 Bronze unglazed furnace transmutation glaze and preparation method thereof
CN109942188A (en) * 2019-04-16 2019-06-28 福建省德化问瓷阁陶瓷有限公司 A kind of green temmoku glaze ceramics of matt and its manufacture craft

Also Published As

Publication number Publication date
CN110526580B (en) 2022-04-19

Similar Documents

Publication Publication Date Title
CN101786795B (en) Enamel glaze and preparation process thereof
CN104892021B (en) A kind of electronics fume purifier open pore ceramic material and preparation method thereof
KR101384251B1 (en) Glaze composition containing ashes of bean pod
CN106082656B (en) The preparation method of bluish white glaze under a kind of oxidizing atmosphere
CN109384476A (en) A kind of anti-skid wearable negative ion ceramic ceramic tile and preparation method thereof
CN109179997A (en) A kind of high temperature transmutation TianXing glaze ceramic glaze and its high temperature transmutation TianXing glaze ceramics preparation process
CN107032832A (en) A kind of Ceramic Tiles with color changeable effect and preparation method thereof
CN106830681A (en) A kind of compound furnace transmutation glaze glaze, compound furnace transmutation glaze pottery and preparation method thereof
CN107935394A (en) A kind of Gu tea dust glaze and preparation method thereof
CN107698155A (en) A kind of pottery purple glaze
CN111320458A (en) Preparation method of tea dust glaze light porcelain
CN104478482A (en) Nansong offcial kiln cream-colored glaze transmutation formula and making technology
CN105502944A (en) Bright yellow glaze material and process utilizing same to prepare porcelains
CN112374762A (en) Moon white glaze for jun porcelain and preparation method thereof
CN112279515A (en) Jun porcelain sky blue glaze and preparation method thereof
CN106082990A (en) A kind of teaching pottery and preparation method thereof
CN106277792B (en) A kind of emerald blueness glaze and its method for cooking
CN101348363B (en) Color generation ceramic blank and preparation thereof
CN110526580A (en) A kind of bronze glaze and preparation method thereof
CN105272152A (en) Novel combination method of cobalt blue material and Nixing ceramic
CN107382281A (en) A kind of burning process of emerald green stove an ancient unit of weight
CN108483909B (en) Carbon-absorbing crack glaze for firewood burning pottery, preparation method of carbon-absorbing crack glaze, ceramic prepared from carbon-absorbing crack glaze and preparation method of ceramic
CN111233324A (en) Electric porcelain ash glaze material, electric porcelain ash glaze and preparation thereof
JP5142583B2 (en) Glaze for visiting iris tile
JP4903245B2 (en) Method for producing green pigment for reduction firing using copper oxide and green ceramics produced thereby

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right
TA01 Transfer of patent application right

Effective date of registration: 20220328

Address after: No.99 SHANGDA Road, Baoshan District, Shanghai

Applicant after: Shanghai University

Address before: 2200 Wenxiang Road, Songjiang District, Shanghai, 201620

Applicant before: SHANGHAI INSTITUTE OF VISUAL ART

GR01 Patent grant
GR01 Patent grant