CN110463710A - A kind of Herbicidal combinations for preventing and treating weeds of wheat - Google Patents
A kind of Herbicidal combinations for preventing and treating weeds of wheat Download PDFInfo
- Publication number
- CN110463710A CN110463710A CN201910834124.2A CN201910834124A CN110463710A CN 110463710 A CN110463710 A CN 110463710A CN 201910834124 A CN201910834124 A CN 201910834124A CN 110463710 A CN110463710 A CN 110463710A
- Authority
- CN
- China
- Prior art keywords
- ethoxyfen
- ethyl
- herbicidal combinations
- quinoline humulone
- wheat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
- A01N25/14—Powders or granules wettable
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
- A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
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- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of Herbicidal combinations for preventing and treating weeds of wheat, active constituent is quinoline humulone and ethoxyfen-ethyl, and the weight ratio of quinoline humulone and ethoxyfen-ethyl is 10:1 ~ 1:5.Pharmacodynamic test shows that the composition has the characteristics that with strong complementarity, synergistic effect is obvious, amount of application is reduced, high, environmental pollution reduces, is strong with environment compatibility to crop safety.
Description
Technical field
The present invention relates to plant protection composition technical fields, specifically, being a kind of weeding for preventing and treating weeds of wheat
Composition.
Background technique
Quinoline humulone, a kind of HPPD inhibitor, broad weed-killing spectrum is efficient to a variety of broadleaf weeds and gramineae weed, to dog tail
Careless preventive effect is brilliant, and quick-acting is good.
Ethoxyfen-ethyl, a kind of diphenyl ether herbicide, be mainly used for seedling rear defence except soybean, wheat, barley, peanut,
Broadleaf weeds in the crop fields such as pea, such as more than ten kinds of weeds of piemarker, redroot amaranth, clearvers, Siberian cocklebur.
Summary of the invention
The purpose of the present invention is aiming at the shortcomings in the prior art, provide a kind of Herbicidal combination for preventing and treating weeds of wheat
Object.
To achieve the above object, the technical solution adopted by the present invention is that: it is a kind of prevent and treat weeds of wheat Herbicidal combinations,
Its active constituent is quinoline humulone and ethoxyfen-ethyl, and the weight ratio of quinoline humulone and ethoxyfen-ethyl is 10:1 ~ 1:5.
The invention has the advantages that:
Two kinds of active components show as synergistic effect in composition of the invention, and the activity of the composition is than using single compound
The expected summation of activity and single compound independent activity it is more significant.The composition has with strong complementarity, synergistic effect
Obviously, the features such as amount of application is reduced, high, environmental pollution reduces, is strong with environment compatibility to crop safety.
Specific embodiment
It elaborates below with reference to embodiment to specific embodiment provided by the invention.
Embodiment 1
Quinoline humulone 15%, ethoxyfen-ethyl 5%, sodium methylene bis-naphthalene sulfonate 7%, calcium lignosulfonate 5%, kaolin complements to
100%.It is uniformly mixed entering in mixer after above-mentioned formula in proportion coarse crushing, obtains wettable after the airflow crushes
Pulvis.
Embodiment 2
Quinoline humulone, ethoxyfen-ethyl are processed into 20% wettable powder respectively, are administered according to the amount of 4g effective component per acre,
The mixture that different proportion is prepared in experimental design processing carries out field weeding test.
Each treatment region 30m2, it is administered in the weeds of wheat 2-3 leaf phase, each chemicals treatment is repeated 3 times.7 days after application,
15 days, the safety of 35 days investigation preventive effects and confection to wheat.
Using quinoline humulone as standard agent, disease index and control efficiency are calculated.Control efficiency is converted into probability value
(y), liquor strength (μ g/ml) is converted into logarithm (x), calculates concentration EC50 in virulence equation and inhibition with least square method,
The toxicity index grade co-toxicity coefficient (CTC) of medicament is calculated according to Sun Yunpei's Method.
Survey toxicity index (ATI)=(standard agent EC50/ reagent agent EC50) * 100
B in the percentage composition+B medicament toxicity index * mixture of A in theoretical toxicity index (TTI)=A medicament toxicity index * mixture
Percentage composition
Co-toxicity coefficient (CTC)=[mixture surveys toxicity index (ATI)/mixtures theoretical toxicity index (TTI)] * 100
CTC≤80, composition show as antagonism, 80 < CTC < 120, and composition shows as summation action, CTC >=120,
Composition shows as synergistic effect.
35 days Herbicidal Testing Trials results after 1 medicine of table
Medicament | EC50(μg/ml) | ATI | TTI | CTC |
A | 0.47 | 100.00 | / | / |
B | 6.49 | 7.24 | / | / |
A:B=10:1 | 0.41 | 114.63 | 91.57 | 125.19 |
A:B =5:1 | 0.37 | 127.03 | 84.54 | 150.26 |
A:B =3:1 | 0.35 | 134.29 | 76.81 | 174.83 |
A:B =1:1 | 0.54 | 87.04 | 53.62 | 162.32 |
A:B =1:3 | 1.05 | 44.76 | 30.43 | 147.09 |
A:B =1:5 | 1.59 | 29.56 | 22.70 | 130.21 |
In table, A refers to that quinoline humulone, B refer to ethoxyfen-ethyl.
The result shows that quinoline humulone and ethoxyfen-ethyl be between proportion 10:1 ~ 1:5, co-toxicity coefficient 120 or more,
Illustrate that quinoline humulone compounds preventing and kill off with significant synergistic function to weeds of wheat with ethoxyfen-ethyl.
Embodiment 3
Quinoline humulone 15%, ethoxyfen-ethyl 5%, lauryl sodium sulfate 3%, polyvinyl alcohol 1%, white carbon black 20%, kaolin is supplied
To 100%.It is granulated after weighing each component progress ultra-fine grinding by formula, is dry, sieved up to water-dispersible granules.The water dispersion
Property granula for preventing and kill off wheat paddock annual gramineous weed, mu is with 30 grams, weeds 2-3 leaf phase spraying treatment, prevents within 10 days after medicine
Effect is 98.5%.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
Member, under the premise of not departing from the method for the present invention, can also make several improvement and supplement, these are improved and supplement also should be regarded as
Protection scope of the present invention.
Claims (10)
1. a kind of Herbicidal combinations for preventing and treating weeds of wheat, which is characterized in that the active constituent in the Herbicidal combinations
For quinoline humulone and ethoxyfen-ethyl, the weight ratio of quinoline humulone and ethoxyfen-ethyl is 10:1 ~ 1:5.
2. Herbicidal combinations according to claim 1, which is characterized in that the weight ratio of quinoline humulone and ethoxyfen-ethyl is
10:1。
3. Herbicidal combinations according to claim 1, which is characterized in that the weight ratio of quinoline humulone and ethoxyfen-ethyl is
5:1。
4. Herbicidal combinations according to claim 1, which is characterized in that the weight ratio of quinoline humulone and ethoxyfen-ethyl is
3:1。
5. Herbicidal combinations according to claim 1, which is characterized in that the weight ratio of quinoline humulone and ethoxyfen-ethyl is
1:1。
6. Herbicidal combinations according to claim 1, which is characterized in that the weight ratio of quinoline humulone and ethoxyfen-ethyl is
1:3。
7. Herbicidal combinations according to claim 1, which is characterized in that the weight ratio of quinoline humulone and ethoxyfen-ethyl is
1:5。
8. Herbicidal combinations according to claim 1, which is characterized in that also include plant protection in the Herbicidal combinations
In acceptable auxiliary agent and/or carrier.
9. application of described in any item Herbicidal combinations in prevention and treatment weeds of wheat according to claim 1 ~ 8.
10. a kind of method for preventing and treating weeds of wheat, which is characterized in that by weeding group described in any one of claims 1 to 8
The effective component quinoline humulone and ethoxyfen-ethyl for closing object are applied to plant, plant parts, vegetable seeds or plant together or separately
The region of object growth.
Priority Applications (1)
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CN201910834124.2A CN110463710A (en) | 2019-09-04 | 2019-09-04 | A kind of Herbicidal combinations for preventing and treating weeds of wheat |
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CN201910834124.2A CN110463710A (en) | 2019-09-04 | 2019-09-04 | A kind of Herbicidal combinations for preventing and treating weeds of wheat |
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102613180A (en) * | 2012-02-27 | 2012-08-01 | 江苏辉丰农化股份有限公司 | Weeding composition |
WO2013080484A1 (en) * | 2011-11-30 | 2013-06-06 | クミアイ化学工業株式会社 | Herbicide composition |
CN104557739A (en) * | 2013-10-25 | 2015-04-29 | 华中师范大学 | Triketone compound and preparation method and application thereof |
CN106665587A (en) * | 2016-12-11 | 2017-05-17 | 广东中迅农科股份有限公司 | Weeding composition containing traloxydim and quinclorac |
WO2018008766A1 (en) * | 2016-07-08 | 2018-01-11 | クミアイ化学工業株式会社 | Herbicide composition |
CN110037035A (en) * | 2019-04-29 | 2019-07-23 | 广东中迅农科股份有限公司 | A kind of Herbicidal combinations containing quinoline humulone and clodinafop-propargyl |
-
2019
- 2019-09-04 CN CN201910834124.2A patent/CN110463710A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013080484A1 (en) * | 2011-11-30 | 2013-06-06 | クミアイ化学工業株式会社 | Herbicide composition |
CN102613180A (en) * | 2012-02-27 | 2012-08-01 | 江苏辉丰农化股份有限公司 | Weeding composition |
CN104557739A (en) * | 2013-10-25 | 2015-04-29 | 华中师范大学 | Triketone compound and preparation method and application thereof |
WO2018008766A1 (en) * | 2016-07-08 | 2018-01-11 | クミアイ化学工業株式会社 | Herbicide composition |
CN106665587A (en) * | 2016-12-11 | 2017-05-17 | 广东中迅农科股份有限公司 | Weeding composition containing traloxydim and quinclorac |
CN110037035A (en) * | 2019-04-29 | 2019-07-23 | 广东中迅农科股份有限公司 | A kind of Herbicidal combinations containing quinoline humulone and clodinafop-propargyl |
Non-Patent Citations (2)
Title |
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滕春红: "氯氟草醚乙酯防除大豆杂草", 《大豆科学》 * |
葛发祥 等: "高效旱田除草剂氯氟草醚乙酯的制备及应用", 《安徽化工》 * |
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Application publication date: 20191119 |