CN110463710A - A kind of Herbicidal combinations for preventing and treating weeds of wheat - Google Patents

A kind of Herbicidal combinations for preventing and treating weeds of wheat Download PDF

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Publication number
CN110463710A
CN110463710A CN201910834124.2A CN201910834124A CN110463710A CN 110463710 A CN110463710 A CN 110463710A CN 201910834124 A CN201910834124 A CN 201910834124A CN 110463710 A CN110463710 A CN 110463710A
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CN
China
Prior art keywords
ethoxyfen
ethyl
herbicidal combinations
quinoline humulone
wheat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910834124.2A
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Chinese (zh)
Inventor
史卫斌
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Individual
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Individual
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Publication date
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Priority to CN201910834124.2A priority Critical patent/CN110463710A/en
Publication of CN110463710A publication Critical patent/CN110463710A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12Powders or granules
    • A01N25/14Powders or granules wettable
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • A01N37/40Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/541,3-Diazines; Hydrogenated 1,3-diazines

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  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to a kind of Herbicidal combinations for preventing and treating weeds of wheat, active constituent is quinoline humulone and ethoxyfen-ethyl, and the weight ratio of quinoline humulone and ethoxyfen-ethyl is 10:1 ~ 1:5.Pharmacodynamic test shows that the composition has the characteristics that with strong complementarity, synergistic effect is obvious, amount of application is reduced, high, environmental pollution reduces, is strong with environment compatibility to crop safety.

Description

A kind of Herbicidal combinations for preventing and treating weeds of wheat
Technical field
The present invention relates to plant protection composition technical fields, specifically, being a kind of weeding for preventing and treating weeds of wheat Composition.
Background technique
Quinoline humulone, a kind of HPPD inhibitor, broad weed-killing spectrum is efficient to a variety of broadleaf weeds and gramineae weed, to dog tail Careless preventive effect is brilliant, and quick-acting is good.
Ethoxyfen-ethyl, a kind of diphenyl ether herbicide, be mainly used for seedling rear defence except soybean, wheat, barley, peanut, Broadleaf weeds in the crop fields such as pea, such as more than ten kinds of weeds of piemarker, redroot amaranth, clearvers, Siberian cocklebur.
Summary of the invention
The purpose of the present invention is aiming at the shortcomings in the prior art, provide a kind of Herbicidal combination for preventing and treating weeds of wheat Object.
To achieve the above object, the technical solution adopted by the present invention is that: it is a kind of prevent and treat weeds of wheat Herbicidal combinations, Its active constituent is quinoline humulone and ethoxyfen-ethyl, and the weight ratio of quinoline humulone and ethoxyfen-ethyl is 10:1 ~ 1:5.
The invention has the advantages that:
Two kinds of active components show as synergistic effect in composition of the invention, and the activity of the composition is than using single compound The expected summation of activity and single compound independent activity it is more significant.The composition has with strong complementarity, synergistic effect Obviously, the features such as amount of application is reduced, high, environmental pollution reduces, is strong with environment compatibility to crop safety.
Specific embodiment
It elaborates below with reference to embodiment to specific embodiment provided by the invention.
Embodiment 1
Quinoline humulone 15%, ethoxyfen-ethyl 5%, sodium methylene bis-naphthalene sulfonate 7%, calcium lignosulfonate 5%, kaolin complements to 100%.It is uniformly mixed entering in mixer after above-mentioned formula in proportion coarse crushing, obtains wettable after the airflow crushes Pulvis.
Embodiment 2
Quinoline humulone, ethoxyfen-ethyl are processed into 20% wettable powder respectively, are administered according to the amount of 4g effective component per acre, The mixture that different proportion is prepared in experimental design processing carries out field weeding test.
Each treatment region 30m2, it is administered in the weeds of wheat 2-3 leaf phase, each chemicals treatment is repeated 3 times.7 days after application, 15 days, the safety of 35 days investigation preventive effects and confection to wheat.
Using quinoline humulone as standard agent, disease index and control efficiency are calculated.Control efficiency is converted into probability value (y), liquor strength (μ g/ml) is converted into logarithm (x), calculates concentration EC50 in virulence equation and inhibition with least square method, The toxicity index grade co-toxicity coefficient (CTC) of medicament is calculated according to Sun Yunpei's Method.
Survey toxicity index (ATI)=(standard agent EC50/ reagent agent EC50) * 100
B in the percentage composition+B medicament toxicity index * mixture of A in theoretical toxicity index (TTI)=A medicament toxicity index * mixture Percentage composition
Co-toxicity coefficient (CTC)=[mixture surveys toxicity index (ATI)/mixtures theoretical toxicity index (TTI)] * 100
CTC≤80, composition show as antagonism, 80 < CTC < 120, and composition shows as summation action, CTC >=120, Composition shows as synergistic effect.
35 days Herbicidal Testing Trials results after 1 medicine of table
Medicament EC50(μg/ml) ATI TTI CTC
A 0.47 100.00 / /
B 6.49 7.24 / /
A:B=10:1 0.41 114.63 91.57 125.19
A:B =5:1 0.37 127.03 84.54 150.26
A:B =3:1 0.35 134.29 76.81 174.83
A:B =1:1 0.54 87.04 53.62 162.32
A:B =1:3 1.05 44.76 30.43 147.09
A:B =1:5 1.59 29.56 22.70 130.21
In table, A refers to that quinoline humulone, B refer to ethoxyfen-ethyl.
The result shows that quinoline humulone and ethoxyfen-ethyl be between proportion 10:1 ~ 1:5, co-toxicity coefficient 120 or more, Illustrate that quinoline humulone compounds preventing and kill off with significant synergistic function to weeds of wheat with ethoxyfen-ethyl.
Embodiment 3
Quinoline humulone 15%, ethoxyfen-ethyl 5%, lauryl sodium sulfate 3%, polyvinyl alcohol 1%, white carbon black 20%, kaolin is supplied To 100%.It is granulated after weighing each component progress ultra-fine grinding by formula, is dry, sieved up to water-dispersible granules.The water dispersion Property granula for preventing and kill off wheat paddock annual gramineous weed, mu is with 30 grams, weeds 2-3 leaf phase spraying treatment, prevents within 10 days after medicine Effect is 98.5%.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art Member, under the premise of not departing from the method for the present invention, can also make several improvement and supplement, these are improved and supplement also should be regarded as Protection scope of the present invention.

Claims (10)

1. a kind of Herbicidal combinations for preventing and treating weeds of wheat, which is characterized in that the active constituent in the Herbicidal combinations For quinoline humulone and ethoxyfen-ethyl, the weight ratio of quinoline humulone and ethoxyfen-ethyl is 10:1 ~ 1:5.
2. Herbicidal combinations according to claim 1, which is characterized in that the weight ratio of quinoline humulone and ethoxyfen-ethyl is 10:1。
3. Herbicidal combinations according to claim 1, which is characterized in that the weight ratio of quinoline humulone and ethoxyfen-ethyl is 5:1。
4. Herbicidal combinations according to claim 1, which is characterized in that the weight ratio of quinoline humulone and ethoxyfen-ethyl is 3:1。
5. Herbicidal combinations according to claim 1, which is characterized in that the weight ratio of quinoline humulone and ethoxyfen-ethyl is 1:1。
6. Herbicidal combinations according to claim 1, which is characterized in that the weight ratio of quinoline humulone and ethoxyfen-ethyl is 1:3。
7. Herbicidal combinations according to claim 1, which is characterized in that the weight ratio of quinoline humulone and ethoxyfen-ethyl is 1:5。
8. Herbicidal combinations according to claim 1, which is characterized in that also include plant protection in the Herbicidal combinations In acceptable auxiliary agent and/or carrier.
9. application of described in any item Herbicidal combinations in prevention and treatment weeds of wheat according to claim 1 ~ 8.
10. a kind of method for preventing and treating weeds of wheat, which is characterized in that by weeding group described in any one of claims 1 to 8 The effective component quinoline humulone and ethoxyfen-ethyl for closing object are applied to plant, plant parts, vegetable seeds or plant together or separately The region of object growth.
CN201910834124.2A 2019-09-04 2019-09-04 A kind of Herbicidal combinations for preventing and treating weeds of wheat Pending CN110463710A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910834124.2A CN110463710A (en) 2019-09-04 2019-09-04 A kind of Herbicidal combinations for preventing and treating weeds of wheat

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910834124.2A CN110463710A (en) 2019-09-04 2019-09-04 A kind of Herbicidal combinations for preventing and treating weeds of wheat

Publications (1)

Publication Number Publication Date
CN110463710A true CN110463710A (en) 2019-11-19

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CN201910834124.2A Pending CN110463710A (en) 2019-09-04 2019-09-04 A kind of Herbicidal combinations for preventing and treating weeds of wheat

Country Status (1)

Country Link
CN (1) CN110463710A (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102613180A (en) * 2012-02-27 2012-08-01 江苏辉丰农化股份有限公司 Weeding composition
WO2013080484A1 (en) * 2011-11-30 2013-06-06 クミアイ化学工業株式会社 Herbicide composition
CN104557739A (en) * 2013-10-25 2015-04-29 华中师范大学 Triketone compound and preparation method and application thereof
CN106665587A (en) * 2016-12-11 2017-05-17 广东中迅农科股份有限公司 Weeding composition containing traloxydim and quinclorac
WO2018008766A1 (en) * 2016-07-08 2018-01-11 クミアイ化学工業株式会社 Herbicide composition
CN110037035A (en) * 2019-04-29 2019-07-23 广东中迅农科股份有限公司 A kind of Herbicidal combinations containing quinoline humulone and clodinafop-propargyl

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013080484A1 (en) * 2011-11-30 2013-06-06 クミアイ化学工業株式会社 Herbicide composition
CN102613180A (en) * 2012-02-27 2012-08-01 江苏辉丰农化股份有限公司 Weeding composition
CN104557739A (en) * 2013-10-25 2015-04-29 华中师范大学 Triketone compound and preparation method and application thereof
WO2018008766A1 (en) * 2016-07-08 2018-01-11 クミアイ化学工業株式会社 Herbicide composition
CN106665587A (en) * 2016-12-11 2017-05-17 广东中迅农科股份有限公司 Weeding composition containing traloxydim and quinclorac
CN110037035A (en) * 2019-04-29 2019-07-23 广东中迅农科股份有限公司 A kind of Herbicidal combinations containing quinoline humulone and clodinafop-propargyl

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
滕春红: "氯氟草醚乙酯防除大豆杂草", 《大豆科学》 *
葛发祥 等: "高效旱田除草剂氯氟草醚乙酯的制备及应用", 《安徽化工》 *

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Application publication date: 20191119