CN110292046A - A kind of Herbicidal combinations - Google Patents
A kind of Herbicidal combinations Download PDFInfo
- Publication number
- CN110292046A CN110292046A CN201910696961.3A CN201910696961A CN110292046A CN 110292046 A CN110292046 A CN 110292046A CN 201910696961 A CN201910696961 A CN 201910696961A CN 110292046 A CN110292046 A CN 110292046A
- Authority
- CN
- China
- Prior art keywords
- benzoic acid
- orthosulfamuron
- herbicidal combinations
- pyrimidine
- acid derivative
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of Herbicidal combinations; its effective component is orthosulfamuron and 2- pyrimidine oxy-benzoic acid derivative; orthosulfamuron and the weight ratio of 2- pyrimidine oxy-benzoic acid derivative are 20:1 ~ 1:10, and 2- pyrimidine oxy-benzoic acid derivative is 12- ((5- methoxyl group -2- ((4- methoxy pyrimidine -2- base) oxygroup) benzoyl) oxygroup) lauryl sodium sulfate.Pharmacodynamic test shows that the composition has the characteristics that with strong complementarity, synergistic effect is obvious, degrass spectrum expands, amount of application is reduced, high, environmental pollution reduces, is strong with environment compatibility to crop safety.
Description
Technical field
The present invention relates to plant protection composition technical fields, specifically, being a kind of containing orthosulfamuron and 2- pyrimidine
The Herbicidal combinations of p-methoxybenzoic acid derivative.
Background technique
Orthosulfamuron, chemical name: 1- (4,6- dimethoxypyridin -2- base) -3- [2- (formyl-dimethylamino)
Phenylsulfamoyl base] urea, by inhibiting the acetolactate synthestase (ALS) of weeds, prevention valine, leucine, isoleucine
Biosynthesis stop weeds cell division to prevent the synthesis of weeds protein, last weeds are withered.
12- ((5- methoxyl group -2- ((4- methoxy pyrimidine -2- base) oxygroup) benzoyl) oxygroup) dodecyl sulphate
Sodium, structural formula are as follows:
It is 2- pyrimidine oxy-benzoic acid derivative disclosed in a kind of CN106946794A, has to rice field ear leaf water amaranth etc. good
Preventive effect.
Summary of the invention
The purpose of the present invention is aiming at the shortcomings in the prior art, provide a kind of Herbicidal combinations.
To achieve the above object, the technical solution adopted by the present invention is that: a kind of Herbicidal combinations, the Herbicidal combinations
In effective component be orthosulfamuron and 2- pyrimidine oxy-benzoic acid derivative, orthosulfamuron and 2- pyrimidine oxy-benzoic acid
The weight ratio of derivative is 20:1 ~ 1:10, and 2- pyrimidine oxy-benzoic acid derivative is 12- ((5- methoxyl group -2- ((4- methoxyl group
Pyrimidine -2-base) oxygroup) benzoyl) oxygroup) lauryl sodium sulfate.
Preferably, orthosulfamuron and the weight ratio of 2- pyrimidine oxy-benzoic acid derivative are 10:1 ~ 1:5.It is furthermore preferred that
Orthosulfamuron and the weight ratio of 2- pyrimidine oxy-benzoic acid derivative are 1:1,3:1 or 5:1.
The invention has the advantages that:
Two kinds of effective components show as synergistic effect in composition of the invention, and the activity of the composition is than using single compound
The expected summation of activity and single compound independent activity it is more significant.The composition has with strong complementarity, synergistic effect
Obviously, the features such as degrass spectrum expands, amount of application is reduced, high, environmental pollution reduces, is strong with environment compatibility to crop safety.
Specific embodiment
It elaborates below with reference to embodiment to specific embodiment provided by the invention.
In following embodiment, 2- pyrimidine oxy-benzoic acid derivative is that ((((4- methoxyl group is phonetic by 5- methoxyl group -2- by 12-
Pyridine -2- base) oxygroup) benzoyl) oxygroup) lauryl sodium sulfate.
1 wettable powder of embodiment
Orthosulfamuron 30%, 2- pyrimidine oxy-benzoic acid derivative 10%, alkyl phenol polyoxyethylene ether phosphate 10%, to methoxy
Base fatty acyl anilinesulfonic acid 6%, diatomite surplus.
It is uniformly mixed, obtains after the airflow crushes wettable by entering in mixer after above-mentioned formula in proportion coarse crushing
Property pulvis.
2 wettable powder of embodiment
Orthosulfamuron 30%, 2- pyrimidine oxy-benzoic acid derivative 10%, white carbon black 2%, polycarboxylate 1%, di-2-ethylhexylphosphine oxide naphthalene sulphur
Sour sodium 2%, neopelex 2%, sodium lignin sulfonate 3%, diatomite surplus.
It is uniformly mixed, obtains after the airflow crushes wettable by entering in mixer after above-mentioned formula in proportion coarse crushing
Property pulvis.
3 water dispersible granules of embodiment
Orthosulfamuron 30%, 2- pyrimidine oxy-benzoic acid derivative 10%, white carbon black 2%, lauryl sodium sulfate 3%, methyl naphthalene
Sodium sulfonate formaldehyde condensation products 4%, polycarboxylate 1%, calcium lignosulfonate 2%, di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate 1%, sodium carboxymethyl starch
1%, soluble starch surplus.
Above-mentioned formula is mixed in proportion, is crushed with micro jet, through mediating, subsequently into extrusion granulation
Machine is granulated, and after dry screening, water dispersible granules are made.
4 water dispersible granules of embodiment
Orthosulfamuron 30%, 2- pyrimidine oxy-benzoic acid derivative 10%, lauryl sodium sulfate 10%, alkylphenol-polyethenoxy
Ether sulfate 5%, sodium bicarbonate 2%, white carbon black 15%, kaolin surplus.
Above-mentioned formula is mixed in proportion, is crushed with micro jet, through mediating, subsequently into extrusion granulation
Machine is granulated, and after dry screening, water dispersible granules are made.
Embodiment 5
Using orthosulfamuron as standard agent, disease index and control efficiency are calculated.Control efficiency is converted into probability value
(y), liquor strength (μ g/ml) is converted into logarithm (x), calculates concentration EC50 in virulence equation and inhibition with least square method,
The toxicity index grade co-toxicity coefficient (CTC) of medicament is calculated according to Sun Yunpei's Method.Orthosulfamuron and 2- pyrimidine oxy-benzoic acid are derivative
Object compounding the results are shown in Table 1 to the toxicity test of nutgrass flatsedge.
Survey toxicity index (ATI)=(standard agent EC50/ reagent agent EC50) * 100
B in the percentage composition+B medicament toxicity index * mixture of A in theoretical toxicity index (TTI)=A medicament toxicity index * mixture
Percentage composition
Co-toxicity coefficient (CTC)=[mixture surveys toxicity index (ATI)/mixtures theoretical toxicity index (TTI)] * 100
CTC≤80, composition show as antagonism, 80 < CTC < 120, and composition shows as summation action, CTC >=120,
Composition shows as synergistic effect.
The toxicity test interpretation of result of 1 nutgrass flatsedge of table
In table, X refers to orthosulfamuron, and Y refers to 12- ((5- methoxyl group -2- ((4- methoxy pyrimidine -2- base) oxygroup) benzoyl)
Oxygroup) lauryl sodium sulfate.
The result shows that orthosulfamuron and 2- pyrimidine oxy-benzoic acid derivative are between proportion 10:1 ~ 1:20, poison is altogether
Number illustrates that orthosulfamuron compounds preventing and kill off with aobvious to Amaranthus retroflexus with 2- pyrimidine oxy-benzoic acid derivative 120 or more
The synergistic function of work.
6 field control effectiveness test of embodiment
Medicament: herbicide prepared by embodiment 1 ~ 4,50% orthosulfamuron water dispersible granules.
Crop: rice.Rice seedlings grow fine, robust plant, without other pest and disease damages.
Control object: the weeds such as barnyard grass, clearvers, Veronica, Monochoria vaginalis, mexicana.
Test method:
According to the area of experimental plot, the good various medicaments of precise, and after being watered dilution, knapsack sprayer is utilized, is carried out
Even spraying.When spraying, it should be noted that the phenomenon that uniformly spraying application in experimental plot medical fluid, accomplishing no drain spray, more sprays.
20 days observation weeds death conditions after medicine, and the activity of weeding of more various medicaments.In addition, also to observe crop
Growing state, whether have phytotoxicity to investigate medicament to crop.
Test result:
2 field control effectiveness test result of table (after medicine 20 days)
It lives the results show that orthosulfamuron compounds to have to expand herbicidal spectrum and improve weeding with 2- pyrimidine oxy-benzoic acid derivative
Property effect, can effectively prevent and kill off broadleaf weeds and gramineae weed, preventive effect is better than the preventive effect of single dose, both illustrates compounding
There is significant synergistic effect to the preventive effect of broadleaf weeds in paddy field and gramineae weed.
The rice is doing well in each experimental plot, has no any medicine spot, illustrates that various medicaments are safe to rice.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
Member, under the premise of not departing from the method for the present invention, can also make several improvement and supplement, these are improved and supplement also should be regarded as
Protection scope of the present invention.
Claims (8)
1. a kind of Herbicidal combinations, which is characterized in that the effective component in the Herbicidal combinations is orthosulfamuron and 2-
The weight ratio of pyrimidine oxy-benzoic acid derivative, orthosulfamuron and 2- pyrimidine oxy-benzoic acid derivative is 20:1 ~ 1:10,2-
Pyrimidine oxy-benzoic acid derivative is 12- ((5- methoxyl group -2- ((4- methoxy pyrimidine -2- base) oxygroup) benzoyl) oxygroup)
Lauryl sodium sulfate.
2. Herbicidal combinations according to claim 1, which is characterized in that orthosulfamuron and 2- pyrimidine oxy-benzoic acid spread out
The weight ratio of biology is 10:1 ~ 1:5.
3. Herbicidal combinations according to claim 1, which is characterized in that orthosulfamuron and 2- pyrimidine oxy-benzoic acid spread out
The weight ratio of biology is 1:1.
4. Herbicidal combinations according to claim 1, which is characterized in that orthosulfamuron and 2- pyrimidine oxy-benzoic acid spread out
The weight ratio of biology is 3:1.
5. Herbicidal combinations according to claim 1, which is characterized in that orthosulfamuron and 2- pyrimidine oxy-benzoic acid spread out
The weight ratio of biology is 5:1.
6. Herbicidal combinations according to claim 1, which is characterized in that also include plant protection in the Herbicidal combinations
In acceptable auxiliary agent and/or carrier.
7. the application in described in any item Herbicidal combinations prevention and treatment crop weeds according to claim 1 ~ 6.
8. a kind of method for preventing and treating crop weeds, which is characterized in that by Herbicidal combination described in any one of claim 1 ~ 6
The effective component orthosulfamuron and 2- pyrimidine oxy-benzoic acid derivative of object be applied to together or separately plant, plant parts,
The region of vegetable seeds or plant growth.
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CN201910696961.3A CN110292046A (en) | 2019-07-30 | 2019-07-30 | A kind of Herbicidal combinations |
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CN201910696961.3A CN110292046A (en) | 2019-07-30 | 2019-07-30 | A kind of Herbicidal combinations |
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106857616A (en) * | 2017-04-14 | 2017-06-20 | 江苏莱科化学有限公司 | A kind of Herbicidal combinations containing orthosulfamuron Yu bispyribac-sodium |
CN106946794A (en) * | 2017-05-11 | 2017-07-14 | 赣南师范大学 | A kind of 2 pyrimidine oxy-benzoic acid derivatives and preparation method thereof and a kind of water surface weeds herbicide |
-
2019
- 2019-07-30 CN CN201910696961.3A patent/CN110292046A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106857616A (en) * | 2017-04-14 | 2017-06-20 | 江苏莱科化学有限公司 | A kind of Herbicidal combinations containing orthosulfamuron Yu bispyribac-sodium |
CN106946794A (en) * | 2017-05-11 | 2017-07-14 | 赣南师范大学 | A kind of 2 pyrimidine oxy-benzoic acid derivatives and preparation method thereof and a kind of water surface weeds herbicide |
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