CN110423517A - Sunlight-variable anti-counterfeiting ink - Google Patents

Sunlight-variable anti-counterfeiting ink Download PDF

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Publication number
CN110423517A
CN110423517A CN201910629155.4A CN201910629155A CN110423517A CN 110423517 A CN110423517 A CN 110423517A CN 201910629155 A CN201910629155 A CN 201910629155A CN 110423517 A CN110423517 A CN 110423517A
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CN
China
Prior art keywords
parts
counterfeiting
ink
printing ink
false proof
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910629155.4A
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Chinese (zh)
Inventor
任强
曾凡庚
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Hubei Zhongbei Industry And Trade Co ltd
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Hubei Zhongbei Industry And Trade Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Hubei Zhongbei Industry And Trade Co ltd filed Critical Hubei Zhongbei Industry And Trade Co ltd
Priority to CN201910629155.4A priority Critical patent/CN110423517A/en
Publication of CN110423517A publication Critical patent/CN110423517A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/50Sympathetic, colour changing or similar inks

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention provides a sunlight-variable anti-counterfeiting ink, and relates to anti-counterfeiting ink. The invention relates to a sunlight-variable anti-counterfeiting ink which comprises the following components in parts by weight: 8-16 parts of magnetic pigment flakes, 45-60 parts of resin, 4-8 parts of diallyl phthalate, 15-23 parts of sulfonic acid compounds, 5-10 parts of hydroxy acid ester, 5-9.5 parts of water-soluble auxiliary agent and 7-11 parts of cosolvent. The invention provides a sunlight-variable anti-counterfeiting ink, which utilizes the magnetism of magnetic pigment flakes to adjust the arrangement direction and the arrangement patterns of the magnetic pigment flakes, and can change the color at observation angles of different angles, thereby realizing the anti-counterfeiting effect of color change at the viewing angles; the anti-counterfeiting liquid is added with a substance of which the color changes along with the temperature change, the color changes under the environment of higher temperature, and the anti-counterfeiting liquid is anti-counterfeiting under the dual effects of the photochromic substance and the thermochromic substance, so that the anti-counterfeiting liquid has a good anti-counterfeiting effect and is not easy to imitate by others.

Description

A kind of day light variation false proof printing ink
Technical field
The present invention relates to anti-forgery inks, and in particular to a kind of day light variation false proof printing ink.
Background technique
False proof printing ink is a pith in anti-counterfeiting technology, and anti-forgery ink refers to anti-fraud functional oil Ink, the ink are made of colorant, link stuff and ink addition agent, i.e., the anti-fake material of property is added in ink vehicle And the special printing inks being process through special process.Why it can be anti-fake, is to utilize the color for having specific function in ink Material and link stuff come anti-fake.By applying different external condition, mainly using forms such as illumination, heating, spectral detections, come The color change for observing ink pull, achievees the purpose that anti-fake.
Photochromatic printing ink is also known as optical disclour printing ink and chameleon, and a pair of of color is presented in printing color lump, such as: red-green, green- Indigo plant, Jin-silver etc..It is just being seen under white light or side view, with the change at human eye visual angle, two different colors is being presented, light becomes characteristic By force, chromatic aberration is big, and feature is obvious, and not needing any instrument and equipment can identify, color angular effect can not be with any Scanner, color copy machine and other device replications high-definition, any other ink of print characteristics and mode of printing are all Can not imitate, anti-fake reliability is extremely strong, so by multiple countries in the world specify for require most tight, the maximum currency of difficulty and Marketable securities it is anti-fake on, domestic some famous producers also have been used for package anti-counterfeiting.
Photochromatic printing ink is of practical significance very much in the application of field of anti-counterfeit technology, and anti-counterfeiting information can be hidden in ink shape At conjunction crowd's pattern in.Photochromatic printing ink in the prior art often can only by convert angle recognition, range function just with Reflection optically, refraction, belong to that monotechnics are anti-fake, others is easy to imitate, and anti-counterfeiting performance is weaker.
Summary of the invention
In view of this, the present invention provides a kind of day light variation false proof printing ink, its arrangement is adjusted using the magnetism of magnetic pigment flakes Direction, arrangement pattern, the variation of color can occur in the viewing angle of different angle, realize visual angle color-changing anti-counterfeit;Add color The variation of color occurs in the environment of higher temperature for the substance for varying with temperature and changing, in phototropic substance, Wen Bianse object Carry out anti-fake under the double action of matter, antifalse effect is good, others is not easy to imitate.
The present invention is a kind of day light variation false proof printing ink, by weight includes following components: 8-16 parts of magnetic pigment flakes, tree 45-60 parts of rouge, 4-8 parts of diallyl phthalate, 15-23 parts of sulfonic compound, 5-10 parts of hydroxy acid rouge, water-soluble additive 5-9.5 parts, 7-11 parts of cosolvent.
Preferably, the magnetic pigment flakes can be one of ferroso-ferric oxide, di-iron trioxide, such as can be with For ferroso-ferric oxide (black).The color of magnetic pigment flakes may will affect the color of the pigment of other colour systems, but of the invention It is emphasised that anti-fake effect can be played, color is the mixing of multicolour, without primary and secondary point.Magnetic paint Piece can be arranged into certain group under the magnetic effect of another magnet using the magnetic of its own in ink layer, hide anti-fake Mark.Resin is as constitutive material important in ink, and as binder, the performance of resin directly affects the ink film of ink formation Quality, and in printing process ink adhesion, viscosity etc..Resin can be water-based acrylic resin cream in the present invention One of liquid, chlorination PP resin emulsion, chlorination PE resin emulsion are a variety of, such as can be water-based acrylic resin lotion.
Diallyl phthalate, sulfonic compound, hydroxy acid rouge form warm variable color system, the temperature change the case where Lower diallyl phthalate can discharge electronics to sulfonic compound, and sulfonic compound is used as by electron species, determine Variation later color.Hydroxy acid rouge is used to be to be able to effectively reduce discoloring temperature as solvent, with realize can be Discoloration under stronger sunshine.Ink is irradiated in the case where sunny can cause the raising of ink temperature so as to cause color Variation, but just ink can only be made to change colour by way of auxiliary heating in the insufficient situation of sunlight.The sulfonic acid Class compound is aryl sulfonic acid compound, and the aryl sulfonic acid compound can be one in benzene sulfonic acid, p-methyl benzenesulfonic acid sodium Kind or two kinds.
Suitable some pigment can be added to increase the chromaticity of ink, by weight further include 1-3 parts of pigment, The pigment is one of titanium dioxide, pearl powder, zinc yellow, Lithol Red or a variety of.The additive amount of pigment cannot be excessive In order to avoid influencing the sensibility of the color change of temperature discoloration base.It need to be noted that be warm variable color system in temperature change Shi Huifa Entire ink system apparent color can occur for the variation of raw color when adding some a small amount of pigment in temperature change Variation.
Ink in the present invention needs when in use through magnetic orientation device when ink is not dry in ink It is formed in layer and thinks specific magnetic field, magnetic orientation is carried out to magnetic pigment flakes, so that different angles is presented in ink layer different zones Direction is spent, magnetic pigment flakes generate the magnetic orientation pattern of effect unique in ink layer.Under the reflex of light, face enters The magnetic pigment flakes of firing angle are capable of reflecting light, and display color, brightness are higher, and the magnetic paint sector-meeting not faced is darker, are seen Less than the color of magnetic paint on piece.
Antifalse effect belongs to double anti-forge, is not easy to imitate, and the anti-fake item authentication for coating ink of the present invention is true and false: first It takes and is irradiated under daylight, convert viewing angle, bright or color the variation of security pattern is observed, if intensity of illumination is stronger Directly article is put into irradiate under sunlight and observes whole color change situation for a moment, anti-fake color-shifting images is found, if illumination It does not need then artificially to heat article by force.
Water-soluble additive, cosolvent are used in common ink, if water-soluble additive can be the poly- diformazan of dispersing agent Radical siloxane, defoaming agent are silicone emulsion, and cosolvent is ethyl alcohol.
The present invention provides a kind of day light variation false proof printing ink, adjusts its orientation, arrangement using the magnetism of magnetic pigment flakes The variation of color can occur in the viewing angle of different angle for pattern, realize visual angle color-changing anti-counterfeit;Addition color varies with temperature And the substance changed, the variation of color occurs in the environment of higher temperature, in phototropic substance, the dual work of warm electrochromic substance Carried out under anti-fake, antifalse effect is good, others is not easy to imitate.
Specific embodiment
The present invention will be described in detail With reference to embodiment.
Embodiment 1
A kind of day light variation false proof printing ink includes following components: 8 parts of Fe 3 O 4 magnetic pigment flakes, aqueous third by weight 45 portions of olefin(e) acid resin emulsion, 15 parts of benzene sulfonic acid, 5 parts of hydroxy acid rouge, 5 parts of water-soluble additive, helps 4 parts of diallyl phthalate 7 parts of solvent, 1 part of titanium dioxide.
Ink in the present embodiment is sprayed on product surface and carries out the drafting of security pattern using magnetisable material, it is dry It after solidification, looks for 50 people at random in the case where fine day, them is allowed to observe anti-counterfeiting mark, judge that whether obvious (from 3 daylight becomes The observation of a angle, left side, right side, centre), product is exposed to the sun the 15-30 people in the sunlight, observation color changeable effect is how, statistics knot Fruit is as follows,
Embodiment 2
A kind of day light variation false proof printing ink includes following components: 16 parts of di-iron trioxide magnetic pigment flakes, chlorination PP by weight 60 parts of resin emulsion, 8 parts of diallyl phthalate, 23 parts of p-methyl benzenesulfonic acid sodium, 10 parts of hydroxy acid rouge, water-soluble additive 9.5 parts, 11 parts of cosolvent, 3 parts of pearl powder.
Ink in the present embodiment is sprayed on product surface and carries out the drafting of security pattern using magnetisable material, it is dry It after solidification, looks for 50 people at random in the case where fine day, them is allowed to observe anti-counterfeiting mark, judge that whether obvious (from 3 daylight becomes The observation of a angle, left side, right side, centre), product is exposed to the sun the 15-30 people in the sunlight, observation color changeable effect is how, statistics knot Fruit is as follows,
Embodiment 3
A kind of day light variation false proof printing ink includes following components: 10 parts of Fe 3 O 4 magnetic pigment flakes, chlorination PE by weight 50 parts of resin emulsion, 6 parts of diallyl phthalate, 20 parts of p-methyl benzenesulfonic acid sodium, 8 parts of hydroxy acid rouge, water-soluble additive 8 Part, 9 parts of cosolvent, 1.2 parts of zinc yellow.
Ink in the present embodiment is sprayed on product surface and carries out the drafting of security pattern using magnetisable material, it is dry It after solidification, looks for 50 people at random in the case where fine day, them is allowed to observe anti-counterfeiting mark, judge that whether obvious (from 3 daylight becomes The observation of a angle, left side, right side, centre), product is exposed to the sun the 15-30 people in the sunlight, observation color changeable effect is how, statistics knot Fruit is as follows,
Embodiment 4
A kind of day light variation false proof printing ink includes following components: 8-16 parts of di-iron trioxide magnetic pigment flakes, aqueous by weight 55 parts of emulsion acrylic resin, 7 parts of diallyl phthalate, 20 parts of p-methyl benzenesulfonic acid, hydroxy acid rouge 7, water-soluble additive 6 Part, 7 parts of cosolvent, 2 parts of Lithol Red pigment.
Ink in the present embodiment is sprayed on product surface and carries out the drafting of security pattern using magnetisable material, it is dry It after solidification, looks for 50 people at random in the case where fine day, them is allowed to observe anti-counterfeiting mark, judge that whether obvious (from 3 daylight becomes The observation of a angle, left side, right side, centre), product is exposed to the sun the 15-30 people in the sunlight, observation color changeable effect is how, statistics knot Fruit is as follows,
Embodiment 5
A kind of day light variation false proof printing ink includes following components: 10 parts of di-iron trioxide magnetic pigment flakes, aqueous third by weight 60 parts of olefin(e) acid resin emulsion, 8 parts of diallyl phthalate, benzene sulfonic acid, 22 parts of p-methyl benzenesulfonic acid sodium, hydroxy acid rouge 10, water 8 parts of soluble builder, 10 parts of cosolvent.
Ink in the present embodiment is sprayed on product surface and carries out the drafting of security pattern using magnetisable material, it is dry It after solidification, looks for 50 people at random in the case where fine day, them is allowed to observe anti-counterfeiting mark, judge that whether obvious (from 3 daylight becomes The observation of a angle, left side, right side, centre), product is exposed to the sun the 15-30 people in the sunlight, observation color changeable effect is how, statistics knot Fruit is as follows,
The present invention provides a kind of day light variation false proof printing ink, adjusts its orientation, arrangement pattern using the magnetism of magnetic pigment flakes, The variation of color can occur in the viewing angle of different angle, realize visual angle color-changing anti-counterfeit;Addition color varies with temperature and becomes The variation of color occurs in the environment of higher temperature for the substance of change, phototropic substance, warm electrochromic substance double action under Carry out anti-fake, antifalse effect is good, others is not easy to imitate.
The present invention is not limited to above-mentioned specific embodiment, and the invention may be variously modified and varied.All foundations Technical spirit of the invention should be included in the present invention to embodiment of above any modification, equivalent replacement, improvement and so on Protection scope.

Claims (7)

1. a kind of day light variation false proof printing ink, which is characterized in that by weight include following components: 8-16 parts of magnetic pigment flakes, 45-60 parts of resin, 4-8 parts of diallyl phthalate, 15-23 parts of sulfonic compound, 5-10 parts of hydroxy acid rouge, water solubility help 5-9.5 parts of agent, 7-11 parts of cosolvent.
2. a kind of day light variation false proof printing ink according to claim 1, which is characterized in that the magnetic pigment flakes are four oxidations One of three-iron, di-iron trioxide.
3. a kind of day light variation false proof printing ink according to claim 1, which is characterized in that by weight further include pigment 1- 3 parts.
4. a kind of day light variation false proof printing ink according to claim 3, which is characterized in that the pigment is titanium dioxide, pearly-lustre One of powder, zinc yellow, Lithol Red are a variety of.
5. a kind of day light variation false proof printing ink according to claim 1, which is characterized in that the resin is water soluble acrylic acid tree One of fat liquor, chlorination PP resin emulsion, chlorination PE resin emulsion are a variety of.
6. a kind of day light variation false proof printing ink according to claim 1, which is characterized in that the sulfonic compound is aryl Sulfoacid compound.
7. a kind of day light variation false proof printing ink according to claim 6, which is characterized in that the aryl sulfonic acid compound is benzene One or both of sulfonic acid, p-methyl benzenesulfonic acid sodium.
CN201910629155.4A 2019-07-12 2019-07-12 Sunlight-variable anti-counterfeiting ink Pending CN110423517A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910629155.4A CN110423517A (en) 2019-07-12 2019-07-12 Sunlight-variable anti-counterfeiting ink

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910629155.4A CN110423517A (en) 2019-07-12 2019-07-12 Sunlight-variable anti-counterfeiting ink

Publications (1)

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CN110423517A true CN110423517A (en) 2019-11-08

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102649890A (en) * 2012-04-28 2012-08-29 武汉虹之彩包装印刷有限公司 Solvent type optically variable anti-counterfeiting ink applicable to different printing modes

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102649890A (en) * 2012-04-28 2012-08-29 武汉虹之彩包装印刷有限公司 Solvent type optically variable anti-counterfeiting ink applicable to different printing modes

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
张团红: "高温可逆热致变色材料的微胶囊化研究", 《中国优秀硕士学位论文全文数据库 工程科技I辑》 *
谢艳招等: "磁性光变油墨及其在防伪中的应用", 《包装工程》 *
高道德等: "《烟草科普知识读本》", 30 September 2010, 湖北科学技术出版社 *

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Application publication date: 20191108