CN110423107A - 一种灭菌陶瓷板及其制备方法 - Google Patents

一种灭菌陶瓷板及其制备方法 Download PDF

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CN110423107A
CN110423107A CN201910480858.5A CN201910480858A CN110423107A CN 110423107 A CN110423107 A CN 110423107A CN 201910480858 A CN201910480858 A CN 201910480858A CN 110423107 A CN110423107 A CN 110423107A
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卢高峰
卢禹杞
郭绍义
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Yixing Minghaote Porcelain Technology Co Ltd
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Abstract

本发明公开了一种灭菌陶瓷板及其制备方法,所述灭菌陶瓷板原料组成包括堇青石10%‑15%、莫来石30%‑45%、高铝质18%‑35%、粘结剂5%‑10%、硫酸铜0.2%‑0.6%、氧化钛0.4%‑1%以及适量水,本发明采用该方法制备的陶瓷板具有很好的吸水率,3组实施例的平均吸水率和硬度,使用寿命较长,陶瓷板的成品率较高,易于加工推广,无刺激性异味,抗菌率高达99.9%,硫酸铜中的Cu+具有一定的杀菌效果,对动物没有伤害,同时具有很好的灭菌效果,很好地避免了因宠物与人接触的过程中把细菌传到人体身上,陶瓷板表面涂覆有氧化钛层,可以起到抗菌和自洁净的效果,具有很好的应用前景。

Description

一种灭菌陶瓷板及其制备方法
技术领域
本发明涉及陶瓷技术领域,具体为一种灭菌陶瓷板及其制备方法。
背景技术
如今,饲养宠物的热潮正在我国的都市里悄悄兴起,随着宠物队伍的日 益壮大,一支新兴的产业——宠物产业也正如冰山浮出水面。比起宠物养殖, 宠物食品、用品的生产销售似乎要灵活许多,在整个宠物业中也显得比较突 出。目前我国已拥有一定数量的宠物食品、用品、玩具等厂家,大部分起步 于20世纪90年代。如果以上海为例,每个宠物的食品与用品每月按50元 计算,市民每年用于宠物的开支也有6亿元之巨。而实际上就犬、猫而言, 每月50元是十分经济型的消费,如果带宠物定期上美容院或进趟诊所医院, 外加专门的宠物食品、宠物玩具等,奢侈型的消费就要逾千元。随着经济的 发展,人民生活水平的提高,宠物消费无疑会呈增长趋势。
宠物与人类的共患病一般有弓形虫、狂犬病、布氏杆菌、钩端螺旋体、 大肠杆菌、沙门氏菌等等。狂犬病打疫苗就可以预防,而其他病菌和寄生虫 只要讲究卫生,不要跟宠物有过分亲密的接触,根本难以传染给你。例如弓 形虫,传播途径只有误食卵囊、吃受污染生肉,或速殖子/缓殖子进入损伤皮 肤、粘膜才会感染弓形虫;人与宠物接触的过程中,宠物身上的细菌往往会 传到人体身上,对人体健康安全造成一定隐患,一般的宠物用具表面容易产 生积水,进而会导致宠物用具表面滋生细菌,不利于宠物的健康成长等问题。
针对上述陶瓷板中存在的技术缺陷,发明一种灭菌陶瓷板及其制备方法, 去解决上述问题,很有应用前景。
发明内容
本发明的目的在于提供一种灭菌陶瓷板及其制备方法,该灭菌陶瓷板及其制备方法具体如下:所述灭菌陶瓷板原料组成包括堇青石、莫来石、高铝质、粘结剂、硫酸铜、氧化钛、水,按照以下各组分质量百分比进行称量:
堇青石 10%-15%;
莫来石 30%-45%;
高铝质 18%-35%;
粘结剂 5%-10%;
硫酸铜 0.2%-0.6%;
氧化钛 0.4%-1%。。
作为优选的,所述堇青石的粒度大小为30~50目,莫来石的粒度大小为50~70目,高铝质的粒度大小为70~90目,粘结剂的粒度大小为90~110目。
本发明还提供一种灭菌陶瓷板及其制备方法,包括如下步骤:
S1:将堇青石、莫来石、高铝质、粘结剂、硫酸铜、氧化钛分别喷雾干燥后进行颗粒粉碎,随后进行过滤、除铁,备用;
S2:将S1中的原料加水进行搅拌混合,陈腐36~64小时,备用;
S3:将S2中的混合料进行压制成型、轻压排气、重压排气、重压成型后制备成陶瓷板坯体;
S4:将S3中的坯体放在窑炉内烧制成品,最后进行抛光;
S5:将S4中的成品表面涂覆一层氧化钛并进行烘烤成灭菌层,进行封装。
作为优选的,所述S4中陶瓷板的烧制温度为1100℃~1400℃,烧制时间为10~12小时。
作为优选的,所述陶瓷板的吸收率为15%~18%。
作为优选的,所述氧化钛按照1g-5g/m2的比例均匀涂覆在在陶瓷板表面。
与现有技术相比,本发明的有益效果是:
1、本发明采用该方法制备的陶瓷板具有很好的吸水率,3组实施例的平均吸水率和硬度,使用寿命较长,陶瓷板的成品率较高,易于加工推广,无刺激性异味,抗菌率高达99.9%,硫酸铜中的Cu+具有一定的杀菌效果,对动物没有伤害,同时具有很好的灭菌效果,很好地避免了因宠物与人接触的过程中把细菌传到人体身上,陶瓷板表面涂覆有氧化钛层,可以起到抗菌和自洁净的效果,具有很好的应用前景。
具体实施方式
为了使本发明的目的、技术方案及优点更加清楚明白,以下结合具体实施例,对本发明进行进一步详细说明。应当理解,此处所描述的具体实施例仅仅用以解释本发明,并不用于限定本发明。
实施例1
一种灭菌陶瓷板,所述灭菌陶瓷板原料组成包括堇青石、莫来石、高铝质、粘结剂、硫酸铜、氧化钛、水,按照以下各组分质量百分比进行称量:
堇青石 10%;
莫来石 30%;
高铝质 18%;
粘结剂 5%;
硫酸铜 0.2%;
氧化钛 0.4%。
本实施例的灭菌陶瓷板制备方法,包括如下步骤:
S1:将堇青石、莫来石、高铝质、粘结剂、硫酸铜、氧化钛分别喷雾干燥后进行颗粒粉碎,随后进行过滤、除铁,备用;
S2:将S1中的原料加水进行搅拌混合,陈腐36~64小时,备用;
S3:将S2中的混合料进行压制成型、轻压排气、重压排气、重压成型后制备成陶瓷板坯体;
S4:将S3中的坯体放在窑炉内烧制成品,最后进行抛光;
S5:将S4中的成品表面涂覆一层氧化钛并进行烘烤成灭菌层,进行封装。
所述S4中陶瓷板的烧制温度为1100℃,烧制时间为10小时,可以避免陶瓷板上出现黑白点现象,烧制时间为10小时。
所述陶瓷板的吸收率为15%~18%。
所述氧化钛按照1g/m2的比例均匀涂覆在在陶瓷板表面。
实施例2
一种灭菌陶瓷板,所述灭菌陶瓷板原料组成包括堇青石、莫来石、高铝质、粘结剂、硫酸铜、氧化钛、水,按照以下各组分质量百分比进行称量:
堇青石 12%;
莫来石 38%;
高铝质 25%;
粘结剂 8%;
硫酸铜 0.4%;
氧化钛 0.6%。
本实施例的灭菌陶瓷板制备方法,包括如下步骤:
S1:将堇青石、莫来石、高铝质、粘结剂、硫酸铜、氧化钛分别喷雾干燥后进行颗粒粉碎,随后进行过滤、除铁,备用;
S2:将S1中的原料加水进行搅拌混合,陈腐48小时,备用;
S3:将S2中的混合料进行压制成型、轻压排气、重压排气、重压成型后制备成陶瓷板坯体;
S4:将S3中的坯体放在窑炉内烧制成品,最后进行抛光;
S5:将S4中的成品表面涂覆一层氧化钛并进行烘烤成灭菌层,进行封装。
所述S4中陶瓷板的烧制温度为1200℃,烧制时间为11小时,可以避免陶瓷板上出现黑白点现象,烧制时间为11小时。
所述陶瓷板的吸收率为15%~18%。
所述氧化钛按照3g/m2的比例均匀涂覆在在陶瓷板表面。
实施例3
一种灭菌陶瓷板,所述灭菌陶瓷板原料组成包括堇青石、莫来石、高铝质、粘结剂、硫酸铜、氧化钛、水,按照以下各组分质量百分比进行称量:
堇青石 15%;
莫来石 45%;
高铝质 35%;
粘结剂 10%;
硫酸铜 0.6%;
氧化钛 1%。
本实施例的灭菌陶瓷板制备方法,包括如下步骤:
S1:将堇青石、莫来石、高铝质、粘结剂、硫酸铜、氧化钛分别喷雾干燥后进行颗粒粉碎,随后进行过滤、除铁,备用;
S2:将S1中的原料加水进行搅拌混合,陈腐64小时,备用;
S3:将S2中的混合料进行压制成型、轻压排气、重压排气、重压成型后制备成陶瓷板坯体;
S4:将S3中的坯体放在窑炉内烧制成品,最后进行抛光;
S5:将S4中的成品表面涂覆一层氧化钛并进行烘烤成灭菌层,进行封装。
所述S4中陶瓷板的烧制温度为1400℃,烧制时间为12小时,可以避免陶瓷板上出现黑白点现象,烧制时间为12小时。
所述陶瓷板的吸收率为15%~18%。
所述氧化钛按照5g/m2的比例均匀涂覆在在陶瓷板表面。
对实施例1-3中所制备的陶瓷板,按照《陶瓷砖》(GBT4100-2015)“的标准,测得数据如下表:
检测项目 实施例1 实施例2 实施例3
吸水率 E>3% 17.9% 17.8% 18.5%
断裂模数:≥28 [N/mm<sup>2</sup>(MPa)] 36.3 37.6 37.1
成品率(%) 99.8% 99.4% 99.7%
抗菌率(%) 99.93% 99.96% 99.91%
刺激性试验 无刺激 无刺激 无刺激
异味性试验 无异味 无异味 无异味
毒性性实验 无毒 无毒 无毒
由上述表格易知:采用该方法制备的陶瓷板具有很好的吸水率,3组实施例的平均吸水率为18.1%,远高于国家标准规定,3组实施例的断裂模数平均值接近37,表现出较好的强度性能,陶瓷板的成品率较高,易于加工推广,无刺激性异味,抗菌率高达99.9%,硫酸铜中的Cu+具有一定的杀菌效果,对动物没有伤害,同时具有很好的灭菌效果,很好地避免了因宠物与人接触的过程中把细菌传到人体身上,陶瓷板表面涂覆有氧化钛层,可以起到抗菌和自洁净的效果,具有很好的应用前景。
以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,根据本发明的技术方案及其发明构思加以等同替换或改变,都应涵盖在本发明的保护范围之内。

Claims (6)

1.一种灭菌陶瓷板,其特征在于,所述灭菌陶瓷板原料组成包括堇青石、莫来石、高铝质、粘结剂、硫酸铜、氧化钛、水,按照以下各组分质量百分比进行称量:
堇青石 10%-15%;
莫来石 30%-45%;
高铝质 18%-35%;
粘结剂 5%-10%;
硫酸铜 0.2%-0.6%;
氧化钛 0.4%-1%。
2.根据权利要求1所述的一种灭菌陶瓷板,其特征在于,所述堇青石的粒度大小为30~50目,莫来石的粒度大小为50~70目,高铝质的粒度大小为70~90目,粘结剂的粒度大小为90~110目。
3.根据权利要求1所述的一种灭菌陶瓷板及其制备方法,其特征在于,包括如下步骤:
S1:将堇青石、莫来石、高铝质、粘结剂、硫酸铜、氧化钛分别喷雾干燥后进行颗粒粉碎,随后进行过滤、除铁,备用;
S2:将S1中的原料加水进行搅拌混合,陈腐36~64小时,备用;
S3:将S2中的混合料进行压制成型、轻压排气、重压排气、重压成型后制备成陶瓷板坯体;
S4:将S3中的坯体放在窑炉内烧制成品,最后进行抛光;
S5:将S4中的成品表面涂覆一层氧化钛并进行烘烤成灭菌层,进行封装。
4.根据权利要求3所述的一种灭菌陶瓷板及其制备方法,其特征在于,所述S4中陶瓷板的烧制温度为1100℃~1400℃,烧制时间为10~12小时。
5.根据权利要求1所述的一种灭菌陶瓷板及其制备方法,其特征在于,所述陶瓷板的吸收率为15%~18%。
6.根据权利要求1所述的一种灭菌陶瓷板及其制备方法,其特征在于,所述氧化钛按照1g-5g/m2的比例均匀涂覆在在陶瓷板表面。
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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0271717A (ja) * 1988-09-06 1990-03-12 Eiwa Kasei Kogyo Kk 抗菌性俎
EP2088134A1 (en) * 2007-12-19 2009-08-12 Imerys Kiln Furniture Hungary Ltd.hu Lightweight Ceramic Material
CN101886256A (zh) * 2010-07-09 2010-11-17 辽宁工程技术大学 镁合金表面Ni-Cu-P/纳米TiO2化学复合镀层的制备方法
CN103524122A (zh) * 2013-09-27 2014-01-22 湖南嘉盛电陶新材料股份有限公司 一种微波炉用快速合成堇青石免抛陶瓷薄板及其制作方法
CN104692820A (zh) * 2015-03-02 2015-06-10 营口瑞德镁质材料科技有限公司 一种高温致密的不烧复合砖及其成型工艺
CN108218392A (zh) * 2018-01-30 2018-06-29 福建省德化县福庆陶瓷有限公司 一种低膨胀防粘抗菌陶瓷锅及其制造工艺
CN109400215A (zh) * 2018-11-19 2019-03-01 北京崇高纳米科技有限公司 一种表面抗菌陶瓷的制备方法和应用

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0271717A (ja) * 1988-09-06 1990-03-12 Eiwa Kasei Kogyo Kk 抗菌性俎
EP2088134A1 (en) * 2007-12-19 2009-08-12 Imerys Kiln Furniture Hungary Ltd.hu Lightweight Ceramic Material
CN101886256A (zh) * 2010-07-09 2010-11-17 辽宁工程技术大学 镁合金表面Ni-Cu-P/纳米TiO2化学复合镀层的制备方法
CN103524122A (zh) * 2013-09-27 2014-01-22 湖南嘉盛电陶新材料股份有限公司 一种微波炉用快速合成堇青石免抛陶瓷薄板及其制作方法
CN104692820A (zh) * 2015-03-02 2015-06-10 营口瑞德镁质材料科技有限公司 一种高温致密的不烧复合砖及其成型工艺
CN108218392A (zh) * 2018-01-30 2018-06-29 福建省德化县福庆陶瓷有限公司 一种低膨胀防粘抗菌陶瓷锅及其制造工艺
CN109400215A (zh) * 2018-11-19 2019-03-01 北京崇高纳米科技有限公司 一种表面抗菌陶瓷的制备方法和应用

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
邱小林: "《现代建筑材料科学》", 30 September 2014, 东南大学出版社 *

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