CN110396335A - A kind of environment-friendly water-based oil polish of high glaze and preparation method thereof - Google Patents

A kind of environment-friendly water-based oil polish of high glaze and preparation method thereof Download PDF

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Publication number
CN110396335A
CN110396335A CN201910562349.7A CN201910562349A CN110396335A CN 110396335 A CN110396335 A CN 110396335A CN 201910562349 A CN201910562349 A CN 201910562349A CN 110396335 A CN110396335 A CN 110396335A
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CN
China
Prior art keywords
water
environment
high glaze
based oil
oil polish
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Pending
Application number
CN201910562349.7A
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Chinese (zh)
Inventor
曾家明
曾志平
吴松恩
钟永红
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FOSHAN GREEN COLOR PRINTING Co Ltd
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FOSHAN GREEN COLOR PRINTING Co Ltd
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Priority to CN201910562349.7A priority Critical patent/CN110396335A/en
Publication of CN110396335A publication Critical patent/CN110396335A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention discloses a kind of environment-friendly water-based oil polish of high glaze, including following component and its parts by weight percentage: water-based acrylic resin 30%-34%;Ethyl acrylate modified aqueous polyurethane 7%-10%;High-melting-point oxidized polyethylene wax emulsion 5%-7%;Deionized water 21%-24%;Ethylene glycol 10%-14%;Propylene glycol 8%-10%;Ethyl alcohol 2%-4%;Glycerol 1%-1.5%;Dioctyl phthalate 1%-1.5%;Water-soluble aldehyde ketone resin liquid 1.5%-2%;Optical brightener 0.5%-1%;Water lustering oil of the present invention can not only keep its feature of environmental protection but also glossiness can be improved;Separately the present invention also provides a kind of implementations to be easy, quick, and the water lustering oil preparation method of high glaze is made.

Description

A kind of environment-friendly water-based oil polish of high glaze and preparation method thereof
Technical field
The present invention relates to environment-friendly water-based oil polish technical field, the environment-friendly water-based oil polish of especially a kind of high glaze and its system Preparation Method.
Background technique
With the continuous improvement of economic progress and living standards of the people, quality requirement and printing industry to printed matter Environmental requirement is continuously improved;Glazing is printing industry using one of maximum technique, is indispensable one in printing industry Point, it is imperative to be developed and improved to it.Water lustering oil belongs to environmental type product, its solvent for use is mainly water With some alcohols, volatile matter does not pollute the environment, and is constantly increased and gradually develops recently as the cry of people's environmental protection Get up, its technology is not mature enough at present, and main problem shows that surface finish is ineffective, and glossiness cannot reach reason Think effect etc..
Summary of the invention
Not only its feature of environmental protection can be kept the object of the present invention is to provide one kind but also the water lustering oil of glossiness can be improved.
Another object of the present invention also reside in provide it is a kind of implement to be easy, be quick, and the environment-friendly water-based glazing of high glaze is made The preparation method of oil.
The object of the present invention is achieved like this:
A kind of environment-friendly water-based oil polish of high glaze, which is characterized in that including following component and its parts by weight percentage:
Water-based acrylic resin 30%-34%;
Ethyl acrylate modified aqueous polyurethane 7%-10%;
High-melting-point oxidized polyethylene wax emulsion 5%-7%;
Deionized water 21%-24%;
Ethylene glycol 10%-14%;
Propylene glycol 8%-10%;
Ethyl alcohol 2%-4%;
Glycerol 1%-1.5%;
Dioctyl phthalate 1%-1.5%;
Water-soluble aldehyde ketone resin liquid 1.5%-2%;
Optical brightener 0.5%-1%.
Water lustering oil includes above-mentioned host agent, solvent and auxiliary agent composition;
Wherein, water-based acrylic resin, with good guarantor's light colour retention, water-fast chemical resistance, fast drying, price is low, uses Safety saves resource and the energy, reduces environmental pollution and is the most important ingredient of water lustering oil the advantages that public hazards;And propylene Acetoacetic ester modified aqueous polyurethane, mixed the good Physical Mechanical of aqueous polyurethane, cold resistance, elasticity, thermal adaptability, The feature of environmental protection and acrylic acid ester emulsion high mechanical strength, it is ageing-resistant, fast light do not turn yellow, water-tolerant the advantages that, the two is learnt from other's strong points to offset one's weaknesses; High-melting-point oxidized polyethylene wax emulsion has outstanding anti scuffing, wear-resisting, gloss and waterproof performance, above-mentioned three kinds of component conducts Host agent.
Deionized water, ethylene glycol, propylene glycol and ethyl alcohol are as solvent, and due to the slow drying speed of water, contemporary solvent is Good gloss, it is most of with 80% ethylene glycol and propylene glycol substitution water, and ignore the excellent of water lustering oil Traditional Environmental-protection Point;In order to keep the feature of environmental protection when optimizing gloss, we reduce the amount of ethylene glycol and propylene glycol, and ethyl alcohol is added in right amount Improve the drying property of solvent.
Glycerol is that wetting agent has good wetting to pigment, increases water solubility;Dioctyl phthalate is plasticizer, energy Make ink that there is soffening, ink itself is made to form the effect of more stable plasticizing film;Water-soluble aldehyde ketone resin liquid is to water down Agent mainly plays desalination color;The brightness that form and aspect can be increased makes color more highlight gorgeous, optical brightener addition and optimizes and revises in right amount Gloss.
It is another object of the present invention to what is be achieved:
A kind of preparation method of the environment-friendly water-based oil polish of high glaze, which comprises the following steps:
S1, water-based acrylic resin, ethyl acrylate modified aqueous polyurethane, the poly- second of high-melting-point oxidation are weighed according to deal proportion Alkene wax emulsion sequentially adds above-mentioned component in reaction kettle, is sufficiently stirred at 70-90 DEG C, persistently stirs 40-80min;
S2, be warming up to 85-95 DEG C to S1, keep the temperature 25-35min, be cooled to 35-45 DEG C thereafter, according to deal proportion weigh from Sub- water, ethylene glycol, propylene glycol, ethyl alcohol are put into reaction kettle, mix slowly 25-35min at 35-45 DEG C;
S3, glycerol, dioctyl phthalate, water-soluble aldehyde ketone resin liquid, optical brightener are put into reaction kettle, at 35-45 DEG C Lower stirring 15-25min;
S4., stand after the completion, filtering and discharging, the environment-friendly water-based oil polish of this high glaze can be obtained.
Beneficial effects of the present invention are as follows:
(1) water lustering oil of the present invention can not only keep its feature of environmental protection but also glossiness can be improved.
(2) preparation method of water lustering oil of the present invention has implementation and is easy, is quick, and it is environment-friendly water-based that high glaze is made The effect of oil polish.
Specific embodiment
The present invention is further described combined with specific embodiments below.
A kind of environment-friendly water-based oil polish of high glaze, including following component and its parts by weight percentage: water-based acrylic resin 30%-34%;Ethyl acrylate modified aqueous polyurethane 7%-10%;High-melting-point oxidized polyethylene wax emulsion 5%-7%;Deionized water 21%-24%;Ethylene glycol 10%-14%;Propylene glycol 8%-10%;Ethyl alcohol 2%-4%;Glycerol 1%-1.5%;Dioctyl phthalate 1%- 1.5%;Water-soluble aldehyde ketone resin liquid 1.5%-2%;Optical brightener 0.5%-1%.
A kind of preparation method of the environment-friendly water-based oil polish of high glaze, which comprises the following steps:
S1, water-based acrylic resin, ethyl acrylate modified aqueous polyurethane, the poly- second of high-melting-point oxidation are weighed according to deal proportion Alkene wax emulsion sequentially adds above-mentioned component in reaction kettle, is sufficiently stirred at 70-90 DEG C, persistently stirs 40-80min;
S2, be warming up to 85-95 DEG C to S1, keep the temperature 25-35min, be cooled to 35-45 DEG C thereafter, according to deal proportion weigh from Sub- water, ethylene glycol, propylene glycol, ethyl alcohol are put into reaction kettle, mix slowly 25-35min at 35-45 DEG C;
S3, glycerol, dioctyl phthalate, water-soluble aldehyde ketone resin liquid, optical brightener are put into reaction kettle, at 35-45 DEG C Lower stirring 15-25min;
S4., stand after the completion, filtering and discharging, the environment-friendly water-based oil polish of this high glaze can be obtained.
Below with regard to above-mentioned preparation method, make following several embodiments:
Embodiment one: a kind of preparation method of the environment-friendly water-based oil polish of high glaze includes the following:
S1, water-based acrylic resin 31%, ethyl acrylate modified aqueous polyurethane 8%, high-melting-point oxygen are weighed according to deal proportion Change polythene wax emulsion 7%, above-mentioned raw materials are sequentially added in reaction kettle, is sufficiently stirred at 80 DEG C, persistently stirs 60min;
S2, it is warming up to 90 DEG C to S1, keeps the temperature 30min, is cooled to 40 DEG C thereafter, weigh deionized water 23%, second according to deal proportion 13.5 glycol 9% of glycol, ethyl alcohol 3 are answered in kettle, 40 DEG C at a temperature of mix slowly 30min;
S3, glycerol 1.5%, dioctyl phthalate 1%, water-soluble aldehyde ketone resin liquid 2%, optical brightener 1% are put into reaction kettle, 20min is stirred at 40 DEG C;
S4., stand after the completion, filtering and discharging, the environment-friendly water-based oil polish of this high glaze can be obtained.
Example two: a kind of preparation method of the environment-friendly water-based oil polish of high glaze includes the following:
S1, water-based acrylic resin 32%, ethyl acrylate modified aqueous polyurethane 9%, high-melting-point oxygen are weighed according to deal proportion Change polythene wax emulsion 6.5%, above-mentioned raw materials are sequentially added in reaction kettle, is sufficiently stirred at 80 DEG C, persistently stirs 60min;
S2,90 DEG C are warming up to S1,30min is kept the temperature, is cooled to 40 DEG C thereafter, according to deal proportion weigh deionized water 22.5%, Ethylene glycol 14%, propylene glycol 8.5%, ethyl alcohol 2.5% are put into reaction kettle, 40 DEG C at a temperature of mix slowly 30min;
S3, glycerol 1%, dioctyl phthalate 1.5%, water-soluble aldehyde ketone resin liquid 1.7%, optical brightener 0.8% are put into reaction In kettle, 40 DEG C at a temperature of stir 20min;
S4., stand after the completion, filtering and discharging, the environment-friendly water-based oil polish of this high glaze can be obtained.
Example three: a kind of preparation method of the environment-friendly water-based oil polish of high glaze includes the following:
S1, water-based acrylic resin 33%, ethyl acrylate modified aqueous polyurethane 8.5%, high-melting-point are weighed according to deal proportion Oxidized polyethylene wax emulsion 5%, above-mentioned raw materials are sequentially added in reaction kettle, are sufficiently stirred at 80 DEG C, are persistently stirred 60min;
S2, it is warming up to 90 DEG C to S1, keeps the temperature 30min, is cooled to 40 DEG C thereafter, weigh deionized water 24%, second according to deal proportion Glycol 13%, propylene glycol 8%, ethyl alcohol 4% are put into reaction kettle, 40 DEG C at a temperature of mix slowly 30min;
S3, glycerol 1.3%, dioctyl phthalate 1.1%, water-soluble aldehyde ketone resin liquid 1.6%, optical brightener 0.5% are put into instead Answer in kettle, 40 DEG C at a temperature of stir 20min;
S4., stand after the completion, filtering and discharging, the environment-friendly water-based oil polish of this high glaze can be obtained.
Example four: a kind of preparation method of the environment-friendly water-based oil polish of high glaze includes the following:
S1, water-based acrylic resin 34%, ethyl acrylate modified aqueous polyurethane 10%, high-melting-point oxygen are weighed according to deal proportion Change polythene wax emulsion 6%, above-mentioned raw materials sequentially added in reaction kettle, 80 DEG C at a temperature of be sufficiently stirred, it is lasting to stir 60min;
S2,90 DEG C are warming up to S1,30min is kept the temperature, is cooled to 40 DEG C thereafter, according to deal proportion weigh deionized water 21.5%, Ethylene glycol 11.5%, propylene glycol 10%, ethyl alcohol 2% are put into reaction kettle, mix slowly 30min at 40 DEG C;
S3, glycerol 1.2%, dioctyl phthalate 1.4%, water-soluble aldehyde ketone resin liquid 1.8%, optical brightener 0.6% are put into instead It answers in kettle, stirs 20min at a temperature of 40;
S4., stand after the completion, filtering and discharging, the environment-friendly water-based oil polish of this high glaze can be obtained.
Certainly, the above description is only a specific example of the present invention, be not to limit practical range of the invention, it is all according to The equivalent change or modification that structure, feature and principle described in scope of the present invention patent is done should be included in Shen of the present invention It please be in the scope of the patents.

Claims (2)

1. a kind of environment-friendly water-based oil polish of high glaze, which is characterized in that including following component and its parts by weight percentage:
Water-based acrylic resin 30%-34%;
Ethyl acrylate modified aqueous polyurethane 7%-10%;
High-melting-point oxidized polyethylene wax emulsion 5%-7%;
Deionized water 21%-24%;
Ethylene glycol 10%-14%;
Propylene glycol 8%-10%;
Ethyl alcohol 2%-4%;
Glycerol 1%-1.5%;
Dioctyl phthalate 1%-1.5%;
Water-soluble aldehyde ketone resin liquid 1.5%-2%;
Optical brightener 0.5%-1%.
2. a kind of preparation method of the environment-friendly water-based oil polish of high glaze as described in claim 1, which is characterized in that including following step It is rapid:
S1, water-based acrylic resin, ethyl acrylate modified aqueous polyurethane, the poly- second of high-melting-point oxidation are weighed according to deal proportion Alkene wax emulsion sequentially adds above-mentioned component in reaction kettle, is sufficiently stirred at 70-90 DEG C, persistently stirs 40-80min;
S2, be warming up to 85-95 DEG C to S1, keep the temperature 25-35min, be cooled to 35-45 DEG C thereafter, according to deal proportion weigh from Sub- water, ethylene glycol, propylene glycol, ethyl alcohol are put into reaction kettle, mix slowly 25-35min at 35-45 DEG C;
S3, glycerol, dioctyl phthalate, water-soluble aldehyde ketone resin liquid, optical brightener are put into reaction kettle, at 35-45 DEG C Lower stirring 15-25min;
S4., stand after the completion, filtering and discharging, the environment-friendly water-based oil polish of this high glaze can be obtained.
CN201910562349.7A 2019-06-26 2019-06-26 A kind of environment-friendly water-based oil polish of high glaze and preparation method thereof Pending CN110396335A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001329182A (en) * 2000-05-22 2001-11-27 Nippon Shokubai Co Ltd Water-based quick-drying resin composition
CN103756496A (en) * 2014-01-21 2014-04-30 繁昌县朱氏印务有限责任公司 Environment-friendly printed matter oil polish
CN104893485A (en) * 2015-06-26 2015-09-09 中荣印刷(昆山)有限公司 Environment-friendly high-glossiness waterborne gloss oil and method for manufacturing same
CN109233435A (en) * 2018-07-28 2019-01-18 广东绿之彩印刷科技股份有限公司 A kind of ink and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001329182A (en) * 2000-05-22 2001-11-27 Nippon Shokubai Co Ltd Water-based quick-drying resin composition
CN103756496A (en) * 2014-01-21 2014-04-30 繁昌县朱氏印务有限责任公司 Environment-friendly printed matter oil polish
CN104893485A (en) * 2015-06-26 2015-09-09 中荣印刷(昆山)有限公司 Environment-friendly high-glossiness waterborne gloss oil and method for manufacturing same
CN109233435A (en) * 2018-07-28 2019-01-18 广东绿之彩印刷科技股份有限公司 A kind of ink and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
凌云星等: "《油墨技术手册.上》", 31 May 2009, 印刷工业出版社 *

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