CN110372284A - A kind of ceramic tile viscose glue mud - Google Patents
A kind of ceramic tile viscose glue mud Download PDFInfo
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- CN110372284A CN110372284A CN201910505566.2A CN201910505566A CN110372284A CN 110372284 A CN110372284 A CN 110372284A CN 201910505566 A CN201910505566 A CN 201910505566A CN 110372284 A CN110372284 A CN 110372284A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/12—Nitrogen containing compounds organic derivatives of hydrazine
- C04B24/14—Peptides; Proteins; Derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/26—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B24/2652—Nitrogen containing polymers, e.g. polyacrylamides, polyacrylonitriles
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/26—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B24/2688—Copolymers containing at least three different monomers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/04—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polycarbonamides, polyesteramides or polyimides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/0045—Polymers chosen for their physico-chemical characteristics
- C04B2103/0051—Water-absorbing polymers, hydrophilic polymers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00637—Uses not provided for elsewhere in C04B2111/00 as glue or binder for uniting building or structural materials
- C04B2111/00646—Masonry mortars
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/10—Mortars, concrete or artificial stone characterised by specific physical values for the viscosity
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The present invention relates to a kind of ceramic tile viscose glue mud, belong to ceramic tile additive technology field.The present invention is with itaconic anhydride, citronellol is as raw material, by in alkaline atmosphere, form sodium salt, initiation is carried out with acrylamide again to polymerize, form water-absorbing resin, during the preparation process, it joined polyglutamic acid, in conjunction with making the water absorbent polymer to be formed with polyglutamic acid carry out crosslinking, part forms polyacrylamide simultaneously, and by carrying out graft modification to it using adjuvant, quaternized processing is carried out simultaneously, first is that while water suction can be increased, increase water-retaining property, second is that utilizing absorption property, it flocculates to metal ion therein, increase the conjugation of each raw material, improve the combination degree with wall.
Description
Technical field
The present invention relates to a kind of ceramic tile viscose glue mud, belong to ceramic tile additive technology field.
Background technique
In recent years, as urbanization leads to the high speed development of real estate sector, the raising of quality of life, people are to building decoration mark
Quasi- is continuous surging, using ceramics, Art Stone, vitrified tile etc. be artificial and lithotome as the ornament materials of representative has obtained large area
Use.But various facing ornament materials construction qualities are very different, and each finishing material especially stone material and ceramic tile etc. is shorter
The phenomenon that falling off in time there have been large area, causes metope mottled, this is mainly due to binding material unstable quality, mostly
Field worker oneself is by virtue of experience prepared, and after the exterior wall damage of skyscraper, reparation is extremely difficult, needs to pound original system
It re-lays, complicated external environment makes recovery project almost and has can not prosthetic again.Wherein binding material is uneven, viscous
Knotting strength is insufficient, bonding slurry is not full, adhesive layer freeze thawing is poor, these phenomenons are primarily due to lack dedicated binding material
Caused by.Only by construction personnel's by virtue of experience mixing, arbitrariness is also big for proportion, and deposits because of insufficient to the cognition of stone material and basal plane
In very big error.Ceramic tile bond performance is unstable, and early strength develops slowly, and ceramic tile bond anti-slipping property is bad
Deng causing ceramic tile to be easy to fall off.And ceramic tile is different according to the place of patch and is divided into floor tile and wall brick.It is just easy to according to title
Understand, floor tile pastes on the ground, and wall brick is exactly to paste on the wall.And the difficulty of Wall brick will be far longer than patch floor tile
Difficulty is primarily due to wall brick during patch, downwards without supporter, is easy to happen downward displacement.For this purpose, Wall brick
Mortar is different compared with floor tile mortar.And in existing current wall brick mortar use process, dry than very fast, cement weathering is compared
Fastly, it is easy to flake, when there is wall brick out-of-flatness, bad adjustment wall brick position, and easily lead to ceramic tile and wall associativity
It can be poor.
Summary of the invention
The technical problems to be solved by the invention: it is fast for current ceramic tile viscose glue mud dehydration, it easily causes and flakes, so as to cause
The problem for leading to ceramic tile Yu wall binding performance difference, the present invention provides a kind of ceramic tile viscose glue mud.
In order to solve the above technical problems, the present invention is using technical solution as described below:
A kind of ceramic tile viscose glue mud, according to parts by weight, including 300~350 parts of ordinary portland cements, 200~250 parts of quartz
Sand, 100~120 parts of dicalcium powders, 10~15 parts of dispersing agents, 80~120 parts of modified mixtures, 30~60 parts of additives.
The preparation method of the modified mixture includes the following steps:
(1) according to parts by weight, 160~190 parts of water, 30~35 parts of polyglutamic acids, 20~23 parts of citronellols, 19~22 parts of clothing are taken
Health acid anhydrides, 15~18 parts of acrylamides, 6~8 parts of triethylamines, 2~7 parts of initiators, 2~5 parts of auxiliary agents, 1~3 part of adjuvant；
(2) water, polyglutamic acid and citronellol are put into reactor using nitrogen protection, preheating adds itaconic anhydride and third
Acrylamide adjusts pH to 9.0~10.0, heats up, heat preservation, and initiator is added, and stirring adds triethylamine, auxiliary agent and adjuvant,
Continue to stir, discharge while hot, collect out material, by material out and 1- ethyl-(3- dimethylaminopropyl) phosphinylidyne diimmonium salt
Hydrochlorate 10:1 in mass ratio~3 mixes to get modified mixture.
The initiator be azo diethyl fourth cyanogen, potassium peroxydisulfate, ascorbic acid and hydrogen peroxide 3~5:1:1 in mass ratio~
3:5 is mixed.
The auxiliary agent is N, and N- methylene acrylamide, glutaraldehyde 5:1~3 in mass ratio mix.
The adjuvant is dimethylaminoethyl methacrylate, iodomethane 1:5~8 in mass ratio mix.
The additive the preparation method comprises the following steps:
A. ammonium hydrogen carbonate, water 5:10~13 in mass ratio are put into reaction kettle, using nitrogen protection, are stirred, carbon is added
The fluosilicic acid of sour hydrogen ammonium quality 30~35% stirs, and heats, cooling, stands；
B. wait stand after, discharge, filtering, collect filtrate, by filtrate, mixture and water 7~9:3 in mass ratio~5:6 into
Row mixing, is stirred to react at 40~50 DEG C, filters, and collects filtered fluid, filtered fluid is concentrated, and collects concentrate；
C. concentrate is spray-dried, collect dried object, by dried object, additive and surfactant in mass ratio 6~
9:4~6:1 carries out ball milling, collects ball milling object to get additive.
Mixture is aluminum sulfate in the step A, sodium sulphate 4~7:2 in mass ratio is mixed.
Additive is that tourmaline powder, fluorite, magnesium carbide 5~7:3:1~3 in mass ratio mix in the step C.
Surfactant is neopelex, any one in lauryl sodium sulfate in the step C.
The dispersing agent is calcium stearate, any one in magnesium stearate.
The present invention is compared with other methods, and advantageous effects are:
The present invention is using itaconic anhydride, citronellol as raw material, by alkaline atmosphere, forming sodium salt, then with acrylamide into
It goes and causes polymerization, forming water-absorbing resin joined polyglutamic acid during the preparation process, makes the water absorbent polymer to be formed and is gathering
Glutamic acid carries out crosslinking combination, while part forms polyacrylamide, and by carrying out graft modification to it using adjuvant,
Quaternized processing is carried out simultaneously, first is that increasing water-retaining property, second is that using absorption property, to wherein while water suction can be increased
Metal ion flocculate, increase the conjugation of each raw material, improve the combination degree with wall, then recycle addition
Particle keeps activity, while inhibiting the dilatancy of water absorbent polymer, increases mechanical property, and polyglutamic acid is degraded wherein
When forming amino acids substance, by 1- ethyl-(3- dimethylaminopropyl) phosphinylidyne diimmonium salt hydrochlorate to therein
Group is activated, and the water heat release of magnesium carbide chance is polymerize under additive catalytic action in additive, forms amino
Acid polymerization, improves water-retaining property.
Specific embodiment
Dispersing agent is calcium stearate, any one in magnesium stearate.
Additive the preparation method comprises the following steps:
A. ammonium hydrogen carbonate, water 5:10~13 in mass ratio are put into reaction kettle, using nitrogen protection, are stirred, carbon is added
The fluosilicic acid of sour hydrogen ammonium quality 30~35%, stirring are heated to 80 DEG C, heat 5h, are cooled to room temperature, and stand 10h；
B. wait stand after, discharge, filtering, collect filtrate, by filtrate, mixture and water 7~9:3 in mass ratio~5:6 into
Row mixing, is stirred to react 12h at 40~50 DEG C, filters, and collects filtered fluid, filtered fluid is carried out to be concentrated into filtered fluid volume
60%, collect concentrate；
C. concentrate is spray-dried, collect dried object, by dried object, additive and surfactant in mass ratio 6~
9:4~6:1 carries out ball milling, collects ball milling object to get additive.
Mixture is aluminum sulfate, sodium sulphate 4~7:2 in mass ratio is mixed.
Additive is that tourmaline powder, fluorite, magnesium carbide 5~7:3:1~3 in mass ratio mix.
Surfactant is neopelex, any one in lauryl sodium sulfate.
Initiator is azo diethyl fourth cyanogen, potassium peroxydisulfate, ascorbic acid and 0.6mol/L hydrogen peroxide 3~5:1 in mass ratio:
1~3:5 is mixed.
Adjuvant is dimethylaminoethyl methacrylate, iodomethane 1:5~8 in mass ratio mix.
The preparation method of modified mixture includes the following steps:
(1) according to parts by weight, 160~190 parts of water, 30~35 parts of polyglutamic acids, 20~23 parts of citronellols, 19~22 parts of clothing are taken
Health acid anhydrides, 15~18 parts of acrylamides, 6~8 parts of triethylamines, 2~7 parts of initiators, 2~5 parts of auxiliary agents, 1~3 part of adjuvant；
(2) water, polyglutamic acid and citronellol are put into reactor using nitrogen protection, in 40~50 DEG C of preheating 30min, then plus
Enter itaconic anhydride and acrylamide, adjust pH to 9.0~10.0, be warming up to 60~80 DEG C, keep the temperature 4~8h, initiator is added, with
300r/min stirs 3~6h, adds triethylamine, auxiliary agent and adjuvant, continues to stir 2h, discharges while hot, collect out material, will
Material is mixed with 1- ethyl-(3- dimethylaminopropyl) phosphinylidyne diimmonium salt hydrochlorate 10:1~3 in mass ratio to get modification out
Mixture.
A kind of ceramic tile viscose glue mud, according to parts by weight, including 300~350 parts of ordinary portland cements, 200~250 parts of stones
Sand, 100~120 parts of dicalcium powders, 10~15 parts of dispersing agents, 80~120 parts of modified mixtures, 30~60 parts of additives.
Ceramic tile viscose glue mud is prepared as each component with 10~15min of 500r/min mixing to get ceramic tile viscose glue mud.
Embodiment 1
Dispersing agent is calcium stearate.
Additive the preparation method comprises the following steps:
A. ammonium hydrogen carbonate, water 5:13 in mass ratio are put into reaction kettle, using nitrogen protection, are stirred, bicarbonate is added
The fluosilicic acid of ammonium quality 35%, stirring are heated to 80 DEG C, heat 5h, are cooled to room temperature, and stand 10h；
B. wait stand after, discharge, filtering, collect filtrate, filtrate, mixture and water 9:5:6 in mass ratio are mixed,
It is stirred to react 12h at 50 DEG C, is filtered, filtered fluid is collected, filtered fluid is carried out to be concentrated into the 60% of filtered fluid volume, is collected
Concentrate；
C. concentrate is spray-dried, collects dried object, by dried object, additive and surfactant 9:6 in mass ratio:
1 carries out ball milling, collects ball milling object to get additive.
Mixture is aluminum sulfate, sodium sulphate 7:2 in mass ratio is mixed.
Additive is tourmaline powder, fluorite, magnesium carbide 7:3:3 in mass ratio are mixed.
Surfactant is lauryl sodium sulfate.
Initiator be azo diethyl fourth cyanogen, potassium peroxydisulfate, ascorbic acid and hydrogen peroxide 5:1:3:5 in mass ratio mixing and
At.
Auxiliary agent is N, and N- methylene acrylamide, glutaraldehyde 5:3 in mass ratio are mixed.
Adjuvant is dimethylaminoethyl methacrylate, iodomethane 1:8 in mass ratio is mixed.
The preparation method of modified mixture includes the following steps:
(1) according to parts by weight, 190 parts of water, 35 parts of polyglutamic acids, 23 parts of citronellols, 22 parts of itaconic anhydrides, 18 parts of acryloyls are taken
Amine, 8 parts of triethylamines, 7 parts of initiators, 5 parts of auxiliary agents, 3 parts of adjuvants；
(2) water, polyglutamic acid and citronellol are put into reactor and add clothing in 50 DEG C of preheating 30min using nitrogen protection
Health acid anhydrides and acrylamide adjust pH to 10.0, are warming up to 80 DEG C, keep the temperature 8h, and initiator is added, and stir 6h with 300r/min,
Triethylamine, auxiliary agent and adjuvant are added, continues to stir 2h, discharges while hot, collect out material, by material out and 1- ethyl-one
Kind ceramic tile viscose glue mud, according to parts by weight, including 350 parts of ordinary portland cements, 250 parts of quartz sands, 120 parts of dicalcium powders, 15
Part dispersing agent, 120 parts of modified mixtures, 60 parts of additives.
Ceramic tile viscose glue mud is prepared as each component with 500r/min mixing 15min to get ceramic tile viscose glue mud.
Embodiment 2
Dispersing agent is magnesium stearate.
Additive the preparation method comprises the following steps:
A. ammonium hydrogen carbonate, water 5:12 in mass ratio are put into reaction kettle, using nitrogen protection, are stirred, bicarbonate is added
The fluosilicic acid of ammonium quality 33%, stirring are heated to 80 DEG C, heat 5h, are cooled to room temperature, and stand 10h；
B. wait stand after, discharge, filtering, collect filtrate, filtrate, mixture and water 8:4:6 in mass ratio are mixed,
It is stirred to react 12h at 45 DEG C, is filtered, filtered fluid is collected, filtered fluid is carried out to be concentrated into the 60% of filtered fluid volume, is collected
Concentrate；
C. concentrate is spray-dried, collects dried object, by dried object, additive and surfactant 8:5 in mass ratio:
1 carries out ball milling, collects ball milling object to get additive.
Mixture is aluminum sulfate, sodium sulphate 5:2 in mass ratio is mixed.
Additive is tourmaline powder, fluorite, magnesium carbide 6:3:2 in mass ratio are mixed.
Surfactant is neopelex.
Initiator be azo diethyl fourth cyanogen, potassium peroxydisulfate, ascorbic acid and hydrogen peroxide 4:1:2:5 in mass ratio mixing and
At.
Auxiliary agent is N, and N- methylene acrylamide, glutaraldehyde 5:2 in mass ratio are mixed.
Adjuvant is dimethylaminoethyl methacrylate, iodomethane 1:6 in mass ratio is mixed.
The preparation method of modified mixture includes the following steps:
(1) according to parts by weight, 180 parts of water, 33 parts of polyglutamic acids, 22 parts of citronellols, 21 parts of itaconic anhydrides, 16 parts of acryloyls are taken
Amine, 7 parts of triethylamines, 5 parts of initiators, 4 parts of auxiliary agents, 2 parts of adjuvants；
(2) water, polyglutamic acid and citronellol are put into reactor and add clothing in 45 DEG C of preheating 30min using nitrogen protection
Health acid anhydrides and acrylamide adjust pH to 10.0, are warming up to 70 DEG C, keep the temperature 6h, and initiator is added, and stir 5h with 300r/min,
Triethylamine, auxiliary agent and adjuvant are added, continues to stir 2h, discharges while hot, collect out material, by material out and 1- ethyl-(3-
Dimethylaminopropyl) phosphinylidyne diimmonium salt hydrochlorate 10:2 in mass ratio mixing to get modified mixture.
A kind of ceramic tile viscose glue mud, according to parts by weight, including 330 parts of ordinary portland cements, 230 parts of quartz sands, 110 parts
Dicalcium powder, 13 parts of dispersing agents, 90 parts of modified mixtures, 40 parts of additives.
Ceramic tile viscose glue mud is prepared as each component with 500r/min mixing 13min to get ceramic tile viscose glue mud.
Embodiment 3
Dispersing agent is calcium stearate.
Additive the preparation method comprises the following steps:
A. ammonium hydrogen carbonate, water 5:10 in mass ratio are put into reaction kettle, using nitrogen protection, are stirred, bicarbonate is added
The fluosilicic acid of ammonium quality 30%, stirring are heated to 80 DEG C, heat 5h, are cooled to room temperature, and stand 10h；
B. wait stand after, discharge, filtering, collect filtrate, filtrate, mixture and water 7:3:6 in mass ratio are mixed,
It is stirred to react 12h at 40 DEG C, is filtered, filtered fluid is collected, filtered fluid is carried out to be concentrated into the 60% of filtered fluid volume, is collected
Concentrate；
C. concentrate is spray-dried, collects dried object, by dried object, additive and surfactant 6:4 in mass ratio:
1 carries out ball milling, collects ball milling object to get additive.
Mixture is aluminum sulfate, sodium sulphate 4:2 in mass ratio is mixed.
Additive is tourmaline powder, fluorite, magnesium carbide 5:3:1 in mass ratio are mixed.
Surfactant is neopelex.
Initiator be azo diethyl fourth cyanogen, potassium peroxydisulfate, ascorbic acid and hydrogen peroxide 3:1:1:5 in mass ratio mixing and
At.
Auxiliary agent is N, and N- methylene acrylamide, glutaraldehyde 5:1 in mass ratio are mixed.
Adjuvant is dimethylaminoethyl methacrylate, iodomethane 1:5 in mass ratio is mixed.
The preparation method of modified mixture includes the following steps:
(1) according to parts by weight, 160 parts of water, 30 parts of polyglutamic acids, 20 parts of citronellols, 19 parts of itaconic anhydrides, 15 parts of acryloyls are taken
Amine, 6 parts of triethylamines, 2 parts of initiators, 2 parts of auxiliary agents, 1 part of adjuvant；
(2) water, polyglutamic acid and citronellol are put into reactor and add clothing in 40 DEG C of preheating 30min using nitrogen protection
Health acid anhydrides and acrylamide adjust pH to 9.0, are warming up to 60 DEG C, keep the temperature 4h, and initiator is added, and stir 3h with 300r/min, then
Triethylamine, auxiliary agent and adjuvant is added, continues to stir 2h, discharges while hot, collect out material, by material out and 1- ethyl-(3- bis-
Dimethylaminopropyl) phosphinylidyne diimmonium salt hydrochlorate 10:1 in mass ratio mixing to get modified mixture.
A kind of ceramic tile viscose glue mud, according to parts by weight, including 300 parts of ordinary portland cements, 200 parts of quartz sands, 100 parts
Dicalcium powder, 10 parts of dispersing agents, 80 parts of modified mixtures, 30 parts of additives.
Ceramic tile viscose glue mud is prepared as each component with 500r/min mixing 10min to get ceramic tile viscose glue mud.
Comparative example 1
It is substantially the same manner as Example 2, only the difference is that lacking modified mixture, additive.
Comparative example 2
It is substantially the same manner as Example 2, only the difference is that lacking modified mixture.
Comparative example 3
It is substantially the same manner as Example 2, only the difference is that lacking additive.
By the ceramic tile viscose glue mud in the Examples 1 to 3 ceramic tile viscose glue mud and comparative example 1~3 of above-mentioned preparation method according to JC/
T547-2005 is tested, is tested using " JC-T984-2001 Polymer cement materials " standard, specific to test
As a result it is detailed in the following table 1:
Table 1
| Test item | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| Stretch gluing original intensity/MPa | 1.82 | 1.89 | 1.83 | 1.32 | 1.26 | 1.56 |
| Heat ageing post-tensioning adhesion strength/MPa | 1.50 | 1.56 | 1.52 | 0.26 | 0.45 | 0.34 |
| Frozen-thawed cycled post-tensioning bonds original intensity/MPa | 1.23 | 1.45 | 1.32 | 0.13 | 0.25 | 1.11 |
In conclusion as shown in Table 1, ceramic tile viscose glue mud better performances prepared by the present invention have broad application prospects.
Claims (10)
1. a kind of ceramic tile viscose glue mud, according to parts by weight, including 300~350 parts of ordinary portland cements, 200~250 parts of quartz
Sand, 100~120 parts of dicalcium powders, 10~15 parts of dispersing agents, which is characterized in that further include 80~120 parts of modified mixtures, 30~
60 parts of additives.
2. ceramic tile viscose glue mud according to claim 1, which is characterized in that the preparation method of the modified mixture includes as follows
Step:
(1) according to parts by weight, 160~190 parts of water, 30~35 parts of polyglutamic acids, 20~23 parts of citronellols, 19~22 parts of clothing are taken
Health acid anhydrides, 15~18 parts of acrylamides, 6~8 parts of triethylamines, 2~7 parts of initiators, 2~5 parts of auxiliary agents, 1~3 part of adjuvant；
(2) water, polyglutamic acid and citronellol are put into reactor using nitrogen protection, preheating adds itaconic anhydride and third
Acrylamide adjusts pH to 9.0~10.0, heats up, heat preservation, and initiator is added, and stirring adds triethylamine, auxiliary agent and adjuvant,
Continue to stir, discharge while hot, collect out material, by material out and 1- ethyl-(3- dimethylaminopropyl) phosphinylidyne diimmonium salt
Hydrochlorate 10:1 in mass ratio~3 mixes to get modified mixture.
3. ceramic tile viscose glue mud according to claim 2, which is characterized in that the initiator is azo diethyl fourth cyanogen, persulfuric acid
Potassium, ascorbic acid and hydrogen peroxide 3~5:1:1 in mass ratio~3:5 are mixed.
4. ceramic tile viscose glue mud according to claim 2, which is characterized in that the auxiliary agent is N, N- methylene acrylamide, penta
Dialdehyde 5:1~3 in mass ratio mix.
5. ceramic tile viscose glue mud according to claim 2, which is characterized in that the adjuvant is dimethylaminoethyl second
Ester, iodomethane 1:5~8 in mass ratio mix.
6. ceramic tile viscose glue mud according to claim 1, which is characterized in that the additive the preparation method comprises the following steps:
A. ammonium hydrogen carbonate, water 5:10~13 in mass ratio are put into reaction kettle, using nitrogen protection, are stirred, carbon is added
The fluosilicic acid of sour hydrogen ammonium quality 30~35% stirs, and heats, cooling, stands；
B. wait stand after, discharge, filtering, collect filtrate, by filtrate, mixture and water 7~9:3 in mass ratio~5:6 into
Row mixing, is stirred to react at 40~50 DEG C, filters, and collects filtered fluid, filtered fluid is concentrated, and collects concentrate；
C. concentrate is spray-dried, collect dried object, by dried object, additive and surfactant in mass ratio 6~
9:4~6:1 carries out ball milling, collects ball milling object to get additive.
7. ceramic tile viscose glue mud according to claim 6, which is characterized in that mixture is aluminum sulfate, sodium sulphate in the step A
4~7:2 is mixed in mass ratio.
8. ceramic tile viscose glue mud according to claim 6, which is characterized in that additive is tourmaline powder, firefly in the step C
Stone, magnesium carbide 5~7:3:1~3 in mass ratio mix.
9. ceramic tile viscose glue mud according to claim 6, which is characterized in that surfactant is dodecyl in the step C
Any one in benzene sulfonic acid sodium salt, lauryl sodium sulfate.
10. ceramic tile viscose glue mud according to claim 1, which is characterized in that the dispersing agent is calcium stearate, in magnesium stearate
Any one.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910505566.2A CN110372284A (en) | 2019-06-12 | 2019-06-12 | A kind of ceramic tile viscose glue mud |
Applications Claiming Priority (1)
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112194439A (en) * | 2020-09-15 | 2021-01-08 | 亚士创能科技(上海)股份有限公司 | Plastering mortar, exterior wall coating and preparation method thereof |
| CN114409342A (en) * | 2022-02-14 | 2022-04-29 | 清远楼邦建材科技有限公司 | Preparation method of ceramic tile glue |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1225345A (en) * | 1998-11-30 | 1999-08-11 | 韩敏芳 | Artificial stone products |
| CN1361815A (en) * | 1999-01-20 | 2002-07-31 | 宝洁公司 | Dishwashing detergent composition containing mixtures of crystallinity-disrupted surfactants |
| CN1384857A (en) * | 1999-10-26 | 2002-12-11 | 莫纳工业公司 | Iwitterionic siloxane polymers and ionically cross-linked polymers formed therefrom |
| CN101041751A (en) * | 2006-11-02 | 2007-09-26 | 董善刚 | Highly dynamic cracking resistant type elastic putty |
| CN101796088A (en) * | 2007-09-04 | 2010-08-04 | 巴斯夫欧洲公司 | Method for the production of leather, copolymers that are suitable therefor, and further uses thereof |
| CN107840604A (en) * | 2017-11-01 | 2018-03-27 | 贵州省独山县顺峰装潢建材厂 | A kind of viscose glue mud of Wall brick |
-
2019
- 2019-06-12 CN CN201910505566.2A patent/CN110372284A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1225345A (en) * | 1998-11-30 | 1999-08-11 | 韩敏芳 | Artificial stone products |
| CN1361815A (en) * | 1999-01-20 | 2002-07-31 | 宝洁公司 | Dishwashing detergent composition containing mixtures of crystallinity-disrupted surfactants |
| CN1384857A (en) * | 1999-10-26 | 2002-12-11 | 莫纳工业公司 | Iwitterionic siloxane polymers and ionically cross-linked polymers formed therefrom |
| CN101041751A (en) * | 2006-11-02 | 2007-09-26 | 董善刚 | Highly dynamic cracking resistant type elastic putty |
| CN101796088A (en) * | 2007-09-04 | 2010-08-04 | 巴斯夫欧洲公司 | Method for the production of leather, copolymers that are suitable therefor, and further uses thereof |
| CN107840604A (en) * | 2017-11-01 | 2018-03-27 | 贵州省独山县顺峰装潢建材厂 | A kind of viscose glue mud of Wall brick |
Non-Patent Citations (9)
| Title |
|---|
| 《生物产业》: "《生物产业》", 30 June 2014 * |
| 冯文钦主编: "《神奇的矿晶宝石》", 30 September 2015 * |
| 刘新容: ""丙烯酸-丙烯酰胺高吸水树脂溶液共聚合成与吸液吸附性能研究"", 《万方数据库》 * |
| 刘晓红等: ""由氟硅酸、碳酸氢铵制备高分子比冰晶石"", 《无机盐工业》 * |
| 孟德勇等: ""改性吸水树脂的合成及其在吸水膨胀橡胶中的应用"", 《橡胶工业》 * |
| 成青等: ""衣康酸-丙烯酰胺高吸水树脂的合成"", 《合成树脂及塑料》 * |
| 朱洪法主编: "《催化剂手册》", 31 August 2008 * |
| 舒冬梅: ""高吸水树脂对水泥性能的影响"", 《第六届中国功能材料及其应用学术会议论文集（9）》 * |
| 谭树波: ""梳形聚合物聚甲基丙烯酸二甲氨基乙酯--丙烯酰胺的合成与性能"", 《万方数据库》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112194439A (en) * | 2020-09-15 | 2021-01-08 | 亚士创能科技(上海)股份有限公司 | Plastering mortar, exterior wall coating and preparation method thereof |
| CN114409342A (en) * | 2022-02-14 | 2022-04-29 | 清远楼邦建材科技有限公司 | Preparation method of ceramic tile glue |
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