CN110315831A - A kind of antistatic compact-panel and preparation method thereof - Google Patents
A kind of antistatic compact-panel and preparation method thereof Download PDFInfo
- Publication number
- CN110315831A CN110315831A CN201810288101.1A CN201810288101A CN110315831A CN 110315831 A CN110315831 A CN 110315831A CN 201810288101 A CN201810288101 A CN 201810288101A CN 110315831 A CN110315831 A CN 110315831A
- Authority
- CN
- China
- Prior art keywords
- beam curing
- antistatic
- electronic beam
- facing paper
- compact
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B29/00—Layered products comprising a layer of paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B29/00—Layered products comprising a layer of paper or cardboard
- B32B29/02—Layered products comprising a layer of paper or cardboard next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/28—Polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
- B32B2260/028—Paper layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/04—Impregnation, embedding, or binder material
- B32B2260/046—Synthetic resin
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention relates to a kind of antistatic compact-panel and preparation method thereof, which includes substrate, and for the outside cladding of substrate through the processed facing paper of impregnating resin, the surface of the facing paper coats electronic beam curing coating；By laying electronic beam curing coating on anti-times of special incrustation paper, electronic beam curing coating resin includes nano-silver powder and antistatic agent, and antistatic agent is the permanent type Polymer-metallic Catalyst having been commercialized, and it is blended with cheap nano-silver powder by physical blending process, electronic beam curing coating resin is obtained, so that the antistatic property of compact-panel is substantially improved.
Description
Technical field
The present invention relates to technical field of construction and decoration materials, especially a kind of antistatic compact-panel and preparation method thereof.
Background technique
Compact-panel has excellent stability, and is readily cleaned maintenance, thus the scope of application is extremely wide, and compact-panel is wide
It is general to be applied to the large-scale public places such as school, hospital, airport, station, hotel, market, office building, kitchen tools table top in life,
Wash one's hands and face table top, dining table, desk, door leaf, bath lavatory compartment, wash platform, reception counters, article placing cabinet, the ceiling, office of public space
Table and office cubicles etc..
In the prior art, compact-panel is as a kind of wood fiber and thermosetting resin through high-strength flat made of high pressure polymerisation
Plate has apparent stepped construction；Electrostatic is a kind of charge to remain static, when accumulation on some object or
Electrostatic is formed when surface；When static electrification object contacts zero potential object (ground connection object) or has the object of potential difference with it
Electric charge transfer will occur, being exactly that we are daily sees Spark Discharges, and electrostatic is to fine gram of the interference of people's daily life
Clothes, existing compact-panel lack special project measure, but the field more demanding in operating room, laboratory etc. in terms of antistatic
Institute, the antistatic performance of compact-panel are unable to satisfy requirement, cause using limited.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of antistatic compact-panel that is wear-resisting, being easy to production and its preparations
Method.
In order to solve the above technical problems, antistatic compact-panel provided by the invention, comprising: substrate, the outside packet of substrate
It covers through the processed facing paper of impregnating resin, the surface of the facing paper coats electronic beam curing coating, the electronic beam curing
Coating is made of by weight percentage following raw material: polyester acrylic 30%, phenolic aldehyde acrylic acid 19%, co-crosslinker 15%, oneself two
Alcohol diacrylate 15%, fire retardant 4%, coupling agent 0.5%, levelling agent 0.5%, nano-silver powder 10%, dispersing agent 1% are antistatic
Agent 5%.
Further, the co-crosslinker is trimethylolpropane trimethacrylate, the resistance to punching of electronic beam curing coating of acquisition
Hit better effect.
The preparation method of above-mentioned antistatic compact-panel, includes the following steps:
A, electronic beam curing coating resin prepares: following raw material being added in blender by weight percentage, wherein polyester
Acid 30%, phenolic aldehyde acrylic acid 19%, co-crosslinker 15%, hexanediyl ester 15%, fire retardant 4%, coupling agent 0.5%, stream
Flat agent 0.5%, nano-silver powder 10%, dispersing agent 1%, antistatic agent 5% start blender and are heated to 50 DEG C, stir evenly, and take out
Vacuum obtains electronic beam curing coating resin solution.
B, by facing paper impregnating resin, and rewinding is dried, it is ensured that obtained facing paper grammes per square metre is uniform, and surface is smooth, printing
The sun-proof grade of ink is not less than 6 grades.
C, adhesive curing is applied, takes roller coating or pour mode that the electronic beam curing coating resin in step A is coated onto step B institute
On facing paper after the dipping obtained, coating layer thickness is 0.15 to 0.20mm, and is solidified by electron beam curing apparatus, is obtained
Surface is coated with the facing paper of electronic beam curing coating.
D, the layers of kraft paper of multilayer impregnation melamine formaldehyde resin is storied at substrate, or be made of phenol an aromatic plant metioned in ancient books glue
Fiberboard substrate obtain substrate.
E, the step C facing paper obtained is attached to the surface of the substrate of step D acquisition, and it is solid to be sent into hot press progress hot pressing
Change, hot pressing temperature is 145 DEG C to 155 DEG C, and pressure is not less than 9.5MPa, and hot pressing time is to take cold into cold not less than 35 minutes
Mode out obtains the compact-panel that surface is coated with electronic beam curing coating.
Further, in the step B, the grammes per square metre before facing paper dipping is 70 to 130 grams/m, and dipping spread is
50 to 150 grams/m, fugitive constituent 2-4%, it is ensured that facing paper dipping is uniform.
Further, in the step B, the resin of dipping is the mixing of melamine formaldehyde resin and phenol-formaldehyde resin
Object, wherein mass percent shared by melamine formaldehyde resin is 40% to 60%, it is ensured that the facing paper after dipping possesses toughness,
Affinity is kept with electronic beam curing coating resin simultaneously.
Further, in the step E, 45 DEG C to 55 DEG C are first warming up to, facing paper is preheated, so that the trimerization of substrate
Cyanogen amine-formaldehyde resin or phenol an aromatic plant metioned in ancient books glue melt, and keep heating up so that temperature is slowly raised to 145 DEG C extremely again while platen pressure
155 DEG C, it is cooled to room temperature after keeping the temperature the predetermined time, removes pressing plate, is once pressurized to the hot pressing mode to heat up again at bottom with traditional
It compares, can effectively avoid facing paper rupture, rate of becoming a useful person height.
The technical effect of invention: (1) of the invention antistatic compact-panel, compared with the existing technology, by special at anti-times
Electronic beam curing coating is laid on incrustation paper, electronic beam curing coating resin includes nano-silver powder and antistatic agent, and anti-
Electrostatic agent is the permanent type Polymer-metallic Catalyst having been commercialized, and passes through physical blending process for itself and cheap nano-silver powder
It is blended, electronic beam curing coating resin is obtained, so that the antistatic property of compact-panel is substantially improved；(2) by electronic beam curing
Technology uses anti-times of spy above, can improve compact-panel surface property, accomplishes the antistatic ability that commonly anti-times of spy does not accomplish；
And there are self-cleaning ability, resistance and fingerprint resistance ability in the compact-panel surface obtained, these all common compact-panels are not accomplished, in addition
Its surface abrasion resistance scratch resistance performance greatly improves；The characteristics of due to electronic beam curing coating, electronic beam curing coating product have very
Strong resistance, while because the chemical substance in coating is the high molecular weight steric network polymers formed by cross-linking reaction,
So coating surface has very strong chemical-resistance and crocking resistance；(3) polyester acrylic, the phenol of special ratios are used
Aldehyde acrylic acid, hexanediyl ester, fire retardant, coupling agent, levelling agent, nano-silver powder, dispersing agent, resists co-crosslinker
The presence of electronic beam curing coating resin, especially antistatic agent and nano-silver powder is made in electrostatic agent, can effectively improve anti-times of spy
The antistatic property of plate；(4) when thermocompression forming, first pre-heating temperature elevation to 50 DEG C or so so that glue on substrate melt after again into
Row pressurization, with it is traditional be once pressurized to the hot pressing mode that bottom is heated up again compared with, can effectively avoid facing paper rupture, rate of becoming a useful person
Height, while can avoid influencing electronic beam curing coating because of temperature change dramatically.
Detailed description of the invention
Invention is further described in detail with reference to the accompanying drawings of the specification:
Fig. 1 is the schematic diagram of the section structure of the antistatic compact-panel of the embodiment of the present invention 1.
In figure: substrate 1, facing paper 2, electronic beam curing coating 3.
Specific embodiment
Embodiment 1
As shown in Figure 1, the antistatic compact-panel of the present embodiment includes substrate 1, the outside cladding of substrate 1 is handled through impregnating resin
The facing paper 2 crossed, facing paper 2 are coated on before substrate 1 through one layer of electronic beam curing coating 3 of electronic beam curing, and the electron beam is solid
Change coating 3 to be made of by weight percentage following raw material: polyester acrylic 30%, phenolic aldehyde acrylic acid 19%, co-crosslinker 15%, oneself
Omega-diol diacrylate 15%, fire retardant 4%, coupling agent 0.5%, levelling agent 0.5%, nano-silver powder 10%, dispersing agent 1% resist quiet
Electric agent 5%, the above-mentioned agitated mixing of material obtain electronic beam curing coating resin, and wherein co-crosslinker is trimethylolpropane tris
Acrylate.
Embodiment 2
The manufacturing method of the antistatic compact-panel of embodiment 1, includes the following steps:
A, electronic beam curing coating resin prepares: following raw material being added in blender by weight percentage, wherein polyester
Acid 30%, phenolic aldehyde acrylic acid 19%, co-crosslinker 15%, hexanediyl ester 15%, fire retardant 4%, coupling agent 0.5%, stream
Flat agent 0.5%, nano-silver powder 10%, dispersing agent 1%, antistatic agent 5% start blender and are heated to 50 DEG C, stir evenly, and take out
Vacuum obtains electronic beam curing coating resin solution.
B, by facing paper impregnating resin, and rewinding is dried, it is ensured that obtained facing paper grammes per square metre is uniform, and surface is smooth, printing
The sun-proof grade of ink is not less than 6 grades.
C, adhesive curing is applied, takes roller coating or pour mode that the electronic beam curing coating resin in step A is coated onto step B institute
On facing paper after the dipping obtained, coating layer thickness is 0.15 to 0.20mm, and is solidified by electron beam curing apparatus, is obtained
Surface is coated with the facing paper of electronic beam curing coating.
D, the layers of kraft paper of multilayer impregnation melamine formaldehyde resin is storied at substrate, or be made of phenol an aromatic plant metioned in ancient books glue
Fiberboard substrate obtain substrate.
E, the step C facing paper obtained is attached to the surface of the substrate of step D acquisition, and it is solid to be sent into hot press progress hot pressing
Change, hot pressing temperature is 145 DEG C to 155 DEG C, and pressure is not less than 9.5MPa, and hot pressing time is to take cold into cold not less than 35 minutes
Mode out obtains the compact-panel that surface is coated with electronic beam curing coating.
Wherein in step B, facing paper dipping before 75 grams/m of grammes per square metre, dipping spread be 60 grams/m, wave
Part 3% is sent out, the printing sun-proof grade of ink is 6 grades, it is ensured that facing paper dipping is uniform.
In step B, the resin of dipping is the mixture of melamine formaldehyde resin and phenol-formaldehyde resin, wherein trimerization
Mass percent shared by cyanogen amine-formaldehyde resin is 40%, and mass percent shared by phenol-formaldehyde resin is 60%, it is ensured that after dipping
Facing paper possess toughness, while keeping affinity with electronic beam curing coating resin.
In step C, coating layer thickness 0.19mm；In step D, brown paper that substrate is impregnated by melamine formaldehyde resin
It is made.
In step E, first it is warming up to 55 DEG C and facing paper is preheated, so that the melamine formaldehyde resin of substrate melts,
It keeps heating up again while platen pressure so that temperature is slowly raised to 150 DEG C, pressure is maintained to 9.5MPa, after keeping the temperature 35 minutes
Be cooled to room temperature, remove pressing plate, with it is traditional be once pressurized to the hot pressing mode that bottom is heated up again compared with, can effectively avoid facing paper
Rupture, rate of becoming a useful person height.
The antistatic compact-panel that this method obtains is according to national standard GB/T 7911-2013 " thermosetting resin impregnated paper high pressure
Laminated decorative board " is detected, and the result of acquisition is referring to table 1.
Embodiment 3
A kind of manufacturing method of antistatic compact-panel, on the basis of embodiment 2, the manufacturing method of the present embodiment exists as follows
Difference:
In step B, facing paper dipping before 130 grams/m of grammes per square metre, dipping spread be 80 grams/m, fugitive constituent 3%,
Printing the sun-proof grade of ink is 7 grades, it is ensured that facing paper dipping is uniform.
In step B, the resin of dipping is the mixture of melamine formaldehyde resin and phenol-formaldehyde resin, wherein trimerization
Mass percent shared by cyanogen amine-formaldehyde resin is 50%, and mass percent shared by phenol-formaldehyde resin is 50%, it is ensured that after dipping
Facing paper possess toughness, while keeping affinity with electronic beam curing coating resin.
In step C, coating layer thickness 0.15mm；In step D, substrate is made of the fiberboard substrate that phenol an aromatic plant metioned in ancient books glue impregnates.
It in step E, is first warming up to 45 DEG C and facing paper is preheated, so that the phenol glue water of substrate melts, keep pressing plate
Heating is so that temperature is slowly raised to 150 DEG C again while pressure, and pressure is maintained to 10.0MPa, and heat preservation is cooled to after forty minutes
Room temperature removes pressing plate, with it is traditional be once pressurized to the hot pressing mode that bottom is heated up again compared with, can effectively avoid facing paper rupture,
Rate of becoming a useful person height.
The antistatic compact-panel that this method obtains is according to national standard GB/T 7911-2013 " thermosetting resin impregnated paper high pressure
Laminated decorative board " is detected, and the result of acquisition is referring to table 1.
Embodiment 4
A kind of manufacturing method of antistatic compact-panel, on the basis of embodiment 2, the manufacturing method of the present embodiment exists as follows
Difference:
In step B, facing paper dipping before 110 grams/m of grammes per square metre, dipping spread be 100 grams/m, fugitive constituent 2%,
Printing the sun-proof grade of ink is 7 grades, it is ensured that facing paper dipping is uniform.
In step B, the resin of dipping is the mixture of melamine formaldehyde resin and phenol-formaldehyde resin, wherein trimerization
Mass percent shared by cyanogen amine-formaldehyde resin is 60%, and mass percent shared by phenol-formaldehyde resin is 40%, it is ensured that after dipping
Facing paper possess toughness, while keeping affinity with electronic beam curing coating resin.
In step C, coating layer thickness 0.18mm；In step D, substrate is made of the fiberboard substrate that phenol an aromatic plant metioned in ancient books glue impregnates.
It in step E, is first warming up to 50 DEG C and facing paper is preheated, so that the phenol glue water of substrate melts, keep pressing plate
Heating is so that temperature is slowly raised to 145 DEG C again while pressure, and pressure is maintained to 9.5MPa, and heat preservation is cooled to often after 35 minutes
Temperature removes pressing plate, with it is traditional be once pressurized to the hot pressing mode that bottom is heated up again compared with, can effectively avoid facing paper rupture, at
Ability rate is high.
The antistatic compact-panel that this method obtains is according to national standard GB/T 7911-2013 " thermosetting resin impregnated paper high pressure
Laminated decorative board " is detected, and the result of acquisition is referring to table 1.
Embodiment 5
A kind of manufacturing method of antistatic compact-panel, on the basis of embodiment 2, the manufacturing method of the present embodiment exists as follows
Difference:
In step B, facing paper dipping before 90 grams/m of grammes per square metre, dipping spread be 110 grams/m, fugitive constituent 2%,
Printing the sun-proof grade of ink is 6 grades, it is ensured that facing paper dipping is uniform.
In step B, the resin of dipping is the mixture of melamine formaldehyde resin and phenol-formaldehyde resin, wherein trimerization
Mass percent shared by cyanogen amine-formaldehyde resin is 45%, and mass percent shared by phenol-formaldehyde resin is 55%, it is ensured that after dipping
Facing paper possess toughness, while keeping affinity with electronic beam curing coating resin.
In step C, coating layer thickness 0.17mm；In step D, brown paper that substrate is impregnated by melamine formaldehyde resin
It is made.
In step E, first it is warming up to 45 DEG C and facing paper is preheated, so that the melamine-formaldehyde glue of substrate melts,
It keeps heating up again while platen pressure so that temperature is slowly raised to 155 DEG C, pressure is maintained to 9.5MPa, after keeping the temperature 35 minutes
Be cooled to room temperature, remove pressing plate, with it is traditional be once pressurized to the hot pressing mode that bottom is heated up again compared with, can effectively avoid facing paper
Rupture, rate of becoming a useful person height.
The antistatic compact-panel that this method obtains is according to national standard GB/T 7911-2013 " thermosetting resin impregnated paper high pressure
Laminated decorative board " is detected, and the result of acquisition is referring to table 1.
The antistatic compact-panel GB/T 7911-2013 inspection result table of comparisons of table 1
4 embodiments antistatic compact-panel tensile strength obtained, bending strength exceed 15% or more standard value, resist quiet
Electrical property is substantially better than market product, is suitable for the harsh standard of laboratory, operating room etc., and wet-heat resisting, resistance to vapor, resistance to perfume (or spice)
Cigarette calcination can achieve 1 grade, and surface is unchanged.By the nano effect of nano-silver powder particle and its with permanent type height
Interaction (such as Van der Waals force and hydrogen bond) between molecule antistatic agent molecule improves effect to the antistatic property of compact-panel
Fruit is significant.
Obviously, the above embodiment is merely an example for clearly illustrating the present invention, and is not to of the invention
The restriction of embodiment.For those of ordinary skill in the art, it can also be made on the basis of the above description
Its various forms of variation or variation.There is no necessity and possibility to exhaust all the enbodiments.And these belong to this hair
Bright spiritual changes and variations that derived from are still in the protection scope of this invention.
Claims (6)
1. a kind of antistatic compact-panel characterized by comprising the outside cladding of substrate, substrate is processed through impregnating resin
Facing paper, the surface of the facing paper coats electronic beam curing coating, and the electronic beam curing coating is by following raw material by weight
Measure percentage composition: polyester acrylic 30%, phenolic aldehyde acrylic acid 19%, co-crosslinker 15%, hexanediyl ester 15%, resistance
Fire agent 4%, coupling agent 0.5%, levelling agent 0.5%, nano-silver powder 10%, dispersing agent 1%, antistatic agent 5%.
2. antistatic compact-panel according to claim 1, which is characterized in that the co-crosslinker is trimethylolpropane
Triacrylate.
3. the preparation method of antistatic compact-panel according to claim 1, which comprises the steps of:
A, electronic beam curing coating resin prepares: following raw material being added in blender by weight percentage, wherein polyester
Acid 30%, phenolic aldehyde acrylic acid 19%, co-crosslinker 15%, hexanediyl ester 15%, fire retardant 4%, coupling agent 0.5%, stream
Flat agent 0.5%, nano-silver powder 10%, dispersing agent 1%, antistatic agent 5% start blender and are heated to 50 DEG C, stir evenly, and take out
Vacuum obtains electronic beam curing coating resin solution；
B, by facing paper impregnating resin, and rewinding is dried, it is ensured that obtained facing paper grammes per square metre is uniform, and surface is smooth, prints ink
Sun-proof grade is not less than 6 grades；
C, adhesive curing is applied, roller coating is taken or pours mode that the electronic beam curing coating resin in step A is coated onto step B is resulting
On facing paper after dipping, coating layer thickness is 0.15 to 0.20mm, and is solidified by electron beam curing apparatus, obtains surface
Facing paper coated with electronic beam curing coating；
D, the layers of kraft paper of multilayer impregnation melamine formaldehyde resin is storied at substrate, or using fibre made of phenol an aromatic plant metioned in ancient books glue
It ties up plate substrate and obtains substrate；
E, the step C facing paper obtained is attached to the surface of the substrate of step D acquisition, and is sent into hot press and carries out hot-press solidifying,
Hot pressing temperature is 145 DEG C to 155 DEG C, and pressure is not less than 9.5MPa, and hot pressing time is to take cold into cold side out not less than 35 minutes
Formula obtains the compact-panel that surface is coated with electronic beam curing coating.
4. the preparation method of antistatic compact-panel according to claim 3, which is characterized in that in the step B, decoration
Grammes per square metre before paper dipping is 70 to 130 grams/m, and dipping spread is 50 to 150 grams/m, fugitive constituent 2-4%.
5. the preparation method of antistatic compact-panel according to claim 4, which is characterized in that in the step B, dipping
Resin be melamine formaldehyde resin and phenol-formaldehyde resin mixture, wherein matter shared by melamine formaldehyde resin
Measuring percentage is 40% to 60%.
6. the preparation method of antistatic compact-panel according to claim 5, which is characterized in that in the step E, first rise
Temperature preheats facing paper to 45 DEG C to 55 DEG C, so that the melamine formaldehyde resin of substrate or phenol an aromatic plant metioned in ancient books glue melt, keeps
Heating is cooled to room temperature after keeping the temperature the predetermined time so that temperature is slowly raised to 145 DEG C to 155 DEG C again while platen pressure,
Remove pressing plate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810288101.1A CN110315831A (en) | 2018-03-31 | 2018-03-31 | A kind of antistatic compact-panel and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810288101.1A CN110315831A (en) | 2018-03-31 | 2018-03-31 | A kind of antistatic compact-panel and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110315831A true CN110315831A (en) | 2019-10-11 |
Family
ID=68112173
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810288101.1A Withdrawn CN110315831A (en) | 2018-03-31 | 2018-03-31 | A kind of antistatic compact-panel and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110315831A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1099047A (en) * | 1994-06-27 | 1995-02-22 | 北京市富通光电工程公司 | Compositions of ultraviolet curing type |
| CN101314981A (en) * | 2007-05-29 | 2008-12-03 | 汪宏伟 | UV decorative lamination decoration board and manufacturing process |
| CN101821090A (en) * | 2007-10-09 | 2010-09-01 | 太尔公司 | Laminated product with improved weatherability |
| CN103289533A (en) * | 2013-05-10 | 2013-09-11 | 成都彭州立源高分子材料有限公司 | Method for preparing highlight colored paint plate by using electron beam radiation curing technology |
| CN104877547A (en) * | 2015-05-15 | 2015-09-02 | 成都纳硕科技有限公司 | Ultraviolet-light curing antibacterial, antiseptic and antistatic coating for metals |
| CN106696043A (en) * | 2017-01-06 | 2017-05-24 | 福建永林家居有限公司 | Production method and production device of non-formaldehyde laminated wood flooring |
-
2018
- 2018-03-31 CN CN201810288101.1A patent/CN110315831A/en not_active Withdrawn
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1099047A (en) * | 1994-06-27 | 1995-02-22 | 北京市富通光电工程公司 | Compositions of ultraviolet curing type |
| CN101314981A (en) * | 2007-05-29 | 2008-12-03 | 汪宏伟 | UV decorative lamination decoration board and manufacturing process |
| CN101821090A (en) * | 2007-10-09 | 2010-09-01 | 太尔公司 | Laminated product with improved weatherability |
| CN103289533A (en) * | 2013-05-10 | 2013-09-11 | 成都彭州立源高分子材料有限公司 | Method for preparing highlight colored paint plate by using electron beam radiation curing technology |
| CN104877547A (en) * | 2015-05-15 | 2015-09-02 | 成都纳硕科技有限公司 | Ultraviolet-light curing antibacterial, antiseptic and antistatic coating for metals |
| CN106696043A (en) * | 2017-01-06 | 2017-05-24 | 福建永林家居有限公司 | Production method and production device of non-formaldehyde laminated wood flooring |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US7771837B2 (en) | Derived timber board with a surface coating applied at least in parts | |
| AU2002217603B2 (en) | Fire-resistant composite panel and fire-resistant decorative composite panel using the same | |
| AU2002219657B2 (en) | Fire-resistant panel comprising loess and fire-resistant decorative panel using the same | |
| AU752630B2 (en) | Abrasion resistant laminate and process for producing same | |
| EP1549491A1 (en) | Electrostatic charge dissipating hard laminate surfaces | |
| JPS6240191B2 (en) | ||
| DE2146101A1 (en) | DECORATIVE ASBESTOS CEMENT SHEET AND METHOD OF MANUFACTURING IT | |
| US20060216536A1 (en) | Synthetic resin film for laminates and method of producing same | |
| CN110315832A (en) | A kind of weather-proof compact-panel of outdoor use and preparation method thereof | |
| EP2177372A2 (en) | Laminate surface layer without an overlay and method of manufacture | |
| CN110315831A (en) | A kind of antistatic compact-panel and preparation method thereof | |
| WO1999028101A1 (en) | Ligneous finishing material | |
| CZ301136B6 (en) | Process for producing impregnant and impregnant per se | |
| CN110315819A (en) | A kind of antibacterial and mouldproof plate and preparation method thereof | |
| CN110315806A (en) | A kind of super abrasive compact-panel and preparation method thereof | |
| CN110315835A (en) | A kind of plate surface electronic beam curing coating process | |
| CN110315808A (en) | A kind of nanoscale anti-pollution polymeric plate and preparation method thereof | |
| JP3081985B2 (en) | Non-combustible decorative board | |
| CN110328954A (en) | A kind of novel negative ion functional decoration plate and preparation method thereof | |
| CN209666512U (en) | A kind of lightweight composite anticorrosive deck plate | |
| JP5517643B2 (en) | Melamine decorative board and method for producing the same | |
| CN110315830A (en) | A kind of 0 grade of plate of new E and preparation method thereof | |
| CA1057599A (en) | Flexible decorative cladding sheet or strip | |
| JP2004034512A (en) | Decorative sheet and its manufacturing method | |
| JPS63246242A (en) | Abrasion-resistant board material and manufacture thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20191011 |
|
| WW01 | Invention patent application withdrawn after publication |