CN110315835A - A kind of plate surface electronic beam curing coating process - Google Patents

A kind of plate surface electronic beam curing coating process Download PDF

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Publication number
CN110315835A
CN110315835A CN201810287067.6A CN201810287067A CN110315835A CN 110315835 A CN110315835 A CN 110315835A CN 201810287067 A CN201810287067 A CN 201810287067A CN 110315835 A CN110315835 A CN 110315835A
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CN
China
Prior art keywords
beam curing
electronic beam
curing coating
facing paper
resin
Prior art date
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Pending
Application number
CN201810287067.6A
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Chinese (zh)
Inventor
孙学民
高聪民
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Individual
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Individual
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Priority to CN201810287067.6A priority Critical patent/CN110315835A/en
Publication of CN110315835A publication Critical patent/CN110315835A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/08Impregnating
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J161/00Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
    • C09J161/04Condensation polymers of aldehydes or ketones with phenols only
    • C09J161/06Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/24Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22Addition to the formed paper
    • D21H23/50Spraying or projecting
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/30Multi-ply
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B2038/0052Other operations not otherwise provided for
    • B32B2038/0076Curing, vulcanising, cross-linking
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • B32B2307/3065Flame resistant or retardant, fire resistant or retardant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554Wear resistance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion

Abstract

The present invention relates to a kind of plate surface electronic beam curing coating processes, the plate surface electronic beam curing coating process includes glue, dipping, electronic beam curing coating resin prepares, applies adhesive curing, hot pressing generates substrate, by laying the electronic beam curing coating being made of specific components on plate surface facing paper, so that the facing paper flame retardant property of plate surface is substantially improved.

Description

A kind of plate surface electronic beam curing coating process
Technical field
The present invention relates to board technology field, especially a kind of plate surface electronic beam curing coating process.
Background technique
Compact-panel has excellent stability, and is readily cleaned maintenance, thus the scope of application is extremely wide, and compact-panel is wide It is general to be applied to the large-scale public places such as school, hospital, airport, station, hotel, market, office building, kitchen tools table top in life, Wash one's hands and face table top, dining table, desk, door leaf, bath lavatory compartment, wash platform, reception counters, article placing cabinet, the ceiling, office of public space Table and office cubicles etc..
One layer of facing paper of existing compact-panel surface hot pressing, to obtain the compact-panel with surface marking or color, The performance of the special plate surface of confrontation times has some impact on after above-mentioned facing paper hot pressing, especially flame retardant property.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of plate surface electronic beam curing coating sides for improving its performance Method.
In order to solve the above technical problems, plate surface electronic beam curing coating process provided by the invention, including walk as follows It is rapid:
A, glue obtains phenolic resin;Dipping is added flexibility agent, fire retardant, antioxidant and dyestuff in phenolic resin and is formed Phenolic resin glue, and brown paper is immersed carry out impregnation.
B, by facing paper impregnating resin, and rewinding is dried, it is ensured that obtained facing paper grammes per square metre is uniform, and surface is smooth, printing The sun-proof grade of ink is not less than 6 grades.
C, electronic beam curing coating resin prepares: following raw material being added in blender by weight percentage, in which: poly- ammonia Ester acrylic acid 30%, epoxy acrylic 30%, co-crosslinker 10%, hexanediyl ester 18%, light stablize 1%, and ultraviolet light is inhaled Receive agent 1%, fire retardant 4%, coupling agent 0.5%, levelling agent 0.5%, bronze 4%, dispersing agent 1%.
D, adhesive curing is applied, takes roller coating or pour mode that the electronic beam curing coating resin in step C is coated onto step B institute On facing paper after the dipping obtained, coating layer thickness is 0.15 to 0.20mm, and is solidified by electron beam curing apparatus, is obtained Surface is coated with the facing paper of electronic beam curing coating.
E, the layers of kraft paper obtained step A is storied at substrate;The facing paper that step D is obtained pastes on the surface of the substrate, And be sent into hot press and carry out hot-press solidifying, hot pressing temperature is 145 DEG C to 155 DEG C, and pressure is not less than 9.5MPa, and hot pressing time is not Lower than 35 minutes, take it is cold into it is cold go out mode, obtain surface and be coated with the plate of electronic beam curing coating.
Further, in the step B, the grammes per square metre before facing paper dipping is 70 to 130 grams/m, and dipping spread is 50 to 150 grams/m, fugitive constituent 2-4%, it is ensured that facing paper dipping is uniform.
Further, in the step B, impregnating resin is the mixing of melamine formaldehyde resin and phenol-formaldehyde resin Object, wherein mass percent shared by melamine formaldehyde resin is 40% to 60%, it is ensured that the facing paper after dipping possesses toughness, Affinity is kept with electronic beam curing coating resin simultaneously.
Further, in the step E, 45 DEG C to 55 DEG C are first warming up to, facing paper is preheated, so that the phenolic aldehyde of substrate Glue melts, and keeps while platen pressure heating again so that temperature is slowly raised to 145 DEG C to 155 DEG C, keeps the temperature the predetermined time After be cooled to room temperature, remove pressing plate, with it is traditional be once pressurized to the hot pressing mode that bottom is heated up again compared with, can effectively avoid decoration Paper rupture, rate of becoming a useful person height.
The technical effect of invention: (1) of the invention plate surface electronic beam curing coating process, compared with the existing technology, By laying the electronic beam curing coating being made of specific components on plate surface facing paper, so that the facing paper of plate surface Flame retardant property is substantially improved;(2) Electron beam curing technology is used into plate surface, plate surface performance, surface tool can be improved There is self-cleaning ability, this is that common compact-panel is not accomplished;The characteristics of due to electronic beam curing coating, electronic beam curing coating Product has very strong resistance, while because the chemical substance in coating is the high molecular weight steric net formed by cross-linking reaction Shaped polymer, so coating surface has very strong chemical-resistance and crocking resistance;(3) when thermocompression forming, first preheating is risen Temperature is to 50 DEG C or so, so that the glue on substrate pressurizes again after melting, is once pressurized to the heat to heat up again at bottom with traditional Pressure mode is compared, and can effectively avoid facing paper rupture, and rate of becoming a useful person is high, while can avoid consolidating because temperature change dramatically influences electron beam Change coating.
Detailed description of the invention
Invention is further described in detail with reference to the accompanying drawings of the specification:
Fig. 1 is the schematic diagram of the section structure for the plate that the embodiment of the present invention 1 obtains.
In figure: substrate 1, facing paper 2, electronic beam curing coating 3.
Specific embodiment
Embodiment 1
A kind of manufacturing method of plate surface electronic beam curing coating process, includes the following steps:
A, glue obtains phenolic resin;Dipping is added flexibility agent, fire retardant, antioxidant and dyestuff in phenolic resin and is formed Phenolic resin glue, and brown paper is immersed carry out impregnation.
B, by facing paper impregnating resin, and rewinding is dried, it is ensured that obtained facing paper grammes per square metre is uniform, and surface is smooth, printing The sun-proof grade of ink is not less than 6 grades.
C, electronic beam curing coating resin prepares: following raw material being added in blender by weight percentage, in which: poly- ammonia Ester acrylic acid 30%, epoxy acrylic 30%, co-crosslinker 10%, hexanediyl ester 18%, light stablize 1%, and ultraviolet light is inhaled Receive agent 1%, fire retardant 4%, coupling agent 0.5%, levelling agent 0.5%, bronze 4%, dispersing agent 1%.
D, adhesive curing is applied, takes roller coating or pour mode that the electronic beam curing coating resin in step C is coated onto step B institute On facing paper after the dipping obtained, coating layer thickness is 0.15 to 0.20mm, and is solidified by electron beam curing apparatus, is obtained Surface is coated with the facing paper of electronic beam curing coating;Electron-beam voltage is 300KV during electronic beam curing, and energy is 100KGy, curing rate are 200 ms/min.
E, the layers of kraft paper obtained step A is storied at substrate;The facing paper that step D is obtained pastes on the surface of the substrate, And be sent into hot press and carry out hot-press solidifying, hot pressing temperature is 145 DEG C to 155 DEG C, and pressure is not less than 9.5MPa, and hot pressing time is not Lower than 35 minutes, take it is cold into it is cold go out mode, obtain surface and be coated with the plate of electronic beam curing coating, cross-section structure is as schemed Shown in 1.
Wherein in step B, facing paper dipping before 120 grams/m of grammes per square metre, dipping spread be 120 grams/m, Fugitive constituent 3.5%, the printing sun-proof grade of ink are 7 grades, it is ensured that facing paper dipping is uniform.
In step B, the resin of dipping is the mixture of melamine formaldehyde resin and phenol-formaldehyde resin, wherein trimerization Mass percent shared by cyanogen amine-formaldehyde resin is 40%, and mass percent shared by phenol-formaldehyde resin is 60%, it is ensured that after dipping Facing paper possess toughness, while keeping affinity with electronic beam curing coating resin.
In step D, coating layer thickness 0.17mm.
It in step E, is first warming up to 50 DEG C and facing paper is preheated, so that the phenolic resin of substrate melts, keep pressing plate Heating is so that temperature is slowly raised to 155 DEG C again while pressure, and pressure is maintained to 9.5MPa, and heat preservation is cooled to often after 35 minutes Temperature removes pressing plate, with it is traditional be once pressurized to the hot pressing mode that bottom is heated up again compared with, can effectively avoid facing paper rupture, at Ability rate is high.
The plate that this method obtains is hindered according to GB 8624-2012 " construction material and classification of combustion properties of building materials and products " Service check is fired, specific testing result is referring to table 1.
Embodiment 2
A kind of manufacturing method of plate surface electronic beam curing coating process, on the basis of embodiment 1, the manufacture of the present embodiment There is following difference in method:
In step B, facing paper dipping before 95 grams/m of grammes per square metre, dipping spread be 105 grams/m, fugitive constituent 4.0%, the printing sun-proof grade of ink is 7 grades, it is ensured that facing paper dipping is uniform.
In step B, impregnating resin is the mixture of melamine formaldehyde resin and phenol-formaldehyde resin, wherein melamine Mass percent shared by amine-formaldehyde resin is 50%, and mass percent shared by phenol-formaldehyde resin is 50%, it is ensured that after dipping Facing paper possesses toughness, while keeping affinity with electronic beam curing coating resin.
In step D, coating layer thickness 0.20mm.
It in step E, is first warming up to 50 DEG C and facing paper is preheated, so that the phenol glue water of substrate melts, keep pressing plate Heating is so that temperature is slowly raised to 155 DEG C again while pressure, and pressure is maintained to 10.0MPa, and heat preservation is cooled to after forty minutes Room temperature removes pressing plate, with it is traditional be once pressurized to the hot pressing mode that bottom is heated up again compared with, can effectively avoid facing paper rupture, Rate of becoming a useful person height.
The plate that this method obtains is hindered according to GB 8624-2012 " construction material and classification of combustion properties of building materials and products " Service check is fired, specific testing result is referring to table 1.
Embodiment 3
A kind of manufacturing method of plate surface electronic beam curing coating process, on the basis of embodiment 1, the manufacture of the present embodiment There is following difference in method:
In step B, facing paper dipping before 100 grams/m of grammes per square metre, dipping spread be 80 grams/m, fugitive constituent 2.5%, the printing sun-proof grade of ink is 7 grades, it is ensured that facing paper dipping is uniform.
In step B, impregnating resin is the mixture of melamine formaldehyde resin and phenol-formaldehyde resin, wherein melamine Mass percent shared by amine-formaldehyde resin is 60%, and mass percent shared by phenol-formaldehyde resin is 40%, it is ensured that after dipping Facing paper possesses toughness, while keeping affinity with electronic beam curing coating resin.
In step D, coating layer thickness 0.15mm.
It in step E, is first warming up to 50 DEG C and facing paper is preheated, so that the phenol glue water of substrate melts, keep pressing plate Heating is so that temperature is slowly raised to 150 DEG C again while pressure, and pressure is maintained to 9.5MPa, and heat preservation is cooled to often after 35 minutes Temperature removes pressing plate, with it is traditional be once pressurized to the hot pressing mode that bottom is heated up again compared with, can effectively avoid facing paper rupture, at Ability rate is high.
The plate that this method obtains is hindered according to GB 8624-2012 " construction material and classification of combustion properties of building materials and products " Service check is fired, specific testing result is referring to table 1.
Embodiment 4
A kind of manufacturing method of plate surface electronic beam curing coating process, on the basis of embodiment 1, the manufacture of the present embodiment There is following difference in method:
In step B, facing paper dipping before 120 grams/m of grammes per square metre, dipping spread be 120 grams/m, fugitive constituent 2.5%, the printing sun-proof grade of ink is 8 grades, it is ensured that facing paper dipping is uniform.
In step B, impregnating resin is the mixture of melamine formaldehyde resin and phenol-formaldehyde resin, wherein melamine Mass percent shared by amine-formaldehyde resin is 55%, and mass percent shared by phenol-formaldehyde resin is 45%, it is ensured that after dipping Facing paper possesses toughness, while keeping affinity with electronic beam curing coating resin.
In step D, coating layer thickness 0.15mm.
It in step E, is first warming up to 55 DEG C and facing paper is preheated, so that the phenol glue water of substrate melts, keep pressing plate Heating is so that temperature is slowly raised to 155 DEG C again while pressure, and pressure is maintained to 9.5MPa, and heat preservation is cooled to often after 35 minutes Temperature removes pressing plate, with it is traditional be once pressurized to the hot pressing mode that bottom is heated up again compared with, can effectively avoid facing paper rupture, at Ability rate is high.
The plate that this method obtains is hindered according to GB 8624-2012 " construction material and classification of combustion properties of building materials and products " Service check is fired, specific testing result is referring to table 1.
The 1 plate GB 8624-2012 inspection result table of comparisons of table
By carrying out combustibility detection to the sheet coupon obtained of embodiment 1 to 4, combustibility meets GB8624- B1 grades of prescribed requirement in 2012, additional classification meet s1, d0, t1 grades of prescribed requirement.It may conform to hotel, market, office building The fire protection requirement of equal large-scale public places, improves the scope of application of plate.
Obviously, the above embodiment is merely an example for clearly illustrating the present invention, and is not to of the invention The restriction of embodiment.For those of ordinary skill in the art, it can also be made on the basis of the above description Its various forms of variation or variation.There is no necessity and possibility to exhaust all the enbodiments.And these belong to this hair Bright spiritual changes and variations that derived from are still in the protection scope of this invention.

Claims (4)

1. a kind of plate surface electronic beam curing coating process, which comprises the steps of:
A, glue obtains phenolic resin;Dipping is added flexibility agent, fire retardant, antioxidant and dyestuff in phenolic resin and is formed Phenolic resin glue, and brown paper is immersed carry out impregnation;
B, by facing paper impregnating resin, and rewinding is dried, it is ensured that obtained facing paper grammes per square metre is uniform, and surface is smooth, prints ink Sun-proof grade is not less than 6 grades;
C, electronic beam curing coating resin prepares: following raw material being added in blender by weight percentage, in which: polyurethane third Olefin(e) acid 30%, epoxy acrylic 30%, co-crosslinker 10%, hexanediyl ester 18%, light stablize 1%, ultraviolet absorbing agent 1%, fire retardant 4%, coupling agent 0.5%, levelling agent 0.5%, bronze 4%, dispersing agent 1%;
D, adhesive curing is applied, roller coating is taken or pours mode that the electronic beam curing coating resin in step C is coated onto step B is resulting On facing paper after dipping, coating layer thickness is 0.15 to 0.20mm, and is solidified by electron beam curing apparatus, obtains surface Facing paper coated with electronic beam curing coating;
E, the layers of kraft paper obtained step A is storied at substrate;The facing paper patch that step D is obtained on the surface of the substrate, and is sent Enter hot press carry out hot-press solidifying, hot pressing temperature be 145 DEG C to 155 DEG C, pressure be not less than 9.5MPa, hot pressing time be not less than 35 minutes, take it is cold into it is cold go out mode, obtain surface and be coated with the plate of electronic beam curing coating.
2. the preparation method of plate surface electronic beam curing coating process according to claim 1, which is characterized in that described In step B, the grammes per square metre before facing paper dipping is 70 to 130 grams/m, and dipping spread is 50 to 150 grams/m, is waved Send out part 2-4%.
3. the preparation method of plate surface electronic beam curing coating process according to claim 1, which is characterized in that described In step B, impregnating resin is the mixture of melamine formaldehyde resin and phenol-formaldehyde resin, wherein melamine-formaldehyde Mass percent shared by resin is 40% to 60%.
4. the preparation method of plate surface electronic beam curing coating process according to claim 1, which is characterized in that described It in step E, is first warming up to 45 DEG C to 55 DEG C and facing paper is preheated, so that the phenol an aromatic plant metioned in ancient books glue of substrate melts, keep pressing plate pressure Heating is cooled to room temperature after keeping the temperature the predetermined time, removes pressure so that temperature is slowly raised to 145 DEG C to 155 DEG C again while power Plate.
CN201810287067.6A 2018-03-31 2018-03-31 A kind of plate surface electronic beam curing coating process Pending CN110315835A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810287067.6A CN110315835A (en) 2018-03-31 2018-03-31 A kind of plate surface electronic beam curing coating process

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Application Number Priority Date Filing Date Title
CN201810287067.6A CN110315835A (en) 2018-03-31 2018-03-31 A kind of plate surface electronic beam curing coating process

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112941953A (en) * 2020-12-31 2021-06-11 南京盛凯新材料有限公司 Wear-resistant paper produced by EB (Electron Beam) curing and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN1503739A (en) * 2001-03-14 2004-06-09 �������(ŷ��)�ɷ����޹�˾ A process for the manufacturing of decorative boards
CN101503581A (en) * 2009-03-09 2009-08-12 中国科学技术大学 Radiation curable expansion type flame-retardant transparent nano composite coating and preparation thereof
CN101628450A (en) * 2009-08-31 2010-01-20 李运生 Method for pasting melamine dipped paper on blockboard or plywood
CN101821090A (en) * 2007-10-09 2010-09-01 太尔公司 Laminated product with improved weatherability
CN102876175A (en) * 2011-07-15 2013-01-16 尹梦秋 Metal powder coating
CN103289533A (en) * 2013-05-10 2013-09-11 成都彭州立源高分子材料有限公司 Method for preparing highlight colored paint plate by using electron beam radiation curing technology
CN106696043A (en) * 2017-01-06 2017-05-24 福建永林家居有限公司 Production method and production device of non-formaldehyde laminated wood flooring

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1503739A (en) * 2001-03-14 2004-06-09 �������(ŷ��)�ɷ����޹�˾ A process for the manufacturing of decorative boards
CN101821090A (en) * 2007-10-09 2010-09-01 太尔公司 Laminated product with improved weatherability
CN101503581A (en) * 2009-03-09 2009-08-12 中国科学技术大学 Radiation curable expansion type flame-retardant transparent nano composite coating and preparation thereof
CN101628450A (en) * 2009-08-31 2010-01-20 李运生 Method for pasting melamine dipped paper on blockboard or plywood
CN102876175A (en) * 2011-07-15 2013-01-16 尹梦秋 Metal powder coating
CN103289533A (en) * 2013-05-10 2013-09-11 成都彭州立源高分子材料有限公司 Method for preparing highlight colored paint plate by using electron beam radiation curing technology
CN106696043A (en) * 2017-01-06 2017-05-24 福建永林家居有限公司 Production method and production device of non-formaldehyde laminated wood flooring

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112941953A (en) * 2020-12-31 2021-06-11 南京盛凯新材料有限公司 Wear-resistant paper produced by EB (Electron Beam) curing and preparation method thereof

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Application publication date: 20191011

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