CN106305757B - A kind of Synergistic herbicide compositions grand comprising diflufenican and thiophene ketone sulphur - Google Patents
A kind of Synergistic herbicide compositions grand comprising diflufenican and thiophene ketone sulphur Download PDFInfo
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- CN106305757B CN106305757B CN201610846671.9A CN201610846671A CN106305757B CN 106305757 B CN106305757 B CN 106305757B CN 201610846671 A CN201610846671 A CN 201610846671A CN 106305757 B CN106305757 B CN 106305757B
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- diflufenican
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
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- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of Synergistic herbicide compositions grand comprising diflufenican and thiophene ketone sulphur, effective component diflufenican and the grand weight ratio of thiophene ketone sulphur can be 1:0.03~30 in the composition.Pharmacodynamic test shows that the composition has the characteristics that with strong complementarity, synergistic effect is obvious, degrass spectrum expands, amount of application is reduced, the optimum period for applying fertilizer extends, high, environmental pollution reduces, is by force etc. positive with environment compatibility to crop safety.
Description
Technical field
The invention belongs to agriculture plant protection fields, more particularly to a kind of with the Herbicidal combinations for improving performance.Tool
Body is related to a kind of Synergistic herbicide compositions grand comprising diflufenican and thiophene ketone sulphur.
Background technique
Active component diflufenican (diflufenican) medicine belongs to herxheimer-liked reaction inhibitor.Cause
Destruction of Chlorophyll and cell rupture, Plant death.Diflufenican is a kind of acetamide-group herbicides, is applied before and after weeds germination
The medicine soil layer of anti-leaching can be formed in native table, keep activity in crop entire growth period.When weed germination passes through medicine soil layer young shoot
Or root system can absorb medicament, diflufenican, which has, inhibits herxheimer-liked reaction effect, absorbs the weeds plant of medicament
Middle carotenoid content decline, causes chlorophyll to be destroyed, and membranolysis, weeds then show as young shoot decoloration or white, most
Whole strain is wilted dead afterwards.
Grand grand (thiencarbazone-methyl) the thiophene ketone sulphur of active component thiophene ketone sulphur is can effectively to prevent and kill off corn field grass
Section weeds and broadleaf weeds show good balance between blade face application and residual action.The effective component can be prevented and kill off effectively
Piemarker and many Caryophyllaceae weeds, early stage all can be used before bud and after bud.Thiophene ketone sulphur is grand to can be used for lawn and ornamental plant,
Method of administration does not allow to be administered by irrigation system only in ground installation.
Actual pesticide experience have shown that, repeat and single-minded apply a kind of reactive compound and carry out controlling weeds in many feelings
It will lead to the fast selective of weeds under condition, prevent and treat injurious weed usually using the mixture of different activities compound at present.
By will have the reactive compound of different role mechanism to be combined, can delaying drug resistance generate, reduce amount of application, reduce prevention and treatment
Cost.
Summary of the invention
The purpose of the present invention is being directed to herbicide resistance and pedo relict problem in practical applications, filter out containing two
The herbicide diflufenican of kind different weeding principles and thiophene ketone sulphur is grand is compounded, to improve herbicide prevention effect, delays
Resistance generates, and reduces amount of application, reduces control cost.
It is a further object of the present invention to provide a kind of application of above-mentioned composition in agriculture field controlling weeds.
The purpose of the present invention can be achieved by the following measures:
The present invention provides a kind of Herbicidal combinations with synergistic effect, contain effective constituents A and B in the composition,
Effective constituents A is diflufenican, and effective component B is that thiophene ketone sulphur is grand.
Inventor is found by experiment that above-mentioned Herbicidal combinations synergy is obvious, it is often more important that amount of application is reduced, and reduction makes
Use cost.Different from the compound structure type of component B containing component A, mechanism of action is different, and the two compounding can expand weeding
Spectrum, and generation and the development speed of Weed Resistance can be delayed to a certain extent, and no interactions between component A and component B
Resistance.
The effective component of the present composition can only include A and B, can also be in the base for not influencing composition overall performance
On plinth, other effective components are further included.
In a kind of scheme, the effective constituents A of Herbicidal combinations of the present invention and the weight ratio of B are 1:0.03~30.
In another scheme, the effective constituents A of Herbicidal combinations of the present invention and the weight ratio of B are 1:0.05~20.
In another scheme, the effective constituents A of Herbicidal combinations of the present invention and the weight ratio of B are 1:0.1~10.
In a preferred solution, the weight ratio between two component of A and B can be arbitrarily in the range of following proportions
Be adjusted: 1:0.03,1:0.04,1:0.05,1:0.06,1:0.07,1:0.08,1:0.09,1:0.1,1:0.2,1:0.3,
1:0.4,1:0.5,1:0.6,1:0.7,1:0.8,1:0.9,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10,
1:11,1:12,1:13,1:14,1:15,1:16,1:17,1:18,1:19,1:20,1:21,1:22,1:23,1:24,1:25,1:
26,1:27,1:28,1:29,1:30 can also be matched at any of the above two and be selected in composed range, these ratios
Example can be understood as weight ratio, also may include molar ratio.
Dosage form pesticide-acceptable can be made by effective component and insecticides adjuvant in composition of the invention jointly.
The mass content of effective component can be 2~95%, preferably 5~80% in composition of the invention.
To give full play to function and effect of the invention, the present composition can also be with other pesticide (such as fungicide, desinsection
Agent, herbicide, plant growth regulator), fertilizer etc. be used in mixed way, it is to commonly use disclosed in the prior art that these are mixed therewith
Pesticide or fertilizer.Suitable fertilizer includes: inorganic fertilizer or organic fertilizer, and specific fertilizer such as contains one of nitrogen, phosphorus, potassium
Or several a great number of elements, or containing one or more of copper, iron, manganese, zinc, boron, calcium, magnesium, sulphur etc. microelement, or contain corruption
Grow at least one mixture of the fertilizer such as acid, amino acid.
It may include carrier, auxiliary agent and/or surfactant in the present composition.It can be mixed during application
Common auxiliary agent.
Suitable auxiliary agent can be solid or liquid, they are usually common substance during formulation, such as day
Right or regenerated minerals, solvent, dispersing agent, wetting agent, adhesive, thickener, adhesive or fertilizer.
The method of administration of the present composition includes the aerial part that composition of the invention is used for plant growth, especially
It is leaf portion or blade face.The growth place of plant, such as rice field can be soaked with the liquid preparation of composition, or by composition
It is applied in soil in solid form, such as in granular form (soil application), composition can be entered by soil through plant root
In plant (systemic action).
These compositions can only include that active constituent (also known as effective component) is administered, can also with additive or
Auxiliary agent mixes together, therefore composition of the invention can be prepared into various dosage forms, for example, wettable powder, suspending agent,
Dispersible oil-suspending agent, aqueous emulsion, missible oil, water dispersible granules etc..According to the property of these compositions and application composition institute
Purpose to be achieved and ambient conditions can choose composition to be sprayed, atomizing, dust, broadcast sowing or sprinkle the side poured or the like
Method application.
Composition of the invention can be prepared into various dosage forms by known method, such as can by effective component with help
Agent can uniformly mix together with surfactant when needing, grind, be prepared into required agent such as solvent, solid carrier
Type.
Above-mentioned solvent can be selected from aromatic hydrocarbon, preferably contain 8-12 carbon atom, such as xylene mixture or substituted benzene, phthalein
Esters of gallic acid, such as two octanoic acid of Dibutyl phthalate or phthalandione, fat hydrocarbon, such as thiacyclohexane or paraffin, the ether of pure and mild ethylene glycol and they
And ester, such as ethyl alcohol, ethylene glycol, ethylene glycol monomethyl；Ketone, such as cyclohexanone, highly polar solvent, such as N- methyl -2- pyrrolidines
Ketone, dimethyl sulfoxide or dimethylformamide and vegetable oil or vegetable oil, such as soybean oil.
Above-mentioned solid carrier, such as usually natural mineral fillers, such as talcum, kaolinite for pulvis and dispersible agent
Soil, montmorillonite or atlapulgite.In order to manage the physical property of composition, polymolecularity silicic acid or polymolecularity can also be added
Adsorpting polymerization object carrier, such as granulated adsorptive carriers or non-adsorbed carrier, suitable granulated adsorptive carriers are porous types, it is such as floating
Stone, bentonite or bentonite；Suitable non-adsorbed carrier such as calcite or sand.Further, it is possible to use a large amount of inorganic in nature or having
The prefabricated material to granulate of machine property is as carrier, especially dolomite.
The chemical property of effective component in composition according to the present invention, suitable surfactant are sulfomethylated lignin
Acid, naphthalene sulfonic acids, phenolsulfonic acid, alkali salt or amine salt, alkylaryl sulfonates, alkyl sulfate, alkylsulfonate, fat
Alcohol sulfate, fatty acid and sulphated fatty alcohol glycol ether, there are also the condensation product of sulfonated naphthalene and naphthalene derivatives and formaldehyde, naphthalene or
The condensation product of naphthalene sulfonic acids and phenol and formaldehyde, NONIN HS 240, ethoxylated isooctyl-phenol, octyl phenol, nonyl phenol,
Alkylaryl polyglycol ether, tributyl benzene polyglycol ether, three stearyl phenyl polyglycol ethers, alkyl aryl polyether alcohol,
Ethoxylated castor oil, polyoxyethylene alkyl ether, ethylene oxide condensation product, ethoxylation polyoxypropylene, laurel acid polyethylene glycol
Ether acetal, sorbitol ester, lignin sulfite waste liquor and methylcellulose.
Two kinds of effective components show as synergistic effect in composition of the invention, and the activity of the composition is than using individualized
The independent activity of the expected summation of activity and single compound of closing object is more significant.Synergistic effect shows as allowing amount of application
Reduce, broader weeding control spectrum, quick, more longlasting control efficiency, by only once or a small number of application several times more preferably
Control weeds and broaden the possible administration interval time.These characteristics are to prevent and kill off in control weeds practice process especially
It needs.
In terms of Herbicidal combinations of the invention can be applicable to agriculture field prevention and treatment crop weeds, iron amaranth is especially prevented and treated
Dish, humulus grass, field bindweed, sowthistle.
The other features of Herbicidal combinations of the invention shown are mainly shown as: 1, due to two lists of this composition
Agent chemical structure is widely different, and the mechanism of action is entirely different, and cross resistance is not present, and two single dose exclusive uses can be delayed to be produced
Raw resistance problem；2, composition of the invention is good to crop safety, preventive effect.Tests prove that herbicidal composition of the present invention
Chemical property is stablized, and synergy is significant, shows apparent synergy and complementation to controlling object.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that described herein, specific examples are only used to explain the present invention, is not used to limit
The fixed present invention, any modifications, equivalent replacements and improvementsmade within the spirit and principles of the invention, etc. should be included in
Within protection scope of the present invention.
Percentage is weight percentage in all formulas of following embodiment.The processing work of the various preparations of the present composition
Skill is the prior art, can be varied according to different situations.
One, dosage form prepares embodiment
(1) processing and embodiment of wettable powder
Active constituent diflufenican and active constituent thiophene ketone sulphur is grand sufficiently mixed in proportion with various auxiliary agents and filler etc.
It closes, wettable powder is made after ultra-fine pulverizer disintegrating.
The grand sylvite wettable powder of embodiment 1:21% diflufenican thiophene ketone sulphur
Diflufenican 20%, the grand sylvite 1% of thiophene ketone sulphur, diatomite 8%, sodium lignin sulfonate 4%, naphthalene sulfonic acid potassium 5%,
Kaolin complements to 100%.
The grand wettable powder of embodiment 2:55% diflufenican thiophene ketone sulphur
Diflufenican 5%, thiophene ketone sulphur grand 50%, aliphatic alcohol sulfate 4%, bentonite 6%, methyl naphthalene sulfonic acid sodium formaldehyde
Condensation product 6%, white carbon black complements to 100%.
The grand wettable powder of embodiment 3:31% diflufenican thiophene ketone sulphur
Diflufenican 1%, thiophene ketone sulphur grand 30%, calcite 3%, methyl naphthalene sulfonate formaldehyde condensate 5%, octyl phenol
6%, kaolin complements to 100%.
(2) processing and embodiment of missible oil
By active constituent diflufenican and thiophene ketone sulphur, each components such as grand, emulsifier, organic solvent are mixed in the ratio of formula
Conjunction is uniformly got product.
Embodiment 4:11% diflufenican thiophene ketone sulphur mamaplasty oil
Diflufenican 10%, thiophene ketone sulphur grand 1%, alkylaryl polyglycol ether 7%, dimethyl sulfoxide complements to
100%.
Embodiment 5:63% diflufenican thiophene ketone sulphur mamaplasty oil
Diflufenican 3%, thiophene ketone sulphur grand 60%, ethylene glycol 10%, toluene complements to 100%.
Embodiment 6:24% diflufenican thiophene ketone sulphur mamaplasty oil
Diflufenican 8%, thiophene ketone sulphur grand 16%, methyl naphthalene sulfonate formaldehyde condensate 9%, dimethylbenzene complements to
100%.
(3) processing and embodiment of aqueous emulsion
The each components such as grand, emulsifier, dispersing agent, organic solvent, antifreeze by active constituent diflufenican and thiophene ketone sulphur
It is mixed according to the formula and uniformly gets product.
Embodiment 7:30% diflufenican thiophene ketone sulphur precititation emulsion
Diflufenican 20%, thiophene ketone sulphur grand 10%, sulfuric acid diammonium 5%, sodium lignin sulfonate 3% are polyxyethylated
Ether 5%, ethyl alcohol 9%, water complements to 100%.
Embodiment 8:31% diflufenican thiophene ketone sulphur precititation emulsion
Diflufenican 30%, thiophene ketone sulphur grand 1%, lauric acid polyglycol ether acetal 5%, polyoxyethylene alkyl ether 6%,
Toluene 10%, propylene glycol 5%, water complements to 100%.
Embodiment 9:20% diflufenican thiophene ketone sulphur precititation emulsion
Diflufenican 10%, thiophene ketone sulphur grand 10%, methyl naphthalene sulfonate formaldehyde condensate 4%, toluene 11%, ammonium sulfate
5%, benzoate 2%, water complements to 100%.
Two, drug effect verification test
(1) Assays Example
Using diflufenican as standard agent, disease index and control efficiency are calculated.Control efficiency is converted into probability
It is worth (y), liquor strength (μ g/ml) is converted into logarithm (x), calculates concentration in virulence equation and inhibition with least square method
EC50 calculates the toxicity index grade co-toxicity coefficient (CTC) of medicament according to Sun Yunpei's Method.Toxicity test the results are shown in Table 1.
Survey toxicity index (ATI)=(standard agent EC50/ reagent agent EC50) * 100
Percentage composition+B medicament toxicity index * the mixture of A in theoretical toxicity index (TTI)=A medicament toxicity index * mixture
The percentage composition of middle B
Co-toxicity coefficient (CTC)=[mixture surveys toxicity index (ATI)/mixtures theoretical toxicity index (TTI)] * 100
CTC≤80, composition show as antagonism, 80 < CTC < 120, and composition shows as summation action, and CTC >=
120, composition shows as synergistic effect.
1, diflufenican tests the toxicity test of acalypha copperleaf with grand compound of thiophene ketone sulphur
1 diflufenican of table is compounded with the grand different ratio of thiophene ketone sulphur analyzes (one) to the toxicity test of acalypha copperleaf
As a result (table 1) shows that diflufenican and thiophene ketone sulphur are grand between proportion 1~30:1~30, and co-toxicity coefficient exists
122 or more, illustrate diflufenican with thiophene ketone sulphur is grand compounds preventing and kill off with significant synergistic function to acalypha copperleaf.Experiment
It was found that when diflufenican and the grand proportion of thiophene ketone sulphur not within the scope of the invention when, the two is difficult have association to acalypha copperleaf
Same synergistic effect.
2, diflufenican tests (two) to the toxicity test of humulus grass with grand compound of thiophene ketone sulphur
2 diflufenican of table and the grand toxicity test interpretation of result compounded to humulus grass of thiophene ketone sulphur
As a result (table 2) shows that diflufenican and thiophene ketone sulphur are grand between proportion 1~30:1~30, and co-toxicity coefficient exists
126 or more, illustrate diflufenican with thiophene ketone sulphur is grand compounds preventing and kill off with significant synergistic function to humulus grass.Experiment hair
It is existing, when diflufenican and the grand proportion of thiophene ketone sulphur not within the scope of the invention when, the two is difficult that there is collaboration to increase to humulus grass
Effect effect.
(2) field control effectiveness test
1, diflufenican and the grand field control effect of thiophene ketone sulphur are verified using embodiment produced by the present invention.
It is expected that preventive effect (%)=X+Y-XY/100 (wherein, X, Y are single dose preventive effect)
3. diflufenican of table and the grand field efficiency test result compounded to field bindweed and sowthistle of thiophene ketone sulphur
Measurement result (table 3) shows that diflufenican and thiophene ketone sulphur are grand and compounds to controlling weeds field bindweed and sowthistle
Preventive effect significantly improves, and illustrates that the two compounding has significant synergistic function to field bindweed and sowthistle.
Claims (7)
1. a kind of Herbicidal combinations with synergistic effect, it is characterised in that the composition contains effective constituents A and B, wherein having
Effect ingredient A is diflufenican, and effective component B is that thiophene ketone sulphur is grand；The effective constituents A and the weight ratio of B are 1:0.03~30.
2. Herbicidal combinations according to claim 1, it is characterised in that the effective constituents A and the weight ratio of B are 1:
0.05~20.
3. Herbicidal combinations according to claim 1, it is characterised in that the composition is total to by effective component and insecticides adjuvant
It is same that dosage form pesticide-acceptable is made.
4. Herbicidal combinations according to claim 3, it is characterised in that the mass content of effective component is 2 in the composition
~95%.
5. Herbicidal combinations according to claim 3, it is characterised in that the dosage form be wettable powder, suspending agent, can
Disperse oil-suspending agent, aqueous emulsion, missible oil or water dispersible granules.
6. use of the Herbicidal combinations described in any one of Claims 1 to 5 in terms of agriculture field prevents and treats crop weeds
On the way.
7. purposes according to claim 6, it is characterised in that the weeds are selected from and broadcast acalypha copperleaf, humulus grass, field bindweed, lettuce Mai
Dish.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610846671.9A CN106305757B (en) | 2016-09-23 | 2016-09-23 | A kind of Synergistic herbicide compositions grand comprising diflufenican and thiophene ketone sulphur |
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| CN201610846671.9A CN106305757B (en) | 2016-09-23 | 2016-09-23 | A kind of Synergistic herbicide compositions grand comprising diflufenican and thiophene ketone sulphur |
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| CN107027762A (en) * | 2017-06-09 | 2017-08-11 | 安徽省农业科学院植物保护与农产品质量安全研究所 | A kind of Herbicidal combinations containing diflufenican and mesosulfuron |
| CN107926970A (en) * | 2017-11-30 | 2018-04-20 | 南京红太阳股份有限公司 | A kind of sulphur of ketone containing thiophene is grand with the Herbicidal combinations of isopropyl methoxalamine and its application |
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| CN108077297A (en) * | 2017-12-15 | 2018-05-29 | 江苏辉丰生物农业股份有限公司 | Herbicidal combinations containing diflufenican and rimsulfuron |
| CN108077302A (en) * | 2017-12-25 | 2018-05-29 | 南京红太阳股份有限公司 | A kind of grand Herbicidal combinations and its application with propisochlor of sulphur of ketone containing thiophene |
| CN107996596A (en) * | 2017-12-25 | 2018-05-08 | 南京红太阳股份有限公司 | A kind of sulphur of ketone containing thiophene is grand with making its grand Herbicidal combinations and its application |
| CN108077298A (en) * | 2017-12-25 | 2018-05-29 | 南京红太阳股份有限公司 | A kind of grand Herbicidal combinations and its application with butachlor of sulphur of ketone containing thiophene |
| CN108094437A (en) * | 2017-12-25 | 2018-06-01 | 南京红太阳股份有限公司 | A kind of grand Herbicidal combinations and its application with alachlor of sulphur of ketone containing thiophene |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1361778A (en) * | 1999-07-15 | 2002-07-31 | 拜尔公司 | Substituted thiene-3-yl-sulfonyl amino (thio) carbonyl-triazolin (thi) ones |
| CN101677529A (en) * | 2007-06-21 | 2010-03-24 | 拜尔农作物科学股份公司 | Active ingredient suspensions in glycerine |
-
2016
- 2016-09-23 CN CN201610846671.9A patent/CN106305757B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1361778A (en) * | 1999-07-15 | 2002-07-31 | 拜尔公司 | Substituted thiene-3-yl-sulfonyl amino (thio) carbonyl-triazolin (thi) ones |
| CN101677529A (en) * | 2007-06-21 | 2010-03-24 | 拜尔农作物科学股份公司 | Active ingredient suspensions in glycerine |
Non-Patent Citations (1)
| Title |
|---|
| "吡啶酰胺类除草剂-吡氟酰草胺";顾群等;《现代农药》;20100210;第9卷(第1期);正文第1段好第4点应用 |
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