CN110204967A - A kind of increase roofing distributed photovoltaic power generation system photoelectric conversion efficiency nanometer absorption-type insulating moulding coating and application - Google Patents

A kind of increase roofing distributed photovoltaic power generation system photoelectric conversion efficiency nanometer absorption-type insulating moulding coating and application Download PDF

Info

Publication number
CN110204967A
CN110204967A CN201910590295.5A CN201910590295A CN110204967A CN 110204967 A CN110204967 A CN 110204967A CN 201910590295 A CN201910590295 A CN 201910590295A CN 110204967 A CN110204967 A CN 110204967A
Authority
CN
China
Prior art keywords
power generation
photovoltaic power
insulating moulding
moulding coating
absorption
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910590295.5A
Other languages
Chinese (zh)
Inventor
吴征
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Harbin Extension Bes Environmental Protection Coating Co Ltd
Original Assignee
Harbin Extension Bes Environmental Protection Coating Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Harbin Extension Bes Environmental Protection Coating Co Ltd filed Critical Harbin Extension Bes Environmental Protection Coating Co Ltd
Priority to CN201910590295.5A priority Critical patent/CN110204967A/en
Publication of CN110204967A publication Critical patent/CN110204967A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/08Copolymers of styrene
    • C09D125/14Copolymers of styrene with unsaturated esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/32Radiation-absorbing paints
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04DROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D13/00Special arrangements or devices in connection with roof coverings; Protection against birds; Roof drainage; Sky-lights
    • E04D13/16Insulating devices or arrangements in so far as the roof covering is concerned, e.g. characterised by the material or composition of the roof insulating material or its integration in the roof structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/222Magnesia, i.e. magnesium oxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02SGENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
    • H02S20/00Supporting structures for PV modules
    • H02S20/20Supporting structures directly fixed to an immovable object
    • H02S20/22Supporting structures directly fixed to an immovable object specially adapted for buildings
    • H02S20/23Supporting structures directly fixed to an immovable object specially adapted for buildings specially adapted for roof structures
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B10/00Integration of renewable energy sources in buildings
    • Y02B10/10Photovoltaic [PV]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

Abstract

A kind of increase roofing distributed photovoltaic power generation system photoelectric conversion efficiency nanometer absorption-type insulating moulding coating and application, the present invention relates to a kind of coating and applications.It solves the problem of that the low photovoltaic DC-to-AC converter service life of existing photovoltaic power generation photoelectric conversion efficiency is low and influences generated energy.Nanometer absorption-type insulating moulding coating includes lotion, solvent, nanometer absorption-type pigments and fillers, dispersing agent, defoaming agent and coalescing agent;Application of the nanometer absorption-type insulating moulding coating in the photoelectric conversion efficiency for increasing roofing distributed photovoltaic power generation system.The present invention is for increasing roofing distributed photovoltaic power generation system photoelectric conversion efficiency.

Description

A kind of increase roofing distributed photovoltaic power generation system photoelectric conversion efficiency nanometer absorption-type Insulating moulding coating and application
Technical field
The present invention relates to a kind of coating and applications.
Background technique
Photovoltaic system is most commonly that roof distributed photovoltaic power generation system, common roof in conjunction with building roof at present Type is divided to concrete and two kinds of color steel tile, also there is exposed coiled material situation.
The temperature effect and solar energy power generating core cell of solar battery are solar battery, at present the big rule of investment The mainly silicon systems solar battery of mould commercial applications: monocrystaline silicon solar cell, polysilicon solar cell and amorphous silicon Solar battery.Influence of the temperature to silicon solar cell, be mainly reflected in the open-circuit voltage of solar battery, short circuit current, The parameters such as peak power variation with temperature and change.
1, influence of the temperature to monomer solar battery: the open-circuit voltage of monomer solar battery is dropped with the raising of temperature Low, i.e., temperature rises 1 DEG C, crystal-silicon solar cell: peak power output decline 0.04%, open-circuit voltage decline 0.04% (- 2.13mv/ DEG C), short circuit current rises 0.04%.Such as: the power of the silicon solar cell under 20 DEG C of environment is than at 80 DEG C It is high by 24%.
2, temperature influences the battery component of photovoltaic power generation: monolithic solar cell module is usually by 36 monomer solar energy Battery is composed in series.According in In Hangzhou Region of Zhe Jiang Province field survey as a result, solar cell module back surface temperature can be with when summer Reach 70 DEG C, and solar cell working junction temperature at this time can achieve 90 DEG C (nominal parameter calibration is under the conditions of 25 DEG C), The open-circuit voltage of the component will reduce about 5000mv, peak power loss late about 30% compared with rated value at this time.
It can thus be seen that solar cell working is in the higher situation of temperature, open-circuit voltage is big with the raising of temperature Width decline, also results in the serious offset of charging work point, easily makes system undercharge and damage, the output work of solar battery Rate also declines to a great extent with the raising of temperature, causes solar cell module that cannot give full play to maximum performance.
Photovoltaic DC-to-AC converter is the core component in photovoltaic system, and the component in inverter has specified operating temperature. The quality of installation environment is also to have a significant impact to the service life of inverter.If inverter is mounted on direct sunlight, humidity, acid The biggish environment of basicity can make the service life of inverter reduce, and can easily cause inverter in the environment of being exposed to the sun and cross temperature drop It carries to influence generated energy.As the long-time of inverter uses, the aging of component, the increasing of loss, efficiency will be It reduces.
Summary of the invention
The invention solves existing photovoltaic power generation photoelectric conversion efficiency is low, photovoltaic DC-to-AC converter service life is low and influences power generation The problem of amount, and provide a kind of increase roofing distributed photovoltaic power generation system photoelectric conversion efficiency nanometer absorption-type insulating moulding coating and Using.
A kind of increase roofing distributed photovoltaic power generation system photoelectric conversion efficiency nanometer absorption-type insulating moulding coating include lotion, Solvent, nanometer absorption-type pigments and fillers, dispersing agent, defoaming agent and coalescing agent;
The nanometer absorption-type pigments and fillers are nano antimony tin oxide, nano-indium stannum oxide, fluorine-doped tin oxide, aluminium doping One of zinc oxide, nano-titanium dioxide, nano zine oxide, nano magnesia and nano silica or in which several mixed Close object.
Application of the nanometer absorption-type insulating moulding coating in the photoelectric conversion efficiency for increasing roofing distributed photovoltaic power generation system.
The beneficial effects of the present invention are:
Solar battery theoretical efficiency is determined by following formula:
Its value is dependent on the maximum value of open-circuit voltage Voc, short circuit current Isc and fill factor FF.The present invention can increase Photovoltaic battery panel open-circuit voltage Voc, to improve the photoelectric conversion efficiency of photovoltaic power generation.
Nanometer absorption-type coating of the present invention has excellent absorbent properties, can effectively absorb sunlight.Film is logical Infrared ray, the far infrared, ultraviolet light absorbed in sunlight is crossed, coating temperature is increased, then through convective heat transfer by heat transfer To air, therefore film can play the role of " covert reflection ", when speed air flow is bigger, cross-ventilation for infra-red radiation Rate of heat transfer is accelerated, and film will have better heat insulation, to reduce roofing temperature.
Ambient temperature increases the raising that will lead to photovoltaic battery temperature, and solar battery temperature is every to increase by 1 DEG C, short circuit Electric current Isc is influenced less by temperature change, and open-circuit voltage Voc about reduces 5mV, and photoelectric conversion efficiency value can reduce 0.4%~ 0.5%.Coating of the present invention can reduce by 5 DEG C~18 DEG C of roof surface temperature, to reduce photovoltaic power generation plate temperature, increase Roofing photoelectric conversion efficiency.
By increasing the value of open-circuit voltage Voc, therefore, when nanometer absorption-type insulating moulding coating of the present invention is coated on roofing basis When between layer and photovoltaic power generation plate, roofing distributed photovoltaic photoelectric conversion can be increased using this nanometer of absorption-type insulating moulding coating and imitated Rate, so that photovoltaic power generation quantity increases by 2.3%~3.5%.
When photovoltaic DC-to-AC converter external coating nanometer absorption-type insulating moulding coating of the present invention, antiseptic and rustproof erosion.Reduce cabinet Body surface temperature, reaching reduces in-cabinet temperature purpose, can reduce by 3 DEG C of in-cabinet temperature or more.Increase cabinet inner electronic equipment and uses the longevity Life 1 year or more, increase by 0.5%~1.5% photovoltaic power generation quantity, reduces equipment fault.It radiates without opening the door, saves maintenance maintenance Cost.
The present invention is used for a kind of heat-insulated painting of increase roofing distributed photovoltaic power generation system photoelectric conversion efficiency nanometer absorption-type Material and application.
Detailed description of the invention
Fig. 1 is that the present invention increases the painting of roofing distributed photovoltaic power generation system photoelectric conversion efficiency nanometer absorption-type insulating moulding coating The structural schematic diagram being overlying between concrete substrate or coiled material substrate roofing basal layer and photovoltaic power generation plate;
Fig. 2 is that the present invention increases the painting of roofing distributed photovoltaic power generation system photoelectric conversion efficiency nanometer absorption-type insulating moulding coating The structural schematic diagram being overlying between metal base roofing basal layer and photovoltaic power generation plate;
Fig. 3 is that the present invention increases the painting of roofing distributed photovoltaic power generation system photoelectric conversion efficiency nanometer absorption-type insulating moulding coating It is overlying on the structural schematic diagram on the inverter cabinet surface of roofing distributed photovoltaic power generation system.
Specific embodiment
Specific embodiment 1: present embodiment nanometer absorption-type insulating moulding coating includes lotion, solvent, nanometer absorption-type face Filler, dispersing agent, defoaming agent and coalescing agent;
The nanometer absorption-type pigments and fillers are nano antimony tin oxide, nano-indium stannum oxide, fluorine-doped tin oxide, aluminium doping One of zinc oxide, nano-titanium dioxide, nano zine oxide, nano magnesia and nano silica or in which several mixed Close object.
Nanometer absorption-type insulating moulding coating described in present embodiment is coated on roofing formation coating and matches with photovoltaic power generation Set can form a nanometer absorption-type thermal insulation layer, reduce roofing temperature, increase photovoltaic efficiency, extend roofing service life.
The beneficial effect of present embodiment is:
Solar battery theoretical efficiency is determined by following formula:
Its value is dependent on the maximum value of open-circuit voltage Voc, short circuit current Isc and fill factor FF.The present invention can increase Photovoltaic battery panel open-circuit voltage Voc, to improve the photoelectric conversion efficiency of photovoltaic power generation.
Nanometer absorption-type coating described in present embodiment has excellent absorbent properties, can effectively absorb the sun Light.Film increases coating temperature by infrared ray, far infrared, ultraviolet light in absorption sunlight, then will through convective heat transfer Heat transfer is to air, therefore film can play the role of " covert reflection " for infra-red radiation, when speed air flow is bigger, Cross-ventilation rate of heat transfer is accelerated, and film will have better heat insulation, to reduce roofing temperature.
Ambient temperature increases the raising that will lead to photovoltaic battery temperature, and solar battery temperature is every to increase by 1 DEG C, short circuit Electric current Isc is influenced less by temperature change, and open-circuit voltage Voc about reduces 5mV, and photoelectric conversion efficiency value can reduce 0.4%~ 0.5%.Coating of the present invention can reduce by 5 DEG C~18 DEG C of roof surface temperature, to reduce photovoltaic power generation plate temperature, increase Roofing photoelectric conversion efficiency.
By increasing the value of open-circuit voltage Voc, therefore, when present embodiment nanometer absorption-type insulating moulding coating is coated on When between roofing basal layer and photovoltaic power generation plate, roofing distributed photovoltaic photoelectricity can be increased using this nanometer of absorption-type insulating moulding coating Transfer efficiency, so that photovoltaic power generation quantity increases by 2.3%~3.5%.
The nanometer absorption-type insulating moulding coating described in the photovoltaic DC-to-AC converter external coating present embodiment, it is antiseptic and rustproof Erosion.Cabinet body surface temperature is reduced, reaching reduces in-cabinet temperature purpose, can reduce by 3 DEG C of in-cabinet temperature or more.Increase electronics in cabinet to set Standby service life 1 year or more, increase by 0.5%~1.5% photovoltaic power generation quantity, reduces equipment fault.It radiates, saves without opening the door Maintenance maintenance cost.
Specific embodiment 2: the present embodiment is different from the first embodiment in that: the nanometer absorption-type every Hot coating includes 5 parts~50 parts lotions, 5 parts~50 parts solvents, 5 parts~45 parts nanometer absorption-type pigments and fillers, 0.1 in parts by weight Part~5 parts of dispersing agents, 0.1 part~5 parts defoaming agents and 0.1 part~5 parts coalescing agents.It is other same as the specific embodiment one.
Specific embodiment 3: unlike one of present embodiment and specific embodiment one or two: the nanometer The partial size of absorption-type pigments and fillers is 1nm~2500nm.It is other the same as one or two specific embodiments.
Specific embodiment 4: unlike one of present embodiment and specific embodiment one to three: the lotion For acrylic emulsions, polyurethanes lotion or fluorine carbon lotion.It is other identical as specific embodiment one to three.
Specific embodiment 5: unlike one of present embodiment and specific embodiment one to four: the propylene Acids lotion is pure-acrylic emulsion, machine fluorine-silicon modified acrylic lotion, styrene-acrylic emulsion or acrylate and vinyl acetate emulsion;The polyurethanes lotion is Aqueous polyurethane emulsion, acroleic acid polyurethane lotion, urethane alkyd lotion or epoxy modified polyurethane lotion;Institute The fluorine carbon lotion stated is water-base fluorocarbon emulsion resin.It is other identical as specific embodiment one to four.
Specific embodiment 6: unlike one of present embodiment and specific embodiment one to five: the solvent For one of deionized water, ethyl alcohol, toluene and dimethylbenzene or in which several mixing.Other and specific embodiment one or five It is identical.
Specific embodiment 7: present embodiment nanometer absorption-type insulating moulding coating is increasing roofing distributed photovoltaic power generation system Application in the photoelectric conversion efficiency of system.
Specific embodiment 8: present embodiment is unlike specific embodiment seven: the nanometer absorption-type every Hot coating is coated between roofing basal layer and photovoltaic power generation plate.It is other identical as specific embodiment seven.
Specific embodiment 9: unlike one of present embodiment and specific embodiment seven or eight: the roofing Basal layer is concrete substrate, coiled material substrate or metal base.It is other identical as specific embodiment seven or eight.
The concrete substrate surface can primer coating layer, this prime coat be cement matrix closed reinforcement priming paint, for Concrete porous, hydrophily and alkaline material and a kind of Thief zone ability base paint special researched and developed, for reinforcing loose, powder Change, dusting, the insufficient concrete base layer of intensity.While closing base's hole, basal plane intensity is effectively improved, it is durable to extend roofing Property.
The coiled material substrate surface can primer coating layer, this prime coat be coiled material substrate be isolated priming paint, as Harbin is opened up All generations environmental protection coating material Co., Ltd production TC-R-AB, have good anti-small molecule sulfide permeability, low temperature flexibility and The features such as water resistance, is suitable for all kinds of waterproof roll roofings.Effective closed substrate, avoids surface yellowing at the infiltration of isolation small molecule Occur.
The metallic substrate surface can primer coating layer, this prime coat be metal base anti-corrosive primer, as Harbin is opened up The TC-R-MB of all generations environmental protection coating material Co., Ltd production is water-thinned antirust primer, suitable for non-corroding or slightly corrodes various Metal base effectively prevents new corrosion from being formed, and makes activity corrosion inerting, have good water resistance, anti-corrosion ability and High adhesion force.
Specific embodiment 10: unlike one of present embodiment and specific embodiment seven to nine: the nanometer Absorption-type insulating moulding coating is coated on the inverter cabinet surface of roofing distributed photovoltaic power generation system.Other and specific embodiment Seven to nine is identical.
Beneficial effects of the present invention are verified using following embodiment:
Embodiment one:
A kind of increase roofing distributed photovoltaic power generation system photoelectric conversion efficiency nanometer absorption-type insulating moulding coating is specifically to press Following steps preparation:
One, nano heat-insulating powder slurry is prepared:
Weigh 23.20g deionized water, 0.50g thickener, 0.60g antifreezing agent, 0.30g wetting agent, 0.40g dispersing agent, 0.50g defoaming agent and 31.00g nano antimony tin oxide (ATO);First by deionized water, wetting agent, antifreezing agent, dispersing agent and thickening Agent mixing, stirred 2h under revolving speed at 500r/ minutes, then adds defoaming agent stirring, merges completely to defoaming agent with deionized water Nano antimony tin oxide (ATO) is added afterwards, after the completion of addition, was dispersed under revolving speed at 800r/ minutes, nano heat-insulating powder slurry is obtained Material;
The thickener is HPK100M thickener, and producer is Shenyang scientific and technological building materials Co., Ltd with the wind;Described is antifreeze Agent is propylene glycol;The wetting agent is NX4070 wetting agent, and producer is Beijing Yi Liaotong Science and Technology Ltd.;The dispersion Agent is sodium trimetaphosphate;The defoaming agent is neopelex;Described nano antimony tin oxide (ATO) partial size is 1nm~100nm;
Two, coating is prepared:
Weigh 41.50g lotion, 0.50g emulsifier, 0.40g defoaming agent, 0.50g coalescing agent, 0.30g rheological agent and 0.30g fungicide;Lotion is added in the nano heat-insulating powder slurry that step 1 obtains, then sequentially adds emulsifier, disappears Infusion, coalescing agent, rheological agent and fungicide, all materials addition finish, and stirring obtains a nanometer absorption-type insulating moulding coating;
The lotion is styrene-acrylic emulsion;The emulsifier is 1407 emulsifiers, and producer is Shenyang scientific and technological building materials with the wind Co., Ltd;The defoaming agent is ST2410 defoaming agent, and producer is Beijing Yi Liaotong Science and Technology Ltd.;The film forming helps Agent is alcohol ester 12;The rheological agent is 2025 rheological agents, and producer is Shenyang scientific and technological building materials Co., Ltd with the wind;Described kills Microbial inoculum is 320 fungicide, and producer is Yi Tailong (Tianjin) synthetic material Co., Ltd.
It is illustrated in conjunction with Fig. 1, the present embodiment nanometer absorption-type insulating moulding coating is coated on roofing basal layer and photovoltaic power generation Between plate, increase roofing distributed photovoltaic power generation system effectiveness, method particularly includes: coating thickness is 100 on roofing basal layer 3 μm priming paint, obtain prime coat 4, coating thickness is 380 μm of nanometer absorption-type insulating moulding coating on prime coat 4, obtains nanometer suction Receipts type heat insulating coat 5, photovoltaic power generation plate 1 are set to the roofing that surface has nanometer absorption-type heat insulating coat 5 by photovoltaic bracket 2 3 upper surface of basal layer;
The photovoltaic power generation plate 1 and roofing basal layer 3 is in 38 degree of angles;
Roofing basal layer 3 is concrete substrate;
The priming paint is cement matrix closed reinforcement priming paint.
The primer coating on roofing basal layer 3 enhances the adhesive force of roofing basal layer 3 and nanometer absorption-type heat insulating coat 5, Extended service life avoids nanometer absorption-type heat insulating coat 5 and roofing basal layer 3 from removing.
The nanometer thermal insulation coating (5) can also increase the integral waterproofing of roofing other than with heat insulation and heat control effect Can, increase its service life.
This nanometer of absorption-type insulating moulding coating is applied on concrete roof distributed photovoltaic power generation, installed capacity 60kw, Average daily generation is 305kWh before construction, and construction front roof temperature is 52 DEG C, and average daily generation is 312kWh after construction, is applied Roofing temperature is 41 DEG C after work, reduces by 11 DEG C of roof surface temperature, photovoltaic power generation quantity increases by 2.3%.
Embodiment two:
A kind of increase roofing distributed photovoltaic power generation system photoelectric conversion efficiency nanometer absorption-type insulating moulding coating is specifically to press Following steps preparation:
One, nano heat-insulating powder slurry is prepared:
Weigh 15.00g deionized water, 0.10g thickener, 0.30g wetting agent, 0.40g dispersing agent, 1.00g defoaming agent, First deionized water, dispersing agent, thickener and wetting agent are added for 20.00g nano-titanium dioxide and 21.00g nano zine oxide, Low whipping speed is to stir at low speed under conditions of 450r/ minutes, adds defoaming agent stirring later, complete with deionized water to defoaming agent Nano-titanium dioxide and nano zine oxide are added after full fusion, after the completion of addition, low whipping speed is under conditions of 900r/ minutes Dispersion, obtains nano heat-insulating powder slurry;
The thickener is 150 thickeners, and the wetting agent is 1096 wetting agents, and producer is that science and technology is built with the wind in Shenyang Material Co., Ltd;The dispersing agent is 731A dispersing agent;The defoaming agent is NXZ defoaming agent;The nanometer titanium dioxide The partial size of titanium and nano zine oxide is 1nm~100nm;
Two, coating is prepared:
40.80g lotion, 0.10g defoaming agent, 0.80g coalescing agent and 0.50g fungicide are weighed, lotion is added to step In rapid one obtained nano heat-insulating powder slurry, after sequentially add defoaming agent, coalescing agent and fungicide, stir evenly to get To nanometer absorption-type insulating moulding coating;
The lotion is aqueous polyurethane emulsion;The defoaming agent is RT-10 defoaming agent, and producer is that Beijing easily expects logical Science and Technology Ltd.;The coalescing agent is alcohol ester 12;The fungicide is 623 fungicide.
It is illustrated in conjunction with Fig. 2, the present embodiment nanometer absorption-type insulating moulding coating is coated on roofing basal layer and photovoltaic power generation Between plate, increase roofing distributed photovoltaic power generation system effectiveness, method particularly includes: coating thickness is 100 on roofing basal layer 3 μm priming paint, obtain prime coat 4, coating thickness is 400 μm of nanometer absorption-type insulating moulding coating on prime coat 4, obtains nanometer suction Receipts type heat insulating coat 5, photovoltaic power generation plate 1 are set to the roofing that surface has nanometer absorption-type heat insulating coat 5 by photovoltaic bracket 2 3 upper surface of basal layer.
The photovoltaic power generation plate 1 is arranged in parallel with roofing basal layer 3;
The roofing basal layer 3 is color steel plate metal base.
The priming paint is metal base anti-corrosive primer, and producer is the TC- that all generations environmental protection coating material Co., Ltd is opened up in Harbin R-MB。
The primer coating on roofing basal layer 3 enhances the adhesive force of roofing basal layer 3 and nanometer absorption-type heat insulating coat 5, Extended service life avoids nanometer absorption-type heat insulating coat 5 and roofing basal layer 3 from removing.
The nanometer thermal insulation coating 5 can also increase the integral waterproofing of metal Roof other than with heat insulation and heat control effect Performance increases its service life, antiseptic and rustproof erosion.
This nanometer of absorption-type insulating moulding coating is applied on metal Roof distributed photovoltaic power generation, and installed capacity 53kW is applied Average daily generation is 286kWh before work, and construction front roof temperature is 57 DEG C, and daily generation is 293kWh after construction, backhouse of constructing Face temperature is 43 DEG C, and roof surface temperature reduces by 14 DEG C, and photovoltaic power generation quantity increases by 2.4%.
Embodiment three:
A kind of increase roofing distributed photovoltaic power generation system photoelectric conversion efficiency nanometer absorption-type insulating moulding coating is specifically to press Following steps preparation:
One, nano heat-insulating powder slurry is prepared:
Weigh 19.50g deionization, 0.50g thickener, 0.20g wetting agent, 0.30g dispersing agent, 0.70g defoaming agent, 34.20g nano magnesia;First deionized water, dispersing agent, thickener and wetting agent are added, low whipping speed is 420r/ minutes Under conditions of, it stirs at low speed, adds defoaming agent stirring later, be added after defoaming agent merges completely with deionized water nano oxidized Magnesium, after the completion of addition, low whipping speed is under conditions of 850r/ minutes, and high speed dispersion obtains nano heat-insulating powder slurry;
The thickener is cellulose ether;The wetting agent is ND805 wetting agent;The dispersing agent is three inclined phosphorus Sour sodium;The defoaming agent is NXZ defoaming agent;The partial size of the nano magnesia is 1nm~100nm;
Two, coating is prepared:
43.00g lotion, 0.30g pH adjusting agent, 0.70g coalescing agent, 0.30g fungicide and 0.30g defoaming agent are weighed, Lotion is added in the nano heat-insulating powder slurry that step 1 obtains, after sequentially add pH adjusting agent, defoaming agent, coalescing agent And fungicide, it stirs evenly, obtains a nanometer absorption-type insulating moulding coating;
The lotion is water-base fluorocarbon emulsion resin;The pH adjusting agent is the ammonium hydroxide that mass percent is 28%; The coalescing agent is OE300 coalescing agent;The fungicide is 320 fungicide;The defoaming agent is NXZ defoaming Agent.
It is illustrated in conjunction with Fig. 1, the present embodiment nanometer absorption-type insulating moulding coating is coated on roofing basal layer and photovoltaic power generation Between plate, increase roofing distributed photovoltaic power generation system effectiveness, method particularly includes: coating thickness is 100 on roofing basal layer 3 μm priming paint, obtain prime coat 4, coating thickness is 500 μm of nanometer absorption-type insulating moulding coating on prime coat 4, obtains nanometer suction Receipts type heat insulating coat 5, photovoltaic power generation plate 1 are set to the roofing that surface has nanometer absorption-type heat insulating coat 5 by photovoltaic bracket 2 3 upper surface of basal layer.
The photovoltaic power generation plate 1 and roofing basal layer 3 is in 42 degree of angles;
The roofing basal layer 3 is coiled material substrate;
The priming paint is that priming paint is isolated in coiled material substrate, and producer is the TC- that all generations environmental protection coating material Co., Ltd is opened up in Harbin R-AB。
The primer coating on roofing basal layer 3 enhances the adhesive force of roofing basal layer 3 and nanometer absorption-type heat insulating coat 5, Extended service life avoids nanometer absorption-type heat insulating coat 5 and roofing basal layer 3 from removing.
For the nanometer absorption-type heat insulating coat 5 other than with heat insulation and heat control effect, the entirety that can also increase roofing is anti- Aqueous energy, increases its service life.
This nanometer of absorption-type insulating moulding coating is applied on prepared roofing distributed photovoltaic power generation, and installed capacity 53kW is applied Average daily generation is 257kWh before work, and construction front roof temperature is 58 DEG C, and daily generation is 266kWh after construction, backhouse of constructing Face temperature is 43 DEG C, reduces by 15 DEG C of roof surface temperature, photovoltaic power generation quantity increases by 3.5%.
Example IV:
A kind of increase roofing distributed photovoltaic power generation system photoelectric conversion efficiency nanometer absorption-type insulating moulding coating is specifically to press Following steps preparation:
One, nano heat-insulating powder slurry is prepared:
Weigh 22.50g deionized water, 0.1g thickener, 0.20g pH adjusting agent, 0.30g wetting agent, 0.40g dispersing agent, Deionized water, dispersing agent, thickener and wetting agent are first mixed, are then existed by 0.60g defoaming agent and 30.30g nano silica Mixing speed is to stir at low speed under conditions of 440r/ minutes, then add defoaming agent stirring, is melted completely to defoaming agent with deionized water Nano silica is added after conjunction, after the completion of addition, pH adjusting agent is added, the condition that then low whipping speed is 900r/ minutes Lower high speed dispersion, obtains nano heat-insulating powder slurry;
The thickener is 250MBR thickener, Ke Naiou trade (Shanghai) Co., Ltd. Beijing Company;Described PH adjusting agent is dimethylethanolamine, and producer is Beijing Xing Meiya Chemical Co., Ltd.;The wetting agent is X405 wetting agent; The dispersing agent is 5027 dispersing agents;The defoaming agent is NXZ defoaming agent;The nano silica partial size is 1nm ~100nm;
Two, coating is prepared:
Weigh 44.20g lotion, 0.30g defoaming agent, 0.70g coalescing agent, 0.30g rheological agent and 0.10g fungicide;It will Lotion is added in the nano heat-insulating powder slurry that step 1 obtains, then sequentially add defoaming agent, coalescing agent, rheological agent and Fungicide stirs evenly to get nanometer absorption-type insulating moulding coating is arrived;
The lotion is pure-acrylic emulsion, and the defoaming agent is NXZ defoaming agent;The coalescing agent is alcohol ester ten Two;The rheological agent is 9119 rheological agents, and producer is Shenyang scientific and technological building materials Co., Ltd with the wind;The fungicide is K20 Fungicide.
It is illustrated in conjunction with Fig. 3, the present embodiment nanometer absorption-type insulating moulding coating is coated on inverter surface layer, increases roofing Distributed photovoltaic power generation system effectiveness, method particularly includes: the priming paint that coating thickness is 100 μm on a of inverter surface layer obtains on earth The nanometer absorption-type insulating moulding coating that coating thickness is 380 μm on paint layer b, prime coat b, obtains a nanometer absorption-type heat insulating coat c.
The inverter surface layer a is stainless steel material.
The priming paint is metal base anti-corrosive primer, and producer is the TC- that all generations environmental protection coating material Co., Ltd is opened up in Harbin R-MB。
The primer coating on a of inverter surface layer enhances the adhesive force of inverter surface layer a and nanometer absorption-type heat insulating coat c, Extended service life avoids nanometer absorption-type heat insulating coat c and inverter surface layer a from removing.
The nanometer absorption-type heat insulating coat c increases its service life other than with reflective insulation cooling effect, prevents Rotten anti-corrosion.
This nanometer of absorption-type insulating moulding coating is applied on inverter surface, power 72kW, inverter outer surface before constructing Temperature is 52 DEG C, and interior of equipment cabinet temperature is 53 DEG C, and average daily generation is 324kWh, and inverter hull-skin temperature is 41 after construction DEG C, interior of equipment cabinet temperature is 49 DEG C, and cabinet surface reduces by 11 DEG C, and interior of equipment cabinet temperature reduces by 4 DEG C, and average daily generation is 327kWh increases photovoltaic power generation quantity 0.9%.

Claims (10)

1. a kind of increase roofing distributed photovoltaic power generation system photoelectric conversion efficiency nanometer absorption-type insulating moulding coating, it is characterised in that Nanometer absorption-type insulating moulding coating includes lotion, solvent, nanometer absorption-type pigments and fillers, dispersing agent, defoaming agent and coalescing agent;
The nanometer absorption-type pigments and fillers are nano antimony tin oxide, nano-indium stannum oxide, fluorine-doped tin oxide, aluminium doping oxidation One of zinc, nano-titanium dioxide, nano zine oxide, nano magnesia and nano silica or in which several mixing Object.
2. a kind of increase roofing distributed photovoltaic power generation system photoelectric conversion efficiency nanometer absorption-type according to claim 1 Insulating moulding coating, it is characterised in that the nanometer absorption-type insulating moulding coating include in parts by weight 5 parts~50 parts lotions, 5 parts~ 50 parts of solvents, 5 parts~45 parts nanometer absorption-type pigments and fillers, 0.1 part~5 parts dispersing agents, 0.1 part~5 parts defoaming agents and 0.1 part~ 5 parts of coalescing agents.
3. a kind of increase roofing distributed photovoltaic power generation system photoelectric conversion efficiency nanometer absorption-type according to claim 1 Insulating moulding coating, it is characterised in that the partial size of the nanometer absorption-type pigments and fillers is 1nm~2500nm.
4. a kind of increase roofing distributed photovoltaic power generation system photoelectric conversion efficiency nanometer absorption-type according to claim 1 Insulating moulding coating, it is characterised in that the lotion is acrylic emulsions, polyurethanes lotion or fluorine carbon lotion.
5. a kind of increase roofing distributed photovoltaic power generation system photoelectric conversion efficiency nanometer absorption-type according to claim 4 Insulating moulding coating, it is characterised in that the acrylic emulsions be pure-acrylic emulsion, machine fluorine-silicon modified acrylic lotion, styrene-acrylic emulsion or Acrylate and vinyl acetate emulsion;The polyurethanes lotion is aqueous polyurethane emulsion, acroleic acid polyurethane lotion, polyurethane-modified alkyd tree Fat liquor or epoxy modified polyurethane lotion;The fluorine carbon lotion is water-base fluorocarbon emulsion resin.
6. a kind of increase roofing distributed photovoltaic power generation system photoelectric conversion efficiency nanometer absorption-type according to claim 1 Insulating moulding coating, it is characterised in that the solvent is one of deionized water, ethyl alcohol, toluene and dimethylbenzene or in which several Mixing.
7. described in claim 1 nanometer of absorption-type insulating moulding coating is in the photoelectric conversion for increasing roofing distributed photovoltaic power generation system Application in efficiency.
8. application according to claim 7, it is characterised in that the nanometer absorption-type insulating moulding coating is coated on roofing base Between plinth layer and photovoltaic power generation plate.
9. application according to claim 8, it is characterised in that the roofing basal layer is concrete substrate, coiled material substrate Or metal base.
10. application according to claim 7, it is characterised in that the nanometer absorption-type insulating moulding coating is coated on roofing point The inverter cabinet surface of cloth photovoltaic generating system.
CN201910590295.5A 2019-07-02 2019-07-02 A kind of increase roofing distributed photovoltaic power generation system photoelectric conversion efficiency nanometer absorption-type insulating moulding coating and application Pending CN110204967A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910590295.5A CN110204967A (en) 2019-07-02 2019-07-02 A kind of increase roofing distributed photovoltaic power generation system photoelectric conversion efficiency nanometer absorption-type insulating moulding coating and application

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910590295.5A CN110204967A (en) 2019-07-02 2019-07-02 A kind of increase roofing distributed photovoltaic power generation system photoelectric conversion efficiency nanometer absorption-type insulating moulding coating and application

Publications (1)

Publication Number Publication Date
CN110204967A true CN110204967A (en) 2019-09-06

Family

ID=67795817

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910590295.5A Pending CN110204967A (en) 2019-07-02 2019-07-02 A kind of increase roofing distributed photovoltaic power generation system photoelectric conversion efficiency nanometer absorption-type insulating moulding coating and application

Country Status (1)

Country Link
CN (1) CN110204967A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113150637A (en) * 2021-04-26 2021-07-23 上海裕生智能节能设备有限公司 Water-based heat-insulating transparent coating for building glass curtain wall and preparation method thereof
CN115000186A (en) * 2022-05-23 2022-09-02 广州大学 Crystalline silicon solar cell substrate and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101870842A (en) * 2010-03-02 2010-10-27 刘立新 Aqueous cold pigment double-coat multifunctional thermal-insulation external wall paint and preparation method thereof
CN102241938A (en) * 2011-06-13 2011-11-16 华南理工大学 High-performance heat-insulation coating and preparation method thereof
CN105482590A (en) * 2016-01-27 2016-04-13 吴征 Seal primer special for heat-insulating waterproof paint and preparation method of seal primer

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101870842A (en) * 2010-03-02 2010-10-27 刘立新 Aqueous cold pigment double-coat multifunctional thermal-insulation external wall paint and preparation method thereof
CN102241938A (en) * 2011-06-13 2011-11-16 华南理工大学 High-performance heat-insulation coating and preparation method thereof
CN105482590A (en) * 2016-01-27 2016-04-13 吴征 Seal primer special for heat-insulating waterproof paint and preparation method of seal primer

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113150637A (en) * 2021-04-26 2021-07-23 上海裕生智能节能设备有限公司 Water-based heat-insulating transparent coating for building glass curtain wall and preparation method thereof
CN115000186A (en) * 2022-05-23 2022-09-02 广州大学 Crystalline silicon solar cell substrate and preparation method thereof

Similar Documents

Publication Publication Date Title
CN102286243B (en) Method for preparing solar selective heat absorbing paint by using spinel type pigment as light absorbent
CN103740204B (en) A kind of intelligence temperature-adjusting type heat-reflecting insulating coating and preparation method thereof
CN104250498A (en) Water-based weather-proof stain-proof thermal reflective insulation coating and preparation method thereof
CN102496642B (en) Back sheet of solar cell and preparation method for back sheet
CN105906832A (en) Preparation method of graphene-containing water-based electrothermal film
CN101210128A (en) Thin type reflective insulation exterior wall paint
CN105331220A (en) Compound-type metal roof thermal-insulation waterproof coating and preparing method thereof
CN102311690A (en) Waterborne exterior elastic reflective heat insulation coating and production method thereof
CN110204967A (en) A kind of increase roofing distributed photovoltaic power generation system photoelectric conversion efficiency nanometer absorption-type insulating moulding coating and application
CN104231701A (en) Infrared radiating coating for photovoltaic module backing plate and preparation method of radiating photovoltaic module backing plate
CN114539861B (en) Water-based radiation refrigeration coating and preparation method thereof
CN101824258A (en) Waterborne reflective heat-insulating building coating
CN107298886A (en) Reflective heat-insulation paint and preparation method thereof
CN105860815A (en) Waterborne anti-static anti-corrosive thermal insulation coating and preparation method
CN106242312A (en) The preparation of a kind of photovoltaic glass coating liquid and application
CN101818013A (en) Reflecting thermal insulating paint
CN110183922A (en) A kind of increase roofing distributed photovoltaic power generation system photoelectric conversion efficiency reflection-type coating and application
CN107216762A (en) A kind of Metal roof heat-insulation waterproof paint and preparation method thereof
CN103289492A (en) A zinc oxide-containing, heat-insulating and cooling waterproof coating for metal roofs and a manufacturing method therefor
CN108659657A (en) A kind of building external paint and its application
CN105419531A (en) Preparing method of superhigh-sunshine reflectance ratio coating
CN103929120B (en) A kind of external wall photovoltaic generating system and preparation method thereof
CN105733384A (en) Preparation method of cool and sunlight-reflective waterproof coating for roof and outer wall
CN112391089A (en) Thermal super-structured micro-nano energy-saving heat-insulating coating and preparation method thereof
CN105949949B (en) Wear-resistant epoxy coating that a kind of blade of wind-driven generator uses and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20190906

WD01 Invention patent application deemed withdrawn after publication