CN110204951A - A kind of aqueous UV ink and preparation method thereof - Google Patents
A kind of aqueous UV ink and preparation method thereof Download PDFInfo
- Publication number
- CN110204951A CN110204951A CN201910479539.2A CN201910479539A CN110204951A CN 110204951 A CN110204951 A CN 110204951A CN 201910479539 A CN201910479539 A CN 201910479539A CN 110204951 A CN110204951 A CN 110204951A
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- parts
- aqueous
- ink
- filler material
- expanded perlite
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
Abstract
The invention discloses a kind of aqueous UV ink, raw material comprising following parts by weight of component: water base light-cured resin 30-40 parts, 10-15 parts of pigment, 4-8 parts of filler material, 5-15 parts of nanometer anion powder, 2-6 parts of trimethylolpropane, 15-20 parts of vermiculite power, 10-15 parts of expanded perlite, 10-20 parts of nano zine oxide, 5-10 parts of modified nano-titanium dioxide, it further include a kind of preparation method of aqueous UV ink, vermiculite power and expanded perlite cooperate, with stronger toughness and resistance to mechanical frictional behaviour, it can be used to solve the problems, such as common water borne UV ink because of loss of gloss caused by poor toughness or fall off, further thorough protection and good decorative effect are provided for aqueous UV ink product.By using nano zine oxide, the roughness of aqueous UV ink is improved, so as to improve the waterproof performance of its coating, improves the durability of aqueous UV ink.
Description
Technical field
The present invention relates to aqueous UV technical field of ink, specifically a kind of aqueous UV ink and preparation method thereof.
Background technique
Ink is by chromoplast (such as pigment, dyestuff), link stuff, fills out and (fill) the uniform of the material compositions such as material, additional material
Mixture；It can be carried out printing, and dry in printed body；It is to have color, the pulpous state adherent with certain fluidity.Cause
This, color (form and aspect), body bone (rheological properties such as dilute thick, fluidity) and drying property are three most important performances of ink.
There are many their type, and physical property is also different, and some is very thick, very viscous；And some is quite dilute.Some is connected with vegetable oil work
Ramming material；Some resins and solvent or water etc. make link stuff.These be all according to the object i.e. stock of printing, printing process,
The type of printing plate and drying means etc. determine.
The maximum difference of aqueous UV ink and common UV ink is with water as solvent, without the use of monomer diluent, this
It fundamentally solves monomer diluent and contacts the stimulation generated with people, cause skin allergy etc. one caused by human body
Fixed injury, there is greater advantages in environmental protection.Aqueous UV ink used at present has following technical problem: (1) anti-microbial property is poor, with
After human contact, various diseases can be infected, threaten human health.(2) poor toughness, washability, does not occur obscission easily.
Summary of the invention
The purpose of the present invention is to provide a kind of aqueous UV ink and preparation method thereof, to solve to mention in above-mentioned background technique
Out the problem of.
To achieve the above object, the invention provides the following technical scheme:
A kind of aqueous UV ink, the raw material comprising following parts by weight of component: water base light-cured resin 30-40 parts, pigment 10-
15 parts, 4-8 parts of filler material, 5-15 parts of nanometer anion powder, 2-6 parts of trimethylolpropane, 15-20 parts of vermiculite power, expanded pearlite
10-15 parts of rock, 10-20 parts of nano zine oxide, 5-10 parts of modified nano-titanium dioxide.
As a further solution of the present invention: the raw material comprising following parts by weight of component: water base light-cured resin 32-38
Part, 11-13 parts of pigment, 5-7 parts of filler material, 8-12 parts of nanometer anion powder, 3-5 parts of trimethylolpropane, vermiculite power 16-18
Part, 12-14 parts of expanded perlite, 13-17 parts of nano zine oxide, 7-9 parts of modified nano-titanium dioxide.
As a further solution of the present invention: the raw material comprising following parts by weight of component: 35 parts of water base light-cured resin, face
Material 12 parts, 6 parts of filler material, 10 parts of nanometer anion powder, 4 parts of trimethylolpropane, 17 parts of vermiculite power, 13 parts of expanded perlite,
15 parts of nano zine oxide, 8 parts of modified nano-titanium dioxide.
As a further solution of the present invention: the filler material is to add beneficial powder.
A kind of preparation method of aqueous UV ink, steps are as follows:
(1) water base light-cured resin, filler material are successively weighed into addition solvent by the formula and is mixed to get water-base resin
Lotion；
(2) it is formulated by described by pigment, nanometer anion powder, trimethylolpropane, vermiculite power, expanded perlite, nanometer
It is uniform that zinc oxide, modified nano-titanium dioxide successively weigh ultrasonic disperse, obtains mixture；
(3) after mixing evenly by step (1) obtains resin aqueous emulsion and step (2) obtains mixture dispersion, it above grinds
Grinding machine grinding when fineness reaches 7-15 μm after testing, stops grinding, obtains aqueous UV ink；
(4)) form and aspect are examined, are contained admittedly, fineness, viscosity, filters, is packed to get finished product after qualified.
As a further solution of the present invention: ultrasonic disperse disperses 1-2h under the conditions of 15-25 DEG C in the step (2).
Compared with prior art, the beneficial effects of the present invention are: vermiculite power and expanded perlite cooperate, have stronger tough
Property with resistance to mechanical frictional behaviour, can be used to solve common water borne UV ink because of loss of gloss caused by poor toughness or what is fallen off ask
Topic, further provides thorough protection and good decorative effect for aqueous UV ink product.By using nano zine oxide, mention
The high roughness of aqueous UV ink improves the durability of aqueous UV ink, by changing so as to improve the waterproof performance of its coating
The use of property nano-titanium dioxide, improves the compatibility of nano inorganic antimicrobial agent and paint matrix, and nano inorganic antimicrobial agent
It is remarkably improved the antibacterial and bactericidal property of aqueous UV ink, resultant effect is excellent.Base of the present invention in reasonable formula design
On plinth, aqueous UV ink product is made by simple preparation method, not only aqueous UV ink product is low in cost, anti-corrosive antibacterial
Effect is good, and preparation process is simple, is easy to industrialization, and have splendid high rigidity, waterproof performance good, not easily to fall off,
Effectively reduce environmental pollution, long service life.
Specific embodiment
It should be noted that in the absence of conflict, the feature in embodiment and embodiment in the present invention can phase
Mutually combination.
Below in conjunction with embodiment, the present invention will be described in detail.
Embodiment one
A kind of aqueous UV ink, the raw material comprising following parts by weight of component: 40 parts of water base light-cured resin, 15 parts of pigment,
It is 8 parts of filler material, 15 parts of nanometer anion powder, 6 parts of trimethylolpropane, 20 parts of vermiculite power, 15 parts of expanded perlite, nano oxidized
20 parts of zinc, 10 parts of modified nano-titanium dioxide.
The filler material is to add beneficial powder.
A kind of preparation method of aqueous UV ink, steps are as follows:
(1) water base light-cured resin, filler material are successively weighed into addition solvent by the formula and is mixed to get water-base resin
Lotion；
(2) it is formulated by described by pigment, nanometer anion powder, trimethylolpropane, vermiculite power, expanded perlite, nanometer
It is uniform that zinc oxide, modified nano-titanium dioxide successively weigh ultrasonic disperse, obtains mixture；
(3) after mixing evenly by step (1) obtains resin aqueous emulsion and step (2) obtains mixture dispersion, it above grinds
Grinding machine grinding when fineness reaches 15 μm after testing, stops grinding, obtains aqueous UV ink；
(4)) form and aspect are examined, are contained admittedly, fineness, viscosity, filters, is packed to get finished product after qualified.
Ultrasonic disperse disperses 2h under the conditions of 25 DEG C in the step (2).
Embodiment two
A kind of aqueous UV ink, the raw material comprising following parts by weight of component: 30 parts of water base light-cured resin, 10 parts of pigment,
It is 4 parts of filler material, 5 parts of nanometer anion powder, 2 parts of trimethylolpropane, 15 parts of vermiculite power, 10 parts of expanded perlite, nano oxidized
10 parts of zinc, 5 parts of modified nano-titanium dioxide.
The filler material is to add beneficial powder.
A kind of preparation method of aqueous UV ink, steps are as follows:
(1) water base light-cured resin, filler material are successively weighed into addition solvent by the formula and is mixed to get water-base resin
Lotion；
(2) it is formulated by described by pigment, nanometer anion powder, trimethylolpropane, vermiculite power, expanded perlite, nanometer
It is uniform that zinc oxide, modified nano-titanium dioxide successively weigh ultrasonic disperse, obtains mixture；
(3) after mixing evenly by step (1) obtains resin aqueous emulsion and step (2) obtains mixture dispersion, it above grinds
Grinding machine grinding when fineness reaches 7 μm after testing, stops grinding, obtains aqueous UV ink；
(4)) form and aspect are examined, are contained admittedly, fineness, viscosity, filters, is packed to get finished product after qualified.
Ultrasonic disperse disperses 1h under the conditions of 15 DEG C in the step (2).
Embodiment three
A kind of aqueous UV ink, the raw material comprising following parts by weight of component: 35 parts of water base light-cured resin, 12 parts of pigment,
It is 6 parts of filler material, 10 parts of nanometer anion powder, 4 parts of trimethylolpropane, 17 parts of vermiculite power, 13 parts of expanded perlite, nano oxidized
15 parts of zinc, 8 parts of modified nano-titanium dioxide.
The filler material is to add beneficial powder.
A kind of preparation method of aqueous UV ink, steps are as follows:
(1) water base light-cured resin, filler material are successively weighed into addition solvent by the formula and is mixed to get water-base resin
Lotion；
(2) it is formulated by described by pigment, nanometer anion powder, trimethylolpropane, vermiculite power, expanded perlite, nanometer
It is uniform that zinc oxide, modified nano-titanium dioxide successively weigh ultrasonic disperse, obtains mixture；
(3) after mixing evenly by step (1) obtains resin aqueous emulsion and step (2) obtains mixture dispersion, it above grinds
Grinding machine grinding when fineness reaches 11 μm after testing, stops grinding, obtains aqueous UV ink；
(4)) form and aspect are examined, are contained admittedly, fineness, viscosity, filters, is packed to get finished product after qualified.
Ultrasonic disperse disperses 1.5h at 20 °C in the step (2).
Comparative example one
Common aqueous UV ink in the market.
Experimental example
Under equal conditions, embodiment 1-3 and the aqueous UV ink of comparative example 1 are formed a film after the solidification of PE frosting
Afterwards, it is detected according to standard, it is as shown in the table for performance:
| Water resistance | Wearability (750g, 500r) | Glossiness/degree | |
| Embodiment one | It is excellent | 0.04 | 106 |
| Embodiment two | It is excellent | 0.02 | 101 |
| Embodiment three | It is excellent | 0.04 | 103 |
| Comparative example one | It is good | 0.06 | 68 |
Vermiculite power and expanded perlite cooperate, and have stronger toughness and resistance to mechanical frictional behaviour, can be used to solve common
For aqueous UV ink because of loss of gloss or the problem of fall off caused by poor toughness, it is thorough further to provide for aqueous UV ink product
Protection and good decorative effect.By using nano zine oxide, the roughness of aqueous UV ink is improved, so as to improve its painting
The waterproof performance of layer, the durability for improving aqueous UV ink improve nano inorganic by the use of modified nano-titanium dioxide
The compatibility of antibacterial agent and paint matrix, and nano inorganic antimicrobial agent is remarkably improved the antibacterial and bactericidal properties of aqueous UV ink
Can, resultant effect is excellent.Aqueous UV oil is made on the basis of reasonable formula design, through simple preparation method in the present invention
Graphite product, not only aqueous UV ink product is low in cost, and anti-corrosive antibacterial effect is good, and preparation process is simple, is easy to industrialization,
And have splendid high rigidity, waterproof performance good, and it is not easily to fall off, effectively reduce environmental pollution, long service life.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (7)
1. a kind of aqueous UV ink, which is characterized in that the raw material comprising following parts by weight of component: water base light-cured resin 30-40
Part, 10-15 parts of pigment, 4-8 parts of filler material, 5-15 parts of nanometer anion powder, 2-6 parts of trimethylolpropane, vermiculite power 15-20
Part, 10-15 parts of expanded perlite, 10-20 parts of nano zine oxide, 5-10 parts of modified nano-titanium dioxide.
2. a kind of aqueous UV ink according to claim 1, which is characterized in that the raw material comprising following parts by weight of component:
Water base light-cured resin 32-38 parts, 11-13 parts of pigment, 5-7 parts of filler material, 8-12 parts of nanometer anion powder, trimethylolpropane
3-5 parts, 16-18 parts of vermiculite power, 12-14 parts of expanded perlite, 13-17 parts of nano zine oxide, modified nano-titanium dioxide 7-9
Part.
3. a kind of aqueous UV ink according to claim 1, which is characterized in that the raw material comprising following parts by weight of component:
35 parts of water base light-cured resin, 12 parts of pigment, 6 parts of filler material, 10 parts of nanometer anion powder, 4 parts of trimethylolpropane, vermiculite power
17 parts, 13 parts of expanded perlite, 15 parts of nano zine oxide, 8 parts of modified nano-titanium dioxide.
4. a kind of aqueous UV ink according to claim 1, which is characterized in that the filler material is to add beneficial powder.
5. a kind of preparation method of aqueous UV ink as described in claim 1, which is characterized in that steps are as follows: (1) by described
Water base light-cured resin, filler material are successively weighed addition solvent and are mixed to get resin aqueous emulsion by formula；(2) formula is pressed
By pigment, nanometer anion powder, trimethylolpropane, vermiculite power, expanded perlite, nano zine oxide, modified nano-silica
It is uniform that titanium successively weighs ultrasonic disperse, obtains mixture；(3) step (1) is obtained into resin aqueous emulsion and that step (2) obtains is mixed
Close material dispersion after mixing evenly, upper grinder grinding obtains aqueous UV ink；(4)) form and aspect are examined, are contained admittedly, fineness, viscosity, are closed
It filters, is packed to get finished product after lattice.
6. a kind of preparation method of aqueous UV ink as claimed in claim 5, which is characterized in that ultrasonic in the step (2)
Disperse 1-2h under the conditions of being dispersed in 15-25 DEG C.
7. such as a kind of preparation method of aqueous UV ink described in claim 5 or 6, which is characterized in that ground in the step (3)
When mill, when fineness reaches 7-15 μm after testing, stop grinding.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201910479539.2A CN110204951A (en) | 2019-06-04 | 2019-06-04 | A kind of aqueous UV ink and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910479539.2A CN110204951A (en) | 2019-06-04 | 2019-06-04 | A kind of aqueous UV ink and preparation method thereof |
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| CN110204951A true CN110204951A (en) | 2019-09-06 |
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| CN201910479539.2A Pending CN110204951A (en) | 2019-06-04 | 2019-06-04 | A kind of aqueous UV ink and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112321165A (en) * | 2020-11-23 | 2021-02-05 | 湖南衡义材料科技有限公司 | Low-melting-point glass powder and preparation method thereof |
| CN112408798A (en) * | 2020-11-23 | 2021-02-26 | 湖南衡义材料科技有限公司 | High-temperature inorganic ink based on low-melting-point glass powder and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105482677A (en) * | 2015-12-29 | 2016-04-13 | 安徽安大华泰新材料有限公司 | Antifouling polyurethane coating |
| CN108017950A (en) * | 2017-12-15 | 2018-05-11 | 成都海瑞斯特新材料有限公司 | Water-based UV ink and preparation method thereof |
| CN109791373A (en) * | 2016-07-27 | 2019-05-21 | 英默里斯筛选矿物公司 | The additive of index matching for Photocurable composition |
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2019
- 2019-06-04 CN CN201910479539.2A patent/CN110204951A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105482677A (en) * | 2015-12-29 | 2016-04-13 | 安徽安大华泰新材料有限公司 | Antifouling polyurethane coating |
| CN109791373A (en) * | 2016-07-27 | 2019-05-21 | 英默里斯筛选矿物公司 | The additive of index matching for Photocurable composition |
| CN108017950A (en) * | 2017-12-15 | 2018-05-11 | 成都海瑞斯特新材料有限公司 | Water-based UV ink and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112321165A (en) * | 2020-11-23 | 2021-02-05 | 湖南衡义材料科技有限公司 | Low-melting-point glass powder and preparation method thereof |
| CN112408798A (en) * | 2020-11-23 | 2021-02-26 | 湖南衡义材料科技有限公司 | High-temperature inorganic ink based on low-melting-point glass powder and preparation method thereof |
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Application publication date: 20190906 |