CN110204250B - Polymer pavement brick - Google Patents

Polymer pavement brick Download PDF

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CN110204250B
CN110204250B CN201910414465.4A CN201910414465A CN110204250B CN 110204250 B CN110204250 B CN 110204250B CN 201910414465 A CN201910414465 A CN 201910414465A CN 110204250 B CN110204250 B CN 110204250B
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parts
mesh
resistant layer
wear
unsaturated resin
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CN110204250A (en
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聂长海
张萍
乔海明
赵瑞广
蔡亦文
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Outmet Transportation Technology Co Ltd
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Outmet Transportation Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/04Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/06Unsaturated polyesters
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C15/00Pavings specially adapted for footpaths, sidewalks or cycle tracks
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C5/00Pavings made of prefabricated single units
    • E01C5/04Pavings made of prefabricated single units made of bricks
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00612Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/2038Resistance against physical degradation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Architecture (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Road Paving Structures (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention belongs to the technical field of pavement bricks, and particularly relates to a novel polymer pavement brick, which comprises a main body structure, a wear-resistant layer and a reinforcing layer, wherein the wear-resistant layer comprises unsaturated resin, 50-60-mesh glass flakes and 50-100-mesh anti-slip rubber particles, the wear-resistant layer comprises unsaturated resin, 350-plus-450-mesh glass fiber reinforced plastic particles, 300-plus-450-mesh toothpaste-grade aluminum hydroxide, 350-plus-400-mesh ceramic microspheres, color paste and a defoaming agent, and the reinforcing layer comprises unsaturated resin, sand, 80-100-mesh stone powder, 80-100-mesh floating beads, 350-plus-400-mesh light calcium carbonate, 350-plus-400-mesh glass microspheres and color paste; it is resistant dirty nature strong, and outward appearance colour is bright-colored, and the antiskid rubber granule of adding makes the pavement brick meet water more antiskid, protects ecological environment's safety when waste recycling.

Description

Polymer pavement brick
The technical field is as follows:
the invention belongs to the technical field of pavement bricks, and particularly relates to a polymer pavement brick which is a composite material prepared by blending unsaturated resin and crushed scrap glass reinforced plastic particles serving as main raw materials and wear-resistant powder, reinforcing aggregate and pigment serving as auxiliary materials.
Background art:
the pavement bricks or the pavement bricks are artificial blocks made of industrial wastes or local materials such as concrete, slag, fly ash and the like, the pavement bricks are divided into small bricks, medium bricks and large bricks according to the size and the mass, the bricks with the height of 115-380mm are called small bricks, the bricks with the height of 380-980mm are called medium bricks, and the bricks with the height of 980mm are called large bricks, when in use, the medium-small bricks are used for a plurality of times, the pavement bricks have the advantages of simple structure and high building speed, meet the requirement of wall reform in the industrial development of buildings, and are used for covering sidewalks or squares of public transportation; chinese patent 201611021499.X discloses a composite material for a pavement brick, which comprises the following components in parts by weight: 60-85 parts of polyolefin, 10-35 parts of talcum powder and 0.1-10 parts of auxiliary agent, wherein the polyolefin comprises one or a mixture of more of polypropylene, polyethylene, polybutylene, polypentene, polyhexene, polyoctene or cycloolefine: the auxiliary agent comprises a stabilizer, an ultraviolet protective agent and an antistatic agent, and the auxiliary agent also comprises potassium carbonate and sodium hydroxide; the formula ratio (calculated by weight percent) of the color pavement brick disclosed in the Chinese patent 99112873.7 is 23-30% of high-alumina cement 625#, 30-40% of broken stone or pebble, 30-40% of river sand, 0.1-0.2% of reinforcing agent, 0.5-0.7% of inorganic mineral pigment and 4.5-5.5% of water; b) the mold release agent consists of a reinforcing agent and soapy water, and the formula of the mold release agent is as follows: QP-10 reinforcing agent, namely (1-2) soapy water and (5-6); the main raw materials of the fly ash colored sidewalk brick disclosed in the Chinese patent 03157533.1 comprise 65-76%, 4-10% and 20-25% by weight of fly ash, a curing agent and cement; the precoat of the quartz sand color pavement brick disclosed in the Chinese patent 01106282.7 comprises the following components in percentage by weight: 15-35 parts of color cement, 20-50 parts of quartz sand and 25-50 parts of refined quartz sand; the carbide slag concrete pavement brick disclosed in the Chinese patent 200510010600.7 comprises a base material lower layer and a fabric upper layer, wherein the base material lower layer and the fabric upper layer are firmly combined into a whole, the fabric upper layer consists of 35-45 parts by weight of color cement and 55-65 parts by weight of medium sand, and the base material lower layer consists of 5-15 parts by weight of carbide slag, 15-25 parts by weight of cement, 15-20 parts by weight of medium sand, 30-40 parts by weight of broken stone and 15-20 parts by weight of mineral powder; the Chinese patent 200610147843.X discloses an environment-friendly rubber pavement brick which is composed of rubber powder with a certain amount and size, a certain amount of moisture-curing polyurethane adhesive with 100 percent of solid content, and a certain amount of water according to the proportion of 100: 5-20: 5-10; the light water-permeable concrete pavement brick disclosed in the Chinese patent 200610155831.1 is a finished product formed by uniformly mixing a cullet raw material, cement and fly ash according to the mass ratio of 2: 1-5, mixing the obtained mixture 1 with hydrogen peroxide and water according to the mass ratio of 7: 1, and mixing the obtained mixture 2 according to the mass ratio of 1: 0.2-1; the materials adopted by the ecological environment-friendly type pavement brick disclosed in the Chinese patent 200710157475.1 comprise a gelled material, aggregate and an activating agent; the cementing material contains slag micropowder, red mud, C-class fly ash and diatomite: the aggregate is waste residue particles; the activating agent contains a polycarboxylic acid water reducing agent, power plant desulfurized gypsum, aluminum sulfate slag and fly ash; the pavement bricks in the patent products and the prior art mostly use inorganic substances such as cement sand and the like as main materials, the cement bricks use fly ash, coal cinder, tailing slag, chemical industry slag or natural sand, tidal marsh mud and the like (one or more of the above raw materials) as main raw materials, cement is used as a coagulant, and the pavement bricks are prepared without high-temperature calcination. The traditional method for treating the waste glass fiber reinforced plastics is burying and burning. Burying has the defects of occupying a large amount of land, polluting underground water and the like, and burning has the defect of generating harmful gases to pollute the environment. In recent years, researches have proved that styrene which is the main raw material of unsaturated polyester is environmental hormone, has stable chemical structure, can not be biodegraded, has high environmental retention, can form persistent organic pollutants, can be strongly adsorbed on particles in air, water and soil, causes serious harm to the ecological environment by means of continuous enrichment of aquatic and terrestrial food chains, and can reduce the discharge amount of glass fiber reinforced plastic wastes in society by reasonably recycling the waste glass fiber reinforced plastics. Therefore, the polymer pavement brick taking the waste glass fiber reinforced plastics as the raw material is researched and designed to replace the pavement brick in the prior art, so that the labor intensity is reduced, the wear resistance and the weather resistance are improved, and the application prospect is good.
The invention content is as follows:
the invention aims to overcome the defects in the prior art, and designs the polymer pavement brick with satisfactory mechanical properties, which has good skid resistance, wear resistance and weather resistance, bright appearance color, environmental protection and energy conservation.
In order to achieve the purpose, the main body structure of the polymer pavement brick comprises a surface wear-resistant layer, a wear-resistant layer and a reinforcing layer; the surface wear-resistant layer, the wear-resistant layer and the reinforcing layer are firmly combined into a whole, and the thickness ratio of the surface wear-resistant layer to the reinforcing layer is 1:4-6: 5-7; the surface wear-resistant layer consists of 48 to 74 portions of unsaturated resin, 10 to 26 portions of 50 to 60-mesh glass flakes and 15 to 30 portions of 50 to 100-mesh antiskid rubber particles according to the weight portion, the wear-resistant layer consists of 40 to 60 weight parts of unsaturated resin, 25 to 35 weight parts of glass fiber reinforced plastic particles with 350-450 meshes, 5 to 10 weight parts of toothpaste grade aluminum hydroxide with 300-450 meshes, 5 to 10 weight parts of ceramic micro-beads with 400 meshes and 350-350 meshes, 1.5 to 3 weight parts of color paste and 0.2 to 0.8 weight part of defoaming agent, the reinforcing layer consists of 15 to 25 weight portions of unsaturated resin, 40 to 60 weight portions of ceramic sand, 10 to 15 weight portions of 80 to 100 mesh stone powder, 2.5 to 4.5 weight portions of 80 to 100 mesh floating beads, 2.5 to 4.5 weight portions of 350-mesh light calcium carbonate, 5 to 8 weight portions of 350-mesh 400-mesh glass beads and 0.75 to 1 weight portion of color paste.
The unsaturated resin comprises p-benzene unsaturated resin, m-benzene unsaturated resin, o-benzene unsaturated resin and vinyl ester unsaturated resin.
The size of the polymer pavement brick related to the embodiment is selected according to the use requirement, the preferable size is 600mm multiplied by 20mm, the compressive strength is more than or equal to 20MPa, the bending strength is more than or equal to 3MPa, the length of a grinding pit is less than or equal to 37mm, the Babbitt hardness is more than or equal to 35, the water absorption rate is less than or equal to 1%, and meanwhile, the polymer pavement brick has the anti-skid.
Compared with the prior art, the main structure comprises a surface wear-resistant layer, a wear-resistant layer and a reinforcing layer, wherein the surface wear-resistant layer consists of unsaturated resin, 50-60-mesh glass flakes and 50-100-mesh anti-skid rubber particles, the wear-resistant layer consists of unsaturated resin, 350-plus-450-mesh glass reinforced plastic particles, 300-plus-450-mesh toothpaste-grade aluminum hydroxide, 350-plus-400-mesh ceramic microspheres, color paste and a defoaming agent, and the reinforcing layer consists of unsaturated resin, ceramic sand, 80-100-mesh stone powder, 80-100-mesh floating beads, 350-plus-400-mesh light calcium carbonate, 350-plus-400-mesh glass microspheres and color paste; it is resistant dirty strong, and appearance color is bright-colored, can cooperate all ring edge borders and molding needs, makes into the arch or other patterns of similar sidewalk brick, and the antiskid rubber granule of interpolation makes the pavement brick meet water more antiskid, protects ecological environment's safety when waste recycling.
Description of the drawings:
fig. 1 is a schematic diagram of the principle of the main structure of the present invention.
The specific implementation mode is as follows:
the following is a further description by way of example and with reference to the accompanying drawings.
Example 1:
the main structure of the polymer pavement brick related to the embodiment comprises a surface wear-resistant layer 1, a wear-resistant layer 2 and a reinforcing layer 3; the surface wear-resistant layer 1, the wear-resistant layer 2 and the reinforcing layer 3 are firmly combined into a whole; the surface wear-resistant layer 1 comprises 60 parts by weight of benzol unsaturated resin containing an accelerant and a curing agent, 15 parts of 50-60-mesh glass flakes and 25 parts of 50-100-mesh anti-slip rubber particles, the wear-resistant layer 2 comprises 50 parts by weight of benzol unsaturated resin containing the accelerant and the curing agent, 30 parts of 350-plus-450-mesh glass fiber reinforced plastic particles, 8.3 parts of 300-plus-450-mesh toothpaste-grade aluminum hydroxide, 10 parts of 350-plus-400-mesh ceramic microspheres, 1.5 parts of color paste and 0.2 part of a defoaming agent, and the reinforcing layer 3 comprises 20 parts by weight of benzol unsaturated resin containing the accelerant and the curing agent, 50 parts of ceramic sand, 15 parts of 80-100-mesh stone powder, 3.5 parts of 80-100-mesh floating beads, 3.5 parts of 350-plus-400-mesh light calcium carbonate, 7 parts of 350-plus-mesh glass microspheres and 1 part of color paste.
Example 2:
the main structure of the polymer pavement brick related to the embodiment comprises a surface wear-resistant layer 1, a wear-resistant layer 2 and a reinforcing layer 3; the surface wear-resistant layer 1, the wear-resistant layer 2 and the reinforcing layer 3 are firmly combined into a whole; the surface wear-resistant layer 1 comprises 70 parts by weight of benzol-containing unsaturated resin containing an accelerant and a curing agent, 15 parts of 50-60-mesh glass flakes and 15 parts of 50-100-mesh anti-slip rubber particles, the wear-resistant layer 2 comprises 50 parts by weight of benzol-containing unsaturated resin containing the accelerant and the curing agent, 30 parts of 350-plus-450-mesh glass fiber reinforced plastic particles, 8.3 parts of 300-plus-450-mesh toothpaste-grade aluminum hydroxide, 10 parts of 350-plus-400-mesh ceramic microspheres, 1.5 parts of color paste and 0.2 part of a defoaming agent, and the reinforcing layer 3 comprises 20 parts by weight of benzol-containing unsaturated resin containing the accelerant and the curing agent, 50 parts of ceramic sand, 15 parts of 80-100-mesh stone powder, 3.5 parts of 80-100-mesh floating beads, 3.5 parts of 350-plus-mesh light calcium carbonate, 7 parts of 350-plus-mesh glass microspheres and 1 part of color paste.
Example 3:
the main structure of the polymer pavement brick related to the embodiment comprises a surface wear-resistant layer 1, a wear-resistant layer 2 and a reinforcing layer 3; the surface wear-resistant layer 1, the wear-resistant layer 2 and the reinforcing layer 3 are firmly combined into a whole; the surface wear-resistant layer 1 comprises 60 parts by weight of benzol unsaturated resin containing an accelerant and a curing agent, 15 parts of 50-60-mesh glass flakes and 25 parts of 50-100-mesh anti-slip rubber particles, the wear-resistant layer 2 comprises 45 parts by weight of benzol unsaturated resin containing the accelerant and the curing agent, 35 parts of 350-plus-450-mesh glass fiber reinforced plastic particles, 8.3 parts of 300-plus-450-mesh toothpaste-grade aluminum hydroxide, 10 parts of 350-plus-400-mesh ceramic microspheres, 1.5 parts of color paste and 0.2 part of a defoaming agent, and the reinforcing layer 3 comprises 20 parts by weight of benzol unsaturated resin containing the accelerant and the curing agent, 55 parts of ceramic sand, 12 parts of 80-100-mesh stone powder, 2.5 parts of 80-100-mesh floating beads, 2.5 parts of 350-plus-400-mesh light calcium carbonate, 7 parts of 350-plus-mesh glass microspheres and 1 part of color paste.
Example 4:
the main structure of the polymer pavement brick related to the embodiment comprises a surface wear-resistant layer 1, a wear-resistant layer 2 and a reinforcing layer 3; the surface wear-resistant layer 1, the wear-resistant layer 2 and the reinforcing layer 3 are firmly combined into a whole; the surface wear-resistant layer 1 comprises 70 parts by weight of benzol unsaturated resin containing an accelerant and a curing agent, 15 parts of 50-60-mesh glass flakes and 15 parts of 50-100-mesh anti-slip rubber particles, the wear-resistant layer 2 comprises 45 parts by weight of benzol unsaturated resin containing an accelerant and a curing agent, 35 parts of 350-plus-450-mesh glass fiber reinforced plastic particles, 8 parts of 300-plus-450-mesh toothpaste-grade aluminum hydroxide, 10 parts of 350-plus-400-mesh ceramic microspheres, 1.5 parts of color paste and 0.2 part of an antifoaming agent, and the reinforcing layer 3 comprises 20 parts by weight of benzol unsaturated resin containing an accelerant and a curing agent, 55 parts of ceramic sand, 12 parts of 80-100-mesh stone powder, 2.5 parts of 80-100-mesh floating beads, 2.5 parts of 350-plus-400-mesh light calcium carbonate, 7 parts of 350-plus-mesh 400-mesh glass microspheres and 1 part of color paste.
Example 5:
the main structure of the polymer pavement brick related to the embodiment comprises a surface wear-resistant layer 1, a wear-resistant layer 2 and a reinforcing layer 3; the surface wear-resistant layer 1, the wear-resistant layer 2 and the reinforcing layer 3 are firmly combined into a whole; the surface wear-resistant layer 1 comprises 60 parts by weight of m-benzene unsaturated resin containing an accelerant and a curing agent, 15 parts of 50-60-mesh glass flakes and 25 parts of 50-100-mesh anti-slip rubber particles, the wear-resistant layer 2 comprises 45 parts by weight of m-benzene unsaturated resin containing an accelerant and a curing agent, 35 parts of 350-plus-450-mesh glass reinforced plastic particles, 8 parts of 300-plus-450-mesh toothpaste-grade aluminum hydroxide, 10 parts of 350-plus-400-mesh ceramic microspheres, 1.5 parts of color paste and 0.5 part of an antifoaming agent, and the reinforcing layer 3 comprises 20 parts by weight of m-benzene unsaturated resin containing an accelerant and a curing agent, 50 parts of ceramic sand, 15 parts of 80-100-mesh stone powder, 3.5 parts of 80-100-mesh floating beads, 3.5 parts of 350-plus-400-mesh light calcium carbonate, 7 parts of 350-plus-mesh 400-mesh glass microspheres and 1 part of color.
Example 6:
the main structure of the polymer pavement brick related to the embodiment comprises a surface wear-resistant layer 1, a wear-resistant layer 2 and a reinforcing layer 3; the surface wear-resistant layer 1, the wear-resistant layer 2 and the reinforcing layer 3 are firmly combined into a whole; the surface wear-resistant layer 1 comprises 70 parts by weight of m-benzene unsaturated resin containing an accelerant and a curing agent, 15 parts of 50-60-mesh glass flakes and 15 parts of 50-100-mesh anti-slip rubber particles, the wear-resistant layer 2 comprises 45 parts by weight of m-benzene unsaturated resin containing an accelerant and a curing agent, 35 parts of 350-plus-450-mesh glass reinforced plastic particles, 8 parts of 300-plus-450-mesh toothpaste-grade aluminum hydroxide, 10 parts of 350-plus-400-mesh ceramic microspheres, 1.5 parts of color paste and 0.5 part of an antifoaming agent, and the reinforcing layer 3 comprises 20 parts by weight of m-benzene unsaturated resin containing an accelerant and a curing agent, 50 parts of ceramic sand, 15 parts of 80-100-mesh stone powder, 3.5 parts of 80-100-mesh floating beads, 3.5 parts of 350-plus-400-mesh light calcium carbonate, 7 parts of 350-plus-400-mesh glass microspheres and 1 part of color paste.
Example 7:
the main structure of the polymer pavement brick related to the embodiment comprises a surface wear-resistant layer 1, a wear-resistant layer 2 and a reinforcing layer 3; the surface wear-resistant layer 1, the wear-resistant layer 2 and the reinforcing layer 3 are firmly combined into a whole; the surface wear-resistant layer 1 comprises 60 parts by weight of m-benzene unsaturated resin containing an accelerant and a curing agent, 15 parts by weight of 50-60-mesh glass flakes and 25 parts by weight of 50-100-mesh anti-slip rubber particles, the wear-resistant layer 2 comprises 45 parts by weight of m-benzene unsaturated resin containing an accelerant and a curing agent, 35 parts by weight of 350-plus-450-mesh glass reinforced plastic particles, 8 parts by weight of 300-plus-450-mesh toothpaste-grade aluminum hydroxide, 10 parts by weight of 350-plus-400-mesh ceramic microspheres, 1.5 parts by weight of color paste and 0.5 part by weight of an antifoaming agent, and the reinforcing layer 3 comprises 20 parts by weight of m-benzene unsaturated resin containing an accelerant and a curing agent, 55 parts by weight of ceramic sand, 12 parts by weight of 80-100-mesh stone powder, 2.5 parts by weight of 80-100-mesh floating beads, 2.5 parts by weight of 350-plus-mesh 400-.
Example 8:
the main structure of the polymer pavement brick related to the embodiment comprises a surface wear-resistant layer 1, a wear-resistant layer 2 and a reinforcing layer 3; the surface wear-resistant layer 1, the wear-resistant layer 2 and the reinforcing layer 3 are firmly combined into a whole; the surface wear-resistant layer 1 comprises 70 parts by weight of m-benzene unsaturated resin containing an accelerant and a curing agent, 15 parts of 50-60-mesh glass flakes and 15 parts of 50-100-mesh anti-slip rubber particles, the wear-resistant layer 2 comprises 45 parts by weight of m-benzene unsaturated resin containing an accelerant and a curing agent, 35 parts of 350-plus-450-mesh glass reinforced plastic particles, 8 parts of 300-plus-450-mesh toothpaste-grade aluminum hydroxide, 10 parts of 350-plus-400-mesh ceramic microspheres, 1.5 parts of color paste and 0.5 part of an antifoaming agent, and the reinforcing layer 3 comprises 20 parts by weight of m-benzene unsaturated resin containing an accelerant and a curing agent, 55 parts of ceramic sand, 12 parts of 80-100-mesh stone powder, 2.5 parts of 80-100-mesh floating beads, 2.5 parts of 350-plus-400-mesh light calcium carbonate, 7 parts of 350-plus-400-mesh glass microspheres and 1 part of color paste.
Example 9:
the main structure of the polymer pavement brick related to the embodiment comprises a surface wear-resistant layer 1, a wear-resistant layer 2 and a reinforcing layer 3; the surface wear-resistant layer 1, the wear-resistant layer 2 and the reinforcing layer 3 are firmly combined into a whole; the surface wear-resistant layer 1 comprises 60 parts by weight of p-phenylene unsaturated resin containing an accelerant and a curing agent, 15 parts of 50-60-mesh glass flakes and 25 parts of 50-100-mesh anti-slip rubber particles, the wear-resistant layer 2 comprises 50 parts by weight of p-phenylene unsaturated resin containing an accelerant and a curing agent, 30 parts of 350-plus-450-mesh glass fiber reinforced plastic particles, 8.3 parts of 300-plus-450-mesh toothpaste-grade aluminum hydroxide, 10 parts of 350-plus-400-mesh ceramic microspheres, 1.5 parts of color paste and 0.2 part of an antifoaming agent, and the reinforcing layer 3 comprises 20 parts by weight of p-phenylene unsaturated resin containing an accelerant and a curing agent, 50 parts of ceramic sand, 15 parts of 80-100-mesh stone powder, 3.5 parts of 80-100-mesh floating beads, 3.5 parts of 350-plus-400-mesh light calcium carbonate, 7 parts of 350-plus-mesh 400-mesh glass microspheres and.
Example 10:
the main structure of the polymer pavement brick related to the embodiment comprises a surface wear-resistant layer 1, a wear-resistant layer 2 and a reinforcing layer 3; the surface wear-resistant layer 1, the wear-resistant layer 2 and the reinforcing layer 3 are firmly combined into a whole; the surface wear-resistant layer 1 comprises 70 parts by weight of p-phenylene unsaturated resin containing an accelerant and a curing agent, 15 parts of 50-60-mesh glass flakes and 15 parts of 50-100-mesh anti-slip rubber particles, the wear-resistant layer 2 comprises 50 parts by weight of p-phenylene unsaturated resin containing an accelerant and a curing agent, 30 parts of 350-plus-450-mesh glass fiber reinforced plastic particles, 8.3 parts of 300-plus-450-mesh toothpaste-grade aluminum hydroxide, 10 parts of 350-plus-400-mesh ceramic microspheres, 1.5 parts of color paste and 0.2 part of an antifoaming agent, and the reinforcing layer 3 comprises 20 parts by weight of p-phenylene unsaturated resin containing an accelerant and a curing agent, 50 parts of ceramic sand, 15 parts of 80-100-mesh stone powder, 3.5 parts of 80-100-mesh floating beads, 3.5 parts of 350-plus-400-mesh light calcium carbonate, 7 parts of 350-plus-mesh 400-mesh glass microspheres and.
Example 11:
the main structure of the polymer pavement brick related to the embodiment comprises a surface wear-resistant layer 1, a wear-resistant layer 2 and a reinforcing layer 3; the surface wear-resistant layer 1, the wear-resistant layer 2 and the reinforcing layer 3 are firmly combined into a whole; the surface wear-resistant layer 1 comprises, by weight, 60 parts of vinyl ester unsaturated resin containing an accelerator and a curing agent, 15 parts of 50-60-mesh glass flakes and 25 parts of 50-100-mesh anti-slip rubber particles, the wear-resistant layer 2 comprises, by weight, 50 parts of vinyl ester unsaturated resin containing an accelerator and a curing agent, 30 parts of 350-plus-450-mesh glass fiber reinforced plastic particles, 8.3 parts of 300-plus-450-mesh toothpaste-grade aluminum hydroxide, 10 parts of 350-plus-400-mesh ceramic microspheres, 1.5 parts of color paste and 0.2 part of an antifoaming agent, and the reinforcing layer 3 comprises, by weight, 20 parts of vinyl ester unsaturated resin containing an accelerator and a curing agent, 50 parts of ceramic sand, 15 parts of 80-100-mesh stone powder, 3.5 parts of 80-100-mesh floating beads, 3.5 parts of 350-plus-400-mesh light calcium carbonate, 7 parts of 350-plus-mesh 400-mesh.
Example 12:
the main structure of the polymer pavement brick related to the embodiment comprises a surface wear-resistant layer 1, a wear-resistant layer 2 and a reinforcing layer 3; the surface wear-resistant layer 1, the wear-resistant layer 2 and the reinforcing layer 3 are firmly combined into a whole; the surface wear-resistant layer 1 comprises, by weight, 70 parts of vinyl ester unsaturated resin containing an accelerator and a curing agent, 15 parts of 50-60-mesh glass flakes and 15 parts of 50-100-mesh anti-slip rubber particles, the wear-resistant layer 2 comprises, by weight, 50 parts of vinyl ester unsaturated resin containing an accelerator and a curing agent, 30 parts of 350-plus-450-mesh glass fiber reinforced plastic particles, 8.3 parts of 300-plus-450-mesh toothpaste-grade aluminum hydroxide, 10 parts of 350-plus-400-mesh ceramic microspheres, 1.5 parts of color paste and 0.2 part of an antifoaming agent, and the reinforcing layer 3 comprises, by weight, 20 parts of vinyl ester unsaturated resin containing an accelerator and a curing agent, 50 parts of ceramic sand, 15 parts of 80-100-mesh stone powder, 3.5 parts of 80-100-mesh floating beads, 3.5 parts of 350-plus-400-mesh light calcium carbonate, 7 parts of 350-plus-mesh 400-mesh.

Claims (4)

1. A polymer pavement brick is characterized in that the main structure comprises a surface wear-resistant layer, a wear-resistant layer and a reinforcing layer; the surface wear-resistant layer, the wear-resistant layer and the reinforcing layer are firmly combined into a whole, and the thickness ratio of the surface wear-resistant layer to the reinforcing layer is 1:4-6: 5-7; the surface wear-resistant layer consists of unsaturated resin, glass flakes and anti-skid rubber particles, the wear-resistant layer consists of unsaturated resin, glass fiber reinforced plastic particles, toothpaste-grade aluminum hydroxide, ceramic microspheres, color paste and a defoaming agent, and the reinforcing layer consists of unsaturated resin, ceramic sand, stone powder, floating beads, light calcium carbonate, glass microspheres and color paste.
2. The polymer pavement brick as claimed in claim 1, wherein the wear-resistant layer comprises, by weight, 48-74 parts of unsaturated resin, 10-26 parts of 50-60 mesh glass flakes and 15-30 parts of 50-100 mesh anti-slip rubber particles, the wear-resistant layer comprises, by weight, 40-60 parts of unsaturated resin, 25-35 parts of 350-450 mesh glass fiber reinforced plastic particles, 5-10 parts of 300-450 mesh toothpaste-grade aluminum hydroxide, 5-10 parts of 350-400 mesh ceramic microspheres, 1.5-3 parts of color paste and 0.2-0.8 part of defoaming agent, and the reinforcing layer comprises, by weight, 15-25 parts of unsaturated resin, 40-60 parts of ceramic sand, 10-15 parts of 80-100 mesh stone powder, 2.5-4.5 parts of 80-100 mesh floating beads, 2.5-4.5 parts of 350-400-mesh light calcium carbonate, 5 to 8 portions of 350-400-mesh glass beads and 0.75 to 1 portion of color paste.
3. A polymer pavement brick according to claim 1, wherein the unsaturated resin includes p-benzene unsaturated resin, m-benzene unsaturated resin, o-benzene unsaturated resin and vinyl ester unsaturated resin.
4. The polymer pavement brick according to claim 2, wherein the compressive strength is not less than 20MPa, the bending strength is not less than 3MPa, the length of the grinding pit is not more than 37mm, the Babbitt hardness is not less than 35, the water absorption is not more than 1%, and the brick has anti-skid property.
CN201910414465.4A 2019-05-17 2019-05-17 Polymer pavement brick Active CN110204250B (en)

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CN113501678B (en) * 2021-08-10 2022-01-07 温州恒福新型建材有限公司 Stone-like ecological water permeable brick and preparation method thereof
CN113800877A (en) * 2021-09-28 2021-12-17 上海缘滔新材料有限公司 Preparation method of concrete road brick

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CN2592703Y (en) * 2003-02-14 2003-12-17 韩杰 Landscape artistic road board
JP5232984B2 (en) * 2007-07-04 2013-07-10 荒木窯業株式会社 Porous brick and method for producing the same
CN103469712A (en) * 2013-09-30 2013-12-25 济南城建集团有限公司 Method for paving anti-rut anti-skid pavement coating
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