CN110171242A - A kind of cinnabar is inlaid with gold product and its preparation process - Google Patents
A kind of cinnabar is inlaid with gold product and its preparation process Download PDFInfo
- Publication number
- CN110171242A CN110171242A CN201910461024.XA CN201910461024A CN110171242A CN 110171242 A CN110171242 A CN 110171242A CN 201910461024 A CN201910461024 A CN 201910461024A CN 110171242 A CN110171242 A CN 110171242A
- Authority
- CN
- China
- Prior art keywords
- cinnabar
- gold
- product
- inlaid
- preparation process
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C3/00—Processes, not specifically provided for elsewhere, for producing ornamental structures
- B44C3/12—Uniting ornamental elements to structures, e.g. mosaic plates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J177/00—Adhesives based on polyamides obtained by reactions forming a carboxylic amide link in the main chain; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
It is inlaid with gold product and its preparation process the present invention relates to a kind of cinnabar.The cinnabar be inlaid with gold product preparation process the following steps are included: (1) grinds cinnabar, mixed with epoxide-resin glue, obtain pre-composition；(2) pre-composition is solidified, is prepared into the reeded product substrate of surface band；(3) gold jewellery and groove are binded with glue of polishing and is inlaid with gold product to get cinnabar.The cinnabar is inlaid with gold the preparation process of product, by grinding cinnabar, prepares substrate, bonding gold jewellery, has obtained the good product of gold jewellery bonding effect.And prove by peel test, bonding effect is better than the common bisphenol type epoxy glue in market and JQ-2 polyurethane adhesive, enable cinnabar be inlaid with gold the product longer time holding it is complete.
Description
Technical field
The invention belongs to preparation fields, and in particular to a kind of cinnabar is inlaid with gold product and its preparation process.
Background technique
Cinnabar original name cinnabar, is typically used to drug therapy, is the natural cinnabar of six sides.Shennong's Herbal is classified as
Product, medicinal processing can it is relieving convulsion, detoxify, control insane disease, infantile convulsion, palpitation and being susceptible to fright, insomnia, dreaminess, blurred vision etc..Outside control sore swollen toxin,
Aphthae.Cinnabar not only can be medicinal, and in national defence chemical industry, radiation protection laser, the anti-attaching organism of naval vessels ship etc. also has
Extensive use.Therefore, cinnabar has the good name of " soft ruby " again.
In addition, cinnabar can also be processed to the art work as ore, cinnabar product can be further continued for being repaired for beauty
Decorations wherein the decorations that are inlaid with gold have become the means for promoting its added value, however are inlaid with gold that adorn existing main problem be gold jewellery and Zhu at present
The cohesive force of sand substrate is insufficient, and gold jewellery obscission easily occurs over time, therefore still needs to further improve.
Summary of the invention
It is of the existing technology in order to solve the problems, such as, it is inlaid with gold product and its preparation process the present invention provides a kind of cinnabar.
The cinnabar is inlaid with gold the preparation process of product, by grinding cinnabar, prepares substrate, bonding gold jewellery, it is glutinous to have obtained gold jewellery
Close the good product of effect.
The solution of the present invention is the preparation process for providing a kind of cinnabar and being inlaid with gold product, comprising the following steps:
(1) cinnabar is ground, is mixed with epoxide-resin glue, obtain pre-composition；
(2) pre-composition is solidified, is prepared into the reeded product substrate of surface band；
(3) gold jewellery and groove are binded with glue of polishing and is inlaid with gold product to get cinnabar.
After having prepared, product that cinnabar need to be inlaid with gold is polished, perfect to carry out.
In addition, gold jewellery surface can also carve various embossing patterns on demand, make whole more beautiful.Polishing glue is filled in groove
It is formed by gap with gold jewellery, after glue of polishing is fully cured, gold jewellery is then bonded with product substrate completely.
The cinnabar can be ground into graininess or powdery on demand, therefore preferably, it is described to be ground to cinnabar in step (1)
Granularity is 18~120 mesh.
Preferably, in step (1), the weight ratio of the epoxide-resin glue and cinnabar is 1:5~6；Wherein epoxide-resin glue
The trade mark be 6101.
Preferably, in step (1), the mixed revolving speed be 100~150r/min, the mixed time be 20~
30min。
Preferably, in step (2), the cured temperature be 30~40 DEG C, the cured time be 20~for 24 hours.
Wherein, when prepolymer being solidified, silica gel mould need to be used, the demoulding in later period is conducive to.
Preferably, in step (3), it is described polishing glue the preparation method comprises the following steps: by epoxy resin E-5, glycidyl butyl ether,
Precipitated calcium carbonate, silicon powder and the mixing of 650 polyamide are reacted.
Preferably, the epoxy resin E-5, glycidyl butyl ether, precipitated calcium carbonate, silicon powder and 650 polyamide
Weight ratio is 28~30:3~5:15~20:15~20:28~30.
Preferably, the revolving speed of the mixing is 40~60r/min.
Preferably, the reaction time is 4~5h.
Based on the same technical idea, it is inlaid with gold product the present invention also provides a kind of cinnabar being prepared by above-mentioned technique.
The invention has the benefit that
Cinnabar of the present invention is inlaid with gold the preparation process of product, by grinding cinnabar, prepares the steps such as substrate, bonding gold jewellery
Suddenly, the good product of gold jewellery bonding effect has been obtained.And proved by peel test, bonding effect is better than the common bisphenol-A in market
Type epoxy glue and JQ-2 polyurethane adhesive, enable cinnabar be inlaid with gold the product longer time holding it is complete.
Detailed description of the invention
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below
There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this
Some embodiments of invention for those of ordinary skill in the art without creative efforts, can be with
It obtains other drawings based on these drawings.
Fig. 1 is peel strength experiment schematic diagram.
Appended drawing reference in figure are as follows:
The first collet of 1-；The second collet of 2-；3- rigid material；4- polishing glue-line；5- flexible material.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, technical solution of the present invention will be carried out below
Detailed description.Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Base
Embodiment in the present invention, those of ordinary skill in the art are obtained all without making creative work
Other embodiment belongs to the range that the present invention is protected.
Embodiment 1
It is inlaid with gold the preparation process of product, includes the following steps: the present embodiment provides a kind of cinnabar
(I) preparation polishing glue, method particularly includes: by 28g epoxy resin E-5,3g glycidyl butyl ether, 15g lightweight carbon
Sour calcium, 15g silicon powder and 28g polyamide 6 50 mix 5h under the conditions of 40r/min and are reacted, after the completion up to polishing glue.
(II) cinnabar is prepared to be inlaid with gold the preparation process of product, method particularly includes:
(1) cinnabar is ground to granularity is 18~30 mesh, is mixed with epoxide-resin glue according to weight ratio for 6:1, and
30min is stirred under conditions of 100r/min, obtains pre-composition after the completion；
(2) pre-composition is fitted into mold, is solidified for 24 hours under the conditions of 30 DEG C, be prepared into the reeded system of surface band
Product substrate；
(3) gold jewellery surface engraving is gone out into embossing pattern, be placed into groove, bonding is filled with glue of polishing, wait polish
Glue is inlaid with gold product after being fully cured to get cinnabar.
Embodiment 2
It is inlaid with gold the preparation process of product, includes the following steps: the present embodiment provides a kind of cinnabar
(I) preparation polishing glue, method particularly includes: by 30g epoxy resin E-5,5g glycidyl butyl ether, 20g lightweight carbon
Sour calcium, 20g silicon powder and 30g polyamide 6 50 mix 4h under the conditions of 60r/min and are reacted, after the completion up to polishing glue.
(II) cinnabar is prepared to be inlaid with gold the preparation process of product, method particularly includes:
(1) cinnabar is ground to granularity is 100~120 mesh, is mixed with epoxide-resin glue according to weight ratio for 5:1,
And 20min is stirred under conditions of 150r/min, pre-composition is obtained after the completion；
(2) pre-composition is fitted into mold, carries out solidification 20h under the conditions of 40 DEG C, be prepared into the reeded system of surface band
Product substrate；
(3) gold jewellery surface engraving is gone out into embossing pattern, be placed into groove, bonding is filled with glue of polishing, wait polish
Glue is inlaid with gold product after being fully cured to get cinnabar.
Embodiment 3
It is inlaid with gold the preparation process of product, includes the following steps: the present embodiment provides a kind of cinnabar
(I) preparation polishing glue, method particularly includes: by 29g epoxy resin E-5,4g glycidyl butyl ether, 18g lightweight carbon
Sour calcium, 18g silicon powder and 29g polyamide 6 50 mix 4.5h under the conditions of 50r/min and are reacted, after the completion up to polishing glue.
(II) cinnabar is prepared to be inlaid with gold the preparation process of product, method particularly includes:
(1) cinnabar is ground to granularity is 60~70 mesh, is mixed with epoxide-resin glue according to weight ratio for 5.5:1,
And 25min is stirred under conditions of 125r/min, pre-composition is obtained after the completion；
(2) pre-composition is fitted into mold, carries out solidification 22h under the conditions of 35 DEG C, be prepared into the reeded system of surface band
Product substrate；
(3) gold jewellery surface engraving is gone out into embossing pattern, be placed into groove, bonding is filled with glue of polishing, wait polish
Glue is inlaid with gold product after being fully cured to get cinnabar.
In order to verify polishing glue of the present invention to the cohesive force of gold jewellery, following peel strength experiment is designed:
Experimental considerations analysis: it since gold jewellery of the present invention and product substrate are rigid material, can not directly be shelled
From experiment, and the effect mainly between gold jewellery interface, polishing glue and product substrate interface three is binded, therefore gold jewellery material is plated
In rigid material (label 3 in Fig. 1) surface, product substrate material is fixed on flexible material (label 5 in Fig. 1) surface, and join
GB/T 2790-1995 to be examined, peel test is designed, wherein the first collet (label 1 in Fig. 1) is mobile to white arrow direction, the
Two collets (label 2 in Fig. 1) are mobile to black arrow direction, removed with this, until polishing glue-line (label 4 in Fig. 1)
When cohesional failure occurs, peel strength is recorded.
Experimental procedure:
(i) selection width is the strip of 25.0mm ± 0.5mm, a length of 200mm or more as rigid material；
(ii) 180 ° can be bent without serious non-response deformation by choosing, and sample of the length not less than 350mm is made
For flexible material；
(iii) the resulting polishing glue of the present invention is respectively sticked rigid material and flexible material with commercially available polishing glue
It closes, gluing length is 150mm；
(iv) one end for not being glued flexible material is bent 180 °, rigid material is fixed on the first collet, by flexible material
Material is fixed on the second collet, and the rate of departure of collet is 100 ± 10mm/min；Until cohesional failure occurs for polishing glue, record is real
Test result.
Wherein, experimental result is as shown in table 1.
1 peel strength test result of table
| Polishing glue type | Peel strength (kN/m) |
| 1 gained of embodiment | 9.5 |
| 2 gained of embodiment | 8.9 |
| 3 gained of embodiment | 10.3 |
| Commercially available bisphenol type epoxy glue | 9.3 |
| Commercially available JQ-2 polyurethane adhesive | 9.6 |
As a result and conclusion it chooses common bisphenol type epoxy glue and JQ-2 polyurethane adhesive on the market and carries out proving and comparisom,
Display:
1, as the peel strength of polishing glue obtained by Examples 1 to 3 it is found that polishing glue peel strength obtained by embodiment 3 is best,
Show that when raw material dosage and parameter are in median, effect is best during glue is polished in preparation.
2, polishing glue is compared with commercially available bisphenol type epoxy glue, commercially available JQ-2 polyurethane adhesive obtained by embodiment 3, peel strength
Both after being superior to.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any
Those familiar with the art in the technical scope disclosed by the present invention, can easily think of the change or the replacement, and should all contain
Lid is within protection scope of the present invention.Therefore, protection scope of the present invention should be based on the protection scope of the described claims.
Claims (10)
- The preparation process of product 1. a kind of cinnabar is inlaid with gold, which comprises the following steps:(1) cinnabar is ground, is mixed with epoxide-resin glue, obtain pre-composition；(2) pre-composition is solidified, is prepared into the reeded product substrate of surface band；(3) gold jewellery and groove are binded with glue of polishing and is inlaid with gold product to get cinnabar.
- The preparation process of product 2. cinnabar according to claim 1 is inlaid with gold, which is characterized in that in step (1), the grinding It is 18~120 mesh to cinnabar granularity.
- The preparation process of product 3. cinnabar according to claim 1 is inlaid with gold, which is characterized in that in step (1), the epoxy The weight ratio of resin glue and cinnabar is 1:5~6.
- The preparation process of product 4. cinnabar according to claim 1 is inlaid with gold, which is characterized in that in step (1), the mixing Revolving speed be 100~150r/min, the mixed time be 20~30min.
- The preparation process of product 5. cinnabar according to claim 1 is inlaid with gold, which is characterized in that in step (2), the solidification Temperature be 30~40 DEG C, the cured time be 20~for 24 hours.
- The preparation process of product 6. cinnabar according to claim 1 is inlaid with gold, which is characterized in that in step (3), the polishing Glue the preparation method comprises the following steps: by epoxy resin E-5, glycidyl butyl ether, precipitated calcium carbonate, silicon powder and 650 polyamide mix Stirring is reacted.
- The preparation process of product 7. cinnabar according to claim 6 is inlaid with gold, which is characterized in that the epoxy resin E-5, ring Oxygen propyl group butyl ether, precipitated calcium carbonate, silicon powder and 650 polyamide weight ratio be 28~30:3~5:15~20:15~20: 28~30.
- The preparation process of product 8. cinnabar according to claim 6 is inlaid with gold, which is characterized in that the revolving speed of the mixing For 40~60r/min.
- The preparation process of product 9. cinnabar according to claim 6 is inlaid with gold, which is characterized in that the reaction time be 4~ 5h。
- The product 10. cinnabar that any one of claim 1~9 technique is prepared is inlaid with gold.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910461024.XA CN110171242A (en) | 2019-05-30 | 2019-05-30 | A kind of cinnabar is inlaid with gold product and its preparation process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910461024.XA CN110171242A (en) | 2019-05-30 | 2019-05-30 | A kind of cinnabar is inlaid with gold product and its preparation process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110171242A true CN110171242A (en) | 2019-08-27 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910461024.XA Pending CN110171242A (en) | 2019-05-30 | 2019-05-30 | A kind of cinnabar is inlaid with gold product and its preparation process |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2695260Y (en) * | 2003-12-28 | 2005-04-27 | 李德志 | Calabash inlay work of art |
| CN102039773A (en) * | 2009-10-22 | 2011-05-04 | 吴先见 | Manufacture technology of vermilion ornament |
| EP2380864A1 (en) * | 2010-04-23 | 2011-10-26 | Omega SA | Ceramic element inlaid with at least one metal decoration |
| CN102529552A (en) * | 2011-12-07 | 2012-07-04 | 贵州省万山特区丹缘朱砂工艺品有限公司 | Technique for filling cinnabar to hollow pattern of transparent object |
| CN104228442A (en) * | 2014-07-31 | 2014-12-24 | 杨昭斌 | Cinnabar crystal raw ore and cinnabar engraving technology |
| CN109466228A (en) * | 2018-12-03 | 2019-03-15 | 丹寨县益家益银饰服饰有限公司 | Utilize Cinnabar production ornaments and preparation method thereof |
-
2019
- 2019-05-30 CN CN201910461024.XA patent/CN110171242A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2695260Y (en) * | 2003-12-28 | 2005-04-27 | 李德志 | Calabash inlay work of art |
| CN102039773A (en) * | 2009-10-22 | 2011-05-04 | 吴先见 | Manufacture technology of vermilion ornament |
| EP2380864A1 (en) * | 2010-04-23 | 2011-10-26 | Omega SA | Ceramic element inlaid with at least one metal decoration |
| CN102529552A (en) * | 2011-12-07 | 2012-07-04 | 贵州省万山特区丹缘朱砂工艺品有限公司 | Technique for filling cinnabar to hollow pattern of transparent object |
| CN104228442A (en) * | 2014-07-31 | 2014-12-24 | 杨昭斌 | Cinnabar crystal raw ore and cinnabar engraving technology |
| CN109466228A (en) * | 2018-12-03 | 2019-03-15 | 丹寨县益家益银饰服饰有限公司 | Utilize Cinnabar production ornaments and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| ABC1234789A: "环氧树脂胶水配方和性能", 《百度文库》 * |
| 上海市化轻公司第二化工供应部: "《化工产品应用手册 合成材料助剂·食品添加剂》", 31 May 1989, 上海科学技术出版社 * |
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Application publication date: 20190827 |
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