CN110167215A - A kind of preparation method of new far infrared electric heating film - Google Patents

A kind of preparation method of new far infrared electric heating film Download PDF

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Publication number
CN110167215A
CN110167215A CN201910523245.5A CN201910523245A CN110167215A CN 110167215 A CN110167215 A CN 110167215A CN 201910523245 A CN201910523245 A CN 201910523245A CN 110167215 A CN110167215 A CN 110167215A
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Prior art keywords
heating film
electric heating
preparation
far infrared
parts
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CN201910523245.5A
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Chinese (zh)
Inventor
钟海波
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Ningbo Lingguang Thermal Materials Technology Co Ltd
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Ningbo Lingguang Thermal Materials Technology Co Ltd
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Priority to CN201910523245.5A priority Critical patent/CN110167215A/en
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    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/10Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
    • H05B3/12Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/20Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
    • H05B3/34Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater flexible, e.g. heating nets or webs

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  • Resistance Heating (AREA)
  • Surface Heating Bodies (AREA)

Abstract

The present invention relates to Electric radiant Heating Film fields, the preparation method of specifically a kind of new far infrared electric heating film, the following steps are included: the heating film is by 30~70 parts of parts by weight of aquadag powder, 30~70 parts of conductive black powder, 2~10 parts of aluminium oxide powder compound at conductive filler, be added matrix resin electric heating slurry is made.Electric heating film base material is made coated in sintering cured on glass-fiber-fabric, then after cutting connection electrode, finally in two face composite insulation layers of base sheet, obtains far-infrared electrothermal film.Far infrared electric heating film prepared by the present invention has many advantages, such as that electric conversion efficiency is high, generate heat uniformly and substrate bond strength is high, the service life is long, generates the far infrared of beneficial human body;And simple process, material is cheap, is suitble to large-scale continuous production.

Description

A kind of preparation method of new far infrared electric heating film
Technical field
The present invention relates to Electric radiant Heating Film field, the preparation method of specifically a kind of new far infrared electric heating film.
Background technique
Currently, electric heating has become family life or the most common heating method of industrial production.Common heating source There are resistance wire, quartz ampoule, PTC, infrared ray and Electric radiant Heating Film etc..Electric radiant Heating Film is from the external time for introducing existing decades, due to making With conveniently, cleanliness without any pollution is applied widely, more and more applies in all trades and professions.
And most electric heating film for heating materials are metallic resistance silk, printing ink and carbon fiber on the market.In the presence of such as Electric conversion rate is low, fever is uneven, power attenuation is fast, the service life is short, it is at high cost using precious metal, with substrate be detached from etc. ask Topic.
Therefore, for this status, there is an urgent need to develop a kind of Novel electric heating films, to overcome in currently practical application It is insufficient.
Summary of the invention
The purpose of the present invention is to provide a kind of preparation methods of new far infrared electric heating film, to solve above-mentioned background skill The problem of being proposed in art.
To achieve the above object, the invention provides the following technical scheme:
A kind of preparation method of new far infrared electric heating film, comprising the following steps:
One, the preparation of electric heating film base material:
(1) it makes conductive filler: weighing 30-70 parts of aquadag powder by weight, 30-70 parts of conductive black powder, 2-10 parts of aluminium oxide powder is placed in powder mixer spare after mixing 4-6h;
(2) it makes conductive paste masterbatch: weighing 10-30 parts of powder prepared in step (1), dimethyl acetamide by weight It is 40-90 parts, the mixed grinding 60-120min in grinder, spare after filtering;
(3) it configures electric heating slurry: weighing 50-100 parts of polyimide varnish, the conductive paste prepared in step (2) by weight It 20-50 parts of masterbatch, is placed in dispersion machine and disperses 30-60min, and adjust viscosity to 120-300mPa.s, after filtering with diluent Obtain electrothermal coating slurry;
(4) it is coated with: by the slurry coater prepared in step (3) on glass-fiber-fabric, be tentatively crosslinked in an oven, Solidification;
(5) by step (4) prepare film be placed in Muffle furnace, be sintered 60-120min, 300-400 DEG C of sintering temperature;
(6) sheet material that the electrothermal film material prepared in step (5) is cut into demand size is implanted on both sides or two sides (paste, brush) electrode, obtains electric heating film base material;
Two, Electric radiant Heating Film is prepared:
(7) electric heating film base material tow sides prepared by step 1 are respectively coated into one layer of thermally conductive bonded adhesives;
It (8), will be through step (7) treated each compound layer insulating of Electric radiant Heating Film sheet material tow sides on laminating machine;
(9) conducting wire is connected on the membrane electrode after laminating, and far-infrared electrothermal film is obtained after insulation.
As a further solution of the present invention: aquadag powder diameter≤10 μm, conductive black powder diameter≤10 μm, Aluminium oxide powder partial size≤100 μm.
As a further solution of the present invention: the diluent is dimethyl acetamide or dimethylbenzene.
As a further solution of the present invention: the glass-fiber-fabric is the glass-fiber-fabric of thickness 0.06-0.15mm.
As a further solution of the present invention: the electrode is metal foil, metal foil belt, electricity conductive cloth tape, conductive silver Any one in slurry.
As a further solution of the present invention: the insulating film is teflon insulation film, PA membrane, polyester The combination of one or more of film, mica sheet, electricity conductive cloth tape, epoxy plate.
Far infrared electric heating film provided by the invention is using micron order graphite powder, conductive black powder and macromolecule resin etc. Material cladding forms.Take full advantage of excellent electric property, high-termal conductivity and high-fire resistance that carbon composite has, Yi Jigao The structural stability of molecular material, workability.The Far infrared electric heating film of preparation has electric conversion efficiency height, fever equal Even and substrate bond strength is high, the service life is long, generates the advantages that far infrared beneficial to human body, and simple process and low cost, It is suitble to large-scale continuous production.
Specific embodiment
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field Art personnel every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
Embodiment 1
A kind of preparation method of new far infrared electric heating film, comprising the following steps:
One, the preparation of electric heating film base material:
(1) it makes conductive filler: weighing 70 parts of aquadag powder by weight, 30 parts of conductive black powder, the three of 2 parts Al 2 O powder is placed in powder mixer spare, mixing velocity 55rpm after mixing 4h under normal temperature conditions;
(2) it makes conductive paste masterbatch: weighing 20 parts of powder prepared in step (1) by weight, stupid 70 parts of diformazan, grinding Mixed grinding 60min under normal temperature condition in grinding machine, grinding rate 1100rpm, with spare after the screen to filtrate;
(3) it configures electric heating slurry: weighing 50 parts of polyimide varnish, the conductive paste masterbatch prepared in step (2) by weight 40 parts, under normal temperature conditions, be placed in dispersion machine and disperse 30min, rate of dispersion 1300rpm, and with diluent adjust viscosity to 120mPa.s, with obtaining electrothermal coating slurry after the screen to filtrate;
(4) it is coated with: by the slurry coater prepared in step (3) on glass-fiber-fabric, be tentatively crosslinked in an oven, Solidification;
(5) by step (4) prepare film be placed in Muffle furnace, be sintered 60min, 350 DEG C of sintering temperature;
(6) sheet material that the electrothermal film material prepared in step (5) is cut into demand size, in both sides implant electrode, Electrode contact surface coats one layer of transition conductive layer to get electric heating film base material is arrived;
Two, Electric radiant Heating Film is prepared:
(7) electric heating film base material tow sides prepared by step 1 are respectively coated into one layer of thermally conductive bonded adhesives;
It (8), will be through step (7) treated each compound one layer of insulating film of Electric radiant Heating Film sheet material tow sides on laminating machine;
(9) conducting wire is connected on the membrane electrode after laminating, and far-infrared electrothermal film is obtained after insulation.
Wherein, aquadag powder diameter≤10 μm, conductive black powder diameter≤10 μm, aluminium oxide powder partial size≤ 100μm;The diluent is that diformazan is stupid;The glass-fiber-fabric is the glass-fiber-fabric of thickness 0.15mm;The electrode is metal foil (copper Foil);The insulating film is the combination of teflon insulation film and PA membrane.
Embodiment 2
A kind of preparation method of new far infrared electric heating film, comprising the following steps:
One, the preparation of electric heating film base material:
(1) it makes conductive filler: weighing 50 parts of aquadag powder by weight, 70 parts of conductive black powder, 10 parts Aluminium oxide powder is placed in powder mixer spare, mixing velocity 65rpm after mixing 6h under normal temperature conditions;
(2) it makes conductive paste masterbatch: weighing 30 parts of powder prepared in step (1), dimethyl acetamide 90 by weight Part, mixed grinding 120min under normal temperature condition, grinding rate 1300rpm in grinder, with spare after the screen to filtrate;
(3) it configures electric heating slurry: weighing 100 parts of polyimide varnish, the conductive paste masterbatch prepared in step (2) by weight 50 parts, under normal temperature conditions, be placed in dispersion machine and disperse 60min, rate of dispersion 1500rpm, and with diluent adjust viscosity to 300mPa.s, with obtaining electrothermal coating slurry after the screen to filtrate;
(4) it is coated with: by the slurry coater prepared in step (3) on glass-fiber-fabric, be tentatively crosslinked in an oven, Solidification;
(5) by step (4) prepare film be placed in Muffle furnace, be sintered 120min, 400 DEG C of sintering temperature;
(6) sheet material that the electrothermal film material prepared in step (5) cuts into demand size is obtained in both sides adhesive electrode To electric heating film base material;
Two, Electric radiant Heating Film is prepared:
It (7), will be through step (7) treated each compound one layer of insulating film of Electric radiant Heating Film sheet material tow sides on laminating machine;
(8) conducting wire is connected on the membrane electrode after laminating, and far-infrared electrothermal film is obtained after insulation.
Wherein, aquadag powder diameter≤10 μm, conductive black powder diameter≤10 μm, aluminium oxide powder partial size≤ 100μm;The diluent is dimethyl acetamide;The glass-fiber-fabric is the glass-fiber-fabric of thickness 0.06mm;The electrode is metal Foil belt;The insulating film is polyester film.
Embodiment 3
A kind of preparation method of new far infrared electric heating film, comprising the following steps:
One, the preparation of electric heating film base material:
(1) it makes conductive filler: weighing 50 parts of aquadag powder by weight, 50 parts of conductive black powder, the three of 5 parts Al 2 O powder is placed in powder mixer spare, mixing velocity 60rpm after mixing 5h under normal temperature conditions;
(2) it makes conductive paste masterbatch: weighing 20 parts of powder prepared in step (1), dimethyl acetamide 80 by weight Part, mixed grinding 80min under normal temperature condition, grinding rate 1200rpm in grinder, with spare after the screen to filtrate;
(3) it configures electric heating slurry: weighing 75 parts of polyimide varnish, the conductive paste masterbatch prepared in step (2) by weight 20 parts, under normal temperature conditions, be placed in dispersion machine and disperse 45min, rate of dispersion 1400rpm, and with diluent adjust viscosity to 200mPa.s, with obtaining electrothermal coating slurry after the screen to filtrate;
(4) it is coated with: by the slurry coater prepared in step (3) on glass-fiber-fabric, be tentatively crosslinked in an oven, Solidification;
(5) by step (4) prepare film be placed in Muffle furnace, be sintered 90min, 300 DEG C of sintering temperature;
(6) sheet material that the electrothermal film material prepared in step (5) cuts into demand size is obtained in two sides adhesive electrode To electric heating film base material;
Two, Electric radiant Heating Film is prepared:
It (7), will treated that Electric radiant Heating Film sheet material tow sides respectively press a layer insulating through step (7) on laminating machine;
(8) conducting wire is connected on the membrane electrode after laminating, and far-infrared electrothermal film is obtained after insulation.
Wherein, aquadag powder diameter≤10 μm, conductive black powder diameter≤10 μm, aluminium oxide powder partial size≤ 100μm;The diluent is dimethyl acetamide;The glass-fiber-fabric is the glass-fiber-fabric of thickness 0.09mm;The electrode is conduction Cloth rubber belt;The insulating film is acetate fabric adhesive tape.
Outstanding feature of the invention is as follows:
1) entire film surface fever, do not generate heat gap, coating uniform, and the film surface temperature difference is small;
2) electric heating slurry entirety penetrating substrate, is formed together whole heater with substrate after solidification, do not generate cracking and take off It falls;
3) electric heating element is non-metal base thermo electric material, and non-oxidation is reacted when use, will not be shortened the working life because of oxidation, is tried It tests the result service life > 100,000 hours;
4) wholesome far infrared, experimental result: 4-20 μm of radiation wavelength, 8-10 μm of peak value are generated;
5) through testing: electric conversion efficiency >=95% reaches 99% in portion voltage;
6) the precious metal materials such as argentiferous, palladium, the equal simplicity of all material are not easy to get, simple process and low cost.
Far infrared electric heating film provided by the invention is using micron order graphite powder, conductive black powder and macromolecule resin etc. Material cladding forms.The material takes full advantage of excellent electric property, high-termal conductivity and the high-fire resistance that carbon composite has, And the structural stability of high molecular material, workability.The Far infrared electric heating film of preparation, high with electric conversion efficiency, Fever is uniformly and substrate bond strength is high, the service life is long, generates the advantages that far infrared beneficial to human body, and simple process, cost It is cheap, it is suitble to large-scale continuous production.
The above are merely the preferred embodiment of the present invention, it is noted that for those skilled in the art, not Under the premise of being detached from present inventive concept, several modifications and improvements can also be made, these also should be considered as protection model of the invention It encloses, these all will not influence the effect and patent practicability that the present invention is implemented.

Claims (8)

1. a kind of preparation method of new far infrared electric heating film, which comprises the following steps:
(1) it makes conductive filler: weighing 30-70 parts of aquadag powder, 30-70 parts of conductive black powder, 2-10 by weight The aluminium oxide powder of part is placed in powder mixer spare after mixing 4-6h;
(2) it makes conductive paste masterbatch: weighing 10-30 parts of powder prepared in step (1), dimethyl acetamide 40- by weight It is 90 parts, the mixed grinding 60-120min in grinder, spare after filtering;
(3) it configures electric heating slurry: weighing 50-100 parts of polyimide varnish, the conductive paste masterbatch prepared in step (2) by weight It 20-50 parts, is placed in dispersion machine and disperses 30-60min, and adjust viscosity to 120-300mPa.s with diluent, obtained after filtering Electrothermal coating slurry;
(4) it is coated with: preliminary in an oven to be crosslinked, is solid by the slurry coater prepared in step (3) on glass-fiber-fabric Change;
(5) film prepared by step (4) is placed in high temperature oven and is sintered;
(6) sheet material that the electrothermal film material prepared in step (5) is cut into demand size, in both sides or two sides connection electrode, Obtain Electric radiant Heating Film substrate;
(7) the electric heating film base material tow sides of preparation are respectively coated into one layer of thermally conductive bonded adhesives;
It (8), will be through step (7) treated each compound layer insulating of Electric radiant Heating Film sheet material tow sides on laminating machine;
(9) conducting wire is connected on the membrane electrode after laminating, and far-infrared electrothermal film is obtained after insulation.
2. the preparation method of new far infrared electric heating film according to claim 1, which is characterized in that in step (1), Aquadag powder diameter≤10 μm, conductive black powder diameter≤10 μm, aluminium oxide powder partial size≤100 μm.
3. the preparation method of new far infrared electric heating film according to claim 1 or 2, which is characterized in that in step (3) In, the diluent is dimethyl acetamide or dimethylbenzene.
4. the preparation method of new far infrared electric heating film according to claim 3, which is characterized in that in step (4), The glass-fiber-fabric is the glass-fiber-fabric of thickness 0.06-0.15mm.
5. the preparation method of new far infrared electric heating film according to claim 4, which is characterized in that in step (5), The film of preparation, which is placed in Muffle furnace, to be sintered, sintering time 60-120min, and 300-400 DEG C of sintering temperature.
6. the preparation method of new far infrared electric heating film according to claim 5, which is characterized in that in step (6), The electrode can be connected on sheet material stickup, brushing or by way of interting.
7. the preparation method of new far infrared electric heating film according to claim 6, which is characterized in that in step (6), The electrode is metal foil, metal foil belt, electricity conductive cloth tape, any one in conductive silver paste.
8. the preparation method of new far infrared electric heating film according to claim 7, which is characterized in that in step (8), The insulating film is in teflon insulation film, PA membrane, polyester film, mica sheet, acetate fabric adhesive tape, epoxy plate etc. One or more of combinations.
CN201910523245.5A 2019-06-17 2019-06-17 A kind of preparation method of new far infrared electric heating film Pending CN110167215A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110798922A (en) * 2019-11-13 2020-02-14 苏州苏绝电工材料股份有限公司 Conductive film and preparation method thereof, and heatable mica tube and manufacturing method thereof
CN111698797A (en) * 2019-09-06 2020-09-22 宁波晨中热膜科技有限公司 Preparation method of far infrared electric heating film
CN115257208A (en) * 2021-12-29 2022-11-01 山东华滋自动化技术股份有限公司 Method and device for manufacturing low-temperature electrothermal film

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101873729B (en) * 2010-06-07 2012-01-04 刘忠耀 Electric heating film and preparation method thereof
CN102821495A (en) * 2012-08-17 2012-12-12 慈溪市圣唯诺电器有限公司 Polytetrafluoroethylene (PTFE) base electrothermal thick film and manufacturing method thereof
CN102932974B (en) * 2012-11-20 2014-10-15 叶么华 Method for preparing polymer electrothermal film
KR20190058794A (en) * 2017-11-22 2019-05-30 전자부품연구원 Toner fused metal plate heater and fusing belt using the same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101873729B (en) * 2010-06-07 2012-01-04 刘忠耀 Electric heating film and preparation method thereof
CN102821495A (en) * 2012-08-17 2012-12-12 慈溪市圣唯诺电器有限公司 Polytetrafluoroethylene (PTFE) base electrothermal thick film and manufacturing method thereof
CN102932974B (en) * 2012-11-20 2014-10-15 叶么华 Method for preparing polymer electrothermal film
KR20190058794A (en) * 2017-11-22 2019-05-30 전자부품연구원 Toner fused metal plate heater and fusing belt using the same

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111698797A (en) * 2019-09-06 2020-09-22 宁波晨中热膜科技有限公司 Preparation method of far infrared electric heating film
CN111698797B (en) * 2019-09-06 2021-07-13 宁波晨中热膜科技有限公司 Preparation method of far infrared electric heating film
CN110798922A (en) * 2019-11-13 2020-02-14 苏州苏绝电工材料股份有限公司 Conductive film and preparation method thereof, and heatable mica tube and manufacturing method thereof
CN115257208A (en) * 2021-12-29 2022-11-01 山东华滋自动化技术股份有限公司 Method and device for manufacturing low-temperature electrothermal film
CN115257208B (en) * 2021-12-29 2023-12-05 山东华滋自动化技术股份有限公司 Manufacturing method and manufacturing device of low-temperature electrothermal film

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Application publication date: 20190823

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