CN110130123A - The preparation process of high-performance antimildew and antibacterial gelsemium cotton - Google Patents
The preparation process of high-performance antimildew and antibacterial gelsemium cotton Download PDFInfo
- Publication number
- CN110130123A CN110130123A CN201910320757.1A CN201910320757A CN110130123A CN 110130123 A CN110130123 A CN 110130123A CN 201910320757 A CN201910320757 A CN 201910320757A CN 110130123 A CN110130123 A CN 110130123A
- Authority
- CN
- China
- Prior art keywords
- cotton
- dye yam
- gelsemium
- juice
- performance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/06—After-treatment with organic compounds containing nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/10—After-treatment with compounds containing metal
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Abstract
The present invention relates to the preparation processes of high-performance antimildew and antibacterial gelsemium cotton, comprising the following steps: cotton is spare with natural air drying after aqueous slkali soaking 2 hours；The mould inhibitor that weight percent is 1% is added in aqueous slkali；Step 1: cotton fabric impregnates dye yam juice, pulls out and dry after soaking completely；Step 2: being dried after drying, uniform sprinkle dye yam juice；After cotton fabric dries, then sprinkle dye yam juice, it smoothens and dries, repeat 5-10 times；It is impregnated Step 3: cotton fabric is put into dye yam juice, circulation step one and step 2, until the ember of dye yam juice is presented in weaved cotton cloth completely；Step 4: the pond sludge chosen is diluted with water to mud, shading is equably painted on the positive mordant dyeing of cotton fabric, stands after the completion of brushing；Step 5: cotton fabric is put into lye wash clean, continuous exposure 4-7 days after immersion；Step 6: cotton fabric obtained in step 5 is placed in immersion trough dipping dye yam juice, dipping dries naturally after 3-5 hours, obtains gelsemium cotton.
Description
Technical field
The present invention relates to the technical fields of textile material, more particularly, to the preparation process of high-performance antimildew and antibacterial gelsemium cotton.
Background technique
Gambiered Guangdong silk is also known as gambiered Guangdong gauze, mainly using domestic silkworm silk as raw material, through spinning, weave etc. process flows woven into fabric with
Afterwards, with a kind of distinctive plant -- after the stem tuber juice of dye yam is repeatedly impregnated, dried, fabric is made to adhere to one layer of yellowish-brown
Jelly, then it is evenly applied to fabric surface with the pond sludge containing ferric ion, front is made after repeated multiple times sunning, washing
The fabric of black, bottom surface coffee color.Entire dyeing and finishing process is manual operations, because the complexity of process it is cumbersome with it is unique, allow gambiered Guangdong silk
With unique color, texture, and there are the performances such as nice and cool, sweat proof, easy to wash, sun-proof, antibacterial, obtain designers and
Garment enterprise more widely uses.Inherently a kind of Chinese medicine of dye yam, there is mould proof, degerming, deodorization and other effects, so in the industry one
As think that also there is phase to post-processing the clothes that are made by metal ion again after silk fabric dyeing weight gain with dye yam extracting solution
Same " medical " effect (influence of the metal ion to dye yam extracting solution processing real silk fabric, Ye Haohua, Tang Xiaoming, Chen Guoqiang, dye
Adjusting technique, 2009,31 (4): 1-6).
But existing gambiered Guangdong silk product, because using silk as raw material, and due to the distinctive dyeing and finishing technology of gambiered Guangdong silk, so that product
It is relatively simple.For example the performances such as cotton absorbing sweat, heat resistanceheat resistant are good and comfortable and easy to wear, but cotton is easy mildew, especially directly uses
The preparation process of gambiered Guangdong silk is easy to go mouldy to prepare, and the cloth after mildew cannot be made into clothes to application on human skin nocuousness.
Summary of the invention
The purpose of the present invention one is to provide a kind of preparation process of high-performance antimildew and antibacterial gelsemium cotton, is contaminated with potato gelsemium to cotton
Whole, dyeing effect is good, it is not easy to decolourize.
The purpose of the present invention one has the technical scheme that a kind of system of high-performance antimildew and antibacterial gelsemium cotton
Standby technique, comprising the following steps:
Pre-processing: cotton is spare with natural air drying after aqueous slkali soaking 2 hours；Wherein aqueous slkali is that the sodium chloride of 1mol/L is molten
Liquid, and the mould inhibitor that weight percent is 1% is added in aqueous slkali；
Step 1: cotton fabric is placed in immersion trough dipping dye yam juice, naturally dry is pulled out after soaking completely, is subject to fall liquid pearl；
It is dried, and uniformly sprinkle dye yam juice, and is smeared uniform Step 2: being laid flat after drying；After equal cotton fabrics dry, then
Secondary sprinkle dye yam juice, smoothens and dries, and repeats 5-10 times；
It is impregnated Step 3: cotton fabric obtained in step 2 is put into dye yam juice, circulation step one and step 2, Zhi Daomian
Woven fabric shows the ember of dye yam juice completely；
Step 4: the front for being equably painted on cotton fabric carries out mordant dyeing after the pond sludge chosen is diluted with water to mud, brush
Shading carries out in the process, stands 2-3h after the completion of brushing；
Step 5: cotton fabric obtained in step 4 is put into lye wash clean after immersion 1-2h, exposure in the sunlight is placed,
Continuous exposure 4-7 days, cotton fabric became brown from light red；
Step 6: cotton fabric obtained in step 5 is placed in immersion trough dipping dye yam juice solution, dipping shines naturally after 3-5 hours
It is dry, obtain gelsemium cotton.
By using above-mentioned technical proposal, cotton can play good tint retention after dipping by lye, can also remove
The impurity such as the dust of cotton surface；Mould inhibitor is added in lye, the cotton fungicidal properties after dipping by lye is fine.It air-dries, refers to
It is placed on shady and cool place, makes wind dry, natural air drying after cotton is soaking can be dried faster, place into dye yam juice and soak
Stain can preferably dye also be not easy it is mouldy；It is dried after impregnating dye yam juice, sunlight has good bactericidal effect, and cotton is more
It is not easy to go mouldy；And cotton is more preferable by disseminating repeatedly and drying dyeing effect, later period also more difficult decoloration.Under shading,
The black coloring material that chemical reaction generation occurs for the tannin in Fe and dye yam juice in pond sludge is only attached to fabric and crosses pond sludge
On one side, the another side of fabric will not be penetrated into, i.e. the one side of pond sludge covering is in black, brown, and another side is then shallower reddish brown
It is red.
Step 5 directly can play good fixation and bactericidal effect with dipping by lye, and cotton fabric is through daylight after wash clean
Exposure further promotes reaction and sterilization.It is finally impregnated, is further dyed again.
Gelsemium cotton by preparation process of the invention is not easy mouldy, there is the effect of mould proof, degerming, deodorization, and
Do not allow to crease easily, anti-ultraviolet property is also more preferable；The performances such as cotton absorbing sweat, heat resistanceheat resistant are maintained, are worn also more comfortable.This
Outside, cotton goods decoloration phenomenon is good using the gelsemium cotton colour fixation of preparation process of the invention, it is not easy to change colour than more serious
Or staining.
The present invention is further arranged to: being equipped with water barrier in step 2 below cotton fabric, each sprinkle dye yam juice makes potato
Liang juice is impregnated with cotton fabric completely, and environment temperature is 30-35 DEG C.
By using above-mentioned technical proposal, water barrier can prevent dye yam juice is cracking to flow away, and keep cotton fabric more preferable
Absorption dye yam juice, dyeing effect is more preferable.Dyeing effect is more preferable when discovery environment temperature is 30-35 DEG C after tested, and does not allow
Easily the performance of cotton itself is impacted.
The present invention is further arranged to: the dye yam juice in step 1 is filtering gained after dye yam peeling juicing.
By using above-mentioned technical proposal, the concentration of dye yam juice is high, it is not easy to there is concentration difference, dyeing effect is more preferable, and
Dye yam juice is not allowed perishable.
The present invention is further arranged to: aldehyde-free colour stabilizer is added in dye yam juice, aldehyde-free colour stabilizer is that quaternary ammonium salt is solid without aldehyde
Toner or sodium chloride or potassium chloride.
By using above-mentioned technical proposal, aldehyde-free colour stabilizer is not only environmentally friendly but also the Anti-fade performance of gelsemium cotton can be improved.
The present invention is further arranged to: in step 4 brushing pond sludge with a thickness of 0.5-1cm, environment temperature in painting process
It is 20-25 DEG C, environment temperature is 25-30 DEG C during standing after the completion of brushing.
By using above-mentioned technical proposal, the thickness reaction that pond sludge reaches certain is more abundant, and the blocked up effect promoting of pond sludge is not
Obviously, and it will increase workload；Temperature is lower in painting process, and the tannin in pond sludge and dye yam juice reacts slow, this hair
Reaction is concentrated after the completion of bright middle brushing, more evenly, more evenly, Liang cotton quality is higher for dyeing for reaction.
The present invention is further arranged to: the temperature of lye is 30-35 DEG C in step 5.
By using above-mentioned technical proposal, the temperature of lye is higher, further reacts conducive to pond sludge and dye yam juice, and
It is more preferable to sterilize colour fixation.
The present invention is further arranged to: the weight percent of water is 70%-85% in the dye yam juice solution in step 6.
By using above-mentioned technical proposal, step 6 is mainly the complementary stain and cleaning to cotton fabric, and dye yam juice is not necessarily to
Excessive concentration, cleaning effect are more preferable.
The present invention is further arranged to: softener is added in the dye yam juice solution in step 6, it is soft in dye yam juice solution
Soft dose of weight percent is 3%.
By using above-mentioned technical proposal, cotton is easy corrugation, and softener is added in dye yam juice solution can play very
Good crease-resistant effect.
The present invention is further arranged to: further including Step 7: cotton goods obtained in step 6 are put into lemonade water
Impregnate 5-6h, naturally dry；Wherein the mass percent of lemon juice is 5%-10% in lemonade.
By using above-mentioned technical proposal, lemonade can play the role of further fungus and mildew resistance to cotton fabric, be promoted
The fungicidal properties of gelsemium cotton.
In conclusion advantageous effects of the invention are as follows:
1. cotton can play good tint retention after dipping by lye, the impurity such as the dust of cotton surface can be also removed；Alkali
Mould inhibitor is added in liquid, the cotton fungicidal properties after dipping by lye is fine.It air-dries, refers to and be placed on shady and cool place, make wind dry,
Natural air drying after cotton is soaking, can dry faster, place into dye yam juice dipping and can preferably dye and be also not easy
It is mouldy；It is dried after impregnating dye yam juice, sunlight has good bactericidal effect, the more difficult mildew of cotton；And cotton passes through
It disseminates repeatedly and more preferable, later period also more difficult decoloration of drying dyeing effect.The list in Fe and dye yam juice under shading, in pond sludge
The peaceful black coloring material that chemical reaction generation occurs is only attached to the one side that fabric crosses pond sludge, will not penetrate into the another of fabric
The one side of face, i.e. pond sludge covering is in black, brown, and another side is then shallower ember.Step 5 directly uses dipping by lye
Good fixation and bactericidal effect can be played, cotton fabric further promotes reaction and sterilization through being exposed to sunlight after wash clean.Most
It is impregnated, is further dyed again afterwards.Gelsemium cotton by preparation process of the invention be not easy it is mouldy, have mould proof, degerming,
The effect of deodorization, and do not allow to crease easily, anti-ultraviolet property is also more preferable；The performances such as cotton absorbing sweat, heat resistanceheat resistant are maintained, are worn
It is also more comfortable.In addition, cotton goods decolourize, phenomenon uses the gelsemium cotton colour fixation of preparation process of the invention than more serious
It is good, it is not easy to discoloration or staining.
2. water barrier can prevent dye yam juice is cracking to flow away, cotton fabric is enable preferably to absorb dye yam juice, dyeing effect
Fruit is more preferable.Dyeing effect is more preferable when discovery environment temperature is 30-35 DEG C after tested, and is not easy to make the performance of cotton itself
At influence.
3. the thickness reaction that pond sludge reaches certain is more abundant, the blocked up effect promoting of pond sludge is unobvious, and will increase workload；
Temperature is lower in painting process, and the tannin reaction in pond sludge and dye yam juice is slow, concentrates after the completion of brushing in the present invention anti-
It answers, more evenly, more evenly, Liang cotton quality is higher for dyeing for reaction.
Specific embodiment
Below in conjunction with table and embodiment, invention is further described in detail.
The preparation process of high-performance antimildew and antibacterial gelsemium cotton, comprising the following steps:
Pre-processing: dye yam cleans peeling juicing, spare after filtering；Cotton is spare with natural air drying after aqueous slkali soaking 2 hours；
Wherein aqueous slkali is the sodium chloride solution of 1mol/L, and the mould inhibitor that weight percent is 1% is added in aqueous slkali, mould inhibitor choosing
The ribbon mould inhibitor DR-0067 sold with Dongguan City a century grand plan Chemical Industry Science Co., Ltd.
Step 1: cotton fabric is placed in immersion trough dipping dye yam juice, naturally dry is pulled out after soaking completely, is not fall liquid pearl
It is quasi-；It is dried, and uniformly sprinkle dye yam juice, and is smeared uniform Step 2: being laid flat after drying；After equal cotton fabrics dry, then
Secondary sprinkle dye yam juice, smoothens and dries, and repeats n times；Each sprinkle dye yam juice makes dye yam juice be impregnated with cotton fabric, environment completely
Temperature is T1.
It is impregnated Step 3: cotton fabric obtained in step 2 is put into dye yam juice, circulation step one and step 2, directly
Show the ember of dye yam juice completely to weaved cotton cloth；
Step 4: the front for being equably painted on cotton fabric with brush carries out matchmaker after the pond sludge chosen is diluted with water to mud
It contaminates, shading carries out in painting process, stands after the completion of brushing, time of repose t1；Brushing pond sludge with a thickness of d, painting process
Middle environment temperature is T2, and environment temperature is T3 during standing after the completion of brushing；
Step 5: cotton fabric obtained in step 4 is put into lye wash clean after immersion t2, exposure in the sunlight is placed, even
Continuous exposure t3, cotton fabric become brown from light red；The temperature of lye is T4；
It dries, obtains naturally after impregnating t4 Step 6: cotton fabric obtained in step 5 is placed in immersion trough dipping dye yam juice solution
To gelsemium cotton；The weight percent of water is 80% in dye yam juice solution.
The following table 1 is the specific value of each parameter in embodiment 1-3 and comparative example 1-6 in preparation process；Cotton fabric at
Divide and weight ratio is cotton 87%, fiber crops 13%, grammes per square metre is 69 grams/m.
The specific value of each parameter in 1 embodiment 1-3 of table and comparative example 1-5 preparation process
| N/ times | T1/℃ | t1/h | d/cm | T2/℃ | T3/℃ | t2/h | T3/ days | T4/℃ | t4/h | |
| Embodiment 1 | 5 | 35 | 2 | 0.5 | 25 | 30 | 1 | 4 | 35 | 5 |
| Embodiment 2 | 8 | 33 | 2 | 0.8 | 22 | 28 | 1.5 | 5 | 33 | 4 |
| Embodiment 3 | 10 | 30 | 3 | 1 | 20 | 25 | 2 | 7 | 30 | 3 |
| Comparative example 1 | 3 | 40 | 2 | 0.8 | 22 | 28 | 1.5 | 5 | 33 | 4 |
| Comparative example 2 | 8 | 33 | 1 | 0.8 | 22 | 28 | 1.5 | 5 | 33 | 4 |
| Comparative example 3 | 8 | 33 | 2 | 0.8 | 22 | 22 | 1.5 | 5 | 33 | 4 |
| Comparative example 4 | 8 | 33 | 2 | 0.8 | 22 | 28 | 0 | 5 | 33 | 4 |
| Comparative example 5 | 8 | 33 | 2 | 0.8 | 22 | 28 | 1.5 | 5 | 33 | 0 |
Comparative example 6
The preparation process of high-performance antimildew and antibacterial gelsemium cotton, comparative example 6 is with embodiment 2 the difference is that comparative example 6 is without early period
The step of processing.
Embodiment 1-3 and comparative example 1-5 the gelsemium cotton handled are tested for the property, specific test item and test
Standard see the table below 2.According to the test method of table 2, the performance for the cotton fabric that embodiment 1-3 and comparative example 1-6 are handled is shown in
The following table 3.
2 test item of table and testing standard
The performance test table for the gelsemium cotton that table 3 embodiment 1-3 and comparative example 1-6 is handled
It can be seen that, the crocking resistance of embodiment 1-3, perspiration resistance performance and water resistance are all fine, and fabric is torn from table 2-3
Broken strength has also reached corresponding standard, especially embodiment 2 and embodiment 3, wet to rub index and perspiration resistance, water resistance all
The requirement of Grade A is reached；The duplicate number of comparative example 1 is few, therefore environment temperature wants relatively high, but in this way dye yam juice with
The reaction time of cotton fabric is relatively short, and perspiration resistance performance is just poor, and discoloration index is unqualified；Water resistance also under
Drop, the decline of fabric tearing brute force.Fe ion is short compared with cotton fabric haptoreaction in 2 pond sludge of comparative example, and color is not deep enough, sweat proof
Stain and water resistance are also declined；Environment temperature does not increase after comparative example 3 has brushed pond sludge, Fe ion and cotton fabric in pond sludge
Haptoreaction is not enough, and color is not deep enough, and the discoloration index in perspiration resistance performance also has decline；Fe in pond sludge in comparative example 4
Ion and cotton fabric unused dipping by lye after the reaction was completed, colour fixation is not good enough, and the discoloration index in perspiration resistance performance does not conform to
Lattice, the discoloration index in water resistance are also unqualified；It is not impregnated again with dye yam juice solution after dipping by lye in comparative example 5, it is above-mentioned
Detection performance has no significant change；Pre-processing is not done in comparative example 6, perspiration resistance performance is unqualified, the discoloration index in performance
Also unqualified.
It is 90% that embodiment 1-3 and comparative example 1-6 the gelsemium cotton handled, which are placed on relative humidity, and temperature is 30 DEG C
It is placed 10 days in environment, observes the mouldy situation of gelsemium cotton.The gelsemium cotton that wherein embodiment 1-3 is handled does not occur mouldy feelings
Condition, the gelsemium cotton that the processing of comparative example 1 obtains have mildew at 5-10, and the gelsemium cotton that the processing of comparative example 2 obtains has mildew at 5-10；Comparative example
The gelsemium cotton that 3 processing obtain has mildew at 3-5；The gelsemium cotton that the processing of comparative example 4 obtains has mildew at 15-20；Comparative example 5 is handled
To gelsemium cotton have mildew at 3-5；There is the mildew of large area in comparative example 6.It can be seen that preparation process of the invention can be fine
Improvement gelsemium cotton be easy mouldy problem.
Embodiment 4
The preparation process of high-performance antimildew and antibacterial gelsemium cotton, embodiment 4 and embodiment 2 are the difference is that dye yam in step 1
Aldehyde-free colour stabilizer is added in juice, aldehyde-free colour stabilizer is quaternary ammonium salt aldehyde-free colour stabilizer, the specially limited public affairs of Qingyuan City fine horse space chemical industry
Take charge of the high fastness aldehyde-free colour stabilizer JYB215 of sale.The weight percent of quaternary ammonium salt aldehyde-free colour stabilizer is 2%.
Embodiment 5
The preparation process of high-performance antimildew and antibacterial gelsemium cotton, embodiment 5 and embodiment 4 are the difference is that dye yam in step 6
Softener is added in juice solution, the weight percent of softening agent is 3% in dye yam juice solution.
Embodiment 6
The preparation process of high-performance antimildew and antibacterial gelsemium cotton, embodiment 6 and embodiment 5 the difference is that further include Step 7:
Gelsemium cotton obtained in step 6 is put into lemonade water and impregnates 5h, naturally dry；Wherein in lemonade lemon juice quality hundred
Divide than being 8%.
Embodiment 7
After the preparation process of high-performance antimildew and antibacterial gelsemium cotton, embodiment 7 and embodiment 6 in step 1 the difference is that soak
Cotton fabric pull out after dried up with blowing device, and adjust wind temperature be 25 DEG C.Cotton fabric is placed on sprinkle slot in step 2
Interior, sprinkle groove groove wall is equipped with water barrier.
The gelsemium cotton that embodiment 4-7 is handled is tested for the property, with embodiment 2, test result is shown in Table test method
4。
The performance test table for the gelsemium cotton that 4 embodiment 4-7 of table is handled
As can be seen from the above table, quaternary ammonium salt aldehyde-free colour stabilizer is added in the preparation process of embodiment 4 in dye yam juice, it can be obvious
Improve the water resistance of gelsemium cotton；Further addition softener, the unlubricated friction index of crocking resistance are more preferable for embodiment 5；In embodiment 6
After gelsemium cotton is impregnated with lemonade, gelsemium cotton perspiration resistance performance is also significantly improved, and reaches the requirement of high-class product.The preparation work of embodiment 7
Artistic skill enough greatly shortens preparation time, and product qualified rate is higher in preparation process, and sprinkle slot can guarantee that cotton fabric more fills
The long-time divided absorbs dye yam juice, and dye yam juice is also not easy to waste.
The present invention also carries out mouldy situation test, test method used in test method and embodiment 2 to embodiment 4-7
Identical, the gelsemium cotton that embodiment 4-7 is handled does not occur mildew；And the gelsemium cotton wrinkle resistance that embodiment 5-7 is handled
Also it greatly improves.
The application is also tested the absorbing sweat of gelsemium cotton, heat resistanceheat resistant, permeability simultaneously, inhales relative to untreated cotton
Sweat, heat resistanceheat resistant, permeability are without being substantially reduced.
The safety of cloth is also very important index.The present invention also carries out gelsemium cotton cloth made from embodiment 1-7
The detection of content of formaldehyde test and decomposable carcinogenic aromatic amine dyestuff, it is specific test results in the following table:
| Content of formaldehyde (mg/kg) (FZ/T81007-2012) | Decomposable carcinogenic aromatic amine dyestuff (FZ/T81007-2012) | |
| Embodiment 1 | (method detection is limited to 20) is not detected | It is not detected |
| Embodiment 2 | (method detection is limited to 20) is not detected | It is not detected |
| Embodiment 3 | (method detection is limited to 20) is not detected | It is not detected |
| Embodiment 4 | (method detection is limited to 20) is not detected | It is not detected |
| Embodiment 5 | (method detection is limited to 20) is not detected | It is not detected |
| Embodiment 6 | (method detection is limited to 20) is not detected | It is not detected |
| Embodiment 7 | (method detection is limited to 20) is not detected | It is not detected |
Detection method standard and standard requirements see the table below:
| Detection project | Method standard | Standard requirements |
| Content of formaldehyde (mg/kg) (FZ/T81007-2012) | GB/T2912.1-2009 | B class :≤75 |
| Decomposable carcinogenic aromatic amine dyestuff (FZ/T81007-2012) | GB/T17592-2011 | It disables (Limited Doses≤20mg/kg) |
Carcinogenic aromatic amine inventory is as follows:
| Number | Chemical abstracts number | Chinese |
| 1 | 92-67-1 | 4- aminobphenyl |
| 2 | 92-87-5 | Benzidine |
| 3 | 95-69-2 | The chloro- ortho-aminotoluene of 4- |
| 4 | 91-59-8 | 2- naphthylamines |
| 5 | 97-56-3 | O-aminoazotoluene |
| 6 | 99-55-8 | 5- nitro-o-toluidine |
| 7 | 106-47-8 | Parachloroanilinum |
| 8 | 615-05-4 | 2,4- diamino anisole |
| 9 | 101-77-9 | 4,4'- diaminodiphenylmethane |
| 10 | 91-94-1 | 3,3'- dichloro-benzidine |
| 11 | 119-90-4 | 3,3'- dimethoxy benzidine |
| 12 | 119-93-7 | 3,3'- dimethylbenzidine |
| 13 | 838-88-0 | 3,3'- dimethyl -4,4'- diaminodiphenylmethane |
| 14 | 120-71-8 | 2- methoxyl group -5- methylaniline |
| 15 | 101-14-4 | 4,4'- methylene-two-(2- chlordiphenyl amine) |
| 16 | 101-80-4 | 4,4'- diamino dipropyl ether |
| 17 | 139-65-1 | 4,4'- diaminodiphenyl sulfide |
| 18 | 95-53-4 | Ortho-aminotoluene |
| 19 | 95-80-7 | 2,4 di amino toluene |
| 20 | 137-17-7 | 2,4,5- trimethylaniline |
| 21 | 90-04-0 | O-aminoanisole |
| 22 | 60-09-3 | 4- aminoazabenzol |
| 23 | 95-68-1 | 2,4- dimethylaniline |
It should be apparent that gelsemium cotton produced by the present invention without formaldehyde by above three table, being also free of can decompose carcinogenic virtue
Fragrant amine dyestuff, will not endanger health of human body.
The present invention also has detected gelsemium cotton pH value made from embodiment 7, detection method according to GB/T7573-2009, according to
The regulation of GB/T7573-2009, the standard requirements of B class cloth are pH=4.0~8.5, and gelsemium cotton pH value made from embodiment 7 is
5.1, wherein spe medium is Klorvess Liquid, also complies with regulation.
The embodiment of present embodiment is presently preferred embodiments of the present invention, not limits protection of the invention according to this
Range, therefore: the equivalence changes that all structures under this invention, shape, principle are done, should all be covered by protection scope of the present invention it
It is interior.
Claims (9)
1. a kind of preparation process of high-performance antimildew and antibacterial gelsemium cotton, characterized in that the following steps are included:
Pre-processing: cotton is spare with natural air drying after aqueous slkali soaking 2 hours；Wherein aqueous slkali is that the sodium chloride of 1mol/L is molten
Liquid, and the mould inhibitor that weight percent is 1% is added in aqueous slkali；
Step 1: cotton fabric is placed in immersion trough dipping dye yam juice, naturally dry is pulled out after soaking completely, is subject to fall liquid pearl；
It is dried, and uniformly sprinkle dye yam juice, and is smeared uniform Step 2: being laid flat after drying；After equal cotton fabrics dry, then
Secondary sprinkle dye yam juice, smoothens and dries, and repeats 5-10 times；
It is impregnated Step 3: cotton fabric obtained in step 2 is put into dye yam juice, circulation step one and step 2, Zhi Daomian
Woven fabric shows the ember of dye yam juice completely；
Step 4: the front for being equably painted on cotton fabric carries out mordant dyeing after the pond sludge chosen is diluted with water to mud, brush
Shading carries out in the process, stands 2-3h after the completion of brushing；
Step 5: cotton fabric obtained in step 4 is put into lye wash clean after immersion 1-2h, exposure in the sunlight is placed,
Continuous exposure 4-7 days, cotton fabric became brown from light red；
Step 6: cotton fabric obtained in step 5 is placed in immersion trough dipping dye yam juice solution, dipping shines naturally after 3-5 hours
It is dry, obtain gelsemium cotton.
2. the preparation process of high-performance antimildew and antibacterial gelsemium cotton according to claim 1, characterized in that cotton fabric in step 2
Lower section is equipped with water barrier, and each sprinkle dye yam juice makes dye yam juice be impregnated with cotton fabric completely, and environment temperature is 30-35 DEG C.
3. the preparation process of high-performance antimildew and antibacterial gelsemium cotton according to claim 1, characterized in that the dye yam in step 1
Juice is filtering gained after dye yam peeling juicing.
4. the preparation process of high-performance antimildew and antibacterial gelsemium cotton according to claim 3, characterized in that be added in dye yam juice
Aldehyde-free colour stabilizer, aldehyde-free colour stabilizer are quaternary ammonium salt aldehyde-free colour stabilizer or sodium chloride or potassium chloride.
5. the preparation process of high-performance antimildew and antibacterial gelsemium cotton according to claim 1, characterized in that brush the pool in step 4
Mud with a thickness of 0.5-1cm, environment temperature is 20-25 DEG C in painting process, and environment temperature is during standing after the completion of brushing
25-30℃。
6. the preparation process of high-performance antimildew and antibacterial gelsemium cotton according to claim 1, characterized in that lye in step 5
Temperature is 30-35 DEG C.
7. the preparation process of high-performance antimildew and antibacterial gelsemium cotton according to claim 1, in the dye yam juice solution in step 6
The weight percent of water is 70%-85%.
8. the preparation process of high-performance antimildew and antibacterial gelsemium cotton according to claim 7, characterized in that the dye yam in step 6
Softener is added in juice solution, the weight percent of softening agent is 3% in dye yam juice solution.
9. the preparation process of high-performance antimildew and antibacterial gelsemium cotton according to claim 1, characterized in that further include Step 7:
Cotton goods obtained in step 6 are put into lemonade water and impregnate 5-6h, naturally dry；Wherein in lemonade lemon juice matter
Amount percentage is 5%-10%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910320757.1A CN110130123A (en) | 2019-04-20 | 2019-04-20 | The preparation process of high-performance antimildew and antibacterial gelsemium cotton |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910320757.1A CN110130123A (en) | 2019-04-20 | 2019-04-20 | The preparation process of high-performance antimildew and antibacterial gelsemium cotton |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110130123A true CN110130123A (en) | 2019-08-16 |
Family
ID=67570501
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910320757.1A Pending CN110130123A (en) | 2019-04-20 | 2019-04-20 | The preparation process of high-performance antimildew and antibacterial gelsemium cotton |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110130123A (en) |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101046069A (en) * | 2007-03-29 | 2007-10-03 | 苏州大学 | Method of raising light fastness of natural dye fabric |
| CN102061631A (en) * | 2009-11-12 | 2011-05-18 | 上海甲秀工业设计有限公司 | Modern gambiered Canton gauze product processing and manufacturing method |
| CN102634993A (en) * | 2012-02-01 | 2012-08-15 | 常州美胜生物材料有限公司 | Method for dyeing cotton fibers by using natural dye |
| CN102733182A (en) * | 2012-07-11 | 2012-10-17 | 周晓刚 | Process for producing double-sided gambiered Guangdong silk |
| CN103015232A (en) * | 2013-01-14 | 2013-04-03 | 深圳市梁子时装实业有限公司 | Method for preparing color Setaria viridis |
| CN106149405A (en) * | 2015-04-17 | 2016-11-23 | 深圳市梁子时装实业有限公司 | Preparation method of a kind of color Liang and products thereof and application |
| CN106192271A (en) * | 2016-08-31 | 2016-12-07 | 周晓刚 | A kind of solarization Liang technique preparing Canton gauze gambiered silk fabric and solarization Liang device |
| CN106978744A (en) * | 2017-04-21 | 2017-07-25 | 深圳市梁子时装实业有限公司 | A kind of gambiered Guangdong silk dyeing |
| CN107022909A (en) * | 2017-05-17 | 2017-08-08 | 万秦君 | A kind of colouring method of dye yam fabric |
| TW201831608A (en) * | 2017-02-17 | 2018-09-01 | 東方學校財團法人東方設計學院 | Manufacturing method for improving sun protection factor of fabric having an plant extract composed of one of Diospyros Kaki rind, Dioscorea Cirrhosa, Millettia, Ecliptae and Macrocarpa without any environmentally harmful chemicals |
-
2019
- 2019-04-20 CN CN201910320757.1A patent/CN110130123A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101046069A (en) * | 2007-03-29 | 2007-10-03 | 苏州大学 | Method of raising light fastness of natural dye fabric |
| CN102061631A (en) * | 2009-11-12 | 2011-05-18 | 上海甲秀工业设计有限公司 | Modern gambiered Canton gauze product processing and manufacturing method |
| CN102634993A (en) * | 2012-02-01 | 2012-08-15 | 常州美胜生物材料有限公司 | Method for dyeing cotton fibers by using natural dye |
| CN102733182A (en) * | 2012-07-11 | 2012-10-17 | 周晓刚 | Process for producing double-sided gambiered Guangdong silk |
| CN103015232A (en) * | 2013-01-14 | 2013-04-03 | 深圳市梁子时装实业有限公司 | Method for preparing color Setaria viridis |
| CN106149405A (en) * | 2015-04-17 | 2016-11-23 | 深圳市梁子时装实业有限公司 | Preparation method of a kind of color Liang and products thereof and application |
| CN106192271A (en) * | 2016-08-31 | 2016-12-07 | 周晓刚 | A kind of solarization Liang technique preparing Canton gauze gambiered silk fabric and solarization Liang device |
| TW201831608A (en) * | 2017-02-17 | 2018-09-01 | 東方學校財團法人東方設計學院 | Manufacturing method for improving sun protection factor of fabric having an plant extract composed of one of Diospyros Kaki rind, Dioscorea Cirrhosa, Millettia, Ecliptae and Macrocarpa without any environmentally harmful chemicals |
| CN106978744A (en) * | 2017-04-21 | 2017-07-25 | 深圳市梁子时装实业有限公司 | A kind of gambiered Guangdong silk dyeing |
| CN107022909A (en) * | 2017-05-17 | 2017-08-08 | 万秦君 | A kind of colouring method of dye yam fabric |
Non-Patent Citations (2)
| Title |
|---|
| 吴水田: "《话说疍民文化》", 31 July 2013, 广东经济出版社 * |
| 赖寄丹: "《传统与现代的邂逅》", 31 December 2017, 华南理工出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Khan et al. | Extraction of natural dye from red calico leaves: Gamma ray assisted improvements in colour strength and fastness properties | |
| US8697429B2 (en) | Method for dyeing a textile product using Neem and Holy basil extract | |
| KR19990007624A (en) | How to dye natural dyes | |
| CN104372610B (en) | A kind of preparation method of the bafta with function of removing formaldehyde | |
| CN105220505B (en) | A kind of formaldehydeless permanent press finishing agent and its application method | |
| Salah | Antibacterial activity and UV protection property of some Egyptian cotton fabrics treated with aqueous extract from banana peel | |
| CN110130127A (en) | A kind of application of organic-metallic ion complex antimicrobials | |
| JP3188871B2 (en) | Manufacturing method of antibacterial fiber | |
| CN108867038A (en) | The efficient dyeing and printing process of modified fibre fabric | |
| Salah | Antibacterial activity and ultraviolet(UV) protection property of some Egyptian cotton fabrics treated with aqeous extract from banana peel | |
| CN101591846A (en) | A kind of preparation method of moisture-absorption and perspiration finish fabric | |
| Maulik et al. | Sustainable dyeing and printing of knitted fabric with natural dyes | |
| CN108070941A (en) | A kind of preparation method of high-strength antibacterial environment-friendlyfabric fabric | |
| CN106245357A (en) | A kind of method that pigment in leaves be transfer will be made directly on fabric | |
| CN106868889B (en) | A kind of dyeing and printing products and its dyeing method based on plant | |
| CN110130123A (en) | The preparation process of high-performance antimildew and antibacterial gelsemium cotton | |
| KR20110041011A (en) | Tannin textile manufacturing method | |
| CN109385885A (en) | The preparation method of nylon fabric with uvioresistant function | |
| CN107956117A (en) | A kind of dyeing and finishing technology of people's cotton face fabric comprising acrylic yarn | |
| CN108193520A (en) | A kind of dyeing and finishing method of people's cotton face fabric | |
| JP3660891B2 (en) | Manufacturing method of antibacterial tea-dyed fiber products | |
| JP3144863B2 (en) | Dyed textile products and their production | |
| Moses et al. | Study of K/S, anti-bacterial, UV-protection, anti-odor and sem on chemical treated cotton fabrics | |
| Madhu et al. | Sustainable environment friendly approach for Psilocybe zapotecorumcolour dyeing integrated with anti-microbial finish | |
| JP4415421B2 (en) | Antibacterial acrylonitrile fiber and process for producing the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190816 |
|
| RJ01 | Rejection of invention patent application after publication |