CN110105984A - A kind of static bed gas making oxygenation gas-made technology - Google Patents

A kind of static bed gas making oxygenation gas-made technology Download PDF

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Publication number
CN110105984A
CN110105984A CN201910389514.3A CN201910389514A CN110105984A CN 110105984 A CN110105984 A CN 110105984A CN 201910389514 A CN201910389514 A CN 201910389514A CN 110105984 A CN110105984 A CN 110105984A
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China
Prior art keywords
oxygen
air
gas
oxygenation
static bed
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CN201910389514.3A
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Chinese (zh)
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魏奇
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Anhui Huaertai Chemical Industry Co Ltd
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Anhui Huaertai Chemical Industry Co Ltd
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Priority to CN201910389514.3A priority Critical patent/CN110105984A/en
Publication of CN110105984A publication Critical patent/CN110105984A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02Fixed-bed gasification of lump fuel
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1603Integration of gasification processes with another plant or parts within the plant with gas treatment

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Separation Of Gases By Adsorption (AREA)

Abstract

A kind of static bed gas making oxygenation gas-made technology, comprising the following steps: S1, oxygen enter oxygen surge tank;S2, the oxygen for going out oxygen surge tank are sufficiently mixed after pneumatic control valve and Roots blower with air, and the oxygen content in air is made to increase to 25%-27% as oxygenation air by 21%;S3, oxygenation air is sent to each Gas-making Furnace use.After oxygen enters oxygen surge tank, the concentration and pressure of oxygen can be preferably controlled, so that the oxygen and air that meet the requirements are sufficiently mixed, the oxygen content in air is made quickly to increase to 25%-27% as oxygenation air by 21%.

Description

A kind of static bed gas making oxygenation gas-made technology
Technical field
The present invention relates to a kind of gas preparation technical field more particularly to a kind of static bed gas making oxygenation gas-made technologies.
Background technique
Gas making at present mainly produces good semiwater gas as the unstripped gas of synthesis ammonia using fixed-bed intermittent formula regenerative process. One of traditional fixed-bed intermittent gasification process circulation be divided into blowing, on blow, under blow, it is secondary on blow, blow off five stages.Tradition Fixed-bed intermittent gasification process feature: technology maturation, easy to operate;Effective component is higher in coal gas, above blows effective gas (CO+H2) Average 85%, under blow effective gas average 96%;It is wide to be applicable in coal range;Small investment;Aspect of blowing efficiency is low, and single furnace gas production is low, by For the oxygen sources needed for entering gasification furnace burning in atmosphere, oxygen concentration is low (21%), and the unit time reacts releasing with charcoal Heat is few, can only improve gasification layer temperature by extending blow-time, cause aspect of blowing efficiency low, capacity usage ratio is low, and single furnace produces Tolerance is low;Environmental pollution is big, and dust, carbon dioxide and sulfide are contained in the blowing-out gas of generation, atmosphere is discharged into and causes to environment Pollution.
Therefore, oxygen-enriched continuous gasification process is mostly used in recent years, the characteristics of oxygen-enriched continuous gasification process: technology maturation, fortune Row is unstable (being directed to existing inferior raw material);Mating air separation unit is needed, one-time investment is big, and industrialized unit is not yet universal;It is right Coal is selectively strong;Carbon dioxide is high in coal gas, and methane content is high, available gas 65-72%;Single furnace gas production is high, about between 1 times of having a short break or more;It is always continuous upper blowing gas, no blowing-out gas is vented, and environmental pollution is small.
Fixed-bed intermittent gasification process is mostly used at present, fixed-bed intermittent gasification process process is simple, using air, steam Gasifying agent oxygenation air gas stage by stage belongs to accumulation of heat gas making method, and temperature difference amplitude is big, and gas overall quality is good, especially blows down In the stage, makings is more preferable than above blowing, and the current energy consumption of the technique remains high, and main cause is blowing heating using air, the thermal efficiency Difference, heat loss are big.Oxygen-rich gasification is continuous upper blowing gas, the self-heating gas making method that heat supply and gas processed carry out together, temperature difference amplitude Small, gas production is big, and environmental pollution is small, but carbon dioxide, methane content are high in coal gas, and the continuous and steady operation time is short, is gasifying Easy slagging agglomeration, needs timing blowing out manually to take off block processing when inferior raw material.
Summary of the invention
The object of the present invention is to provide a kind of static bed gas making oxygenation gas-made technology, the gas making for being able to carry out highly effective and safe increases Oxygen.
To realize the above-mentioned technical purpose, the technical solution of the embodiment of the present invention is specific as follows.
A kind of static bed gas making oxygenation gas-made technology, comprising the following steps:
S1, oxygen enter oxygen surge tank;
S2, the oxygen for going out oxygen surge tank are sufficiently mixed after pneumatic control valve and Roots blower with air, make sky Oxygen content in gas increases to 25%-27% as oxygenation air by 21%;
S3, oxygenation air is sent to each Gas-making Furnace use.
Further, the oxygen in step S1 comes from pressure swing adsorption oxygen making device, and the oxygen concentration is 90% or more, institute Stating oxygen pressure is 0.06-0.08MPa.
Further, it in step S2, is analyzed after oxygen and air mixing through online oxygen analyzer, according to its oxygen amount point The oxygen concentration that instrument is measured adjusts pneumatic control valve aperture.
Further, instruction, record, warning device are provided on the oxygen analyzer.
Further, in step S3, oxygenation air oxygen concentration is analyzed, adjusts oxygen flow.
Further, high-concentration and low-concentration alarm interlocking is carried out to oxygenation air oxygen concentration.
Further, acquisition blowing valve control signal, surge tank outlet oxygen pressure feedover to oxygenation air oxygen concentration and mend Repay adjusting, bunch grade adjustment, modeling adjusting.
Compared with prior art, this have the advantage that:
A kind of static bed gas making oxygenation gas-made technology, comprising the following steps: S1, oxygen enter oxygen surge tank;S2, go out oxygen The oxygen of gas surge tank is sufficiently mixed with after Roots blower with air by pneumatic control valve, make oxygen content in air by 21% increases to 25%-27% as oxygenation air;S3, oxygenation air is sent to each Gas-making Furnace use.It is slow that oxygen enters oxygen After rushing tank, the concentration and pressure of oxygen can be preferably controlled, so that the oxygen and air that meet the requirements are sufficiently mixed, makes air In oxygen content quickly increase to 25%-27% as oxygenation air by 21%.Further, in step S2, oxygen and air It is analyzed after mixing through online oxygen analyzer, the oxygen concentration for dividing instrument to measure according to its oxygen amount adjusts pneumatic control valve and opens Degree.Using online oxygen analyzer can real-time measurement oxygen concentration, and then accurately control out the oxygen of oxygen surge tank so that Oxygen content in air preferably controls between 25%-27%.
Detailed description of the invention
The present invention will be further described in detail below with reference to the accompanying drawings and specific embodiments.
Fig. 1 is static bed gas making oxygenation gas-made technology schematic diagram in the embodiment of the present invention.
Specific embodiment
Technical solution of the present invention is clearly and completely described below in conjunction with attached drawing, it is clear that described implementation Example is a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, ordinary skill Personnel's every other embodiment obtained without making creative work, shall fall within the protection scope of the present invention.
As shown in Figure 1, to realize the above-mentioned technical purpose, the technical solution of the embodiment of the present invention is specific as follows.
Embodiment 1
A kind of static bed gas making oxygenation gas-made technology, comprising the following steps: S1, oxygen enter oxygen surge tank;S2, go out oxygen The oxygen of gas surge tank is sufficiently mixed with after Roots blower with air by pneumatic control valve, make oxygen content in air by 21%, which increases to 25%, becomes oxygenation air;S3, oxygenation air is sent to each Gas-making Furnace use.Oxygen enters oxygen surge tank Afterwards, the concentration and pressure of oxygen can be preferably controlled, so that the oxygen and air that meet the requirements are sufficiently mixed, is made in air Oxygen content, which quickly increases to 25% by 21%, becomes oxygenation air.
Further, the oxygen in step S1 comes from pressure swing adsorption oxygen making device, and the oxygen concentration is 90%, the oxygen Atmospheric pressure is 0.06MPa.
Further, it in step S2, is analyzed after oxygen and air mixing through online oxygen analyzer, according to its oxygen amount point The oxygen concentration that instrument is measured adjusts pneumatic control valve aperture.Using online oxygen analyzer can real-time measurement oxygen it is dense Degree, and then the oxygen of oxygen surge tank is accurately controlled out, so that the oxygen content in air is preferably controlled 25%.
Further, instruction, record, warning device are provided on the oxygen analyzer.
Further, in step S3, oxygenation air oxygen concentration is analyzed, adjusts oxygen flow.
Further, high-concentration and low-concentration alarm interlocking is carried out to oxygenation air oxygen concentration, it is ensured that the safety of Gas-making Furnace.
Further, acquisition blowing valve control signal, surge tank outlet oxygen pressure feedover to oxygenation air oxygen concentration and mend Repay adjusting, bunch grade adjustment, modeling adjusting.Enter furnace oxygenation air oxygen concentration analysis acquisition delay time it is longer (10 seconds with On), therefore enter furnace oxygenation air oxygen concentration Adjust and use blowing valve control signal, surge tank outlet oxygen pressure, enter stove air The signals such as manifold pressure carry out feedforward compensation adjusting, bunch grade adjustment, modeling are adjusted etc., it is ensured that it is basicly stable to enter furnace oxygen concentration, full The requirement of sufficient technique.
Further, when the electric current of Roots blower is lower than a certain lower limit value (can set), pneumatic cut-off valve closes buffering Tank outlet, it is ensured that the safety of Gas-making Furnace production.
Further, a pneumatic cut-off valve is equipped with before pneumatic control valve, this valve and blower current, blowing valve are chain, when When air blower trips, this valve quickly by oxygen cutting, guarantees system safety.
Embodiment 2
A kind of static bed gas making oxygenation gas-made technology, comprising the following steps: S1, oxygen enter oxygen surge tank;S2, go out oxygen The oxygen of gas surge tank is sufficiently mixed with after Roots blower with air by pneumatic control valve, make oxygen content in air by 21%, which increases to 26%, becomes oxygenation air;S3, oxygenation air is sent to each Gas-making Furnace use.Oxygen in step S1 is from change Adsorption oxygen-preparation device is pressed, for the oxygen concentration 91%, the oxygen pressure is 0.06MPa.After oxygen enters oxygen surge tank, The concentration and pressure of oxygen can be preferably controlled, so that the oxygen and air that meet the requirements are sufficiently mixed, makes containing in air Oxygen amount, which quickly increases to 26% by 21%, becomes oxygenation air.
Further, it in step S2, is analyzed after oxygen and air mixing through online oxygen analyzer, according to its oxygen amount point The oxygen concentration that instrument is measured adjusts pneumatic control valve aperture.Using online oxygen analyzer can real-time measurement oxygen it is dense Degree, and then the oxygen of oxygen surge tank is accurately controlled out, so that the oxygen content in air preferably controls between 26%.
Embodiment 3
A kind of static bed gas making oxygenation gas-made technology, comprising the following steps: S1, oxygen enter oxygen surge tank;S2, go out oxygen The oxygen of gas surge tank is sufficiently mixed with after Roots blower with air by pneumatic control valve, make oxygen content in air by 21%, which increases to 27%, becomes oxygenation air;S3, oxygenation air is sent to each Gas-making Furnace use.Oxygen in step S1 is from change Adsorption oxygen-preparation device is pressed, for the oxygen concentration 92%, the oxygen pressure is 0.06MPa.After oxygen enters oxygen surge tank, The concentration and pressure of oxygen can be preferably controlled, so that the oxygen and air that meet the requirements are sufficiently mixed, makes containing in air Oxygen amount, which quickly increases to 27% by 21%, becomes oxygenation air.
Further, it in step S2, is analyzed after oxygen and air mixing through online oxygen analyzer, according to its oxygen amount point The oxygen concentration that instrument is measured adjusts pneumatic control valve aperture.Using online oxygen analyzer can real-time measurement oxygen it is dense Degree, and then the oxygen of oxygen surge tank is accurately controlled out, so that the oxygen content in air is preferably controlled 27%.
Embodiment 4
A kind of static bed gas making oxygenation gas-made technology, comprising the following steps: S1, oxygen enter oxygen surge tank;S2, go out oxygen The oxygen of gas surge tank is sufficiently mixed with after Roots blower with air by pneumatic control valve, make oxygen content in air by 21%, which increases to 27%, becomes oxygenation air;S3, oxygenation air is sent to each Gas-making Furnace use.Oxygen in step S1 is from change Adsorption oxygen-preparation device is pressed, for the oxygen concentration 93%, the oxygen pressure is 0.08MPa.After oxygen enters oxygen surge tank, The concentration and pressure of oxygen can be preferably controlled, so that the oxygen and air that meet the requirements are sufficiently mixed, makes containing in air Oxygen amount, which quickly increases to 27% by 21%, becomes oxygenation air.
Further, it in step S2, is analyzed after oxygen and air mixing through online oxygen analyzer, according to its oxygen amount point The oxygen concentration that instrument is measured adjusts pneumatic control valve aperture.Using online oxygen analyzer can real-time measurement oxygen it is dense Degree, and then the oxygen of oxygen surge tank is accurately controlled out, so that the oxygen content in air is preferably controlled 27%.
The basic principles, main features and advantages of the invention have been shown and described above.The technical staff of the industry should Understand, the present invention is not limited to the above embodiments, and the above embodiments and description only describe originals of the invention Reason, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes and improvements It both falls in the scope of protection of present invention.The claimed scope of the invention is by appended claims and its equivalent circle It is fixed.

Claims (7)

1. a kind of static bed gas making oxygenation gas-made technology, which comprises the following steps:
S1, oxygen enter oxygen surge tank;
S2, the oxygen for going out oxygen surge tank are sufficiently mixed after pneumatic control valve and Roots blower with air, are made in air Oxygen content increase to 25%-27% as oxygenation air by 21%;
S3, oxygenation air is sent to each Gas-making Furnace use.
2. static bed gas making oxygenation gas-made technology as described in claim 1, which is characterized in that the oxygen in step S1 is from change Adsorption oxygen-preparation device is pressed, for the oxygen concentration 90% or more, the oxygen pressure is 0.06-0.08MPa.
3. static bed gas making oxygenation gas-made technology as described in claim 1, which is characterized in that in step S2, oxygen and air It is analyzed after mixing through online oxygen analyzer, the oxygen concentration for dividing instrument to measure according to its oxygen amount adjusts pneumatic control valve and opens Degree.
4. static bed gas making oxygenation gas-made technology as claimed in claim 3, which is characterized in that be arranged on the oxygen analyzer There are instruction, record, warning device.
5. static bed gas making oxygenation gas-made technology as described in claim 1, which is characterized in that in step S3, to oxygenation air Oxygen concentration analysis, adjusts oxygen flow.
6. static bed gas making oxygenation gas-made technology as claimed in claim 5, which is characterized in that carry out oxygenation air oxygen concentration High-concentration and low-concentration alarm interlocking.
7. static bed gas making oxygenation gas-made technology as claimed in claim 5, which is characterized in that acquisition blowing valve control signal, Surge tank exports oxygen pressure and adjusts to the adjusting of oxygenation air oxygen concentration feedforward compensation, bunch grade adjustment, modeling.
CN201910389514.3A 2019-05-10 2019-05-10 A kind of static bed gas making oxygenation gas-made technology Pending CN110105984A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110105985A (en) * 2019-05-13 2019-08-09 安徽华尔泰化工股份有限公司 A kind of static bed gas making oxygenation gas-made technology

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB673418A (en) * 1950-03-22 1952-06-04 United Eng & Constructors Inc Method of making carburetted combustible gas
CN203033954U (en) * 2012-11-02 2013-07-03 华强化工集团股份有限公司 Flow device for preparing semi-water gas with enriched oxygen
CN204006083U (en) * 2014-07-03 2014-12-10 首钢京唐钢铁联合有限责任公司 A kind of sleeve kiln low purity oxygen oxygen-enriched burning device
CN108102724A (en) * 2017-12-27 2018-06-01 贵州开磷息烽合成氨有限责任公司 A kind of method of gas burner oxygenation gas
CN108264939A (en) * 2018-01-13 2018-07-10 安徽金禾实业股份有限公司 A kind of pressure control control oxygen system for fixed bed oxygen enhanced gasification technique

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB673418A (en) * 1950-03-22 1952-06-04 United Eng & Constructors Inc Method of making carburetted combustible gas
CN203033954U (en) * 2012-11-02 2013-07-03 华强化工集团股份有限公司 Flow device for preparing semi-water gas with enriched oxygen
CN204006083U (en) * 2014-07-03 2014-12-10 首钢京唐钢铁联合有限责任公司 A kind of sleeve kiln low purity oxygen oxygen-enriched burning device
CN108102724A (en) * 2017-12-27 2018-06-01 贵州开磷息烽合成氨有限责任公司 A kind of method of gas burner oxygenation gas
CN108264939A (en) * 2018-01-13 2018-07-10 安徽金禾实业股份有限公司 A kind of pressure control control oxygen system for fixed bed oxygen enhanced gasification technique

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110105985A (en) * 2019-05-13 2019-08-09 安徽华尔泰化工股份有限公司 A kind of static bed gas making oxygenation gas-made technology

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Application publication date: 20190809