CN110078983A - Gloves made of latex slurry with touch screen functionality and preparation method thereof - Google Patents

Gloves made of latex slurry with touch screen functionality and preparation method thereof Download PDF

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Publication number
CN110078983A
CN110078983A CN201910391485.4A CN201910391485A CN110078983A CN 110078983 A CN110078983 A CN 110078983A CN 201910391485 A CN201910391485 A CN 201910391485A CN 110078983 A CN110078983 A CN 110078983A
Authority
CN
China
Prior art keywords
carbon black
touch screen
parts
natural emulsion
polyvinyl alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910391485.4A
Other languages
Chinese (zh)
Inventor
陈习文
张军
雷民
周峰
王斯琪
陈卓
周玮
卢冰
王旭
郭子娟
齐聪
汪泉
聂高宁
金淼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
State Grid Corp of China SGCC
China Electric Power Research Institute Co Ltd CEPRI
Original Assignee
State Grid Corp of China SGCC
China Electric Power Research Institute Co Ltd CEPRI
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by State Grid Corp of China SGCC, China Electric Power Research Institute Co Ltd CEPRI filed Critical State Grid Corp of China SGCC
Priority to CN201910391485.4A priority Critical patent/CN110078983A/en
Publication of CN110078983A publication Critical patent/CN110078983A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D19/00Gloves
    • A41D19/0055Plastic or rubber gloves
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • C08J3/205Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase
    • C08J3/2053Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase the additives only being premixed with a liquid phase
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • C08L7/02Latex
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2307/00Characterised by the use of natural rubber
    • C08J2307/02Latex
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2429/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
    • C08J2429/02Homopolymers or copolymers of unsaturated alcohols
    • C08J2429/04Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention proposes a kind of gloves made of latex slurry with touch screen functionality, the raw material including following parts by weight: 15 parts -25 parts of high-molecular polyvinyl alcohol lotion, 0.05 part of carbon black, 75 parts -85 parts of natural emulsion mixture.The beneficial effects of the present invention are: natural emulsion itself has good insulation performance, by adding carbon black wherein, emgloves obtained is made to have the function of that touch screen uses.Simultaneously, it is mixed by the way that carbon black to be added in high-molecular polyvinyl alcohol lotion, mixed solution is retell to be added in natural emulsion mixture, it efficiently avoids adding the problem of carbon black be easy to cause carbon black reunion that carbon black is caused to be unevenly distributed directly in natural emulsion, to improve the touch screen effect of emgloves tool obtained.

Description

Gloves made of latex slurry with touch screen functionality and preparation method thereof
Technical field
The present invention relates to emgloves technical fields, starch in particular to a kind of gloves made of latex with touch screen functionality Material and preparation method thereof.
Background technique
Currently, latex protective gloves is usually process by latex, heat preservation wear-resisting with its, antiseepage, easy processing, applicability By force, the features such as reusable, is widely used in family, automobile manufacture, electronic apparatus manufacture, aerospace, industry, medical treatment, beauty The various industries such as appearance are indispensable hand protection articles.
With the development of science and technology, touch screen technology has obtained great development, is widely used in life, greatly side Our work and life.But when using touch screen technology in the case where wearing gloves, frequently wearing off gloves again can be to User brings many inconvenience.It the touch screen of touch-screen equipment that can be used can be come into being with gloves so not needing to unglove.
For example, the Chinese patent literature of Publication No. CN105603769A disclose a kind of touch-screen glove synthetic leather and its Preparation method includes substrate, surface layer 1 and surface layer 2 from bottom to top, and wherein substrate is washer wrinkle fabric, and surface layer 1 and surface layer 2 are to add not The synthetic leather of touch screen powder in proportion.
The Chinese patent literature of Publication No. CN203096487U discloses a kind of touch-screen glove leather with conducting function, By it is upper under successively are as follows: surface layer, touch screen layer, back cover layer, leather layer.Wherein surface layer is made of softening agent, and touch screen layer is by nanoscale Powdered carbon, metal powder, polyphosphazene polymer ammoniacum and acrylic acid mix, and back cover layer main component is cationic compound resin, skin Removing from office layer is that goat upper leather or abortive calfskin are removed from office.
Above-mentioned technical proposal is synthetic leather gloves, and usage scenario is limited, and touch screen effect is poor.
Summary of the invention
In consideration of it, the invention proposes a kind of gloves made of latex slurry with touch screen functionality, it is intended to solve to improve latex hand The problem of application range and touch screen effect of set.
On one side, the invention proposes a kind of gloves made of latex slurry with touch screen functionality, including following parts by weight Raw material:
15 parts -25 parts of high-molecular polyvinyl alcohol lotion
0.05 part of carbon black
75 parts -85 parts of natural emulsion mixture.
Further, the fineness of the carbon black is 800-1000 mesh.
Further, the high-molecular polyvinyl alcohol emulsion solid content is 10%, told natural emulsion mixture solid content It is 45%.
On the other hand, the preparation method of the invention proposes a kind of gloves made of latex slurry with touch screen functionality, including with Lower step:
Step 1: the carbon black of 0.05 parts by weight and poly-vinyl alcohol solution being mixed, mixed solution is obtained;
Step 2: the mixed solution being added in a certain proportion of natural emulsion mixture, slurry is obtained after mixing.
Compared with prior art, the beneficial effects of the present invention are: natural emulsion itself has good insulation performance, lead to It crosses and adds carbon black wherein, emgloves obtained is made to have the function of that touch screen uses.Meanwhile by the way that carbon black is added to polyethylene It is mixed in alcohol macromolecule emulsion, retells mixed solution and be added in natural emulsion mixture, efficiently avoid directly existing The problem of carbon black be easy to cause carbon black reunion that carbon black is caused to be unevenly distributed is added in natural emulsion, to improve cream obtained The touch screen effect of Rubber gloves tool.
Further, carbon black is added in high-molecular polyvinyl alcohol latex, carbon black is uniform in high-molecular polyvinyl alcohol lotion Dispersion, then mixed solution is added in natural emulsion mixture, it can guarantee that carbon black is evenly dispersed in natural emulsion, simultaneously The problem of poly-vinyl alcohol solution can improve the precipitating of natural emulsion, turn yellow is added in natural emulsion, makes product with stable quality, Also reduce the manufacturing cost of product.
Specific embodiment
The exemplary embodiment of the disclosure will be described in detail belows.It should be appreciated that may be realized in various forms this public affairs It opens and should not be limited by the embodiments set forth herein.It is to be able to thoroughly understand this on the contrary, providing these embodiments It is open, and the scope of the present disclosure can be fully disclosed to those skilled in the art.It should be noted that not conflicting In the case where, the feature in embodiment and embodiment in the present invention can be combined with each other.Come below in conjunction with embodiment detailed Illustrate the present invention.
The embodiment of the invention provides a kind of the gloves made of latex slurry with touch screen functionality, the original including following parts by weight Material:
15 parts -25 parts of high-molecular polyvinyl alcohol lotion
0.05 part of carbon black
75 parts -85 parts of natural emulsion mixture.
Further, the fineness of the carbon black is 800-1000 mesh.
Further, the high-molecular polyvinyl alcohol emulsion solid content is 10%, told natural emulsion mixture solid content It is 45%.
On the other hand, the preparation side of the embodiment of the invention also provides a kind of gloves made of latex slurry with touch screen functionality Method, comprising the following steps:
Step 1: a certain proportion of carbon black and poly-vinyl alcohol solution being mixed, mixed solution is obtained;
Step 2: the mixed solution being added in a certain proportion of natural emulsion mixture, slurry is obtained after mixing.
Embodiment 1
The present embodiment provides a kind of gloves made of latex slurry with touch screen functionality, which is by step system in detail below , the specific steps are as follows:
Step 1: by weight, weighing 25 parts of high-molecular polyvinyl alcohol lotion, 0.05 part of carbon black, in proportion uniformly mixing, Wherein high-molecular polyvinyl alcohol emulsion solid content is 10%;
Step 2: by weight, weighing 75 parts of natural emulsion mixture, and the mixed solution in step 1 is added in proportion It is uniformly mixed in natural emulsion mixture, wherein natural emulsion mixture solid content is 45%.Finally obtain a kind of band touch screen function The gloves made of latex slurry of energy.
Embodiment 2
The present embodiment provides a kind of gloves made of latex slurry with touch screen functionality, which is by step system in detail below , the specific steps are as follows:
Step 1: by weight, weighing 20 parts of high-molecular polyvinyl alcohol lotion, 0.05 part of carbon black, in proportion uniformly mixing, Wherein high-molecular polyvinyl alcohol emulsion solid content is 10%;
Step 2: by weight, weighing 80 parts of natural emulsion mixture, and the mixed solution in step 1 is added in proportion It is uniformly mixed in natural emulsion mixture, wherein natural emulsion mixture solid content is 45%.Finally obtain a kind of band touch screen function The gloves made of latex slurry of energy.
Embodiment 3
The present embodiment provides a kind of gloves made of latex slurry with touch screen functionality, which is by step system in detail below , the specific steps are as follows:
Step 1: by weight, weighing 15 parts of high-molecular polyvinyl alcohol lotion, 0.05 part of carbon black, in proportion uniformly mixing, Wherein high-molecular polyvinyl alcohol emulsion solid content is 10%;
Step 2: by weight, weighing 85 parts of natural emulsion mixture, and the mixed solution in step 1 is added in proportion It is uniformly mixed in natural emulsion mixture, wherein natural emulsion mixture solid content is 45%.Finally obtain a kind of band touch screen function The gloves made of latex slurry of energy.
Embodiment 4
The present embodiment provides a kind of gloves made of latex slurry with touch screen functionality, which is by step system in detail below , the specific steps are as follows:
Step 1: by weight, weighing 15 parts of high-molecular polyvinyl alcohol lotion, 0.05 part of carbon black, in proportion uniformly mixing, Wherein high-molecular polyvinyl alcohol emulsion solid content is 10%;
Step 2: by weight, weighing 75 parts of natural emulsion mixture, and the mixed solution in step 1 is added in proportion It is uniformly mixed in natural emulsion mixture, wherein natural emulsion mixture solid content is 45%.Finally obtain a kind of band touch screen function The gloves made of latex slurry of energy.
Embodiment 5
The present embodiment provides a kind of gloves made of latex slurry with touch screen functionality, which is by step system in detail below , the specific steps are as follows:
Step 1: by weight, weighing 25 parts of high-molecular polyvinyl alcohol lotion, 0.05 part of carbon black, in proportion uniformly mixing, Wherein high-molecular polyvinyl alcohol emulsion solid content is 10%;
Step 2: by weight, weighing 85 parts of natural emulsion mixture, and the mixed solution in step 1 is added in proportion It is uniformly mixed in natural emulsion mixture, wherein natural emulsion mixture solid content is 45%.Finally obtain a kind of band touch screen function The gloves made of latex slurry of energy.
It is understood that natural emulsion itself has good insulation performance, by adding carbon black wherein, make to be made Emgloves have the function of touch screen using.Meanwhile being mixed by the way that carbon black to be added in high-molecular polyvinyl alcohol lotion, It retells mixed solution to be added in natural emulsion mixture, efficiently avoids the addition carbon black directly in natural emulsion and be easy to make The problem of causing carbon black to be unevenly distributed at carbon black reunion, to improve the touch screen effect of emgloves tool obtained.
Further, carbon black is added in high-molecular polyvinyl alcohol latex, carbon black is uniform in high-molecular polyvinyl alcohol lotion Dispersion, then mixed solution is added in natural emulsion mixture, it can guarantee that carbon black is evenly dispersed in natural emulsion, simultaneously The problem of poly-vinyl alcohol solution can improve the precipitating of natural emulsion, turn yellow is added in natural emulsion, makes product with stable quality, Also reduce the manufacturing cost of product.
Obviously, various changes and modifications can be made to the invention without departing from essence of the invention by those skilled in the art Mind and range.In this way, if these modifications and changes of the present invention belongs to the range of the claims in the present invention and its equivalent technologies Within, then the present invention is also intended to include these modifications and variations.

Claims (4)

1. a kind of gloves made of latex slurry with touch screen functionality, which is characterized in that the raw material including following parts by weight:
15 parts -25 parts of high-molecular polyvinyl alcohol lotion
0.05 part of carbon black
75 parts -85 parts of natural emulsion mixture.
2. the gloves made of latex slurry according to claim 1 with touch screen functionality, which is characterized in that the fineness of the carbon black For 800-1000 mesh.
3. the gloves made of latex slurry according to claim 1 with touch screen functionality, which is characterized in that the polyvinyl alcohol is high Molecule emulsion solid content is 10%, and told natural emulsion mixture solid content is 45%.
4. a kind of preparation method of the gloves made of latex slurry as claimed in any one of claims 1-3 with touch screen functionality, It is characterized in that, comprising the following steps:
Step 1: the carbon black of 0.05 parts by weight and poly-vinyl alcohol solution being mixed, mixed solution is obtained;
Step 2: the mixed solution being added in a certain proportion of natural emulsion mixture, slurry is obtained after mixing.
CN201910391485.4A 2019-05-10 2019-05-10 Gloves made of latex slurry with touch screen functionality and preparation method thereof Pending CN110078983A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910391485.4A CN110078983A (en) 2019-05-10 2019-05-10 Gloves made of latex slurry with touch screen functionality and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910391485.4A CN110078983A (en) 2019-05-10 2019-05-10 Gloves made of latex slurry with touch screen functionality and preparation method thereof

Publications (1)

Publication Number Publication Date
CN110078983A true CN110078983A (en) 2019-08-02

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114234791A (en) * 2021-12-16 2022-03-25 四川大学 Preparation method of composite film strain sensor based on dropping deposition

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104311906A (en) * 2014-11-12 2015-01-28 海南天然橡胶产业集团股份有限公司 Preparation method for white carbon black/NR (natural rubber) master batch for belted layer of tire
US20150185872A1 (en) * 2014-01-02 2015-07-02 Gerald Leto Glove for use with capacitive touch screen and method of manufacturing same
CN105754159A (en) * 2016-03-15 2016-07-13 青岛科技大学 High-strength antistatic emulsion composite and preparation and application thereof
CN106519323A (en) * 2016-11-11 2017-03-22 青岛科技大学 Method for preparing rubber powder/natural rubber liquid-phase mixed compound rubber
CN108384078A (en) * 2018-02-24 2018-08-10 山东星宇手套有限公司 A kind of preparation method of conductive protection rubber gloves
CN109222290A (en) * 2018-08-15 2019-01-18 山东星宇手套有限公司 A kind of conductive preparation method for reinforcing finger gloves

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150185872A1 (en) * 2014-01-02 2015-07-02 Gerald Leto Glove for use with capacitive touch screen and method of manufacturing same
CN104311906A (en) * 2014-11-12 2015-01-28 海南天然橡胶产业集团股份有限公司 Preparation method for white carbon black/NR (natural rubber) master batch for belted layer of tire
CN105754159A (en) * 2016-03-15 2016-07-13 青岛科技大学 High-strength antistatic emulsion composite and preparation and application thereof
CN106519323A (en) * 2016-11-11 2017-03-22 青岛科技大学 Method for preparing rubber powder/natural rubber liquid-phase mixed compound rubber
CN108384078A (en) * 2018-02-24 2018-08-10 山东星宇手套有限公司 A kind of preparation method of conductive protection rubber gloves
CN109222290A (en) * 2018-08-15 2019-01-18 山东星宇手套有限公司 A kind of conductive preparation method for reinforcing finger gloves

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114234791A (en) * 2021-12-16 2022-03-25 四川大学 Preparation method of composite film strain sensor based on dropping deposition

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Application publication date: 20190802

RJ01 Rejection of invention patent application after publication