CN110078409A - High-performance polycarboxylic acids water reducing agent anti-mud agent and preparation method thereof - Google Patents
High-performance polycarboxylic acids water reducing agent anti-mud agent and preparation method thereof Download PDFInfo
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- CN110078409A CN110078409A CN201910414984.0A CN201910414984A CN110078409A CN 110078409 A CN110078409 A CN 110078409A CN 201910414984 A CN201910414984 A CN 201910414984A CN 110078409 A CN110078409 A CN 110078409A
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- mud
- polycarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Treatment Of Sludge (AREA)
- Excavating Of Shafts Or Tunnels (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
Abstract
The invention discloses high-performance polycarboxylic acids water reducing agent anti-mud agent and preparation method thereof.The present invention relates to anti-mud agent technical fields, a kind of anti-mud agent of high-performance polycarboxylic acids water reducing agent, raw material include: 2-4 parts of polyethylene glycol, 1-2 parts of beta-cyclodextrin, 3-6 parts of cetyl trimethylammonium bromide, 0-40 parts of potassium chloride, 0-20 parts of sodium tripolyphosphate part, 0-5 parts of citric acid, 0-1 parts of EDTA-2Na and 150-273 parts of water according to parts by weight.A kind of anti-mud agent preparation method of high-performance polycarboxylic acids water reducing agent, 80-100 DEG C of water is successively dissolved into cetyl trimethylammonium bromide, beta-cyclodextrin, potassium chloride and/or sodium tripolyphosphate, citric acid and/or EDTA-2Na, 40 DEG C of redissolution polyethylene glycol are cooled to, are cooled to 20-30 DEG C.Anti- mud agent can carry out Preferential adsorption or selective absorption to the mud in sand, and reducing absorption of the soil to diminishing agent molecule will be of great significance to the development of polycarboxylate water-reducer to sufficiently keep the performance of polycarboxylate water-reducer.
Description
Technical field
The present invention relates to anti-mud agent technical field, especially a kind of high-performance polycarboxylic acids water reducing agent anti-mud agent and its preparation
Method.
Background technique
Recent decades are prepared high with the continuous development of Concrete and construction technology using poly carboxylic acid series water reducer
Performance concrete using more and more extensive, it has also become the development trend of concrete.Poly carboxylic acid series water reducer is due to volume
It is small, water-reducing rate is high, cement adaptability is good, it is slump-retaining can excellent, chloride ion content and alkali content is low, shrinking percentage is small and resistance to
The environmentally protective advantages such as long performance is good, be widely used in room build in infrastructure construction engineering.But in practical application mistake
Cheng Zhong, discovery sand clay content are larger to the adverse effect for mixing polycarboxylate water-reducer concrete.The interlayer structure of soil and institute in sand
The high volence metal ions such as the magnesium ion, the aluminium ion that include can largely adsorb polycarboxylate water-reducer molecule, and water-reducing agent is made to lose activity.
In recent years, natural sand resource scarcity, it is a large amount of high containing mud with the quickening of Process of Housing Industrialization and increasing for infrastructural project
The sand of amount is used directly in concrete, so that the workability for mixing the fresh concrete of polycarboxylate water-reducer is deteriorated, the slump is protected
Ability decline is held, or even influences the intensity and durability of concrete.
There is presently no a kind of effective methods to solve the above problems, and can only pass through the volume of raising polycarboxylate water-reducer
It solves, improves the cost of concrete, while also will increase the trouble of other techniques.Although and having claimed anti-mud on the market
The anti-mud agent of agent, either powder liquid is all one or more kinds of formulas of water-reducing agent actually, although equally matching
In the case of can improve water-reducing rate, but easily bleeding, slump-loss is fast, materials increased costs.
Summary of the invention
The purpose of the present invention is to overcome the shortcomings of the existing technology, provides a kind of high-performance polycarboxylic acids water reducing agent anti-mud
Agent, in mixing concrete, anti-mud agent can carry out Preferential adsorption or selective absorption to the mud in sand, reduce soil to diminishing
The absorption of agent molecule will have important meaning to the development of polycarboxylate water-reducer to sufficiently keep the performance of polycarboxylate water-reducer
Justice.
The purpose of the present invention is achieved through the following technical solutions, and the embodiment provides a kind of poly- carboxylics of high-performance
The anti-mud agent of sour water-reducing agent, raw material include: 2-4 parts of polyethylene glycol, 1-2 parts of beta-cyclodextrin, cetyl according to parts by weight
3-6 parts of trimethylammonium bromide, 0-40 parts of potassium chloride, 0-20 parts of sodium tripolyphosphate part, 0-5 parts of citric acid, 0-1 parts of EDTA-2Na
And 150-273 parts of water.
In other embodiments of the invention, raw material includes: 2-4 parts of polyethylene glycol, beta-cyclodextrin according to parts by weight
1-2 parts, 3-5 parts of cetyl trimethylammonium bromide, 10-30 parts of potassium chloride, 5-15 parts of sodium tripolyphosphate part, 1-3 parts of citric acid,
0-1 parts of EDTA-2Na and 173-246 parts of water.
In other embodiments of the invention, raw material includes: 3 parts of polyethylene glycol, beta-cyclodextrin 1 according to parts by weight
Part, 3 parts of cetyl trimethylammonium bromide, 20 parts of potassium chloride, 10 parts of sodium tripolyphosphate part, 2 parts of citric acid, 1 part of EDTA-2Na
And 173 parts of water.
The embodiment of the invention also provides a kind of above-mentioned anti-mud agent preparation methods of high-performance polycarboxylic acids water reducing agent, will
80-100 DEG C of water successively dissolves cetyl trimethylammonium bromide, beta-cyclodextrin, potassium chloride and/or sodium tripolyphosphate, lemon
Acid and/or EDTA-2Na, are cooled to 40 DEG C of redissolution polyethylene glycol, are cooled to 20-30 DEG C.
The present invention has the following advantages that potassium chloride, sodium tripolyphosphate effect are that soil is separated into zwitterion, lemon
Acid, EDTA-2Na main function are ion complexation component, and complexing is come out by dispersion can be to polycarboxylate water-reducer harmful metal sun
Ion.Polyethylene glycol, cetyl trimethylammonium bromide main function are the anion that absorption disperses out, are being mixed to realize
When concrete processed, high-performance polycarboxylic acids water reducing agent provided by the invention with anti-mud agent the mud in sand can be carried out Preferential adsorption or
Selective absorption reduces absorption of the soil to diminishing agent molecule, so that the performance of polycarboxylate water-reducer is sufficiently kept, it will be to poly- carboxylic
The development of sour water-reducing agent is of great significance.
Detailed description of the invention
Fig. 1 is the preparation method schematic diagram provided of the invention.
Specific embodiment
The present invention will be further described with reference to the accompanying drawing, but protection scope of the present invention be not limited to it is following.
Some embodiments of the invention provide a kind of anti-mud agent of high-performance polycarboxylic acids water reducing agent, and raw material is in parts by weight
Meter includes: 2-4 parts of polyethylene glycol, 1-2 parts of beta-cyclodextrin, 3-6 parts of cetyl trimethylammonium bromide, 0-40 parts of potassium chloride, three
0-20 parts of polyphosphate sodium part, 0-5 parts of citric acid, 0-1 parts of EDTA-2Na and 150-273 parts of water.
In other embodiments of the invention, raw material includes: 2-4 parts of polyethylene glycol, beta-cyclodextrin according to parts by weight
1-2 parts, 3-5 parts of cetyl trimethylammonium bromide, 10-30 parts of potassium chloride, 5-15 parts of sodium tripolyphosphate part, 1-3 parts of citric acid,
0-1 parts of EDTA-2Na and 173-246 parts of water.
In other embodiments of the invention, raw material includes: 3 parts of polyethylene glycol, beta-cyclodextrin 1 according to parts by weight
Part, 3 parts of cetyl trimethylammonium bromide, 20 parts of potassium chloride, 10 parts of sodium tripolyphosphate part, 2 parts of citric acid, 1 part of EDTA-2Na
And 173 parts of water.
Referring to Fig. 1, some embodiments of the present invention additionally provide a kind of anti-mud agent system of high-performance polycarboxylic acids water reducing agent
80-100 DEG C of water is successively dissolved cetyl trimethylammonium bromide, beta-cyclodextrin, potassium chloride and/or trimerization phosphorus by Preparation Method
Sour sodium, citric acid and/or EDTA-2Na are cooled to 40 DEG C of redissolution polyethylene glycol, are cooled to 20-30 DEG C.It should be noted that
It in the preferred embodiment, is to be completely dissolved during dissolved constituent, each component is completely dissolved the time and is
15-30min.It is completely dissolved and is subject to solution clarification without muddiness.
Embodiment 1
A kind of anti-mud agent preparation method of high-performance polycarboxylic acids water reducing agent is present embodiments provided, 80 DEG C of water is successively molten
Solve cetyl trimethylammonium bromide, beta-cyclodextrin, potassium chloride and sodium tripolyphosphate mixture, citric acid and EDTA-2Na mixing
Object, is cooled to 40 DEG C of redissolution polyethylene glycol, and last system is cooled to 20 DEG C of obtained high-performance polycarboxylic acids water reducing agents with anti-mud agent.
Embodiment 2
A kind of anti-mud agent preparation method of high-performance polycarboxylic acids water reducing agent is present embodiments provided, 85 DEG C of water is successively molten
Solve cetyl trimethylammonium bromide, beta-cyclodextrin, potassium chloride and sodium tripolyphosphate mixture, citric acid and EDTA-2Na mixing
Object, is cooled to 40 DEG C of redissolution polyethylene glycol, and last system is cooled to 22 DEG C of obtained high-performance polycarboxylic acids water reducing agents with anti-mud agent.
Embodiment 3
A kind of anti-mud agent preparation method of high-performance polycarboxylic acids water reducing agent is present embodiments provided, 90 DEG C of water is successively molten
Solve cetyl trimethylammonium bromide, beta-cyclodextrin, potassium chloride, sodium tripolyphosphate mixture, citric acid, EDTA-2Na mixing
Object, is cooled to 40 DEG C of redissolution polyethylene glycol, and last system is cooled to 25 DEG C of obtained high-performance polycarboxylic acids water reducing agents with anti-mud agent.
Embodiment 4
A kind of anti-mud agent preparation method of high-performance polycarboxylic acids water reducing agent is present embodiments provided, 95 DEG C of water is successively molten
Solve cetyl trimethylammonium bromide, beta-cyclodextrin, potassium chloride, sodium tripolyphosphate mixture, citric acid, EDTA-2Na mixing
Object, is cooled to 40 DEG C of redissolution polyethylene glycol, and last system is cooled to 28 DEG C of obtained high-performance polycarboxylic acids water reducing agents with anti-mud agent.
Embodiment 5
A kind of anti-mud agent preparation method of high-performance polycarboxylic acids water reducing agent is present embodiments provided, successively by 100 DEG C of water
Dissolve cetyl trimethylammonium bromide, beta-cyclodextrin, potassium chloride, sodium tripolyphosphate mixture, citric acid, EDTA-2Na mixing
Object, is cooled to 40 DEG C of redissolution polyethylene glycol, and last system is cooled to 30 DEG C of obtained high-performance polycarboxylic acids water reducing agents with anti-mud agent.
Embodiment 6
A kind of anti-mud agent preparation method of high-performance polycarboxylic acids water reducing agent is present embodiments provided, 80 DEG C of water is successively molten
Solve cetyl trimethylammonium bromide, beta-cyclodextrin, potassium chloride and sodium tripolyphosphate mixture, citric acid and EDTA-2Na mixing
Object, is cooled to 40 DEG C of redissolution polyethylene glycol, and last system is cooled to 30 DEG C of obtained high-performance polycarboxylic acids water reducing agents with anti-mud agent.
Embodiment 7
A kind of anti-mud agent preparation method of high-performance polycarboxylic acids water reducing agent is present embodiments provided, 85 DEG C of water is successively molten
Solve cetyl trimethylammonium bromide, beta-cyclodextrin, potassium chloride and sodium tripolyphosphate mixture, citric acid and EDTA-2Na mixing
Object, is cooled to 40 DEG C of redissolution polyethylene glycol, and last system is cooled to 28 DEG C of obtained high-performance polycarboxylic acids water reducing agents with anti-mud agent.
Embodiment 8
A kind of anti-mud agent preparation method of high-performance polycarboxylic acids water reducing agent is present embodiments provided, 90 DEG C of water is successively molten
Solve cetyl trimethylammonium bromide, beta-cyclodextrin, potassium chloride, sodium tripolyphosphate mixture, citric acid, EDTA-2Na mixing
Object, is cooled to 40 DEG C of redissolution polyethylene glycol, and last system is cooled to 25 DEG C of obtained high-performance polycarboxylic acids water reducing agents with anti-mud agent.
Embodiment 9
A kind of anti-mud agent preparation method of high-performance polycarboxylic acids water reducing agent is present embodiments provided, 95 DEG C of water is successively molten
Solve cetyl trimethylammonium bromide, beta-cyclodextrin, potassium chloride, sodium tripolyphosphate mixture, citric acid, EDTA-2Na mixing
Object, is cooled to 40 DEG C of redissolution polyethylene glycol, and last system is cooled to 22 DEG C of obtained high-performance polycarboxylic acids water reducing agents with anti-mud agent.
Embodiment 10
A kind of anti-mud agent preparation method of high-performance polycarboxylic acids water reducing agent is present embodiments provided, successively by 100 DEG C of water
Dissolve cetyl trimethylammonium bromide, beta-cyclodextrin, potassium chloride, sodium tripolyphosphate mixture, citric acid, EDTA-2Na mixing
Object, is cooled to 40 DEG C of redissolution polyethylene glycol, and last system is cooled to 20 DEG C of obtained high-performance polycarboxylic acids water reducing agents with anti-mud agent.
Embodiment 11
A kind of anti-mud agent preparation method of high-performance polycarboxylic acids water reducing agent is present embodiments provided, 95 DEG C of water is successively molten
Solve cetyl trimethylammonium bromide, beta-cyclodextrin, potassium chloride, sodium tripolyphosphate mixture, citric acid, EDTA-2Na mixing
Object, is cooled to 40 DEG C of redissolution polyethylene glycol, and last system is cooled to 20 DEG C of obtained high-performance polycarboxylic acids water reducing agents with anti-mud agent.
Embodiment 12
A kind of anti-mud agent preparation method of high-performance polycarboxylic acids water reducing agent is present embodiments provided, successively by 100 DEG C of water
Dissolve cetyl trimethylammonium bromide, beta-cyclodextrin, potassium chloride, sodium tripolyphosphate mixture, citric acid, EDTA-2Na mixing
Object, is cooled to 40 DEG C of redissolution polyethylene glycol, and last system is cooled to 25 DEG C of obtained high-performance polycarboxylic acids water reducing agents with anti-mud agent.
Embodiment 1- is into embodiment 12, the weight proportion of the anti-each component of mud agent raw material of high-performance polycarboxylic acids water reducing agent
It is as shown in table 1:
The anti-mud agent raw material weight proportioning of soup processed of high-performance polycarboxylic acids water reducing agent in 1 embodiment 1-12 of table
Test example
Using high-performance polycarboxylic acids water reducing agent made from embodiment 1-12 use anti-mud agent and anti-mud agent common in the market as
Comparative example carries out the Costco Wholesale under theory of testing solid content, pH value and recommendation volume same case, and test result is shown in Table 2
Costco Wholesale under 2 same performance index of table
Claims (4)
1. a kind of anti-mud agent of high-performance polycarboxylic acids water reducing agent, which is characterized in that its raw material includes: poly- second two according to parts by weight
2-4 parts of alcohol, 1-2 parts of beta-cyclodextrin, 3-6 parts of cetyl trimethylammonium bromide, 0-40 parts of potassium chloride, sodium tripolyphosphate part 0-20
Part, 0-5 parts of citric acid, 0-1 parts of EDTA-2Na and 150-273 parts of water.
2. a kind of anti-mud agent of high-performance polycarboxylic acids water reducing agent according to claim 1, which is characterized in that its raw material is by weight
Measuring number meter includes: 2-4 parts of polyethylene glycol, 1-2 parts of beta-cyclodextrin, 3-5 parts of cetyl trimethylammonium bromide, potassium chloride 10-
30 parts, 5-15 parts of sodium tripolyphosphate part, 1-3 parts of citric acid, 0-1 parts of EDTA-2Na and 173-246 parts of water.
3. a kind of anti-mud agent of high-performance polycarboxylic acids water reducing agent according to claim 1, which is characterized in that its raw material is by weight
Measuring number meter includes: 3 parts of polyethylene glycol, 1 part of beta-cyclodextrin, 3 parts of cetyl trimethylammonium bromide, 20 parts of potassium chloride, trimerization
10 parts of sodium phosphate part, 2 parts of citric acid, 1 part of EDTA-2Na and 173 parts of water.
4. a kind of high-performance polycarboxylic acids water reducing agent as described in any one of claims 1-3 anti-mud agent preparation method, feature
It is, 80-100 DEG C of the water is successively dissolved into the cetyl trimethylammonium bromide, the beta-cyclodextrin, the chlorination
Potassium and/or the sodium tripolyphosphate, the citric acid and/or the EDTA-2Na are cooled to 40 DEG C and are redissolved the poly- second two
Alcohol is cooled to 20-30 DEG C.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112960935A (en) * | 2021-02-25 | 2021-06-15 | 贵州天威建材科技有限责任公司 | Special mud-resistant sacrificial agent for polycarboxylic acid water reducer and preparation method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104891853A (en) * | 2015-06-05 | 2015-09-09 | 陕西友邦新材料科技有限公司 | Composite anti-mud agent based on polycarboxylate-type pumping agent, anti-mud pumping agent and preparation method of anti-mud pumping agent |
CN108658502A (en) * | 2018-06-01 | 2018-10-16 | 湖南云中再生科技股份有限公司 | A kind of recycled water is surely with anti-mud agent and its application process |
CN108947301A (en) * | 2018-09-27 | 2018-12-07 | 武汉奥克化学有限公司 | A kind of anti-mud sacrifice agent of Compositional type and preparation method thereof |
-
2019
- 2019-05-17 CN CN201910414984.0A patent/CN110078409A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104891853A (en) * | 2015-06-05 | 2015-09-09 | 陕西友邦新材料科技有限公司 | Composite anti-mud agent based on polycarboxylate-type pumping agent, anti-mud pumping agent and preparation method of anti-mud pumping agent |
CN108658502A (en) * | 2018-06-01 | 2018-10-16 | 湖南云中再生科技股份有限公司 | A kind of recycled water is surely with anti-mud agent and its application process |
CN108947301A (en) * | 2018-09-27 | 2018-12-07 | 武汉奥克化学有限公司 | A kind of anti-mud sacrifice agent of Compositional type and preparation method thereof |
Non-Patent Citations (1)
Title |
---|
秦红梅等: "抗泥型聚羧酸减水剂研究及应用进展", 《应用化工》 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112960935A (en) * | 2021-02-25 | 2021-06-15 | 贵州天威建材科技有限责任公司 | Special mud-resistant sacrificial agent for polycarboxylic acid water reducer and preparation method thereof |
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