CN110054957A - A kind of double-component aqueous zinc-rich coating - Google Patents
A kind of double-component aqueous zinc-rich coating Download PDFInfo
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- CN110054957A CN110054957A CN201811391942.1A CN201811391942A CN110054957A CN 110054957 A CN110054957 A CN 110054957A CN 201811391942 A CN201811391942 A CN 201811391942A CN 110054957 A CN110054957 A CN 110054957A
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- component
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- rich coating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0053—Details of the reactor
- B01J19/0066—Stirrers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/106—Anti-corrosive paints containing metal dust containing Zn
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0893—Zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Abstract
The invention proposes a kind of double-component aqueous zinc-rich coating, including component A and B component, the weight ratio of the component A and B component is 7:3;Its constituent of component A includes: 35-45 parts of water-compatible amino resin, 12-25 parts of acrylic emulsion, 5-15 parts of silica solution, 11-18 parts of zinc powder in parts by weight;Its constituent of B component includes: 5-15 parts of kaolin, 4-11 parts of modified manometer silicon dioxide, 30-45 parts of deionized water in parts by weight.New formulation is taken, this Qi Zucheng is simple, easy for construction.Paint film has excellent electrochemical protection performance and very strong adhesive force, can be 400 ~ 500 DEG C of continuous high temperature resistance, and resistivity is low, and antistatic, anti-radiation, salt fog resistance is excellent, has long-acting anti-corrosion effect.
Description
Technical field
The present invention relates to a kind of coating, in particular to a kind of double-component aqueous zinc-rich coating.
Background technique
Zinc rich primer is a kind of anticorrosive paint product using the zinc powder with sacrificial anode effect as main rust resisting pigment,
There is cathodic protection effect to steel substrate.Mainly there are three types for currently used zinc rich primer: epoxy zinc rich primer, alcohol-soluble
Zinc-rich coating and waterborne inorganic einc-rich primer.
In the prior art, water paint using water as diluent, without the coating of organic solvent, be free of benzene, toluene, diformazan
Benzene, formaldehyde, free TDI toxic heavy metal, nontoxic non-stimulated smell is harmless, free from environmental pollution.Aqueous inorganic zinc-rich bottom
Paint is the priming paint suitable for being painted on steel construction basal plane.In the prior art, the ingredient of waterborne zinc-rich primer standard recipe includes
Potassium silicate, silica solution, deionized water, auxiliary agent and zinc powder, viscosity is low, poor to the adhesive force of paint, is easy from steel construction table
Emaciated face is fallen, and the antirust time limit is shorter.
It needs to develop a kind of not only environmentally friendly but also there is adhesive force height, and the aqueous inorganic zinc-rich bottom with outstanding rustless property
Paint.
Summary of the invention
The present invention proposes a kind of double-component aqueous zinc-rich coating regarding to the issue above.
Specific technical solution is as follows:
A kind of double-component aqueous zinc-rich coating, which is characterized in that including component A and B component, the component A and B component
Weight ratio is 7:3.
Further, its constituent of component A includes: in parts by weight
35-45 parts of water-compatible amino resin
12-25 parts of acrylic emulsion
5-15 parts of silica solution
11-18 parts of zinc powder.
Further, its constituent of B component includes: in parts by weight
5-15 parts of kaolin
4-11 parts of modified manometer silicon dioxide
30-45 parts of deionized water.
Further, the zinc powder is the mixture of 800 mesh zinc powders and 500 mesh zinc powders.
Further, the zinc powder is the mixture that 800 mesh zinc powders are mixed with 500 mesh zinc powders with weight ratio 3:4.
Further, the kaolin is nano-calcination-kaolinite, and kaolin partial size is 50-10nm.
A kind of preparation method of double-component aqueous zinc-rich coating, which is characterized in that preparation step is as follows:
(1) zinc powder is prepared, 800 mesh zinc powders are mixed with 500 mesh zinc powders with weight ratio 3:4, obtain zinc powder after mixing;
(2) component A is prepared, water-compatible amino resin, acrylic emulsion, silica solution, zinc powder are sequentially placed into paint reaction kettle, stirred
Time 1-2H is mixed, stirring rate 750-800r/min obtains component A after mixing evenly;
(3) B component is prepared, kaolin, modified manometer silicon dioxide, deionized water are sequentially placed into paint reaction kettle, is stirred
Time 1-2H, stirring rate 650-800r/min, obtains B component after mixing evenly;
(4) component A and B component are sequentially placed into paint reaction kettle, stirring weight ratio is 7:3, mixing time 1-3H, stirring
Rate 750-900r/min, obtains finished product after mixing evenly.
The invention has the benefit that
The present invention takes new formulation, this Qi Zucheng is simple, easy for construction.Paint film is with excellent electrochemical protection performance and very
Strong adhesive force, can be 400 ~ 500 DEG C of continuous high temperature resistance, and resistivity is low, and antistatic, anti-radiation, salt fog resistance is excellent, have length
The anti-corrosion effect of effect.
And using water as diluent, organic solvent is few, and environmentally protective, VOC emission amount is low, and using effect is good.The present invention uses
Preparation method it is simple, technique simplifies, and is produced only with the process of stirring, and combination reaction is few, does not generate pollution, green
Energy conservation.
Detailed description of the invention
Fig. 1 is paint reaction kettle schematic cross-sectional view.
Fig. 2 is half section structure diagram at Fig. 1 spray head.
Appended drawing reference: shell 1, bottom plate 2, suspension column 3, driving motor bracket 4, driving motor 5, stirring rod 6, agitating shaft 6-1,
Stirrer paddle 6-2, manhole 7, feed inlet 8, discharge port 9, cleaning motor 10, Simmer ring 11, cleaning seat 12, stirring convex block 13,
Cleansing tablet 14, cleaning pipe 15, spray head 16, spray orifice 16-1.
Specific embodiment
It is clear to be more clear technical solution of the present invention, below the present invention is described further, any pair of sheet
The technical characteristic of inventive technique scheme carries out the scheme that equivalencing is obtained with conventional reasoning and each falls within the scope of the present invention.
Embodiment one
A kind of preparation method of double-component aqueous zinc-rich coating, which is characterized in that preparation step is as follows:
(1) zinc powder is prepared, 800 mesh zinc powders are mixed with 500 mesh zinc powders with weight ratio 3:4, obtain zinc powder after mixing;
(2) component A is prepared, water-compatible amino resin, acrylic emulsion, silica solution, zinc powder are sequentially placed into paint reaction kettle, stirred
Time 2H is mixed, stirring rate 800r/min obtains component A after mixing evenly;
(3) B component is prepared, kaolin, modified manometer silicon dioxide, deionized water are sequentially placed into paint reaction kettle, is stirred
Time 2H, stirring rate 800r/min, obtains B component after mixing evenly;
(4) component A and B component are sequentially placed into paint reaction kettle, stirring weight ratio is 7:3, mixing time 3H, stirring speed
Rate 900r/min, obtains finished product after mixing evenly.
Its constituent of component A includes: in parts by weight
45 parts of water-compatible amino resin
25 parts of acrylic emulsion
15 parts of silica solution
18 parts of zinc powder.
Its constituent of B component includes: in parts by weight
15 parts of kaolin
11 parts of modified manometer silicon dioxide
45 parts of deionized water.
Paint reaction kettle used in preparation process, including shell, bottom plate, suspension column, driving motor bracket, driving motor,
Stirring rod, manhole, feed inlet, discharge port, cleaning motor, Simmer ring, cleaning seat, stirring convex block, cleansing tablet, cleaning pipe, spray
Head, the cylindrical shape of shell are hollow structure, the bottom plate rectangular plate structure, the suspension column circumferentially setting
In the housing bottom outer wall, each described suspension column one end and the oblique fixed setting of the shell, the suspension column other end and institute
Bottom plate is stated to achieve a fixed connection by fastener;The driving motor bracket is set to housing tip center, vertical with shell solid
Fixed connection;The driving motor is fixedly installed on housing tip by driving motor bracket, the stirring rod include agitating shaft and
Stirrer paddle, the agitating shaft are in round bar shape structure, and agitating shaft top one end is through shell, driving motor bracket and transmission
Motor is vertically fixedly connected, and the stirrer paddle is in " S " type structure, and the stirrer paddle is set to the agitating shaft bottom end two
Side, is in integral structure, and the stirrer paddle is set in the shell;The manhole is set to housing tip side;It is described
Feed inlet is set to housing tip side, and the discharge port is set to housing bottom side;The cleaning motor is set to shell
Bottom side, the cleaning seat fitting are set to the inner walls bottom end, and described cleaning motor one end is through shell and the cleaning
Seat realizes and is vertically fixedly connected that the cleaning motor realizes that dynamic sealing is connect by Simmer ring with the shell, the stirring
Convex block is circumferentially set to the cleaning seat top surface, and the stirring convex block and the cleaning seat are in integral structure;The cleansing tablet
Quantity is two panels, every piece of L-shaped structure in cleansing tablet section, and the every cleansing tablet is respectively arranged at the cleaning seat two
Side, the every cleansing tablet bottom end are fixedly connected with cleaning seat side;The cleaning pipe is set to the housing tip, described clear
Clean pipe and the shell are vertically through connection, and the spray head is set to the cleaning tube bottom end, the cylindrical shape of spray head,
For hollow structure, the spray head outer wall is circumferentially with spray orifice, and the cleaning pipe is with the spray head top vertically through connection.
Further, the cleaning motor realizes be fixedly connected vertical with bottom plate by fastener with the bottom plate.
Further, the cleaning seat bottom shape and the housing bottom surface inner wall shape are adapted, the cleaning seat top
Face is in convex structure.
Further, each stirring convex block top surface is in convex structure.
Further, the every cleansing tablet is in up-narrow and down-wide structure, and the every cleansing tablet fits in the shell
Wall setting, the every cleaning plate shape and the inner walls shape are adapted.
Further, the fastener is one of setscrew, bolt, nut, screw, tapping screw or a variety of.
The working principle of paint reaction kettle is:
In use, opening driving motor, driving motor drives stirring rod rotation, stirring rod bottom end stirrer paddle rotation, by raw material
It is put into shell from feed inlet, cleaning motor can be opened simultaneously, cleaning motor rotation drives cleaning seat rotation, upper part of the housing
Raw material is stirred by stirrer paddle turning effort, and the raw material of housing bottom is stirred by cleaning the stirring convex block of seat bottom end
It mixes, the raw material of inner walls is stirred by cleansing tablet, at the end of stirring, opens raw material in discharge port discharge shell;This hair
When bright invention is cleaned, cleaning pipe is connected into diluent or other clean solutions, the cleaned pipe of solution enters in spray head, through spray orifice
In injection to inner walls and stirring rod, the raw material of the adherency in inner walls starts to dissolve by the cleaning action of solution, and
By the rotation of the cleansing tablet effect of striking off drainage downwards, waste liquid is discharged by discharge port, the raw material adhered on stirring rod passes through molten
Liquid dissolution, and act on waste liquor stream by the rotating centrifugal of stirring rod down toward housing bottom, and be discharged together from discharge port, it completes
Cleaning action in shell.
Paint reaction kettle has the beneficial effect that
(1) radius is stirred when increasing stirring, the raw material at housing bottom, side wall dead angle can be sufficiently stirred, avoid stirring
Dead angle, stirring efficiency are high.
(2) cleaning action can be achieved, inner walls and the raw material of stirring rod adhering on surface can be cleaned, under guarantee
One is cleaned completely using enclosure interior when the reaction kettle, and raw material generates error when avoiding that equipment stirring is used for multiple times.
Embodiment two
Compared to embodiment one, the present embodiment the difference is that:
A kind of preparation method of double-component aqueous zinc-rich coating, which is characterized in that preparation step is as follows:
(1) zinc powder is prepared, 800 mesh zinc powders are mixed with 500 mesh zinc powders with weight ratio 3:4, obtain zinc powder after mixing;
(2) component A is prepared, water-compatible amino resin, acrylic emulsion, silica solution, zinc powder are sequentially placed into paint reaction kettle, stirred
Time 1H is mixed, stirring rate 750r/min obtains component A after mixing evenly;
(3) B component is prepared, kaolin, modified manometer silicon dioxide, deionized water are sequentially placed into paint reaction kettle, is stirred
Time 1H, stirring rate 650r/min, obtains B component after mixing evenly;
(4) component A and B component are sequentially placed into paint reaction kettle, stirring weight ratio is 7:3, mixing time 1H, stirring speed
Rate 750r/min, obtains finished product after mixing evenly.
Its constituent of component A includes: in parts by weight
35 parts of water-compatible amino resin
12 parts of acrylic emulsion
5 parts of silica solution
11 parts of zinc powder.
Its constituent of B component includes: in parts by weight
5 parts of kaolin
4 parts of modified manometer silicon dioxide
30 parts of deionized water.
Embodiment three
A kind of preparation method of double-component aqueous zinc-rich coating, which is characterized in that preparation step is as follows:
(1) zinc powder is prepared, 800 mesh zinc powders are mixed with 500 mesh zinc powders with weight ratio 3:4, obtain zinc powder after mixing;
(2) component A is prepared, water-compatible amino resin, acrylic emulsion, silica solution, zinc powder are sequentially placed into paint reaction kettle, stirred
Time 1.5H is mixed, stirring rate 780r/min obtains component A after mixing evenly;
(3) B component is prepared, kaolin, modified manometer silicon dioxide, deionized water are sequentially placed into paint reaction kettle, is stirred
Time 1.5H, stirring rate 700r/min, obtains B component after mixing evenly;
(4) component A and B component are sequentially placed into paint reaction kettle, stirring weight ratio is 7:3, mixing time 2H, stirring speed
Rate 800r/min, obtains finished product after mixing evenly.
Its constituent of component A includes: in parts by weight
37 parts of water-compatible amino resin
19 parts of acrylic emulsion
7 parts of silica solution
15 parts of zinc powder.
Its constituent of B component includes: in parts by weight
9 parts of kaolin
6 parts of modified manometer silicon dioxide
38 parts of deionized water.
The key technical indexes of the invention is as follows
Claims (7)
1. a kind of double-component aqueous zinc-rich coating, which is characterized in that including component A and B component, the component A and B component
Weight ratio be 7:3.
2. a kind of double-component aqueous zinc-rich coating as described in claim 1, it is characterized in that, its constituent of component A is pressed
Include: according to parts by weight meter
35-45 parts of water-compatible amino resin
12-25 parts of acrylic emulsion
5-15 parts of silica solution
11-18 parts of zinc powder.
3. a kind of double-component aqueous zinc-rich coating as described in claim 1, it is characterized in that, its constituent of B component is pressed
Include: according to parts by weight meter
5-15 parts of kaolin
4-11 parts of modified manometer silicon dioxide
30-45 parts of deionized water.
4. a kind of double-component aqueous zinc-rich coating as claimed in claim 2, it is characterized in that, the zinc powder is 800 mesh zinc
The mixture of powder and 500 mesh zinc powders.
5. a kind of double-component aqueous zinc-rich coating as claimed in claim 2, it is characterized in that, the zinc powder is 800 mesh zinc
The mixture that powder is mixed with 500 mesh zinc powders with weight ratio 3:4.
6. a kind of double-component aqueous zinc-rich coating as claimed in claim 3, it is characterized in that, the kaolin is forged for nanometer
Kaolin is burnt, kaolin partial size is 50-10nm.
7. a kind of preparation method of double-component aqueous zinc-rich coating, which is characterized in that preparation step is as follows:
Zinc powder is prepared, 800 mesh zinc powders are mixed with 500 mesh zinc powders with weight ratio 3:4, obtain zinc powder after mixing;
Component A is prepared, water-compatible amino resin, acrylic emulsion, silica solution, zinc powder are sequentially placed into paint reaction kettle, is stirred
Time 1-2H, stirring rate 750-800r/min, obtains component A after mixing evenly;
B component is prepared, kaolin, modified manometer silicon dioxide, deionized water are sequentially placed into paint reaction kettle, mixing time
1-2H, stirring rate 650-800r/min, obtains B component after mixing evenly;
Component A and B component are sequentially placed into paint reaction kettle, stirring weight ratio is 7:3, mixing time 1-3H, stirring speed
Rate 750-900r/min, obtains finished product after mixing evenly.
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CN201811391942.1A CN110054957A (en) | 2018-11-21 | 2018-11-21 | A kind of double-component aqueous zinc-rich coating |
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CN201811391942.1A CN110054957A (en) | 2018-11-21 | 2018-11-21 | A kind of double-component aqueous zinc-rich coating |
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Cited By (1)
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CN114806313A (en) * | 2022-04-28 | 2022-07-29 | 湖北巴司特科技股份有限公司 | Preparation method and equipment of high-solid-volume low-voc inorganic hybrid zinc-rich resin paint |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN114806313A (en) * | 2022-04-28 | 2022-07-29 | 湖北巴司特科技股份有限公司 | Preparation method and equipment of high-solid-volume low-voc inorganic hybrid zinc-rich resin paint |
CN114806313B (en) * | 2022-04-28 | 2022-12-16 | 湖北巴司特科技股份有限公司 | Preparation method and equipment of high-solid-volume low-voc inorganic hybrid zinc-rich resin paint |
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Application publication date: 20190726 |