CN109881063A - A kind of high tough high-modulus diecast magnesium alloy and preparation method thereof - Google Patents
A kind of high tough high-modulus diecast magnesium alloy and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a kind of high tough high-modulus diecast magnesium alloys and preparation method thereof, it is made of following element by mass percentage: the Al of a%, the mixing of one or more of La, Ce, Pr of b%, the Mn of c%, one or more of total RE rare earth Gd containing d%, Y, Sm, Nd, Er, Eu, Ho, Tm, Lu, Dy, Yb element, one or more of total Si, Ge, Ca, Li, Sn, Zn, Sb containing e% element, impurity of the total amount less than 0.2%, surplus Mg；A, b, c, d and e meet: 3.5≤a≤6.5,3.5≤b≤4.5,0.01≤c≤1.5,0.01≤d≤3.0 and 0 < e≤5.0.Raw material is preheated, fusing, cast, sand mold gravitational casting obtains Mg alloy castings, and method is simple, technology stability is good and degree of controllability is high.
Description
Technical field
The invention belongs to nonferrous materials and its manufacture fields, and in particular to a kind of high tough high-modulus diecast magnesium alloy
And preparation method thereof.
Background technique
Magnesium and its alloy be industrial applicable most light-weight metal structural material at present, with small (the about aluminium of density
2/3, the 1/4 of steel), specific strength and the advantages that specific stiffness height, damping and amortization, machinability, good casting property, is widely used to
The fields such as automobile, communication electronics, aerospace, military affairs.In recent years, with aerospace and the rapid hair of transport facility
Exhibition, operates that required aerodynamic power is increasing, therefore obdurability to material members and elastoresistance adaptability to changes propose more
High requirement.But the lower absolute intensity of magnesium alloy, plasticity and elasticity modulus constrain its further pushing away in these fields
Extensively with application so that the demand of high tough high-modulus magnesium alloy is higher and higher.
AE44 (Mg-4Al-4RE, wt.%) magnesium alloy is that both had excellent room temperature mechanical property so far in commercial magnesium alloy
Energy (die casting state, tensile strength sigma b > 240MPa, elongation percentage δ > 10.0%), and have both a kind of conjunction of good high-temperature creep resistance
Gold.Its excellent mechanical property has benefited from the Al of Al element and RE Element generation11RE3Hardening constituent, but due to most of Al11RE3
Hardening constituent be it is needle-shaped, can the second phase tip generate stress concentrate, deteriorate material property.In response to this problem, Chinese patent
CN108588524A is gone bad needle-shaped Al by elements such as alloying Gd, Y, Sm11RE3It is mutually corynebacterium or graininess, and introduces
Al2RE hardening constituent significantly improves the obdurability of alloy.For magnesium alloy modulus is promoted, according to mixing rule it is found that introducing high
Matrix modulus can be improved in modulus reinforcement.Chinese patent CN105624502A and CN104087800A are disclosed respectively by adding
Add aluminium oxide and SiC particulate, to obtain the preparation method of high-modulus magnesium-based composite material.But by additional high-modulus reinforcement with
Basal body interface, which is easy to exist, matches bad problem, and routine casting is difficult to ensure that reinforcement is uniformly distributed in the base.And pass through
Addition alloying element in-situ preparation high-modulus reinforced phase can preferably solve the above problems, Chinese patent CN104928549A and
CN104928550A just forms Al using the elements such as addition Al, Li, Si in the magnesium alloy3Li、Mg2The high-modulus such as Si reinforced phase with
Improve magnesium alloy modulus.
Though it is generated in-situ to pass through alloying currently, magnesium alloy modulus can be effectively improved by introducing high-modulus reinforced phase
High-modulus is mutually such as Al3Li、Mg2Si、Al2Ca etc. belongs to brittlement phase, and crack initiation point can be become by being distributed in crystal boundary, reduces magnesium and closes
Golden obdurability, especially plasticity.
Summary of the invention
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to provide a kind of high tough high-modulus diecast magnesium alloy and its
Preparation method.By Reasonable Regulation And Control component ratio, controls reinforced phase and form and ratio is precipitated, so that the alloy is at room temperature
It is provided simultaneously with high-strength tenacity and high elastic modulus.Alloy provided by the invention can satisfy high tough high-modulus light material and
(or) components manufacture demand.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of high tough high-modulus diecast magnesium alloy, is made of: the Al of a%, b% following element by mass percentage
One or more of La, Ce, Pr mixing, the Mn of c%, add up to the RE rare earth Gd containing d%, Y, Sm, Nd, Er,
One or more of Eu, Ho, Tm, Lu, Dy, Yb element add up to one of Si, Ge, Ca, Li, Sn, Zn, Sb containing e%
Or several elements, impurity of the total amount less than 0.2%, surplus Mg, a, b, c, d and e meet following formulas (1)~(5),
(1)3.5≤a≤6.5；
(2)3.5≤b≤4.5；
(3)0.01≤c≤1.5；
(4)0.01≤d≤3.0；
(5)0<e≤5.0。
Preferably, in the formula (3) c value range are as follows: 0.2≤c≤1.5.Mn element additive amount >=0.2 can significantly mention
Corrosion resistance, enhancing aging response effect and raising elasticity modulus of high magnesium alloy etc., but additive amount > 1.5, can generate coarse
Al-Mn-RE phase, deteriorate material property.
Preferably, in the formula (4) d value range are as follows: 0.1≤d≤3.0.The rare earth elements such as Gd, Y, Sm consolidating in Mg
Solubility is larger, the additive amount of d >=0.1 ageing strengthening, rotten Al in formula (4)11RE3Second phase effect more preferably, but additive amount > 3.0
Matrix is isolated in the roughening that will cause the second phase during military service, and as crack initiation point severe exacerbation material mechanical performance.
Preferably, in the formula (5) e value range are as follows: 0.2≤e≤4.0.The elements such as Si, Ge, Ca, Li, Sn are in Mg
Solid solubility is smaller, in magnesium-rare earth containing Al, mainly forms reinforced phase reinforced alloys performance with other alloying elements.Formula (5)
The effect that alloy modulus is improved in the additive amount of middle e >=0.1 is more significant, but additive amount > 4.0 reinforced phases can excessively be roughened, so that
Alloy obdurability drastically reduces.
The independent role of alloying element
Wherein, 1) Al is used for balanced alloy strength, plasticity, improves Production Practice of Casting Technologies, makes the suitable big batch of the present invention
Production.2) for La, Ce, Pr element for improving alloy mechanical property, La, Ce, Pr element and aluminium are preferentially produced Al11RE3Phase inhibits
Generate the Mg of thermostability difference17Al12Phase improves the room temperature and mechanical behavior under high temperature of alloy；In addition, La, Ce, Pr can remove it is molten
Impurity when refining in magnesium alloy fused mass achievees the effect that refinery by de-gassing, purification melt.3) Mn is used to improve the corrosion resistance of alloy
Can, Mn can form compound with iron in magnesium alloy or other heavy metal elements, remove it mostly as slag；Mn can also promote
Into the ageing strengthening effect of alloy, Al-Mn nanometers of timeliness phases are formed, alloy obdurability and modulus are further increased；In addition, 720
At DEG C, solid solubility of the Mn in Mg is~1.1at.%, and under die-casting process, part Mn element, which has little time to be precipitated, forms supersaturation
Solid solution reduces matrix lattice constant, improves alloy elastic modulus.4) rare earth elements such as Gd, Y, Sm solid solubility in Mg is larger,
Mainly exist in the form of three kinds in magnesium alloy containing Al: solid solution is in the base；Segregation is in crystal boundary, phase boundary and dendrite circle；It is solid-solubilized in
In compound or formed compound.Above-mentioned rare earth element is added into alloy, can be played the role of solution strengthening, be improved intensity.
The content of above-mentioned rare earth is further increased, fine particle shape high-melting-point Al can be preferentially produced with Al element2RE intermetallic compound,
Crystal grain can be refined as heterogeneous forming core core, and Dispersed precipitate changes crack initiation position during alloy fracture in matrix
With extension approach, the plasticity of alloy is further increased.In addition, the addition of the rare earth elements such as Gd, Y, Sm can also promote magnesium containing Al
The ageing strengthening effect of alloy further increases the intensity and modulus of alloy.5) elements such as Si, Ge, Ca, Li, Sn are solid in Mg
Solubility is lower, mainly generates reinforced phase with Mg or Al in magnesium alloy containing Al.As shown in table 1, the above element and Mg or Al are preferential
The reinforced phase elasticity modulus range of generation is 80~120GPa.According to mixing rule it is found that the reinforced phase being distributed in alloy substrate
Modulus is higher, and volume ratio is bigger, and the modulus of alloy is higher.And the test modulus value of Mg is 39~46GPa, therefore shown in table 1
Reinforced phase can effectively improve the elasticity modulus of magnesium alloy.
Table 1: the elasticity modulus of reinforced phase
The synergistic effect of alloying element
High tough high-modulus magnesium alloy, can further regulate and control the addition element type and content of different component in the present invention,
Crystal grain, rotten second phase can be further refined, alloy obdurability and elasticity modulus are improved.1) rare earth elements such as Gd, Y, Sm exist
Solute distribution coefficient k < 1 in Mg, and Rare-Earth Element Chemistry activity is extremely strong segregation and can be adsorbed on the crystal grain boundary or branch grown up
On crystal boundary face, crystal grain and dendrite are hindered, can significantly refine crystal grain, granulating Al11RE3Needlelike phase greatly improves alloy properties
Energy, especially plasticity.2) rare earth elements such as Gd, Y, Sm can go bad Chinese character shape Mg2Si and Al in net distribution2Ca is particle
Shape reduces isolate effect of the high-modulus reinforced phase to matrix, while capable of improving alloy modulus, does not drop low-alloyed obdurability.
Preferably, in the magnesium alloy materials, 3.6%≤b+d≤7.0%.It is further preferred that the magnesium alloy materials
In, 4.5%≤b+d≤6.0%.
The preparation method of the above-mentioned tough high-modulus diecast magnesium alloy of height, includes the following steps,
S1: molten alloy, by pure Mg, pure Al, magnesium rare earth intermediate alloy, aluminium manganese or magnesium manganese intermediate alloy and remaining group
Divide and preheats respectively；
Preferably, in the step S1, preheating temperature is 200~250 DEG C, and preheating time is 2~6 hours.The preheating
Temperature and time can effectively remove the moisture of raw material, and be avoided that raw material surface excessive oxidation in warm is asked
Topic.
Preferably, in the step S1, magnesium rare earth intermediate alloy is magnesium cerium-rich mischmetal intermediate alloy, the centre conjunction of magnesium lanthanum
Gold, magnesium cerium intermediate alloy, magnesium praseodymium intermediate alloy, magnesium samarium intermediate alloy, magnesium gadolinium intermediate alloy, magnesium yttrium intermediate alloy, magnesium richness yttrium are mixed
Close rare earth intermediate alloy, magnesium neodymium intermediate alloy, magnesium praseodymium neodymium mixed rare-earth intermediate alloy, magnesium erbium intermediate alloy, magnesium europium intermediate alloy,
One of magnesium holmium intermediate alloy, magnesium thulium intermediate alloy, magnesium lutetium intermediate alloy, magnesium dysprosium intermediate alloy, magnesium ytterbium intermediate alloy are several
The combination of kind intermediate alloy.
Contain tri- kinds of rare earth elements of La, Ce, Pr in the cerium-rich mischmetal.
Preferably, in the step S1, remaining group is divided into Mg-based master alloy or contained aluminium-base intermediate alloy or pure metal.It is described
Mg-based master alloy is magnesium silicon intermediate alloy, magnesium calcium intermediate alloy, magnesium lithium intermediate alloy, magnesium zinc intermediate alloy, the centre conjunction of magnesium antimony
The combination of one or more of gold intermediate alloy；The contained aluminium-base intermediate alloy is aluminium silicon intermediate alloy, aluminium germanium intermediate alloy, aluminium
The group of one or more of calcium intermediate alloy, aluminium lithium intermediate alloy, aluminium tin intermediate alloy, aluminium antimony intermediate alloy intermediate alloy
It closes；The pure metal is one or both of pure silicon, pure zinc.
S2: the pure Mg after preheating is completely melt in protective atmosphere；It is pure after preheating is added at 670~690 DEG C
Al；When temperature is raised to 720~740 DEG C, the intermediate alloy or pure metal after preheating is added；It is completely molten to intermediate alloy or pure metal
It is warming up to 720~740 DEG C after change, refining agent is added and is refined, is stood after refining at 710-730 DEG C, it is cooled to 680~
Skimming operation after 700 DEG C obtains magnesium alloy fused mass, or casting obtains magnesium alloy ingot；
Preferably, in step S2, refining agent is added and is refined, at 720 DEG C after refining, is stood.Refining temperature choosing
Select 720 DEG C, refining effect is best, can degasification to the full extent slagging-off, purify melt.
The protective atmosphere of the step S2 is SF6And CO2Mixed gas.Preferably, the SF6And CO2Volume ratio be
1:99.
The refining agent of the step S2 is the refining agent of Mg alloy containing inorganic salts, it is preferred that sodium salt, sylvite, villiaumite
Inorganic salts refining agent of Mg alloy or carbon trichloride.
Preferably, the additional amount of refining agent is the 1-5% of all total mass of raw materiales.
S3: in step S2 magnesium alloy fused mass or magnesium alloy ingot remelting after carry out evacuated die-casting process or antivacuum die casting,
Obtain Mg alloy castings.
Preferably, the process conditions of the evacuated die-casting process are, by magnesium alloy fused mass or magnesium alloy ingot remelting, 680~
Die casting is carried out at 700 DEG C, obtains Mg alloy castings, and the effective vacuum pressure of type chamber is 1~10kPa, and mold temperature is 220~300
DEG C, low speed speed is 0.2~0.4m/s, and high speed speed is 1.0~3.0m/s, and pressure charging press-shoot power is 20~50MPa；The vacuum
The casting of Die Casting, good compactness, inner void defect are few, can carry out effective heat treatment reinforcement.
Preferably, the process conditions of the antivacuum die casting are, by magnesium alloy fused mass or magnesium alloy ingot remelting, 680
It carrying out die casting at~700 DEG C, obtains Mg alloy castings, metal die temperature is 220~300 DEG C, low speed speed is 0.2~
0.4m/s, high speed speed are 1.0~3.0m/s, and pressure charging press-shoot power is 20~50MPa.The melt cast temperature and metal die
Temperature makes melt have good mobility, feeding in press casting procedure；The low speed speed and high speed speed energy maximum journey
Melt volume gas is reduced on degree, avoids the hole defect that cast-internal is excessive；The pressure charging press-shoot power can be in melt process of setting
Compact tissue is finally perfected, the few die casting of defect.
The tough high-modulus diecast magnesium alloy of height produced by the invention can be used directly, or the magnesium prepared in step S3 is closed
Golden evacuated die-casting process part carries out solution treatment, artificial aging processing.
Preferably, the temperature of the solution treatment is 300~500 DEG C, and the time of the solution treatment is 0.1~4 hour；
The temperature of the artificial aging processing is 175~225 DEG C, and the time of the ageing treatment is 1~32 hour.The solution treatment
Technique can to the full extent dissolve in the second phase in magnesium matrix under the premise of avoiding casting from occurring being bubbled or deforming；When described
Effect treatment process can make casting obtain significant ageing strengthening effect.
Or the Mg alloy castings prepared in step S3 are subjected to direct labor's ageing treatment, the temperature of the ageing treatment
It is 175~225 DEG C, the time of the ageing treatment is 1~32 hour.
Preferably, the Cooling Method After Heat-treatment is air-cooled or water cooling.
Compared with prior art, the beneficial effects of the present invention are:
1, magnesium alloy materials prepared by the present invention compared with prior art, can guarantee preferably again while improving elasticity modulus
Obdurability.The present invention introduces Mg using alloyage process in situ2Si、Al2Ca or Al3Li et al. high-modulus hardening constituent, significantly improves
Alloy elastic modulus.
2, the RE such as Gd, Y, Nd element is in addition to that can refine matrix, and go bad Al11RE3Needlelike phase introduces Al2RE hardening constituent, mentions
The obdurability of high alloy, the Chinese character shape that can also go bad Mg2Si, netted Al2Ca reinforced phase, improve alloy elastic modulus while again
Preferable obdurability can be had both.
3, this preparation method is simple, technology stability is good, technique degree of controllability is high.
Specific embodiment
Below with reference to embodiment, the invention will be further described:
Various intermediate alloys used in the present invention are commercial product, and the magnesium rare earth intermediate alloy is purchased from Ganzhou and soars
Light-alloy Co., Ltd.
Embodiment 1:
The alloying component (mass percent) of diecast magnesium alloy: 3.50%Al, 1.72%Ce, 0.87%La, 0.91%Pr,
1.19%Sm, 1.76%Gd, 0.01%Dy, 0.04%Er, 0.01%Lu, 0.5%Si, 0.01%Mn, it is other inevitable
For impurity less than 0.2%, remaining is Mg.
The present embodiment is related to the alloy die cast method in the method for smelting and the present invention of conventional rare magnesium alloy:
Wherein, melting process is in SF6And CO2It is carried out under the conditions of mixed gas protected, steps are as follows:
(1) baking material: melting raw material is preheated 3 hours at 200 DEG C；
(2) it melts magnesium: the pure magnesium after drying has been put into SF6/CO2It is melted in the crucible electrical resistance furnace of gas shield；
(3) add fine aluminium and magnesium manganese intermediate alloy: pure after preheating is added after temperature reaches 670 DEG C when pure magnesium is completely melt
Aluminium, magnesium manganese intermediate alloy；
(4) plus intermediate alloy: when temperature is raised to 720 DEG C, the magnesium cerium-rich mischmetal intermediate alloy, magnesium samarium after preheating is added
Intermediate alloy, magnesium gadolinium intermediate alloy, magnesium dysprosium intermediate alloy, magnesium erbium intermediate alloy, magnesium lutetium intermediate alloy, magnesium silicon intermediate alloy.
(5) refining agent is added after intermediate alloy is completely melt, when melt temperature gos up to 720 DEG C to be refined, refines
It is stood afterwards at 720 DEG C, skimming operation after being cooled to 680 DEG C, obtains magnesium alloy fused mass, casting obtains magnesium alloy ingot；
Die casting process are as follows:
By the magnesium alloy ingot remelting, die casting is carried out at 680 DEG C, obtains Mg alloy castings, and metal die temperature is
300 DEG C, low speed speed is 0.2m/s, and high speed speed is 1.0m/s, and pressure charging press-shoot power is 50MPa.
The room-temperature mechanical property test result of the embodiment of the present invention 1 is as shown in table 2.
Embodiment 2:
The alloying component (mass percent) of high tough high-modulus diecast magnesium alloy: 5.67%Al, 2.20%Ce, 1.13%
La, 1.17%Pr, 0.01%Sm, 5.00%Si, 0.41%Mn, for other inevitable impurity less than 0.2%, remaining is Mg.
The present embodiment is related to the alloy die cast method in the method for smelting and the present invention of conventional rare magnesium alloy:
Wherein, melting process is in SF6And CO2It is carried out under the conditions of mixed gas protected, steps are as follows:
(1) baking material: melting raw material is preheated 2 hours at 250 DEG C；
(2) it melts magnesium: the pure magnesium after drying has been put into SF6/CO2It is melted in the crucible electrical resistance furnace of gas shield；
(3) add fine aluminium and magnesium manganese intermediate alloy: pure after preheating is added after temperature reaches 680 DEG C when pure magnesium is completely melt
Aluminium, magnesium manganese intermediate alloy；
(4) plus intermediate alloy: when temperature is raised to 730 DEG C, the magnesium cerium-rich mischmetal intermediate alloy, magnesium samarium after preheating is added
Intermediate alloy, aluminium silicon intermediate alloy；
(5) refining agent is added after intermediate alloy is completely melt, when melt temperature gos up to 730 DEG C to be refined, refines
It is stood afterwards at 720 DEG C, skimming operation after being cooled to 690 DEG C obtains magnesium alloy fused mass；
Die casting process are as follows:
The magnesium alloy fused mass is subjected to die casting at 690 DEG C, obtains Mg alloy castings, metal die temperature is 250 DEG C,
Low speed speed is 0.3m/s, and high speed speed is 2.0m/s, and pressure charging press-shoot power is 30MPa.
The room-temperature mechanical property test result of the embodiment of the present invention 2 is as shown in table 2.
Embodiment 3:
The alloying component (mass percent) of high tough high-modulus diecast magnesium alloy: 4.69%Al, 1.92%Ce, 2.07%
La, 0.16%Sm, 0.11%Nd, 0.40%Gd, 0.31%Y, 1.00%Si, 0.34%Mn, other inevitable impurity are small
In 0.2%, remaining is Mg.
The present embodiment is related to the alloy die cast method in the method for smelting and the present invention of conventional rare magnesium alloy:
Wherein, melting process is in SF6And CO2It is carried out under the conditions of mixed gas protected, steps are as follows:
(1) baking material: melting raw material is preheated 6 hours at 200 DEG C；
(2) it melts magnesium: the pure magnesium after drying has been put into SF6/CO2It is melted in the crucible electrical resistance furnace of gas shield；
(3) add fine aluminium and magnesium manganese intermediate alloy: pure after preheating is added after temperature reaches 690 DEG C when pure magnesium is completely melt
Aluminium, magnesium manganese intermediate alloy；
(4) plus intermediate alloy: when temperature is raised to 740 DEG C, the magnesium mixed rare earth of lanthanum and cerium intermediate alloy, magnesium samarium after preheating is added
Intermediate alloy, magnesium neodymium intermediate alloy, magnesium gadolinium intermediate alloy, magnesium yttrium intermediate alloy and magnesium silicon intermediate alloy；
(5) refining agent is added after intermediate alloy fusing, when melt temperature gos up to 740 DEG C to be refined, after refining
720 DEG C are stood, and skimming operation after being cooled to 700 DEG C obtains magnesium alloy fused mass；
Die casting process are as follows:
The magnesium alloy fused mass is subjected to die casting at 700 DEG C, obtains Mg alloy castings, metal die temperature is 220 DEG C,
Low speed speed is 0.3m/s, and high speed speed is 2.0m/s, and pressure charging press-shoot power is 30MPa.
The room-temperature mechanical property test result of the embodiment of the present invention 3 is as shown in table 2.
Embodiment 4:
The alloying component (mass percent) of high tough high-modulus diecast magnesium alloy: 5.11%Al, 1.92%Ce, 2.07%
La, 0.16%Sm, 0.11%Nd, 0.40%Gd, 0.31%Y, 0.03%Eu, 1.00%Si, 1.00%Zn, 0.34%Mn,
For its inevitable impurity less than 0.2%, remaining is Mg.
The present embodiment is related to the alloy die cast method in the method for smelting and the present invention of conventional rare magnesium alloy:
Wherein, melting process is in SF6And CO2It is carried out under the conditions of mixed gas protected, steps are as follows:
(1) baking material: melting raw material is preheated 3 hours at 200 DEG C；
(2) it melts magnesium: the pure magnesium after drying has been put into SF6/CO2It is melted in the crucible electrical resistance furnace of gas shield；
(3) add fine aluminium, pure zinc and aluminium manganese intermediate alloy: when pure magnesium is completely melt, after temperature reaches 670 DEG C, preheating is added
Fine aluminium, pure zinc, aluminium manganese intermediate alloy afterwards；
(4) plus intermediate alloy: when temperature is raised to 720 DEG C, magnesium lanthanum intermediate alloy, magnesium cerium intermediate alloy after preheating is added,
Magnesium samarium intermediate alloy, magnesium neodymium intermediate alloy, magnesium gadolinium intermediate alloy, magnesium yttrium intermediate alloy, magnesium europium intermediate alloy, magnesium silicon centre are closed
Gold；
(5) refining agent is added after intermediate alloy fusing, when melt temperature gos up to 720 DEG C to be refined, after refining
720 DEG C are stood, and skimming operation after being cooled to 680 DEG C obtains magnesium alloy fused mass；
Die casting process are as follows:
The magnesium alloy fused mass is subjected to die casting at 680 DEG C, obtains Mg alloy castings, metal die temperature is 300 DEG C,
Low speed speed is 0.2m/s, and high speed speed is 2.0m/s, and pressure charging press-shoot power is 40MPa.
The room-temperature mechanical property test result of the embodiment of the present invention 4 is as shown in table 2.
Embodiment 5:
The alloying component (mass percent) of high tough high-modulus diecast magnesium alloy: 5.50%Al, 1.92%Ce, 2.07%
La, 0.16%Sm, 0.11%Nd, 0.40%Gd, 0.31%Y, 2.00%Si, 1.00%Zn, 0.34%Mn, it is other inevitable
Impurity less than 0.2%, remaining is Mg.
The present embodiment is related to the alloy die cast method in the method for smelting and the present invention of conventional rare magnesium alloy:
Wherein, melting process is in SF6And CO2It is carried out under the conditions of mixed gas protected, steps are as follows:
(1) baking material: melting raw material is preheated 3 hours at 200 DEG C；
(2) it melts magnesium: the pure magnesium after drying has been put into SF6/CO2It is melted in the crucible electrical resistance furnace of gas shield；
(3) add fine aluminium, pure zinc and magnesium manganese intermediate alloy: when pure magnesium is completely melt, after temperature reaches 690 DEG C, preheating is added
Fine aluminium, pure zinc, magnesium manganese intermediate alloy afterwards；
(4) plus intermediate alloy: when temperature is raised to 740 DEG C, magnesium lanthanum intermediate alloy, magnesium cerium intermediate alloy after preheating is added,
Magnesium samarium intermediate alloy, magnesium neodymium intermediate alloy, magnesium gadolinium intermediate alloy, magnesium yttrium intermediate alloy, magnesium silicon intermediate alloy；
(5) refining agent is added after intermediate alloy fusing, when melt temperature gos up to 740 DEG C to be refined, after refining
720 DEG C are stood, and skimming operation after being cooled to 700 DEG C obtains magnesium alloy fused mass；
Die casting process are as follows:
The magnesium alloy fused mass is subjected to die casting at 700 DEG C, obtains Mg alloy castings, metal die temperature is 220 DEG C,
Low speed speed is 0.3m/s, and high speed speed is 2.0m/s, and pressure charging press-shoot power is 30MPa.
The room-temperature mechanical property test result of the embodiment of the present invention 5 is as shown in table 2.
Embodiment 6:
The alloying component (mass percent) of high tough high-modulus diecast magnesium alloy: 6.50%Al, 1.92%Ce, 2.07%
La, 0.16%Sm, 0.11%Nd, 0.40%Gd, 0.31%Y, 2.00%Si, 2.00%Zn, 0.34%Mn, it is other inevitable
Impurity less than 0.2%, remaining is Mg.
The present embodiment is related to the alloy die cast method in the method for smelting and the present invention of conventional rare magnesium alloy:
Wherein, melting process is in SF6And CO2It is carried out under the conditions of mixed gas protected, steps are as follows:
(1) baking material: melting raw material is preheated 3 hours at 200 DEG C；
(2) it melts magnesium: the pure magnesium after drying has been put into SF6/CO2It is melted in the crucible electrical resistance furnace of gas shield；
(3) add fine aluminium, pure zinc and aluminium manganese intermediate alloy: when pure magnesium is completely melt, after temperature reaches 680 DEG C, preheating is added
Fine aluminium, pure zinc, aluminium manganese intermediate alloy afterwards；
(4) plus intermediate alloy: when temperature is raised to 730 DEG C, be added preheated magnesium lanthanum intermediate alloy, magnesium cerium intermediate alloy,
Magnesium samarium intermediate alloy, magnesium neodymium intermediate alloy, magnesium gadolinium intermediate alloy, magnesium yttrium intermediate alloy, magnesium silicon intermediate alloy；
(5) refining agent is added after intermediate alloy is completely melt, when melt temperature gos up to 730 DEG C to be refined, refines
It is stood afterwards at 720 DEG C, skimming operation after being cooled to 690 DEG C obtains magnesium alloy fused mass；
Die casting process are as follows:
The magnesium alloy fused mass is subjected to die casting at 690 DEG C, obtains Mg alloy castings, metal die temperature is 250 DEG C,
Low speed speed is 0.3m/s, and high speed speed is 2.0m/s, and pressure charging press-shoot power is 20MPa.
The room-temperature mechanical property test result of the embodiment of the present invention 6 is as shown in table 2.
Embodiment 7:
The alloying component (mass percent) of high tough high-modulus diecast magnesium alloy: 5.30%Al, 1.92%Ce, 2.07%
La, 0.16%Sm, 0.11%Nd, 0.40%Gd, 0.31%Y, 0.03%Tb, 1.00%Ge, 1.00%Zn, 1.50%Mn,
For its inevitable impurity less than 0.2%, remaining is Mg.
The present embodiment is related to the alloy die cast method in the method for smelting and the present invention of conventional rare magnesium alloy:
Wherein, melting process is in SF6And CO2It is carried out under the conditions of mixed gas protected, steps are as follows:
(1) baking material: melting raw material is preheated 3 hours at 200 DEG C；
(2) it melts magnesium: the pure magnesium after drying has been put into SF6/CO2It is melted in the crucible electrical resistance furnace of gas shield；
(3) add fine aluminium, pure zinc and aluminium manganese intermediate alloy: when pure magnesium is completely melt, after temperature reaches 670 DEG C, preheating is added
Fine aluminium, pure zinc, aluminium manganese intermediate alloy afterwards；
(4) plus intermediate alloy: when temperature is raised to 720 DEG C, magnesium lanthanum intermediate alloy, magnesium cerium intermediate alloy after preheating is added,
Magnesium samarium intermediate alloy, magnesium neodymium intermediate alloy, magnesium gadolinium intermediate alloy, magnesium yttrium intermediate alloy, magnesium terbium intermediate alloy, magnesium germanium centre are closed
Gold；
(5) refining agent is added after intermediate alloy fusing, when melt temperature gos up to 720 DEG C to be refined, after refining
720 DEG C are stood, and skimming operation after being cooled to 680 DEG C obtains magnesium alloy fused mass；
Die casting process are as follows:
The magnesium alloy fused mass is subjected to die casting at 680 DEG C, obtains Mg alloy castings, metal die temperature is 300 DEG C,
Low speed speed is 0.4m/s, and high speed speed is 3.0m/s, and pressure charging press-shoot power is 20MPa.
The room-temperature mechanical property test result of the embodiment of the present invention 7 is as shown in table 2.
Embodiment 8:
The alloying component (mass percent) of high tough high-modulus diecast magnesium alloy: 6.00%Al, 1.92%Ce, 2.07%
La, 0.16%Sm, 0.11%Nd, 0.40%Gd, 0.31%Y, 0.02%Ho, 0.70%Li, 0.34%Mn, it is other inevitable
Impurity less than 0.2%, remaining is Mg.
The present embodiment is related to the alloy die cast method in the method for smelting and the present invention of conventional rare magnesium alloy:
Wherein, melting process is in SF6And CO2It is carried out under the conditions of mixed gas protected, steps are as follows:
(1) baking material: melting raw material is preheated 3 hours at 200 DEG C；
(2) it melts magnesium: the pure magnesium after drying has been put into SF6/CO2It is melted in the crucible electrical resistance furnace of gas shield；
(3) add fine aluminium and aluminium manganese intermediate alloy: pure after preheating is added after temperature reaches 690 DEG C when pure magnesium is completely melt
Aluminium, aluminium manganese intermediate alloy；
(4) plus intermediate alloy: when temperature is raised to 740 DEG C, magnesium lanthanum intermediate alloy, magnesium cerium intermediate alloy after preheating is added,
Magnesium samarium intermediate alloy, magnesium neodymium intermediate alloy, magnesium gadolinium intermediate alloy, magnesium yttrium intermediate alloy, magnesium holmium intermediate alloy, magnesium lithium centre are closed
Gold；
(5) refining agent is added after the fusing of magnesium rare earth intermediate alloy, when melt temperature gos up to 740 DEG C to be refined, essence
It is stood after refining at 720 DEG C, skimming operation after being cooled to 700 DEG C obtains magnesium alloy fused mass；
Die casting process are as follows:
The magnesium alloy fused mass is subjected to die casting at 700 DEG C, obtains Mg alloy castings, metal die temperature is 220 DEG C,
Low speed speed is 0.3m/s, and high speed speed is 2.0m/s, and pressure charging press-shoot power is 50MPa.
The room-temperature mechanical property test result of the embodiment of the present invention 8 is as shown in table 2.
Embodiment 9:
The alloying component (mass percent) of high tough high-modulus diecast magnesium alloy: 6.00%Al, 1.92%Ce, 2.07%
La, 0.16%Sm, 0.11%Nd, 0.40%Gd, 0.31%Y, 0.70%Li, 0.50%Si, 0.50%Zn, 0.34%Mn,
For its inevitable impurity less than 0.2%, remaining is Mg.
The present embodiment is related to the alloy die cast method in the method for smelting and the present invention of conventional rare magnesium alloy:
Wherein, melting process is in SF6And CO2It is carried out under the conditions of mixed gas protected, steps are as follows:
(1) baking material: melting raw material is preheated 3 hours at 200 DEG C；
(2) it melts magnesium: the pure magnesium after drying has been put into SF6/CO2It is melted in the crucible electrical resistance furnace of gas shield；
(3) add fine aluminium, pure zinc and aluminium manganese intermediate alloy: when pure magnesium is completely melt, after temperature reaches 680 DEG C, preheating is added
Fine aluminium, pure zinc, aluminium manganese intermediate alloy afterwards；
(4) plus intermediate alloy: when temperature is raised to 730 DEG C, magnesium lanthanum intermediate alloy, magnesium cerium intermediate alloy after preheating is added,
Magnesium samarium intermediate alloy, magnesium neodymium intermediate alloy, magnesium gadolinium intermediate alloy, magnesium yttrium intermediate alloy, magnesium lithium intermediate alloy, aluminium silicon centre are closed
Gold；
(5) refining agent is added after intermediate alloy fusing, when melt temperature gos up to 730 DEG C to be refined, after refining
720 DEG C are stood, and skimming operation after being cooled to 690 DEG C obtains magnesium alloy fused mass；
Die casting process are as follows:
The magnesium alloy fused mass is subjected to die casting at 690 DEG C, obtains Mg alloy castings, metal die temperature is 250 DEG C,
Low speed speed is 0.3m/s, and high speed speed is 3.0m/s, and pressure charging press-shoot power is 30MPa.
The room-temperature mechanical property test result of the embodiment of the present invention 9 is as shown in table 2.
Embodiment 10:
The alloying component (mass percent) of diecast magnesium alloy: 5.00%Al, 1.92%Ce, 2.07%La, 0.16%Sm,
0.11%Nd, 0.40%Gd, 0.31%Y, 0.20%Ca, 0.34%Mn, other inevitable impurity less than 0.2%, remaining
For Mg.
The present embodiment is related to the alloy die cast method in the method for smelting and the present invention of conventional rare magnesium alloy:
Wherein, melting process is in SF6And CO2It is carried out under the conditions of mixed gas protected, steps are as follows:
(1) baking material: melting raw material is preheated 3 hours at 200 DEG C；
(2) it melts magnesium: the pure magnesium after drying has been put into SF6/CO2It is melted in the crucible electrical resistance furnace of gas shield；
(3) add fine aluminium and magnesium manganese intermediate alloy: pure after preheating is added after temperature reaches 690 DEG C when pure magnesium is completely melt
Aluminium, magnesium manganese intermediate alloy；
(4) plus intermediate alloy: when temperature is raised to 740 DEG C, magnesium lanthanum intermediate alloy, magnesium cerium intermediate alloy after preheating is added,
Magnesium samarium intermediate alloy, magnesium neodymium intermediate alloy, magnesium gadolinium intermediate alloy, magnesium yttrium intermediate alloy, magnesium calcium intermediate alloy；
(5) refining agent is added after intermediate alloy fusing, when melt temperature gos up to 740 DEG C to be refined, after refining
720 DEG C are stood, and skimming operation after being cooled to 700 DEG C obtains magnesium alloy fused mass；
Die casting process are as follows:
The magnesium alloy fused mass is subjected to die casting at 700 DEG C, obtains Mg alloy castings, metal die temperature is 200 DEG C,
Low speed speed is 0.3m/s, and high speed speed is 2.0m/s, and pressure charging press-shoot power is 30MPa.
The room-temperature mechanical property test result of the embodiment of the present invention 10 is as shown in table 2.
Embodiment 11:
The alloying component (mass percent) of high tough high-modulus diecast magnesium alloy: 5.00%Al, 1.92%Ce, 2.07%
La, 0.16%Sm, 0.11%Nd, 0.40%Gd, 0.31%Y, 0.01%Tm, 0.50%Ca, 0.34%Mn, it is other inevitable
Impurity less than 0.2%, remaining is Mg.
The present embodiment is related to the alloy die cast method in the method for smelting and the present invention of conventional rare magnesium alloy:
Wherein, melting process is in SF6And CO2It is carried out under the conditions of mixed gas protected, steps are as follows:
(1) baking material: melting raw material is preheated 3 hours at 200 DEG C；
(2) it melts magnesium: the pure magnesium after drying has been put into SF6/CO2It is melted in the crucible electrical resistance furnace of gas shield；
(3) add fine aluminium and aluminium manganese intermediate alloy: pure after preheating is added after temperature reaches 680 DEG C when pure magnesium is completely melt
Aluminium, aluminium manganese intermediate alloy；
(4) plus intermediate alloy: when temperature is raised to 730 DEG C, magnesium lanthanum intermediate alloy, magnesium cerium intermediate alloy after preheating is added,
Magnesium samarium intermediate alloy, magnesium neodymium intermediate alloy, magnesium gadolinium intermediate alloy, magnesium yttrium intermediate alloy, magnesium thulium intermediate alloy, magnesium calcium centre are closed
Gold；
(5) refining agent is added after intermediate alloy fusing, when melt temperature gos up to 730 DEG C to be refined, after refining
720 DEG C are stood, and skimming operation after being cooled to 690 DEG C obtains magnesium alloy fused mass；
Die casting process are as follows:
The magnesium alloy fused mass is subjected to die casting at 690 DEG C, obtains Mg alloy castings, metal die temperature is 250 DEG C,
Low speed speed is 0.3m/s, and high speed speed is 3.0m/s, and pressure charging press-shoot power is 30MPa.
The room-temperature mechanical property test result of the embodiment of the present invention 11 is as shown in table 2.
Embodiment 12:
The alloying component (mass percent) of high tough high-modulus diecast magnesium alloy: 5.00%Al, 1.92%Ce, 2.07%
La, 0.16%Sm, 0.11%Nd, 0.40%Gd, 0.31%Y, 0.50%Ca, 0.20%Sb, 0.34%Mn, it is other inevitable
Impurity less than 0.2%, remaining is Mg.
The present embodiment is related to the alloy die cast method in the method for smelting and the present invention of conventional rare magnesium alloy:
Wherein, melting process is in SF6And CO2It is carried out under the conditions of mixed gas protected, steps are as follows:
(1) baking material: melting raw material is preheated 3 hours at 200 DEG C；
(2) it melts magnesium: the pure magnesium after drying has been put into SF6/CO2It is melted in the crucible electrical resistance furnace of gas shield；
(3) add fine aluminium and aluminium manganese intermediate alloy: pure after preheating is added after temperature reaches 670 DEG C when pure magnesium is completely melt
Aluminium, aluminium manganese intermediate alloy；
(4) plus intermediate alloy: when temperature is raised to 720 DEG C, magnesium lanthanum intermediate alloy, magnesium cerium intermediate alloy after preheating is added,
Magnesium samarium intermediate alloy, magnesium neodymium intermediate alloy, magnesium gadolinium intermediate alloy, magnesium yttrium intermediate alloy, aluminium calcium intermediate alloy, aluminium antimony centre are closed
Gold；
(5) refining agent is added after the fusing of magnesium rare earth intermediate alloy, when melt temperature gos up to 720 DEG C to be refined, essence
It is stood after refining at 720 DEG C, skimming operation after being cooled to 680 DEG C obtains magnesium alloy fused mass；
Die casting process are as follows:
The magnesium alloy fused mass is subjected to die casting at 680 DEG C, obtains Mg alloy castings, metal die temperature is 300 DEG C,
Low speed speed is 0.4m/s, and high speed speed is 2.0m/s, and pressure charging press-shoot power is 20MPa.
The room-temperature mechanical property test result of the embodiment of the present invention 12 is as shown in table 2.
Embodiment 13:
The alloying component (mass percent) of high tough high-modulus diecast magnesium alloy: 4.50%Al, 1.92%Ce, 2.07%
La, 0.16%Sm, 0.11%Nd, 0.40%Gd, 0.31%Y, 1.00%Sn, 0.73%Mn, other inevitable impurity are small
In 0.2%, remaining is Mg.
The present embodiment is related to the alloy die cast method in the method for smelting and the present invention of conventional rare magnesium alloy:
Wherein, melting process is in SF6And CO2It is carried out under the conditions of mixed gas protected, steps are as follows:
(1) baking material: melting raw material is preheated 3 hours at 200 DEG C；
(2) it melts magnesium: the pure magnesium after drying has been put into SF6/CO2It is melted in the crucible electrical resistance furnace of gas shield；
(3) add fine aluminium and aluminium manganese intermediate alloy: pure after preheating is added after temperature reaches 670 DEG C when pure magnesium is completely melt
Aluminium, aluminium manganese intermediate alloy；
(4) plus intermediate alloy: when temperature is raised to 720 DEG C, magnesium lanthanum intermediate alloy, magnesium cerium intermediate alloy after preheating is added,
Magnesium samarium intermediate alloy, magnesium neodymium intermediate alloy, magnesium gadolinium intermediate alloy, magnesium yttrium intermediate alloy, aluminium tin intermediate alloy；
(5) refining agent is added after intermediate alloy fusing, when melt temperature gos up to 720 DEG C to be refined, after refining
720 DEG C are stood, and skimming operation after being cooled to 680 DEG C obtains magnesium alloy fused mass；
Die casting process are as follows:
The magnesium alloy fused mass is subjected to die casting at 680 DEG C, obtains Mg alloy castings, metal die temperature is 300 DEG C,
Low speed speed is 0.3m/s, and high speed speed is 2.5m/s, and pressure charging press-shoot power is 20MPa.
The room-temperature mechanical property test result of the embodiment of the present invention 13 is as shown in table 2.
Embodiment 14:
The alloying component (mass percent) of high tough high-modulus diecast magnesium alloy: 4.50%Al, 1.92%Ce, 2.07%
La, 0.16%Sm, 0.11%Nd, 0.40%Gd, 0.31%Y, 2.00%Sn, 1.20%Mn, other inevitable impurity are small
In 0.2%, remaining is Mg.
The present embodiment is related to the alloy die cast method in the method for smelting and the present invention of conventional rare magnesium alloy:
Wherein, melting process is in SF6And CO2It is carried out under the conditions of mixed gas protected, steps are as follows:
(1) baking material: melting raw material is preheated 3 hours at 200 DEG C；
(2) it melts magnesium: the pure magnesium after drying has been put into SF6/CO2It is melted in the crucible electrical resistance furnace of gas shield；
(3) add fine aluminium and aluminium manganese intermediate alloy: pure after preheating is added after temperature reaches 670 DEG C when pure magnesium is completely melt
Aluminium, aluminium manganese intermediate alloy；
(4) plus intermediate alloy: when temperature is raised to 720 DEG C, magnesium lanthanum intermediate alloy, magnesium cerium intermediate alloy after preheating is added,
Magnesium samarium intermediate alloy, magnesium neodymium intermediate alloy, magnesium gadolinium intermediate alloy, magnesium yttrium intermediate alloy, aluminium tin intermediate alloy；
(5) refining agent is added after intermediate alloy fusing, when melt temperature gos up to 720 DEG C to be refined, after refining
720 DEG C are stood, and skimming operation after being cooled to 680 DEG C obtains magnesium alloy fused mass；
Die casting process are as follows:
The magnesium alloy fused mass is subjected to die casting at 680 DEG C, obtains Mg alloy castings, metal die temperature is 250 DEG C,
Low speed speed is 0.5m/s, and high speed speed is 3.0m/s, and pressure charging press-shoot power is 20MPa.
The room-temperature mechanical property test result of the embodiment of the present invention 14 is as shown in table 2.
Comparative example 1
The alloying component (mass percent) of 1 diecast magnesium alloy of comparative example: 6.00%Al, 1.92%Ce, 2.07%La,
0.16%Sm, 0.11%Nd, 0.40%Gd, 0.31%Y, 0.34%Mn, other inevitable impurity less than 0.2%, remaining
For Mg.
The present embodiment is related to the alloy die cast method in the method for smelting and the present invention of conventional rare magnesium alloy:
Wherein, melting process is in SF6And CO2It is carried out under the conditions of mixed gas protected, steps are as follows:
(1) baking material: melting raw material is preheated 3 hours at 200 DEG C；
(2) it melts magnesium: the pure magnesium after drying has been put into SF6/CO2It is melted in the crucible electrical resistance furnace of gas shield；
(3) add fine aluminium and aluminium manganese intermediate alloy: pure after preheating is added after temperature reaches 680 DEG C when pure magnesium is completely melt
Aluminium, aluminium manganese intermediate alloy；
(4) plus intermediate alloy: when temperature is raised to 730 DEG C, magnesium lanthanum intermediate alloy, magnesium cerium intermediate alloy after preheating is added,
Magnesium samarium intermediate alloy, magnesium neodymium intermediate alloy, magnesium gadolinium intermediate alloy, magnesium yttrium intermediate alloy,；
(5) refining agent is added after intermediate alloy fusing, when melt temperature gos up to 730 DEG C to be refined, after refining
720 DEG C are stood, and skimming operation after being cooled to 690 DEG C obtains magnesium alloy fused mass；
Die casting process are as follows:
The magnesium alloy fused mass is subjected to die casting at 690 DEG C, obtains Mg alloy castings, metal die temperature is 250 DEG C,
Low speed speed is 0.3m/s, and high speed speed is 3.0m/s, and pressure charging press-shoot power is 30MPa.
The room-temperature mechanical property test result of comparative example 1 of the present invention is as shown in table 2.
Table 2 is the tough high-modulus diecast magnesium alloy room temperature of height that 1~embodiment of the embodiment of the present invention 14 and comparative example 1 obtain
Mechanical experimental results.
Table 2
| Tensile strength/MPa | Elongation percentage/% | Modulus/GPa | |
| Embodiment 1 | 256 | 8.4 | 51.2 |
| Embodiment 2 | 284 | 5.4 | 53.2 |
| Embodiment 3 | 271 | 10.7 | 55.4 |
| Embodiment 4 | 284 | 12.1 | 56.6 |
| Embodiment 5 | 297 | 10.1 | 61.1 |
| Embodiment 6 | 276 | 11.4 | 60.4 |
| Embodiment 7 | 274 | 10.1 | 60.8 |
| Embodiment 8 | 305 | 14.5 | 59.6 |
| Embodiment 9 | 301 | 12.2 | 61.2 |
| Embodiment 10 | 281 | 11.3 | 58.2 |
| Embodiment 11 | 276 | 8.4 | 60.4 |
| Embodiment 12 | 284 | 10.5 | 60.4 |
| Embodiment 13 | 294 | 15.4 | 52.1 |
| Embodiment 14 | 284 | 13.2 | 55.2 |
| Comparative example 1 | 304 | 14.8 | 51.9 |
As shown in Table 2, the tough high-modulus diecast magnesium alloy of height that the embodiment of the present invention obtains has excellent room temperature mechanics
Performance significantly improves the elasticity modulus of magnesium alloy while guaranteeing obdurability.Wherein the elasticity modulus of embodiment 9 improves most
To be significant, and intensity is similarly obtained raising, and elongation percentage is in a slight decrease, but elongation percentage is still greater than 10%.This is because Mg2Si、
RE-Si and Al3Raising of the introducing of Li et al. reinforced phase to modulus and intensity, and metamorphism of the RE element to the above reinforced phase,
It can be reduced the influence to elongation percentage.
Embodiment 15
The alloying component (mass percent) of high tough high-modulus diecast magnesium alloy: 5.50%Al, 1.92%Ce, 2.07%
La, 0.16%Sm, 0.11%Nd, 0.40%Gd, 0.31%Y, 2.00%Si, 1.00%Zn, 0.34%Mn, it is other inevitable
Impurity less than 0.2%, remaining is Mg.
The present embodiment is related to the alloy die cast method in the method for smelting and the present invention of conventional rare magnesium alloy:
Wherein, melting process is in SF6And CO2It is carried out under the conditions of mixed gas protected, steps are as follows:
(1) baking material: melting raw material is preheated 3 hours at 200 DEG C；
(2) it melts magnesium: the pure magnesium after drying has been put into SF6/CO2It is melted in the crucible electrical resistance furnace of gas shield；
(3) add fine aluminium, pure zinc and magnesium manganese intermediate alloy: when pure magnesium is completely melt, after temperature reaches 690 DEG C, preheating is added
Fine aluminium, pure zinc, magnesium manganese intermediate alloy afterwards；
(4) plus intermediate alloy: when temperature is raised to 740 DEG C, magnesium lanthanum intermediate alloy, magnesium cerium intermediate alloy after preheating is added,
Magnesium samarium intermediate alloy, magnesium neodymium intermediate alloy, magnesium gadolinium intermediate alloy, magnesium yttrium intermediate alloy, magnesium silicon intermediate alloy；
(5) refining agent is added after intermediate alloy fusing, when melt temperature gos up to 740 DEG C to be refined, after refining
720 DEG C are stood, skimming operation after being cooled to 700 DEG C, obtain magnesium alloy fused mass, and casting obtains magnesium alloy ingot；
Die casting process are as follows:
After the magnesium alloy ingot remelting, evacuated die-casting process is carried out at 680~700 DEG C, obtains Mg alloy castings, metal
Mold temperature is 200~300 DEG C, and the effective vacuum pressure of type chamber is 10kPa, and low speed speed is 0.3m/s, and high speed speed is 2.0m/
S, pressure charging press-shoot power are 3MPa.
The room-temperature mechanical property test result of the embodiment of the present invention 15 is as shown in table 3.
Embodiment 16:
The alloying component (mass percent) of high tough high-modulus diecast magnesium alloy: 6.00%Al, 1.92%Ce, 2.07%
La, 0.16%Sm, 0.11%Nd, 0.40%Gd, 0.31%Y, 0.70%Li, 0.50%Si, 0.50%Zn, 0.34%Mn,
For its inevitable impurity less than 0.2%, remaining is Mg.
The present embodiment is related to the alloy die cast method in the method for smelting and the present invention of conventional rare magnesium alloy:
Wherein, melting process is in SF6And CO2It is carried out under the conditions of mixed gas protected, steps are as follows:
(1) baking material: melting raw material is preheated 3 hours at 200 DEG C；
(2) it melts magnesium: the pure magnesium after drying has been put into SF6/CO2It is melted in the crucible electrical resistance furnace of gas shield；
(3) add fine aluminium, pure zinc and aluminium manganese intermediate alloy: when pure magnesium is completely melt, after temperature reaches 680 DEG C, preheating is added
Fine aluminium, pure zinc, aluminium manganese intermediate alloy afterwards；
(4) plus intermediate alloy: when temperature is raised to 730 DEG C, magnesium lanthanum intermediate alloy, magnesium cerium intermediate alloy after preheating is added,
Magnesium samarium intermediate alloy, magnesium neodymium intermediate alloy, magnesium gadolinium intermediate alloy, magnesium yttrium intermediate alloy, magnesium lithium intermediate alloy, aluminium silicon centre are closed
Gold；
(5) refining agent is added after intermediate alloy fusing, when melt temperature gos up to 730 DEG C to be refined, after refining
720 DEG C are stood, skimming operation after being cooled to 690 DEG C, obtain magnesium alloy fused mass, and casting obtains magnesium alloy ingot；
Die casting process are as follows:
After the magnesium alloy ingot remelting, evacuated die-casting process is carried out at 680~700 DEG C, obtains Mg alloy castings, metal
Mold temperature is 200~300 DEG C, and the effective vacuum pressure of type chamber is 4kPa, and low speed speed is 0.2m/s, and high speed speed is 3.0m/
S, pressure charging press-shoot power are 30MPa.
The room-temperature mechanical property test result of the embodiment of the present invention 16 is as shown in table 3.
Embodiment 17
The alloying component (mass percent) of high tough high-modulus diecast magnesium alloy: 5.00%Al, 1.92%Ce, 2.07%
La, 0.16%Sm, 0.11%Nd, 0.40%Gd, 0.31%Y, 0.50%Ca, 0.20%Sb, 0.34%Mn, it is other inevitable
Impurity less than 0.2%, remaining is Mg.
The present embodiment is related to the alloy die cast method in the method for smelting and the present invention of conventional rare magnesium alloy:
Wherein, melting process is in SF6And CO2It is carried out under the conditions of mixed gas protected, steps are as follows:
(1) baking material: melting raw material is preheated 3 hours at 200 DEG C；
(2) it melts magnesium: the pure magnesium after drying has been put into SF6/CO2It is melted in the crucible electrical resistance furnace of gas shield；
(3) add fine aluminium and aluminium manganese intermediate alloy: pure after preheating is added after temperature reaches 670 DEG C when pure magnesium is completely melt
Aluminium, aluminium manganese intermediate alloy；
(4) plus intermediate alloy: when temperature is raised to 720 DEG C, magnesium lanthanum intermediate alloy, magnesium cerium intermediate alloy after preheating is added,
Magnesium samarium intermediate alloy, magnesium neodymium intermediate alloy, magnesium gadolinium intermediate alloy, magnesium yttrium intermediate alloy, aluminium calcium intermediate alloy, aluminium antimony centre are closed
Gold；
(5) refining agent is added after the fusing of magnesium rare earth intermediate alloy, when melt temperature gos up to 720 DEG C to be refined, essence
It is stood after refining at 720 DEG C, skimming operation after being cooled to 680 DEG C, obtains magnesium alloy fused mass, casting obtains magnesium alloy ingot；
Die casting process are as follows:
After the magnesium alloy ingot remelting, evacuated die-casting process is carried out at 680~700 DEG C, obtains Mg alloy castings, metal
Mold temperature is 200~300 DEG C, and the effective vacuum pressure of type chamber is 1kPa, and low speed speed is 0.3m/s, and high speed speed is 1.0m/
S, pressure charging press-shoot power are 50MPa.
The room-temperature mechanical property test result of the embodiment of the present invention 17 is as shown in table 3.
Table 3 is the tough high-modulus diecast magnesium alloy room-temperature mechanical property of height that 15~embodiment of the embodiment of the present invention 17 obtains
Test result.
Table 3
| Tensile strength/MPa | Elongation percentage/% | Modulus/GPa | |
| Embodiment 15 | 303 | 12.5 | 62.0 |
| Embodiment 16 | 313 | 14.5 | 62.4 |
| Embodiment 17 | 296 | 11.4 | 61.2 |
As shown in Table 3, vacuum die casting process provided by the invention can be further improved the obdurability and elasticity of magnesium alloy
Modulus.
Embodiment 18
The tough high-modulus diecast magnesium alloy of height that the embodiment of the present invention 16 obtains is carried out to 32 hours timeliness at 175 DEG C
Processing, the type of cooling of the ageing treatment are air-cooled.
The room-temperature mechanical property test result of the embodiment of the present invention 18 is as shown in table 4.
Embodiment 19
The tough high-modulus diecast magnesium alloy of height that the embodiment of the present invention 16 obtains is carried out to 16 hours timeliness at 200 DEG C
Processing, the type of cooling of the ageing treatment are water cooling.
The room-temperature mechanical property test result of the embodiment of the present invention 19 is as shown in table 4.
Embodiment 20
The tough high-modulus diecast magnesium alloy of height that the embodiment of the present invention 16 obtains is carried out to 1 hour timeliness at 225 DEG C
Processing, the type of cooling of the ageing treatment are water cooling.
The room-temperature mechanical property test result of the embodiment of the present invention 20 is as shown in table 4.
Embodiment 21
The tough high-modulus diecast magnesium alloy of height that the embodiment of the present invention 16 obtains is carried out to solid solution in 4 hours at 300 DEG C
Processing and carries out 32 hours ageing treatments at 175 DEG C, the type of cooling of the solid solution and ageing treatment is water cooling.
The room-temperature mechanical property test result of the embodiment of the present invention 21 is as shown in table 4.
Embodiment 22
The tough high-modulus diecast magnesium alloy of height that the embodiment of the present invention 16 obtains is carried out to solid solution in 2 hours at 400 DEG C
Processing and carries out 16 hours ageing treatments at 200 DEG C, the type of cooling of the ageing treatment is water cooling.
The room-temperature mechanical property test result of the embodiment of the present invention 22 is as shown in table 4.
Embodiment 23
The tough high-modulus diecast magnesium alloy of height that the embodiment of the present invention 16 obtains is carried out consolidating for 0.1 hour at 500 DEG C
The type of cooling of the molten ageing treatment handled and 1 hour is carried out at 225 DEG C, the solid solution and ageing treatment is water cooling.
The room-temperature mechanical property test result of the embodiment of the present invention 23 is as shown in table 4.
Table 4 is the tough high-modulus diecast magnesium alloy room-temperature mechanical property test knot of height that 18~embodiment of embodiment 23 obtains
Fruit.
Table 4
| Tensile strength/MPa | Elongation percentage/% | Modulus/GPa | |
| Embodiment 18 | 320 | 14 | 62.6 |
| Embodiment 19 | 334 | 12.8 | 63.4 |
| Embodiment 20 | 329 | 14.3 | 62.4 |
| Embodiment 21 | 338 | 13.5 | 65.3 |
| Embodiment 22 | 351 | 13.9 | 67.5 |
| Embodiment 23 | 328 | 14.1 | 63.8 |
As shown in Table 4, heat treatment process provided by the invention can be further improved the obdurability and springform of magnesium alloy
Amount.The obdurability and elasticity modulus for the heat treatment process raising alloy that wherein embodiment 22 provides are the most significant.
Claims (10)
1. a kind of high tough high-modulus diecast magnesium alloy, which is characterized in that be made of following element by mass percentage:
The Al of a%, the mixing of one or more of La, Ce, Pr of b%, the Mn of c%, total RE rare earth Gd containing d%,
Y, one or more of Sm, Nd, Er, Eu, Ho, Tm, Lu, Dy, Yb element, add up to Si, Ge containing e%, Ca, Li, Sn,
One or more of Zn, Sb element, impurity of the total amount less than 0.2%, surplus Mg；Wherein, a, b, c, d and e meet following
Formula (1)~(5),
(1)3.5≤a≤6.5；
(2)3.5≤b≤4.5；
(3)0.01≤c≤1.5；
(4)0.01≤d≤3.0；
(5)0<e≤5.0。
2. the tough high-modulus diecast magnesium alloy of height according to claim 1, which is characterized in that
The value range of c in the formula (3) are as follows: 0.2≤c≤1.5, and/or
The value range of d in the formula (4) are as follows: 0.1≤d≤3.0, and/or
The value range of e in the formula (5) are as follows: 0.2≤e≤4.0.
3. the tough high-modulus diecast magnesium alloy of height according to claim 1 characterized by comprising
The Mg that (I) is gone bad by RE element2Si、Al2Ca、Mg2Ge、Al3Li and Mg2Sn high-modulus hardening constituent, and
(II) corynebacterium Al11RE3, graininess Al2RE hardening constituent, and/or
(III) Al-Mn nanometers of ageing strengthening phases.
4. the tough high-modulus diecast magnesium alloy of height according to claim 1, which is characterized in that in the magnesium alloy materials,
3.6%≤b+d≤7.0%.
5. the tough high-modulus diecast magnesium alloy of height according to claim 4, which is characterized in that in the magnesium alloy materials,
4.5%≤b+d≤6.0%.
6. the preparation method of any one of the claim 1-5 height is tough high-modulus diecast magnesium alloy, which is characterized in that including such as
Lower step:
S1: molten alloy, by pure Mg, pure Al, magnesium rare earth intermediate alloy, aluminium manganese or magnesium manganese intermediate alloy and remaining component point
It does not preheat, preheating temperature is 200~250 DEG C, and preheating time is 2~6 hours；
S2: the pure Mg after preheating is completely melt in protective atmosphere；Pure Al after preheating is added at 670~690 DEG C；When
Temperature is raised to 720~740 DEG C, the intermediate alloy or pure metal after preheating is added；After intermediate alloy or pure metal are completely melt
720~740 DEG C are warming up to, refining agent is added and is refined, is stood after refining at 710-730 DEG C, is cooled to 680~700
Skimming operation after DEG C obtains magnesium alloy fused mass, or casting obtains magnesium alloy ingot；
S3: in step S2 magnesium alloy fused mass or magnesium alloy ingot remelting after carry out evacuated die-casting process or antivacuum die casting, obtain
Mg alloy castings.
7. the preparation method of high tough high-modulus diecast magnesium alloy according to claim 6, which is characterized in that in step S1:
The magnesium rare earth intermediate alloy is magnesium cerium-rich mischmetal intermediate alloy, magnesium lanthanum intermediate alloy, magnesium cerium intermediate alloy, magnesium praseodymium
Intermediate alloy, magnesium samarium intermediate alloy, magnesium gadolinium intermediate alloy, magnesium yttrium intermediate alloy, magnesium richness yttrium mixed rare earth intermediate alloy, in magnesium neodymium
Between alloy, magnesium praseodymium neodymium mixed rare-earth intermediate alloy, magnesium erbium intermediate alloy, magnesium europium intermediate alloy, magnesium holmium intermediate alloy, among magnesium thulium
The combination of one or more of alloy, magnesium lutetium intermediate alloy, magnesium dysprosium intermediate alloy, magnesium ytterbium intermediate alloy intermediate alloy；Wherein:
Contain tri- kinds of rare earth elements of La, Ce, Pr in the cerium-rich mischmetal；
Remaining described group is divided into Mg-based master alloy or contained aluminium-base intermediate alloy or pure metal；Wherein:
The Mg-based master alloy is magnesium silicon intermediate alloy, magnesium calcium intermediate alloy, magnesium lithium intermediate alloy, magnesium zinc intermediate alloy, magnesium
The combination of one or more of antimony intermediate alloy intermediate alloy；
The contained aluminium-base intermediate alloy is aluminium silicon intermediate alloy, aluminium germanium intermediate alloy, aluminium calcium intermediate alloy, aluminium lithium intermediate alloy, aluminium
The combination of one or more of tin intermediate alloy, aluminium antimony intermediate alloy intermediate alloy；
The pure metal is one or both of pure silicon, pure zinc.
8. the preparation method of high tough high-modulus diecast magnesium alloy according to claim 6, which is characterized in that in step S2:
Refining agent is added to be refined, at 720 DEG C after refining, is stood；
The protective atmosphere is SF6And CO2Mixed gas, and SF6And CO2Volume ratio be 1:99；
The refining agent is the inorganic salts refining agent of Mg alloy or carbon trichloride of sodium salt, sylvite, villiaumite, and additional amount is all
The 1-5% of total mass of raw material.
9. the preparation method of high tough high-modulus diecast magnesium alloy according to claim 6, which is characterized in that in step S3:
The process conditions of the evacuated die-casting process are as follows: by magnesium alloy fused mass or magnesium alloy ingot remelting, carried out at 680~700 DEG C
Die casting obtains Mg alloy castings, and the effective vacuum pressure of type chamber is 1~10kPa, and mold temperature is 220~300 DEG C, low speed speed
For 0.2~0.4m/s, high speed speed is 1.0~3.0m/s, and pressure charging press-shoot power is 20~50MPa；
The process conditions of the antivacuum die casting are as follows: by magnesium alloy fused mass or magnesium alloy ingot remelting, at 680~700 DEG C into
Row die casting obtains Mg alloy castings, and metal die temperature is 220~300 DEG C, and low speed speed is 0.2~0.4m/s, high speed speed
For 1.0~3.0m/s, pressure charging press-shoot power is 20~50MPa.
10. the preparation method of high tough high-modulus diecast magnesium alloy according to claim 6, which is characterized in that further include by
Mg alloy castings obtained by step S3 carry out at heat treatment reinforcement or the direct labor's timeliness of solution treatment and artificial aging processing
Reason；Wherein: the temperature of the solution treatment is 300~500 DEG C, and the time of the solution treatment is 0.1~4 hour；
The temperature of the artificial aging processing is 175~225 DEG C, and the time of the ageing treatment is 1~32 hour.
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