CN109797601A - A kind of sizing agent and its preparation and glue applying method for heating the tobacco product cigarette paper that do not burn - Google Patents
A kind of sizing agent and its preparation and glue applying method for heating the tobacco product cigarette paper that do not burn Download PDFInfo
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- CN109797601A CN109797601A CN201910084236.0A CN201910084236A CN109797601A CN 109797601 A CN109797601 A CN 109797601A CN 201910084236 A CN201910084236 A CN 201910084236A CN 109797601 A CN109797601 A CN 109797601A
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- cigarette paper
- burn
- sizing agent
- heating
- expanded graphite
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- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 101
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 53
- 238000004513 sizing Methods 0.000 title claims abstract description 46
- 238000010438 heat treatment Methods 0.000 title claims abstract description 45
- 235000019505 tobacco product Nutrition 0.000 title claims abstract description 45
- 239000003292 glue Substances 0.000 title claims abstract description 23
- 238000000034 method Methods 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 47
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 45
- 239000010439 graphite Substances 0.000 claims abstract description 45
- 241000208125 Nicotiana Species 0.000 claims abstract description 25
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims abstract description 25
- 239000002245 particle Substances 0.000 claims abstract description 21
- 238000003756 stirring Methods 0.000 claims abstract description 19
- 238000000889 atomisation Methods 0.000 claims abstract description 13
- 229920002472 Starch Polymers 0.000 claims abstract description 11
- 239000008107 starch Substances 0.000 claims abstract description 11
- 235000019698 starch Nutrition 0.000 claims abstract description 11
- 238000006243 chemical reaction Methods 0.000 claims abstract description 10
- 238000002156 mixing Methods 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000001035 drying Methods 0.000 claims abstract description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 30
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 18
- 239000001993 wax Substances 0.000 claims description 11
- 239000007787 solid Substances 0.000 claims description 7
- BGTBFNDXYDYBEY-FNORWQNLSA-N 4-(2,6,6-Trimethylcyclohex-1-enyl)but-2-en-4-one Chemical compound C\C=C\C(=O)C1=C(C)CCCC1(C)C BGTBFNDXYDYBEY-FNORWQNLSA-N 0.000 claims description 6
- POIARNZEYGURDG-FNORWQNLSA-N beta-damascenone Chemical compound C\C=C\C(=O)C1=C(C)C=CCC1(C)C POIARNZEYGURDG-FNORWQNLSA-N 0.000 claims description 6
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 6
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 6
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 6
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 238000011002 quantification Methods 0.000 claims description 6
- 238000003892 spreading Methods 0.000 claims description 6
- MDYZKJNTKZIUSK-UHFFFAOYSA-N tyloxapol Chemical compound O=C.C1CO1.CC(C)(C)CC(C)(C)C1=CC=C(O)C=C1 MDYZKJNTKZIUSK-UHFFFAOYSA-N 0.000 claims description 6
- 229930007850 β-damascenone Natural products 0.000 claims description 6
- 239000004368 Modified starch Substances 0.000 claims description 5
- 229920000881 Modified starch Polymers 0.000 claims description 5
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 5
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 5
- 235000019426 modified starch Nutrition 0.000 claims description 5
- 239000001254 oxidized starch Substances 0.000 claims description 5
- 235000013808 oxidized starch Nutrition 0.000 claims description 5
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 5
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 5
- YKVWPZJHENXDAJ-VOTSOKGWSA-N Megastigmatrienone Chemical compound CC1=CC(=O)CC(C)(C)C1\C=C\C=C YKVWPZJHENXDAJ-VOTSOKGWSA-N 0.000 claims description 4
- 238000012545 processing Methods 0.000 claims description 4
- 238000007664 blowing Methods 0.000 claims description 3
- 239000000779 smoke Substances 0.000 abstract description 7
- 238000009835 boiling Methods 0.000 abstract description 2
- 230000001953 sensory effect Effects 0.000 abstract description 2
- 206010013786 Dry skin Diseases 0.000 abstract 1
- 239000000523 sample Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000000391 smoking effect Effects 0.000 description 2
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 206010006784 Burning sensation Diseases 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 206010023126 Jaundice Diseases 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000011285 coke tar Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- WASQWSOJHCZDFK-UHFFFAOYSA-N diketene Chemical compound C=C1CC(=O)O1 WASQWSOJHCZDFK-UHFFFAOYSA-N 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 150000002561 ketenes Chemical class 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910021382 natural graphite Inorganic materials 0.000 description 1
- 229960002715 nicotine Drugs 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Abstract
The present invention provides a kind of sizing agent for heating the tobacco product cigarette paper that do not burn and its preparation and glue applying method.The sizing agent is AKD glue to be placed in reaction vessel, and be heated with stirring to 60~90 DEG C, while being added that treated that expanded graphite, regulator and tobacco aromaticss use high pressure homogenizer to obtain homogeneous after mixing evenly；It is that 10~100 μm of expanded graphite particles are placed in atomization agent solution after stirring fully absorbs atomizer solution under condition of negative pressure that the expanded graphite, which is by partial size, using the expanded graphite particles obtained after 70~100 DEG C of low temperature dryings.The AKD glue is that 30~60min of insulated and stirred reaction gained in 60~90 DEG C of hot water is added to by starch and AKD wax.Above-mentioned sizing agent is transported in feeding groove, the inner surface for being applied to cigarette paper in surface size press is re-fed into；It can preferably protect cigarette paper is excessively boiling hot from high-temperature baking and cigarette, influences consumer sensory to experience, and improve amount of smoke when suction.
Description
Technical field
The present invention relates to heating not to burn tobacco product technical field, specifically a kind of for heating the tobacco product that do not burn
Cigarette paper sizing agent and preparation and glue applying method.
Background technique
With Modern cigarette industry industrial development, heats the tobacco product that do not burn and be increasingly becoming a kind of emerging traditional cigarette substitution
Product.It heats the tobacco product that do not burn and heats the tobacco ingredient containing Alevaires such as glycerol using the modes such as electricity, carbon, chemistry, generate
Smog containing nicotine, flavor component is realized and the approximate consumption experience of traditional cigarette.Due to using on-fuel mode, add
The hot harmfulness ingredient for not burning tobacco product generation is greatly decreased compared with traditional cigarette, and in international markets such as Japan and Korea S, development is popular
Rapidly.
In heating the tobacco product that do not burn, the main function of cigarette paper is package pipe tobacco, while having high temperature resistant (heating
Temperature is 300 DEG C or so), avoid cigarette paper after suction from turning to be yellow, be even carbonized.The existing cigarette paper technology of not burning that heats also has
It is open, such as patent " a kind of low-temperature heat type cigarette non-ignitable cigarette paper and preparation method thereof ", application number
CN201410437696.4.The patented technology is by being filled with magnesium hydroxide, aluminium hydroxide and being coated with phosphorus system on paper base surface in slurry
Fire retardant is come non-ignitable when achieving the purpose that cigarette paper uses.The testing result of its disclosed embodiment show to accomplish 350 DEG C not
It fires (being carbonized at 450 DEG C), but all jaundice.
Meanwhile heating do not burn tobacco product mainly pass through heating cause the volatile substances such as glycerol, propylene glycol atomization produce
The smog of raw approximation cigarette burning brings consumer's suction experience for being more nearly traditional cigarette.Its volatile substances added
It is main to pass through thin slice (such as: patent 200580036230.2 is the electrically heated cigarette of Fei Mo company application) or directly apply in the tobacco
Add.
Due to absorbent properties of the tobacco leaf to Alevaires such as glycerol it is not high (in Tang's roasting roasting etc. " tobacco science and technology ", 2015 3
Month, the 3rd phase of volume 48) report in, glycerol under tobacco leaf hot property and heated condition flue gas discharge influence, it is known that when glycerol exists
After pipe tobacco additive amount is greater than 10%, under certain temperature heating condition, releasing content of coke tar increases unobvious), individually add big ratio
Example Alevaire can not be fully absorbed by tobacco leaf, caused the Alevaire largely applied to be adsorbed on tobacco leaf surface, utilized traditional cigarette
Equipment, the Alevaire of pipe tobacco surface attachment are easy moisture absorption blocking plume and Tobacco-feeding device.
Between above-mentioned reason, most of amount of smoke for heating the tobacco product that do not burn is relatively low compared with traditional cigarette at present, work
Industry enterprise is improved by other technologies approach, but is rarely reported；And increase the phase of smoke delivery by cigarette paper
Pass technology also has not been reported.
Summary of the invention
The object of the invention is to solve existing non-ignitable cigarette paper and amount of smoke be applied to heat the cigarette that do not burn
When existing drawbacks described above, a kind of sizing agent for heating the cigarette paper for the tobacco product that do not burn and preparation and sizing side are provided
Method improves the heat-resisting quantity (300 DEG C or so) of cigarette paper, and improve heating not by applying upper sizing agent in cigarette paper surface
Smoke delivery, increase tobacco aroma when burning cigarette smoking.
In order to achieve the above object, the technical solution adopted by the present invention is as follows: it is described a kind of for heating the tobacco product that do not burn
The sizing agent of cigarette paper, it is characterised in that be by the material composition of following parts by weight:
Wherein, the expanded graphite is that partial size is used to be placed in atomization agent solution for 10~100 μm of expanded graphite particles,
And under conditions of pressure is -0.2~-0.1MPa after stirring fully absorbs atomizer solution in 20~30 minutes, using 70~
The expanded graphite particles obtained after 100 DEG C of low temperature drying.
The present invention preferably technical solution: it is described atomization agent solution be by mass percent be 5~30% propylene glycol and
What the glycerol that mass percent is 70~95% obtained after mixing.
The present invention preferably technical solution: the tobacco aromaticss include damascenone, damascone, Megastigmatrienone, cloud and mist leaching
Cream, Peru's medicinal extract, any one or more in Tolu concrete.
The present invention preferably technical solution: the AKD glue is by 100 weight starch and 3~6 parts by weight AKD wax (alkane
Base ketene dimer) it is added in the hot water of 60~90 DEG C of 300 parts by weight, 30~60min of insulated and stirred reaction gained；The shallow lake
Powder is one of oxidized starch or modified starch；The solid content of AKD wax is 15 ± 1%, and grain diameter is 0.5~2 μm.
It is provided by the invention a kind of for heating the preparation method of the sizing agent for the tobacco product cigarette paper that do not burn, feature
It is that specific step is as follows:
(1) processing of expanded graphite:
A. expanded graphite is crushed to 10~100 μm of particle diameter；
B. the glycerol that the propylene glycol and mass percent that mass percent is 5~30% are 70~95% is uniformly mixed composition
It is atomized agent solution；
C. it by the atomization agent solution in step b after mixing, injects in more mouthfuls of reactor tanks, closes each feed inlet and start to take out
The expanded graphite particles in step (1), stirring 20~30 is added when reaching negative pressure -0.2~-0.1MPa in reactor tank in vacuum
Stop stirring after minute, expanded graphite particles micropore is made to fully absorb atomization agent solution, solid outlet is opened, from reacting tank body
Bottom blowing；
D. the cryogenic conditions by step c treated expanded graphite particles at 70~100 DEG C are dried, and vibrosieve obtains
Absorb the expanded graphite particles for having Alevaire；
(2) it prepares AKD glue: 100 parts of starch and 3~6 parts of AKD waxes being taken to be added in 300 parts 60~90 DEG C of hot water, protect
30~60min of temperature stirring obtains AKD glue；
(3) it takes the AKD glue prepared in 60~75 parts by weight steps (2) to be placed in reaction vessel, and is heated with stirring to 60
~90 DEG C, at the same be added 5~20 parts by weight steps (1) in handle expanded graphite, 10~25 parts by weight regulator, 0.1~
The tobacco aromaticss of 0.5 parts by weight, are stirred continuously, and are uniformly mixed, and are obtained mixed liquor homogeneous 1~3 time using high pressure homogenizer
The sizing agent for being used to heat the tobacco product cigarette paper that do not burn.
The present invention preferably technical solution: the starch in the step (2) in AKD glue is oxidized starch or modified starch
One of；AKD wax solid content is 15 ± 1%, and grain diameter is 0.5~2 μm.
The present invention preferably technical solution: the tobacco aromaticss in the step (3) include damascenone, damascone, huge beans three
Ketenes, yunyan extract, Peru's medicinal extract, any one or more in Tolu concrete.
The present invention preferably technical solution: the regulator in the step (3) is hydroxypropyl methyl cellulose, carboxymethyl fibre
Tie up one or both of plain sodium.
A kind of glue applying method of sizing agent heating the tobacco product cigarette paper that do not burn provided by the invention, feature exist
In: the above-mentioned sizing agent for being used to heat the tobacco product cigarette paper that do not burn is transported in feeding groove, top sizing is re-fed into
The inner surface that cigarette paper is contacted with pipe tobacco is applied in machine；Wherein quantification of 28~35g/m of cigarette paper2, temperature when sizing
For system at 25 DEG C~35 DEG C, single spreading amount is 3~10g/m2。
Tobacco aromaticss are the tobacco aromaticss product directly bought in the present invention.
Compared with prior art, the beneficial effects of the present invention are:
1, the actual temperature that can be born by expanded graphite is -204~1650 DEG C, is good fire retardant, and have Halogen,
It is the features such as nontoxic, pollution-free, harmless, and heating tobacco product heating temperature of not burning is 300 DEG C or so (existing researchs
And not more than 450 DEG C of test result)；Therefore the cigarette paper in the present invention can be good at protecting during heating
Cigarette paper prevents high temperature from scalding deformation, is more not in carbonization, metachromatism, and do not increase any external fragrance, chemical breath.
2, because the expansion temperature of expanded graphite is 300 DEG C, expansion rear surface product is greatly increased, and heats not burning tobacco
Product heating temperature just expands expanded graphite, use of the invention, can use less expanded graphite, lower cost, rises
It is acted on to preferable heated protective.
3, because of the density of expanded graphite hundred times generally smaller than natural graphite, expanded graphite bulk density is 0.002~
0.005g/cm3, extrudate density is 0.8~1.8g/cm3.So expanded graphite meterial lighter weight has plasticity again；Hardness is very
It is low, it is cleavable with common cutter, and can arbitrarily wind, bend；Therefore cigarette paper of the invention has good production and processing
(cigarette cutting) performance.
4, because expanded graphite has excellent heating conduction, therefore, cigarette paper of the invention during heating, can be very well
The expanded graphite that passes through heat quickly be transmitted to outside cigarette paper, it is faster to radiate, reduce the tired of heat in aspiration procedure
Product, not only preferably protected cigarette paper from high-temperature baking, but also avoided cigarette is excessively boiling hot, influences consumer sensory from experiencing.
5, because expanded graphite has good oil absorption and hydrophobicity, it is better than active carbon, therefore cigarette paper of the invention
In expanded graphite can adsorb relatively large number of atomization agent solution, make its heating aspiration procedure in, release more cigarette
Gas improves amount of smoke when suction, meets the suction satisfaction of consumer.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
It is a kind of for heating the sizing agent for the tobacco product cigarette paper that do not burn in the present invention, it is by the object of following parts by weight
Matter composition: 5~20 parts of expanded graphites, 0.1~0.5 part of tobacco aromatics, 60~75 parts of AKD glues, 10~25 parts of regulators.It is described
Tobacco aromaticss include damascenone, damascone, Megastigmatrienone, yunyan extract, Peru's medicinal extract, in Tolu concrete any one or
It is a variety of.The regulator is one or both of hydroxypropyl methyl cellulose, sodium carboxymethylcellulose.
The processing method of expanded graphite in following embodiment is as follows:
A. expanded graphite is crushed to 10~100 μm of particle diameter；
B. the glycerol that the propylene glycol and mass percent that mass percent is 5~30% are 70~95% is uniformly mixed composition
It is atomized agent solution；
C. it by the atomization agent solution in step b after mixing, injects in more mouthfuls of reactor tanks, closes each feed inlet and start to take out
The expanded graphite particles in step (1), stirring 20~30 is added when reaching negative pressure -0.2~-0.1MPa in reactor tank in vacuum
Stop stirring after minute, expanded graphite particles micropore is made to fully absorb atomization agent solution, solid outlet is opened, from reacting tank body
Bottom blowing；
D. the cryogenic conditions by step c treated expanded graphite particles at 70~100 DEG C are dried, and vibrosieve obtains
Absorb the expanded graphite particles for having Alevaire.
The AKD glue is by taking 100 weight starch and 3~6 parts by weight AKD waxes to be added to 300 parts by weight 60~90
DEG C hot water in, 30~60min of insulated and stirred is obtained, the starch be one of oxidized starch or modified starch；AKD wax
Solid content is 15 ± 1%, and grain diameter is 0.5~2 μm.
Embodiment 1 provides a kind of for heating the sizing agent for the tobacco product cigarette paper that do not burn, and specific preparation method is such as
Under: the AKD glue for taking the 60 parts by weight above methods to prepare is placed in reaction vessel, and is heated with stirring to 65 DEG C, while 5 weights are added
The damascenone of part above method treated expanded graphite, the hydroxypropyl methyl cellulose of 10 parts by weight, 0.1 parts by weight is measured, no
Disconnected stirring, is uniformly mixed, and will obtain for mixed liquor homogeneous 1 time described being used to heat the tobacco product that do not burn using high pressure homogenizer
The sizing agent A of cigarette paper.
The sizing agent A for being used to heat the tobacco product cigarette paper that do not burn prepared in embodiment 1 is transported in feeding groove,
It is re-fed into and is applied to the inner surface of cigarette paper in surface size press and is prepared into cigarette paper A；The wherein quantification of 30g/ of cigarette paper
m2, for temperature system when sizing at 25 DEG C, single spreading amount is 6g/m2。
Embodiment 2 provides a kind of for heating the sizing agent for the tobacco product cigarette paper that do not burn, and specific preparation method is such as
Under: the AKD glue for taking the 65 parts by weight above methods to prepare is placed in reaction vessel, and is heated with stirring to 70 DEG C, while being added 10
The parts by weight above method treated expanded graphite, the sodium carboxymethylcellulose of 10 parts by weight, 0.2 parts by weight damascone, no
Disconnected stirring, is uniformly mixed, and will obtain for mixed liquor homogeneous 2 times described being used to heat the tobacco product that do not burn using high pressure homogenizer
The sizing agent B of cigarette paper.
The sizing agent B for being used to heat the tobacco product cigarette paper that do not burn prepared in embodiment 2 is transported in feeding groove,
It is re-fed into and is applied to the inner surface of cigarette paper in surface size press and is prepared into cigarette paper B；The wherein quantification of 32g/ of cigarette paper
m2, for temperature system when sizing at 30 DEG C, single spreading amount is 6g/m2。
Embodiment 3 provides a kind of for heating the sizing agent for the tobacco product cigarette paper that do not burn, and specific preparation method is such as
Under: the AKD glue for taking the 65 parts by weight above methods to prepare is placed in reaction vessel, and is heated with stirring to 75 DEG C, while being added 15
The parts by weight above method handles the cloud and mist of the sodium carboxymethylcellulose of the expanded graphite, 15 parts by weight that post-process, 0.25 parts by weight
Medicinal extract is stirred continuously, and is uniformly mixed, and using high pressure homogenizer will obtain for mixed liquor homogeneous 3 times it is described be used to heat do not burn
The sizing agent C of tobacco product cigarette paper.
The sizing agent C for being used to heat the tobacco product cigarette paper that do not burn prepared in embodiment 3 is transported in feeding groove,
It is re-fed into and is applied to the inner surface of cigarette paper in surface size press and is prepared into cigarette paper C；The wherein quantification of 32g/ of cigarette paper
m2, for temperature system when sizing at 30 DEG C, single spreading amount is 8g/m2。
Embodiment 4 provides a kind of for heating the sizing agent for the tobacco product cigarette paper that do not burn, and specific preparation method is such as
Under: the AKD glue for taking the 75 parts by weight above methods to prepare is placed in reaction vessel, and is heated with stirring to 80 DEG C, while being added 20
The Tolu concrete of the expanded graphite of parts by weight above method processing, the hydroxypropyl methyl cellulose of 25 parts by weight, 0.3 parts by weight,
It is stirred continuously, is uniformly mixed, and will obtain for mixed liquor homogeneous 1~3 time described being used to heat the cigarette that do not burn using high pressure homogenizer
The sizing agent D of straw-made articles cigarette paper.
The sizing agent D for being used to heat the tobacco product cigarette paper that do not burn prepared in embodiment 4 is transported in feeding groove,
It is re-fed into and is applied to the inner surface of cigarette paper in surface size press and is prepared into cigarette paper D；The wherein quantification of 32g/ of cigarette paper
m2, for temperature system when sizing at 30 DEG C, single spreading amount is 10g/m2。
Test 1: using cigarette paper A, B, C, D of the preparation in above-described embodiment as the cigarette for heating the tobacco product that do not burn
Paper conventionally rolls heating respectively and does not burn cigarette, and use the heating of regular-size cigarette paper roll do not burn cigarette as
Contrast sample controls heated probe temperature respectively in 200 DEG C, 250 DEG C, 300 DEG C, 350 DEG C, 450 DEG C, by regular volume cigarette paper and
Each embodiment fills same pipe tobacco respectively and is inserted into heated probe, observes its heated situation, as shown in Table 1 below:
The combustion case of table 1 different embodiments and conventional products in different temperatures environment
It can be seen that compared with conventional products from 1 test result of table, the heat resistance of each embodiment is better than conventional sample,
Because reducing cigarette paper surface temperature, effective protection outer layer cigarette paper embodies superior flame retardant property, thermal diffusivity and Nai Gao
Warm nature energy.
Test 2: using cigarette paper A, B, C, D of the preparation in above-described embodiment as the cigarette for heating the tobacco product that do not burn
Paper conventionally rolls heating respectively and does not burn cigarette, and use the heating of regular-size cigarette paper roll do not burn cigarette as
Contrast sample is aspirated respectively, and smoking result is as shown in table 2:
The different embodiments of table 2 and conventional products roll into cigarette and smoke panel test situation
The results show that different embodiment samples are compared compared to regular volume cigarette paper in above-mentioned table, aesthetic quality is obviously improved,
Especially perfume quantity and concentration are promoted obvious, may its preferable heat dissipation, high temperature resistance, burning sensation and drying because of the present embodiment
Sense is also promoted, and conventional sample is totally substantially better than.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (10)
1. a kind of for heating the sizing agent for the tobacco product cigarette paper that do not burn, it is characterised in that be by the object of following parts by weight
Matter composition:
Wherein, the expanded graphite be use partial size for 10~100 μm of expanded graphite particles be placed in atomization agent solution in, and
After pressure stirs 20~30 minutes under conditions of being -0.2~-0.1MPa and fully absorbs atomizer solution, using 70~100 DEG C
Low temperature drying after obtained expanded graphite particles.
2. according to claim 1 a kind of for heating the sizing agent for the tobacco product cigarette paper that do not burn, it is characterised in that:
The AKD glue is added in the hot water of 60~90 DEG C of 300 parts by weight by 100 weight starch and 3~6 parts by weight AKD waxes,
30~60min of insulated and stirred reaction gained；The starch is one of oxidized starch or modified starch；The solid content of AKD wax
It is 15 ± 1%, grain diameter is 0.5~2 μm.
3. according to claim 1 a kind of for heating the sizing agent for the tobacco product cigarette paper that do not burn, it is characterised in that:
It is described to be atomized agent solution to be the glycerol mixing that the propylene glycol for being 5~30% by mass percent and mass percent are 70~95%
It is obtained after uniformly.
4. according to claim 1 a kind of for heating the sizing agent for the tobacco product cigarette paper that do not burn, it is characterised in that:
The tobacco aromaticss include damascenone, damascone, Megastigmatrienone, yunyan extract, Peru's medicinal extract, any one in Tolu concrete
Kind is a variety of.
5. according to claim 1 a kind of for heating the sizing agent for the tobacco product cigarette paper that do not burn, it is characterised in that:
The regulator is one or both of hydroxypropyl methyl cellulose, sodium carboxymethylcellulose.
6. a kind of for heating the preparation method of the sizing agent for the tobacco product cigarette paper that do not burn, it is characterised in that specific steps are such as
Under:
(1) processing of expanded graphite:
A. expanded graphite is crushed to 10~100 μm of particle diameter；
B. the glycerol that the propylene glycol and mass percent that mass percent is 5~30% are 70~95% is uniformly mixed composition atomization
Agent solution；
C. it by the atomization agent solution in step b after mixing, injects in more mouthfuls of reactor tanks, closes each feed inlet and start to take out very
The expanded graphite particles in step (1) are added when reaching negative pressure -0.2~-0.1MPa in reactor tank in sky, stir 20~30 points
Stop stirring after clock, expanded graphite particles micropore is made to fully absorb atomization agent solution, solid outlet is opened, from reacting tank body bottom
Portion's blowing；
D. the cryogenic conditions by step c treated expanded graphite particles at 70~100 DEG C are dried, and vibrosieve is absorbed
There are the expanded graphite particles of Alevaire；
(2) it prepares AKD glue: 100 weight starch and 3~6 parts by weight AKD waxes being taken to be added to 60~90 DEG C of 300 parts by weight
In hot water, 30~60min of insulated and stirred obtains AKD glue；Wherein the quality of AKD wax is the 3~6% of starch quality ratio；
(3) it takes the AKD glue prepared in 60~75 parts by weight steps (2) to be placed in reaction vessel, and is heated with stirring to 60~90
DEG C, while regulator, 0.1~0.5 weight of the expanded graphite, 10~25 parts by weight that handle in 5~20 parts by weight steps (1) is added
The tobacco aromaticss for measuring part, are stirred continuously, and are uniformly mixed, and obtain the use for mixed liquor homogeneous 1~3 time using high pressure homogenizer
In the sizing agent for heating the tobacco product cigarette paper that do not burn.
7. it is according to claim 6 a kind of for heating the preparation method of the sizing agent for the tobacco product cigarette paper that do not burn,
It is characterized by: the starch in the step (2) in AKD glue is one of oxidized starch or modified starch；AKD wax contains admittedly
Amount is 15 ± 1%, and grain diameter is 0.5~2 μm.
8. it is according to claim 6 a kind of for heating the preparation method of the sizing agent for the tobacco product cigarette paper that do not burn,
It is characterized by: the tobacco aromaticss in the step (3) include damascenone, damascone, Megastigmatrienone, yunyan extract, Peru
Any one or more in medicinal extract, Tolu concrete.
9. it is according to claim 6 a kind of for heating the preparation method of the sizing agent for the tobacco product cigarette paper that do not burn,
It is characterized by: the regulator in the step (3) is one of hydroxypropyl methyl cellulose, sodium carboxymethylcellulose or two
Kind.
The sizing side of the sizing agent of tobacco product cigarette paper 10. the heating in a kind of claim 1 to 9 any one is not burnt
Method, it is characterised in that: the above-mentioned sizing agent for being used to heat the tobacco product cigarette paper that do not burn is transported in feeding groove, is re-fed into
The inner surface that cigarette paper is contacted with pipe tobacco is applied into surface size press；Wherein quantification of 28~35g/m of cigarette paper2, apply
For temperature system when glue at 25 DEG C~35 DEG C, single spreading amount is 3~10g/m2。
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Cited By (1)
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| CN113005818A (en) * | 2021-02-26 | 2021-06-22 | 中烟摩迪(江门)纸业有限公司 | Cigarette paper for improving storage appearance of heated cigarette and preparation method and application thereof |
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