CN109786867A - Lithium ion battery packet protection of liquid nitrogen technology - Google Patents

Lithium ion battery packet protection of liquid nitrogen technology Download PDF

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Publication number
CN109786867A
CN109786867A CN201811494456.2A CN201811494456A CN109786867A CN 109786867 A CN109786867 A CN 109786867A CN 201811494456 A CN201811494456 A CN 201811494456A CN 109786867 A CN109786867 A CN 109786867A
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China
Prior art keywords
lithium ion
ion battery
liquid nitrogen
batteries piles
ion batteries
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CN201811494456.2A
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Chinese (zh)
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潘乐平
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Anhui University of Science and Technology
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Anhui University of Science and Technology
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Priority to CN201811494456.2A priority Critical patent/CN109786867A/en
Publication of CN109786867A publication Critical patent/CN109786867A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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Abstract

The present invention relates to a kind of 1, lithium ion battery packet protection of liquid nitrogen technologies, it is characterised in that: using the ultralow temperature of liquid nitrogen, controls the explosive reaction on fire of lithium ion battery packet rapidly.Guarantee the safety of lithium battery pack;The technology, which can protect lithium ion battery packet, on fire to explode; it explodes if one or more lithium-ion battery monomers are on fire in lithium ion battery packet, make the lithium ion battery around the lithium ion battery of explosion on fire that explosion time on fire occur; the protection can inject liquid nitrogen to explosion site on fire in time; rapid cooling fire extinguishing; control the explosion on fire in lithium ion battery packet; lithium ion battery packet will not be made entirely to occur explosion phenomenon on fire, guarantee lithium ion battery packet using safe.

Description

Lithium ion battery packet protection of liquid nitrogen technology
Technical field
The present invention relates to lithium ion power storage battery field, the protection side of specifically a kind of lithium ion power storage battery packet Case.
Background technique
The part briefly explains technical background relevant to scheme of the invention, similar to the technical background in paper.
In recent years, with the rapid development of electric car, power lithium-ion battery demand is more and more.Electric vehicle to lithium from The requirement of sub- battery energy density, gross energy is continuously improved.The energy density and gross energy of lithium ion battery packet are also continuous It improves.But because the continuous improvement of lithium ion battery energy density, gross energy, risk also have opposite increase tendency. If the out-of-control phenomenon of explosion on fire occurs in lithium ion battery packet in lithium ion battery, easily lead to rising for lithium ion battery packet It is hot fried.
In recent years with the more and more electric cars occurred in society, mixed electrical automobile.At the same time, more and more There is dieseling in these automobiles, are all so special to driver, passenger and surrounding people when traffic accident especially occurs Not dangerous phenomenon, easily causes casualties.
For the explosion phenomenon on fire of lithium ion battery packet, now with the scheme of many maturations, but each have their own excellent lack Point.Most commonly battery management system (BMS) controls the whole service state of lithium ion battery packet, it is made to work as far as possible In a zone of reasonableness, to reduce the probability for explosion phenomenon on fire occur.In addition there are also air-cooled, liquid coolings, Li-ion batteries piles The various Control Measures such as encapsulating.But generally speaking, these measures have certain limitation, if there is lithium ion Battery cell explosion on fire has certain prevention and control to act on.But in case of largely Li-ion batteries piles explosion on fire Phenomenon, these measures are all ineffective.
Summary of the invention
The object of the present invention is to provide a kind of lithium ion battery packet protection of liquid nitrogen technology;The lithium ion battery packet liquid nitrogen is protected Shield technology has advantage and disadvantage:
Advantage: 1. liquid nitrogen inject Li-ion batteries piles, can rapidly reduce the blast temperature on fire of Li-ion batteries piles, rapidly Control out-of-control phenomenon.2. liquid nitrogen is small in size, light weight, too large space will not be occupied, while lithium ion battery packet will not be improved Weight.3. liquid nitrogen is nontoxic, even if being revealed during subsequent lithium ion battery maintenance packet again, as long as being careful not to make At frostbite, anoxic, personnel's life safety would not be influenced.
The present invention realizes that goal of the invention adopts the following technical scheme that
1, a kind of lithium ion battery packet protection of liquid nitrogen technology, it is characterised in that: using the ultralow temperature of liquid nitrogen, control lithium rapidly The explosive reaction on fire of ion battery packet, it is characterised in that: guarantee the safety of lithium ion battery packet,
The technology is made of following link:
(1) Li-ion batteries piles are mutually isolated, and isolation method is isolation cover, make each Li-ion batteries piles mutually not by It influences.
(2) liquid nitrogen can be injected among each isolation cover of (or can manufacture ultralow in a very short period of time as associated class The gas of warm environment) pipeline.This gas can be injected as needed at any time.
(3) there is temperature detecting module in each Li-ion batteries piles of, if detecting that the temperature of lithium ion battery group is more than The safe temperature of lithium ion battery, and continue 5 to 10S (or even longer time) when, determine the lithium ion battery in the isolation cover There is thermal failure reaction in group.
(4) lithium ion battery Bao Zhongyou voltage detection module and current detection module, if detecting abnormal voltage and electricity Stream, and predetermined state is not recovered at the appointed time, Li-ion batteries piles at abort situation will be judged according to setting rule There is explosion danger on fire, and starts link (5).
(5) in case of lithium ion battery thermal failure reaction in (3), start (2) step, where to the Li-ion batteries piles Isolation cover injection liquid nitrogen (or similar gas).
(6) Li-ion batteries piles are mutually isolated, and isolation method is isolation cover, make each Li-ion batteries piles mutually not by It influences.
(7) liquid nitrogen can be injected among each isolation cover of (or can manufacture ultralow in a very short period of time as associated class The gas of warm environment) pipeline.This gas can be injected as needed at any time.
(8) there is temperature detecting module in each Li-ion batteries piles of, if detecting that the temperature of lithium ion battery group is more than The safe temperature of lithium ion battery, and continue 5 to 10S (or even longer time) when, determine the lithium ion battery in the isolation cover There is thermal failure reaction in group.
(9) lithium ion battery Bao Zhongyou voltage detection module and current detection module, if detecting abnormal voltage and electricity Stream, and predetermined state is not recovered at the appointed time, Li-ion batteries piles at abort situation will be judged according to setting rule There is explosion danger on fire, and starts link (5).
(10) in case of lithium ion battery thermal failure reaction in (3), start (2) step, to the Li-ion batteries piles institute Isolation cover injection liquid nitrogen (or similar gas).
Preferably, a kind of lithium ion battery packet protection of liquid nitrogen technology provided by the invention, liquid nitrogen is as refrigeration drop rapidly Temperature, fire extinguishing protective gas, can be replaced by other gases, as long as there is room temperature to gasify rapidly, fire-retardant and cooling property rapidly Matter, such as carbon dioxide, helium gas;
Preferably, a kind of lithium ion battery packet protection of liquid nitrogen technology provided by the invention, the liquid nitrogen as cooling fire extinguishing, And other are with similar: rapid refrigeration cool-down, fire extinguishing material, can room temperature gasify rapidly heat absorption, can not burn, and Nontoxicity will not cause harm to the human body.
Preferably, a kind of lithium ion battery packet protection of liquid nitrogen technology provided by the invention, Li-ion batteries piles are separately put It sets in mutually isolated area of isolation, if explosion phenomenon on fire occur in a Li-ion batteries piles, it will not be jeopardized rapidly His Li-ion batteries piles, and if liquid nitrogen injects the Li-ion batteries piles, it can only work to the Li-ion batteries piles, to it He will not have an impact Li-ion batteries piles;
The utility model has the advantages that
Compared with prior art, the present invention its advantages are embodied in:
1. can control the explosion phenomenon on fire of lithium ion battery packet mould group rank, electric car and the peace of personnel are protected Entirely.This is the level that former protection technique is not achieved.
2. the invention, in protection, movement is fast, explosion phenomenon on fire can be controlled rapidly, and pollution-free, to personnel, ring Border fanout free region.
3. lithium ion battery packet protection technique used at present, if extensive rise occurs in lithium ion battery in battery pack It is hot fried, it will be unable to be effectively treated, and protect unspoiled lithium ion battery and vehicle safety, personnel safety;But this hair Bright technology can be after there are a large amount of lithium ion battery explosions on fire in lithium ion battery packet, and unspoiled lithium ion is left in protection Safety and vehicle safety, the personnel safety of battery.
Detailed description of the invention
Fig. 1 is the schematic diagram of the lithium ion battery protection of liquid nitrogen technology:
Specific embodiment
Explanation is further explained to the present invention below by way of specific embodiment.
Firstly, there is abnormal phenomenon during lithium ion battery is undertaken to perform work within a time limit and according to specifications and made, lithium-ion battery monomer appearance explosion on fire Phenomenon, the region will appear abnormal temperature and increase rapidly, detect overheating in temperature sensor, and the duration is more than It after setting time, can judge explosion phenomenon on fire occur, and judge its severe degree, when reaching sets requirement, controller is vertical That is starting liquid nitrogen cooling refrigeration.It is first turned on valve F, and valve corresponding to blast area on fire occurs, because of lithium-ion electric Pond job contract is made within the scope of room temperature, so, if valve is opened at two, liquid nitrogen can gasify rapidly, be injected into explosion on fire Li-ion batteries piles where region, so that the region is cooled down rapidly, and be full of nitrogen, thus reach cooling fire extinguishing purpose. After injection liquid nitrogen reaches setting time, valve corresponding to valve F and Li-ion batteries piles is successively closed, stops injection liquid Nitrogen.Entire lithium ion battery packet protection of liquid nitrogen scheme is fully completed.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims Variation is included within the present invention.Any reference signs in the claims should not be construed as limiting the involved claims.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiments being understood that.

Claims (4)

1. a kind of lithium ion battery packet protection of liquid nitrogen technology, it is characterised in that: using the ultralow temperature of liquid nitrogen, control lithium ion rapidly The explosive reaction on fire of battery pack.Guarantee that the safety of lithium ion battery packet, the technology are made of following link:
(1) Li-ion batteries piles are mutually isolated, and isolation method is isolation cover, keep each Li-ion batteries piles mutually unaffected.
(2) liquid nitrogen can be injected among each isolation cover of (or can manufacture ultralow temperature ring in a very short period of time as associated class The gas in border) pipeline.This gas can be injected as needed at any time.
(3) have temperature detecting module in each Li-ion batteries piles of, if detect the temperature of lithium ion battery group be more than lithium from The safe temperature of sub- battery, and it is continued above setting time, it is anti-to determine that thermal failure occur in the Li-ion batteries piles in the isolation cover It answers.
(4) lithium ion battery Bao Zhongyou voltage detection module and current detection module, if detect abnormal voltage and electric current, and And predetermined state is not recovered at the appointed time, it will judge there there are on fire Li-ion batteries piles at abort situation according to setting rule Explosion danger, and start link (5).
(5) in case of lithium ion battery thermal failure reaction in (3), start (2) step, where to the Li-ion batteries piles every From cover injection liquid nitrogen (or similar gas).
(6) Li-ion batteries piles are mutually isolated, and isolation method is isolation cover, keep each Li-ion batteries piles mutually unaffected.
(7) liquid nitrogen can be injected among each isolation cover of (or can manufacture ultralow temperature ring in a very short period of time as associated class The gas in border) pipeline.This gas can be injected as needed at any time.
(8) have temperature detecting module in each Li-ion batteries piles of, if detect the temperature of lithium ion battery group be more than lithium from The safe temperature of sub- battery, and it is continued above setting time, it is anti-to determine that thermal failure occur in the Li-ion batteries piles in the isolation cover It answers.
(9) lithium ion battery Bao Zhongyou voltage detection module and current detection module, if detect abnormal voltage and electric current, and And predetermined state is not recovered at the appointed time, it will judge there there are on fire Li-ion batteries piles at abort situation according to setting rule Explosion danger, and start link (5).
(10) in case of lithium ion battery thermal failure reaction in (3), start (2) step, to where the Li-ion batteries piles Isolation cover injects liquid nitrogen (or similar gas).
2. a kind of lithium ion battery packet protection of liquid nitrogen technology according to claim 1, it is characterised in that:
Liquid nitrogen can be replaced as rapid refrigeration cool-down, the protective gas of fire extinguishing by other gases, as long as having the rapid gas of room temperature Change, the fire-retardant and property that cools down rapidly, such as carbon dioxide, helium gas.
3. a kind of lithium ion battery packet protection of liquid nitrogen technology according to claim 1, it is characterised in that:
Liquid nitrogen as cooling fire extinguishing and other with similar: rapid refrigeration cool-down, fire extinguishing material, can room temperature it is fast Speed gasification heat absorption can not burn, and non-toxic, will not cause harm to the human body.
4. a kind of lithium ion battery packet protection of liquid nitrogen technology according to claim 1, it is characterised in that:
Each Li-ion batteries piles are separated in mutually isolated area of isolation, if a Li-ion batteries piles appearance is on fire Explosion phenomenon will not jeopardize rapidly other Li-ion batteries piles, and if liquid nitrogen injects the Li-ion batteries piles, only can be to this Li-ion batteries piles work, and will not have an impact to other Li-ion batteries piles.
CN201811494456.2A 2018-12-07 2018-12-07 Lithium ion battery packet protection of liquid nitrogen technology Pending CN109786867A (en)

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Application Number Priority Date Filing Date Title
CN201811494456.2A CN109786867A (en) 2018-12-07 2018-12-07 Lithium ion battery packet protection of liquid nitrogen technology

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110611138A (en) * 2019-09-02 2019-12-24 北京航天发射技术研究所 Cooling system of refrigerator car fuel cell and control method thereof
CN110838600A (en) * 2019-11-13 2020-02-25 江西优特汽车技术有限公司 Lithium ion battery pack thermal runaway control system for new energy electric vehicle and operation method
CN112701379A (en) * 2020-12-29 2021-04-23 重庆理工大学 Automatic cooling system of nitrogen-water premixed directional jet type battery
CN113013512A (en) * 2019-12-20 2021-06-22 广州汽车集团股份有限公司 Power battery pack, battery explosion-proof control system and battery explosion-proof control method
WO2021142812A1 (en) * 2020-01-17 2021-07-22 华为技术有限公司 Battery system and fire extinguishing method for battery system

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102760920A (en) * 2011-04-29 2012-10-31 肖克建 Liquid-nitrogen cooling method and device for automotive power battery pack
CN106684499A (en) * 2017-01-09 2017-05-17 武汉船用电力推进装置研究所(中国船舶重工集团公司第七二研究所) Method and apparatus for suppressing and preventing thermal runway of lithium ion battery
CN108711660A (en) * 2018-07-27 2018-10-26 清华大学 Lithium ion battery

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102760920A (en) * 2011-04-29 2012-10-31 肖克建 Liquid-nitrogen cooling method and device for automotive power battery pack
CN106684499A (en) * 2017-01-09 2017-05-17 武汉船用电力推进装置研究所(中国船舶重工集团公司第七二研究所) Method and apparatus for suppressing and preventing thermal runway of lithium ion battery
CN108711660A (en) * 2018-07-27 2018-10-26 清华大学 Lithium ion battery

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110611138A (en) * 2019-09-02 2019-12-24 北京航天发射技术研究所 Cooling system of refrigerator car fuel cell and control method thereof
CN110838600A (en) * 2019-11-13 2020-02-25 江西优特汽车技术有限公司 Lithium ion battery pack thermal runaway control system for new energy electric vehicle and operation method
CN113013512A (en) * 2019-12-20 2021-06-22 广州汽车集团股份有限公司 Power battery pack, battery explosion-proof control system and battery explosion-proof control method
WO2021142812A1 (en) * 2020-01-17 2021-07-22 华为技术有限公司 Battery system and fire extinguishing method for battery system
CN114761091A (en) * 2020-01-17 2022-07-15 华为数字能源技术有限公司 Battery system and fire extinguishing method of battery system
CN112701379A (en) * 2020-12-29 2021-04-23 重庆理工大学 Automatic cooling system of nitrogen-water premixed directional jet type battery
CN112701379B (en) * 2020-12-29 2022-03-08 重庆理工大学 Automatic cooling system of nitrogen-water premixed directional jet type battery

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Application publication date: 20190521