CN103682193A - High-capacity lithium ion battery - Google Patents

High-capacity lithium ion battery Download PDF

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Publication number
CN103682193A
CN103682193A CN201210337493.9A CN201210337493A CN103682193A CN 103682193 A CN103682193 A CN 103682193A CN 201210337493 A CN201210337493 A CN 201210337493A CN 103682193 A CN103682193 A CN 103682193A
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China
Prior art keywords
utmost point
battery
lithium ion
ion battery
positive
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CN201210337493.9A
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CN103682193B (en
Inventor
杨从明
仝志明
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Microvast Holdings Inc
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Microvast Power Systems Huzhou Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/116Primary casings; Jackets or wrappings characterised by the material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/116Primary casings; Jackets or wrappings characterised by the material
    • H01M50/124Primary casings; Jackets or wrappings characterised by the material having a layered structure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/30Arrangements for facilitating escape of gases
    • H01M50/342Non-re-sealable arrangements
    • H01M50/3425Non-re-sealable arrangements in the form of rupturable membranes or weakened parts, e.g. pierced with the aid of a sharp member
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Secondary Cells (AREA)

Abstract

The invention discloses a high-capacity lithium ion battery which comprises a shell sealed overall by a liquid, a plurality of battery cells arranged in the shell, two current collectors located in the shell, a positive output electrode and a negative output electrode, wherein the anode and cathode of battery cell are respectively connected with one of the current collectors, the positive output electrode and the negative output electrode are respectively and electrically with one of the current collectors, and an insulative fire retardant liquid is injected to the shell. By adopting injecting the insulative fire retardant liquid to the battery shell, the plurality of battery cells are infiltrated in the insulative fire retardant liquid, so that the temperature between battery cells can be kept balanced so as to prevent an internal heat point from happening to further cause thermal runaway, in addition, in such a condition, even if an accident of piercing a battery is happened, the spilled electrolyte of the battery cells is surrounded by the insulative fire retardant liquid, and can not be contacted with air, so that a fire accident can be avoided; even if outside flames enters into the shell, the insulative fire retardant liquid can be used for putting out a fire after being heated and volatilized.

Description

High capacity lithium ion battery
[technical field]
The present invention relates to a kind of lithium ion battery, especially, relate to a kind of jumbo lithium ion battery.
[background technology]
Along with petroleum resources day by day reduce and the pollution of environment day by day serious, protection of the environment, energy-saving and emission-reduction have become current trend and trend in the world.Under this background, in recent years, the motor vehicle that the battery of take is main power source or partial power source (mainly comprises hybrid electric vehicle, plug-in hybrid electric vehicle, pure electric vehicle) engender and increasing, the carbon emission amount of motor vehicle is less than traditional combustion engine automobile, and the carbon emission of pure electric vehicle is even zero, and have the advantages that energy conversion efficiency is high, this makes people electric automobile is considered as to an important selection of following replace internal combustion engines car.
The power of current electric automobile is mainly selected lithium ion battery bag, lithium ion battery bag consists of a plurality of lithium-ion battery monomers, when carrying out power brick design, if adopted compared with the lithium-ion battery monomer of low capacity, the connection more complicated between lithium-ion battery monomer, BMS(battery management system) design is more complicated also; And if adopt the lithium-ion battery monomer of larger capacity, the connection between lithium-ion battery monomer is more convenient, the design of BMS system is also relatively simple and easy.Here said compared with the lithium-ion battery monomer of low capacity, mainly refer to traditional lithium-ion battery monomers such as 18650 traditional types, 26650 types, their general storage power are less than 10Wh.And high capacity lithium ion battery monomer mainly refers to larger Soft Roll or the box hat rectangular cell monomer occurring in recent years, their general storage power are greater than 10Wh.
But existing jumbo lithium-ion battery monomer has following shortcoming: first, its storage power is more, once break down, only need several even battery cells just can cause serious consequence, secondly, overcharging or crossing under the condition of putting, it is overheated that high capacity lithium ion battery monomer easily occurs, and the in the situation that of puncture, at a large amount of electrolyte, overflow rapidly after ingress of air, even may there is the situations such as blast on fire in high capacity lithium ion battery monomer.
Have part producer to adopt the little battery cell of a plurality of parallel connections be set in a battery container, thereby form the way of a large battery cell, thus but this way easily causes generating heat between the battery cell of enclosure interior the inhomogeneous thermal runaway that causes.And this way can not overcome the blast problem on fire in above-mentioned puncture situation equally.
[summary of the invention]
The object of this invention is to provide a kind of safe high capacity lithium ion battery.
For above-mentioned purpose, the technical solution used in the present invention is:
A kind of high capacity lithium ion battery, it comprises the housing of whole liquid sealing, be arranged on a plurality of battery cells in described housing, be positioned at two collectors of housing, the positive output utmost point and the negative output utmost point, wherein the both positive and negative polarity of battery cell is connected with a collector respectively, the described positive output utmost point and the negative output utmost point are electrically connected with a collector respectively, in housing, be perfused with flame-resistant insulation liquid, the liquid level of described flame-resistant insulation liquid is higher than the both positive and negative polarity of battery cell and the tie point of collector, the liquid level of described flame-resistant insulation liquid is higher than the both positive and negative polarity of battery cell and the tie point of collector, in the positive output utmost point and negative output, be provided with ptc material or fuse on extremely.
As preferred technical scheme: be provided with pressure valve on described housing.
As preferred technical scheme: be provided with copper separator between described battery cell.
As preferred technical scheme: be provided with compound insulation layer between described battery cell, described compound insulation layer is wrapped up in paraffin by copper-clad and formed.
As preferred technical scheme: described flame-resistant insulation liquid is silicone oil.
As preferred technical scheme: described flame-resistant insulation liquid is fire resistant oil.
The present invention adopts and in battery container, pours into flame-resistant insulation liquid, a plurality of battery cells infiltrate in flame-resistant insulation liquid, thereby the temperature between battery cell is kept in balance, thereby be unlikely, occur that inner focus causes thermal runaway, in addition, in this case, even if pierce through the accident of battery, the electrolyte of battery cell is surrounded by flame-resistant insulation liquid after overflowing, can not ingress of air, can not cause accident on fire; Even if there is extraneous flare to enter into enclosure interior, flame-resistant insulation liquid, after the volatilization of being heated, can also play the effect of fire extinguishing.So high capacity lithium ion battery of the present invention has the effect of large capacity and high safety.In addition, by the liquid level setting of flame-resistant insulation liquid in housing higher than the both positive and negative polarity of battery cell and the tie point of collector.Owing to being generally the larger place of the larger heating of electric current at tie point place, be also the place being prone to accidents, so by the liquid level setting of flame-resistant insulation liquid higher than tie point, guarantee further the safety of whole high capacity lithium ion battery.Finally, in the positive output utmost point and negative output, be provided with ptc material or fuse on extremely, when high capacity lithium ion battery occurs abnormal, for example, when having abnormal High-current output, ptc material is subject to thermal resistance can become large, thereby reach the object of current limliting, thereby can there is fusing turn-off current, the fail safe that more improves whole high capacity lithium ion battery in fuse.
In one of preferred technical scheme, on housing, be provided with pressure valve, when high capacity lithium ion battery internal pressure is excessive, can carry out release by pressure valve, prevent from that internal pressure is excessive to set off an explosion.
In one of preferred technical scheme, between described battery cell, be provided with copper separator.Copper is hot excellence conductor, add copper separator can further make the temperature between battery cell keep in balance, on the other hand, when having an accident, for example, when having hard thing to thrust high capacity lithium ion battery, copper separator can stop hard thing, makes hard thing be difficult for running through whole high capacity lithium ion battery.Can further improve the fail safe of high capacity lithium ion battery when being punctured like this.
In one of preferred technical scheme, between described battery cell, be provided with compound insulation layer, described compound insulation layer is wrapped up in paraffin by copper-clad and is formed.Paraffin is a kind of phase-change material, when being heated, can absorbing heat and become liquid, adopt copper-clad to wrap up in paraffin, can there is above-mentioned copper separator, can also further utilize paraffin liquefaction to absorb the heating of battery cell, thereby make whole high capacity lithium ion battery under good temperature conditions, carry out work.
[accompanying drawing explanation]
Fig. 1 is the schematic diagram of one embodiment of the invention;
Fig. 2 is the schematic diagram of another embodiment of the present invention;
Fig. 3 is the schematic diagram of another embodiment of the present invention;
Fig. 4 is the schematic diagram of another embodiment of the present invention;
Wherein:
1. housing; 2. battery cell; 3. collector; 4. the positive output utmost point or the negative output utmost point; 5. flame-resistant insulation liquid liquid level; 6. the both positive and negative polarity of battery cell and the tie point of collector; 7.PTC material; 8. fuse; 9. pressure valve; 10. copper separator; 11. compound insulation layers; The copper of 111. compound insulation layers is outer; The paraffin internal layer of 112. compound insulation layers.
[embodiment]
Embodiment 1
A kind of high capacity lithium ion battery, it comprise whole liquid sealing housing 1, be arranged on a plurality of battery cells 2 in described housing 1, be positioned at two collectors 3, the positive output utmost point and the negative output utmost point 4 of housing, the both positive and negative polarity of described battery cell 2 is connected with a collector 3 respectively, affiliated the positive output utmost point and the negative output utmost point 4 are electrically connected with a collector 3 respectively, in described housing 1, are perfused with silicone oil.
Embodiment 2
As schematically shown in Figure 1: a kind of high capacity lithium ion battery, it comprise whole liquid sealing housing 1, be arranged on a plurality of battery list 2 bodies in described housing 1, be positioned at two collectors 3, the positive output utmost point and the negative output utmost point 4 of housing, the both positive and negative polarity of described battery cell 2 is connected with a collector 3 respectively, affiliated the positive output utmost point and the negative output utmost point 4 are electrically connected with a collector 3 respectively, in described housing 1, are perfused with dimethicone.The liquid level 5 of described dimethicone is higher than the both positive and negative polarity of battery cell and the tie point of collector 6.
Embodiment 3
As schematically shown in Figure 2: a kind of high capacity lithium ion battery, it comprise whole liquid sealing housing 1, be arranged on a plurality of battery list 2 bodies in described housing 1, be positioned at two collectors 3, the positive output utmost point and the negative output utmost point 4 of housing, the both positive and negative polarity of described battery cell 2 is connected with a collector 3 respectively, affiliated the positive output utmost point and the negative output utmost point 4 are electrically connected with a collector 3 respectively, in described housing 1, are perfused with dimethicone.The liquid level 5 of described dimethicone is higher than the both positive and negative polarity of battery cell and the tie point of collector 6.
On the positive output utmost point and the negative output utmost point 4, be provided with ptc material 7.
Embodiment 4
A kind of high capacity lithium ion battery, it comprise whole liquid sealing housing 1, be arranged on a plurality of battery list 2 bodies in described housing 1, be positioned at two collectors 3, the positive output utmost point and the negative output utmost point 4 of housing, the both positive and negative polarity of described battery cell 2 is connected with a collector 3 respectively, affiliated the positive output utmost point and the negative output utmost point 4 are electrically connected with a collector 3 respectively, are perfused with EH fire resistant oil in described housing 1.The liquid level 5 of described EH fire resistant oil is higher than the both positive and negative polarity of battery cell and the tie point of collector 6.
On the positive output utmost point and the negative output utmost point 4, be provided with fuse 8.
Embodiment 5
A kind of high capacity lithium ion battery, it comprise whole liquid sealing housing 1, be arranged on a plurality of battery list 2 bodies in described housing 1, be positioned at two collectors 3, the positive output utmost point and the negative output utmost point 4 of housing, the both positive and negative polarity of described battery cell 2 is connected with a collector 3 respectively, affiliated the positive output utmost point and the negative output utmost point 4 are electrically connected with a collector 3 respectively, in described housing 1, are perfused with dimethicone.The liquid level 5 of described dimethicone is higher than the both positive and negative polarity of battery cell and the tie point of collector 6.
On the positive output utmost point and the negative output utmost point 4, be provided with ptc material 7.
On described housing 1, be provided with pressure valve 9.
Embodiment 6
A kind of high capacity lithium ion battery, it comprise whole liquid sealing housing 1, be arranged on a plurality of battery list 2 bodies in described housing 1, be positioned at two collectors 3, the positive output utmost point and the negative output utmost point 4 of housing, the both positive and negative polarity of described battery cell 2 is connected with a collector 3 respectively, affiliated the positive output utmost point and the negative output utmost point 4 are electrically connected with a collector 3 respectively, in described housing 1, are perfused with dimethicone.The liquid level 5 of described dimethicone is higher than the both positive and negative polarity of battery cell and the tie point of collector 6.
On the positive output utmost point and the negative output utmost point 4, be provided with fuse 8.
On described housing 1, be provided with pressure valve 9.
Embodiment 7
As schematically shown in Figure 3: a kind of high capacity lithium ion battery, it comprise whole liquid sealing housing 1, be arranged on a plurality of battery list 2 bodies in described housing 1, be positioned at two collectors 3, the positive output utmost point and the negative output utmost point 4 of housing, the both positive and negative polarity of described battery cell 2 is connected with a collector 3 respectively, affiliated the positive output utmost point and the negative output utmost point 4 are electrically connected with a collector 3 respectively, are perfused with EH fire resistant oil in described housing 1.The liquid level 5 of described EH fire resistant oil is higher than the both positive and negative polarity of battery cell and the tie point of collector 6.
On the positive output utmost point and the negative output utmost point 4, be provided with ptc material 7.
On described housing 1, be provided with pressure valve 9.
Between described battery cell 2, be provided with copper separator 10.
Embodiment 8
A kind of high capacity lithium ion battery, it comprise whole liquid sealing housing 1, be arranged on a plurality of battery list 2 bodies in described housing 1, be positioned at two collectors 3, the positive output utmost point and the negative output utmost point 4 of housing, the both positive and negative polarity of described battery cell 2 is connected with a collector 3 respectively, affiliated the positive output utmost point and the negative output utmost point 4 are electrically connected with a collector 3 respectively, in described housing 1, are perfused with dimethicone.The liquid level 5 of described dimethicone is higher than the both positive and negative polarity of battery cell and the tie point of collector 6.
On the positive output utmost point and the negative output utmost point 4, be provided with fuse 8.
On described housing 1, be provided with pressure valve 9.
Between described battery cell 2, be provided with copper separator 10.
Embodiment 9
As schematically shown in Figure 4: a kind of high capacity lithium ion battery, it comprise whole liquid sealing housing 1, be arranged on a plurality of battery list 2 bodies in described housing 1, be positioned at two collectors 3, the positive output utmost point and the negative output utmost point 4 of housing, the both positive and negative polarity of described battery cell 2 is connected with a collector 3 respectively, affiliated the positive output utmost point and the negative output utmost point 4 are electrically connected with a collector 3 respectively, are perfused with EH fire resistant oil in described housing 1.The liquid level 5 of described EH fire resistant oil is higher than the both positive and negative polarity of battery cell and the tie point of collector 6.
On the positive output utmost point and the negative output utmost point 4, be provided with ptc material 7.
On described housing 1, be provided with pressure valve 9.
Between described battery cell, be provided with compound insulation layer 11, the internal layer 112 that skin 111 parcels that described compound insulation layer 11 consists of copper consist of paraffin forms.
Embodiment 10
A kind of high capacity lithium ion battery, it comprise whole liquid sealing housing 1, be arranged on a plurality of battery list 2 bodies in described housing 1, be positioned at two collectors 3, the positive output utmost point and the negative output utmost point 4 of housing, the both positive and negative polarity of described battery cell 2 is connected with a collector 3 respectively, affiliated the positive output utmost point and the negative output utmost point 4 are electrically connected with a collector 3 respectively, in described housing 1, are perfused with dimethicone.The liquid level 5 of described dimethicone is higher than the both positive and negative polarity of battery cell and the tie point of collector 6.
On the positive output utmost point and the negative output utmost point 4, be provided with fuse 8.
On described housing 1, be provided with pressure valve 9.
Between described battery cell, be provided with compound insulation layer 11, the internal layer 112 that skin 111 parcels that described compound insulation layer 11 consists of copper consist of paraffin forms.
Protection scope of the present invention is not limited in above-described embodiment, and all variations of doing under spirit of the present invention and change, within all should dropping on protection range of the present invention.

Claims (6)

1. a high capacity lithium ion battery, it is characterized in that: it comprises the housing of whole liquid sealing, be arranged on a plurality of battery cells in described housing, be positioned at two collectors of housing, the positive output utmost point and the negative output utmost point, the both positive and negative polarity of described battery cell is connected with a collector respectively, the described positive output utmost point and the negative output utmost point are electrically connected with a collector respectively, in described housing, be perfused with flame-resistant insulation liquid, the liquid level of described flame-resistant insulation liquid is higher than the both positive and negative polarity of battery cell and the tie point of collector, in the positive output utmost point and negative output, be provided with ptc material or fuse on extremely.
2. high capacity lithium ion battery as claimed in claim 1, is characterized in that: between described battery cell, be provided with copper separator.
3. high capacity lithium ion battery as claimed in claim 1, is characterized in that: described, between described battery cell, be provided with compound insulation layer, described compound insulation layer is wrapped up in paraffin by copper-clad and formed.
4. the high capacity lithium ion battery as described in as arbitrary in claim 1 ~ 3, is characterized in that: on described housing, be provided with pressure valve.
5. the high capacity lithium ion battery as described in as arbitrary in claim 1~3, is characterized in that: described flame-resistant insulation liquid is any in silicone oil or fire resistant oil.
6. high capacity lithium ion battery as claimed in claim 4, is characterized in that: described flame-resistant insulation liquid is any in silicone oil or fire resistant oil.
CN201210337493.9A 2012-09-13 2012-09-13 High capacity lithium ion battery Active CN103682193B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105470442A (en) * 2015-11-13 2016-04-06 王晓秋 Lithium battery pack module with high safety design
CN108550720A (en) * 2018-03-16 2018-09-18 深圳市前海星火同为科技有限公司 A kind of navigation anticorrosion large-capacity battery and manufacturing method
CN109524586A (en) * 2018-11-19 2019-03-26 颍上北方动力新能源有限公司 Compact battery mould group protecting box
CN110609235A (en) * 2019-10-14 2019-12-24 中国民用航空飞行学院 Lithium battery thermal safety monitoring system based on optical fiber detection technology
CN116404117A (en) * 2023-06-07 2023-07-07 四川富临新能源科技有限公司 Method for improving capacity of sodium ion positive electrode material

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Publication number Priority date Publication date Assignee Title
JP2003092094A (en) * 2001-09-19 2003-03-28 Japan Storage Battery Co Ltd Cell device
CN101325269A (en) * 2007-06-13 2008-12-17 深圳市比克电池有限公司 Lithium ion battery
CN102157716A (en) * 2011-03-18 2011-08-17 南京双登科技发展研究院有限公司 Battery combination device
CN102544406A (en) * 2012-02-15 2012-07-04 中国电力科学研究院 Flexibly-packaged battery module group
CN202817051U (en) * 2012-09-13 2013-03-20 微宏动力***(湖州)有限公司 High-capacity lithium ion battery

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003092094A (en) * 2001-09-19 2003-03-28 Japan Storage Battery Co Ltd Cell device
CN101325269A (en) * 2007-06-13 2008-12-17 深圳市比克电池有限公司 Lithium ion battery
CN102157716A (en) * 2011-03-18 2011-08-17 南京双登科技发展研究院有限公司 Battery combination device
CN102544406A (en) * 2012-02-15 2012-07-04 中国电力科学研究院 Flexibly-packaged battery module group
CN202817051U (en) * 2012-09-13 2013-03-20 微宏动力***(湖州)有限公司 High-capacity lithium ion battery

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105470442A (en) * 2015-11-13 2016-04-06 王晓秋 Lithium battery pack module with high safety design
CN108550720A (en) * 2018-03-16 2018-09-18 深圳市前海星火同为科技有限公司 A kind of navigation anticorrosion large-capacity battery and manufacturing method
CN109524586A (en) * 2018-11-19 2019-03-26 颍上北方动力新能源有限公司 Compact battery mould group protecting box
CN110609235A (en) * 2019-10-14 2019-12-24 中国民用航空飞行学院 Lithium battery thermal safety monitoring system based on optical fiber detection technology
CN116404117A (en) * 2023-06-07 2023-07-07 四川富临新能源科技有限公司 Method for improving capacity of sodium ion positive electrode material
CN116404117B (en) * 2023-06-07 2023-08-11 四川富临新能源科技有限公司 Method for improving capacity of sodium ion positive electrode material

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Address after: 313000 Huzhou economic and Technological Development Zone, Zhejiang, Hung Fung Road, No. 2198

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