CN109786801A

CN109786801A - A kind of chemical energy electric energy conversion method

Info

Publication number: CN109786801A
Application number: CN201910107802.5A
Authority: CN
Inventors: 靳北彪
Original assignee: Entropy Zero Technology Logic Engineering Group Co Ltd
Current assignee: Entropy Zero Technology Logic Engineering Group Co Ltd
Priority date: 2018-08-26
Filing date: 2019-02-02
Publication date: 2019-05-21
Also published as: CN109860960A; CN109802201A; CN109786793A; CN109860680A; CN109786802A

Abstract

The invention discloses a kind of chemical energy electric energy conversion methods, electrochemistry region is set alternately to contact or make reducing agent and oxidant alternately to contact with electrochemistry region with reducing agent and oxidant, the electrochemistry region has non-electronic conducting electrical relation through at least one of non-electronic charged particle transmitter, electronic conduction area and dielectric three and region B, is imported using the export of the electronics between the electrochemistry region and the region B and realizes output electric energy and/or absorption electric energy.Chemical energy electric energy conversion method disclosed in this invention is by termination Conventional electrochemical method and electrochemical appliance (such as fuel cell etc.) with the history for existing for necessary condition of electrolyte (such as proton exchange membrane and solid oxide electrolyte etc.), the Conventional electrochemical method and device that terminates also can not be used securely and reliably to the history of oxidant reduction agent composition, exploitation for efficient, long-life, Low-cost electric chemical devices provides new approach, and will redefine engine.

Description

A kind of chemical energy electric energy conversion method

Technical field

The present invention relates to electricity field, electrochemical field more particularly to a kind of chemical energy electric energy conversion methods.

Background technique

Conventional electrochemical method is required to non-electronic charged particle (such as ion or proton) and transmits between two electrodes, that is, needs Positive charged particle and negative charged particles that electrochemistry region (electrode) generates are removed, non-electronic charged particle is in two interpolars Transmission not only consume electric energy, but also be required to conduct non-electronic charged particle non-conducting electronics and there are many particular/special requirements Electrolyte (such as proton exchange membrane and solid oxide electrolyte etc. of hydrogen fuel cell), because of its complexity, this electrolysis The manufacturing technology of matter is unqualified always, and has become and restrict electrochemical method and be efficiently widely applied and its electrochemical appliance (example Such as fuel cell) improved efficiency, the basic reason of life-span upgrading and cost reduction, also have become and hinders electrochemical appliance (example Such as fuel cell) efficiently industrialization problem the most serious.If can invent a kind of not non-to be removed from electrochemistry region Electronics charged particle is the new chemical energy electric energy conversion method of necessary condition, and termination Conventional electrochemical method and electrochemistry are filled It sets (such as fuel cell etc.) and necessary item is existed for electrolyte (such as proton exchange membrane and solid oxide electrolyte etc.) The history of part, also will termination Conventional electrochemical method and device can not safe and reliable going through using oxidant reduction agent composition History provides new approach for efficient, long-life, Low-cost electric chemical devices exploitation, and will redefine engine.Therefore, Need to invent a kind of new chemical energy electric energy conversion method.

Summary of the invention

To solve the above-mentioned problems, technical solution proposed by the present invention is as follows:

Scheme 1: a kind of chemical energy electric energy conversion method makes electrochemistry region alternately contact or make with reducing agent and oxidant Reducing agent and oxidant are alternately contacted with electrochemistry region, and the electrochemistry region is through non-electronic charged particle transmitter, electronics At least one of area and dielectric three and region B, which is connected, has non-electronic conducting electrical relation, using from the electrochemistry The export of electronics between region and the region B, which imports, realizes output electric energy and/or absorption electric energy；

Or, making electrochemistry region contact with each other with reducing agent and connecing the electrochemistry region mutually discontinuously with oxidant Touching, or electrochemistry region and oxidant is made to contact with each other and make the electrochemistry region and the mutual makes discontinuous contact of reducing agent, it is described Electrochemistry region has through at least one of non-electronic charged particle transmitter, electronic conduction area and dielectric three and region B There is non-electronic conducting electrical relation, is imported and realized using the export of the electronics between the electrochemistry region and the region B It exports electric energy and/or absorbs electric energy.

Scheme 2: on the basis of scheme 1, further selectively selection makes the electrochemistry region through non-electronic electrification Particle conduction object and the region B have non-electronic conducting electrical relation or the electrochemistry region successively through electronic conduction area Have non-electronic conducting electrical relation or the electrochemistry region through electricity with non-electronic charged particle transmitter and the region B Medium and the region B have non-electronic conducting electrical relation or the electrochemistry region through insulation, isolation space, electrolysis At least one of matter, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area with The region B is correspondingly arranged.

Scheme 3: a kind of chemical energy electric energy conversion method contacts electrochemistry region and the mixture of reducing agent and oxidant Or contacting the mixture of reducing agent and oxidant with electrochemistry region, the electrochemistry region is conducted through non-electronic charged particle At least one of object, electronic conduction area and dielectric three and region B have non-electronic conducting electrical relation, using from described The export of electronics between electrochemistry region and the region B, which imports, realizes output electric energy and/or absorption electric energy.

Scheme 4: on the basis of scheme 3, further selectively selection makes the electrochemistry region through non-electronic electrification Particle conduction object and the region B have non-electronic conducting electrical relation, or make the electrochemistry region successively through electronic conduction Area and non-electronic charged particle transmitter and the region B have non-electronic conducting electrical relation, or make the electrochemistry region There is non-electronic conducting electrical relation through dielectric and the region B, or keep the electrochemistry region empty through insulation, isolation Between, in electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area at least It is a kind of to be correspondingly arranged with the region B.

Scheme 5: a kind of chemical energy electric energy conversion method keeps electrochemistry region and the mixture of reducing agent and oxidant interrupted The mixture of reducing agent and oxidant and electrochemistry region makes discontinuous contact are contacted or make, the electrochemistry region is through non-electronic electrification At least one of particle conduction object, electronic conduction area and dielectric three have non-electronic conducting electrical relation with region B, utilize The export of electronics between the electrochemistry region and the region B, which imports, realizes output electric energy and/or absorption electric energy.

Scheme 6: on the basis of scheme 5, further selectively selection makes the electrochemistry region through non-electronic electrification Particle conduction object and the region B have non-electronic conducting electrical relation, or make the electrochemistry region successively through electronic conduction Area and non-electronic charged particle transmitter and the region B have non-electronic conducting electrical relation, or make the electrochemistry region There is non-electronic conducting electrical relation through dielectric and the region B, or keep the electrochemistry region empty through insulation, isolation Between, in electrolyte, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area at least It is a kind of to be correspondingly arranged with the region B.

Scheme 7: a kind of chemical energy electric energy conversion method, make electrochemistry region A and reducing agent and oxidant alternately contact or Contact reducing agent and oxidant and electrochemistry region A alternately, make electrochemistry region B replace with Oxidizing and Reducing Agents contact or Contact Oxidizing and Reducing Agents and electrochemistry region B alternately, the electrochemistry region A through non-electronic charged particle transmitter, At least one of electronic conduction area and dielectric three have non-electronic conducting electrical relation, benefit with the electrochemistry region B It is imported with the export of the electronics between the electrochemistry region A and the electrochemistry region B and realizes output electric energy and/or absorb electric Energy；

Or, contacting electrochemistry region A with reducing agent and making the electrochemistry region A and oxidant makes discontinuous contact and make Electrochemistry region B is contacted with reducing agent and is made the electrochemistry region B and oxidant makes discontinuous contact, or make electrochemistry region A with Oxidant contact and make the electrochemistry region A and reducing agent makes discontinuous contact and also make electrochemistry region B contacted with oxidant and Make the electrochemistry region B and reducing agent makes discontinuous contact, or contacts electrochemistry region A with reducing agent and make the electrochemical school district It domain A and oxidant makes discontinuous contact and contacts electrochemistry region B with oxidant and keeps the electrochemistry region B and reducing agent disconnected Continued access touching, the electrochemistry region A is through at least one in non-electronic charged particle transmitter, electronic conduction area and dielectric three Person and the electrochemistry region B have non-electronic conducting electrical relation, utilize the electrochemistry region A and the electrochemistry region The export of electronics between B, which imports, realizes output electric energy and/or absorption electric energy.

Scheme 8: on the basis of scheme 7, further selectively selection makes the electrochemistry region A through non-electronic electrification Particle conduction object and the electrochemistry region B have non-electronic conducting electrical relation, or make the electrochemistry region A successively through electricity Son conducting area and non-electronic charged particle transmitter and the electrochemistry region B have non-electronic conducting electrical relation, or make institute Electrochemistry region A is stated successively through non-electronic charged particle transmitter A and non-electronic charged particle transmitter B and the electrochemical school district Domain B has non-electronic conducting electrical relation, or makes the electrochemistry region A successively through non-electronic charged particle transmitter A, electronics Area and non-electronic charged particle transmitter B and the electrochemistry region B, which is connected, has non-electronic conducting electrical relation, or makes described Electrochemistry region A is successively through electronic conduction area A, non-electronic charged particle transmitter and electronic conduction area B and the electrochemical school district Domain B has non-electronic conducting electrical relation, or makes the electrochemistry region A through dielectric and the electrochemistry region B with non- Electronic conduction electrical relation, or make the electrochemistry region A through insulation, isolation space, electrolyte, dielectric, capacitor, etc. from At least one of daughter, ionic liquid, ionized gas, solion and electronic conduction area are corresponding with the electrochemistry region B Setting.

Scheme 9: a kind of chemical energy electric energy conversion method meets electrochemistry region A and the mixture of reducing agent and oxidant It touches or makes the mixture of reducing agent and oxidant to contact with electrochemistry region A, make electrochemistry region B and reducing agent and oxidant Mixture contacts or contacts the mixture of reducing agent and oxidant with electrochemistry region B, and the electrochemistry region A is through non-electronic At least one of charged particle transmitter, electronic conduction area and dielectric three have non-electronic with the electrochemistry region B Electrical relation is connected, is imported using the export of the electronics between the electrochemistry region A and the electrochemistry region B and realizes output Electric energy and/or absorption electric energy.

Scheme 10: on the basis of scheme 9, further selectively selection makes the electrochemistry region A through non-electronic band Charged particle transmitter and the electrochemistry region B have non-electronic conducting electrical relation, or pass through the electrochemistry region A successively Electronic conduction region and non-electronic charged particle transmitter and the electrochemistry region B have non-electronic conducting electrical relation, or Make the electrochemistry region A successively through non-electronic charged particle transmitter A and non-electronic charged particle transmitter B and the electrification School district domain B have non-electronic conducting electrical relation, or make the electrochemistry region A successively through non-electronic charged particle transmitter A, Electronic conduction area and non-electronic charged particle transmitter B and the electrochemistry region B have non-electronic conducting electrical relation, or make The electrochemistry region A is successively through electronic conduction area A, non-electronic charged particle transmitter and electronic conduction area B and the electrification School district domain B has non-electronic conducting electrical relation, or has the electrochemistry region A through dielectric and the electrochemistry region B Have non-electronic conducting electrical relation, or make the electrochemistry region A through insulation, isolation space, electrolyte, dielectric, capacitor, At least one of plasma, ionic liquid, ionized gas, solion and electronic conduction area and the electrochemistry region B It is correspondingly arranged.

Scheme 11: a kind of chemical energy electric energy conversion method keeps the mixture of electrochemistry region A and reducing agent and oxidant disconnected Continued access touches or makes the mixture of reducing agent and oxidant and electrochemistry region A makes discontinuous contact, make electrochemistry region B and reducing agent and The mixture makes discontinuous contact of oxidant makes the mixture of reducing agent and oxidant and electrochemistry region B makes discontinuous contact, the electricity Chemical regions A is through at least one of non-electronic charged particle transmitter, electronic conduction area and dielectric three and the electrification School district domain B has non-electronic conducting electrical relation, utilizes the electronics between the electrochemistry region A and the electrochemistry region B Export import realize output electric energy and/or absorb electric energy.

Scheme 12: on the basis of scheme 11, further selectively selection makes the electrochemistry region A through non-electronic band Charged particle transmitter and the electrochemistry region B have non-electronic conducting electrical relation, or pass through the electrochemistry region A successively Electronic conduction area and non-electronic charged particle transmitter and the electrochemistry region B have non-electronic conducting electrical relation, or make The electrochemistry region A is successively through non-electronic charged particle transmitter A and non-electronic charged particle transmitter B and the electrochemistry Region B has non-electronic conducting electrical relation, or makes the electrochemistry region A successively through non-electronic charged particle transmitter A, electricity Son conducting area and the non-electronic charged particle transmitter B and electrochemistry region B have non-electronic conducting electrical relation, or make institute Electrochemistry region A is stated successively through electronic conduction area A, non-electronic charged particle transmitter and electronic conduction area B and the electrochemistry Region B has non-electronic conducting electrical relation, or has the electrochemistry region A through dielectric and the electrochemistry region B Non-electronic conducting electrical relation, or make the electrochemistry region A through insulation, isolation space, electrolyte, dielectric, capacitor, etc. At least one of gas ions, ionic liquid, ionized gas, solion and electronic conduction area and B pairs of the electrochemistry region It should be arranged.

Scheme 13: in scheme 1 and 2 and 7 and 8 on the basis of either a program, further the chemical energy electric energy is converted When method is as the method for exchanging electric energy for chemical energy, being selectively chosen makes in the chemical energy electric energy conversion method Inert substance and/or dead band duration are inserted between reducing agent and oxidant.

During exporting electric energy and/or absorbing electric energy, the aforementioned all schemes of the present invention are optionally using electricity Effect.

During exporting electric energy and/or absorbing electric energy, the aforementioned all schemes of the present invention optionally specifically make With capacitor, DC power supply, AC power source, alternating source, inductor conductor, inductance coil, charged particle pump, phase converter, change To switching circuit, rectifier, electric field, oscillating circuit, motor, reversible electric machine, the motor with additional rotation inertia or its two Conjunction, its three conjunction, its four conjunction, its five conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine Conjunction, its ten conjunction, its 11 conjunction, the conjunction of its ten binomial, its 13 conjunction, its 14 conjunction, its 15 Conjunction.

The aforementioned all schemes of the present invention further can selectively select to apply electricity to the region for participating in electrochemical reaction Effect, so that the substance for participating in electrochemical reaction is difficult to directly carry out redox reaction.

The aforementioned all schemes of the present invention further can selectively select the export of electronics to import as work normality.

The aforementioned all schemes containing the electrochemistry region and the region B of the present invention, can further selectively The export for making electronics between the electrochemistry region and the region B is selected to import as work normality.

The aforementioned all schemes containing the electrochemistry region A and the electrochemistry region B of the present invention, can further select The export for making electronics between the electrochemistry region A and the electrochemistry region B is selected to selecting property to import as work normality.

In the present invention, so-called " inductor conductor " refers to all externally output magnetic force energy and leading from outer absorption magnetic force energy Body.Such as transformer coil, electrical-coil, conductor bars for dynamoelectric machines etc..

In the present invention, so-called " phase converter " is the direction vector and the angled dress of its voltage for instigating electric current It sets, the circuit for example including capacitor, the circuit including inductance and also include circuit of inductance etc. including capacitor.

In the present invention, the principle of electrochemical method disclosed in this invention is carried out as described below:

Through detailed analysis, it can be found that there is the basic logic of universality using the process of redox reaction power generation, specifically Be analyzed as follows: the process to be generated electricity using redox reaction, is exported from reducing agent by electronics, forms reducing agent cation, then By electronics derived from institute imported into reducing agent cation and oxidant coexistence make three react generate the reducing agent and The product of the oxidizing reduction reaction externally exports electric energy on the path that electronics export and electronics import.In tradition In hydrogen-oxygen fuel cell, such as PEMFC, under the effect of the catalyst, hydrogen molecule is separated into proton and electronics, and proton is made to pass through matter Proton exchange enters the oxygen side with catalyst, and electronics is loaded from hydrogen side and imported into proton and what oxygen coexisted has catalyst Oxygen side, proton (H⁺), oxygen (O₂) and electronics (e^-) reaction generation water.This means that the process to be generated electricity using redox reaction With following basic logic: electronics is made into reducing agent positively ionized from reducing agent export, then by electronics imported into reducing agent just from The coexistence of son and oxidant makes reducing agent cation, oxidant and electronics three react the generation reducing agent and the oxidation The product of agent redox reaction, this overall process is external output electric energy, and the output of electric energy is leading by electronics Realization is imported out.This basic logic is it is meant that we can not be by the constraint of conventional fuel cell concrete form, as long as full The requirement of this basic logic of foot, so that it may externally export electric energy using the redox reaction of Oxidizing and Reducing Agents.And this The basic process of the disclosed method including electrochemistry region and region B of invention is exactly to export in electrochemistry region from reducing agent Reducing agent cation is electronically formed, electronics is made to export to region B, then electronics is made to imported into the electrochemical school district from the region B Domain, and electronics, oxidant and the reducing agent cation three coexists, to make electronics and Oxidizing and Reducing Agents cation Three, which reacts, generates the product of the oxidant and the reducing agent redox reaction, and then real there are no by institute Under the premise of stating necessity derived from reducing agent cation, also it is being not present necessity derived from other non-electronic charged particles Under the premise of, externally export electric energy.And the root of the method disclosed in this invention including electrochemistry region A and electrochemistry region B This process is exactly so that reducing agent is formed reducing agent cation from electrochemistry region A export electronics, and Xiang Suoshu electrochemistry region B is imported Electronics, then electronics is made to imported into the electrochemistry region A from the electrochemistry region B, in the electrochemistry region A electronics, oxygen Agent and the reducing agent cation three coexist, in the electrochemistry region B electronics, oxidant and the reducing agent cation Three coexists, so that so that electronics and Oxidizing and Reducing Agents cation three is reacted generates the oxidant and the reduction The product of agent redox reaction, so it is real there are no under the premise of by necessity derived from the reducing agent cation, Also under the premise of there is no by necessity derived from other non-electronic charged particles, electric energy is externally exported.

Disclosed in this invention include reducing agent, oxidant alternating action method principle it is as follows: make electrochemical school district Domain alternately contacts or makes reducing agent and oxidant alternately to contact with electrochemistry region with reducing agent and oxidant, makes reducing agent in institute It states electrochemistry region and generates positive charged particle and electronics, so that electronics is exported to region B from the electrochemistry region, make electronics from institute It states region B to import to the electrochemistry region, positive charged particle, the oxidant and electron back described in the electrochemistry region The product that the reducing agent and the oxidant react should be generated, using the electrochemistry region and the region B it Between the export of electronics import and realize output electric energy and/or absorb electric energy, so recycle, realization continues working process (from institute State region B to the electrochemistry region import electronics when, in some cases, electronics is anti-in the electrochemistry region and oxidant Negative charged particles C should be generated, the negative charged particles C and the positive charged particle reaction generate the reducing agent and the oxidation The product that agent reacts is imported using the export of the electronics between the electrochemistry region and the region B and realizes output Electric energy and/or absorption electric energy, so recycle, realization continues working process).It is alternative in realizing this electrochemical process Ground selection makes the electrochemistry region, external circuit, capacitor and the region B constitute circuit, and/or make the electrochemistry region, External circuit, non-electronic charged particle oscillation area and the region B constitute circuit.It in this approach, can be to the electrochemistry Electro ultrafiltration is implemented in region, and electro ultrafiltration can control export and/or importing with strengthening electronic, thus it is possible to prevente effectively from reduction Redox reaction directly occurs for agent and oxidant mixing, improves safety, reliability and efficiency.In this approach, may be used First to implement electro ultrafiltration to it before the electrochemistry region and material effect, purpose is also to avoid reducing agent and oxidant Redox reaction directly occurs for mixing, improves safety, reliability and efficiency.

Disclosed in this invention include reducing agent and oxidant mixture effect method principle it is as follows: make electrification School district domain contacts with the mixture of reducing agent and oxidant or makes the mixture of reducing agent and oxidant to contact with electrochemistry region, So that electronics is exported to region B from the electrochemistry region using electro ultrafiltration, and then the reducing agent is made to form positive charged particle, from The region B imports electronics, the positive charged particle and the oxidant to the electrochemistry region and electron reaction generates institute The reaction product of reducing agent and the oxidant is stated, next step imports electricity from the region B to the electrochemistry region Son makes electronics export to the region B from the electrochemistry region, the electricity between the electrochemistry region and the region B Under the action of son imports and exports, the reducing agent and the oxidant reaction generate reacting for the reducing agent and the oxidant Product, between the electrochemistry region and the region B electronics export and/or import channel on absorb electric energy and/ Or output electric energy, it so recycles, realization continues working process (in some cases, from the region B to the electrochemical school district When domain imports electronics, the oxidant and electron reaction generate negative charged particles C, the positive band electrochondria described in the electrochemistry region The sub and described negative charged particles C reaction generates the reaction product of the reducing agent and the oxidant, in the electrochemical school district Electric energy and/or output electric energy are absorbed on the channel of electronics export and/or importing between domain and the region B, are so recycled, in fact Now continue working process).In realizing this electrochemical process, be selectively chosen make the electrochemistry region, external circuit, Capacitor and the region B constitute circuit, and/or make the electrochemistry region, external circuit, non-electronic charged particle oscillation Qu Hesuo It states region B and constitutes circuit.In this approach, oxygen directly occurs to be effectively prevented from the reducing agent and oxidant mixing Change reduction reaction, electro ultrafiltration first can be implemented to it before the electrochemistry region and material effect.

Disclosed in this invention include reducing agent and oxidant the principle of method that discontinuously acts on of mixture it is as follows: remove Outside the influence discontinuously acted on, the principle of this method and the principle of the method for the mixture effect for including reducing agent and oxidant are complete It is identical, and interrupted function is that can be better protected from or eliminate reducing agent described in mixture and the oxidant in electricity Pole participates in directly carrying out the ability that redox reaction loses output electric energy in the case where (the i.e. described electrochemistry region participates in), And then the efficiency of the method disclosed in the present is improved, under the influence of mixture discontinuously acts on, a certain electrode may be implemented only There are reducing agents (except non-electronic charged particle) to function, and another electrode only exists oxidant (non-electronic charged particle Except) state that functions, or realize that a certain electrode only exists the high concentration object of reducing agent (except non-electronic charged particle) It functions, and another electrode only exists the state that the high concentration object (except non-electronic charged particle) of oxidant functions, Any state either among these is all conducive to the efficiency for promoting electrochemical reaction.Certainly as described above, optionally Selection imports step using the export of external means (such as foreign current, external electrical field etc.) control electronics, and it is anti-to promote electrochemistry The efficiency answered.Similarly, it in realizing this electrochemical process, is selectively chosen, the electrochemistry region, external circuit, electricity Hold and the region B constitutes circuit and/or the electrochemistry region, external circuit, non-electronic charged particle oscillation area and the area Domain B constitutes circuit.

Disclosed in this invention include reducing agent, oxidant alternating action method principle it is as follows: make electrochemical school district Domain A alternately contacts or makes reducing agent and oxidant alternately to contact with electrochemistry region A with reducing agent and oxidant, makes electrochemistry Region B is alternately contacted with Oxidizing and Reducing Agents or is contacted Oxidizing and Reducing Agents alternately with electrochemistry region B, makes to restore Agent generates positive charged particle and electronics in the electrochemistry region A, and electronics is made to export to the electrification from the electrochemistry region A School district domain B, the oxidant described in the electrochemistry region B coexist with electronics, produce the reducing agent in the electrochemistry region B The raw positive charged particle and electronics, make electronics imported into the electrochemistry region A from the electrochemistry region B, in the electricity Positive charged particle, the oxidant and electron reaction described in chemical regions A generate the reducing agent and the oxidant reaction Product, positive charged particle, the oxidant described in the electrochemistry region B and electron reaction generate the reducing agent and institute The product for stating oxidant reaction is imported using the export of the electronics between the electrochemistry region A and the electrochemistry region B It realizes output electric energy and/or absorbs electric energy, so recycle, realization continues working process (from the electrochemistry region A to described When electrochemistry region B imports electronics, in some cases, electronics generates negative band in the electrochemistry region B and oxidant reaction Charged particle C, the negative charged particles C the electrochemistry region B and the positive charged particle reaction generate the reducing agent and The product that the oxidant reacts utilizes leading for the electronics between the electrochemistry region A and the electrochemistry region B It imports out and realizes output electric energy and/or absorb electric energy, so recycle, realization continues working process).Realizing this electrochemistry mistake Cheng Zhong is selectively chosen, the electrochemistry region A, external circuit, capacitor and electrochemistry region B composition circuit, and/ Or the electrochemistry region A, external circuit, non-electronic charged particle oscillation area and the electrochemistry region B constitute circuit.At this In kind of method, electro ultrafiltration can be implemented to the electrochemistry region A and electrochemistry region B, electro ultrafiltration can control and by force Change the export and/or importing of electronics, thus it is possible to prevente effectively from reducing agent and oxidant mixing directly generation redox are anti- It answers, improves safety, reliability and efficiency.It in this approach, can also be in the electrochemistry region A and the electrochemical school district First implement electro ultrafiltration to it before domain B and material effect, purpose is also to avoid reducing agent and oxidant from mixing oxygen directly occurs Change reduction reaction, improves safety, reliability and efficiency.

Disclosed in this invention include reducing agent and oxidant mixture effect method principle it is as follows: make electrification School district domain A contacts with the mixture of reducing agent and oxidant or makes the mixture of reducing agent and oxidant to connect with electrochemistry region A Touching makes electrochemistry region B that the mixture of reducing agent and oxidant and electrification are contacted or made with the mixture of reducing agent and oxidant School district domain B contact, makes electronics export to the electrochemistry region B from the electrochemistry region A using electro ultrafiltration, and then makes described Reducing agent forms positive charged particle in the electrochemistry region A, imports from the electrochemistry region B to the electrochemistry region A Electronics, the reducing agent generate the positive charged particle, the positive band described in the electrochemistry region A in the electrochemistry region B Charged particle, the oxidant and electron reaction generate the reducing agent and the oxidant reaction product, in the electrochemistry Positive charged particle, the oxidant described in the B of region and electron reaction generate the reducing agent and the oxidant reaction product, Between the electrochemistry region A and the electrochemistry region B electronics export and/or import channel on absorb electric energy and/ Or output electric energy, it so recycles, realization continues working process (in some cases, from the electrochemistry region A to the electricity The oxidant and electron reaction generate negative charged particles C when chemical regions B imports electronics, from the electrochemistry region B to institute It states oxidant described in the A of electrochemistry region and electron reaction and generates negative charged particles C, just charging described in the electrochemistry region A Particle and negative charged particles C reaction generate the reaction product of the reducing agent and the oxidant, in the electrochemistry Positive charged particle described in the B of region and negative charged particles C reaction generate the reducing agent and the reaction of the oxidant generates Object, between the electrochemistry region A and the electrochemistry region B electronics export and/or import channel on absorb electric energy And/or output electric energy, so recycle, realization continues working process).In realizing this electrochemical process, optionally select Selecting makes the electrochemistry region A, external circuit, capacitor and the electrochemistry region B constitute circuit, and/or makes the electrochemical school district Domain A, external circuit, non-electronic charged particle oscillation area and the electrochemistry region B constitute circuit.It in this approach, is effective Ground avoids the reducing agent and the oxidant from mixing redox reaction directly occurs, can in the electrochemistry region A and The electrochemistry region B first implements electro ultrafiltration to it with before material effect.

Disclosed in this invention include reducing agent and oxidant the principle of method that discontinuously acts on of mixture it is as follows: remove Outside the influence discontinuously acted on, the principle of this method and the principle of the method for the mixture effect for including reducing agent and oxidant are complete It is identical, and interrupted function is that can be better protected from or eliminate reducing agent described in mixture and the oxidant in electricity It is anti-that redox is directly carried out in the case where pole participation (the i.e. described electrochemistry region A and/or the electrochemistry region B are participated in) The ability of output electric energy should be lost, and then improves the efficiency of the method disclosed in the present, in the influence that mixture discontinuously acts on Under, it a certain electrode may be implemented only exists reducing agent (except non-electronic charged particle) to function, and another electrode only exists The state that oxidant (except non-electronic charged particle) functions, or realize that a certain electrode only exists the high concentration object of reducing agent (except non-electronic charged particle) functions, and another electrode only exists high concentration object (the non-electronic charged particle of oxidant Except) state that functions, any state either among these is all conducive to the efficiency for promoting electrochemical reaction.When So as described above, being selectively chosen the export using external means (such as foreign current, external electrical field etc.) control electronics Step is imported, the efficiency of electrochemical reaction is promoted.Similarly, in realizing this electrochemical process, being selectively chosen makes institute State electrochemistry region A, external circuit, capacitor and the electrochemistry region B constitute circuit, and/or make the electrochemistry region A, outer Circuit, non-electronic charged particle oscillation area and the electrochemistry region B constitute circuit.

In the present invention, the partial circuit working principle of the electrical return of disclosed method is to utilize non-electronic band electrochondria Sub reciprocating vibration in the electrolyte, which is realized alternation conducting and/or stood facing each other using non-electronic charged particle with electronics, realizes that alternation is led It is logical, and then interior circuit and external circuit is made to form closed circuit, realize electrochemical process.

In the present invention, it is work normality that the export of the electronics in the electrochemistry region, which imports,.

In the present invention, so-called " it is work normality that the export of the electronics in the electrochemistry region, which imports, " refers to from the electricity It is to continue working process that chemical regions, which export electronics and import electronics to the electrochemistry region, i.e., using disclosed in this invention The electrochemical appliance of electrochemical method exports electronics in working condition, from the electrochemistry region and to the electrochemistry region Importing electronics is a kind of lasting process.In other words, the electrochemistry region electrochemistry corresponding and described with alternating current Region is opposite with alternating current to should be the process of continuing working.

In the present invention, it is work normality that export of the electronics between the electrochemistry region and the region B, which imports,.

In the present invention, so-called " it is that work is normal that export of the electronics between the electrochemistry region and the region B, which imports, State " refers to export of the electronics from the electrochemistry region to the region B and electronics from the region B to the electrochemistry region It imports to continue working process, i.e., electrochemical appliance disclosed in this invention is led in working condition from the electrochemistry region It is one that electronics, the region Xiang Suoshu B, which import electronics, electronics exported from the region B and imports electronics to the electrochemistry region, out The lasting process of kind.In other words, the electrochemistry region and region B is corresponding with alternating current and the electrochemical school district The domain and region B is opposite with alternating current should be the process of continuing working.

In the present invention, it is that work is normal that export of the electronics between the electrochemistry region A and the electrochemistry region B, which imports, State.

In the present invention, so-called electrochemistry region, so-called electrochemistry region A, so-called region B, so-called electrochemistry Region B is equal with electrode.

In the present invention, the region that electronics export imports is equal with electrode.

In the present invention, it is selectively chosen, the electrochemistry region and the region B have dielectric capacitance relationship, Dielectric can be gas, liquid, solid or vacuum.

It in the present invention, is selectively chosen, the electrochemistry region A and the electrochemistry region B have dielectric capacitance Relationship, dielectric can be gas, liquid, solid or vacuum.

In the present invention, it is selectively chosen between electrode with dielectric capacitance relationship.

In the present invention, so-called " dielectric capacitance relationship " refers to the capacitance relation by dielectric formation, and dielectric can be with It is gas, liquid, solid or vacuum.

In the present invention, so-called " export of the electronics between the electrochemistry region A and the electrochemistry region B is imported For the normality that works " refer to electronics from the electrochemistry region A to the electrochemistry region B and electronics from the electrochemistry region B It is imported to the export of the electrochemistry region A to continue working process, i.e., electrochemical appliance disclosed in this invention is in work shape When state, electronics is imported from electrochemistry region A export electronics, Xiang Suoshu electrochemistry region B, is led from the electrochemistry region B Out electronics and to the electrochemistry region A import electronics be a kind of lasting process.In other words, the electrochemistry region A and The electrochemistry region the B corresponding and described electrochemistry region A and electrochemistry region B and alternating current phase with alternating current It corresponds to continue working process.

In the present invention, when the reducing agent and the oxidant are certain two kinds of predetermined substance, electrochemical reaction is being realized In the process, having the reaction of the third substance participation cyclicity, (so-called cyclicity reaction, which refers to, generates certain at an electrode Substance, and the reaction that this substance is consumed at another electrode), such as the reducing agent is methanol, the oxidant is When oxygen, in acid condition, water is had as the third substance and participates in cyclicity reaction, is i.e. water produces at the electrode for absorbing electronics It is raw, and be consumed at the electrode of output electronics, and under alkaline condition, hydroxyl, which is had, as the third substance participates in recycling Property reaction, hydroxyl absorb electronics electrode at generate, output electronics electrode at be consumed.For example, methanol fuel is electric The electrochemical reaction process concrete condition in pond is as follows:

Overall reaction under alkaline condition: 2CH₃OH+3O₂+4OH^-=2CO₃ ^2-+6H₂O

Anode reaction: O₂+4e^-+2H₂O=4OH^-

Negative reaction: CH₃OH-6e^-+8OH^-=CO₃ ^2-+6H₂O

Overall reaction in acid condition: 2CH₃OH+3O₂=2CO₂+4H₂O

Anode reaction: O₂+4e^-+4H⁺=2H₂O

Negative reaction: CH₃OH-6e^-+H₂O=6H⁺+CO₂

For another example the electrochemical reaction process concrete condition of methane fuel cell is as follows:

Overall reaction under alkaline condition: CH₄+2O₂+2OH^-=CO₃ ^2-+3H₂O

Anode reaction: 2O₂+8e^-+4H₂O=8OH^-

Negative reaction: CH₄-8e^-+10OH^-=CO₃ ^2-+7H₂O

Overall reaction in acid condition: CH₄+2O₂=CO₂+2H₂O

Anode reaction: 2O₂+8e^-+8H⁺=4H₂O

Negative reaction: CH₄-8e^-+2H₂O=8H⁺+CO₂

In the present invention, according to the method disclosed in the present, the work of substance and electrode (such as electrochemistry region, region B) With prior to electricity and the effect of electrode, this form may be implemented the due electrochemical process of the present invention completely, but reducing agent It will appear in many cases with oxidant and exist simultaneously at same electrode (especially with the mixing of reducing agent and oxidant When object), if this state is precisely that startup stage or electrode did not had in the period of electro ultrafiltration, at this moment reducing agent and oxidant The conversion process between redox reaction forfeiture and electric energy can occur, directly in order to avoid this state generates it is necessary to preparatory Electro ultrafiltration is implemented to electrode, and it is so-called " to the region application electro ultrafiltration for participating in electrochemical reaction, so as to participate in electrochemical reaction Substance be difficult to directly carry out redox reaction " purpose be that this.

In the present invention, under certain temperature and/or pressure, so-called electrochemistry region, which is selectively chosen, to be set as not wrapping The conductive region of catalyst is included, because it is anti-can still to carry out electrochemistry without using catalyst under certain temperature and/or pressure It answers.

It in the present invention, is selectively chosen and electro ultrafiltration is applied to the electrochemistry region, to realize to the electrochemistry Reducing agent and oxygen is reduced or avoided prior to the interaction between substance and the electrochemistry region in the electro ultrafiltration in region Agent directly carries out the case where redox reaction loses output electric energy.

In the present invention, there is non-electronic electric conduction through electronic conduction area and the region B including the electrochemistry region In the method for relationship, be selectively chosen make one in the electrochemistry region and the region B through capacitor or through non- Electronic conduction area (such as the electrolyte such as proton exchange membrane) is again through external circuit and another electric communication, it is possible to realize normality Work.

It is non-electronic having including the electrochemistry region A through electronic conduction area and the electrochemistry region B in the present invention In the method that electrical relation is connected, it is selectively chosen one made in the electrochemistry region A and the electrochemistry region B Through capacitor or through non-electronic conducting area (such as the electrolyte such as proton exchange membrane) again through external circuit and another electric communication, so Normality work may be implemented.

In the present invention, so that charged particle is stored in the means in electrochemistry region as realizing, be selectively chosen and pass through The alternating of the contact of two kinds of metabolies and electric current that make electrochemistry region and participation electrochemical reaction changes to realize, also optional Select to selecting property to make that two kinds of substances for participating in electrochemical reaction alternately contacts with electrochemistry region and the alternating of electric current changes Realize, however two electrodes of electrochemical reaction (for example, the electrochemistry region and the region B, the electrochemistry region A and The electrochemistry region B) between the conducting of non-electronic charged particle may or may not then exist.

In the present invention, charged particle is set to be stored in the means in electrochemistry region as realizing, being selectively chosen makes electricity The mixture contact of two kinds of substances of chemical regions and participation electrochemical reaction and the alternating of electric current change to realize, may be selected Property select to make electrochemistry region and participate in the mixture makes discontinuous contact of two kinds of substances of electrochemical reaction and the alternating of electric current Variation is to realize, however two electrodes of electrochemical reaction are (for example, the electrochemistry region and the region B, the electrification school district The domain A and electrochemistry region B) between the conducting of non-electronic charged particle may or may not then exist.

In the present invention, it is that the Q generated at P is instigated to be stored in institute that the so-called Q for making the generation at P, which is stored at the P, The electrode zone represented at P is stated, including the Q to be unnecessarily transmitted to the electrode zone polarity with representative at the P The process of opposite electrode zone.

In the present invention, in realizing the chemical energy electric energy conversion method, need for certain charged particle to be stored in a certain It is waited in region and participates in reaction in the next step, it is to instigate to produce at P that the so-called Q for making the generation at P, which is stored at the P, Raw Q is stored in the electrode zone represented at the P, including being unnecessarily transmitted to the Q and representative at the P The process of the opposite polarity electrode zone of electrode zone.

In the present invention, the reducing agent used in the chemical energy electric energy conversion method and oxidant with the reducing agent and In the presence of the form of the mixture of the oxidant, further can selectively it select with the reducing agent and the oxygen The form of the molar mixture of agent exists, or with the mixture of the explosion limit reducing agent and the oxidant below Form exist, or by the form of the mixture of the local explosion limit reducing agent below and the oxidant exist, or In the form of the mixture of more than the explosion limit reducing agent and the oxidant exist, or with local explosion limit more than The reducing agent and the oxidant mixture form exist.

In the present invention, the mixture of so-called reducing agent and oxidant further can selectively select to be set as reducing agent and Molar mixture, the explosion limit reducing agent below and the mixture of oxidant, local explosion limit of oxidant are below It is more than the mixture of more than mixture of reducing agent and oxidant, explosion limit reducing agent and oxidant or local explosion limit Reducing agent and oxidant mixture.

In the present invention, so-called molar mixture refers to that the molar concentration rate of mixture is positive and negative in chemical reaction molar ratio Mixture within 10%.

In the present invention, the electrochemistry region, the electrochemistry region A and the electrochemistry region B electronics export Import refer to do not include electronics during being electrically separated appearance and accumulation.

In the present invention, the export of the electronics in the electrochemistry region is imported to continue working process.

In the present invention, the export of the electronics of the electrochemistry region A is imported to continue working process.

In the present invention, the export of the electronics of the electrochemistry region B is imported to continue working process.

In the present invention, electrochemistry region state corresponding with alternating electromotive force and alternating current is to continue working Journey.

In the present invention, electrochemistry region A state corresponding with alternating electromotive force and alternating current is to continue working Process.

In the present invention, electrochemistry region B state corresponding with alternating electromotive force and alternating current is to continue working Process.

The chemical energy electric energy conversion method disclosed in this invention is corresponding with alternating electromotive force and alternating current, i.e., electric Chemical regions are corresponding with alternating electromotive force and alternating current.

In the present invention, relationship is connected for the electricity that non-electronic charged particle is formed, is selectively chosen through non-electronic Relationship is connected in the direct electricity that charged particle is formed, and relationship, warp is connected in the electricity formed through non-electronic charged particle reciprocating vibration One of electricity conducting relationship that capacitance relation is formed, secondly conjunction or thirdly conjunction.

In the present invention, relationship is connected for the electricity that non-electronic charged particle is formed, is selectively chosen including through exhausted The electrical relation that alternating current can be made to be connected of edge body, dielectric and the conducting body isolation of non-electronic charged particle.

In the present invention, in two electrodes (for example, the electrochemistry region and the region B, the electrochemistry region A and institute State electrochemistry region B) between there are in the method for electrolyte, non-electronic charged particle can both pass through electrolyte, from an electrode to Up to another electrode, the effect that alternating current is connected can also be realized by reciprocating vibration in the electrolyte.

In the present invention, electrochemistry region corresponding with alternating electromotive force and alternating current is essence feature of the invention, In the present invention, two kinds of substances due to participating in electrochemical reaction exist with electrochemistry region to be contacted, and electrochemistry region and friendship Power transformation kinetic potential and alternating current are corresponding, i.e., the electromotive force in electrochemistry region in the present invention is alternating electromotive force, absorb and/or The electric current for exporting electric energy is alternating current, and this is through the lasting sex work normality of whole work process, this duration Work normality eliminates the necessity of non-electronic charged particle transmission between two electrodes, thus no matter make between two electrodes in electronics every Exhausted state, non-electronic charged particle state of isolation have the state for the electrolyte that non-electronic charged particle is connected between two electrodes, also It is that can be worked normally in other states as long as can be realized the Oscillating flow of electronics.There are electrolyte between two electrodes In method, non-electronic charged particle can both pass through electrolyte, reach another electrode from an electrode, can also be past in the electrolyte Complex oscillation realizes the effect of alternating current conducting.This provides fine for the manufacture and use of electrochemical appliance especially fuel cell New method.

In the present invention, the alternation of electric current and substance replace and the effect of the alternation and mixture of substances of electric current is formed by Alternation process is a kind of lasting course of work, is a kind of work normality, and its purpose is to eliminate non-electronic band Charged particle two interelectrode transmitting necessity, to promote the science that chemical energy exchanges the electrochemical method of electric energy for, in turn Promote service life, reliability, low cost and the efficiency of electrochemical appliance corresponding with the method disclosed in the present.This electricity The purpose of principle and purpose of chemical method and conventional fuel cell are catalyst regeneration is temporary to exchange Oxidizing and Reducing Agents Feed channel, which forms the principle of temporary electrode change in polarity and purpose, has essential distinction, also and to prevent, weaken and remove The principle and purpose of the frequently pole-reversing electroosmosis of electrode attachment have essential distinction.

In the present invention, from a certain region export electronic processes duration with to this region import electronic processes duration it Than between 1/6 and 6, between 1/5 and 5, between 1/4 and 4, between 1/3 and 3, between 1/2.5 and 2.5,1/2 And between 2, between 1/1.5 and 1.5, between 1/1.3 and 1.3, between 1/1.2 and 1.2 or 1/1.1 and 1.1 it Between, or it is equal with the duration of electronic processes is imported to this region from the duration of a certain region export electronic processes.

In the present invention, during the export of electronics imports, electro ultrafiltration can be used；Or, the export in electronics imports During, it is selectively chosen using capacitor, DC power supply, AC power source, alternating source, inductor conductor, inductor wire Circle, motor, reversible electric machine, has charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, oscillating circuit The motor of additional rotation inertia or its two conjunction, its three conjunction, its four conjunction, its five conjunction, its six conjunction, its Seven conjunctions, its eight conjunction, its nine conjunction, its ten conjunction, its 11 conjunction, the conjunction of its ten binomial, its 13 Conjunction, its 14 conjunction, its 15 conjunction.

In the present invention, during exporting electric energy and/or absorbing electric energy, selectively selection uses electro ultrafiltration；Or, During exporting electric energy and/or absorbing electric energy, selectively selection uses capacitor, DC power supply, AC power source, alternation electricity Source, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, oscillating circuit, Motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four conjunction, its five Conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 conjunction, its ten The conjunction of binomial, its 13 conjunction, its 14 conjunction, its 15 conjunction.

In the present invention, the purpose of so-called " during exporting electric energy and/or absorbing electric energy, using electro ultrafiltration " is benefit The process of output electric energy is controlled or strengthened with electro ultrafiltration and/or absorbs the process of electric energy, in this way can with the efficiency of lifting process and Safety, such as an electrochemical process may take a long time to complete, but if can be made using electro ultrafiltration The reaction rate of the slower procedure segment of electrochemical reaction rates is promoted, and then is improved efficiency.

In the present invention, so-called electro ultrafiltration, which refers to, brings it about displacement and/or stream to electronics application using electric field, electric current etc. Dynamic effect.

In the present invention, it is more big more be conducive to electrochemistry that capacitance is formed by between the electrochemistry region and the region B The promotion of reaction density, therefore when being electrochemically reacted using the method disclosed in the present, the electrochemical school district should be made Capacitance between domain and the region B increases as much as possible.

It, can be in the electrochemical school district in order to increase the capacitance between the electrochemistry region and the region B in the present invention It is arranged in plasma, ionic liquid, ionized gas, solion and electronic conduction area at least between domain and the region B One kind, and vibrate ion between the electrochemistry region and the region B, and/or shake in the electrochemistry areas adjacent It swings and is oscillated around in the region B, to realize the purpose for increasing the capacitance between the electrochemistry region and the region B.

In the present invention, it is more big more be conducive to electricity that the electrochemistry region A and the electrochemistry region B are formed by capacitance The promotion of density is chemically reacted, therefore when being electrochemically reacted using the method disclosed in the present, the electrification should be made Capacitance between school district domain A and the electrochemistry region B increases as much as possible.

It, can be described in order to increase the capacitance between the electrochemistry region A and the electrochemistry region B in the present invention Plasma, ionic liquid, ionized gas, solion and electronics are set between electrochemistry region A and the electrochemistry region B At least one of area is connected, and vibrates ion between the electrochemistry region A and the electrochemistry region B, and/or It oscillates around in the electrochemistry region A and is oscillated around in the electrochemistry region B, increase the electrochemistry region to realize The purpose of capacitance between A and the electrochemistry region B.

In the present invention, between the electrochemistry region and the region B and in the electrochemistry region A and the electrification It is more big more be conducive to the promotion of electrochemical reaction density that capacitance is formed by between the B of school district domain, therefore public using present invention institute When the method opened is electrochemically reacted, should make between the electrochemistry region and the region B and the electrochemistry region A and Capacitance between the electrochemistry region B increases as much as possible.

In the present invention, to realize that specific charged particle is stored in electrochemistry region, need to join the electrochemistry region Alternate change physical environment or make the electrochemistry region between the different material of electrochemical reaction and participate in electrochemical reaction The mixture of different material contacts, and is just able to achieve.Fundamentally, as long as the electrochemistry region is made to participate in electrochemical reaction Different material between alternate change physical environment or make the electrochemistry region and participate in the mixed of the different material of electrochemical reaction Object contact is closed, can be achieved with the purpose that the specific charged particle is stored in electrochemistry region, no matter the electrochemistry region has There are two types of the conductive channel of charged particle, (such as one of is proton conductive channel, i.e. there is conducting certain band between two electrodes The electrolyte of charged particle, another kind be electronic conduction channel) or the electrochemistry region there was only electronic conduction channel, change sentence It talks about, as long as making the electrochemistry region alternate change physical environment or described between the different material for participating in electrochemical reaction Electrochemistry region is contacted with the mixture for the different material for participating in electrochemical reaction, can be achieved with the specific charged particle storage It participates in electrochemistry region and in the next step reacting the purpose for realizing electrochemical reaction, no matter two electrodes are (for example, the electricity Chemical regions and the region B, the electrochemistry region A and the electrochemistry region B) between whether there is electrolyte.Electrochemistry The course of work for the method that region export imports charged particle is similar with this.

In the present invention, in electrochemistry region, tool there are two types of the conductive channel of charged particle, (such as lead for proton by one of which , i.e. there is the electrolyte that specific charged particle is connected between two electrodes in circulation passage, another kind is electronic conduction channel) electrochemistry side In method, alternate change physical environment or made described between the different material for participating in electrochemical reaction by making the electrochemistry region Electrochemistry region is contacted with the mixture for the different material for participating in electrochemical reaction, can be achieved to eliminate from the electrochemistry region The necessity for removing the non-electronic charged particle generated in the electrochemistry region, can also realize that non-electronic charged particle is stored in The electrochemistry region and the purpose for participating in reaction realization electrochemical reaction in the next step.The alternate change of physical environment or The electrochemistry region and the mixture for the different material for participating in electrochemical reaction are contacted, can make to be stored in the electrochemical school district Non-electronic charged particle in domain participates in reacting in the next step, realizes electrochemical process, therefore from the electrochemical school district The necessity that non-electronic charged particle is exported in domain completely disappears.The case where necessity derived from non-electronic charged particle disappears Under, although some non-electronic charged particle that ought to be stored in the electrochemistry region is exported, also have non-electronic Charged particle is stored in the electrochemistry region and waits next reaction step, in other words, if the electrochemistry region The alternate change physical environment between the different material for participating in electrochemical reaction, or it is mixed with the different material of participation electrochemical reaction Object contact is closed, although in two electrodes (for example, the electrochemistry region and the region B, the electrochemistry region A and the electricity Chemical regions B) between there are electrolyte, also have non-electronic charged particle be stored in described electrochemistry region etc. stay in it is next Reaction is participated in step realizes electrochemical reaction process.

Chemical energy electric energy conversion method disclosed in this invention, there are can reduce in the case where electrolyte between two electrodes Electrolyte load extends its service life and is conducive to the balance and stability operation of system.

In the present invention, in the method that electrochemistry region only has electronic conduction channel (the i.e. described electrochemistry region with it is described Between the B of region, interior circuit or external circuit between the electrochemistry region A and the electrochemistry region B are in electronics and non-electronic Charged particle state of isolation), electrochemistry region alternate change physical environment between the different material for participating in electrochemical reaction It is contacted with the electrochemistry region with the mixture for the different material for participating in electrochemical reaction, non-electronic charged particle can be made to deposit Storage is in the electrochemistry region, the change of physical environment or the different material for making the electrochemistry region and participation electrochemical reaction Mixture contact can make the non-electronic charged particle for being stored in the electrochemistry region participates in the next step reaction reality Existing electrochemical process, that is, eliminate the necessity that non-electronic charged particle is removed from electrochemistry region.Express herein, in traditional electricity In chemical method, electrochemistry region (i.e. electrode) includes at least two kinds of charged particles and is connected, such as an electronic conduction channel, and one A proton conductive channel.

Chemical energy electric energy conversion method disclosed in this invention include exchanged for electric energy chemical energy electrochemical method (such as Electrochemical method for synthesizing etc.) and exchange with chemical energy the electrochemical method (such as fuel cell etc.) of electric energy for, it is closed as electrochemistry At method in use, the different step that the export of electronics imports, which may exist, exports the case where electric energy is with electric energy is absorbed, but its Summation is to absorb electric energy, as the method (such as fuel cell etc.) for exchanging electric energy for chemical energy in use, the export of electronics The case where different step of importing may exist output electric energy and absorb electric energy, but its summation is output electric energy.

Chemical energy electric energy conversion method disclosed in this invention self-evidently includes the participation of substance.

Chemical energy electric energy conversion method disclosed in this invention is as exchanging the method for electric energy for chemical energy in use, described Oxidant alternative selection be set as: oxygen, compressed air, oxygen, liquid oxygen, air, liquefied air, fluorine, chlorine, bromine, iodine, ozone, Nitric acid, the concentrated sulfuric acid, hypochlorous acid, chromic acid, Peracetic acid, perchloric acid, chlorate, nitrate, permanganate, perchlorate, weight chromium Hydrochlorate, Calcium perchlorate, ammonium perchlorate, sodium perchlorate, potassium hyperchlorate, lithium perchlorate, magnesium perchlorate, barium perchlorate, perchloric acid strontium, Silver perchlorate, ammonium chlorate, sodium chlorate, potassium chlorate, magron, calcium chlorate, copper chlorate, zinc chlorate, chloric acid thallium, silver chlorate, Gao Meng Sour potassium, acerdol, barium permanganate, lithium nitrate, sodium nitrate, potassium nitrate, calcium nitrate, cesium nitrate, beryllium nitrate, potassium bromate, bromic acid Zinc, ammonium periodate, calcium iodate, iron iodate, sodium dichromate, potassium bichromate, iron chloride, ammonium ceric nitrate, sodium hypochlorite, percarbonic acid Sodium, sodium perborate, calcium hypochlorite, sodium dichloro cyanurate, copper oxide, di-iron trioxide, sodium peroxide, manganese dioxide, dioxy Change nitrogen, potassium peroxide, magnesium dioxide, calcium dioxide, hydrogen peroxide, chromium trioxide, strontium dioxide, sodium dioxide, silver oxide, third Ketone, acrylonitrile, benzaldehyde, dibenzoyl peroxide, benzoquinones, carbon tetrabromide one or more of are set as chloramines etc.； The reducing agent alternative selection is set as: hydrogen, alkane, alkene, alkynes, aromatic hydrocarbon, halogenated hydrocarbons, alcohol compound, phenol generalization Close object, aldehyde compound, ketone compounds, hydroxyl acid compounds, ester type compound, sodium, aluminium, zinc, lithium, potassium, magnesium, manganese, carbon, Calcium, barium, vanadium, chromium, iron, cobalt, copper, boron, silicon, phosphorus, tin, mercury, lead, carbon dust, coal dust end, sulphur, lithium aluminium hydride reduction, diethyl aluminium hydride Sodium, sodium borohydride, potassium borohydride, carbon monoxide, hydrogen sulfide, hydrazine, ammonia, hydrogen chloride, hydrogen iodide, sulfur dioxide, hydrogen peroxide, Vulcanized sodium, stannous chloride, formaldehyde, sulfurous acid, sulfuric acid, oxalic acid, ethyl alcohol, sodium sulfite, sodium hydrogensulfite, ferrous sulfate, methanol, Natural gas, coal gas, methane, coke, diesel oil, dimethyl ether, kerosene, gasoline, hydrogen carbon monoxide mixtures are set as heavy oil etc. It is one or more kinds of.

It more than some numerical value include this number, such as two or more includes two kinds in the present invention.

In the present invention, electrochemical action may be present between the reducing agent and the oxidant.

In the present invention, the item of the reducing agent and the oxidant in chemical energy electric energy conversion method disclosed in this invention Under part, electrochemical reaction can occur.

In the present invention, the reducing agent is simple substance, compound or mixture, and ion or solion are not belonging to the reduction Agent.

In the present invention, the oxidant is simple substance, compound or mixture, and ion or solion are not belonging to the oxidation Agent.

Electrochemical method disclosed in this invention is in the nature chemical energy electric energy conversion method.

It is so-called " during electronics exports and/or imports, to use capacitor, DC power supply, alternating current in the present invention Source, alternating source, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, Oscillating circuit, motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four it Conjunction, its five conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 Conjunction, its ten binomial conjunction, its 13 conjunction, its 14 conjunction, its 15 conjunction " purpose be by electro ultrafiltration control The export of system and/or strengthening electronic imports.

It is so-called " during electronics exports and/or imports, to use capacitor, DC power supply, alternating current in the present invention Source, alternating source, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, Oscillating circuit, motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four it Conjunction, its five conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 Conjunction, its ten binomial conjunction, its 13 conjunction, its 14 conjunction, its 15 conjunction " purpose be by electro ultrafiltration control The export of system and/or strengthening electronic imports, and control and/or the export of strengthening electronic importing can effectively avoid reducing agent and oxidation Redox reaction directly occurs for agent mixing, improves safety, reliability and efficiency, and control and/or strengthening electronic are led Safety, reliability and the effect that can be effectively promoted using reducing agent and oxidant existing method as a mixture are imported out Rate.

Using disclosed in this invention a kind of chemical energy electric energy conversion method as obtain electric energy method when, " in electricity During son export and/or importing, capacitor, DC power supply, AC power source, alternating source, inductor conductor, inductor wire are used Circle, motor, reversible electric machine, has charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, oscillating circuit The motor of additional rotation inertia or its two conjunction, its three conjunction, its four conjunction, its five conjunction, its six conjunction, its Seven conjunctions, its eight conjunction, its nine conjunction, its ten conjunction, its 11 conjunction, the conjunction of its ten binomial, its 13 Conjunction, its 14 conjunction, its 15 conjunction " purpose be by electro ultrafiltration control and/or strengthening electronic export import. A certain step in this control process is power consumption, but whole process is power supply.

Using disclosed in this invention a kind of chemical energy electric energy conversion method as obtain electric energy method and using also When the mixture of former agent and oxidant, " during electronics exports and/or imports, capacitor, DC power supply, alternating current are used Source, alternating source, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, Oscillating circuit, motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four it Conjunction, its five conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 Conjunction, its ten binomial conjunction, its 13 conjunction, its 14 conjunction, its 15 conjunction " purpose be not only by electricity make It is imported with control and/or the export of strengthening electronic, and is that reducing agent and oxidant are prevented by the export importing of strengthening electronic Directly carry out the effective means of redox reaction.A certain step in this control process is power consumption, but whole process is Power supply.

Using disclosed in this invention a kind of chemical energy electric energy conversion method as obtain electric energy method when, " in electricity During son export and/or importing, capacitor, DC power supply, AC power source, alternating source, inductor conductor, inductor wire are used Circle, motor, reversible electric machine, has charged particle pump, phase converter, reversing switch circuit, rectifier, electric field, oscillating circuit The motor of additional rotation inertia or its two conjunction, its three conjunction, its four conjunction, its five conjunction, its six conjunction, its Seven conjunctions, its eight conjunction, its nine conjunction, its ten conjunction, its 11 conjunction, the conjunction of its ten binomial, its 13 Conjunction, its 14 conjunction, its 15 conjunction " purpose be not only by electro ultrafiltration control and/or strengthening electronic export It imports, and is to prevent reducing agent and oxidant from directly carrying out the effective of redox reaction by the export importing of strengthening electronic Means.A certain step in this control process is power consumption, but whole process is power supply.

It in the present invention, further can selectively select that catalyst corresponding with the reducing agent is made to be set as catalyst A, with It is different that the corresponding catalyst of the oxidant is set as catalyst B, the catalyst A and the catalyst B, in this case, Catalyst in the electrochemistry region, which is selectively chosen, is set as the random mixed of the catalyst A and catalyst B Select the catalyst A for being set as contacting near catalytic domain with closing the catalyst choice in object or the electrochemistry region The band electrochondria between the catalyst A and the catalyst B can be increased with the mixture of the catalyst B in order to improve efficiency The mobility of son.

In the present invention, the purpose for being inserted into the inert substance is to evade the reducing agent and the oxidant described Exist while at electrochemistry region, or the reduction reducing agent and the oxidant exist simultaneously at the electrochemistry region Chance.

In the present invention, disclosed chemical energy electric energy conversion method can be used for converting electric energy for chemical energy, it can also be used to Chemical energy is converted electrical energy into, the method that can be used to fuel cell and electrochemistry formated.

In the present invention, electrochemistry region alternative selects one of the electrode for being set as electrochemical reaction or electrode Point, the region B alternative selection is set as the electrode of electrochemical reaction or a part of electrode, and the electrochemistry region A can Selectivity selection is set as the electrode of electrochemical reaction or a part of electrode, and the electrochemistry region B alternative selection is set as The electrode of electrochemical reaction or a part of electrode.

In the present invention, disclosed method can not only make the reducing agent and the oxidant externally discharge electric energy to be formed The reaction product of energy the rank low reducing agent and the oxidant, also can use the reducing agent and the oxidation Agent absorbs the reaction product of electric energy synthesis energy the rank higher reducing agent and the oxidant.

It, can be according to the operating temperature of the property and the electrochemistry region of the reducing agent and the oxidant in the present invention Select different catalyst.

In the present invention, Xiang Suoshu electrochemistry region import concentration proportion in the local explosion limit reducing agent below and The mixture of the oxidant may include fire retardant, such as nitrogen, carbon dioxide etc. are added in the mixture of hydrogen and oxygen.

In the present invention, in the method that the electrochemistry region is under set temperature, the set temperature can be set as high In equal to 100 DEG C.

In the present invention, in the method that the electrochemistry region is under set temperature, the set temperature can be set as low In equal to 90 DEG C.

In the present invention, the reducing agent and the oxidant are to refer to that electrochemical reaction occurs in the electrochemistry region Substance.

In the present invention, it can react after the reducing agent and oxidant absorption electric energy and generate compound, or right It can react after outer feed electric energy and generate compound.

In the present invention, in the method for including AC power source, the reaction of the reducing agent and the oxidant can be suction The reaction for receiving electric energy is also possible to export the reaction of electric energy.

In the present invention, in the method for including alternating source, the reaction of the reducing agent and the oxidant can be suction The reaction for receiving electric energy is also possible to export the reaction of electric energy.

In the present invention, eliminating from the necessity that electrochemistry region removes non-electronic charged particle means only to need to remove electricity Son, rather than electronics charged particle (such as proton) can store in the electrochemistry region that it is generated and the participation electricity during next Chemical reaction, it means that It is not necessary to the interior circuit or outer that centainly there is non-electronic charged particle channel to constitute between two electrodes Circuit, it is only necessary to which electrochemical process can be realized in electronic conduction circuit, in this approach, is selectively chosen electricity in it The conducting on road is that the reciprocating vibration of charged particle in capacitor and/or its internal part by being formed between its internal part is realized , and using external circuit output electric energy and/or absorb electric energy.

In the present invention, eliminating from the necessity that electrochemistry region removes two kinds of charged particles means only to need to remove electricity Son, and another charged particle (such as proton) can store in the electrochemistry region that it is generated and the participation electricity during next Chemical reaction, it means that between two electrodes It is not necessary to certain interior circuit constituted with charged particle channel or, it is only necessary to Electrochemical process can be realized in electronic conduction circuit, and in this approach, the conducting of interior circuit is by between its internal part In the capacitor of formation and/or its internal part charged particle reciprocating vibration realize, and using external circuit output electric energy and/ Or absorb electric energy.

In the present invention, the export importing of electronics is a kind of work normality, and the export importing of so-called electronics refers to through external circuit The export of the electronics carried out imports.

In the present invention, the electrochemistry region, which is selectively chosen, is set as three-diemsnional electrode.

In the present invention, the electrochemistry region A, which is selectively chosen, is set as three-diemsnional electrode.

In the present invention, the electrochemistry region B, which is selectively chosen, is set as three-diemsnional electrode.

In the present invention, such as there is non-electronic conducting electrical relation using Y and X as synonym, Y and X, the electronics of the Y is led The form of presentation imported out refers to that the Y, the X and electronics export import the composition that circuit three is same closed circuit Part is selectively chosen electronics export importing circuit being set as external circuit, and non-electronic conducting electrical relation is formed Circuit be set as interior circuit.

In the present invention, such as using U, W and V as synonym, U has non-electronic conducting electrical relation through W and V, and electronics is in institute The form of presentation for exporting importing between U and the V is stated, refers to that the U, the W, the V and electronics export import circuit It is the component part of same closed circuit, is selectively chosen and electronics export importing circuit is set as external circuit, and will be non- Electronic conduction electrical relation is formed by circuit and is set as interior circuit.

In the present invention, so-called " alternating electromotive force " refers to that the changed electromotive force of electromotive force, such as direction become The changed electromotive force of electromotive force or size of change.

In the present invention, so-called " alternating current " refers to the changed electric current of electric current, such as the changed electricity in direction Stream, the changed electric current of size or alternating current.

In the present invention, so-called " alternating current " is selectively chosen the electric current for being set as the variation of electric current generating period, Such as electric current or alternating current that electric current, the size generating period of direction generating period variation change.

In the present invention, so-called alternating current refers to the alternating current changed by sinusoidal rule.

In the present invention, so-called AC power source refers to the alternating source that electric current is changed by sinusoidal rule.

In the present invention, there is so-called A and B non-electronic conducting electrical relation to refer to having on interior circuit between A and B Non-electronic conducting electrical relation, and its external circuit is selectively chosen electronic conduction relationship；Or, so-called A and B has non-electrical Son conducting electrical relation, which refers to, has non-electronic conducting electrical relation on external circuit between A and B, and its interior circuit may be selected Select electronic conduction relationship to property.

In the present invention, it is so-called " the electrochemistry region through insulation, isolation space, electrolyte, dielectric, capacitor, etc. At least one of gas ions, ionic liquid, ionized gas, solion and electronic conduction area have non-electrical with the region B Son conducting electrical relation " includes that the electrochemistry region is isolated with the region B insulator, dielectric and/or ion conducting body The non-electronic conducting electrical relation that has of two solion ponds.In this approach, being selectively chosen makes the electrification At least one in school district domain and the region B forms electrical relation with capacitive region and/or non-electronic charged particle transmitter.

In the present invention, it is so-called " the electrochemistry region A through insulation, isolation space, electrolyte, dielectric, capacitor, At least one of plasma, ionic liquid, ionized gas, solion and electronic conduction area and the electrochemistry region B With non-electronic conducting electrical relation " include the electrochemistry region A and the electrochemistry region B through insulator, dielectric and/ Or the non-electronic conducting electrical relation that two solion ponds of ion conducting body isolation have.In this approach, alternative Ground selection makes at least one in the electrochemistry region A and the electrochemistry region B and capacitive region and/or non-electronic band electrochondria Sub- transmitter forms electrical relation.

In the present invention, so-called " non-electronic charged particle transmitter " refer to non-conducting electronics but proton conducting or it is specific from The substance of son, i.e. electrolyte in conventional electrochemical device, can be according to the electrochemical properties of the reducing agent and the oxidant Non-electronic charged particle transmitter is selected, such as when the reducing agent is H₂, the oxidant is O₂When, the non-electronic electrification Particle conduction object alternative selects proton exchange membrane.

In the present invention, so-called " non-electronic conducting electrical relation " refers to the electricity formed through the charged particle other than electronics Conducting relationship or the electricity to be formed conducting relationship of standing facing each other through electronics, for example, relationship, non-electronic electrification is connected in the electricity that capacitor is formed The electricity conducting relationship etc. that particle reciprocating vibration is formed.

In the present invention, so-called " capacitor " be selectively chosen be set as electrolytic capacitor, super capacitor, electric double layer capacitance, All capacitors such as pseudo capacitance, fake capacitance.

In the present invention, so-called " reversible electric machine " refers to the motor that can mutually convert between motor and generator, For example, the motor that can be generated electricity when exportable rotary power, rotation when power supply.

In the present invention, it is selectively chosen and uses circumferential magnetic monopole direct current using DC reversible electromotor or selectivity selection Reversible electric machine.

In the present invention, when the purpose using reversible electric machine is the power supply using reversible electric machine when exportable power reception power The characteristics of can generating electricity, realizes the reinforcing and control imported to electronics export with electrode cooperating, and then realizes to electrochemistry mistake The optimization of journey.

It in the present invention, is selectively chosen, so that reversible electric machine movement power generation is implemented electro ultrafiltration to electrode, when the electricity of electrode When kinetic potential reaches setting degree, electrode, which powers to reversible electric machine, pushes reversible electric machine movement, sets when the electromotive force of electrode is reduced to When determining degree, reversible electric machine implements electro ultrafiltration to electrode using the kinetic energy power generation of itself and its STATEMENT OF FEDERALLY SPONSORED, so again and again Carry out cyclic process；In circulation, electrode recycles entirety and is to provide electric energy in the presence of the process for providing electric energy with absorbing electric energy； It is selectively chosen, control device is set between reversible electric machine and electrode；Be selectively chosen, load with reversible electric machine, Electrode is arranged in series, or load is arranged in parallel with reversible electric machine.

It in the present invention, is selectively chosen, so that reversible electric machine movement power generation is implemented electro ultrafiltration to electrode, when electrode is in electricity When electromotive force reaches setting degree under the action of chemical reaction and/or reversible electric machine, electrode is in electrochemical reaction and/or accumulation electricity It powers under the action of lotus to reversible electric machine and pushes reversible electric machine movement, it is reversible when the electromotive force of electrode is reduced to setting degree Motor implements electro ultrafiltration to electrode using the kinetic energy power generation of itself and its STATEMENT OF FEDERALLY SPONSORED, so carries out cyclic process again and again； In circulation, electrode recycles entirety and is to provide electric energy in the presence of the process for providing electric energy with absorbing electric energy；Optionally select It selects, control device is set between reversible electric machine and electrode；It being selectively chosen, load is arranged in series with reversible electric machine, electrode, Or load is arranged in parallel with reversible electric machine.

It in the present invention, is selectively chosen, makes electrode move reversible electric machine reversible electric machine power supply, when the electricity of electrode When kinetic potential is reduced to setting degree, reversible electric machine implements electro ultrafiltration to electrode using the kinetic energy power generation of itself and its STATEMENT OF FEDERALLY SPONSORED, when When the electromotive force of electrode reaches setting degree, electrode, which powers to reversible electric machine, pushes reversible electric machine movement, so again and again Carry out cyclic process；In circulation, electrode recycles entirety and is to provide electric energy in the presence of the process for providing electric energy with absorbing electric energy； It is selectively chosen, control device is set between reversible electric machine and electrode；Be selectively chosen, load with reversible electric machine, Electrode is arranged in series, or load is arranged in parallel with reversible electric machine.

It in the present invention, is selectively chosen, makes electrode under the action of electrochemical reaction and/or stored charge to reversible Motor power supply moves reversible electric machine, and when the electromotive force of electrode is reduced to setting degree, reversible electric machine utilizes itself and its connection The kinetic energy power generation of moving part to electrode implement electro ultrafiltration, when electrode under the action of electrochemical reaction and/or reversible electric machine electromotive force When reaching setting degree, electrode pushes reversible electricity to reversible electric machine power supply under the action of electrochemical reaction and/or stored charge Machine movement, so carries out cyclic process again and again；In circulation, there is the process for providing electric energy and absorbing electric energy in electrode, but Circulation is whole to be to provide electric energy；It is selectively chosen, control device is set between reversible electric machine and electrode；Optionally Selection, load are arranged in series with reversible electric machine, electrode, or load is arranged in parallel with reversible electric machine.

In the present invention, so-called " electrolyte " refer to all be arranged between two electrode of electrochemical appliance only allow it is specific The substance that charged particle passes through but electronics is not allowed to pass through can be solid, liquid or membranous body etc., such as the proton of PEMFC Film and solid oxide electrolyte etc..

In the present invention, so-called " being inserted into inert substance between the reducing agent and the oxidant " refers to goes back described Former agent is contacted with electrochemistry region and the oxidant contacted with this electrochemistry region between make inert substance and this electrochemical school district Domain contact, the purpose is to keep the boundary between the electrochemical reaction of the reducing agent and the electrochemical reaction of the oxidant more clear It is clear.

In the present invention, so-called " dead band duration is inserted between the reducing agent and the oxidant " refers to goes back described Former agent is contacted with electrochemistry region and the oxidant contacted with this electrochemistry region between be arranged dead band duration, the purpose is to keep away Exempt from the reducing agent and oxidant mixing, makes the electrochemical process of the reducing agent and the electrochemical process of the oxidant Between boundary it is apparent, so-called dead band duration refers to the time interval of setting, and specific duration is according to the reducing agent and institute State the property of oxidant, the temperature in electrochemistry region and catalyst whether there is or not and stopping of needing of the reducing agent and the oxidant Time etc. is stayed to determine.

In the present invention, so-called " inert substance " refers to the object not reacted with the reducing agent and the oxidant Matter.

In the present invention, so-called " electrochemistry region " refers to that the region of electrochemical reaction can occurs in all, for example including Catalyst, ultra microstructure and/or region (such as electrode in fuel cell etc.) at a set temperature, then for example in setting temperature Metallic region under degree.

It is so-called to refer to " including catalyst, ultra microstructure and/or electrochemistry region at a set temperature " in the present invention The electrochemistry region or including catalyst or including ultra microstructure or under the set temperature or the electrification School district domain includes two or three in these three conditions.

In the present invention, so-called " ultra microstructure " refers to the microcosmic knot that can cause electrochemical reaction under setting condition Structure.

In the present invention, so-called " local explosion limit " refers under conditions of the electrochemistry region, the reducing agent The concentration ratio that cannot be exploded with the oxidant.

In the present invention, include the catalyst method in, the catalyst be set as include noble metal catalyst, or The catalyst be set as include rare earth element catalyst.

In the present invention, so-called " non-electronic charged particle " refers to the charged particle other than electronics, such as proton or ion.

In the present invention, so-called " motor with additional rotation inertia " refers to the requirement with basis to rotary inertia, The motor of additional setting rotary inertia.

In the present invention, after a certain component names plus the letter such as so-called " A ", " B " is merely to distinguish two or several The identical component of title or substance.

In the present invention, there is non-electronic electric conduction through electronic conduction area and the region B including the electrochemistry region In the method for relationship, one in the electrochemistry region and the region B through capacitor or through non-electronic conducting area (such as matter The electrolyte such as proton exchange) again through external circuit and another electric communication, it is possible to realize that normality works.

It is non-electronic having including the electrochemistry region A through electronic conduction area and the electrochemistry region B in the present invention In the method that electrical relation is connected, one in the electrochemistry region A and the electrochemistry region B is through capacitor or through non-electronic Area (such as the electrolyte such as proton exchange membrane) are connected again through external circuit and another electric communication, it is possible to realize normality work Make.

In the present invention, positive and negative non-electronic charged particle mixing is selectively chosen as non-electronic charged particle transmitter Object.

In the present invention, the non-electronic charged particle transmitter A and the non-electronic charged particle transmitter B are alternative Ground selection is set as same non-electronic charged particle transmitter, is also selectively chosen and is set as non-electronic charged particle not of the same race How on earth transmitter selects, and should be determined according to the conductance calls of corresponding non-electronic charged particle.

It is the electrochemistry region, the non-electronic charged particle transmitter, the electronic conduction area, described in the present invention When getting along near any the two in dielectric and the region B, at least one of neighbour the two got along is got along neighbour Locate have ultra microstructure to increase the neighbour area got along, and then increases capacitance.

It is the electrochemistry region A, the non-electronic charged particle transmitter, the electronic conduction area, described in the present invention When getting along near any the two in dielectric and the electrochemistry region B, at least one of neighbour the two got along than It is adjacent mutually to have ultra microstructure to increase the neighbour area got along everywhere, and then increase capacitance.

In the present invention, the non-electronic charged particle transmitter A and the non-electronic charged particle transmitter B can be identical It can also be different, but alternative when non-electronic charged particle transmitter A and non-electronic charged particle transmitter B are directly contacted Selection is different, such as non-electronic charged particle transmitter A is proton conductive object, non-electronic charged particle transmitter B be negative oxygen from Son conducting object.

In the present invention, so-called interpolar spacer refers to make to have required for non-electronic conducting electrical relation between electrode Substance (including vacuum), for example, electrolyte, dielectric etc..

In the present invention, the selection of interpolar spacer alternative is set as insulation, isolation space, electrolyte, dielectric, electricity At least one of appearance, plasma, ionic liquid, ionized gas, solion and electronic conduction area.

In the present invention, so-called interpolar spacer, which is selectively chosen, is set as interior circuit, is also selectively chosen and sets For external circuit.

In the present invention, so-called electro ultrafiltration is a kind of selectivity selection.

In the present invention, so-called " electronic conduction area " refers to that conduct electrons are not turned on the region of non-electronic charged particle, can Selectively selection is set as metallic conductor area, carbon conductor region etc..

In the present invention, select electronic conduction area shape when, should for the purpose of increasing its capacitance with neighbors into Row selection.

In the present invention, necessary portion should be set in necessary place according to electricity field, the well-known technique of electrochemical field Part, unit or system etc..

Beneficial effects of the present invention are as follows: chemical energy electric energy conversion method disclosed in this invention will terminate Conventional electrochemical Method and electrochemical appliance (such as fuel cell etc.) are with electrolyte (such as proton exchange membrane and solid oxide electrolyte etc.) The history for existing for necessary condition, also will termination Conventional electrochemical method and device can not securely and reliably use oxidant reduction The history of agent composition provides new approach for efficient, long-life, Low-cost electric chemical devices exploitation, and will determine again Adopted engine.

Detailed description of the invention

Fig. 1-1 is the schematic diagram of the embodiment of the present invention 12；

Fig. 1-2 is the schematic diagram of the embodiment of the present invention 13；

Fig. 1-3 is the schematic diagram of the embodiment of the present invention 14；

Fig. 1-4 is the schematic diagram of the embodiment of the present invention 15；

Fig. 1-5 is the schematic diagram of the embodiment of the present invention 16；

Fig. 1-6 is the schematic diagram of the embodiment of the present invention 17；

Fig. 1-7 is the schematic diagram of the embodiment of the present invention 18；

Fig. 2-1 is the schematic diagram of the embodiment of the present invention 19；

Fig. 2-2 is the schematic diagram of the embodiment of the present invention 20；

Fig. 2-3 is the schematic diagram of the embodiment of the present invention 21；

Fig. 2-4 is the schematic diagram of the embodiment of the present invention 22；

Fig. 2-5 is the schematic diagram of the embodiment of the present invention 23；

Fig. 2-6 is the schematic diagram of the embodiment of the present invention 24；

Fig. 2-7 is the schematic diagram of the embodiment of the present invention 25；

Fig. 3-1 is the schematic diagram of the embodiment of the present invention 26；

Fig. 3-2 is the schematic diagram of the embodiment of the present invention 27；

Fig. 3-3 is the schematic diagram of the embodiment of the present invention 28；

Fig. 3-4 is the schematic diagram of the embodiment of the present invention 29；

Fig. 3-5 is the schematic diagram of the embodiment of the present invention 30；

Fig. 3-6 is the schematic diagram of the embodiment of the present invention 31；

Fig. 3-7 is the schematic diagram of the embodiment of the present invention 32；

Fig. 3-8 is the schematic diagram of the embodiment of the present invention 33；

Fig. 3-9 is the schematic diagram of the embodiment of the present invention 34；

Fig. 3-10 is the schematic diagram of the embodiment of the present invention 35；

Fig. 4-1 is the schematic diagram of the embodiment of the present invention 36；

Fig. 4-2 is the schematic diagram of the embodiment of the present invention 37；

Fig. 5-1 is the basic logic chart for exchanging electric energy for chemical energy；

Fig. 5-2 is reducing agent oxidant electrochemical reaction controlled process figure.

Specific embodiment

Technical solution of the present invention is further illustrated in the following with reference to the drawings and specific embodiments.

Embodiment 1

The invention discloses a kind of chemical energy electric energy conversion methods, can specifically make electrochemistry region and reducing agent and oxidant Alternating contacts or makes reducing agent and oxidant alternately to contact with electrochemistry region, and the electrochemistry region is through non-electronic charged particle At least one of transmitter, electronic conduction area and dielectric three and region B have non-electronic conducting electrical relation, using from The export of electronics between the electrochemistry region and the region B, which imports, realizes output electric energy and/or absorption electric energy.

Embodiment 2

Chemical energy electric energy conversion method disclosed in this invention also optionally makes electrochemistry region and reducing agent mutual The electrochemistry region and the mutual makes discontinuous contact of oxidant are contacted and make, the electrochemistry region is conducted through non-electronic charged particle At least one of object, electronic conduction area and dielectric three and region B have non-electronic conducting electrical relation, using from described The export of electronics between electrochemistry region and the region B, which imports, realizes output electric energy and/or absorption electric energy.

Embodiment 3

Chemical energy electric energy conversion method disclosed in this invention also optionally makes electrochemistry region and oxidant mutual The electrochemistry region and the mutual makes discontinuous contact of reducing agent are contacted and make, the electrochemistry region is conducted through non-electronic charged particle At least one of object, electronic conduction area and dielectric three and region B have non-electronic conducting electrical relation, using from described The export of electronics between electrochemistry region and the region B, which imports, realizes output electric energy and/or absorption electric energy.

Afore mentioned chemical energy electric energy conversion method disclosed in this invention in the specific implementation, further can be selected selectively Make the electrochemistry region that there is non-electronic conducting electrical relation through non-electronic charged particle transmitter and the region B, or makes The electrochemistry region successively has non-electronic conducting through electronic conduction area and non-electronic charged particle transmitter and the region B Electrical relation, or make the electrochemistry region that there is non-electronic conducting electrical relation, or selectivity through dielectric and the region B Ground selection make the electrochemistry region through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid, At least one of ionized gas, solion and electronic conduction area are correspondingly arranged with the region B.

Embodiment 4

Chemical energy electric energy conversion method disclosed in this invention also optionally makes electrochemistry region and reducing agent and oxygen The mixture of agent contacts or contacts the mixture of reducing agent and oxidant with electrochemistry region, and the electrochemistry region is through non- At least one of electronics charged particle transmitter, electronic conduction area and dielectric three have non-electronic electric conduction with region B Relationship is imported using the export of the electronics between the electrochemistry region and the region B and realizes output electric energy and/or suction Receive electric energy.

As disposable embodiment, the embodiment of the present invention 4 and its disposable embodiment can be selected further Property select to make the electrochemistry region that there is non-electronic conducting electricity pass through non-electronic charged particle transmitter and the region B System, or make the electrochemistry region successively through electronic conduction area and non-electronic charged particle transmitter and the region B with non- Electronic conduction electrical relation, or make the electrochemistry region that there is non-electronic conducting electrical relation through dielectric and the region B, Or selectively selection make the electrochemistry region through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, At least one of ionic liquid, ionized gas, solion and electronic conduction area are correspondingly arranged with the region B.

Embodiment 5

Chemical energy electric energy conversion method disclosed in this invention also optionally makes electrochemistry region and reducing agent and oxygen The mixture makes discontinuous contact of agent makes the mixture of reducing agent and oxidant and electrochemistry region makes discontinuous contact, the electrochemistry Region has non-electronic through at least one of non-electronic charged particle transmitter, electronic conduction area and dielectric three and region B Electrical relation is connected, is imported using the export of the electronics between the electrochemistry region and the region B and realizes output electric energy And/or absorb electric energy.

As disposable embodiment, the embodiment of the present invention 5 and its disposable embodiment can be selected further Property select to make the electrochemistry region that there is non-electronic conducting electricity pass through non-electronic charged particle transmitter and the region B System, or make the electrochemistry region successively through electronic conduction area and non-electronic charged particle transmitter and the region B with non- Electronic conduction electrical relation, or make the electrochemistry region that there is non-electronic conducting electrical relation through dielectric and the region B, Or selectively selection make the electrochemistry region through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, At least one of ionic liquid, ionized gas, solion and electronic conduction area are correspondingly arranged with the region B.

Embodiment 6

Chemical energy electric energy conversion method disclosed in this invention also optionally makes electrochemistry region A and reducing agent and oxygen Agent alternately contacts or makes reducing agent and oxidant alternately to contact with electrochemistry region A, makes electrochemistry region B and oxidant and goes back Former agent alternately contacts or contacts Oxidizing and Reducing Agents alternately with electrochemistry region B, and the electrochemistry region A is through non-electronic band At least one of charged particle transmitter, electronic conduction area and dielectric three have non-electronic lead with the electrochemistry region B Logical electrical relation is imported using the export of the electronics between the electrochemistry region A and the electrochemistry region B and realizes output electricity It can and/or absorb electric energy.

Embodiment 7

Chemical energy electric energy conversion method disclosed in this invention contacts electrochemistry region A with reducing agent And makes the electrochemistry region A and oxidant makes discontinuous contact and contact electrochemistry region B with reducing agent and make the electrification School district domain B and oxidant makes discontinuous contact, the electrochemistry region A is through non-electronic charged particle transmitter, electronic conduction area and electricity At least one of medium three has non-electronic conducting electrical relation with the electrochemistry region B, utilizes the electrochemical school district The export of electronics between domain A and the electrochemistry region B, which imports, realizes output electric energy and/or absorption electric energy.

Embodiment 8

Chemical energy electric energy conversion method disclosed in this invention contacts electrochemistry region A with oxidant And makes the electrochemistry region A and reducing agent makes discontinuous contact and contact electrochemistry region B with oxidant and make the electrification School district domain B and reducing agent makes discontinuous contact, the electrochemistry region A is through non-electronic charged particle transmitter, electronic conduction area and electricity At least one of medium three has non-electronic conducting electrical relation with the electrochemistry region B, utilizes the electrochemical school district The export of electronics between domain A and the electrochemistry region B, which imports, realizes output electric energy and/or absorption electric energy.

Embodiment 9

Chemical energy electric energy conversion method disclosed in this invention contacts electrochemistry region A with reducing agent And makes the electrochemistry region A and oxidant makes discontinuous contact and contact electrochemistry region B with oxidant and make the electrification School district domain B and reducing agent makes discontinuous contact, the electrochemistry region A is through non-electronic charged particle transmitter, electronic conduction area and electricity At least one of medium three has non-electronic conducting electrical relation with the electrochemistry region B, utilizes the electrochemical school district The export of electronics between domain A and the electrochemistry region B, which imports, realizes output electric energy and/or absorption electric energy.

Embodiment 10

Chemical energy electric energy conversion method disclosed in this invention also optionally makes electrochemistry region A and reducing agent and oxygen The mixture of agent contacts or contacts the mixture of reducing agent and oxidant with electrochemistry region A, makes electrochemistry region B and goes back The mixture of former agent and oxidant contacts or contacts the mixture of reducing agent and oxidant with electrochemistry region B, the electrification School district domain A is through at least one of non-electronic charged particle transmitter, electronic conduction area and dielectric three and the electrochemistry Region B has non-electronic conducting electrical relation, utilizes the electronics between the electrochemistry region A and the electrochemistry region B Export, which imports, realizes output electric energy and/or absorption electric energy.

Embodiment 11

Chemical energy electric energy conversion method disclosed in this invention also optionally makes electrochemistry region A and reducing agent and oxygen The mixture makes discontinuous contact of agent makes the mixture of reducing agent and oxidant and electrochemistry region A makes discontinuous contact, makes electrochemistry The mixture makes discontinuous contact of region B and reducing agent and oxidant makes the mixture of reducing agent and oxidant and electrochemistry region B Makes discontinuous contact, the electrochemistry region A through in non-electronic charged particle transmitter, electronic conduction area and dielectric three at least One and the electrochemistry region B have non-electronic conducting electrical relation, utilize the electrochemistry region A and the electrochemical school district The export of electronics between the B of domain, which imports, realizes output electric energy and/or absorption electric energy.

Embodiment 12

Fig. 1-1 is under unitary electrode (such as the present invention in electrochemistry region), and substance A and substance B replace with electrode to be connect The process chart of touching, chemical energy electric energy conversion method disclosed in this invention are selectively chosen according to following courses of work Work.

In Fig. 1-1,1 is electrode, A representative species A (reducing agent), B representative species B (oxidant).When substance A and electrode connect When touching (1. shown process in figure), the electronics of substance A is exported forming material A cation A under electro ultrafiltration⁺(i.e. reducing agent is being just Ion A⁺), as the reducing agent cation A⁺(intensity and electrode of the amount of accumulation depending on electro ultrafiltration when running up to setting degree Possessed electrical relation), substance A and substance B switching (as in figure 3. and 4. shown in process), and electronics is made to pass through load 5 It is imported into electrode, substance B, substance A cation A at electrode⁺Substance A and substance B redox reaction are generated with electron reaction Product C (in such as figure 5. shown in).Next two-way can be divided to continue, is as 5. passed through in figure all the wayShown in 1., Apply the electro ultrafiltration in direction same as described above again, and switch substance A and substance B again, and then realizes circulation industrial in cycles Make；Another way is as 5. passed through in figureShown in 7., apply the electro ultrafiltration in direction contrary to the above, and continues to make substance B and electricity Pole contact, and then make substance B and electronics coexist in electrode (in some cases substance B can receive electronically form substance B bear from Sub- B^—Or oxidant anion B^—, do not show in figure), when electronics or oxidant anion B-run up to setting degree (in such as figure 9. shown in), switching substance A and substance B and make electronics through load 5 from electrode export (such as figure 10. andIt is shown), also Former agent cation, electronics and oxidant react herein generates C (in such as figureIt is shown), reversed electricity next is implemented to electrode and is made With and continue to make substance A contact with electrode reach in figure 1. shown in state, and then realize cycle operation in cycles.This figure institute The principle and process shown are the course of work of unitary electrode.The purpose of electro ultrafiltration is control and reinforcing electrochemical reaction, electro ultrafiltration It can come from external power supply, can come from the chemical potential in electrochemical reaction, can be from the electric energy (example by storing process Such as, the electric energy through capacitor or oscillating circuit) etc..Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not It is lost, and is stored at electrode, released together when electric current is reversed.

Embodiment 13

Fig. 1-2 is H under unitary electrode (such as electrochemistry region in the present invention)₂And O₂Contact is alternateed with electrode Process chart, chemical energy electric energy conversion method disclosed in this invention are selectively chosen according to following course of work works Make.

In Fig. 1-2,1 is electrode.The principle and process that this figure illustrates are identical as Fig. 1-1, only the reducing agent object in Fig. 1-1 Matter A is with H₂To represent, oxidant species B is with O₂To represent, reducing agent cation A⁺It is then H⁺.Principle shown in this figure and process For the course of work of unitary electrode.The purpose of electro ultrafiltration is control and reinforcing electrochemical reaction, and electro ultrafiltration can come from external electrical Source can come from the chemical potential in electrochemical reaction, can be from the electric energy by storing process (for example, through capacitor or vibration Swing the electric energy of circuit) etc..Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not lost, but by It is stored at electrode, is released together when electric current is reversed.

Embodiment 14

Fig. 1-3 is CH under unitary electrode (such as electrochemistry region in the present invention)₃OH and O₂It alternates and contacts with electrode Process chart, chemical energy electric energy conversion method disclosed in this invention is selectively chosen according to following course of work works Make.

In Fig. 1-3,1 is electrode.The principle and process that this figure illustrates are identical as Fig. 1-1, only the reducing agent object in Fig. 1-1 Matter A is with CH₃OH is representative, and oxidant species B is with O₂To represent.Furthermore compared with Fig. 1-1, the principle shown in Fig. 1-3 and process Middle H₂O takes part in electrochemical reaction process as recycled material.Principle shown in this figure and process are the worked of unitary electrode Journey.The purpose of electro ultrafiltration is that control can come from external power supply, it is anti-to can come from electrochemistry with electrochemical reaction, electro ultrafiltration is strengthened Chemical potential in answering can be from the electric energy (for example, electric energy through capacitor or oscillating circuit) etc. by storing process.Electricity is made With consumption electric energy, but the electric energy consumed during electro ultrafiltration is being lost, and is stored at electrode, anti-to electric current To when release together.

Embodiment 15

Fig. 1-4 is the mixture and electricity of substance A and substance B under unitary electrode (such as electrochemistry region in the present invention) The process chart that pole contacts with each other, chemical energy electric energy conversion method disclosed in this invention are selectively chosen according to following Course of work work.

In Fig. 1-4,1 is electrode, A representative species A (reducing agent), B representative species B (oxidant).When substance A and substance B Mixture and electrode when contacting (in figure 1. shown in process), the electronics of the substance A under electro ultrafiltration in mixture is exported shape At substance A cation A⁺(i.e. reducing agent cation A⁺), as the reducing agent cation A⁺When running up to setting degree (accumulation Electrical relation possessed by intensity and electrode of the amount depending on electro ultrafiltration), so that electronics is imported into electrode by load 5, in electrode Locate substance B, substance A cation A⁺With the product C of electron reaction generation substance A and substance B redox reaction (in such as figure Shown in 4.).Next two-way can be divided to continue, is as, 5. to shown in 1., applied side same as described above again in figure all the way To electro ultrafiltration, that is, reach in figure 1. shown in state, and then realize cycle operation in cycles；Another way be as in figure 5. to 6. It is shown, apply the electro ultrafiltration in direction contrary to the above, and then make substance B forming material B anion B^—That is oxidant anion B^— (in some cases may forming material A, substance B and electronics coexist in the situation of electrode, do not shown in figure), work as oxidant Anion B^—Or electron accumulation to setting degree when (in such as figure 8. shown in), make electronics through load 5 from electrode export (such as figure 9. institute Show) form reducing agent cation A⁺, it is formed by reducing agent cation A⁺, oxidant (substance B) and electronics or reducing agent just from Sub- A⁺With oxidant anion B^—Reaction generates C (also as 9. shown in figure), next implements reversed electro ultrafiltration to electrode and reaches In figure 1. shown in state, and then realize cycle operation in cycles.Although existing always at electrode during shown in Fig. 1-4 There is reducing agent and oxidant always in substance A and substance B, but due to electro ultrafiltration there are reducing agents and oxidant can not be straight Row redox reaction is tapped into, and then avoids or weakens mixture and directly carry out redox reaction forfeiture power supply at electrode The process of ability.Principle shown in this figure and process are the course of work of unitary electrode.The purpose of electro ultrafiltration is control and strengthens Electrochemical reaction, electro ultrafiltration can come from external power supply, can come from the chemical potential in electrochemical reaction, can be from by Electric energy (for example, electric energy through capacitor or oscillating circuit) of storing process etc..Electro ultrafiltration consumes electric energy, but in electro ultrafiltration process The electric energy of middle consumption is not lost, and is stored at electrode, is released together when electric current is reversed.

Embodiment 16

Fig. 1-5 is the mixture and electricity of substance A and substance B under unitary electrode (such as electrochemistry region in the present invention) The process chart of extremely mutual makes discontinuous contact, chemical energy electric energy conversion method disclosed in this invention be selectively chosen according to Following course of work work.

In Fig. 1-5,1 is electrode, A representative species A (reducing agent), B representative species B (oxidant).Except substance A and substance B Mixture and the mutual makes discontinuous contact of electrode influence outside, principle shown in Fig. 1-5 is identical as shown in Fig. 1-4 with process, mixed The purpose for closing object and electrode makes discontinuous contact is to reduce the mixture of substance A and substance B i.e. reducing agent and oxidant at electrode Mixture existing for the time, to realize better control to electrochemical process.As in figure 3., 4., shown in the processes such as 5., Discontinuously contact with each other and be formed by circulation, have at electrode considerable time intervals only exist a kind of substance only exist and also Former agent only exists oxidant (substance B and electronics is regarded as substance B anion B when coexisting^—Rather than substance B).This figure institute The principle and process shown are the course of work of unitary electrode.The purpose of electro ultrafiltration is control and reinforcing electrochemical reaction, electro ultrafiltration It can come from external power supply, can come from the chemical potential in electrochemical reaction, can be from the electric energy (example by storing process Such as, the electric energy through capacitor or oscillating circuit) etc..Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not It is lost, and is stored at electrode, released together when electric current is reversed.

Embodiment 17

Fig. 1-6 is H under unitary electrode (such as electrochemistry region in the present invention)₂And O₂Mixture and electrode phase mutual connection The process chart of touching, chemical energy electric energy conversion method disclosed in this invention are selectively chosen according to following courses of work Work.

In Fig. 1-6,1 is electrode.Principle and process shown in Fig. 1-6 are identical as Fig. 1-4, only the substance A in Fig. 1-4 With H₂To represent, substance B is with O₂To represent.Principle shown in this figure and process are the course of work of unitary electrode.The mesh of electro ultrafiltration Be control and strengthen electrochemical reaction, electro ultrafiltration can come from external power supply, can come from the chemical potential in electrochemical reaction, It can be from the electric energy (for example, electric energy through capacitor or oscillating circuit) etc. by storing process.Electro ultrafiltration consumes electric energy, but The electric energy consumed during electro ultrafiltration is not lost, and is stored at electrode, is released together when electric current is reversed.

Embodiment 18

Fig. 1-7 is CH under unitary electrode (such as electrochemistry region in the present invention)₃OH and O₂Mixture and electrode phase The process chart mutually contacted, chemical energy electric energy conversion method disclosed in this invention are selectively chosen according to following work Process work.

In Fig. 1-7,1 is electrode.Principle and process shown in Fig. 1-7 are identical as Fig. 1-4, only the substance A in Fig. 1-4 With CH₃OH is representative, and substance B is with O₂To represent.In addition to this, compared with principle and process shown in Fig. 1-4, water as shown in the figure Electrochemical reaction is taken part in as recycled material.Principle shown in this figure and process are the course of work of unitary electrode.Electro ultrafiltration Purpose be control and strengthen electrochemical reaction, electro ultrafiltration can come from external power supply, can come from the change in electrochemical reaction Gesture is learned, can be from the electric energy (for example, electric energy through capacitor or oscillating circuit) etc. by storing process.Electro ultrafiltration consumption electricity Can, but the electric energy consumed during electro ultrafiltration is not lost, and be stored at electrode, when electric current is reversed together It releases.

Embodiment 19

Fig. 2-1 is shown including electrode (such as electrochemistry region in the present invention) and electric conductor corresponding with this electrode , the process chart that substance A and substance B are alternately contacted with electrode, chemical energy electric energy conversion method disclosed in this invention can It selectively selects to work according to following courses of work.

In Fig. 2-1,1 is electrode, and 2 be electric conductor, and 6 be interpolar spacer, A representative species A (reducing agent), B representative species B (oxidant), wherein electric conductor plays the role of another electrode in electrodic electron export importing process.When substance A and electricity When pole 1 contacts (1. shown process in figure), the electronics of substance A is exported to electric conductor 2 and then forms substance A under electro ultrafiltration Substance A cation A⁺(i.e. reducing agent cation A⁺), as the reducing agent cation A⁺(the amount of accumulation when running up to setting degree Electrical relation possessed by intensity and electrode depending on electro ultrafiltration), 3. and 4. substance A and substance B switching are (as shown in figure Process), and electronics is made to imported into electrode from electric conductor by load 5, substance B, substance A cation A at electrode⁺And electron back The product C (5. shown in such as figure) of substance A and substance B redox reaction should be generated.Next can divide two-way continue into Row, is as 5. passed through in figure all the wayShown in 1., apply the electro ultrafiltration in direction same as described above again, and switch substance A again With substance B, and then cycle operation in cycles is realized；Another way is as 5. passed through in figureShown in 7., apply contrary to the above The electro ultrafiltration in direction, and continue to contact substance B with electrode, and then substance B and electronics is made to coexist in electrode (in some cases Substance B, which can receive, electronically forms substance B anion B-or oxidant anion B-, does not show in figure), when electronics or oxygen When agent anion B-runs up to setting degree (in such as figure 9. shown in), switching substance A and substance B and make electronics through load 5 from Electrode export to electric conductor (in such as figure 10. andIt is shown), reducing agent cation, electronics and oxidant react at the electrode C is generated (in such as figureIt is shown), reversed electro ultrafiltration next is implemented to electrode and continues to contact substance A with electrode to reach figure In 1. shown in state, and then realize cycle operation in cycles.Principle shown in this figure and process be include being isolated through interpolar Object has the electrode of electrical relation and the course of work of electric conductor.The purpose of electro ultrafiltration is control and reinforcing electrochemical reaction, electricity Effect can come from external power supply, can come from the chemical potential in electrochemical reaction, can be from the electricity by storing process Energy (for example, electric energy through capacitor or oscillating circuit) etc..Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is simultaneously It is not lost, and is stored at electrode, released together when electric current is reversed.

Embodiment 20

Fig. 2-2 is shown including electrode (such as electrochemistry region in the present invention) and electric conductor corresponding with this electrode , H₂And O₂The process chart of contact is alternateed with electrode, chemical energy electric energy conversion method disclosed in this invention is optional It selects to selecting property to work according to following courses of work.

In Fig. 2-2,1 is electrode, and 2 be electric conductor, and 6 be interpolar spacer, and wherein electric conductor is exported in electrodic electron and imported Play the role of another electrode in the process.Except the substance A (reducing agent) in Fig. 2-1 is with H₂To represent, substance B (oxidant) With O₂Outer to represent, principle and the course of work shown in Fig. 2-2 are identical as principle shown in Fig. 2-1 and process.The mesh of electro ultrafiltration Be control and strengthen electrochemical reaction, electro ultrafiltration can come from external power supply, can come from the chemical potential in electrochemical reaction, It can be from the electric energy (for example, electric energy through capacitor or oscillating circuit) etc. by storing process.Electro ultrafiltration consumes electric energy, but The electric energy consumed during electro ultrafiltration is not lost, and is stored at electrode, is released together when electric current is reversed.

Embodiment 21

Fig. 2-3 is shown including electrode (such as electrochemistry region in the present invention) and electric conductor corresponding with this electrode , CH₃OH and O₂The process chart of contact is alternateed with electrode, chemical energy electric energy conversion method disclosed in this invention can It selectively selects to work according to following courses of work.

In Fig. 2-3,1 is electrode, and 2 be electric conductor, and 6 be interpolar spacer, and wherein electric conductor is exported in electrodic electron and imported Play the role of another electrode in the process.Except the substance A (reducing agent) in Fig. 2-1 is with CH₃OH is representative, substance B (oxidation Agent) with O₂To represent, H₂It is outer that O as recycled material participates in reaction, shown in principle and the course of work shown in Fig. 2-3 and Fig. 2-1 Principle it is identical with process.The purpose of electro ultrafiltration is control and reinforcing electrochemical reaction, and electro ultrafiltration can come from external power supply, can With the chemical potential in electrochemical reaction, the electric energy by storing process can be from (for example, through capacitor or oscillating circuit Electric energy) etc..Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not lost, and is stored in At electrode, released together when electric current is reversed.

Embodiment 22

Fig. 2-4 is shown including electrode (such as electrochemistry region in the present invention) and electric conductor corresponding with this electrode , the process chart that the mixture and electrode of substance A and substance B contact with each other, chemical energy electric energy disclosed in this invention turns The method of changing is selectively chosen to work according to following courses of work.

In Fig. 2-4,1 is electrode, and 2 be electric conductor, and 6 be interpolar spacer, A representative species A (reducing agent), B representative species B (oxidant), wherein electric conductor plays the role of another electrode in electrodic electron export importing process.When substance A and object When the mixture and electrode of matter B contact (1. shown process in figure), the electronics of the substance A under electro ultrafiltration in mixture is exported To electric conductor 2 and then make substance A forming material A cation A⁺(i.e. reducing agent cation A⁺), as the reducing agent cation A⁺Product When tiring out setting degree (electrical relation possessed by intensity and electrode of the amount of accumulation depending on electro ultrafiltration), make electronics through loading 5 imported into electrode from electric conductor, substance B, substance A cation A at electrode⁺Substance A and substance B oxidation are generated with electron reaction The product C (4. shown in such as figure) of reduction reaction.Next two-way can be divided to continue, be all the way as in figure 5. to 1. institute Show, apply the electro ultrafiltration in direction same as described above again, that is, reach in figure 1. shown in state, and then realize circulation industrial in cycles Make；Another way is and then to keep substance B forming material B negative as, 5. to shown in 6., applied the electro ultrafiltration in direction contrary to the above in figure Ion B — that is, oxidant anion B^—(in some cases may forming material A, substance B and electronics coexist in the shape of electrode Condition is not shown in figure), as oxidant anion B^—Or electron accumulation to setting degree when (in such as figure 8. shown in), pass through electronics Load 5 exports to electric conductor (in such as figure 9. shown in) from electrode and forms reducing agent cation A⁺, it is formed by reducing agent cation A⁺, oxidant (substance B) and electronics or reducing agent cation A⁺C is generated (also such as 9. institute in figure with oxidant anion B-reaction Show), next to electrode implement reversed electro ultrafiltration reach in figure 1. shown in state, and then realize cycle operation in cycles. Although there is substance A always at electrode during shown in Fig. 2-4 and substance B have reducing agent and oxidant always, Due to the presence of electro ultrafiltration, reducing agent and oxidant can not directly carry out redox reaction, and then avoid or weaken mixing Object directly carries out the process that redox reaction loses power supply capacity at electrode.The purpose of electro ultrafiltration is control and reinforcing electrification Reaction is learned, electro ultrafiltration can come from external power supply, can come from the chemical potential in electrochemical reaction, can be from by storage Electric energy (for example, electric energy through capacitor or oscillating circuit) of process etc..Electro ultrafiltration consumes electric energy, but consumes during electro ultrafiltration Electric energy not lost, and be stored at electrode, released together when electric current is reversed.

Embodiment 23

Fig. 2-5 is shown including electrode (such as electrochemistry region in the present invention) and electric conductor corresponding with this electrode , the mixture of substance A and substance B and the process chart of the mutual makes discontinuous contact of electrode, chemical energy electricity disclosed in this invention Energy conversion method is selectively chosen to work according to following courses of work.

In Fig. 2-5,1 is electrode, and 2 be electric conductor, and 6 be interpolar spacer, A representative species A (reducing agent), B representative species B (oxidant), wherein electric conductor plays the role of another electrode in electrodic electron export importing process.Except substance A and object Outside the mixture of matter B and the influence of the mutual makes discontinuous contact of electrode, shown in principle and the course of work shown in Fig. 2-5 and Fig. 2-4 Principle is identical with process.The purpose of mixture and electrode makes discontinuous contact is when reducing existing for reducing agent and oxidant mixture It is long, improve safety, controllability and reliability.The purpose of electro ultrafiltration is that control can come with electrochemical reaction, electro ultrafiltration is strengthened From external power supply, can come from the chemical potential in electrochemical reaction, can be from by storing process electric energy (for example, through The electric energy of capacitor or oscillating circuit) etc..Electro ultrafiltration consumes electric energy, but there is no damaged the electric energy consumed during electro ultrafiltration It loses, and is stored at electrode, released together when electric current is reversed.

Embodiment 24

Fig. 2-6 is shown including electrode (such as electrochemistry region in the present invention) and electric conductor corresponding with this electrode , H₂And O₂Mixture and the process chart that contacts with each other of electrode, chemical energy electric energy conversion method disclosed in this invention It is selectively chosen and works according to following courses of work.

In Fig. 2-6,1 is electrode, and 2 be electric conductor, and 6 be interpolar spacer, and wherein electric conductor is exported in electrodic electron and imported Play the role of another electrode in the process.Except substance A (reducing agent) is with H₂To represent, substance B (oxidant) is with O₂To represent Outside, principle and the course of work shown in Fig. 2-6 are identical as principle shown in Fig. 2-4 and process.Electro ultrafiltration can come from external electrical Source can come from the chemical potential in electrochemical reaction, can be from the electric energy by storing process (for example, through capacitor or vibration Swing the electric energy of circuit) etc..The purpose of electro ultrafiltration is control and reinforcing electrochemical reaction, and electro ultrafiltration consumes electric energy, but in electro ultrafiltration The electric energy consumed in the process is not lost, and is stored at electrode, is released together when electric current is reversed.

Embodiment 25

Fig. 2-7 is shown including electrode (such as electrochemistry region in the present invention) and electric conductor corresponding with this electrode , CH₃OH and O₂Mixture and the process chart that contacts with each other of electrode, chemical energy electric energy disclosed in this invention conversion side Method is selectively chosen to work according to following courses of work.

In Fig. 2-7,1 is electrode, and 2 be electric conductor, and 6 be interpolar spacer, and wherein electric conductor is exported in electrodic electron and imported Play the role of another electrode in the process.Except substance A (reducing agent) is with CH₃OH is representative, and substance B (oxidant) is with O₂For generation Off-balancesheet, H₂O is participated in outside reaction as recycled material, principle and the course of work shown in Fig. 2-7 and principle and mistake shown in Fig. 2-4 Cheng Xiangtong.The purpose of electro ultrafiltration is that control can come from external power supply, can come from electrification with electrochemical reaction, electro ultrafiltration is strengthened The chemical potential in reaction is learned, can be from the electric energy (for example, electric energy through capacitor or oscillating circuit) etc. by storing process. Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not lost, and is stored at electrode, to electricity It is released together when flowing reversed.

Embodiment 26

Fig. 3-1 show including electrode A (such as the present invention in electrochemistry region A) and electrode B (such as it is of the invention in electricity Chemical regions B), substance A and substance B alternately contacts with electrode A and substance B and substance A replace with electrode B contact it is worked Cheng Tu, chemical energy electric energy conversion method disclosed in this invention is selectively chosen to work according to following courses of work.

In Fig. 3-1,3 be electrode A, and 4 be electrode B, and 6 be interpolar spacer, A representative species A (reducing agent), B representative species B (oxidant).When substance A is contacted with electrode A and substance B and electrode B contact (1. shown process in figure), substance A is in electrode A Forming material A cation A⁺(i.e. reducing agent cation A⁺) and electronics, substance B is in electrode B serious hope electronics (because electronegativity attracts parent And electronics), the electronics of electrode A through load 5 exports to electrode B, and (substance B can receive that electronically form substance B negative in some cases Ion B-or oxidant anion B-, does not show in figure), as the A of electrode A⁺(or the electronics or electrode B of electrode B B -) when running up to setting degree, substance A and substance B switch (in such as figure 4. shown in) and electronics is led through load 5 from electrode B Enter to electrode A, the reaction of generation substance A and substance B redox reaction product C occurs in electrode A and electrode B at this time (5. shown in such as figure).Because substance B has strong electronegativity, therefore electric when exporting from the coexistence state of substance B, substance A and electronics The period of the day from 11 p.m. to 1 a.m will form substance B, substance A cation A⁺With electronics coexistence state, and then three react generate C.Next it can divide two-way Continue, is as 5. passed through in figure all the wayShown in 1., and in process1. locate to switch substance A and substance B again, into And realize cycle operation in cycles；Another way is as 5. passed through in figureShown in 7., that is, carry out that substance B is maintained to connect with electrode A Touching, substance A contacts with electrode B, when the electronics (electronics and substance B coexists in electrode A or electronics is in electrode A and substance B of electrode A Forming material B anion or oxidant anion B-, do not show in figure) or when electrode B A⁺When running up to setting degree (in such as figure 8. shown in), switching substance A and substance B and electronics is made to export to electrode B (such as 9. institute in figure from electrode A through load 5 Show), at this moment occur to generate the reaction (in such as figure 10. shown in) of C in electrode A and electrode B, continues to substance A and connect with electrode A Touching and the state that is contacted with electrode B of substance B reach in figure 1. shown in process, and then realization cycle operation in cycles.

Embodiment 27

Fig. 3-2 show including electrode A (such as the present invention in electrochemistry region A) and electrode B (such as it is of the invention in electricity Chemical regions B), H₂And O₂It is alternately contacted and O with electrode A₂And H₂The process chart alternately contacted with electrode B, institute of the present invention Disclosed chemical energy electric energy conversion method is selectively chosen to work according to following courses of work.

In Fig. 3-2,3 be electrode A, and 4 be electrode B, and 6 be interpolar spacer.The principle and process and Fig. 3-1 that this figure illustrates Shown in it is identical, only the reducing agent substance A in Fig. 3-1 is with H₂To represent, oxidant species B is with O₂For represent, reducing agent just from Sub- A⁺It is then H⁺。

Embodiment 28

Fig. 3-3 show including electrode A (such as the present invention in electrochemistry region A) and electrode B (such as it is of the invention in electricity Chemical regions B), CH₃OH and O₂Contact and O are alternateed with electrode A₂And CH₃OH and electrode B alternate the work of contact Procedure chart, chemical energy electric energy conversion method disclosed in this invention is selectively chosen to work according to following courses of work.

In Fig. 3-3,3 be electrode A, and 4 be electrode B, and 6 be interpolar spacer.The principle and process and Fig. 3-1 that this figure illustrates Shown in it is identical, only the reducing agent substance A in Fig. 3-1 is with CH₃OH is representative, and oxidant species B is with O₂To represent.Furthermore with Principle shown in Fig. 3-1 is compared with process, the principle shown in Fig. 3-3 and in the process H₂O takes part in electrification as recycled material Learn reaction process.

Embodiment 29

Fig. 3-4 show including electrode A (such as the present invention in electrochemistry region A) and electrode B (such as it is of the invention in electricity Chemical regions B), the mixture of substance A and substance B is contacted with electrode A and substance B and the mixture of substance A are contacted with electrode B And electro ultrafiltration participate in process chart, chemical energy electric energy conversion method disclosed in this invention be selectively chosen according to Following course of work work.

In Fig. 3-4,3 be electrode A, and 4 be electrode B, and 6 be interpolar spacer, A representative species A (reducing agent), B representative species B (oxidant).When the mixture of substance A and substance B is contacted with electrode A and the mixture of substance A and substance B and electrode B contact (in figure 1. shown in process), the substance A in mixture is in electrode A forming material A cation A⁺(i.e. reducing agent cation A⁺) and Electronics, the substance A in mixture is in electrode B also forming material A cation A⁺(i.e. reducing agent cation A⁺) and electronics, mixture In substance B thirst for electronics (because electronegativity attracts affine electronics) in electrode A, the substance B in mixture also thirsts for electricity in electrode B Son (because electronegativity attracts affine electronics), therefore, electrode A and electrode B are in symmetry status, without electric current flowing.However, When applying electro ultrafiltration, the electronics of electrode A is exported to electrode B, and (substance B can receive that electronically form substance B negative in some cases Ion B^—Or oxidant anion B^—, do not show in figure) and (in such as figure 1. and 2. shown in), as the A of electrode A⁺(or electrode B Electronics or electrode B B^—) when running up to setting degree (in such as figure 3. shown in), electronics is made to imported into electricity from electrode B through load 5 Pole A (4. shown in such as figure) occurs to generate substance A and substance B redox reaction product C at this time in electrode A and electrode B Reaction (in such as figure 4. shown in).Because substance B has strong electronegativity, therefore from the coexistence state of substance B, substance A and electronics It will form substance B, substance A cation A when exporting electronics⁺With electronics coexistence state, and then three react generate C.It next can be with Point two-way continues, be all the way as in figure 5. to shown in 1., and then realization cycle operation in cycles；Another way is as in figure 5. applying the electro ultrafiltration of opposite direction to shown in 6., when the electronics (electronics and substance B coexists in electrode A or electronics exists of electrode A Electrode A and substance B forming material B anion or oxidant anion B^—, do not show in figure, in B^—In the presence of, work as B^—Accumulation When to setting degree) when running up to setting degree or when electrode B A⁺When running up to setting degree (8. shown in such as figure), make electricity Son exports to electrode B (in such as figure 9. shown in) from electrode A through load 5, and the reaction of generation C at this moment occurs in electrode A and electrode B (in such as figure 9. shown in), apply opposite direction electro ultrafiltration reach in figure 1. shown in process, and then realize and recycle in cycles Work.The purpose of electro ultrafiltration is that control can come from external power supply, can come from electrochemistry with electrochemical reaction, electro ultrafiltration is strengthened Chemical potential in reaction can be from the electric energy (for example, electric energy through capacitor or oscillating circuit) etc. by storing process.Electricity Effect consumption electric energy, but the electric energy consumed during electro ultrafiltration is not lost, and be stored at electrode, to electric current It is released together when reversed.

Embodiment 30

Fig. 3-5 show including electrode A (such as the present invention in electrochemistry region A) and electrode B (such as it is of the invention in electricity Chemical regions B), the mixture and electrode A makes discontinuous contact of substance A and substance B and the mixture and electrode B of substance B and substance A The process chart that makes discontinuous contact and electro ultrafiltration participate in, chemical energy electric energy conversion method disclosed in this invention is optionally Selection works according to following courses of work.

In Fig. 3-5,3 be electrode A, and 4 be electrode B, and 6 be interpolar spacer, A representative species A (reducing agent), B representative species B (oxidant).Other than the influence of electrode and mixture makes discontinuous contact, shown in principle shown in Fig. 3-5 and process and Fig. 3-4 Identical, the purpose for making electrode and mixture makes discontinuous contact is to reduce duration existing for mixture, increases the safety, reliable of process Property and controllability.The purpose of electro ultrafiltration is that control can come from external power supply, can come from electrochemical reaction, electro ultrafiltration is strengthened Chemical potential in electrochemical reaction can be from the electric energy by storing process (for example, the electricity through capacitor or oscillating circuit Can) etc..Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not lost, and is stored in electrode Place, is released together when electric current is reversed.

Embodiment 31

Fig. 3-6 show including electrode A (such as the present invention in electrochemistry region A) and electrode B (such as it is of the invention in electricity Chemical regions B), H₂And O₂Mixture contacted with electrode A and H₂And O₂Mixture contacted with electrode B and also electro ultrafiltration join With process chart, chemical energy electric energy conversion method disclosed in this invention is selectively chosen according to following courses of work Work.

In Fig. 3-6,3 be electrode A, and 4 be electrode B, and 6 be interpolar spacer.In addition to reducing agent is with H₂For represent, oxidant with O₂Outer to represent, principle shown in Fig. 3-6 is identical as shown in Fig. 3-4 as process.The purpose of electro ultrafiltration is control and reinforcing electricity Chemical reaction, electro ultrafiltration can come from external power supply, can come from the chemical potential in electrochemical reaction, can be from by depositing Electric energy (for example, electric energy through capacitor or oscillating circuit) of storage process etc..Electro ultrafiltration consumes electric energy, but disappears during electro ultrafiltration The electric energy of consumption is not lost, and is stored at electrode, is released together when electric current is reversed.

Embodiment 32

Fig. 3-7 show including electrode A (such as the present invention in electrochemistry region A) and electrode B (such as it is of the invention in electricity Chemical regions B), CH₃OH and O₂Mixture contacted with electrode A and CH₃OH and O₂Mixture contacted with electrode B and also electricity The process chart participated in is acted on, chemical energy electric energy conversion method disclosed in this invention is selectively chosen according to following works Make process work.

In Fig. 3-7,3 be electrode A, and 4 be electrode B, and 6 be interpolar spacer.In addition to reducing agent is with CH₃OH is representative, oxidation Agent is with O₂Outer to represent, principle shown in Fig. 3-7 is identical as shown in Fig. 3-4 as process.Furthermore with principle shown in Fig. 3-4 with Process is compared, the principle shown in Fig. 3-7 and in the process H₂O takes part in electrochemical reaction process as recycled material.Electro ultrafiltration Purpose be control and strengthen electrochemical reaction, electro ultrafiltration can come from external power supply, can come from the change in electrochemical reaction Gesture is learned, can be from the electric energy (for example, electric energy through capacitor or oscillating circuit) etc. by storing process.Electro ultrafiltration consumption electricity Can, but the electric energy consumed during electro ultrafiltration is not lost, and be stored at electrode, when electric current is reversed together It releases.

Embodiment 33

Fig. 3-8 show including electrode A (such as the present invention in electrochemistry region A) and electrode B (such as it is of the invention in electricity Chemical regions B), substance A and substance B alternately contacts with electrode A and substance B and substance A are alternately contacted with electrode B and electricity work With the process chart of participation, chemical energy electric energy conversion method disclosed in this invention is selectively chosen according to following work Process work.

In Fig. 3-8,3 be electrode A, and 4 be electrode B, and 6 be interpolar spacer, A representative species A (reducing agent), B representative species B (oxidant).When substance A is contacted with electrode A and substance B and electrode B contact (1. shown process in figure), substance A is in electrode A Forming material A cation A⁺(i.e. reducing agent cation A⁺) and electronics, substance B is in electrode B serious hope electronics (because electronegativity attracts parent And electronics), the electronics of electrode A is exported to electrode B (substance B can connect in some cases under the action of the electro ultrafiltration of application Receipts electronically form substance B anion B-or oxidant anion B-, do not show in figure), as the A of electrode A⁺(or electrode B Electronics or electrode B B -) when running up to setting degree, substance A and substance B switch (in such as figure 3. and 4. shown in) and Electronics imported into electrode A from electrode B through load 5, occurs to generate substance A and substance B oxidation also at this time in electrode A and electrode B The reaction (5. shown in such as figure) of former reaction product C.Because substance B has strong electronegativity, therefore works as from substance B, substance A and electricity It will form substance B, substance A cation A when exporting electronics in the coexistence state of son⁺With electronics coexistence state, and then three react generate C.Next two-way can be divided to continue, is as 5. passed through in figure all the wayShown in 1., and in process1. locating to cut again Substance A and substance B are changed, and then realizes cycle operation in cycles；Another way is as 5. passed through in figureShown in 7., that is, carry out Substance B is maintained to contact with electrode A, substance A is contacted with electrode B, and applies the electro ultrafiltration of opposite direction, when the electronics (electricity of electrode A Son and substance B coexists in electrode A or electronics is in electrode A and substance B forming material B anion or oxidant anion B-, Do not shown in figure, B-in the presence of, when B-runs up to setting degree) when running up to setting degree or when electrode B A⁺Product When tiring out setting degree (9. shown in such as figure), switches substance A and substance B and electronics is made to export to electrode from electrode A through load 5 B (in such as figure 10. withIt is shown), the reaction of generation C at this moment occurs (in such as figure in electrode A and electrode BIt is shown), continue Maintain substance A contact with electrode A and state that substance B is contacted with electrode B reach in figure 1. shown in process, and then realization it is all and Renew cycle operation.The purpose of electro ultrafiltration is that control can come from external power supply, can come with electrochemical reaction, electro ultrafiltration is strengthened From the chemical potential in electrochemical reaction, the electric energy by storing process can be from (for example, the electricity through capacitor or oscillating circuit Can) etc..Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not lost, and is stored in electrode Place, is released together when electric current is reversed.

Embodiment 34

Fig. 3-9 show including electrode A (such as the present invention in electrochemistry region A) and electrode B (such as it is of the invention in electricity Chemical regions B), H₂And O₂It is alternately contacted and O with electrode A₂And H₂With electrode B alternately contact and also electro ultrafiltration participation work Procedure chart, chemical energy electric energy conversion method disclosed in this invention is selectively chosen to work according to following courses of work.

In Fig. 3-9,3 be electrode A, and 4 be electrode B, and 6 be interpolar spacer.The principle and process and Fig. 3-8 that this figure illustrates Shown in it is identical, only the reducing agent substance A in Fig. 3-8 is with H₂To represent, oxidant species B is with O₂For represent, reducing agent just from Sub- A⁺It is then H⁺.The purpose of electro ultrafiltration is that control can come from external power supply, can come from electrochemical reaction, electro ultrafiltration is strengthened Chemical potential in electrochemical reaction can be from the electric energy by storing process (for example, the electricity through capacitor or oscillating circuit Can) etc..Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not lost, and is stored in electrode Place, is released together when electric current is reversed.

Embodiment 35

Fig. 3-10 show including electrode A (such as the present invention in electrochemistry region A) and electrode B (such as it is of the invention in Electrochemistry region B), CH₃OH and O₂Contact and O are alternateed with electrode A₂And CH₃OH alternateed with electrode B contact and The process chart that electro ultrafiltration participates in, chemical energy electric energy conversion method disclosed in this invention are selectively chosen according to following Course of work work.

In Fig. 3-10,3 be electrode A, and 4 be electrode B, and 6 be interpolar spacer.The principle and process and Fig. 3-8 that this figure illustrates Shown in it is identical, only the reducing agent substance A in Fig. 3-8 is with CH₃OH is representative, and oxidant species B is with O₂To represent.Furthermore with Principle shown in Fig. 3-8 is compared with engineering, the principle shown in Fig. 3-10 and in the process H₂O takes part in electrochemistry as recycled material Reaction process.The purpose of electro ultrafiltration is that control can come from external power supply, can come from electricity with electrochemical reaction, electro ultrafiltration is strengthened Chemical potential in chemical reaction can be from the electric energy (for example, electric energy through capacitor or oscillating circuit) by storing process Deng.Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not lost, and is stored at electrode, It is released together when electric current is reversed.

Embodiment 36

Fig. 4-1 show including electrode A (such as the present invention in electrochemistry region A) and electrode B (such as it is of the invention in electricity Chemical regions B), O₂H is contacted with electrode A₂With electrode A makes discontinuous contact and O₂H is contacted with electrode B₂With electrode B makes discontinuous contact and And the process chart that electro ultrafiltration participates in, chemical energy electric energy conversion method disclosed in this invention are selectively chosen under State course of work work.

In Fig. 4-1,3 be electrode A, and 4 be electrode B, and 6 be interpolar spacer.In addition to reducing agent is with H₂For represent, oxidant with O₂It is outer to represent, then in addition to H₂Outside the influence of makes discontinuous contact, principle shown in Fig. 4-1 is identical as shown in Fig. 3-4 as process.It is mixed The purpose for closing object and electrode makes discontinuous contact is to reduce duration existing for reducing agent and oxidant mixture, improves safety, controllable Property and reliability.The purpose of electro ultrafiltration is that control can come from external power supply, can come from electrochemical reaction, electro ultrafiltration is strengthened Chemical potential in electrochemical reaction can be from the electric energy by storing process (for example, the electricity through capacitor or oscillating circuit Can) etc..Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not lost, and is stored in electrode Place, is released together when electric current is reversed.

Embodiment 37

Fig. 4-2 show including electrode A (such as the present invention in electrochemistry region A) and electrode B (such as it is of the invention in electricity Chemical regions B), O₂H is contacted with electrode A₂With electrode A makes discontinuous contact and O₂With electrode B makes discontinuous contact H₂Contacted with electrode B and And the process chart that electro ultrafiltration participates in, chemical energy electric energy conversion method disclosed in this invention are selectively chosen under State course of work work.

In Fig. 4-2,3 be electrode A, and 4 be electrode B, and 6 be interpolar spacer.In addition to reducing agent is with H₂For represent, oxidant with O₂It is outer to represent, then in addition to H₂、O₂Outside the influence of makes discontinuous contact, principle shown in Fig. 4-2 is identical as shown in Fig. 3-4 as process. The purpose of mixture and electrode makes discontinuous contact is to reduce duration existing for reducing agent and oxidant mixture, improves safety, can Control property and reliability.The purpose of electro ultrafiltration is that control can come from external power supply, can come with electrochemical reaction, electro ultrafiltration is strengthened From the chemical potential in electrochemical reaction, the electric energy by storing process can be from (for example, the electricity through capacitor or oscillating circuit Can) etc..Electro ultrafiltration consumes electric energy, but the electric energy consumed during electro ultrafiltration is not lost, and is stored in electrode Place, is released together when electric current is reversed.

As disposable embodiment, the present invention is aforementioned all containing the electrochemistry region A and the electrochemical school district In the specific implementation, be also selectively chosen makes the electrochemistry region A through non-electrical to the chemical energy electric energy conversion method of domain B Subband charged particle transmitter and the electrochemistry region B have non-electronic conducting electrical relation, or make the electrochemistry region A according to It is secondary that there is non-electronic conducting electrical relation through electronic conduction area and non-electronic charged particle transmitter and the electrochemistry region B, Or make the electrochemistry region A successively through non-electronic charged particle transmitter A and non-electronic charged particle transmitter B and the electricity Chemical regions B has non-electronic conducting electrical relation, or makes the electrochemistry region A successively through non-electronic charged particle transmitter A, electronic conduction area and non-electronic charged particle transmitter B and the electrochemistry region B have non-electronic conducting electrical relation, or Make the electrochemistry region A successively through electronic conduction area A, non-electronic charged particle transmitter and electronic conduction area B and the electricity Chemical regions B have non-electronic conducting electrical relation, or selectively selection make the electrochemistry region A through dielectric with it is described Electrochemistry region B have non-electronic conducting electrical relation or the electrochemistry region A through insulation, isolation space, electrolyte, At least one of dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area with it is described Electrochemistry region B is correspondingly arranged.

When the chemical energy electric energy conversion method disclosed in this invention is as the method for exchanging electric energy for chemical energy, It further selectively selects to be inserted into inertia between reducing agent and oxidant used in the chemical energy electric energy conversion method Substance and/or dead band duration.

The aforementioned all chemical energy electric energy conversion methods of the present invention during exporting electric energy and/or absorbing electric energy, Optionally use electro ultrafiltration.

The aforementioned all chemical energy electric energy conversion methods of the present invention during exporting electric energy and/or absorbing electric energy, It is selectively chosen specifically used capacitor, DC power supply, AC power source, alternating source, inductor conductor, inductance coil, band Charged particle pump, reversing switch circuit, rectifier, electric field, oscillating circuit, motor, reversible electric machine, has and adds phase converter The motor of rotary inertia or its two conjunction, its three conjunction, its four conjunction, its five conjunction, its six conjunction, its seven Conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its 11 conjunction, the conjunction of its ten binomial, its 13 conjunction, Its 14 conjunction, its 15 conjunction.

The aforementioned all chemical energy electric energy conversion methods of the present invention in the specific implementation, are selectively chosen to ginseng Apply electro ultrafiltration with the region of electrochemical reaction so that the substance for participating in electrochemical reaction be difficult to directly to carry out redox it is anti- It answers.

The aforementioned all chemical energy electric energy conversion methods containing the electrochemistry region and the region B of the present invention exist When it is implemented, be selectively chosen make electronics between the electrochemistry region and the region B export importing be Work normality.

The aforementioned all chemical energy electric energy containing the electrochemistry region A and electrochemistry region B of the present invention turn Change method in the specific implementation, be selectively chosen make electronics the electrochemistry region A and electrochemistry region B it Between export import be work normality.

The presently disclosed chemical energy electric energy conversion method comprising the electrochemistry region in the specific implementation, It further can selectively select to continue electrochemistry region state corresponding with alternating electromotive force and alternating current The course of work.

The presently disclosed chemical energy electric energy conversion method comprising the electrochemistry region A in the specific implementation, It further can selectively select to hold electrochemistry region A state corresponding with alternating electromotive force and alternating current The continuous course of work.

The presently disclosed chemical energy electric energy conversion method comprising the electrochemistry region B in the specific implementation, It further can selectively select to hold electrochemistry region B state corresponding with alternating electromotive force and alternating current The continuous course of work.

As disposable embodiment, chemical energy electric energy conversion method disclosed in this invention in the specific implementation, It is selectively chosen using the electrochemistry region as an electrode, and using electric conductor as another electrode, and makes two electricity Pole cooperating is to complete the conversion of chemical energy electric energy.It is also selectively chosen using an electrochemistry region as an electrode, Using another electrochemistry region as another electrode, and make two electrode cooperatings to complete the conversion of chemical energy electric energy.

Chemical energy electric energy conversion method disclosed in this invention in the specific implementation, further can be selected selectively with electricity The electrochemical method (such as electrochemical method for synthesizing etc.) of chemical energy can be exchanged for or exchange the electrochemical method of electric energy for chemical energy (such as fuel cell etc.), as electrochemical method for synthesizing in use, the different step that imports of the export of electronics is there may be defeated Out electric energy and absorb electric energy the case where, but its summation be absorb electric energy, as exchanged for chemical energy electric energy method (such as Fuel cell etc.) in use, the case where different step that the export of electronics imports may exist output electric energy and absorb electric energy, but Be its summation be output electric energy.

The principle of the chemical energy electric energy conversion method of the invention is described as follows:

Fig. 5-1 is the basic logic chart for exchanging electric energy for chemical energy.All are that with the process that chemical energy exchanges electric energy for Electronics is exported from reducing agent, so that reducing agent is formed reducing agent cation, electronics is then imported into reducing agent cation and oxygen again In the coexisting body of agent, and then realize that reducing agent cation, oxidant and electronics three react generation reducing agent and oxidant is anti- The product that should be generated, the summation that the electronics export during this imports is to export the process of electric energy.Fig. 5-1 is using hydrogen as also The diagram that the representative of former agent, the representative using oxygen as oxidant carry out this basic logic.

Fig. 5-2 is reducing agent oxidant electrochemical reaction controlled process figure.Reducing agent and oxidant at electrode (such as this Electrochemistry region, electrochemistry region A, electrochemistry region B in invention) reaction that could occur, it can either export electric energy Electrochemical reaction, still cannot export the reducing agent of electric energy and the direct oxidation reduction reaction of oxidant, essence is all also Former agent, oxidant and electrode act on the indispensable reaction of three, and electrode is by electro ultrafiltration reality to the effect of chemical reaction Existing.It means that can be controlled this kind of reaction by the electrical property (or electriferous state) for changing electrode.For example, such as Fruit makes electrode have electronegativity, and (ability of i.e. affine electronics is reinforced, or the energy of the affine electronics electronically formed by export Power), so that it may so that reducing agent is formed reducing agent cation process and occurs and can mistake with Accelerating reduction dosage form at reducing agent cation Journey, if electrode is made to have electropositivity, (i.e. the ability of release electronics is reinforced, or the offer electronics electronically formed by importing Ability), so that it may make oxidant react with reducing agent cation and can accelerated oxidation agent and reducing agent cation react (in other words, make oxidant formed oxidant anion process occur and can accelerated oxidation dosage form at oxidant anion mistake Journey).It is needed during electrode participates in the reducing agent of (such as catalyst participation) and oxidant directly carries out redox reaction It wants electrode i.e. not positively charged and (does not have electropositivity without negative electricity and also do not have electronegativity, not just by the electricity of itself of electro ultrafiltration Property or electronegativity are within the rule, in other words, the electronegativity of electrode and electropositivity are needed not to be changed), otherwise redox Reaction can not be carried out directly.This means that as long as the electrical property that we change electrode (changes its electropositivity, electronegativity, changes it Charging property), so that it may it avoids or weakens reducing agent and oxidant and directly carry out redox reaction heat release and lose output electric energy Process, the safety of chemical energy electric energy conversion process and controllable is carried out with the mixture for realizing using reducing agent and oxidant Property, it also may be implemented to probabilistic control caused by the mixed process being difficult to avoid that in reducing agent and oxidant handoff procedure System.Representative of the Fig. 5-2 using hydrogen as reducing agent, using oxygen as the representative of oxidant, using D as electrode (such as in the present invention Electrochemistry region, electrochemistry region A, electrochemistry region B) representative, for by electrode implement electro ultrafiltration change its electrical property And then the process for controlling chemical reaction is shown, and in figure, D⁺Indicate the electrode (ability of i.e. affine electronics with electronegativity The electrode being reinforced, i.e., because electronics is exported the electrode that its electron affinity energy power is reinforced), D^—Indicate that there is electropositive electrode (i.e. the electrode that the ability of release electronics is reinforced, i.e., because electronics is imported into the electrode that its ability for discharging electronics is reinforced).

Attached drawing of the invention is only a kind of signal, and any technical solution for meeting the application literature record belongs to the application Protection scope.

It is clear that the invention is not restricted to above embodiments, according to techniques known and technology disclosed in this invention Scheme, can derive or associate many variant schemes out, and all these variant schemes also are regarded as being protection model of the invention It encloses.

Claims

1. a kind of chemical energy electric energy conversion method, it is characterised in that: contact electrochemistry region alternately with reducing agent and oxidant Or contact reducing agent and oxidant and electrochemistry region alternately, the electrochemistry region through non-electronic charged particle transmitter, At least one of electronic conduction area and dielectric three and region B have non-electronic conducting electrical relation, using from the electricity The export of electronics between chemical regions and the region B, which imports, realizes output electric energy and/or absorption electric energy；

Or, electrochemistry region and reducing agent is made to contact with each other and make the electrochemistry region and the mutual makes discontinuous contact of oxidant, or Electrochemistry region and oxidant is set to contact with each other and make the electrochemistry region and the mutual makes discontinuous contact of reducing agent, the electrochemistry Region has non-electrical through at least one of non-electronic charged particle transmitter, electronic conduction area and dielectric three and region B Son conducting electrical relation, is imported using the export of the electronics between the electrochemistry region and the region B and realizes output electricity It can and/or absorb electric energy.

2. chemical energy electric energy conversion method as described in claim 1, it is characterised in that: the electrochemistry region is through non-electronic electrification Particle conduction object and the region B have non-electronic conducting electrical relation or the electrochemistry region successively through electronic conduction area Have non-electronic conducting electrical relation or the electrochemistry region through electricity with non-electronic charged particle transmitter and the region B Medium and the region B have non-electronic conducting electrical relation or the electrochemistry region through insulation, isolation space, electrolysis At least one of matter, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area with The region B is correspondingly arranged.

3. a kind of chemical energy electric energy conversion method, it is characterised in that: make the mixture in electrochemistry region Yu reducing agent and oxidant Contact or make the mixture of reducing agent and oxidant to contact with electrochemistry region, the electrochemistry region is through non-electronic charged particle At least one of transmitter, electronic conduction area and dielectric three and region B have non-electronic conducting electrical relation, using from The export of electronics between the electrochemistry region and the region B, which imports, realizes output electric energy and/or absorption electric energy.

4. chemical energy electric energy conversion method as claimed in claim 3, it is characterised in that: the electrochemistry region is through non-electronic electrification Particle conduction object and the region B have non-electronic conducting electrical relation or the electrochemistry region successively through electronic conduction area Have non-electronic conducting electrical relation or the electrochemistry region through electricity with non-electronic charged particle transmitter and the region B Medium and the region B have non-electronic conducting electrical relation or the electrochemistry region through insulation, isolation space, electrolysis At least one of matter, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area with The region B is correspondingly arranged.

5. a kind of chemical energy electric energy conversion method, it is characterised in that: make the mixture in electrochemistry region Yu reducing agent and oxidant Makes discontinuous contact makes the mixture of reducing agent and oxidant and electrochemistry region makes discontinuous contact, and the electrochemistry region is through non-electronic At least one of charged particle transmitter, electronic conduction area and dielectric three have non-electronic conducting electrical relation with region B, It is imported using the export of the electronics between the electrochemistry region and the region B and realizes output electric energy and/or absorption electric energy.

6. chemical energy electric energy conversion method as claimed in claim 5, it is characterised in that: the electrochemistry region is through non-electronic electrification Particle conduction object and the region B have non-electronic conducting electrical relation or the electrochemistry region successively through electronic conduction area Have non-electronic conducting electrical relation or the electrochemistry region through electricity with non-electronic charged particle transmitter and the region B Medium and the region B have non-electronic conducting electrical relation or the electrochemistry region through insulation, isolation space, electrolysis At least one of matter, dielectric, capacitor, plasma, ionic liquid, ionized gas, solion and electronic conduction area with The region B is correspondingly arranged.

7. a kind of chemical energy electric energy conversion method, it is characterised in that: contact electrochemistry region A alternately with reducing agent and oxidant Or contact reducing agent and oxidant alternately with electrochemistry region A, contact electrochemistry region B alternately with Oxidizing and Reducing Agents Or contacting Oxidizing and Reducing Agents alternately with electrochemistry region B, the electrochemistry region A is conducted through non-electronic charged particle At least one of object, electronic conduction area and dielectric three have non-electronic conducting electrical relation with the electrochemistry region B, It is imported using the export of the electronics between the electrochemistry region A and the electrochemistry region B and realizes output electric energy and/or absorption Electric energy；

Or, contacting electrochemistry region A with reducing agent and making the electrochemistry region A and oxidant makes discontinuous contact and make electrification School district domain B is contacted with reducing agent and is made the electrochemistry region B and oxidant makes discontinuous contact, or makes electrochemistry region A and oxidation Agent contacts and makes the electrochemistry region A and reducing agent makes discontinuous contact and contacts electrochemistry region B with oxidant and make institute Electrochemistry region B and reducing agent makes discontinuous contact are stated, or contacts electrochemistry region A with reducing agent and makes the electrochemistry region A With oxidant makes discontinuous contact and contact electrochemistry region B with oxidant and keep the electrochemistry region B and reducing agent interrupted Contact, the electrochemistry region A is through at least one of non-electronic charged particle transmitter, electronic conduction area and dielectric three There is non-electronic conducting electrical relation with the electrochemistry region B, utilize the electrochemistry region A and the electrochemistry region B Between electronics export import realize output electric energy and/or absorb electric energy.

8. chemical energy electric energy conversion method as claimed in claim 7, it is characterised in that: the electrochemistry region A is through non-electronic band Charged particle transmitter and the electrochemistry region B have non-electronic conducting electrical relation or the electrochemistry region A successively through electricity Son conducting area and non-electronic charged particle transmitter and the electrochemistry region B have non-electronic conducting electrical relation or described Electrochemistry region A is successively through non-electronic charged particle transmitter A and non-electronic charged particle transmitter B and the electrochemistry region B has non-electronic conducting electrical relation or the electrochemistry region A successively through non-electronic charged particle transmitter A, electronic conduction Area and non-electronic charged particle transmitter B and the electrochemistry region B have non-electronic conducting electrical relation or the electrochemistry Region A successively has through electronic conduction area A, non-electronic charged particle transmitter and electronic conduction area B and the electrochemistry region B Non-electronic conducting electrical relation or the electrochemistry region A have non-electronic electric conduction through dielectric and the electrochemistry region B Relationship or the electrochemistry region A are through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ionic liquid At least one of body, ionized gas, solion and electronic conduction area are correspondingly arranged with the electrochemistry region B.

9. a kind of chemical energy electric energy conversion method, it is characterised in that: make the mixture of electrochemistry region A Yu reducing agent and oxidant It contacts or makes the mixture of reducing agent and oxidant to contact with electrochemistry region A, make electrochemistry region B and reducing agent and oxidant Mixture contact or contact the mixture of reducing agent and oxidant with electrochemistry region B, the electrochemistry region A is through non-electrical At least one of subband charged particle transmitter, electronic conduction area and dielectric three have non-electrical with the electrochemistry region B It is defeated to import realization using the export of the electronics between the electrochemistry region A and the electrochemistry region B for son conducting electrical relation Electric energy and/or absorption electric energy out.

10. chemical energy electric energy conversion method as claimed in claim 9, it is characterised in that: the electrochemistry region A is through non-electronic band Charged particle transmitter and the electrochemistry region B have non-electronic conducting electrical relation or the electrochemistry region A successively through electricity Sub- conducting region and non-electronic charged particle transmitter and the electrochemistry region B have non-electronic conducting electrical relation or institute Electrochemistry region A is stated successively through non-electronic charged particle transmitter A and non-electronic charged particle transmitter B and the electrochemical school district There is domain B non-electronic conducting electrical relation or the electrochemistry region A successively to lead through non-electronic charged particle transmitter A, electronics Logical area and non-electronic charged particle transmitter B and the electrochemistry region B have non-electronic conducting electrical relation or the electrification School district domain A successively has through electronic conduction area A, non-electronic charged particle transmitter and electronic conduction area B and the electrochemistry region B There are non-electronic conducting electrical relation or the electrochemistry region A that there is non-electronic conducting through dielectric and the electrochemistry region B Electrical relation or the electrochemistry region A are through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ion At least one of liquid, ionized gas, solion and electronic conduction area are correspondingly arranged with the electrochemistry region B.

11. a kind of chemical energy electric energy conversion method, it is characterised in that: make the mixing of electrochemistry region A Yu reducing agent and oxidant Object makes discontinuous contact makes the mixture of reducing agent and oxidant and electrochemistry region A makes discontinuous contact, makes electrochemistry region B and reduction The mixture makes discontinuous contact of agent and oxidant makes the mixture of reducing agent and oxidant and electrochemistry region B makes discontinuous contact, institute State electrochemistry region A through at least one of non-electronic charged particle transmitter, electronic conduction area and dielectric three with it is described Electrochemistry region B has non-electronic conducting electrical relation, using between the electrochemistry region A and the electrochemistry region B The export of electronics, which imports, realizes output electric energy and/or absorption electric energy.

12. chemical energy electric energy conversion method as claimed in claim 11, it is characterised in that: the electrochemistry region A is through non-electronic There is non-electronic conducting electrical relation or the electrochemistry region A successively to pass through by charged particle transmitter and the electrochemistry region B Electronic conduction area and non-electronic charged particle transmitter and the electrochemistry region B have non-electronic conducting electrical relation or institute Electrochemistry region A is stated successively through non-electronic charged particle transmitter A and non-electronic charged particle transmitter B and the electrochemical school district There is domain B non-electronic conducting electrical relation or the electrochemistry region A successively to lead through non-electronic charged particle transmitter A, electronics Logical area and non-electronic charged particle transmitter B and the electrochemistry region B have non-electronic conducting electrical relation or the electrification School district domain A successively has through electronic conduction area A, non-electronic charged particle transmitter and electronic conduction area B and the electrochemistry region B There are non-electronic conducting electrical relation or the electrochemistry region A that there is non-electronic conducting through dielectric and the electrochemistry region B Electrical relation or the electrochemistry region A are through insulation, isolation space, electrolyte, dielectric, capacitor, plasma, ion At least one of liquid, ionized gas, solion and electronic conduction area are correspondingly arranged with the electrochemistry region B.

13. the chemical energy electric energy conversion method as described in any one of claim 1 and 2 and 7 and 8, it is characterised in that: by describedization Learn can electric energy conversion method be used as the method that electric energy is exchanged for chemical energy, used in the chemical energy electric energy conversion method and also Inert substance and/or dead band duration are inserted between former agent and oxidant.

14. the chemical energy electric energy conversion method as described in any one of claims 1 to 12, it is characterised in that: output electric energy and/ Or during absorbing electric energy, use electro ultrafiltration；Or, during exporting electric energy and/or absorbing electric energy, using capacitor, directly Galvanic electricity source, AC power source, alternating source, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch electricity Road, rectifier, electric field, oscillating circuit, motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, thirdly The conjunction of item, its four conjunction, its five conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten The conjunction of item, its 11 conjunction, the conjunction of its ten binomial, its 13 conjunction, its 14 conjunction, its 15 conjunction.

15. chemical energy electric energy conversion method as claimed in claim 13, it is characterised in that: in output electric energy and/or absorb electric energy During, use electro ultrafiltration；Or, using capacitor, DC power supply, exchange during exporting electric energy and/or absorbing electric energy Power supply, alternating source, inductor conductor, inductance coil, charged particle pump, phase converter, reversing switch circuit, rectifier, electricity Field, oscillating circuit, motor, reversible electric machine, the motor with additional rotation inertia or its two conjunction, its three conjunction, its four The conjunction of item, its five conjunction, its six conjunction, its seven conjunction, its eight conjunction, its nine conjunction, its ten conjunction, its ten One conjunction, the conjunction of its ten binomial, its 13 conjunction, its 14 conjunction, its 15 conjunction.

16. the chemical energy electric energy conversion method as described in any one of claim 1 to 12 and 15, it is characterised in that: electric to participating in The region of chemical reaction applies electro ultrafiltration, so that the substance for participating in electrochemical reaction is difficult to directly carry out redox reaction.

17. chemical energy electric energy conversion method as claimed in claim 13, it is characterised in that: applied to the region for participating in electrochemical reaction Power-up effect, so that the substance for participating in electrochemical reaction is difficult to directly carry out redox reaction.

18. chemical energy electric energy conversion method as claimed in claim 14, it is characterised in that: applied to the region for participating in electrochemical reaction Power-up effect, so that the substance for participating in electrochemical reaction is difficult to directly carry out redox reaction.

19. the chemical energy electric energy conversion method as described in any one of claim 1 to 12 and 15 and 17 and 18, it is characterised in that: It is work normality that the export of electronics, which imports,.

20. chemical energy electric energy conversion method as claimed in claim 13, it is characterised in that: it is that work is normal that the export of electronics, which imports, State.

21. chemical energy electric energy conversion method as claimed in claim 14, it is characterised in that: it is that work is normal that the export of electronics, which imports, State.

22. chemical energy electric energy conversion method as claimed in claim 16, it is characterised in that: it is that work is normal that the export of electronics, which imports, State.