CN109777199A - A kind of acid proof printing water ink and preparation method thereof - Google Patents
A kind of acid proof printing water ink and preparation method thereof Download PDFInfo
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- CN109777199A CN109777199A CN201910138041.XA CN201910138041A CN109777199A CN 109777199 A CN109777199 A CN 109777199A CN 201910138041 A CN201910138041 A CN 201910138041A CN 109777199 A CN109777199 A CN 109777199A
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Abstract
The invention discloses a kind of acid proof printing water ink and preparation method thereof.The raw material of the acid proof printing water ink is made of water soluble acrylic resin, modified poly ester lotion, dimethyl silicone polymer, bisphenol A diglycidyl ether, toner, dispersing agent, defoaming agent etc..Also disclose corresponding preparation method, i.e. by toner and dispersing agent, bisphenol A diglycidyl ether, deionized water is agitated that aqueous color paste is made, add water soluble acrylic resin, the stirring of modified poly ester lotion, it is eventually adding dimethyl silicone polymer, defoaming agent progress ultrasonic disperse and ball milling, obtains finished product after adding ethanol in proper amount.Above-mentioned acid proof printing water ink, by the way that the modified poly ester lotion being prepared through ad hoc approach is added, more stable dispersion is together formed with the water soluble acrylic resin in ink, toner, improves acid resistance, it is preferable that edition property is washed simultaneously, is suitable for practical application.
Description
Technical field
The present invention relates to printing water technical field of ink, more particularly to a kind of acid proof printing water ink
And preparation method thereof.
Background technique
In recent years, Chinese packaging association has improved the organic solvent limit standard of all kinds of packing materials, to therein 16
Kind volatile organic compounds (VOCs) is controlled, and substantially increases the environmental requirement that ink is printed in packaging industry, respectively
Local government also successively puts into effect the processing punishment for industrial organic waste exhaust gas, and range will cover the whole nation, including various medium and small
Type enterprise, this will promote relevant packaging industry to concentrate one's energy to research and develop water-base gravure ink, ask thoroughly to solve dissolvent residual
Topic.Since packaging industry maintains the leading position in industrial circle, printing packaging industry has promotion intaglio printing Water-borne modification
Conclusive effect.Water-based ink is to take water as a solvent manufactured ink, mainly by water-soluble resin, organic dyestuff, solvent
And related auxiliaries are formed through abrasive machining.Resin is most important ingredient in water-based ink, is easy propylene usually using water
Acid resin, link stuff ingredient directly affect attached function, rate of drying, preventing stick dirty performance of ink etc..Compared to oiliness and organic
Solvent-based ink, water-based ink not will cause a large amount of organic solvent volatilizations, and toxicity is low, influences on the health of direct labor
It is small.But there is also the deficiencies in performance for water-based ink, if acid resistance is poor, for this problem, the prior art rests on mostly
In terms of the formula of water-based ink, and rarely has and improve acid resistance in terms of polyester emulsion preparation.
Summary of the invention
Based on current printing water ink in terms of be not still able to satisfy consumer demand the problem of, the present invention
A kind of acid proof printing water ink and preparation method thereof is provided.
A kind of acid proof printing water ink, comprises the following raw materials by weight percent:
Water soluble acrylic resin 35~45%
Modified poly ester lotion 20~30%
Dimethyl silicone polymer 6~8%
Bisphenol A diglycidyl ether 4~6%
Toner 3~4%
Dispersing agent 0.8~1.2%
Defoaming agent 0.5~1.5%
Deionized water surplus；
Wherein, the modified poly ester lotion the preparation method comprises the following steps: into reaction kettle be added unsaturated polyester resin, vinyl
Temperature of reaction kettle is increased to 120~130 DEG C, according to 500~600 revs/min of speed by aliphatic ester, dinonylnaphthalene disulfonic acid
Rate is stirred to react 2~3 hours, is subsequently reduced to room temperature, then emulsifier is put into reaction kettle, after stirring at low speed, Xiang Fanying
Appropriate distilled water is added in kettle, at room temperature according to 1800~2200 revs/min of rate high-speed stirred speed, emulsion reaction 3
~4 hours, obtain modified poly ester lotion.
Above-mentioned acid proof printing water ink, it is more healthy with water-based ink, environmentally friendly compared to traditional printing.And
It is common with the water soluble acrylic resin in ink, toner by the way that the modified poly ester lotion being prepared through ad hoc approach is added
More stable dispersion is formd, acid resistance is improved, while it is preferable to wash edition property, is suitable for practical application.
The molecular weight of the water soluble acrylic resin is 3000~5000 in one of the embodiments,.
The unsaturated polyester resin, vinyl fatty acid ester, dinonylnaphthalene disulfonic acid in one of the embodiments,
Molar ratio is 9:4:1.
The emulsifier is alkylphenol-polyethenoxy in one of the embodiments,.
The dispersing agent is any in Tween-20, higher aliphatic and polyethylene wax in one of the embodiments,
It is a kind of.
The defoaming agent is organic silicon defoamer in one of the embodiments,.
Present invention also provides the preparation methods of above-mentioned acid proof printing water ink, comprising the following steps:
(1) high-speed mixer is added in toner, dispersing agent, bisphenol A diglycidyl ether, deionized water, according to 600~
800 revs/min of rate stirs 15~20 minutes, obtains aqueous color paste, aqueous color paste is ground through three-roller, is ground to granularity
Less than 10 μm；
(2) water soluble acrylic resin, modified poly ester lotion are added in ground aqueous color paste, are stirred evenly,
Obtain intermediate mixed liquor；
(3) the addition dimethyl silicone polymer, defoaming agent into intermediate mixed liquor, ultrasonic disperse 15~20 minutes, and place
In ball mill, high speed grinding 30~40 minutes, original print water-based ink is obtained；
(4) to the original print ethyl alcohol that add suitable concentration in water-based ink be 95%, it is stirred at room temperature 35~
45 minutes, obtain finished product printing water ink.
The raw material of the preparation method of above-mentioned printing water ink is easy to get, simple process, is suitable for large-scale industry metaplasia
It produces.
The frequency of the ultrasonic disperse is 60~62KHz in one of the embodiments,, the power of ultrasonic disperse be
1300~1500W.
The ratio of grinding media to material of the ball mill is 20:1 in one of the embodiments, and the revolving speed of ball mill is 4500~5500
Rev/min.
Compared to the prior art the present invention, has the following beneficial effects:
(1) the present invention overcomes printing water printing ink solvent volatile the problem of causing environmental pollution in the prior art,
Product Green environmental protection, will not have an adverse effect to environment.
(2) present invention makes itself and the water in ink by adding modified poly ester lotion into printing water ink raw materials
Soluble acrylic resin, toner together form more stable dispersion, improve the acid resistance of ink, while washing an edition property
Preferably, it is suitable for practical application.
Specific embodiment
In order to make the foregoing objectives, features and advantages of the present invention clearer and more comprehensible, below in conjunction with specific embodiment,
The present invention will be described in further detail.It should be appreciated that the specific embodiments described herein are only used to explain this hair
It is bright, it is not intended to limit the present invention.
Unless otherwise defined, all technical and scientific terms used herein and belong to technical field of the invention
The normally understood meaning of technical staff is identical.Term as used herein in the specification of the present invention is intended merely to description tool
The purpose of the embodiment of body, it is not intended that in the limitation present invention.Term " and or " used herein includes one or more
Any and all combinations of relevant listed item.
Raw materials used and reagent is commercially available common raw material and reagent in following embodiment.
A kind of acid proof printing water ink, comprises the following raw materials by weight percent:
Water soluble acrylic resin 35~45%
Modified poly ester lotion 20~30%
Dimethyl silicone polymer 6~8%
Bisphenol A diglycidyl ether 4~6%
Toner 3~4%
Dispersing agent 0.8~1.2%
Defoaming agent 0.5~1.5%
Deionized water surplus；
Wherein, the modified poly ester lotion the preparation method comprises the following steps: into reaction kettle be added unsaturated polyester resin, vinyl
Temperature of reaction kettle is increased to 120~130 DEG C, according to 500~600 revs/min of speed by aliphatic ester, dinonylnaphthalene disulfonic acid
Rate is stirred to react 2~3 hours, is subsequently reduced to room temperature, then emulsifier is put into reaction kettle, after stirring at low speed, Xiang Fanying
Appropriate distilled water is added in kettle, at room temperature according to 1800~2200 revs/min of rate high-speed stirred speed, emulsion reaction 3
~4 hours, obtain modified poly ester lotion.
The modified poly ester lotion being prepared through the above method, can inclusion pigment particle very well, film-formation result is excellent, and
And can cooperate with water soluble acrylic resin that can crosslink reaction in film forming, it helps to form a film, improves the acidproof of printed matter
Property, while that improves ink washes an edition property.
In a preferred embodiment, the molecular weight of the water soluble acrylic resin is 3000~5000.
In a preferred embodiment, the unsaturated polyester resin, vinyl fatty acid ester, dinonylnaphthalene disulfonic acid
Molar ratio be 9:4:1.
In a preferred embodiment, the emulsifier is alkylphenol-polyethenoxy.
In a preferred embodiment, the dispersing agent is appointing in Tween-20, higher aliphatic and polyethylene wax
It anticipates one kind.
In a preferred embodiment, the defoaming agent is organic silicon defoamer.
Present invention also provides the preparation methods of above-mentioned acid proof printing water ink, comprising the following steps:
(1) high-speed mixer is added in toner, dispersing agent, bisphenol A diglycidyl ether, deionized water, according to 600~
800 revs/min of rate stirs 15~20 minutes, obtains aqueous color paste, aqueous color paste is ground through three-roller, is ground to granularity
Less than 10 μm；
(2) water soluble acrylic resin, modified poly ester lotion are added in ground aqueous color paste, are stirred evenly,
Obtain intermediate mixed liquor；
(3) the addition dimethyl silicone polymer, defoaming agent into intermediate mixed liquor, ultrasonic disperse 15~20 minutes, and place
In ball mill, high speed grinding 30~40 minutes, original print water-based ink is obtained；
(4) to the original print ethyl alcohol that add suitable concentration in water-based ink be 95%, it is stirred at room temperature 35~
45 minutes, obtain finished product printing water ink.
In a preferred embodiment, the frequency of the ultrasonic disperse is 60~62KHz, the power of ultrasonic disperse be
1300~1500W.
In a preferred embodiment, the ratio of grinding media to material of the ball mill is 20:1, the revolving speed of ball mill is 4500~
5500 revs/min.
Below by embodiment, the present invention is furture elucidated.It should be pointed out that the present invention is not intended to be limited to the reality
Apply example.
Embodiment 1
Prepare modified poly ester lotion:
Unsaturated polyester resin, vinyl fatty acid ester, dinonylnaphthalene disulfonic acid are added into reaction kettle, kettle temperature will be reacted
Degree is increased to 120 DEG C, is stirred to react 2 hours according to 500 revs/min of rate, is subsequently reduced to room temperature, then put into reaction kettle
Emulsifier after stirring at low speed, appropriate distilled water is added into reaction kettle, at room temperature according to 1800 revs/min of rate
High-speed stirred speed emulsion reaction 3 hours, obtains modified poly ester lotion.
Raw material proportioning relationship is as follows:
Water soluble acrylic resin 35%
Modified poly ester lotion 20%
Dimethyl silicone polymer 6%
Bisphenol A diglycidyl ether 4%
Toner 3%
Dispersing agent 0.8%
Defoaming agent 0.5%
Deionized water surplus.
Prepare acid proof printing water ink:
(1) by toner, dispersing agent, bisphenol A diglycidyl ether, deionized water be added high-speed mixer, according to 600 turns/
The rate of minute stirs 15 minutes, obtains aqueous color paste, aqueous color paste is ground through three-roller, be ground to granularity less than 10 μm；
(2) water soluble acrylic resin, modified poly ester lotion are added in ground aqueous color paste, are stirred evenly,
Obtain intermediate mixed liquor；
(3) dimethyl silicone polymer, defoaming agent are added into intermediate mixed liquor, ultrasonic disperse 15 minutes, the ultrasound was divided
Scattered frequency is 60KHz, the power of ultrasonic disperse be 1300W, and place in ball mill, high speed grinding 30 minutes, ball mill
Ratio of grinding media to material is 20:1, and the revolving speed of ball mill is 4500 revs/min, obtains original print water-based ink；
(4) 35 points are stirred at room temperature with ethyl alcohol of suitable concentration for 95% is added in water-based ink to original print
Clock obtains finished product printing water ink.
Embodiment 2
Prepare modified poly ester lotion:
Unsaturated polyester resin, vinyl fatty acid ester, dinonylnaphthalene disulfonic acid are added into reaction kettle, kettle temperature will be reacted
Degree is increased to 125 DEG C, is stirred to react 2.5 hours according to 550 revs/min of rate, is subsequently reduced to room temperature, then throw into reaction kettle
Enter emulsifier, after stirring at low speed, appropriate distilled water is added into reaction kettle, at room temperature according to 2000 revs/min of speed
Rate high-speed stirred speed emulsion reaction 3.5 hours, obtains modified poly ester lotion.
Raw material proportioning relationship is as follows:
Water soluble acrylic resin 40%
Modified poly ester lotion 25%
Dimethyl silicone polymer 7%
Bisphenol A diglycidyl ether 5%
Toner 3.5%
Dispersing agent 1.0%
Defoaming agent 1.0%
Deionized water surplus.
Prepare acid proof printing water ink:
(1) by toner, dispersing agent, bisphenol A diglycidyl ether, deionized water be added high-speed mixer, according to 700 turns/
The rate of minute stirs 17.5 minutes, obtains aqueous color paste, aqueous color paste is ground through three-roller, be ground to granularity less than 10 μ
m；
(2) water soluble acrylic resin, modified poly ester lotion are added in ground aqueous color paste, are stirred evenly,
Obtain intermediate mixed liquor；
(3) the addition dimethyl silicone polymer, defoaming agent into intermediate mixed liquor, ultrasonic disperse 17.5 minutes, the ultrasound
The frequency of dispersion is 61KHz, the power of ultrasonic disperse is 1400W, and places in ball mill, high speed grinding 35 minutes, ball mill
Ratio of grinding media to material be 20:1, the revolving speed of ball mill is 5000 revs/min, obtains original print water-based ink；
(4) 40 points are stirred at room temperature with ethyl alcohol of suitable concentration for 95% is added in water-based ink to original print
Clock obtains finished product printing water ink.
Embodiment 3
Prepare modified poly ester lotion:
Unsaturated polyester resin, vinyl fatty acid ester, dinonylnaphthalene disulfonic acid are added into reaction kettle, kettle temperature will be reacted
Degree is increased to 130 DEG C, is stirred to react 3 hours according to 600 revs/min of rate, is subsequently reduced to room temperature, then put into reaction kettle
Emulsifier after stirring at low speed, appropriate distilled water is added into reaction kettle, at room temperature according to 2200 revs/min of rate
High-speed stirred speed emulsion reaction 4 hours, obtains modified poly ester lotion.
Raw material proportioning relationship is as follows:
Water soluble acrylic resin 45%
Modified poly ester lotion 30%
Dimethyl silicone polymer 8%
Bisphenol A diglycidyl ether 6%
Toner 4%
Dispersing agent 1.2%
Defoaming agent 1.5%
Deionized water surplus.
Prepare acid proof printing water ink:
(1) by toner, dispersing agent, bisphenol A diglycidyl ether, deionized water be added high-speed mixer, according to 800 turns/
The rate of minute stirs 20 minutes, obtains aqueous color paste, aqueous color paste is ground through three-roller, be ground to granularity less than 10 μm；
(2) water soluble acrylic resin, modified poly ester lotion are added in ground aqueous color paste, are stirred evenly,
Obtain intermediate mixed liquor；
(3) dimethyl silicone polymer, defoaming agent are added into intermediate mixed liquor, ultrasonic disperse 20 minutes, the ultrasound was divided
Scattered frequency is 62KHz, the power of ultrasonic disperse be 1500W, and place in ball mill, high speed grinding 40 minutes, ball mill
Ratio of grinding media to material is 20:1, and the revolving speed of ball mill is 5500 revs/min, obtains original print water-based ink；
(4) 45 points are stirred at room temperature with ethyl alcohol of suitable concentration for 95% is added in water-based ink to original print
Clock obtains finished product printing water ink.
Comparative example 1
Raw material proportioning relationship is as follows:
Water soluble acrylic resin 40%
Commercially available NovocTMWS114-30 water-soluble polyester 25%
Dimethyl silicone polymer 7%
Bisphenol A diglycidyl ether 5%
Toner 3.5%
Dispersing agent 1.0%
Defoaming agent 1.0%
Deionized water surplus.
Prepare acid proof printing water ink:
(1) by toner, dispersing agent, bisphenol A diglycidyl ether, deionized water be added high-speed mixer, according to 700 turns/
The rate of minute stirs 17.5 minutes, obtains aqueous color paste, aqueous color paste is ground through three-roller, be ground to granularity less than 10 μ
m；
(2) by water soluble acrylic resin, commercially available NovocTMWS114-30 water-soluble polyester is added to ground aqueous
It in mill base, stirs evenly, obtains intermediate mixed liquor；
(3) the addition dimethyl silicone polymer, defoaming agent into intermediate mixed liquor, ultrasonic disperse 17.5 minutes, the ultrasound
The frequency of dispersion is 61KHz, the power of ultrasonic disperse is 1400W, and places in ball mill, high speed grinding 35 minutes, ball mill
Ratio of grinding media to material be 20:1, the revolving speed of ball mill is 5000 revs/min, obtains original print water-based ink；
(4) 40 points are stirred at room temperature with ethyl alcohol of suitable concentration for 95% is added in water-based ink to original print
Clock obtains finished product printing water ink.
Performance test
To acid proof printing water ink made of embodiment 1-3, printing water ink made of comparative example 1 into
It exercises and uses performance test, and common printed use water-based ink (purchased from Yantai Heng Xing ink Co., Ltd) as compareing using commercially available
Example.Wherein, acid resistance test is executed according to GB/T 18724-2002；Washing edition property is after beating and completing the manuscript sample, with alcohol and water according to etc.
Proportions clean galley, observation cleaning difficulty, and test result is shown in Table 1.
Table 1
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Reference examples | |
| Acid resistance (for 24 hours) | 5 grades | 5 grades | 5 grades | 4 grades | 4 grades |
| Wash an edition property | Easily clean | Easily clean | Easily clean | Compared with easy cleaning | Compared with easy cleaning |
As it can be seen from table 1 prepared by acid proof printing water ink prepared by the embodiment of the present invention and comparative example
Printing water ink compare, in acid resistance and wash the aspect of edition property two and be significantly increased, be also considerably better than commercially available light water
Property printing ink.It is able to demonstrate that mentioning to ink overall performance for the modified poly ester lotion that addition is prepared by ad hoc approach of the present invention
Rising has substantial utility.It can be seen that acid proof printing water ink of the invention achieves expected technical effect,
It has a good application prospect.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously
It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that coming for those of ordinary skill in the art
It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to protection of the invention
Range.
Claims (9)
1. a kind of acid proof printing water ink, which is characterized in that comprise the following raw materials by weight percent:
Water soluble acrylic resin 35~45%
Modified poly ester lotion 20~30%
Dimethyl silicone polymer 6~8%
Bisphenol A diglycidyl ether 4~6%
Toner 3~4%
Dispersing agent 0.8~1.2%
Defoaming agent 0.5~1.5%
Deionized water surplus；
Wherein, the modified poly ester lotion the preparation method comprises the following steps: into reaction kettle be added unsaturated polyester resin, vinyl fat
Temperature of reaction kettle is increased to 120~130 DEG C, stirred according to 500~600 revs/min of rate by acid esters, dinonylnaphthalene disulfonic acid
It mixes reaction 2~3 hours, is subsequently reduced to room temperature, then put into emulsifier into reaction kettle, after stirring at low speed, into reaction kettle
Appropriate distilled water is added, at room temperature according to 1800~2200 revs/min of rate high-speed stirred speed, emulsion reaction 3~4 is small
When, obtain modified poly ester lotion.
2. acid proof printing water ink according to claim 1, which is characterized in that the water-soluble acrylic tree
The molecular weight of rouge is 3000~5000.
3. acid proof printing water ink according to claim 1, which is characterized in that the unsaturated polyester (UP) tree
Rouge, vinyl fatty acid ester, dinonylnaphthalene disulfonic acid molar ratio be 9:4:1.
4. acid proof printing water ink according to claim 1, which is characterized in that the emulsifier is alkyl phenol
Polyoxyethylene.
5. acid proof printing water ink according to claim 1, which is characterized in that the dispersing agent is tween-
20, any one in higher aliphatic and polyethylene wax.
6. acid proof printing water ink according to claim 1, which is characterized in that the defoaming agent is organosilicon
Defoaming agent.
7. a kind of preparation method of acid proof printing water ink as claimed in any one of claims 1 to 6, feature exist
In, comprising the following steps:
(1) by toner, dispersing agent, bisphenol A diglycidyl ether, deionized water be added high-speed mixer, according to 600~800 turns/
The rate of minute stirs 15~20 minutes, obtains aqueous color paste, aqueous color paste is ground through three-roller, is ground to granularity less than 10
μm；
(2) water soluble acrylic resin, modified poly ester lotion are added in ground aqueous color paste, stir evenly, obtains
Intermediate mixed liquor；
(3) the addition dimethyl silicone polymer, defoaming agent into intermediate mixed liquor, ultrasonic disperse 15~20 minutes, and place ball milling
In machine, high speed grinding 30~40 minutes, original print water-based ink is obtained；
(4) 35~45 points are stirred at room temperature with ethyl alcohol of suitable concentration for 95% is added in water-based ink to original print
Clock obtains finished product printing water ink.
8. the preparation method of acid proof printing water ink according to claim 7, which is characterized in that the ultrasound
The frequency of dispersion is 60~62KHz, the power of ultrasonic disperse be 1300~1500W.
9. the preparation method of acid proof printing water ink according to claim 7, which is characterized in that the ball milling
The ratio of grinding media to material of machine is 20:1, and the revolving speed of ball mill is 4500~5500 revs/min.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110066545A (en) * | 2019-06-03 | 2019-07-30 | 黄海滨 | A kind of fast-drying type printing water ink and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101792649A (en) * | 2009-12-25 | 2010-08-04 | 巨石集团有限公司 | Production method of unsaturated polyester emulsion binder for chopped strand mats |
| CN107033675A (en) * | 2016-11-29 | 2017-08-11 | 德阳烯碳科技有限公司 | A kind of graphene aquosity intaglio printing ink and preparation method thereof |
| CN108699383A (en) * | 2016-02-22 | 2018-10-23 | 伊士曼化工公司 | Thermosetting coating compositions |
-
2019
- 2019-02-25 CN CN201910138041.XA patent/CN109777199A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101792649A (en) * | 2009-12-25 | 2010-08-04 | 巨石集团有限公司 | Production method of unsaturated polyester emulsion binder for chopped strand mats |
| CN108699383A (en) * | 2016-02-22 | 2018-10-23 | 伊士曼化工公司 | Thermosetting coating compositions |
| CN107033675A (en) * | 2016-11-29 | 2017-08-11 | 德阳烯碳科技有限公司 | A kind of graphene aquosity intaglio printing ink and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 李子东: "《现代胶粘技术手册》", 31 January 2002, 新时代出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110066545A (en) * | 2019-06-03 | 2019-07-30 | 黄海滨 | A kind of fast-drying type printing water ink and preparation method thereof |
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