CN109755339A - Liner plate and preparation method thereof, application - Google Patents
Liner plate and preparation method thereof, application Download PDFInfo
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- CN109755339A CN109755339A CN201810186471.4A CN201810186471A CN109755339A CN 109755339 A CN109755339 A CN 109755339A CN 201810186471 A CN201810186471 A CN 201810186471A CN 109755339 A CN109755339 A CN 109755339A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
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Abstract
The present invention discloses a kind of liner plate and preparation method thereof, application.The liner plate is multilayered structure, and it includes first layer, the second layer and the middle layer between the first layer and the second layer, the first layer and the second layer are 1 layer or 1 layer or more of black glass cloth prepreg, the semi-transparent clear glassine paper prepreg that the middle layer is 1 layer or 1 layer or more.The liner plate, substrate itself are black non transparent, the technique for eliminating surface coating blacking, while improving the production efficiency, solve because of noxious material volatilization problems brought by coating blacking, reduce material cost and production cost.
Description
Technical field
The present invention relates to a kind of liner plates and preparation method thereof, application.
Background technique
Shared bicycle is announced to the world splendidly, and shares economic model for low-carbon and provides a kind of new industry situation.In order to manage and make
With conveniently, it is integrated with embedded chip, GPS module and SIM card in its vehicle body lock, provides server communication, bluetooth for bicycle
The management functions such as connection, electronic lock unlatching, vehicle location, antitheft, firmware upgrade.But if vehicle is out of power, these electronic works
It can all not be available.In order to give the GPS and sim module of very power consumption power supply, need to built-in lithium battery power supply.Due to lithium electricity
Pond is fixed in car body, the charging pile for being difficult to replace, and not fixing, while vehicle is scattered in each corner in city, thus
The power supply of shared bicycle is a very big problem.
The mode that the bicycle of early stage uses axis driving motor to generate electricity drives generator hair for battery power supply while riding
Electricity is simultaneously stored in the battery inside lock, and this axis generation mode not only reduces efficiency of riding, and wastes bicyclist
Physical strength, aggravated the physiological load of bicyclist.The drawbacks of in order to overcome axis generation mode, uses photovoltaic power generation technology,
It is exactly so-called bicycle basket solar energy generation technology.Compared with axis generation technology, bicycle basket solar energy generation technology obviously has more excellent
Point.First is that the physical strength of bicyclist is saved, second is that the bicycle that nobody shows any interest in for a long time is allowed also to be able to maintain good state of charge, third is that
Up to 25 years service lifes and zero mechanical breakdown, so that photovoltaic power generation mode has lower operating cost.Therefore, solar energy
Generation technology can allow " smart lock " to have prolonged energy to guarantee, shared bicycle can really be practiced green and pollution-free
Theory.
Existing bicycle basket solar energy generation technology is by crystal silicon battery photovoltaic module and liner plate EVA adhesive film using hot pressing
Mode is combined together, and structure is as shown in Figure 1.Herein it should be noted that liner plate used in crystal silicon battery photovoltaic module is
A kind of crystal silicon battery photovoltaic module supporting member plays physical support and undertaking effect to the installation of crystal silicon battery photovoltaic module, together
When absorb the sunlight for penetrating crystal silicon battery photovoltaic module, preventing light reflection from causing, cell photoelectric transformation efficiency reduces and light is dirty
Contaminate influence personnel sight.
As shown in Figure 1, liner plate used in the prior art has glass and colourless resin base glass fibre composite material two
Kind material.Glass material has the characteristics that intensity is high, flatness is good, big, frangible but there are weight, it is difficult to process through-hole and light
Line reflection causes the disadvantages of light pollution；Colourless resin base glass fibre composite material have intensity is high, light, easy processing through-hole and
Non-friable feature, but blacking need to be coated on surface to reduce light reflection, largely may be used since the blacking contains
Volatility toxic and harmful substance causes very major injury to human health and environment, at the same reduce production efficiency and at
This increase.
Summary of the invention
The technical problem to be solved by the present invention is in order to overcome existing glass backing plate weight big, the reflection of frangible and light
Defect and colourless resin base glass fibre composite material liner plate are because of environmental pollution, production efficiency brought by coating blacking
Lowly, light reflection and high-cost defect, and provide a kind of liner plate and preparation method thereof, application.The liner plate, substrate itself are
Black non transparent, the technique for eliminating surface coating blacking solves black because coating while improving the production efficiency
Noxious material volatilization problems, reduce material cost and production cost brought by color coating.
The present invention solves above-mentioned technical problem by the following technical programs:
The present invention provides a kind of liner plate, and the liner plate is multilayered structure, and it includes first layer, the second layer and is set to institute
The middle layer between first layer and the second layer is stated, the first layer and the second layer are 1 layer or 1 layer or more of black
Glass cloth prepreg, the semi-transparent clear glassine paper prepreg that the middle layer is 1 layer or 1 layer or more.
In the present invention, the liner plate is commonly used in support crystal silicon battery photovoltaic module.
In the present invention, the intensity of the liner plate must be enough to support crystal silicon battery photovoltaic module as known to those skilled in the art,
Preferably, the liner plate with a thickness of 0.8mm-2mm, may be, for example, 1mm.
In the present invention, preferably, the first layer is 1 layer of black glass cloth prepreg.
In the present invention, preferably, the second layer is 1 layer of black glass cloth prepreg.
In the present invention, preferably, the middle layer is the 3-20 layers of semi-transparent clear glassine paper prepreg.More preferably
Ground, the middle layer are the 3-12 layers of semi-transparent clear glassine paper prepreg.
In the present invention, the preparation method of the black glass cloth prepreg (abbreviation HBPP) can be the system of this field routine
Preparation Method after usually black coating glue is coated on E glass fabric, then is toasted.
In the present invention, preparing the coating of black used in black glass cloth prepreg glue can routinely make for this field
With the resin adhesive liquid containing black pigment, and the resin adhesive liquid generally includes following each component: epoxy resin, is urged at curing agent
Agent, inorganic filler, coupling agent, organic solvent and black pigment, and the type of above-mentioned each component and dosage can be normal for this field
Rule.
In the present invention, preparing E glass fabric used in the black glass cloth prepreg can routinely make for this field
E glass fabric, the grammes per square metre scope are generally 40-300g/m2, may be, for example, 210g/m2。
In the present invention, prepare the black glass cloth prepreg operation and condition can for this field routine operation with
Condition.Preferably, the glue-spread for preparing the coating glue of black used in the black glass cloth prepreg is 20-220g/m2,
It may be, for example, 170g/m2.Herein it should be noted that the glue-spread refers to applying on every square metre of E glass fabric
The black coating glue quality be 20-220g.
In the present invention, the preparation method of the semi-transparent clear glassine paper prepreg (abbreviation NZPP) can be normal for this field
The preparation method of rule after usually colourless coating glue is coated on E all-glass paper, then is toasted.
In the present invention, preparing colourless coating glue used in the semi-transparent clear glassine paper prepreg can be this field
It is conventional to use the resin adhesive liquid for not containing pigment, and the resin adhesive liquid generally includes following each component: epoxy resin, solidification
Agent, catalyst, inorganic filler, coupling agent and organic solvent, and the type of above-mentioned each component and dosage can be conventional for this field.
In the present invention, preparing E all-glass paper used in the semi-transparent clear glassine paper prepreg can be this field
Conventional use of E all-glass paper, the grammes per square metre scope are generally 50-150g/m2, may be, for example, 105g/m2。
In the present invention, the operation and condition for preparing the semi-transparent clear glassine paper prepreg can be this field routine
Operation and condition.Preferably, preparing the glue-spread of colourless coating glue used in the semi-transparent clear glassine paper prepreg
For 250-600g/m2, may be, for example, 395g/m2.Herein it should be noted that the glue-spread refers to every square metre of E glass
The quality of the black coating glue applied in fibrous paper is 250-600g.
In the present invention, prepares colourless coating glue used in the semi-transparent clear glassine paper prepreg and be preferably comprised
The each component of following mass fractions: 100 parts of epoxy resin, 2-30 parts of curing agent, 0.01-0.20 parts of catalyst, inorganic filler 10-
100 parts, 0.1-1 parts of coupling agent and 30-100 parts of organic solvent.More preferably, the number of the curing agent is 3-25 parts, described to urge
The number of agent is 0.03-0.07 parts, and the number of the inorganic filler is 100 parts, and the number of the coupling agent is 1 part, described
The number of organic solvent is 60 parts.Further more preferably, the number of the curing agent is 20 parts.
Wherein, the epoxy resin can be epoxy resin commonly used in the art.Preferably, the epoxy resin is double
Phenol A type epoxy resin, bisphenol f type epoxy resin, bisphenol-s epoxy resin, alicyclic ring based epoxy resin, phenol novolac epoxy tree
Rouge, o-cresol formaldehyde epoxy resin, bisphenol-A phenolic epoxy resin, resorcinol type epoxy, polyglycol type epoxy resins, bromination
Epoxy resin, polyfunctional epoxy resin, isocyanate modified epoxy resin, rubber modified epoxy resin, glycidyl amine type ring
One of oxygen resin and phosphorous epoxy resin are a variety of.More preferably, the epoxy resin be bisphenol A type epoxy resin and/or
Brominated epoxy resin, the model of the bisphenol A type epoxy resin may be, for example, NPSN901A80, and manufacturer is South Asia electronics
Material (Kunshan) Co., Ltd, the model of the brominated epoxy resin may be, for example, BEB530A80, and manufacturer is people from Changchun
Limited liability company, molding resins factory.Further more preferably, the epoxy resin is bisphenol A type epoxy resin, the bisphenol-A type ring
The model of oxygen resin may be, for example, NPSN901A80, and manufacturer is South Asia electronic material (Kunshan) Co., Ltd.
Wherein, the curing agent can be curing agent commonly used in the art.Preferably, the curing agent be dicyandiamide,
M-phenylene diamine (MPD), diaminodiphenyl-methane, diaminodiphenylsulfone, diaminodiphenyl ether, dichloro diaminodiphenyl-methane, phenol
Phenolic resin, bisphenol A phenolic resin, phosphorus containing phenolic resin, benzoxazine, xylene formaldehyde resin, Lauxite, modified phenolic
One of resin, maleic anhydride and styrene maleic anhydride copolymer are a variety of.More preferably, the curing agent is dicyandiamide
And/or phenol novolacs, the model of the phenol novolacs may be, for example, PF8020A65, manufacturer is holy well collection
Group.
Wherein, the catalyst can be catalyst commonly used in the art.Preferably, the catalyst is 2- methyl miaow
Azoles, 2-ethyl-4-methylimidazole, 2- phenylimidazole, benzyl dimethylamine, (dimethylamino methylamine) phenol of 2,4,6- tri- and borontrifluoride
One of boron mono aminoethane is a variety of.More preferably, the catalyst is 2-methylimidazole.
Wherein, the inorganic filler can be inorganic filler commonly used in the art.Preferably, the inorganic filler is two
Silica, calcium oxide, magnesia, aluminium oxide, boron oxide, aluminium hydroxide, magnesium hydroxide, barium sulfate, talcum powder, calcium carbonate, cloud
One of female powder and kaolin are a variety of.More preferably, the inorganic filler be silica, aluminium hydroxide, magnesium hydroxide and
Talcum powder.Further more preferably, the mass ratio of the silica, the aluminium hydroxide, institute's magnesium hydroxide and the talcum powder
For 1:1:1:1.
Wherein, the coupling agent can be coupling agent commonly used in the art.Preferably, the coupling agent is that silanes is even
Join agent KH-560.
Wherein, the organic solvent can be organic solvent commonly used in the art.Preferably, the organic solvent is third
One of ketone, butanone, dimethylformamide, ethylene glycol monomethyl ether and propylene glycol monomethyl ether are a variety of.More preferably, the organic solvent
For one of dimethylformamide, propylene glycol monomethyl ether and acetone or a variety of.
In the present invention, prepare black used in the black glass cloth prepreg coating glue be preferably comprised it is above-mentioned
Colourless coating glue and 5-10 parts of black pigments.Preferably, the black pigment be carbon black, it is black ink, iron oxide black, straight
Connect one of black, acid black, spirit black, nigrosine, pigment black and copper-chrome black or a variety of.More preferably, the black pigment is
Nigrosine.
The present invention also provides a kind of preparation method of liner plate above-mentioned, the preparation method includes the following steps: lamination
It is made after sub-assembly compacting, the stasck of laminations is multilayered structure, and it includes first layer, the second layer and is set to described the
Middle layer between one layer and the second layer, the first layer and the second layer are 1 layer or 1 layer or more of black glass
Cloth prepreg, the semi-transparent clear glassine paper prepreg that the middle layer is 1 layer or 1 layer or more.
In the present invention, preferably, carrying out the compacting again after the two sides covering release film of the stasck of laminations.
A kind of application the present invention also provides liner plate above-mentioned as crystal silicon battery photovoltaic module supporting member.
Without prejudice to the field on the basis of common sense, above-mentioned each optimum condition, can any combination to get the present invention it is each preferably
Example.
The reagents and materials used in the present invention are commercially available.
The positive effect of the present invention is that: the present invention provides a kind of liner plate and preparation method thereof, application.Of the invention
Liner plate, substrate itself are black non transparent, and the technique for eliminating surface coating blacking is improving the same of production efficiency
When, it solves because of noxious material volatilization problems brought by coating blacking, reduces material cost and production cost.
Detailed description of the invention
Fig. 1 shows for the structure of crystal silicon battery photovoltaic module used by bicycle basket solar power generation in the prior art and liner plate
It is intended to, the material of liner plate is glass or colourless resin base glass fibre composite material.
Fig. 2 is the structural schematic diagram of the liner plate of embodiment 1-4.
Description of symbols:
Black glass cloth prepreg 1
Black glass cloth prepreg 2
Semi-transparent clear glassine paper prepreg 3
Specific embodiment
The present invention is further illustrated below by the mode of embodiment, but does not therefore limit the present invention to the reality
It applies among a range.In the following examples, the experimental methods for specific conditions are not specified, according to conventional methods and conditions, or according to quotient
The selection of product specification.
In following embodiments, black glass cloth prepreg is referred to as HBPP；The prepreg letter of semi-transparent clear glassine paper
Referred to as NZPP.
In following embodiments, glass cloth refers to that E glass fabric, glassine paper refer to E all-glass paper.
In following embodiments, the model NPSN901A80 of bisphenol A type epoxy resin, producer is South Asia electronic material (elder brother
Mountain) Co., Ltd；The model BEB530A80 of brominated epoxy resin, producer are Changchun Artificial Resin Factory Co. Ltd.；Benzene
The model PF8020A65 of phenol phenolic resin, producer are holy well group.
The raw material and proportion (mass parts) of the coating glue of table 1
Embodiment 1
After each component mixing of the proportion 1 in table 1, with high shearing mixing emulsor high-speed stirred 5-10 minutes, it is made
Black is coated with glue.After each component mixing of the proportion 3 in table 1, with high shearing mixing emulsor high-speed stirred 5-10 minutes,
Colourless coating glue is made.
It is 210g/m that gained black coating glue and colourless coating glue, which are respectively coated in grammes per square metre,2Glass cloth and grammes per square metre
For 105g/m2Glassine paper on, after the completion of coating 150 DEG C baking 3-7 minutes, be made HBPP and NZPP, resulting HBPP grams
Weight is 380g/m2, NZPP grammes per square metre is 500g/m2。
1 HBPP, 2 NZPP, 1 HBPP are stacked gradually from bottom to up to get the stasck of laminations, by the stasck of laminations
Two sides covering release film after be sent into hot press and carry out high temperature compacting, it is cooling after to get black non transparent liner plate.The knot of the liner plate
Structure is as shown in Figure 2, wherein is followed successively by black glass cloth prepreg 1, semi-transparent clear glassine paper prepreg 3 from top to bottom
With black glass cloth prepreg 2.
Embodiment 2
After each component mixing of the proportion 1 in table 1, with high shearing mixing emulsor high-speed stirred 5-10 minutes, it is made
Black is coated with glue.After each component mixing of the proportion 5 in table 1, with high shearing mixing emulsor high-speed stirred 5-10 minutes,
Colourless coating glue is made.
It is 210g/m that gained black coating glue and colourless coating glue, which are respectively coated in grammes per square metre,2Glass cloth and grammes per square metre
For 105g/m2Glassine paper on, after the completion of coating 150 DEG C baking 3-7 minutes, be made HBPP and NZPP, resulting HBPP grams
Weight is 380g/m2, NZPP grammes per square metre is 500g/m2。
1 HBPP, 2 NZPP, 1 HBPP are stacked gradually from bottom to up to get the stasck of laminations, by the stasck of laminations
Two sides covering release film after be sent into hot press and carry out high temperature compacting, obtain black non transparent liner plate after cooling.The knot of the liner plate
Structure is as shown in Figure 2, wherein is followed successively by black glass cloth prepreg 1, semi-transparent clear glassine paper prepreg 3 from top to bottom
With black glass cloth prepreg 2.
Embodiment 3
After each component mixing of the proportion 2 in table 1, with high shearing mixing emulsor high-speed stirred 5-10 minutes, it is made
Black is coated with glue.After each component mixing of the proportion 4 in table 1, with high shearing mixing emulsor high-speed stirred 5-10 minutes,
Colourless coating glue is made.
It is 210g/m that gained black coating glue and colourless coating glue, which are respectively coated in grammes per square metre,2Glass cloth and grammes per square metre
For 105g/m2Glassine paper on, after the completion of coating 150 DEG C baking 3-7 minutes, be made HBPP and NZPP, resulting HBPP grams
Weight is 380g/m2, NZPP grammes per square metre is 500g/m2。
1 HBPP, 2 NZPP, 1 HBPP are stacked gradually from bottom to up to get the stasck of laminations, by the stasck of laminations
Two sides covering release film after be sent into hot press and carry out high temperature compacting, obtain black non transparent liner plate after cooling.The knot of the liner plate
Structure is as shown in Figure 2, wherein is followed successively by black glass cloth prepreg 1, semi-transparent clear glassine paper prepreg 3 from top to bottom
With black glass cloth prepreg 2.
Embodiment 4
After each component mixing of the proportion 2 in table 1, with high shearing mixing emulsor high-speed stirred 5-10 minutes, it is made
Black is coated with glue.After each component mixing of the proportion 6 in table 1, with high shearing mixing emulsor high-speed stirred 5-10 minutes,
Colourless coating glue is made.
It is 210g/m that gained black coating glue and colourless coating glue, which are respectively coated in grammes per square metre,2Glass cloth and grammes per square metre
For 105g/m2Glassine paper on, after the completion of coating 150 DEG C baking 3-7 minutes, be made HBPP and NZPP, resulting HBPP grams
Weight is 380g/m2, NZPP grammes per square metre is 500g/m2。
1 HBPP, 2 NZPP, 1 HBPP are stacked gradually from bottom to up to get the stasck of laminations, by the stasck of laminations
Two sides covering release film after be sent into hot press and carry out high temperature compacting, obtain black non transparent liner plate after cooling.The knot of the liner plate
Structure is as shown in Figure 2, wherein is followed successively by black glass cloth prepreg 1, semi-transparent clear glassine paper prepreg 3 from top to bottom
With black glass cloth prepreg 2.
Comparative example 1
After 3 each component of the proportion mixing in table 1, with high shearing mixing emulsor high-speed stirred 5-10 minutes, nothing is made
Color is coated with glue.
It is 210g/m that the colourless coating glue of gained, which is respectively coated in grammes per square metre,2Glass cloth and grammes per square metre be 105g/m2Glass
On paper, after the completion of coating 150 DEG C baking 3-7 minutes, semi-transparent clear glass cloth prepreg (abbreviation NBPP) and nothing is made
Color translucent glass paper prepreg (abbreviation NZPP), resulting NBPP grammes per square metre are 380g/m2, NZPP grammes per square metre is 500g/m2。
1 NBPP, 2 NZPP, 1 NBPP are stacked gradually from bottom to up to get the stasck of laminations, by the stasck of laminations
Two sides covering release film after be sent into hot press and carry out high temperature compacting, obtain semi-transparent clear liner plate after cooling.
Comparative example 2
Semi-transparent clear liner plate two sides made from comparative example 1 is coated into black ink, thickness control in 100 microns,
Then horizontal be put into 150 DEG C of baking oven is toasted about 30 minutes, is then cooled to room temperature, is obtained black non transparent liner plate.
Comparative example 3
After each component mixing of the proportion 2 in table 1, with high shearing mixing emulsor high-speed stirred 5-10 minutes, it is made
Black is coated with glue.
It is 210g/m that gained black coating glue, which is respectively coated in grammes per square metre,2Glass cloth and grammes per square metre be 105g/m2Glass
On paper, after the completion of coating 150 DEG C baking 3-7 minutes, black glass cloth prepreg (abbreviation HBPP) and black glass is made
Paper prepreg (hereinafter referred to as HZPP), resulting HBPP grammes per square metre are 380g/m2, HZPP grammes per square metre is 500g/m2。
1 HBPP, 2 HZPP, 1 HBPP are stacked gradually from bottom to up to get the stasck of laminations, by the stasck of laminations
Two sides covering release film after be sent into hot press and carry out high temperature compacting, obtain black non transparent liner plate after cooling.
The liner plate performance of 2 embodiment of table and comparative example preparation
In upper table, the detection method of appearance is visual；The detection method of thickness: IPC TM-650 2.2.18 is laminated plate thickness
Spend mechanical measurement method；The detection method of bending strength: the bending strength of IPC TM-650 2.4.4 laminate；The inspection of breakdown voltage
Survey method: the breakdown voltage of IPC TM-650 2.5.6 rigid printed board material；The detection method of comparative tracking index: GB/T
The survey of 4207 (IEC 60112:2009) solid insulating materials comparative tracking index and resistance to electric trace index in humid conditions
Determine method；The detection method of luminous transmittance: GB/T 5433-2008 domestic glass luminous transmittance measuring method.
Claims (10)
1. a kind of liner plate, which is characterized in that the liner plate be multilayered structure, and it include first layer, the second layer and be set to institute
The middle layer between first layer and the second layer is stated, the first layer and the second layer are 1 layer or 1 layer or more of black
Glass cloth prepreg, the semi-transparent clear glassine paper prepreg that the middle layer is 1 layer or 1 layer or more.
2. liner plate as described in claim 1, which is characterized in that the liner plate with a thickness of 0.8mm-2mm.
3. liner plate as described in claim 1, which is characterized in that the first layer is 1 layer of black glass cloth prepreg；
And/or the second layer is 1 layer of black glass cloth prepreg；
And/or the middle layer is the 3-20 layers of semi-transparent clear glassine paper prepreg；Wherein, preferably, the centre
Layer is the 3-12 layers of semi-transparent clear glassine paper prepreg.
4. liner plate as described in claim 1, which is characterized in that prepare E glass used in the black glass cloth prepreg
The grammes per square metre scope of fiber cloth is 40-300g/m2, preferably 210g/m2；
And/or preparing the glue-spread of the coating glue of black used in the black glass cloth prepreg is 20-220g/m2, compared with
It goodly is 170g/m2。
5. liner plate as described in claim 1, which is characterized in that prepare used in the semi-transparent clear glassine paper prepreg
The grammes per square metre scope of E all-glass paper is 50-150g/m2, preferably 105g/m2；
And/or preparing the glue-spread of colourless coating glue used in the semi-transparent clear glassine paper prepreg is 250-
600g/m2, preferably 395g/m2。
6. liner plate as described in claim 1, which is characterized in that prepare used in the semi-transparent clear glassine paper prepreg
Colourless coating glue includes each component of following mass fractions: 100 parts of epoxy resin, 2-30 parts of curing agent, catalyst 0.01-
0.20 part, 10-100 parts of inorganic filler, 0.1-1 parts of coupling agent and 30-100 parts of organic solvent；Preferably, part of the curing agent
Number is 3-25 parts, and the number of the catalyst is 0.03-0.07 parts, and the number of the inorganic filler is 100 parts, the coupling agent
Number be 1 part, the number of the organic solvent is 60 parts；More preferably, the number of the curing agent is 20 parts.
7. liner plate as claimed in claim 6, which is characterized in that the epoxy resin is bisphenol A type epoxy resin, bisphenol-f type
It is epoxy resin, bisphenol-s epoxy resin, alicyclic ring based epoxy resin, phenol novolac epoxy resins, o-cresol formaldehyde epoxy resin, double
Phenol A novolac epoxy resin, resorcinol type epoxy, polyglycol type epoxy resins, brominated epoxy resin, multi-functional epoxy tree
In rouge, isocyanate modified epoxy resin, rubber modified epoxy resin, glycidyl amine type epoxy resin and phosphorous epoxy resin
It is one or more；Preferably, the epoxy resin is bisphenol A type epoxy resin and/or brominated epoxy resin；More preferably, institute
State the model NPSN901A80 of the bisphenol A type epoxy resin and/or model BEB530A80 of the brominated epoxy resin；
And/or the curing agent is dicyandiamide, m-phenylene diamine (MPD), diaminodiphenyl-methane, diaminodiphenylsulfone, diamino two
Phenylate, dichloro diaminodiphenyl-methane, phenol novolacs, bisphenol A phenolic resin, phosphorus containing phenolic resin, benzoxazine, two
One of toluene formaldehyde resin, Lauxite, phenol-formaldehyde resin modified, maleic anhydride and styrene maleic anhydride copolymer are more
Kind；Preferably, the curing agent is dicyandiamide and/or phenol novolacs；More preferably, the model of the phenol novolacs
PF8020A65；
And/or the catalyst be 2-methylimidazole, 2-ethyl-4-methylimidazole, 2- phenylimidazole, benzyl dimethylamine, 2,4,
6- tri- (dimethylamino methylamine) one of phenol and Boron Trifluoride Ethylamine or a variety of；Preferably, the catalyst is 2- first
Base imidazoles；
And/or the inorganic filler is silica, calcium oxide, magnesia, aluminium oxide, boron oxide, aluminium hydroxide, hydroxide
One of magnesium, barium sulfate, talcum powder, calcium carbonate, mica powder and kaolin are a variety of；Preferably, the inorganic filler is two
Silica, aluminium hydroxide, magnesium hydroxide and talcum powder；More preferably, the silica, the aluminium hydroxide, the hydroxide
The mass ratio of magnesium and the talcum powder is 1:1:1:1；
And/or the coupling agent is silane coupling agent KH-560；
And/or the organic solvent is one of acetone, butanone, dimethylformamide, ethylene glycol monomethyl ether and propylene glycol monomethyl ether
Or it is a variety of；Preferably, the organic solvent is one of dimethylformamide, propylene glycol monomethyl ether and acetone or a variety of.
8. liner plate as described in claim 1, which is characterized in that prepare the painting of black used in the black glass cloth prepreg
Cloth glue includes colourless coating glue and 5-10 parts of black pigments defined in claim 6 or 7；Preferably, described black
Color pigment be carbon black, black ink, iron oxide black, directly in black, acid black, spirit black, nigrosine, pigment black and copper-chrome black
It is one or more；More preferably, the black pigment is nigrosine.
9. a kind of preparation method such as the described in any item liner plates of claim 1-8, which is characterized in that the preparation method includes
Following steps: being made after the stasck of laminations is suppressed, and the stasck of laminations is multilayered structure, and it includes first layer, second
Layer and the middle layer between the first layer and the second layer, the first layer and the second layer are 1 layer or 1
Layer or more black glass cloth prepreg, the middle layer is 1 layer or 1 layer or more of semi-transparent clear glassine paper semi-solid preparation
Piece；Wherein, preferably, carrying out the compacting again after the two sides covering release film of the stasck of laminations.
10. a kind of such as application of the described in any item liner plates of claim 1-8 as crystal silicon battery photovoltaic module supporting member.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810186471.4A CN109755339A (en) | 2018-03-07 | 2018-03-07 | Liner plate and preparation method thereof, application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810186471.4A CN109755339A (en) | 2018-03-07 | 2018-03-07 | Liner plate and preparation method thereof, application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109755339A true CN109755339A (en) | 2019-05-14 |
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| CN201810186471.4A Pending CN109755339A (en) | 2018-03-07 | 2018-03-07 | Liner plate and preparation method thereof, application |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110588116A (en) * | 2019-09-04 | 2019-12-20 | 重庆德凯实业股份有限公司 | Flame-retardant heat-resistant copper foil-coated epoxy glass fiber cloth-based laminated board and preparation method thereof |
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