CN109705764A - A kind of release cloth base adhesive tape of Novel free and preparation method thereof - Google Patents

A kind of release cloth base adhesive tape of Novel free and preparation method thereof Download PDF

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Publication number
CN109705764A
CN109705764A CN201910037955.7A CN201910037955A CN109705764A CN 109705764 A CN109705764 A CN 109705764A CN 201910037955 A CN201910037955 A CN 201910037955A CN 109705764 A CN109705764 A CN 109705764A
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China
Prior art keywords
layer
release
adhesive tape
cloth base
novel free
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Pending
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CN201910037955.7A
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Chinese (zh)
Inventor
蔡振乐
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Jiangsu Jinghua New Materials Technology Co Ltd
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Jiangsu Jinghua New Materials Technology Co Ltd
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Priority to CN201910037955.7A priority Critical patent/CN109705764A/en
Publication of CN109705764A publication Critical patent/CN109705764A/en
Pending legal-status Critical Current

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Abstract

A kind of release cloth base adhesive tape of Novel free, including PE release layer, PE coating layer, gauze substrate layer and the hot melt adhesive layer being successively arranged, the PE release layer weight percentage of each component are as follows: PE 97%-99%, the special release additive 1%-3% of non-silicon.The separation cloth that is formed is used directly for being coated with after the present invention passes through overlay film, can save release process together, improve efficiency, reduce release equipment, solves release coating process and hold since high temperature generates to shrink, and causes gluing coating to crumple or a series of problems, such as glue surface fold;By the way of secondary overlay film, in the PE of first time overlay film, a certain proportion of filler material etc. is added in the case where not influencing the condition of production, the cost of first time overlay film can be reduced, by adjusting the total PE amount ratio of second of overlay film Zhan, overlay film cost can be reduced, and do not influence overall use.

Description

A kind of release cloth base adhesive tape of Novel free and preparation method thereof
Technical field
The present invention relates to a kind of cloth base adhesive tape and preparation method thereof more particularly to a kind of release cloth base adhesive tape of Novel free and its Preparation method.
Background technique
Cloth base adhesive tape is that substrate is complex as with the heat of polyethylene and scrim fiber, apply high viscosity synthetic glue, and with it is two-sided Release paper is combined.There are stronger peeling force, stretching resistance, grease resistance, ageing-resistant, heatproof, waterproof, anticorrosion, is a kind of exhausted The high adhesive tape of edge.Cloth base adhesive tape is mainly used for that carton is sealed, carpet seam is merged, heavy type is tied up, waterproofing packing etc..Exist at present It is also frequently used in automobile industry, electromechanical industries, it is preferably local for waterproof measures such as automobile cab, cabinet, cabinets, easily It is processed in cross cutting.
The structure of common cloth base adhesive tape is currently on the market: first in the laminating PE film of one side of gauze, then in PE film One layer of interleaving agent of surface coating, another side one layer of adhesive of coating of last gauze.In the cloth base adhesive tape of this structure The binding strength of gauze and PE film is bad, influences following process.Especially latitude and longitude are covered than sparse gauze, gauze with PE film It gently will appear stripping phenomenon (i.e. gauze and UF membrane) once rubbing with the hands with finger after conjunction, have an adverse effect to following process.Feelings Condition is serious, also will affect the service performance of finished products of adhesive tapes, such as: occur demoulding, rupture of membranes when adhesive tape uncoiling, adhesive tape is not easy to tear, Or the yarn abjection of tape edge generates the bad phenomenons such as flash when tear fracture.
In addition, since polyethylene itself does not have release performance, existing cloth base film-coated fabrics generally after coating processes, It needs plus the release process in road, i.e., by the coating of release liquid, formation cloth base separation cloth after oven cooking cycle, its is release under normal circumstances Unstable, moisture resistance is poor, and polyethylene, when contacting higher oven cooking cycle, coating process is easy to shrink, and gluing coating is caused to beat A series of problems, such as wrinkle or glue surface fold.
Summary of the invention
In order to solve the above technical problem, the present invention provides a kind of type release-free cloth base adhesive tapes and preparation method thereof, have Release stabilization improves efficiency, reduces the features such as cost and reduction process.
The technical solution adopted by the present invention to solve the technical problems are as follows:
A kind of release cloth base adhesive tape of Novel free, including PE release layer, PE coating layer, gauze substrate layer and the heat being successively arranged Melt layer, the PE release layer weight percentage of each component are as follows: PE 97%-99%, the special release additive 1%-3% of non-silicon.
Further, the PE coating layer is the mixing for adding the PE material or high density PE and low density PE of filler material Material.
Further, the hot melt adhesive layer weight percentage of each component are as follows: thermoplastic elastomer (TPE) 20-30%, softening oil 15- 20%, resin 40-50%, antioxidant 0.5-1.5%, filler material 5-15%.
Further, the gauze substrate layer is cotton, one of washs with elastic filament.
Further, the lamination amount of the PE release layer is 20-40g/m2
Further, the lamination amount of the PE coating layer is 50-80g/m2
Further, the hot melt adhesive layer coating weight is 70-120g/m2
A kind of preparation method of the release cloth base adhesive tape of Novel free the following steps are included:
Step 1: getting out gauze substrate layer, PE covering material, PE separated type material and hot melt adhesive;
Step 2: by squeezing out lamination mode, covering one layer of PE covering material in the one side leaching of the gauze substrate layer, formed The PE coating layer;
Step 3: by squeezing out lamination mode, one layer of PE separated type material is covered in leaching on the PE coating layer, forms the PE Release layer;
Step 4: being coated with one layer of hot melt adhesive in the another side of the gauze substrate layer, the hot melt adhesive layer is formed, after dry Obtain the release cloth base adhesive tape of the Novel free.
The invention has the advantages that:
It is used directly for being coated with by the separation cloth formed after overlay film, release process together can be saved, improve efficiency, subtract Few release equipment solves release coating process and holds since high temperature generates to shrink, and gluing coating is caused to crumple or glue surface fold etc. one Series of problems;By the way of secondary overlay film, in the PE of first time overlay film, certain proportion is added in the case where not influencing the condition of production Filler material etc., the cost of first time overlay film can be reduced, by adjusting the total PE amount ratio of second of overlay film Zhan, can reduce overlay film at This, and overall use is not influenced.
Detailed description of the invention
Fig. 1 is a kind of structural schematic diagram of the release cloth base adhesive tape of Novel free of the present invention.
Specific embodiment
In order to more fully understand technology contents of the invention, in the following with reference to the drawings and specific embodiments to skill of the invention Art scheme is described further and illustrates.
Embodiment 1
Take the pure elastic filament gauze substrate layer of 50 mesh, weight percentage of each component are as follows: the PE of LDPE 80%, filler material 20% Covering material, weight percentage of each component are as follows: the PE separated type material of the release additive 1% of special non-silicon, PE 99%, each component Weight percent are as follows: thermoplastic elastomer (TPE) 30%, softening oil 20%, resin 48.5%, antioxidant 1.5%, the heat of filler material 5% Melten gel.
In the one side of above-mentioned gauze substrate layer 3, through hot melt screw rod in a manner of squeezing out, one layer of PE covering material is covered in leaching, The leaching amount of covering is 80g/m2, PE coating layer 2 is formed, and by equipment complex, gauze substrate layer 3 and PE coating layer 2 is compound;Pass through Lamination mode is squeezed out, one layer of above-mentioned PE separated type material is covered on the PE coating layer 2, the leaching amount of covering is 20g/m2, formed PE from Type layer 1;One layer of hot melt adhesive, coating weight 100g/m are coated in the another side of the gauze substrate layer 32, hot melt adhesive layer 4 is formed, The release cloth base adhesive tape of Novel free is obtained after drying.
Embodiment 2
Take the pure elastic filament gauze substrate layer of 50 mesh, weight percentage of each component are as follows: the PE of LDPE 80%, filler material 20% Covering material, weight percentage of each component are as follows: the PE separated type material of the release additive 2% of special non-silicon, PE 98%, each component Weight percent are as follows: thermoplastic elastomer (TPE) 30%, softening oil 20%, resin 48.5%, antioxidant 1.5%, the heat of filler material 5% Melten gel.
In the one side of above-mentioned gauze substrate layer 3, through hot melt screw rod in a manner of squeezing out, one layer of PE covering material is covered in leaching, The leaching amount of covering is 70g/m2, PE coating layer 2 is formed, and by equipment complex, gauze substrate layer 3 and PE coating layer 2 is compound;Pass through Lamination mode is squeezed out, one layer of above-mentioned PE separated type material is covered on the PE coating layer 2, the leaching amount of covering is 30g/m2, formed PE from Type layer 1;One layer of hot melt adhesive, coating weight 100g/m are coated in the another side of the gauze substrate layer 32, hot melt adhesive layer 4 is formed, The release cloth base adhesive tape of Novel free is obtained after drying.
Embodiment 3
Take the pure elastic filament gauze substrate layer of 50 mesh, weight percentage of each component are as follows: LDPE80%, filler material 20% PE cover Membrane material, weight percentage of each component are as follows: the PE separated type material of the release additive 3% of special non-silicon, PE 97%, each component weight Measure percentage are as follows: thermoplastic elastomer (TPE) 30%, softening oil 20%, resin 48.5%, antioxidant 1.5%, the hot melt of filler material 5% Glue.
In the one side of above-mentioned gauze substrate layer 3, through hot melt screw rod in a manner of squeezing out, one layer of PE covering material is covered in leaching, The leaching amount of covering is 60g/m2, PE coating layer 2 is formed, and by equipment complex, gauze substrate layer 3 and PE coating layer 2 is compound;Pass through Lamination mode is squeezed out, one layer of above-mentioned PE separated type material is covered on the PE coating layer 2, the leaching amount of covering is 40g/m2, formed PE from Type layer 1;One layer of hot melt adhesive, coating weight 100g/m are coated in the another side of the gauze substrate layer 32, hot melt adhesive layer 4 is formed, The release cloth base adhesive tape of Novel free is obtained after drying.
Embodiment 4
Take the pure elastic filament gauze substrate layer of 50 mesh, weight percentage of each component are as follows: the PE of LDPE 80%, filler material 20% Covering material, weight percentage of each component are as follows: the PE separated type material of the release additive 2% of special non-silicon, PE 98%, each component Weight percent are as follows: thermoplastic elastomer (TPE) 30%, softening oil 20%, resin 48.5%, antioxidant 1.5%, the heat of filler material 5% Melten gel.
In the one side of above-mentioned gauze substrate layer 3, through hot melt screw rod in a manner of squeezing out, one layer of PE covering material is covered in leaching, The leaching amount of covering is 80g/m2, PE coating layer 2 is formed, and by equipment complex, gauze substrate layer 3 and PE coating layer 2 is compound;Pass through Lamination mode is squeezed out, one layer of above-mentioned PE separated type material is covered on the PE coating layer 2, the leaching amount of covering is 20g/m2, formed PE from Type layer 1;One layer of hot melt adhesive, coating weight 100g/m are coated in the another side of the gauze substrate layer 32, hot melt adhesive layer 4 is formed, The release cloth base adhesive tape of Novel free is obtained after drying.
Embodiment 5
Take the pure elastic filament gauze substrate layer of 50 mesh, weight percentage of each component are as follows: the PE of LDPE 80%, filler material 20% Covering material, weight percentage of each component are as follows: the PE separated type material of the release additive 3% of special non-silicon, PE 97%, each component Weight percent are as follows: thermoplastic elastomer (TPE) 30%, softening oil 20%, resin 48.5%, antioxidant 1.5%, the heat of filler material 5% Melten gel.
In the one side of above-mentioned gauze substrate layer 3, through hot melt screw rod in a manner of squeezing out, one layer of PE covering material is covered in leaching, The leaching amount of covering is 80g/m2, PE coating layer 2 is formed, and by equipment complex, gauze substrate layer 3 and PE coating layer 2 is compound;Pass through Lamination mode is squeezed out, one layer of above-mentioned PE separated type material is covered on the PE coating layer 2, the leaching amount of covering is 20g/m2, formed PE from Type layer 1;One layer of hot melt adhesive, coating weight 100g/m are coated in the another side of the gauze substrate layer 32, hot melt adhesive layer 4 is formed, The release cloth base adhesive tape of Novel free is obtained after drying.
Experimental comparison's example
It is compared below by by above-mentioned five embodiments with existing preparation process, in prior art, using traditional PE coating layer, and by the release process in another road and one of coating process, it is formed a kind of comprising release layer, PE layers, gauze base Traditional cloth base adhesive tape of material layer, hot melt adhesive layer.
Since traditional release cloth rubber belt of cloth base needs to add release process together, yield is reduced, only 90-92%, and this Only to include that overlay film is release be formed by the release cloth rubber belt of cloth base to a procedure for invention, and yield is up to 94% or more.Complete release work Room temperature is needed after sequence, and left and right cools down for 24 hours, and the cloth base PE film as caused by high temperature is avoided to be detached from gauze;And reduce by one of work Standing time can be greatly lowered in the release cloth base adhesive tape of the Novel free of sequence, improve efficiency.Release process causes separation cloth to receive simultaneously Situations such as contracting, also can avoid.A traditional overlay film is not necessarily to release novel cloth base adhesive tape if you need to be made, and special non-silicon is release The used in amounts of additive increases substantially, and added special non-silicon mould release price is up to 1000 yuan/kg in case column, by most Good 2% addition, is calculated, every square of covering material cost need to be up to 2.96 yuan by 100g/m2 overlay film amount;And after using secondary overlay film, Special mould release PE layers of accounting 20% is being added, in addition filler material adding proportion is 20% in accounting 80% a coating layer, Total every square of covering material cost of accounting is 1.02 yuan, and material cost can be greatly reduced.
The adding proportion of the special non-silicon mould release of embodiment 1 is 1%, and gauze selects the pure elastic filament gauze of 50 mesh, addition The total PE ratio of special non-silicon mould release PE coating layer Zhan is 20%.It is good to wind parent roll the thickness uniformity.The detection of standard rubber band is release Power is 500-700kg/25mm (whether unit is mistaken), and uncoiling is normal after gluing, and release slightly heavy, separation cloth yield is 95.6%, it is at low cost.
The adding proportion of the special non-silicon mould release of embodiment 2 is 2%, and gauze selects the pure elastic filament gauze of 50 mesh, addition The total PE ratio of special non-silicon mould release PE coating layer Zhan is 30%.It is good to wind parent roll the thickness uniformity.The detection of standard rubber band is release Power is 520-700kg/25mm, and uncoiling is normal after gluing, release slightly heavy, and separation cloth yield is 97%, and cost is placed in the middle.
The adding proportion of the special non-silicon mould release of embodiment 3 is 3%, and gauze selects the pure elastic filament gauze of 50 mesh, addition The total PE ratio of special non-silicon mould release PE coating layer Zhan is 40%.It is good to wind parent roll the thickness uniformity.The detection of standard rubber band is release Power is 400-600kg/25mm, and uncoiling is normal after gluing, release normal, and separation cloth yield is 94.7%, at high cost.
The adding proportion of the special non-silicon mould release of embodiment 4 is 2%, and gauze selects the pure elastic filament gauze of 50 mesh, addition The total PE ratio of special non-silicon mould release PE coating layer Zhan is 20%.It is good to wind parent roll the thickness uniformity.The detection of standard rubber band is release Power is 500-700kg/25mm, and uncoiling is normal after gluing, release normal, and separation cloth yield is 96%, at low cost.
The adding proportion of the special non-silicon mould release of embodiment 5 is 3%, and gauze selects the pure elastic filament gauze of 50 mesh, addition The total PE ratio of special non-silicon mould release PE coating layer Zhan is 20%.It is good to wind parent roll the thickness uniformity.The detection of standard rubber band is release Power is 250-500kg/25mm, and uncoiling is normal after gluing, release relatively light, and separation cloth yield is 95.2%, and cost is placed in the middle.
Above-mentioned release force test method are as follows:
A size is taken to be at least 450 millimeters long, Novel free separation cloth base obtained by the embodiment 1-5 of 250 mm wides Standard rubber band is gently overlaid on the PE release layer of the release cloth base adhesive tape of Novel free with finger by adhesive tape along the direction that mould release is coated with On 1.Test bars are cut along mould release coating direction, batten is 175 millimeters long, 25 millimeters wide, and notch wants clean, straight.With FINAT tests pressure roller with 10 millimeters of speed about per second, and roll-in sample 2 times back and forth.Test bars are placed on two blocks of metals Between item or glass plate, batten is subjected to the pressure of 6.86 kPas (70 grams/cm), small in 25 DEG C of at a temperature of holding 20 When, guarantee that standard rubber band comes into full contact with PE release layer 1.Then, batten is taken out, relative humidity be 50%, temperature 25 DEG C standard environment at least place 4 hours after, do peel test force.Tested batten is fixed on test equipment, is set Instrument peeling rate be it is 300 millimeters per minute, peel angle is 180 ° under conditions of adhesive tape removed from release layer 1, instrument During the test, to each batten interlude every 10 millimeters of readings, one data, each batten at least reads 5 numbers to device According to being averaged later to the data obtained.
To sum up, above five embodiments are covered using the adjustment of the release additive adding proportion of special non-silicon by squeezing out Film carries out overlay film to identical gauze, and hot melt glue uses identical constituent, and data are shown, relatively traditional gluing, yield Height reduces process.
Really, above-described embodiment is better embodiment in the present invention, other are any to be less than the protected model of the present invention The embodiment enclosed will be all included within protection scope of the present invention.
Although for illustrative purposes, the preferred embodiment of the present invention is had been disclosed, but the ordinary skill people of this field Member will realize without departing from the scope and spirit of the invention as disclosed by the appended claims, various to change Into, increase and replace be possible.

Claims (8)

1. a kind of release cloth base adhesive tape of Novel free, including PE release layer, PE coating layer, gauze substrate layer and the hot melt being successively arranged Glue-line, which is characterized in that the PE release layer weight percentage of each component are as follows: PE97%-99%, the special release additive of non-silicon 1%-3%.
2. the release cloth base adhesive tape of Novel free according to claim 1, which is characterized in that the PE coating layer is addition filling The PE material of material or the mixing material of high density PE and low density PE.
3. the release cloth base adhesive tape of Novel free according to claim 1, which is characterized in that the hot melt adhesive layer each component weight Percentage are as follows: thermoplastic elastomer (TPE) 20-30%, softening oil 15-20%, resin 40-50%, antioxidant 0.5-1.5%, filler material 5-15%.
4. the release cloth base adhesive tape of Novel free according to claim 1, which is characterized in that the gauze substrate layer is cotton, washs One of with elastic filament.
5. the release cloth base adhesive tape of Novel free according to claim 1, which is characterized in that the lamination amount of the PE release layer is 20-40g/m2
6. the release cloth base adhesive tape of Novel free according to claim 1, which is characterized in that the lamination amount of the PE coating layer is 50-80g/m2
7. the release cloth base adhesive tape of Novel free according to claim 1, which is characterized in that the hot melt adhesive layer coating weight is 70-120g/m2
8. a kind of preparation method of the release cloth base adhesive tape of Novel free, which comprises the following steps:
Step 1: getting out gauze substrate layer, PE covering material, PE separated type material and hot melt adhesive;
Step 2: by squeezing out lamination mode, being drenched in the one side of the gauze substrate layer and cover one layer of PE covering material, described in formation PE coating layer;
Step 3: by squeezing out lamination mode, one layer of PE separated type material is covered in leaching on the PE coating layer, and it is release to form the PE Layer;
Step 4: being coated with one layer of hot melt adhesive in the another side of the gauze substrate layer, form the hot melt adhesive layer, after drying to obtain the final product To the release cloth base adhesive tape of the Novel free.
CN201910037955.7A 2019-01-15 2019-01-15 A kind of release cloth base adhesive tape of Novel free and preparation method thereof Pending CN109705764A (en)

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Publication number Priority date Publication date Assignee Title
CN110305598A (en) * 2019-08-05 2019-10-08 河北来利翼腾塑胶制造有限公司 A kind of cloth base adhesive tape and its production technology
CN111647369A (en) * 2020-07-06 2020-09-11 江苏晶华新材料科技有限公司 Printing-free warning adhesive tape and preparation process thereof
CN115213069A (en) * 2022-06-16 2022-10-21 河北益碧固化科技有限公司 Double-layer cloth-based adhesive tape and preparation method thereof

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CN110305598A (en) * 2019-08-05 2019-10-08 河北来利翼腾塑胶制造有限公司 A kind of cloth base adhesive tape and its production technology
CN111647369A (en) * 2020-07-06 2020-09-11 江苏晶华新材料科技有限公司 Printing-free warning adhesive tape and preparation process thereof
CN115213069A (en) * 2022-06-16 2022-10-21 河北益碧固化科技有限公司 Double-layer cloth-based adhesive tape and preparation method thereof

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Application publication date: 20190503