CN106318245B - A kind of flame retardant type one-faced tapes and its preparation process - Google Patents
A kind of flame retardant type one-faced tapes and its preparation process Download PDFInfo
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- CN106318245B CN106318245B CN201610656755.6A CN201610656755A CN106318245B CN 106318245 B CN106318245 B CN 106318245B CN 201610656755 A CN201610656755 A CN 201610656755A CN 106318245 B CN106318245 B CN 106318245B
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J121/00—Adhesives based on unspecified rubbers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/04—Homopolymers or copolymers of ethene
- C09J123/08—Copolymers of ethene
- C09J123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09J123/0853—Vinylacetate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J145/00—Adhesives based on homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic system; Adhesives based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J193/00—Adhesives based on natural resins; Adhesives based on derivatives thereof
- C09J193/04—Rosin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/241—Polyolefin, e.g.rubber
- C09J7/243—Ethylene or propylene polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/25—Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/25—Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/255—Polyesters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2421/00—Presence of unspecified rubber
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09J2423/00—Presence of polyolefin
- C09J2423/04—Presence of homo or copolymers of ethene
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2423/00—Presence of polyolefin
- C09J2423/10—Presence of homo or copolymers of propene
- C09J2423/106—Presence of homo or copolymers of propene in the substrate
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2467/00—Presence of polyester
- C09J2467/006—Presence of polyester in the substrate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2479/00—Presence of polyamine or polyimide
- C09J2479/08—Presence of polyamine or polyimide polyimide
- C09J2479/086—Presence of polyamine or polyimide polyimide in the substrate
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
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Abstract
The present invention provides a kind of flame retardant type one-faced tapes comprising, base membrane layer is in lamella membrane structure;Printing layer, for coated on the ink on the base membrane layer;Adhesive layer, it is adhered in the printing layer, the adhesive layer includes double-layer structure: first layer is the thickening glue film for being adhered to the printing layer surface, the thickening glue film includes the EVA resin glue film of Surface Modification of Magnesium Hydroxide by Stearic Acid in, and stearic acid mass percentage is 5.5%~6.5% in the Surface Modification of Magnesium Hydroxide by Stearic Acid;The second layer is the tackifying resin for being applied to the grain of frosted containing magnesium hydroxide of first layer surface, and the tackifying resin is one of rosin resin, terpene phenol resin or rubber, and the magnesium hydroxide frosted grain partial size is 500~2000 μm;Separation layer, is in membrane structure, and the separation layer is pasted on the tie layer surface.The flame retardant type one-faced tapes excellent fireproof performance as made from corresponding preparation method, caking property is strong, can effectively improve tensile strength and breaking strength.
Description
Technical field
The present invention relates to adhesive tape area, in particular to a kind of flame retardant type one-faced tapes and its preparation process.
Background technique
Currently, one-faced tapes are widely used in electronic field, with the development of electronics industry, traditional one-faced tapes are
It is not able to satisfy the needs of electronic product.Often type is single for existing one-faced tapes, and intensity is lower, is directed to different product shortage
Property design.
Summary of the invention
It is excellent it is an object of the invention to solve at least the above problems and/or defect, and provide at least to will be described later
Point.
It is a still further object of the present invention to provide a kind of flame retardant type one-faced tapes and its preparation processes, prepare a kind of with spy
The one-faced tapes of different structure and performance.
In order to realize these purposes and other advantages according to the present invention, a kind of flame retardant type one-faced tapes are provided comprising,
Base membrane layer is in lamella membrane structure;
Printing layer, for coated on the ink on the base membrane layer;
Adhesive layer is adhered in the printing layer, and the adhesive layer includes double-layer structure: first layer is to be adhered to the print
The thickening glue film on brush layer surface, the thickening glue film includes the EVA resin glue film of Surface Modification of Magnesium Hydroxide by Stearic Acid in, described
Stearic acid mass percentage is 5.5%~6.5% in Surface Modification of Magnesium Hydroxide by Stearic Acid;The second layer is to be applied to the first layer table
The tackifying resin of the grain of frosted containing magnesium hydroxide in face, the tackifying resin are one in rosin resin, terpene phenol resin or rubber
Kind, the magnesium hydroxide frosted grain partial size is 500~2000 μm;
Separation layer, is in membrane structure, and the separation layer is pasted on the tie layer surface;
Wherein, Surface Modification of Magnesium Hydroxide by Stearic Acid described in the first layer account for EVA resin glue film mass percent be 3~
8%.
Preferably, wherein the base membrane layer selection includes polyethylene terephthalate, polyimides or two-way drawing
One of polypropylene stretched film.
Preferably, wherein the polyethylene terephthalate base membrane layer color is transparent, white or black;Institute
Transparent polyethylene terephthalate base membrane layer is stated with a thickness of 2 ± 1 μm, 4.5 ± 1 μm, 9 ± 1 μm, 12 ± 1 μm or 20 ± 1 μ
m;The white polyethylene terephthalate base membrane layer is with a thickness of 12 ± 1 μm, 25 ± 1 μm or 30 ± 1 μm;The black is poly-
Ethylene glycol terephthalate base membrane layer is with a thickness of 25 ± 1 μm or 50 ± 1 μm.
Preferably, wherein the polyimide-based film layer color is amber or black;The amber polyimides
Base membrane layer is with a thickness of 12.5 ± 1 μm or 20 ± 1 μm;The black polyamide base membrane layer is with a thickness of 15 ± 1 μm or 20 ± 1 μm.
Preferably, wherein the bidirectional stretching polypropylene film base membrane layer color is transparent, the biaxial stretching polypropylene
Alkene film base membrane layer is with a thickness of 12 ± 1 μm or 15 ± 1 μm.
Preferably, wherein the printing layer is by mass percentage, comprising:
Principal component, is polyester resin and polyurethane resin mixture, and the amount that the polyester resin accounts for overall resin is no less than
25%, the principal component accounts for the 70%~83% of printing layer gross mass;
Filler, is carbon black or white carbon black, and the filler accounts for the 15~25% of overall amount of resin;
Dispersing agent, is polyethylene glycol, and the dispersing agent accounts for the 0.5~3% of overall amount of resin;
Defoaming agent, is high temperature defoaming agent, and the defoaming agent accounts for the 0.5~3% of overall number quality;
Wherein, the dispersing agent and defoaming agent account for overall amount of resin no more than 5%.
Preferably, wherein packing material size≤4 μm.
Preferably, wherein the tackifying resin further includes solvent, and the solvent moisture content is less than 200ppm, and chemistry is pure
Degree is greater than 99%.
Preferably, wherein the separation layer selects one of release film or release paper.
This case additionally provides a kind of preparation method for preparing flame retardant type one-faced tapes, is made by following steps,
1) it prepares base membrane layer: choosing in polyethylene terephthalate, polyimides or bidirectional stretching polypropylene film
One kind, unreel, successively pass through 150 mesh, 150 mesh, 175 mesh, the specific net roll one-pass molding of 175 purposes, be made base membrane layer;It is described
Net roll surface sets the angle of 120 ° of engraving needles engraving as 45 ° of diamond shape ink cell, and the space of a whole page is uniform, and chromium plating again is carved after halftone copper facing;
2) it prepares printing layer: one layer of ink being coated in the base membrane layer first surface using rubber roller, is 75 through temperature
DEG C drying tunnel, intake 60%, exhausting amount be 75%, be made printing layer;The ink is uniformly dispersed, big without obvious leakage bletilla
Particle agglomeration, glossiness fluctuate within ± 0.3;The ink stirs 30min through 1000~1200r/min, and uses 300 mesh
Strainer filtering is made;
3) prepare adhesive layer: by include mass percent be 3~8% Surface Modification of Magnesium Hydroxide by Stearic Acid sheet EVA
Resin glue film is adhered to step 2) printing layer surface obtained;The sheet EVA resin glue film is carried out using precision funny knife
Gluing, it is between 60~70 ° that the sheet EVA resin glue film, which requires shore hardness, and institute's gluing is the grain of frosted containing magnesium hydroxide
Tackifying resin, the tackifying resin is one of rosin resin, terpene phenol resin or rubber, the magnesium hydroxide frosted grain
500~2000 μm of partial size;
4) flame retardant type one-faced tapes are prepared: step 3) products obtained therefrom is placed in drying, Yu Suoshu adhesive layer in 110 DEG C of drying tunnels
Surface is bonded isolated material, and flame retardant type one-faced tapes are made.
Flame retardant type one-faced tapes disclosed by the invention and its preparation process's the utility model has the advantages that 1) increasing this by printing layer
The aesthetic appearance of flame retardant type one-faced tapes;2) the adhesive tape adhesion strength is improved by adhesive layer selection, effectively prevent making for a long time
Occurs lamination problem after;3) by the preparation process, tensile strength and breaking strength is improved, elongation at break is increased,
Space of a whole page good evenness;4) the flame retardant type one-faced tapes can be used for electronic product, and adhesive layer uses two-layer composite, by including
The thickening glue film and tackifying resin of fire retardant improve the anti-flammability when one-faced tapes use, electronic product are effectively prevent to catch fire
Etc. hidden danger generation;5) corresponding printing layer is designed for flame retardant property, using high temperature defoaming agent, conducive to realizing under hot environment
Homeostasis;6) design of frosted grain enhances caking property in adhesive layer, and keeps frosted grain equal by control partial size simultaneously
Even dispersion prevents the reunion of frosted grain.
Detailed description of the invention
Fig. 1 is flame retardant type one-faced tapes structural schematic diagram described in the embodiment of the present invention;
Fig. 2 is flame retardant type one-faced tapes preparation method flow chart described in the embodiment of the present invention;
1- base membrane layer;Printing layer -2;Adhesive layer -3;Separation layer -4.
Specific embodiment
Present invention will be described in further detail below with reference to the accompanying drawings, to enable those skilled in the art referring to specification text
Word can be implemented accordingly.
It should be appreciated that such as " having ", "comprising" and " comprising " term used herein do not allot one or more
The presence or addition of a other elements or combinations thereof.
Embodiment 1
The structure of flame retardant type one-faced tapes as shown in Figure 1 comprising:
Base membrane layer 1 is in lamella membrane structure, and 1 selection of base membrane layer is transparent polyethylene terephthalate, described
Transparent polyethylene terephthalate base membrane layer 1 is with a thickness of 2 ± 1 μm;
Printing layer 2, for coated on the ink on the base membrane layer 1;
Adhesive layer 3 is adhered in the printing layer 2, and the adhesive layer 3 includes double-layer structure: first layer is is adhered to
The thickening glue film on 2 surface of printing layer is stated, the thickening glue film includes the EVA resin glue of Surface Modification of Magnesium Hydroxide by Stearic Acid in
Film, stearic acid mass percentage is 5.5% in the Surface Modification of Magnesium Hydroxide by Stearic Acid;The second layer is to be applied to the first layer table
The tackifying resin of the grain of frosted containing magnesium hydroxide in face, the tackifying resin are rosin resin, the magnesium hydroxide frosted grain partial size
It is 500 μm, the tackifying resin further includes solvent, and the solvent moisture content is less than 200ppm, and chemical purity is greater than 99%;
Separation layer 4 is in membrane structure, and the separation layer 4 is pasted on 3 surface of adhesive layer, the separation layer 4 select from
Type film;
Wherein, it is 3% that Surface Modification of Magnesium Hydroxide by Stearic Acid described in the first layer, which accounts for EVA resin glue film mass percent,.
The printing layer 2 is by mass percentage, comprising:
Principal component is polyester resin and polyurethane resin mixture, and the amount that the polyester resin accounts for overall resin is 25%,
The principal component accounts for the 70% of 2 gross mass of printing layer;
Filler, is carbon black, and the filler accounts for the 25% of overall amount of resin;Packing material size≤4 μm;
Dispersing agent, is polyethylene glycol, and the dispersing agent accounts for the 3% of overall amount of resin;
Defoaming agent, is high temperature defoaming agent, and the defoaming agent accounts for the 2% of overall number quality.
As shown in Fig. 2, the preparation method of above-mentioned flame retardant type one-faced tapes, specifically includes the following steps:
1) it prepares base membrane layer 1: choosing polyethylene terephthalate, unreel, successively pass through 150 mesh, 150 mesh, 175
Base membrane layer 1 is made in the specific net roll one-pass molding of mesh, 175 purposes;The net roll surface set 120 ° of engraving needles engraving angle as
45 ° of diamond shape ink cell, the space of a whole page is uniform, and chromium plating again is carved after halftone copper facing;
2) it prepares printing layer 2: one layer of ink being coated in 1 first surface of base membrane layer using rubber roller, is through temperature
75 DEG C of drying tunnel, intake 60%, exhausting amount are 75%, and printing layer 2 is made;The ink is uniformly dispersed, white without obviously leaking
And bulky grain agglomerate, glossiness fluctuate within ± 0.3;The ink stirs 30min through 1000~1200r/min, and uses
The filtering of 300 mesh filter screens is made;
3) it prepares adhesive layer 3: will include that the sheet EVA resin glue film of 3% Surface Modification of Magnesium Hydroxide by Stearic Acid is adhered to
2 surface of printing layer made from step 2);Gluing, the lamella are carried out to the sheet EVA resin glue film using precision funny knife
It is between 60~70 ° that shape EVA resin glue film, which requires shore hardness, and institute's gluing is the tackifying resin of the grain of frosted containing magnesium hydroxide, institute
State tackifying resin be rosin resin, described 500 μm of magnesium hydroxide frosted grain partial size;
4) flame retardant type one-faced tapes are prepared: step 3) products obtained therefrom is placed in drying, Yu Suoshu adhesive layer in 110 DEG C of drying tunnels
3 surfaces are bonded isolated material, and flame retardant type one-faced tapes are made.
Embodiment 2
Flame retardant type one-faced tapes as illustrated in FIG. 1, comprising:
Base membrane layer 1, is in lamella membrane structure, and 1 selection of base membrane layer is polyimides, the polyimide-based film layer 1
Color is amber;The amber polyimide-based film layer 1 is with a thickness of 12.5 ± 1 μm;
Printing layer 2, for coated on the ink on the base membrane layer 1;
Adhesive layer 3 is adhered in the printing layer 2, and the adhesive layer 3 includes double-layer structure: first layer is is adhered to
The thickening glue film on 2 surface of printing layer is stated, the thickening glue film includes the EVA resin glue of Surface Modification of Magnesium Hydroxide by Stearic Acid in
Film, stearic acid mass percentage is 6.5% in the Surface Modification of Magnesium Hydroxide by Stearic Acid;The second layer is to be applied to the first layer table
The tackifying resin of the grain of frosted containing magnesium hydroxide in face, the tackifying resin are terpene phenol resin, the magnesium hydroxide frosted grain grain
Diameter is 2000 μm, and the tackifying resin further includes solvent, and the solvent moisture content is less than 200ppm, and chemical purity is greater than 99%;
Separation layer 4 is in membrane structure, and the separation layer 4 is pasted on 3 surface of adhesive layer, the separation layer 4 select from
One of type film or release paper;
Wherein, it is 8% that Surface Modification of Magnesium Hydroxide by Stearic Acid described in the first layer, which accounts for EVA resin glue film mass percent,.
The printing layer 2 is by mass percentage, comprising:
Principal component is polyester resin and polyurethane resin mixture, and the polyester resin accounts for the 35% of the amount of overall resin,
The principal component accounts for the 83% of 2 gross mass of printing layer;
Filler, is white carbon black, and the filler accounts for the 15% of overall amount of resin, packing material size≤4 μm;
Dispersing agent, is polyethylene glycol, and the dispersing agent accounts for the 0.5% of overall amount of resin;
Defoaming agent, is high temperature defoaming agent, and the defoaming agent accounts for the 1.5% of overall number quality.
As shown in Fig. 2, the preparation method of above-mentioned flame retardant type one-faced tapes, specifically:
1) it prepares base membrane layer 1: choosing in polyethylene terephthalate, polyimides or bidirectional stretching polypropylene film
One kind, unreel, successively pass through 150 mesh, 150 mesh, 175 mesh, the specific net roll one-pass molding of 175 purposes, be made base membrane layer 1;Institute
State net roll surface set 120 ° of engraving needles engraving angle as 45 ° of diamond shape ink cell, the space of a whole page is uniform, carves after halftone copper facing and plates again
Chromium;
2) it prepares printing layer 2: one layer of ink being coated in 1 first surface of base membrane layer using rubber roller, is through temperature
75 DEG C of drying tunnel, intake 60%, exhausting amount are 75%, and printing layer 2 is made;The ink is uniformly dispersed, white without obviously leaking
And bulky grain agglomerate, glossiness fluctuate within ± 0.3;The ink stirs 30min through 1000~1200r/min, and uses
The filtering of 300 mesh filter screens is made;
3) it prepares adhesive layer 3: will include the sheet EVA for the Surface Modification of Magnesium Hydroxide by Stearic Acid that mass percent is 8%
Resin glue film is adhered to 2 surface of printing layer made from step 2);The sheet EVA resin glue film is carried out using precision funny knife
Gluing, it is between 60~70 ° that the sheet EVA resin glue film, which requires shore hardness, and institute's gluing is the grain of frosted containing magnesium hydroxide
Tackifying resin, the tackifying resin be terpene phenol resin, described 2000 μm of magnesium hydroxide frosted grain partial size;
4) flame retardant type one-faced tapes are prepared: step 3) products obtained therefrom is placed in drying, Yu Suoshu adhesive layer in 110 DEG C of drying tunnels
3 surfaces are bonded isolated material, and flame retardant type one-faced tapes are made.
Embodiment 3
A kind of flame retardant type one-faced tapes as shown in Figure 1, comprising:
Base membrane layer 1, is in lamella membrane structure, and 1 selection of base membrane layer is bidirectional stretching polypropylene film, the two-way drawing
1 color of polypropylene stretched film base membrane layer be it is transparent, the bidirectional stretching polypropylene film base membrane layer 1 is with a thickness of 12 ± 1 μm;
Printing layer 2, for coated on the ink on the base membrane layer 1;
Adhesive layer 3 is adhered in the printing layer 2, and the adhesive layer 3 includes double-layer structure: first layer is is adhered to
The thickening glue film on 2 surface of printing layer is stated, the thickening glue film includes the EVA resin glue of Surface Modification of Magnesium Hydroxide by Stearic Acid in
Film, stearic acid mass percentage is 6% in the Surface Modification of Magnesium Hydroxide by Stearic Acid;The second layer is to be applied to first layer surface
The grain of frosted containing magnesium hydroxide tackifying resin, the tackifying resin be rubber, the magnesium hydroxide frosted grain partial size be 1000 μ
M, the tackifying resin further include solvent, and the solvent moisture content is less than 200ppm, and chemical purity is greater than 99%;
Separation layer 4 is in membrane structure, and the separation layer 4 is pasted on 3 surface of adhesive layer, the separation layer 4 select from
One of type film or release paper;
Wherein, it is 6% that Surface Modification of Magnesium Hydroxide by Stearic Acid described in the first layer, which accounts for EVA resin glue film mass percent,.
The printing layer 2 is by mass percentage, comprising:
Principal component is polyester resin and polyurethane resin mixture, and the polyester resin accounts for the 30% of the amount of overall resin,
The principal component accounts for the 75% of 2 gross mass of printing layer;
Filler, is white carbon black, and the filler accounts for the 20% of overall amount of resin, packing material size≤4 μm;
Dispersing agent, is polyethylene glycol, and the dispersing agent accounts for the 2% of overall amount of resin;
Defoaming agent, is high temperature defoaming agent, and the defoaming agent accounts for the 3% of overall number quality.
As shown in Fig. 2, the preparation method of above-mentioned flame retardant type one-faced tapes is prepared, specifically,
1) prepare base membrane layer 1: choosing bidirectional stretching polypropylene film, unreel, successively by 150 mesh, 150 mesh, 175 mesh,
Base membrane layer 1 is made in the specific net roll one-pass molding of 175 purposes;The net roll surface sets the angle of 120 ° of engraving needles engraving as 45 °
Diamond shape ink cell, the space of a whole page is uniform, and chromium plating again is carved after halftone copper facing;
2) it prepares printing layer 2: one layer of ink being coated in 1 first surface of base membrane layer using rubber roller, is through temperature
75 DEG C of drying tunnel, intake 60%, exhausting amount are 75%, and printing layer 2 is made;The ink is uniformly dispersed, white without obviously leaking
And bulky grain agglomerate, glossiness fluctuate within ± 0.3;The ink stirs 30min through 1000~1200r/min, and uses
The filtering of 300 mesh filter screens is made;
3) it prepares adhesive layer 3: will include that the sheet EVA resin glue film of Surface Modification of Magnesium Hydroxide by Stearic Acid is adhered to step
2) 2 surface of printing layer made from;Gluing, the sheet EVA are carried out to the sheet EVA resin glue film using precision funny knife
It is between 60~70 ° that resin glue film, which requires shore hardness, and institute's gluing is the tackifying resin of the grain of frosted containing magnesium hydroxide, the thickening
Resin is rubber, described 1000 μm of magnesium hydroxide frosted grain partial size;
4) flame retardant type one-faced tapes are prepared: step 3) products obtained therefrom is placed in drying, Yu Suoshu adhesive layer in 110 DEG C of drying tunnels
3 surfaces are bonded isolated material, and flame retardant type one-faced tapes are made.
Extension test, anti-flammability test and aging is carried out to flame retardant type one-faced tapes obtained by above three embodiments to survey
Examination:
As seen from the above table, the elongation at break of embodiment 1 is greater than 2 product of embodiment, but its anti-flammability is then lower than embodiment 2
Product, this is because the flame retardant amount added in 2 product of embodiment increases, and the increase of frosted grain partial size can drop to a certain extent
Low product mechanical strength;In burn-in test, the ageing-resistant performance of 2 product of embodiment is most excellent, and one side fire retardant is largely deposited
It is being can absorb a part of heat, 2 high temperature defoaming agent of printing layer also can guarantee the stability of product;On the other hand, base membrane layer 1 selects
Material and thickness design are more resistant to aging;And the tensile property of commercially available one side glue, flame retardant property and resistance to old can be seen that by upper table
The performance of change is weaker than properties of product disclosed in this invention.
Although the embodiments of the present invention have been disclosed as above, but its is not only in the description and the implementation listed
With.It can be applied to various suitable the field of the invention completely.It for those skilled in the art, can be easily
Realize other modification.Therefore without departing from the general concept defined in the claims and the equivalent scope, the present invention is simultaneously unlimited
In specific details and legend shown and described herein.
Claims (10)
1. a kind of flame retardant type one-faced tapes, which is characterized in that including,
Base membrane layer is in lamella membrane structure;
Printing layer, for coated on the ink on the base membrane layer;
Adhesive layer is adhered in the printing layer, and the adhesive layer includes double-layer structure: first layer is to be adhered to the printing layer
The thickening glue film on surface, the thickening glue film include the EVA resin glue film of Surface Modification of Magnesium Hydroxide by Stearic Acid, the tristearin in
Stearic acid mass percentage is 5.5%~6.5% in sour modified magnesium hydroxide;The second layer is to be applied to first layer surface
The tackifying resin of the grain of frosted containing magnesium hydroxide, the tackifying resin are one of rosin resin, terpene phenol resin or rubber, institute
Stating magnesium hydroxide frosted grain partial size is 500~2000 μm;
Separation layer, is in membrane structure, and the separation layer is pasted on the tie layer surface;
Wherein, it is 3~8% that Surface Modification of Magnesium Hydroxide by Stearic Acid described in the first layer, which accounts for EVA resin glue film mass percent,.
2. flame retardant type one-faced tapes according to claim 1, which is characterized in that the base membrane layer selection includes poly- to benzene two
One of formic acid glycol ester, polyimides or bidirectional stretching polypropylene film.
3. flame retardant type one-faced tapes according to claim 2, which is characterized in that the polyethylene terephthalate base
Film color is transparent, white or black;The transparent polyethylene terephthalate base membrane layer is with a thickness of 2 ± 1 μm, 4.5
± 1 μm, 9 ± 1 μm, 12 ± 1 μm or 20 ± 1 μm;The white polyethylene terephthalate base membrane layer is with a thickness of 12 ± 1 μ
M, 25 ± 1 μm or 30 ± 1 μm;The black polyethylene terephthalate base membrane layer is with a thickness of 25 ± 1 μm or 50 ± 1 μm.
4. flame retardant type one-faced tapes according to claim 2, which is characterized in that the polyimide-based film layer color is amber
Amber color or black;The amber polyimide base film layer is with a thickness of 12.5 ± 1 μm or 20 ± 1 μm;The black polyamide
Base membrane layer is with a thickness of 15 ± 1 μm or 20 ± 1 μm.
5. flame retardant type one-faced tapes according to claim 2, which is characterized in that the bidirectional stretching polypropylene film basement membrane
Layer color be it is transparent, the bidirectional stretching polypropylene film base membrane layer is with a thickness of 12 ± 1 μm or 15 ± 1 μm.
6. flame retardant type one-faced tapes according to claim 1, which is characterized in that the printing layer, by mass percentage,
Include:
Principal component is polyester resin and polyurethane resin mixture, and the amount that the polyester resin accounts for overall resin is no less than 25%,
The principal component accounts for the 70%~83% of printing layer gross mass;
Filler, is carbon black or white carbon black, and the filler accounts for the 15~25% of overall amount of resin;
Dispersing agent, is polyethylene glycol, and the dispersing agent accounts for the 0.5~3% of overall amount of resin;
Defoaming agent, is high temperature defoaming agent, and the defoaming agent accounts for the 0.5~3% of overall number quality;
Wherein, the dispersing agent and defoaming agent account for overall amount of resin no more than 5%.
7. flame retardant type one-faced tapes according to claim 6, which is characterized in that packing material size≤4 μm.
8. flame retardant type one-faced tapes according to claim 1, which is characterized in that the tackifying resin further includes solvent, institute
Solvent moisture content is stated less than 200ppm, chemical purity is greater than 99%.
9. flame retardant type one-faced tapes according to claim 1, which is characterized in that the separation layer selects release film or release
One of paper.
10. a kind of preparation method for preparing flame retardant type one-faced tapes described in claim 1, which is characterized in that pass through following step
It is rapid to be made,
1) it prepares base membrane layer: choosing one in polyethylene terephthalate, polyimides or bidirectional stretching polypropylene film
Kind, it unreels, successively passes through 150 mesh, 150 mesh, 175 mesh, the specific net roll one-pass molding of 175 purposes, base membrane layer is made;The net roll
Roll surface sets the angle of 120 ° of engraving needles engraving as 45 ° of diamond shape ink cell, and the space of a whole page is uniform, and chromium plating again is carved after halftone copper facing;
2) it prepares printing layer: one layer of ink being coated in the base membrane layer first surface using rubber roller, is 75 DEG C through temperature
Drying tunnel, intake 60%, exhausting amount are 75%, and printing layer is made;The ink is uniformly dispersed, without obvious leakage bletilla bulky grain
Agglomerate, glossiness fluctuate within ± 0.3;The ink stirs 30min through 1000~1200r/min, and uses 300 mesh filter screens
Filtering is made;
3) prepare adhesive layer: by include mass percent be 3~8% Surface Modification of Magnesium Hydroxide by Stearic Acid sheet EVA resin
Glue film is adhered to step 2) printing layer surface obtained;Gluing is carried out to the sheet EVA resin glue film using precision funny knife,
It is between 60~70 ° that the sheet EVA resin glue film, which requires shore hardness, and institute's gluing is the thickening of the grain of frosted containing magnesium hydroxide
Resin, the tackifying resin are one of rosin resin, terpene phenol resin or rubber, the magnesium hydroxide frosted grain partial size
500~2000 μm;
4) flame retardant type one-faced tapes are prepared: step 3) products obtained therefrom is placed in drying, Yu Suoshu tie layer surface in 110 DEG C of drying tunnels
It is bonded isolated material, flame retardant type one-faced tapes are made.
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1668459A (en) * | 2002-07-19 | 2005-09-14 | 艾利丹尼森公司 | Labeling method employing two-part curable adhesives |
CN101787223A (en) * | 2010-04-06 | 2010-07-28 | 中科院广州化学有限公司 | Modified magnesium hydroxide, preparation method thereof and application thereof in polymer |
CN102760380A (en) * | 2011-04-28 | 2012-10-31 | 藤森工业株式会社 | Hard coating thin film and touch panel using the same |
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2016
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1668459A (en) * | 2002-07-19 | 2005-09-14 | 艾利丹尼森公司 | Labeling method employing two-part curable adhesives |
CN101787223A (en) * | 2010-04-06 | 2010-07-28 | 中科院广州化学有限公司 | Modified magnesium hydroxide, preparation method thereof and application thereof in polymer |
CN102760380A (en) * | 2011-04-28 | 2012-10-31 | 藤森工业株式会社 | Hard coating thin film and touch panel using the same |
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