CN109662239A - It is a kind of to carry out quick freezing technique using liquid nitrogen - Google Patents

It is a kind of to carry out quick freezing technique using liquid nitrogen Download PDF

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Publication number
CN109662239A
CN109662239A CN201910171231.1A CN201910171231A CN109662239A CN 109662239 A CN109662239 A CN 109662239A CN 201910171231 A CN201910171231 A CN 201910171231A CN 109662239 A CN109662239 A CN 109662239A
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liquid nitrogen
time
food
immerses
time interval
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CN109662239B (en
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黄忠民
黄婉婧
雷萌萌
赵蒙娇
潘治利
艾志录
贾若南
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Henan Agricultural University
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Henan Agricultural University
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/36Freezing; Subsequent thawing; Cooling
    • A23L3/37Freezing; Subsequent thawing; Cooling with addition of or treatment with chemicals
    • A23L3/375Freezing; Subsequent thawing; Cooling with addition of or treatment with chemicals with direct contact between the food and the chemical, e.g. liquid nitrogen, at cryogenic temperature
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B4/00General methods for preserving meat, sausages, fish or fish products
    • A23B4/06Freezing; Subsequent thawing; Cooling
    • A23B4/08Freezing; Subsequent thawing; Cooling with addition of chemicals or treatment with chemicals before or during cooling, e.g. in the form of an ice coating or frozen block
    • A23B4/09Freezing; Subsequent thawing; Cooling with addition of chemicals or treatment with chemicals before or during cooling, e.g. in the form of an ice coating or frozen block with direct contact between the food and the chemical, e.g. liquid N2, at cryogenic temperature
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Freezing, Cooling And Drying Of Foods (AREA)
  • Meat, Egg Or Seafood Products (AREA)

Abstract

The invention belongs to fast food freezing technology field, in particular to a kind of to carry out quick freezing technique using liquid nitrogen, key is the repeated multiple times immersion liquid nitrogen of food carrying out contact freezing.The quick freezing technique implementation of food of the present invention is simple, energy consumption, promotion frozen food quality during improving food freezing efficiency, can reducing food freezing.The corresponding equipment one-time investment of technique is low, and occupied area is small.

Description

It is a kind of to carry out quick freezing technique using liquid nitrogen
Technical field
It is the invention belongs to fast food freezing technology field, in particular to a kind of to carry out quick freezing work using liquid nitrogen Skill.
Background technique
Various variations can occur in freezing process for food, such as physical change (volume, thermal conductivity, specific heat, drying loss Variation etc.), chemical change (protein denaturation, discoloration etc.), cell tissue variation and biology and the variation of microorganism etc..Quickly The characteristics of frozen food is to maintain the original nutritive value of food and color, smell and taste to the maximum extent, that is to say, that in freezing process In can guarantee that food is occurred above-mentioned various change reach maximum invertibity.The commercial process of quick-frozen food at present In, food is freezed using quick-freezer or freeze tunnel mostly.Quick-freezer is that food is run through to its maximum Ice crystal generation area is freezed rapidly when central temperature reaches -18 DEG C.Freeze tunnel is as quick freezing repository principle, maximum difference It is exactly that the quick-frozen work of continuity may be implemented in freeze tunnel, production efficiency is higher.But the two freezing method require it is bigger The refrigeration equipment of type, investment is more, land occupation is big, low efficiency, freeze-off time are long, energy consumption is high, drying loss is big.
In order to improve above situation, applicant has developed a kind of fast freezing technique (CN104799394A) of food, will Food, which immerses, carries out contact freezing in liquid nitrogen, which can carry out quick freezing to food, reduces inside food tissue most The generation time of large ice crystals band mitigates the destruction that is subject to of food tissue structure, so that the quality of food, flavor, nutrition are able to more On the basis of good reservation, optimizing network resource utilization is carried out, the waste of resource is reduced.But there is also certain short slabs for this method, such as Liquid nitrogen frozen is directlyed adopt to -18 DEG C of target temperature, although can realize in tens seconds, there may be product freezings The case where rate is excessively high, and portioned product will appear bursting by freezing;If reducing Frost cleft rate, best mode be using dry ice freezing and Liquid nitrogen frozen combines the mode of segmentation freezing, i.e., is first refrigerated to -10 DEG C using one way in which, then be refrigerated to target temperature Degree.It can fast implement in this way and be refrigerated to target temperature, also ensure the quality of freezing.But segmentation freezing is then increased to cold Freeze the requirement of equipment, number of devices increases, and in a disguised form increases frozen costs.
Summary of the invention
Quick freezing new process is carried out using liquid nitrogen the object of the present invention is to provide a kind of, is carried out merely with liquid nitrogen cold Freeze, avoid the trouble of pre-cooling, also do not need additionally to increase equipment, convenience further increases, adaptability further expansion, no It is only capable of reducing freezing cost, moreover it is possible to guarantee the efficiency and quality of freezing.
The technical solution adopted by the invention is as follows:
It is a kind of to carry out quick freezing technique using liquid nitrogen, it is cold that the repeated multiple times immersion liquid nitrogen of food is only subjected to contact Freeze.
Further, the time for immersing liquid nitrogen progress contact refrigeration every time is identical.
Further, the time for immersing liquid nitrogen every time is 2-20s, preferably 5-20s.
Further, it is 10-50s that food, which is removed from liquid nitrogen the time interval being again dipped into,.
Above-mentioned technique is suitble to various wheat flour and rice products, the prefabricated conditioning food such as meat, fish.Wheat flour and rice products such as dumpling, the rice dumpling, meat, It the prefabricated conditioning food of fish such as burger, fish ball and wraps up in the prefabricated conditioning product in face and such as improves spiced chicken legs, chicken wings, crisp-fried shrimp balls etc..Under Face illustrates partial category more preferably processing mode by taking Flour product as an example:
When the food is boiled dumpling, preferred following manner:
The time that food immerses liquid nitrogen every time is 5s, and being removed from liquid nitrogen the time interval being again dipped into is 10s or 20s Or 30s, it repeats to reach -18 DEG C to product centre temperature;
Or food immerses the time of liquid nitrogen every time for 10s, being removed from liquid nitrogen the time interval being again dipped into is 10s Or 20s or 30s, it repeats to reach -18 DEG C to product centre temperature;
Or food immerses the time of liquid nitrogen every time for 15s, being removed from liquid nitrogen the time interval being again dipped into is 10s Or 20s or 50s, it repeats to reach -18 DEG C to product centre temperature;
Or food immerses the time of liquid nitrogen every time for 20s, being removed from liquid nitrogen the time interval being again dipped into is 10s Or 40s, it repeats to reach -18 DEG C to product centre temperature.
When the food is fish ball, preferred following manner:
The time that food immerses liquid nitrogen every time is 4s or 5s or 6s, and being removed from liquid nitrogen the time interval being again dipped into is 20s, being repeated up to central temperature is -18 DEG C;
Or food immerses the time of liquid nitrogen every time for 4s or 8s or 10s, is removed from liquid nitrogen the time being again dipped into Between be divided into 30s, be repeated up to central temperature be -18 DEG C;
Or food immerses the time of liquid nitrogen every time for 5s or 15s or 20s, is removed from liquid nitrogen the time being again dipped into Between be divided into 40s, be repeated up to central temperature be -18 DEG C.
When the food is the rice dumpling, preferred following manner:
The time that food immerses liquid nitrogen every time is 2s, and being removed from liquid nitrogen the time interval being again dipped into is 10s or 20s Or 30s, it repeats to reach -18 DEG C to product centre temperature;
Or food immerses the time of liquid nitrogen every time for 4s, being removed from liquid nitrogen the time interval being again dipped into is 10s Or 20s or 30s or 40s, it repeats to reach -18 DEG C to product centre temperature;
Or food immerses the time of liquid nitrogen every time for 5s, being removed from liquid nitrogen the time interval being again dipped into is 10s Or 20s or 30s or 40s or 50s, it repeats to reach -18 DEG C to product centre temperature;
Or food immerses the time of liquid nitrogen every time for 6s, being removed from liquid nitrogen the time interval being again dipped into is 10s Or 20s or 30s or 40s or 50s, it repeats to reach -18 DEG C to product centre temperature;
Or food immerses the time of liquid nitrogen every time for 8s, being removed from liquid nitrogen the time interval being again dipped into is 10s Or 30s or 50s, it repeats to reach -18 DEG C to product centre temperature;
Or food immerses the time of liquid nitrogen every time for 10s, being removed from liquid nitrogen the time interval being again dipped into is 10s Or 20s, it repeats to reach -18 DEG C to product centre temperature;
Or food immerses the time of liquid nitrogen every time for 15s, being removed from liquid nitrogen the time interval being again dipped into is 10s Or 20s or 30s, it repeats to reach -18 DEG C to product centre temperature;
Or food immerses the time of liquid nitrogen every time for 20s, being removed from liquid nitrogen the time interval being again dipped into is 10s Or 20s or 30s or 40s, it repeats to reach -18 DEG C to product centre temperature.
Compared to the method in a kind of fast freezing technique of food of patent application CN104799394A before, the application Technique is optimized.Original process are to transport the food to be freezed using conveyer belt, and process and immersing in liquid nitrogen is freezed Contact, is then departed from liquid nitrogen, on the basis of residence time reaches -18 DEG C by the internal temperature of frozen food.But due to only logical A contact freezing is crossed to realize, it is found that may be when reaching -18 DEG C, portioned product has already appeared the situation of bursting by freezing.
And by the way of segmentation freezing, then the problem of this quick freeze is brought can be preferably reduced, but is segmented cold Freeze be pre-chilled it is cumbersome, number of devices increases, need segment monitoring solidification point, frozen costs increase the problem of.And this hair It is bright by the way that the study found that the food that will be freezed is by repeatedly immersing liquid nitrogen, and the interval by leaving liquid nitrogen is conducted heat The heat transfer of food inside and outside can be well realized in process, avoids product bursting by freezing.By to immersion time and interval heat transfer time Control, not only may be implemented quickly to freeze food, moreover it is possible to refine the ice crystal of food product.The number of immersion is with final It realizes subject to when food product temperature reaches -18 DEG C of fully charges.Avoiding problems using dry ice and liquid nitrogen segmentation be first refrigerated to- 10 DEG C of operations for carrying out being refrigerated to -18 DEG C again.
During freezing the food, it need to only control that it is immersed in liquid nitrogen and the external time being detained can be complete At the quick-frozen process of food, easy to operate, quick-frozen process is easy to implement serialization and automation.By taking dumpling as an example, in the present invention Freeze dumpling core and reach the control of -18 DEG C of total time-consumings in 140s, the practical time for immersing liquid nitrogen is no more than 60s, some down to 20s;But the generation that quick-frozen technique avoids bursting by freezing is carried out compared to the primary liquid nitrogen that immerses.Although in addition, being multiple immersion liquid Nitrogen, but when each progress fast food freezing using liquid nitrogen, food is immersed in the container for being loaded with liquid nitrogen, and food surface is largely put In liquid nitrogen producing bubbles inside while hot, can equally effectively prevent it is quick-frozen during food it is viscous glutinous.
Compared with the prior art, the invention has the following advantages:
The present invention be to provide it is a kind of carry out quick freezing new process using liquid nitrogen, freezed, be not required to merely with liquid nitrogen Additionally to increase equipment, not need to be pre-chilled, convenience further increases, adaptability further expansion.The present invention is improving food Outside chilling rate, the utilization rate for improving refrigeration equipment and consecutive production efficiency and the convenience of raising operation, it is thus also avoided that The occurrence of bursting by freezing, makes the quality of food be maintained at optimal state, can not only reduce freezing cost, moreover it is possible to guarantee freezing Efficiency and quality.
Specific embodiment
Below the technical scheme of the invention is illustrated by a specific example, but the scope of the present invention is not limited thereto:
One, experimental material: using leek egg dumpling as material, grammes per square metre 20g/.
Experimental method:
1, dumpling is put into place in 4 DEG C of refrigerators and is taken out after twenty minutes, measuring center temperature, record.
2, dumpling is put into the liquid nitrogen container for filling -196 DEG C of liquid nitrogen, the different freeze-off times according to the form below carry out quick-frozen. Infrared thermometer records dumpling central temperature, observes dumpling surface bursting by freezing situation.
Experimental result:
Two, experimental material: the rice dumpling
The production of the rice dumpling
Fillings: quick-frozen oil 180g, granulated sugar powder 240g, hydroxypropylated waxy rice starch 12g, Semen sesami nigrum 138g, peanut 30g.
Musculus cutaneus: glutinous rice flour 930g, water 786g, quick-frozen oil 36g, glue element 48g.
Manufacturing specification is the rice dumpling of 20g/, and skin: filling mass ratio is 3:1, be twisted into after circle by hand the rice dumpling are carried out it is quick-frozen.
Experimental method:
1, the rice dumpling made are put into after being placed 30 minutes in 4 DEG C of refrigerators and are taken out, measuring center temperature, record.
2, the rice dumpling are put into the liquid nitrogen container for filling -196 DEG C of liquid nitrogen, the different freeze-off times according to the form below carry out quick-frozen. Reach -18 DEG C with central temperature for standard, observe its landing assay test rear surface bursting by freezing situation and records.Fixed number of repetition is 5 It is secondary.
Experimental result:
From upper table as it can be seen that at least being needed if using disposable when immersing liquid nitrogen and be refrigerated to central temperature as -18 DEG C 80s.But the technique of multiple immersion liquid nitrogen of the invention is used, in the case where most saving liquid nitrogen, it is put into 2s every time, takes out 30s, 6 times are repeated the above process, i.e., actually immerses the 12s that only has total time of liquid nitrogen, under the premise of the total 192s of whole process just It may be implemented to reach central temperature not only for -18 DEG C but also avoid product bursting by freezing;It certainly, can also be from operation week according to different considerations The one or more aspects such as the phase is most short and number of operations is minimum select optimal scheme.Such as using the time for immersing liquid nitrogen every time For 2s or 4s or 6s or 8s, take out the scheme immersed again after 10s, being repeated up to central temperature is -18 DEG C, above scheme can compared with Realize that product is refrigerated to target temperature simultaneously and avoids product bursting by freezing in short total duration;For synthesis, also can choose with Lower scheme has then taken into account total duration, liquid nitrogen immerses the time and has taken out number (convenient for operability): having immersed the time of liquid nitrogen every time It for 10s, is immersed again after taking out 10s or 20s or 30, being repeated up to central temperature is -18 DEG C;Or the time of liquid nitrogen is immersed every time It for 15s, is immersed again after taking out 10s or 20s or 30, being repeated up to central temperature is -18 DEG C.
Three, experimental material: fish ball
Experimental method:
1, the fish ball of purchase is thawed completely at room temperature, is then placed in after being placed 30 minutes in 4 DEG C of refrigerators and takes out, in measurement Heart temperature, record.
2, fish ball is put into the liquid nitrogen container for filling -196 DEG C of liquid nitrogen, the different freeze-off times according to the form below carry out quick-frozen. Reach -18 DEG C with central temperature for standard, observe its landing assay test rear surface bursting by freezing situation and records.Fixed number of repetition is 5 It is secondary.
Experimental result:
From upper table as it can be seen that at least being needed if using disposable when immersing liquid nitrogen and be refrigerated to central temperature as -18 DEG C 40s, but has also there is the case where bursting by freezing in fish ball in the case of this, in fact, fish ball has just occurred when disposably immersing liquid nitrogen 25s The case where bursting by freezing.But the technique of multiple immersion liquid nitrogen of the invention is used, in terms of the case where most saving liquid nitrogen, it is put into every time 4s, 50s is taken out, repeats the above process 3 times, is i.e. the when a length of 12s of immersion liquid nitrogen, under the premise of the entire total 162s for the treatment of process just It may be implemented to reach central temperature not only for -18 DEG C but also avoid product bursting by freezing;It certainly, can also be from operation week according to different considerations The one or more aspects such as the phase is most short and number of operations is minimum select optimal scheme.Such as using the time for immersing liquid nitrogen every time For 4s or 5s or 6s, the scheme immersed again after 20s is taken out, being repeated up to central temperature is -18 DEG C;Or using immersion liquid every time The time of nitrogen is 4s or 8s or 10s, takes out the scheme immersed again after 30s, and being repeated up to central temperature is -18 DEG C;Or it uses The time for immersing liquid nitrogen every time is 5s or 15s or 20s, takes out the scheme immersed again after 40s, and being repeated up to central temperature is -18 ℃。

Claims (9)

1. a kind of carry out quick freezing technique using liquid nitrogen, which is characterized in that connect the repeated multiple times immersion liquid nitrogen of food Touch freezing.
2. as described in claim 1 carry out quick freezing technique using liquid nitrogen, which is characterized in that immerse liquid nitrogen every time and carry out The time of contact refrigeration is identical.
3. carrying out quick freezing technique using liquid nitrogen as claimed in claim 2, which is characterized in that every time immersion liquid nitrogen when Between be 2-20s.
4. as claimed in claim 3 carry out quick freezing technique using liquid nitrogen, which is characterized in that food is removed from liquid nitrogen It is 10-50s to the time interval being again dipped into.
5. carrying out quick freezing technique using liquid nitrogen as claimed in claim 4, which is characterized in that every time immersion liquid nitrogen when Between be 5-20s.
6. a method as claimed in any one of claims 1 to 5 utilize liquid nitrogen to carry out quick freezing technique, which is characterized in that the food is Conditioning food.
7. as claimed in claim 6 carry out quick freezing technique using liquid nitrogen, which is characterized in that the food is boiled dumpling, The time that food immerses liquid nitrogen every time is 5s, and being removed from liquid nitrogen the time interval being again dipped into is 10s or 20s or 30s, weight Reach -18 DEG C to product centre temperature again;The time that food immerses liquid nitrogen every time is 10s, is removed from liquid nitrogen and is again dipped into Time interval be 10s or 20s or 30s, repeat to reach -18 DEG C to product centre temperature;Food immerses the time of liquid nitrogen every time For 15s, being removed from liquid nitrogen the time interval being again dipped into is 10s or 20s or 50s, repeat to product centre temperature to reach- 18℃;The time that food immerses liquid nitrogen every time is 20s, and being removed from liquid nitrogen the time interval being again dipped into is 10s or 40s, It repeats to reach -18 DEG C to product centre temperature.
8. as claimed in claim 6 carry out quick freezing technique using liquid nitrogen, which is characterized in that the food is fish ball, The time that food immerses liquid nitrogen every time is 4s or 5s or 6s, and being removed from liquid nitrogen the time interval being again dipped into is 20s, is repeated Until central temperature is -18 DEG C;Or food immerses the time of liquid nitrogen every time for 4s or 8s or 10s, is removed from liquid nitrogen again The time interval of secondary immersion is 30s, and being repeated up to central temperature is -18 DEG C;Or food immerses the time of liquid nitrogen every time for 5s Or 15s or 20s, being removed from liquid nitrogen the time interval being again dipped into is 40s, and being repeated up to central temperature is -18 DEG C.
9. as claimed in claim 6 carry out quick freezing technique using liquid nitrogen, which is characterized in that the food is the rice dumpling, The time that food immerses liquid nitrogen every time is 2s, and being removed from liquid nitrogen the time interval being again dipped into is 10s or 20s or 30s, weight Reach -18 DEG C to product centre temperature again;The time that food every time immerses liquid nitrogen is 4s, is removed from liquid nitrogen and is again dipped into Time interval is 10s or 20s or 30s or 40s, repeats to reach -18 DEG C to product centre temperature;Food immerse every time liquid nitrogen when Between be 5s, being removed from liquid nitrogen the time interval that is again dipped into is 10s or 20s or 30s or 40s or 50s, is repeated into food Heart temperature reaches -18 DEG C;The time that food immerses liquid nitrogen every time is 6s, and being removed from liquid nitrogen the time interval being again dipped into is 10s or 20s or 30s or 40s or 50s repeats to reach -18 DEG C to product centre temperature;The time that food immerses liquid nitrogen every time is 8s, being removed from liquid nitrogen the time interval being again dipped into is 10s or 30s or 50s, repeats to reach -18 to product centre temperature ℃;The time that food immerses liquid nitrogen every time is 10s, and being removed from liquid nitrogen the time interval being again dipped into is 10s or 20s, weight Reach -18 DEG C to product centre temperature again;The time that food immerses liquid nitrogen every time is 15s, is removed from liquid nitrogen and is again dipped into Time interval be 10s or 20s or 30s, repeat to reach -18 DEG C to product centre temperature;Food immerses the time of liquid nitrogen every time For 20s, being removed from liquid nitrogen the time interval being again dipped into is 10s or 20s or 30s or 40s, is repeated to product centre temperature Reach -18 DEG C.
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CN113455537A (en) * 2021-07-31 2021-10-01 广东海洋大学 Energy-saving quick-freezing method for golden pomfret
US11700862B2 (en) 2021-07-31 2023-07-18 Guangdong Ocean University Energy-saving quick-freezing method for golden pomfret

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CN111728008A (en) * 2020-07-07 2020-10-02 河南农业大学 High-water-retention quick-frozen scallion oil cake and preparation method thereof
CN113455537A (en) * 2021-07-31 2021-10-01 广东海洋大学 Energy-saving quick-freezing method for golden pomfret
CN113455537B (en) * 2021-07-31 2022-02-01 广东海洋大学 Energy-saving quick-freezing method for golden pomfret
US11700862B2 (en) 2021-07-31 2023-07-18 Guangdong Ocean University Energy-saving quick-freezing method for golden pomfret

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