CN109651863A - A kind of solar energy glass reflection reducing coating having self-cleaning function and preparation method thereof and the high anti-reflection solar energy glass of automatically cleaning - Google Patents
A kind of solar energy glass reflection reducing coating having self-cleaning function and preparation method thereof and the high anti-reflection solar energy glass of automatically cleaning Download PDFInfo
- Publication number
- CN109651863A CN109651863A CN201811408822.8A CN201811408822A CN109651863A CN 109651863 A CN109651863 A CN 109651863A CN 201811408822 A CN201811408822 A CN 201811408822A CN 109651863 A CN109651863 A CN 109651863A
- Authority
- CN
- China
- Prior art keywords
- solar energy
- energy glass
- nano
- self
- reducing coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/30—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/32—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
- C03C17/328—Polyolefins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/44—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the composition of the continuous phase
- C03C2217/445—Organic continuous phases
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
- C03C2217/47—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase consisting of a specific material
- C03C2217/475—Inorganic materials
- C03C2217/477—Titanium oxide
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
- C03C2217/47—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase consisting of a specific material
- C03C2217/475—Inorganic materials
- C03C2217/478—Silica
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/73—Anti-reflective coatings with specific characteristics
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/111—Deposition methods from solutions or suspensions by dipping, immersion
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/116—Deposition methods from solutions or suspensions by spin-coating, centrifugation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/118—Deposition methods from solutions or suspensions by roller-coating
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/30—Aspects of methods for coating glass not covered above
- C03C2218/32—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Abstract
The present invention relates to solar energy glass reflection reducing coating technical fields, and in particular to a kind of solar energy glass reflection reducing coating for having self-cleaning function and preparation method thereof and the high anti-reflection solar energy glass of automatically cleaning.The solar energy glass reflection reducing coating for having self-cleaning function includes nano pulp and nano core-shell silicon dioxide microsphere lotion.The component of nano pulp: hollow nano structure titanium dioxide microsphere powder, dispersing agent and solvent.The preparation method is the hollow nano TiO 2 particles that low-refraction and high catalytic activity are introduced in nano core-shell silicon dioxide microsphere lotion, has the solar energy reflection reducing coating of automatically cleaning and anti-reflection function while to be made a kind of durable.The high anti-reflection solar energy glass of the automatically cleaning solves existing solar energy glass and is easy to be adhered to by industrial pollutants, it is difficult to the problem of cleaning, and the generating efficiency of solar battery can be stabilized and increased and reduce solar battery maintenance management cost.
Description
Technical field
The present invention relates to solar energy glass reflection reducing coating technical fields, and in particular to a kind of to have self-cleaning function too
Positive energy glass reflection reducing coating and preparation method thereof and the high anti-reflection solar energy glass of automatically cleaning.
Background technique
Photovoltaic is one of current most potential clean energy resource, and just exploitation is each with all strength by various countries correlation practitioner
Kind advanced technology and new product, it would be desirable to improve photoelectric conversion efficiency.Major part photovoltaic glass producer is all for raising light at present
The translucency of volt glass does effort, typically increases by one layer of anti-reflection film on glass using the principle of interference of light, in the market very
The coating liquid of more anti-reflection films is attained by anti-reflection 3% effect, but it is little to improve space.On the other hand, modern industry with
The development of urban construction leads to air and water etc., and environmental pollution is serious, so that the pollution sources such as dust are easy in photovoltaic glass
Adhere on glass, when material surface is contaminated, weakens efficient utilization of the photoelectric device to the energy, while also making device etc. and exist
The problem that stability is poor, service life is short, traditional method be that environmental pollution is not only aggravated using surfactant washing,
And need to be repeated, expend a large amount of manpower, financial resources and material resources.Therefore, in recent years, the research of automatically cleaning antireflective coating and
Development receives great attention, and preparing has automatically cleaning characteristic and needs of the efficient antireflective coating as technology development.
In recent years, automatic cleaning coating has received widespread attention, be based on different automatically cleaning principles, have been developed it is a variety of it is antifouling from
Antireflecting coating, such as (1) super-hydrophobic antifouling antireflecting coating are cleaned, increases chain alkyl three in silica reflection reducing coating formula
Oxyalkylsiloxane, polysiloxanes or flucride siloxane component reduce anti-reflection film surface energy, water are made to be formed on its surface droplet,
It tumbles and takes away dust；(2) the super hydrophilic antifouling antireflecting coating of photocatalysis, the dopen Nano dioxy in silica antireflective coating liquid
The method for changing titanium, first resolves into carbon dioxide and water for organic principle in pollutant using the photocatalysis of titanium dioxide, then
Using photic Superhydrophilic, the dust and industrial pollutants for adhering to film surface are easy as rain drop erosion removing；(3) antistatic super parent
The antifouling antireflecting coating of water, the conductive materials such as dopen Nano tin oxide in silica antireflective coating liquid reduce film layer table
Surface resistance makes the inorganic pollutions such as sand and dust be not easy to adhere on surface, can remove under gravity and natural wind effect.
However, above-mentioned three kinds of antifouling equal existing defects of automatically cleaning antireflecting coating: super-hydrophobic antifouling antireflecting coating is due to hydrophobic
Group is divided into organic chain section, is easy by the solar ultraviolet irradiation decomposition reasons such as aging and film layer mechanical friction performance difference
The superhydrophobic characteristic of film layer is set to fade away and lose automatic cleaning action；And antistatic super hydrophilic antifouling antireflecting coating, although right
The inorganic pollutions such as sand and dust and carbon have preferable effect, but helpless to industrial pollutants.Therefore both types
Antifouling automatically cleaning antireflecting coating is not appropriate for the serious southern rainy regions of industrial pollution, and the super hydrophilic antifouling anti-reflection painting of photocatalysis
Layer then belongs to " suiting the remedy to the case ".
Currently, the existing a small amount of report of the super hydrophilic antireflecting coating of photocatalysis, usually in silica antireflective coating liquid
Doped nano titanium dioxide etc. have photocatalysis semiconductor material, as Chinese patent CN102702806,
CN102897833 discloses the preparation and application of a kind of self-cleaning synergy solar paint, using in silica antireflective coating liquid
The method of middle doped nano titanium dioxide wants that industrial pollutants are resolved into carbon dioxide using the photocatalysis of titanium dioxide
The small molecule compound that easily removes and surface can be made to generate Superhydrophilic under light illumination using titanium dioxide, to make glass
Close to zero degree, pollutant is not easy to adhere to the water contact angle on surface, realizes glass by gravity, natural wind or rain drop erosion
Automatically cleaning purpose.But major defect is the reflectivity height of ordinary titanium dioxide, titanium dioxide additive amount will cause film too much
Layer light transmittance be low or even serious catalytic effect that is reflective, however having had film layer, and nano-titania particle must use up can
It being exposed to film surface energy more, can be contacted with pollutant, so additive amount influences film layer photocatalysis effect very little again, caused certainly
Cleaning action is bad, this just makes to increase light transmittance and self-cleaning effect as a paradox.
Summary of the invention
It is an object of the present invention in view of the deficiencies of the prior art, provide a kind of solar energy for having self-cleaning function
Glass reflection reducing coating, which had not only had the advantages that height was anti-reflection, but also tool
Have the advantages that self-cleaning effect is good.
The second object of the present invention is to provide a kind of solar energy for having self-cleaning function in view of the deficiencies of the prior art
The preparation method of glass reflection reducing coating.
The third object of the present invention is in view of the deficiencies of the prior art, to provide a kind of high anti-reflection solar energy glass of automatically cleaning
Glass, the high anti-reflection solar energy glass of the automatically cleaning can well solve light transmittance and self-cleaning effect this to paradox.
One of to achieve the goals above, the present invention adopts the following technical scheme:
A kind of solar energy glass reflection reducing coating for having self-cleaning function is provided, it includes the group of following weight percent
Part:
Nano pulp 1%~25%
Nano core-shell silicon dioxide microsphere lotion 75%~99%；
Wherein, the nano pulp consists of the following components in percentage by weight:
Hollow nano structure titanium dioxide microsphere powder 1%~10%
Dispersing agent 0.25%~1%
Solvent 89%~98.75%；
Wherein, the nano core-shell silicon dioxide microsphere lotion is the invention name according to application No. is 201610301751.6
Method preparation referred to as in the patent application of " nano core-shell silicon dioxide microsphere and anti-reflection anti-reflection Composite Coatings film liquid application and preparation "
's.
Preferably, a kind of solar energy glass reflection reducing coating having self-cleaning function, it includes following weight
The component of percentage:
Nano pulp 5%~20%
Nano core-shell silicon dioxide microsphere lotion 80%~95%；
Wherein, the nano pulp consists of the following components in percentage by weight:
Hollow nano structure titanium dioxide microsphere powder 3%~8%
Dispersing agent 0.25%~1%
Solvent 91%~96%.
More preferably, a kind of solar energy glass reflection reducing coating having self-cleaning function, it includes following
The component of weight percent:
Nano pulp 10%
Nano core-shell silicon dioxide microsphere lotion 90%；
Wherein, the nano pulp consists of the following components in percentage by weight:
Hollow nano structure titanium dioxide microsphere powder 5%
Dispersing agent 0.5%
Solvent 94.5%.
The hollow nano structure titanium dioxide microsphere powder is produced by Suzhou Na Yin Biotechnology Co., Ltd.
The solvent is one of water, ethyl alcohol, isopropanol, propylene glycol monomethyl ether or butyl acetate or any two or more
Composition.
The dispersing agent be Tu Yile DS-136, Tu Yile DS-142B, Tu Yile DS-192L, DisuperS18,
Disuper S19, TDL-ND1, MQ-568, silane coupling agent KH-560, Silane coupling reagent KH-570, methyltrimethoxysilane
Or one of methyltriethoxysilane or any two or more composition.
To achieve the goals above two, the present invention adopts the following technical scheme:
A kind of preparation method of solar energy glass reflection reducing coating for having self-cleaning function is provided, it includes following step
It is rapid:
Step 1 prepares nano pulp: the hollow nano structure titanium dioxide microsphere powder of formula ratio is poured into equipped with molten
In the dispersing apparatus of agent, then the dispersing agent of formula ratio is added thereto while stirring, and is dispersed, nano pulp is made；
Step 2 prepares solar energy glass reflection reducing coating: the nano pulp of formula ratio is added to the nanometer of formula ratio
In nucleocapsid silicon dioxide microsphere lotion, and it is diluted to certain solid content with the solvent, and be stirred, obtains the tool
The solar energy glass reflection reducing coating of standby self-cleaning function.
In above-mentioned technical proposal, in the step 1, the time of the dispersion is 8h~12h.
In above-mentioned technical proposal, in the step 2, and be diluted to the solvent 3%~10% solid content；It is described
Mixing time is 10min~30min.
To achieve the goals above three, the present invention adopts the following technical scheme:
There is provided a kind of automatically cleaning high anti-reflection solar energy glass, be using spraying, dip-coating, lifting, roller coating, spin coating, flow coat or
Any film plating process in film plating process is brushed, one kind described in claim 1 to 6 any one is had into self-cleaning function
Solar energy glass reflection reducing coating be coated on be cleaned and dried after packaging glass of solar cell substrate on, to its dry tack free
Afterwards again through 80 DEG C~250 DEG C baking-curings, finally with glass baseplate through 500 DEG C~700 DEG C tempering processing 3min~5min to get
To the high anti-reflection solar energy glass of automatically cleaning.
Compared with prior art, beneficial effect is the present invention:
(1) a kind of solar energy glass reflection reducing coating for having self-cleaning function provided by the invention, has the advantage that
First, the main component using nano core-shell silicon dioxide microsphere lotion as the coating, and by hollow nano structure titanium dioxide
Titanium microsphere powder is dispersed therein, and then uses solid silica main as reflection reducing coating for improving built in hole
Film layer porosity low problem when ingredient, and avoid fine dust and penetrated into antireflective coating micropore by opening formula hole
Portion causes light transmittance to reduce problem；Second, it is this using hollow nano structure titanium dioxide microsphere powder as photochemical catalyst
Hollow nano structure titanium dioxide microballoon has hollow structure, can substantially reduce the density and refractive index of titanium dioxide；Meanwhile this
The specific surface area of kind hollow structure is very big, and sunlight can constantly reflect inside hollow structure, thus the utilization rate of light
It is relatively high, the photocatalytic activity of material can be significantly improved, so that self-cleaning effect is good.
(2) preparation method of a kind of solar energy glass reflection reducing coating for having self-cleaning function provided by the invention, should
Preparation method is the hollow nano dioxy that low-refraction and high catalytic activity are introduced in nano core-shell silicon dioxide microsphere lotion
Change titanium particle, has the solar energy reflection reducing coating of automatically cleaning and anti-reflection function while to be made a kind of durable.This method
It is simple with preparation method, and can be suitable for industrialization large-scale production the characteristics of.
(3) the high anti-reflection solar energy glass of a kind of automatically cleaning provided by the invention is to solve light transmittance and self-cleaning effect
This is specially developed for the serious southern rainy regions of industrial pollution and a kind of has strong self-cleaning ability and high increasing to paradox
The solar energy glass of permeability energy, and then solve existing solar energy glass and be easy to be adhered to by industrial pollutants, it is difficult to it is clean to ask
Topic, and the generating efficiency of solar battery can be stabilized and increased and reduce solar battery maintenance management cost.
Specific embodiment
In order to which the technical problems, technical solutions and beneficial effects solved by the present invention is more clearly understood, below in conjunction with
Embodiment, the present invention will be described in further detail.It should be appreciated that specific embodiment described herein is only used to explain
The present invention is not intended to limit the present invention.
Embodiment 1.
A kind of solar energy glass reflection reducing coating having self-cleaning function, it includes the component of following weight percent:
Nano pulp 1%~25%
Nano core-shell silicon dioxide microsphere lotion 75%~99%；
Wherein, the nano pulp consists of the following components in percentage by weight:
Hollow nano structure titanium dioxide microsphere powder 1%~10%
Dispersing agent 0.25%~1%
Solvent 89%~98.75%；
Wherein, the nano core-shell silicon dioxide microsphere lotion is the invention name according to application No. is 201610301751.6
Method preparation referred to as in the patent application of " nano core-shell silicon dioxide microsphere and anti-reflection anti-reflection Composite Coatings film liquid application and preparation "
's.
Wherein, hollow nano structure titanium dioxide microsphere powder is produced by Suzhou Na Yin Biotechnology Co., Ltd.
Wherein, solvent is one of water, ethyl alcohol, isopropanol, propylene glycol monomethyl ether or butyl acetate or any two or more
Composition.
Wherein, dispersing agent be Tu Yile DS-136, Tu Yile DS-142B, Tu Yile DS-192L, DisuperS18,
Disuper S19, TDL-ND1, MQ-568, silane coupling agent KH-560, Silane coupling reagent KH-570, methyltrimethoxysilane
Or one of methyltriethoxysilane or any two or more composition.
A kind of preparation method of above-mentioned solar energy glass reflection reducing coating for having self-cleaning function, it is characterised in that: it
The following steps are included:
Step 1 prepares nano pulp: the hollow nano structure titanium dioxide microsphere powder of formula ratio is poured into equipped with molten
In the dispersing apparatus of agent, then the dispersing agent of formula ratio is added thereto while stirring, and carries out dispersion 8h~12h, is made and receives
Rice & peanut milk material；
Step 2 prepares solar energy glass reflection reducing coating: the nano pulp of formula ratio is added to the nanometer of formula ratio
In nucleocapsid silicon dioxide microsphere lotion, and be diluted to the solvent 3%~10% solid content, and be stirred 10min~
30min obtains the solar energy glass reflection reducing coating for having self-cleaning function.
A kind of high anti-reflection solar energy glass of automatically cleaning, it is characterised in that: be using spraying, dip-coating, lifting, roller coating, spin coating,
Any film plating process in flow coat or brushing film plating process, a kind of above-mentioned solar energy glass for having self-cleaning function is subtracted
Reflective coating be coated on be cleaned and dried after packaging glass of solar cell substrate on, after its dry tack free again through 80 DEG C~
250 DEG C of baking-curings finally increase with glass baseplate through 500 DEG C~700 DEG C tempering processing 3min~5min to get to automatically cleaning height
Saturating solar energy glass.
Embodiment 2.
A kind of solar energy glass reflection reducing coating having self-cleaning function, it includes the component of following weight percent:
Nano pulp 10%
Nano core-shell silicon dioxide microsphere lotion 90%；
Wherein, the nano pulp consists of the following components in percentage by weight:
Hollow nano structure titanium dioxide microsphere powder 5%
Dispersing agent 0.5%
Solvent 94.5%.
Wherein, the nano core-shell silicon dioxide microsphere lotion is the invention name according to application No. is 201610301751.6
Method preparation referred to as in the patent application of " nano core-shell silicon dioxide microsphere and anti-reflection anti-reflection Composite Coatings film liquid application and preparation "
's.
Wherein, hollow nano structure titanium dioxide microsphere powder is produced by Suzhou Na Yin Biotechnology Co., Ltd.
In the present embodiment, solvent is water.
In the present embodiment, dispersing agent is methyltriethoxysilane.
A kind of preparation method of above-mentioned solar energy glass reflection reducing coating for having self-cleaning function, it is characterised in that: it
The following steps are included:
Step 1 prepares nano pulp: the hollow nano structure titanium dioxide microsphere powder of formula ratio is poured into equipped with molten
In the dispersing apparatus of agent, then the dispersing agent of formula ratio is added thereto while stirring, and carries out dispersion 10h, nano slurry is made
Material；
Step 2 prepares solar energy glass reflection reducing coating: the nano pulp of formula ratio is added to the nanometer of formula ratio
In nucleocapsid silicon dioxide microsphere lotion, and be diluted to the solvent 6% solid content, and be stirred 20min, obtain institute
State the solar energy glass reflection reducing coating for having self-cleaning function.
A kind of high anti-reflection solar energy glass of automatically cleaning, it is characterised in that: be using spraying, dip-coating, lifting, roller coating, spin coating,
Any film plating process in flow coat or brushing film plating process, a kind of above-mentioned solar energy glass for having self-cleaning function is subtracted
Reflective coating is coated on the packaging glass of solar cell substrate after being cleaned and dried, and is dried again through 150 DEG C after its dry tack free
Roasting solidification finally arrives the high anti-reflection solar energy glass of automatically cleaning through 600 DEG C of tempering processing 4min with glass baseplate.
Embodiment 3.
A kind of solar energy glass reflection reducing coating having self-cleaning function, it includes the component of following weight percent:
Nano pulp 1%
Nano core-shell silicon dioxide microsphere lotion 99%；
Wherein, the nano pulp consists of the following components in percentage by weight:
Hollow nano structure titanium dioxide microsphere powder 1%
Dispersing agent 0.25%
Solvent 98.75%；
Wherein, the nano core-shell silicon dioxide microsphere lotion is the invention name according to application No. is 201610301751.6
Method preparation referred to as in the patent application of " nano core-shell silicon dioxide microsphere and anti-reflection anti-reflection Composite Coatings film liquid application and preparation "
's.
Wherein, hollow nano structure titanium dioxide microsphere powder is produced by Suzhou Na Yin Biotechnology Co., Ltd.
In the present embodiment, solvent is ethyl alcohol.
In the present embodiment, dispersing agent is methyltrimethoxysilane.
A kind of preparation method of above-mentioned solar energy glass reflection reducing coating for having self-cleaning function, it is characterised in that: it
The following steps are included:
Step 1 prepares nano pulp: the hollow nano structure titanium dioxide microsphere powder of formula ratio is poured into equipped with molten
In the dispersing apparatus of agent, then the dispersing agent of formula ratio is added thereto while stirring, and carries out dispersion 8h, nano slurry is made
Material；
Step 2 prepares solar energy glass reflection reducing coating: the nano pulp of formula ratio is added to the nanometer of formula ratio
In nucleocapsid silicon dioxide microsphere lotion, and be diluted to the solvent 3% solid content, and be stirred 10min, obtain institute
State the solar energy glass reflection reducing coating for having self-cleaning function.
A kind of high anti-reflection solar energy glass of automatically cleaning, it is characterised in that: be using spraying, dip-coating, lifting, roller coating, spin coating,
Any film plating process in flow coat or brushing film plating process, a kind of above-mentioned solar energy glass for having self-cleaning function is subtracted
Reflective coating is coated on the packaging glass of solar cell substrate after being cleaned and dried, and is toasted again through 80 DEG C after its dry tack free
Solidification finally arrives the high anti-reflection solar energy glass of automatically cleaning through 500 DEG C of tempering processing 5min with glass baseplate.
Embodiment 4.
A kind of solar energy glass reflection reducing coating having self-cleaning function, it includes the component of following weight percent:
Nano pulp 25%
Nano core-shell silicon dioxide microsphere lotion 75%；
Wherein, the nano pulp consists of the following components in percentage by weight:
Hollow nano structure titanium dioxide microsphere powder 10%
Dispersing agent 1%
Solvent 89%；
Wherein, the nano core-shell silicon dioxide microsphere lotion is the invention name according to application No. is 201610301751.6
Method preparation referred to as in the patent application of " nano core-shell silicon dioxide microsphere and anti-reflection anti-reflection Composite Coatings film liquid application and preparation "
's.
Wherein, hollow nano structure titanium dioxide microsphere powder is produced by Suzhou Na Yin Biotechnology Co., Ltd.
In the present embodiment, solvent is isopropanol.
In the present embodiment, dispersing agent is Silane coupling reagent KH-570.
A kind of preparation method of above-mentioned solar energy glass reflection reducing coating for having self-cleaning function, it is characterised in that: it
The following steps are included:
Step 1 prepares nano pulp: the hollow nano structure titanium dioxide microsphere powder of formula ratio is poured into equipped with molten
In the dispersing apparatus of agent, then the dispersing agent of formula ratio is added thereto while stirring, and carries out dispersion 12h, nano slurry is made
Material；
Step 2 prepares solar energy glass reflection reducing coating: the nano pulp of formula ratio is added to the nanometer of formula ratio
In nucleocapsid silicon dioxide microsphere lotion, and be diluted to the solvent 10% solid content, and be stirred 30min, obtain
The solar energy glass reflection reducing coating for having self-cleaning function.
A kind of high anti-reflection solar energy glass of automatically cleaning, it is characterised in that: be using spraying, dip-coating, lifting, roller coating, spin coating,
Any film plating process in flow coat or brushing film plating process, a kind of above-mentioned solar energy glass for having self-cleaning function is subtracted
Reflective coating is coated on the packaging glass of solar cell substrate after being cleaned and dried, and is dried again through 250 DEG C after its dry tack free
Roasting solidification finally arrives the high anti-reflection solar energy glass of automatically cleaning through 700 DEG C of tempering processing 3min with glass baseplate.
Embodiment 5.
A kind of solar energy glass reflection reducing coating having self-cleaning function, it includes the component of following weight percent:
Nano pulp 5%
Nano core-shell silicon dioxide microsphere lotion 95%；
Wherein, the nano pulp consists of the following components in percentage by weight:
Hollow nano structure titanium dioxide microsphere powder 3%
Dispersing agent 0.5%
Solvent 96.5%.
Wherein, the nano core-shell silicon dioxide microsphere lotion is the invention name according to application No. is 201610301751.6
Method preparation referred to as in the patent application of " nano core-shell silicon dioxide microsphere and anti-reflection anti-reflection Composite Coatings film liquid application and preparation "
's.
Wherein, hollow nano structure titanium dioxide microsphere powder is produced by Suzhou Na Yin Biotechnology Co., Ltd.
In the present embodiment, solvent is the composition of propylene glycol monomethyl ether and butyl acetate.
In the present embodiment, dispersing agent is the composition of MQ-568 and silane coupling agent KH-560.
A kind of preparation method of above-mentioned solar energy glass reflection reducing coating for having self-cleaning function, it is characterised in that: it
The following steps are included:
Step 1 prepares nano pulp: the hollow nano structure titanium dioxide microsphere powder of formula ratio is poured into equipped with molten
In the dispersing apparatus of agent, then the dispersing agent of formula ratio is added thereto while stirring, and carries out dispersion 9h, nano slurry is made
Material；
Step 2 prepares solar energy glass reflection reducing coating: the nano pulp of formula ratio is added to the nanometer of formula ratio
In nucleocapsid silicon dioxide microsphere lotion, and be diluted to the solvent 5% solid content, and be stirred 15min, obtain institute
State the solar energy glass reflection reducing coating for having self-cleaning function.
A kind of high anti-reflection solar energy glass of automatically cleaning, it is characterised in that: be using spraying, dip-coating, lifting, roller coating, spin coating,
Any film plating process in flow coat or brushing film plating process, a kind of above-mentioned solar energy glass for having self-cleaning function is subtracted
Reflective coating is coated on the packaging glass of solar cell substrate after being cleaned and dried, and is dried again through 100 DEG C after its dry tack free
Roasting solidification finally arrives the high anti-reflection solar energy glass of automatically cleaning through 550 DEG C of tempering processing 4.5min with glass baseplate.
Embodiment 6.
A kind of solar energy glass reflection reducing coating having self-cleaning function, it includes the component of following weight percent:
Nano pulp 20%
Nano core-shell silicon dioxide microsphere lotion 80%；
Wherein, the nano pulp consists of the following components in percentage by weight:
Hollow nano structure titanium dioxide microsphere powder 8%
Dispersing agent 1%
Solvent 91%.
Wherein, the nano core-shell silicon dioxide microsphere lotion is the invention name according to application No. is 201610301751.6
Method preparation referred to as in the patent application of " nano core-shell silicon dioxide microsphere and anti-reflection anti-reflection Composite Coatings film liquid application and preparation "
's.
Wherein, hollow nano structure titanium dioxide microsphere powder is produced by Suzhou Na Yin Biotechnology Co., Ltd.
In the present embodiment, solvent is the composition of ethyl alcohol, isopropanol and propylene glycol monomethyl ether.
In the present embodiment, dispersing agent is the composition of Tu Yile DS-136, Tu Yile DS-142B and Tu Yile DS-192L.
A kind of preparation method of above-mentioned solar energy glass reflection reducing coating for having self-cleaning function, it is characterised in that: it
The following steps are included:
Step 1 prepares nano pulp: the hollow nano structure titanium dioxide microsphere powder of formula ratio is poured into equipped with molten
In the dispersing apparatus of agent, then the dispersing agent of formula ratio is added thereto while stirring, and carries out dispersion 11h, nano slurry is made
Material；
Step 2 prepares solar energy glass reflection reducing coating: the nano pulp of formula ratio is added to the nanometer of formula ratio
In nucleocapsid silicon dioxide microsphere lotion, and be diluted to the solvent 8% solid content, and be stirred 25min, obtain institute
State the solar energy glass reflection reducing coating for having self-cleaning function.
A kind of high anti-reflection solar energy glass of automatically cleaning, it is characterised in that: be using spraying, dip-coating, lifting, roller coating, spin coating,
Any film plating process in flow coat or brushing film plating process, a kind of above-mentioned solar energy glass for having self-cleaning function is subtracted
Reflective coating is coated on the packaging glass of solar cell substrate after being cleaned and dried, and is dried again through 200 DEG C after its dry tack free
Roasting solidification finally arrives the high anti-reflection solar energy glass of automatically cleaning through 650 DEG C of tempering processing 3.5min with glass baseplate.
Finally it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than the present invention is protected
The limitation of range is protected, although explaining in detail referring to preferred embodiment to the present invention, those skilled in the art are answered
Work as understanding, it can be with modification or equivalent replacement of the technical solution of the present invention are made, without departing from the reality of technical solution of the present invention
Matter and range.
Claims (10)
1. a kind of solar energy glass reflection reducing coating for having self-cleaning function, it is characterised in that: it includes following weight percent
Several components:
Nano pulp 1%~25%
Nano core-shell silicon dioxide microsphere lotion 75%~99%；
Wherein, the nano pulp consists of the following components in percentage by weight:
Hollow nano structure titanium dioxide microsphere powder 1%~10%
Dispersing agent 0.25%~1%
Solvent 89%~98.75%；
Wherein, the nano core-shell silicon dioxide microsphere lotion be according to application No. is 201610301751.6, it is entitled
Prepared by the method in the patent application of " nano core-shell silicon dioxide microsphere and anti-reflection anti-reflection Composite Coatings film liquid application and preparation ".
2. a kind of solar energy glass reflection reducing coating for having self-cleaning function according to claim 1, it is characterised in that:
It includes the component of following weight percent:
Nano pulp 5%~20%
Nano core-shell silicon dioxide microsphere lotion 80%~95%；
Wherein, the nano pulp consists of the following components in percentage by weight:
Hollow nano structure titanium dioxide microsphere powder 3%~8%
Dispersing agent 0.25%~1%
Solvent 91%~96%.
3. a kind of solar energy glass reflection reducing coating for having self-cleaning function according to claim 1, it is characterised in that:
It includes the component of following weight percent:
Nano pulp 10%
Nano core-shell silicon dioxide microsphere lotion 90%；
Wherein, the nano pulp consists of the following components in percentage by weight:
Hollow nano structure titanium dioxide microsphere powder 5%
Dispersing agent 0.5%
Solvent 94.5%.
4. a kind of solar energy glass reflection reducing coating for having self-cleaning function according to claim 1, it is characterised in that:
The hollow nano structure titanium dioxide microsphere powder is produced by Suzhou Na Yin Biotechnology Co., Ltd.
5. a kind of solar energy glass reflection reducing coating for having self-cleaning function according to claim 1, it is characterised in that:
The solvent is one of water, ethyl alcohol, isopropanol, propylene glycol monomethyl ether or butyl acetate or any two or more composition.
6. a kind of solar energy glass reflection reducing coating for having self-cleaning function according to claim 1, it is characterised in that:
The dispersing agent be Tu Yile DS-136, Tu Yile DS-142B, Tu Yile DS-192L, Disuper S18, Disuper S19,
TDL-ND1, MQ-568, silane coupling agent KH-560, three ethoxy of Silane coupling reagent KH-570, methyltrimethoxysilane or methyl
One of base silane or any two or more composition.
7. a kind of system for the solar energy glass reflection reducing coating for having self-cleaning function described in claim 1 to 6 any one
Preparation Method, it is characterised in that: it the following steps are included:
Step 1 prepares nano pulp: the hollow nano structure titanium dioxide microsphere powder of formula ratio is poured into equipped with solvent
In dispersing apparatus, then the dispersing agent of formula ratio is added thereto while stirring, and is dispersed, nano pulp is made；
Step 2 prepares solar energy glass reflection reducing coating: the nano pulp of formula ratio is added to the nano core-shell of formula ratio
In silicon dioxide microsphere lotion, and certain solid content is diluted to the solvent, and be stirred, obtain it is described have from
The solar energy glass reflection reducing coating of cleaning function.
8. a kind of preparation method of solar energy glass reflection reducing coating for having self-cleaning function according to claim 7,
It is characterized by: the time of the dispersion is 8h~12h in the step 1.
9. a kind of preparation method of solar energy glass reflection reducing coating for having self-cleaning function according to claim 7,
It is characterized by: in the step 2, and be diluted to the solvent 3%~10% solid content；The mixing time is
10min~30min.
10. a kind of high anti-reflection solar energy glass of automatically cleaning, it is characterised in that: be using spraying, dip-coating, lifting, roller coating, spin coating,
Any film plating process in flow coat or brushing film plating process, one kind described in claim 1 to 6 any one is had from clear
The solar energy glass reflection reducing coating of clean function is coated on the packaging glass of solar cell substrate after being cleaned and dried, to its table
Again through 80 DEG C~250 DEG C baking-curings after face is dry, finally with glass baseplate through 500 DEG C~700 DEG C tempering processing 3min~
5min is to get to the high anti-reflection solar energy glass of automatically cleaning.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811408822.8A CN109651863B (en) | 2018-11-23 | 2018-11-23 | Solar glass antireflection coating with self-cleaning function, preparation method thereof and self-cleaning high-antireflection solar glass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811408822.8A CN109651863B (en) | 2018-11-23 | 2018-11-23 | Solar glass antireflection coating with self-cleaning function, preparation method thereof and self-cleaning high-antireflection solar glass |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109651863A true CN109651863A (en) | 2019-04-19 |
| CN109651863B CN109651863B (en) | 2021-06-01 |
Family
ID=66112230
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811408822.8A Active CN109651863B (en) | 2018-11-23 | 2018-11-23 | Solar glass antireflection coating with self-cleaning function, preparation method thereof and self-cleaning high-antireflection solar glass |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109651863B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110307479A (en) * | 2019-07-02 | 2019-10-08 | 苏州蓝锐纳米科技有限公司 | A kind of AR film plating layer, membrane structure, the LED light and lens for being coated with AR coating liquid |
| CN110982325A (en) * | 2019-12-31 | 2020-04-10 | 上海特栎材料科技有限公司 | Antireflection, antistatic and super-hydrophilic coating composition, coating and product |
| CN111060995A (en) * | 2020-01-13 | 2020-04-24 | 苏州众为光电有限公司 | Antireflection film and optical lens |
| CN111883613A (en) * | 2020-07-10 | 2020-11-03 | 上海纳米技术及应用国家工程研究中心有限公司 | Method for preparing fluorine-containing self-cleaning coating on outdoor solar cell panel |
| CN115010380A (en) * | 2022-08-09 | 2022-09-06 | 中国华能集团清洁能源技术研究院有限公司 | Preparation method of photovoltaic glass based on disordered photonic crystals |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013042007A (en) * | 2011-08-17 | 2013-02-28 | Fujifilm Corp | Back sheet for solar cell module and solar cell module |
| CN104059420A (en) * | 2014-05-22 | 2014-09-24 | 张扬 | Nano-paste, self-cleaning coating liquid and thermal insulating coating liquid as well as transparent substrates and preparation methods thereof |
| CN105964195A (en) * | 2016-05-06 | 2016-09-28 | 东莞南玻太阳能玻璃有限公司 | Nanometer core-shell silicon dioxide microsphere as well as preparation and application of antireflection composite coating solution |
-
2018
- 2018-11-23 CN CN201811408822.8A patent/CN109651863B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013042007A (en) * | 2011-08-17 | 2013-02-28 | Fujifilm Corp | Back sheet for solar cell module and solar cell module |
| CN104059420A (en) * | 2014-05-22 | 2014-09-24 | 张扬 | Nano-paste, self-cleaning coating liquid and thermal insulating coating liquid as well as transparent substrates and preparation methods thereof |
| CN105964195A (en) * | 2016-05-06 | 2016-09-28 | 东莞南玻太阳能玻璃有限公司 | Nanometer core-shell silicon dioxide microsphere as well as preparation and application of antireflection composite coating solution |
Non-Patent Citations (1)
| Title |
|---|
| 朱发德等: "二氧化钛中空微球材料的研究进展", 《材料导报》 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110307479A (en) * | 2019-07-02 | 2019-10-08 | 苏州蓝锐纳米科技有限公司 | A kind of AR film plating layer, membrane structure, the LED light and lens for being coated with AR coating liquid |
| CN110307479B (en) * | 2019-07-02 | 2021-01-01 | 苏州蓝锐纳米科技有限公司 | AR coating layer, film structure, LED lamp sprayed with AR coating liquid and lens |
| CN110982325A (en) * | 2019-12-31 | 2020-04-10 | 上海特栎材料科技有限公司 | Antireflection, antistatic and super-hydrophilic coating composition, coating and product |
| CN111060995A (en) * | 2020-01-13 | 2020-04-24 | 苏州众为光电有限公司 | Antireflection film and optical lens |
| CN111060995B (en) * | 2020-01-13 | 2021-07-30 | 苏州众为光电有限公司 | Antireflection film and optical lens |
| CN111883613A (en) * | 2020-07-10 | 2020-11-03 | 上海纳米技术及应用国家工程研究中心有限公司 | Method for preparing fluorine-containing self-cleaning coating on outdoor solar cell panel |
| CN111883613B (en) * | 2020-07-10 | 2022-04-05 | 上海纳米技术及应用国家工程研究中心有限公司 | Method for preparing fluorine-containing self-cleaning coating on outdoor solar cell panel |
| CN115010380A (en) * | 2022-08-09 | 2022-09-06 | 中国华能集团清洁能源技术研究院有限公司 | Preparation method of photovoltaic glass based on disordered photonic crystals |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109651863B (en) | 2021-06-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109651863A (en) | A kind of solar energy glass reflection reducing coating having self-cleaning function and preparation method thereof and the high anti-reflection solar energy glass of automatically cleaning | |
| CN102061111B (en) | Preparation method of self-cleaning ceramic nanometer glass antireflective coating material and preparation method of reflection deducting coating | |
| CN109665719A (en) | A kind of high anti-reflection coating solution of automatically cleaning and preparation method thereof and the high anti-reflection solar energy glass of automatically cleaning | |
| CN101333075B (en) | Method for preparing self-cleaning toughened glass | |
| CN104671672A (en) | Anti-reflective film-plating liquid and preparation method thereof, photovoltaic glass and preparation method of photovoltaic glass, and solar cell module | |
| CN102702806A (en) | Preparation and application of self-cleaning synergistic solar paint | |
| CN102795786A (en) | Super hydrophobic self-cleaning coating and preparation method thereof | |
| CN105399340A (en) | Super-hydrophobic high-transmittance SiO2 anti-reflecting thin film and preparation method thereof | |
| CN110002767A (en) | A kind of preparation method of the hydrophobic film of high transparency for photovoltaic glass | |
| CN104692671A (en) | Preparation method of super-hydrophobic self-cleaning glass based on ZnO nano array coating | |
| CN108948802A (en) | A kind of automatic cleaning coating of translucency enhancing | |
| CN110330839A (en) | Efficient non-sticky hydrophobic coating and preparation method thereof for timber, metal and frosting | |
| CN103059617B (en) | Preparation method for nanometer anti-reflection self-cleaning coating solution | |
| CN102433978B (en) | Novel nanometer titanium dioxide self-cleaning fluorine-carbon aluminum single sheet as well as low-temperature preparation method and application thereof | |
| CN111019522A (en) | Solar module coating with double functions of self-cleaning and anti-reflection and preparation method thereof | |
| CN201853715U (en) | Dustproof self-cleaning type solar cell component | |
| CN202523741U (en) | Antireflection glass used for solar battery packaging | |
| CN101525934B (en) | Spraying process of anti-ultraviolet self-cleaning coat of outer wall of building under normal temperature | |
| CN110606670A (en) | Preparation method of broad-spectrum anti-reflection super-hydrophobic photovoltaic glass | |
| CN115806748A (en) | Preparation method and application of nano coating material for photovoltaic panel | |
| CN202651126U (en) | Nano solar cell assembly with self-cleaning function | |
| CN108855059A (en) | A kind of fly ash float load silver oxide composite photo-catalyst and preparation method thereof | |
| CN106277839A (en) | A kind of laminated film with super-amphiphobic automatically cleaning and anti-reflection performance and preparation method thereof | |
| CN104437516A (en) | CuCrO2/TiO2 composite photocatalyst and preparation method thereof | |
| CN104669717A (en) | Anti-reflective film and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |