CN109594174A - A kind of graphene function of driving mosquitoes fabric and preparation method thereof - Google Patents

A kind of graphene function of driving mosquitoes fabric and preparation method thereof Download PDF

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Publication number
CN109594174A
CN109594174A CN201811557178.0A CN201811557178A CN109594174A CN 109594174 A CN109594174 A CN 109594174A CN 201811557178 A CN201811557178 A CN 201811557178A CN 109594174 A CN109594174 A CN 109594174A
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China
Prior art keywords
graphene
fabric
yarn
fiber
driving mosquitoes
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Application number
CN201811557178.0A
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Chinese (zh)
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CN109594174B (en
Inventor
沙嫣
沙晓林
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Nantong Johnson Graphene Technology Co Ltd
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Nantong Johnson Graphene Technology Co Ltd
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    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01—Natural vegetable fibres
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01—Natural vegetable fibres
    • D10B2201/02—Cotton
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01—Natural vegetable fibres
    • D10B2201/04—Linen
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20—Cellulose-derived artificial fibres
    • D10B2201/22—Cellulose-derived artificial fibres made from cellulose solutions
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20—Cellulose-derived artificial fibres
    • D10B2201/22—Cellulose-derived artificial fibres made from cellulose solutions
    • D10B2201/24—Viscose
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00—Protein-based fibres, e.g. animal fibres
    • D10B2211/01—Natural animal fibres, e.g. keratin fibres
    • D10B2211/04—Silk
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/10—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/13—Physical properties anti-allergenic or anti-bacterial

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Woven Fabrics (AREA)

Abstract

The present invention provides a kind of graphene function of driving mosquitoes fabrics, the fabric is weaved to obtain by warp thread and weft yarn, at least one of the warp thread and weft yarn are graphene yarn, and graphene yarn includes the following component of percentage: graphene fiber: 30~50%；Other fibers: 50~60%.The present invention is with following the utility model has the advantages that natural repellant has many advantages, as low toxicity or it is nontoxic, burning heat sensation will not be generated to skin, smell is pure and fresh, medicament residue is not had after use, it is degradable, no pollution to the environment etc., but it is generally lower than synthesis repellant in terms of mosquito repellent high efficiency and persistence.

Description

A kind of graphene function of driving mosquitoes fabric and preparation method thereof
Technical field
The present invention relates to a kind of graphene function of driving mosquitoes fabrics and preparation method thereof, belong to functional fabric technical field.
Background technique
At this stage mosquito-repellent fabric it is general there are two types of, one kind doing mosquito repellent interlayer between base cloth layer and precoat, one is by Treated that fibrage forms for mosquito repellent liquid.Wherein, general all containing synthesis repellent agent in mosquito repellent liquid, such as DEET (N, N-diethyl Toluamide between base), this kind of repellent agent can generate adverse effect to human health, such as can trigger the nervous system disease, brain Disease and skin disease etc..
Summary of the invention
For the defects in the prior art, the object of the present invention is to provide a kind of graphene function of driving mosquitoes fabric and its preparations Method.
The present invention is achieved by the following technical solutions:
In a first aspect, weaving to obtain by warp thread and weft yarn the present invention provides a kind of graphene function of driving mosquitoes fabric, institute Stating at least one of warp thread and weft yarn is graphene yarn, and graphene yarn includes the following component of percentage:
Graphene fiber: 40~50%；
Other fibers: 50~60%.
Preferably, the weft yarn is graphene yarn, and the warp thread is spun polyester thread, nylon yarn, acrylic fibers One of yarn, cotton, bast yarn and thread, viscose yarn are a variety of.
Preferably, the graphene fiber is graphene chinlon filament, graphene polyester filament, graphene viscose One or more of long filament.
Preferably, in the graphene fiber, graphene mass content is 0.5~5%, the graphene fiber The graphene raw material used is one of graphene, graphene oxide, amino modified graphene or several.
Preferably, the preparation method of the graphene fiber is melt spinning method, dry spinning method, electrostatic spinning One of method, solution spinning.
Preferably, other described fibers include cotton fiber, viscose fiber, silk fiber, tencel fiber, flax fibre One or more of dimension.
Second aspect, the present invention also provides a kind of preparation method of graphene function of driving mosquitoes fabric as the aforementioned, packets Include following steps:
S1, warp thread and weft yarn are weaved using loom；
S2, desizing and heat preservation are carried out；
S3, it is dyed and is cleaned；
S4, it is dried and is formed.
Preferably, in step S1, the weaving Shi Shangji breadth is 145cm, weft density on machine 150/in, is utilized 1-10 pages of brown method is worn along wearing, literary version uses plain weave.
Preferably, in step S1,40~45 minutes are kept the temperature at 90~95 DEG C, bath raio: 1:(10~15), solution PH value controls in 4~5, step S3, and dyeing temperature is not above 90 DEG C.
Preferably, it in step S4, is dried using forming machine, 85~90 DEG C of temperature, 10~100 points of drying time Clock；Add appropriate waterproofing agent and softening agent when sizing, liquid carrying rate 1.5%, at 100 DEG C, with 1~2m/min of cloth transmission speed into Row sizing.
Compared with prior art, the present invention have it is following the utility model has the advantages that
1, natural repellant has many advantages, such as low toxicity or nontoxic, will not generate burning heat sensation to skin, and smell is pure and fresh, Medicament residue is not had after use, degradable, no pollution to the environment etc., but it is universal low in terms of mosquito repellent high efficiency and persistence In synthesis repellant, graphene fabric of the invention is added without chemical reagent, harmless, very environmentally friendly；
2, it is tested according to GB30126, graphene fabric of the invention walks quickly and keeps away rate and can reach A grades to mosquito, has pole Strong walks quickly and keeps away effect, while being tested according to standard GB20944, and graphene fabric of the invention is to staphylococcus aureus, white Candida albicans, Escherichia coli bacteriostasis rate can reach 99.9%；
3, graphene fabric process flow of the invention is simple, and cost is relatively low.
Specific embodiment
The present invention is described in detail combined with specific embodiments below.Following embodiment will be helpful to the technology of this field Personnel further understand the present invention, but the invention is not limited in any way.It should be pointed out that the ordinary skill of this field For personnel, without departing from the inventive concept of the premise, various modifications and improvements can be made.These belong to the present invention Protection scope.
Embodiment 1
The present embodiment is related to a kind of preparation method of graphene function of driving mosquitoes fabric, specifically comprises the following steps:
S1, by graphene chinlon filament and cotton fiber according to the weight ratio of 4:6, graphene is prepared by melt spinning method Yarn is weaved using loom using graphene yarn as weft yarn, using spun polyester thread as warp thread, control weaving Shi Shangji Breadth is 145cm, weft density on machine 150/in, and using wearing brown method page 1~10 along wearing, literary version uses plain weave；
S2, desizing and heat preservation are carried out, keep the temperature 40~45 minutes at 90~95 DEG C, bath raio: 1:(10~15), solution pH value Control is 4~5；
S3, it is dyed and is cleaned, control dyeing temperature is not higher than 90 DEG C；
S4, it is dried and is formed, dried using forming machine, 85~90 DEG C of temperature, drying time 10~100 minutes；It is fixed Add appropriate waterproofing agent and softening agent when type, liquid carrying rate 1.5% is determined at 100 DEG C with 1~2m/min of cloth transmission speed Type.
Embodiment 2
The present embodiment is related to a kind of preparation method of graphene function of driving mosquitoes fabric, specifically comprises the following steps:
S1, by graphene polyester filament and viscose fiber according to the weight ratio of 6:4, graphite is prepared by dry spinning method Alkene yarn is weaved using loom using graphene yarn as warp thread, using nylon yarn as weft yarn, when control weaving on Machine breadth is 145cm, weft density on machine 150/in, and using wearing brown method page 1~10 along wearing, literary version uses plain weave；
S2, desizing and heat preservation are carried out, keep the temperature 40~45 minutes at 90~95 DEG C, bath raio: 1:(10~15), solution pH value Control is 4~5；
S3, it is dyed and is cleaned, control dyeing temperature is not higher than 90 DEG C；
S4, it is dried and is formed, dried using forming machine, 85~90 DEG C of temperature, drying time 10~100 minutes；It is fixed Add appropriate waterproofing agent and softening agent when type, liquid carrying rate 1.5% is determined at 100 DEG C with 1~2m/min of cloth transmission speed Type.
Embodiment 3
The present embodiment is related to a kind of preparation method of graphene function of driving mosquitoes fabric, specifically comprises the following steps:
S1, by graphene viscose filament yarn and silk fiber according to the weight ratio of 1:1, graphite is prepared by method of electrostatic spinning Alkene yarn is weaved using loom using graphene yarn as warp thread, using Acrylic Fiber as weft yarn, when control weaving on Machine breadth is 145cm, weft density on machine 150/in, and using wearing brown method page 1~10 along wearing, literary version uses plain weave；
S2, desizing and heat preservation are carried out, keep the temperature 40~45 minutes at 90~95 DEG C, bath raio: 1:(10~15), solution pH value Control is 4~5；
S3, it is dyed and is cleaned, control dyeing temperature is not higher than 90 DEG C；
S4, it is dried and is formed, dried using forming machine, 85~90 DEG C of temperature, drying time 10~100 minutes；It is fixed Add appropriate waterproofing agent and softening agent when type, liquid carrying rate 1.5% is determined at 100 DEG C with 1~2m/min of cloth transmission speed Type.
Specific embodiments of the present invention are described above.It is to be appreciated that the invention is not limited to above-mentioned Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow Ring substantive content of the invention.

Claims (10)

1. a kind of graphene function of driving mosquitoes fabric, which is characterized in that weave to obtain by warp thread and weft yarn, in the warp thread and weft yarn At least one be graphene yarn, graphene yarn includes the following component of percentage:
Graphene fiber: 40~50%；
Other fibers: 50~60%.
2. graphene function of driving mosquitoes fabric as described in claim 1, which is characterized in that the weft yarn is graphene yarn, institute The warp thread stated is one of spun polyester thread, nylon yarn, Acrylic Fiber, cotton, bast yarn and thread, viscose yarn or a variety of.
3. graphene function of driving mosquitoes fabric as described in claim 1, which is characterized in that the graphene fiber is graphene brocade One or more of synthetic fibre long filament, graphene polyester filament, graphene viscose filament yarn.
4. graphene function of driving mosquitoes fabric as claimed in claim 1 or 3, which is characterized in that in the graphene fiber, graphite Alkene mass content is 0.5~5%, and the graphene raw material that the graphene fiber uses changes for graphene, graphene oxide, amino One of property graphene is several.
5. graphene function of driving mosquitoes fabric as claimed in claim 4, which is characterized in that the preparation method of the graphene fiber For one of melt spinning method, dry spinning method, method of electrostatic spinning, solution spinning.
6. graphene function of driving mosquitoes fabric as described in claim 1, which is characterized in that other described fibers include cotton fiber, One or more of viscose fiber, silk fiber, tencel fiber, flax fiber.
7. a kind of preparation method of graphene function of driving mosquitoes fabric as described in claim 1, which is characterized in that including walking as follows It is rapid:
S1, warp thread and weft yarn are weaved using loom；
S2, desizing and heat preservation are carried out；
S3, it is dyed and is cleaned；
S4, it is dried and is formed.
8. the preparation method of graphene function of driving mosquitoes fabric as claimed in claim 7, which is characterized in that described in step S1 Weaving Shi Shangji breadth is 145cm, weft density on machine 150/in, and using wearing brown method page 1~10 along wearing, literary version is knitted using plain weave It makes.
9. the preparation method of graphene function of driving mosquitoes fabric as claimed in claim 7, which is characterized in that in step S2,90 40~45 minutes are kept the temperature at~95 DEG C, bath raio: 1:(10~15), solution pH value controls in 4~5, step S3, and dyeing temperature is not 90 DEG C can be higher than.
10. the preparation method of graphene function of driving mosquitoes fabric as claimed in claim 7, which is characterized in that in step S4, utilize Forming machine drying, 85~90 DEG C of temperature, drying time 10~100 minutes；Add appropriate waterproofing agent and softening agent, liquid carrying rate when sizing 1.5%, at 100 DEG C, carried out shaping with 1~2m/min of cloth transmission speed.
CN201811557178.0A 2018-12-19 2018-12-19 Graphene fabric with mosquito repelling function and preparation method thereof Active CN109594174B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110575034A (en) * 2019-07-30 2019-12-17 江苏缔凡蚕丝科技创意园有限公司 silk graphene quilt
CN111005121A (en) * 2019-12-20 2020-04-14 恩平锦兴纺织印染企业有限公司 Combed cotton/graphene and chinlon interwoven fabric and production process thereof
CN115012094A (en) * 2022-07-12 2022-09-06 席梦思床褥家具（苏州）有限公司 Anti-splashing fabric for tencel graphene blended yarn
CN116103811A (en) * 2022-12-22 2023-05-12 福建省天鑫高科新材料有限公司 Graphene mosquito-repellent fabric and preparation method thereof

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CN108914314A (en) * 2018-07-12 2018-11-30 宜宾丝丽雅股份有限公司 Manufacturing process of fabric blended with graphene fibers

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110575034A (en) * 2019-07-30 2019-12-17 江苏缔凡蚕丝科技创意园有限公司 silk graphene quilt
CN111005121A (en) * 2019-12-20 2020-04-14 恩平锦兴纺织印染企业有限公司 Combed cotton/graphene and chinlon interwoven fabric and production process thereof
CN115012094A (en) * 2022-07-12 2022-09-06 席梦思床褥家具（苏州）有限公司 Anti-splashing fabric for tencel graphene blended yarn
CN116103811A (en) * 2022-12-22 2023-05-12 福建省天鑫高科新材料有限公司 Graphene mosquito-repellent fabric and preparation method thereof

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