CN1095053A - A kind of surface decorating method of ceramic - Google Patents

A kind of surface decorating method of ceramic Download PDF

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Publication number
CN1095053A
CN1095053A CN 93105355 CN93105355A CN1095053A CN 1095053 A CN1095053 A CN 1095053A CN 93105355 CN93105355 CN 93105355 CN 93105355 A CN93105355 A CN 93105355A CN 1095053 A CN1095053 A CN 1095053A
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CN
China
Prior art keywords
ceramic
coating
metal
slip
pattern
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Pending
Application number
CN 93105355
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Chinese (zh)
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杨德庆
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Individual
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Individual
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Priority to CN 93105355 priority Critical patent/CN1095053A/en
Publication of CN1095053A publication Critical patent/CN1095053A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • C04B2111/00577Coating or impregnation materials applied by spraying

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Coating By Spraying Or Casting (AREA)

Abstract

A kind of surface decorating method of ceramic, its making processes is for preparing crude surface on the ceramic surface, with hot spray process to its metallize layer, metallic coating is carried out application of slip pre-treatment, and the surperficial coating enamel to needing in the metallic coating to cover, the goods heating is burnt till, the metal finishing finishing coat of the not application of slip is polished, polished finish is carried out aftertreatment to metal covering.The more traditional cloisonne ' products made from the present invention of porcelain body cloisonne ' products more is being full of variety aspect the selection of metal species and moulding and the design of patterns, and artistic expression is stronger, and kind is abundanter, and cost is lower.

Description

A kind of surface decorating method of ceramic
What the present invention relates to is the first metallize of a kind of employing, and the mode of the back application of slip is carried out the method for surface decoration to ceramic.
Had research in non-metal product surface decorative metal method of patterning such as potteries, as disclosing a kind of making method of metallic decorative pattern for Chinese patent CN92104962.5 number, wherein mention can be on ceramic the spraying and decorating metal pattern, this patent has designed first making and has protruded pattern, metallize then, again metallic coating is carried out variable color and handle, to protruding the method that pattern carries out grinding process, strengthen the artistic effect of metal pattern at last with this.But,, thereby influenced whole decorative effect so the coating of the non-pattern part of not polishing seems more coarse because the metal level of spraying is particulate state.
The objective of the invention is to avoid above-mentioned weak point of the prior art, and a kind of method of covering the surface of not polishing (non metallic decorative face) in the metallic coating is provided, can on the ceramic surface, make metal finishing face fineness alternate with glaze or embedding mutually with this method and decorate.
Purpose of the present invention can reach by following measure:
At first on the ceramic surface, prepare the crude surface that is fit to carry out metal thermal spraying, then to its metallize layer, application of slip pre-treatment is carried out to metallic coating in the spraying back, surface (can the be referred to as non metallic decorative face) coating enamel of back to be dried to needing in the coating to cover, after to be dried goods being put into process furnace burns till, burn till the coating of the back being covered by the not application of slip (can be referred to as the metal finishing face) and polish, make it appear metalluster.Be polished to metal covering then and the vitreous enamel face all meets the requirements of smooth finish, can also carry out aftertreatment to metal covering as required.
Can go out to protrude pattern in the ceramic surface preparation in the above method, after the spraying with the protrusion pattern part of coating as the metal finishing face, the non-protruding pattern part application of slip of coating is covered.Also can will the metallic coating in the monoblock zone of protruding pattern be arranged as the metal finishing face, this moment is in the goods application of slip, after burning till, can remove this decorative cover metal with pickling, the zone of oxidation on the coating is carried out antique-imitation to coating again or other variable color is handled, then the protrusion pattern part of coating is polished, polished finish, the non-protruding pattern part of coating then keeps the state after variable color is handled.
Preparing crude method on ceramic surface, can be to spray one deck grouting mud with spray gun on the unpainted clay idol surface before pottery burns till, and makes evenly absorption last layer mud particle of its surface, promptly obtains crude ceramic surface after burning till.
It can be to cut out concavo-convex pattern earlier on unpainted clay idol shaping mould therefor that method of patterning is protruded in preparation, again with this mould slip casting or suppress and have the shaping unpainted clay idol that protrudes pattern, also can make the shaping unpainted clay idol earlier, on unpainted clay idol, impress out again or pile by hand and carve the protrusion pattern, the figure of pattern goes out highly can select as required to be provided with, and also pattern can be designed to contour plane.
The metal of spraying can be copper, aluminium, iron, stainless steel, gold and silver etc., both can carry out metal thermal spraying, but the metal of the application of slip again.
Also can only carry out the metal spraying and the application of slip in order to last method to the local surfaces of ceramic, if only carry out locally sprayed, the surface of then not carrying out metal spraying on the ceramic roughening treatment of after unpainted clay idol is shaped, can not whitewashing, and can go up suitable ceramic glaze as required.
The present invention has following advantage compared to existing technology:
1, the present invention can make various metal coverings or the mutually ornament layer of embedding alternate with the vitreous enamel face on the ceramic surface.It is a kind of porcelain body cloisonne goods, and its more traditional cloisonne goods more is being full of variety aspect the selection of metal species and moulding and the design of patterns, thereby artistic expression is stronger, and kind is abundanter, and cost is lower.
2, the present invention can produce the surface and decorate ceramic glaze simultaneously, the ceramic of cloisonne pattern and bronze pattern.
3, the present invention is sprayed one deck grouting mud and is carried out the spraying pre-treating process of the method for ceramic surface roughening as stupalith on unpainted clay idol, ceramic surface roughness than other method preparation is more moderate, the surface evenly, the metal level and the ceramic matrix bonding strength height of spraying on the surface, metallic coating is uniform and smooth more.
The present invention will now be further detailed embodiment:
At first select one of design to be carved with the gypsum vase model that protrudes pattern, turn over then and make the grouting plaster mould, making the surface with slip casting method again has the vase unpainted clay idol that protrudes pattern.With varnish spray gun one deck grouting mud is sprayed on the unpainted clay idol surface.Drying is after high temperature sintering obtains porcelain body, bronze to the porcelain body surface with the arc process spraying, be sprayed onto 0.3 millimeter of thick coating, the spraying back is earlier with concentration 10%, the sodium hydroxide solution that temperature is 80~90 ℃ is handled, coating is to remove degreasing, be that 10~20% sulphuric acid soln carries out cleanup acid treatment to coating with concentration again, and then through washing, dry back is coated with the glaze with method thinkling sound to the non metallic decorative face (non-protruding patterned surfaces) of metallic coating, after to be dried vase being put into process furnace burns till, firing temperature is 750~800 ℃, and 4 minutes time can burn till, and vase is taken out in the cooling back, metal finishing face (convex surface) is polished, exposed until metal covering, polish then, metal covering and enamel glaze are all met the requirements of till the smooth finish.Promptly make porcelain body cloisonne vase.Can carry out gold-plated to this vase.
Among the above embodiment, if design is only to the local surfaces metallize, then can be only during the attached mud of spray on unpainted clay idol to the surface spray of need metallize with mud (available paper or cloth block the not surface of metallize), the surface of not spraying mud can more than suitable ceramic glaze, also should be when the metallize only to the surface spraying of no glaze, spraying back is taken off ester as the aforementioned to coating and is deoiled, pickling, the application of slip, burn till, grinding process, promptly make the ceramic vase that the part has cloisonne to decorate.

Claims (6)

1, a kind of ceramic surface decorating method is characterized in that, is made of following steps:
A) on the ceramic surface, prepare crude surface,
B) with hot spray process to its metallize layer,
C) metallic coating is carried out application of slip pre-treatment,
D) the surperficial coating enamel to needing in the metallic coating to cover,
E) the goods heating is burnt till,
F) the metal finishing finishing coat of the not application of slip is polished, polished finish,
G) metal covering is carried out aftertreatment.
2, the surface decorating method of a kind of ceramic according to claim 1, it is characterized in that: can on ceramic, prepare the protrusion pattern, can the non-protruding pattern part application of slip of coating be covered with the protrusion pattern part of coating as the metal finishing face after the spraying.Also can will the metallic coating in the monoblock zone of protruding pattern be arranged as the metal finishing face.
3, the surface decorating method of a kind of ceramic according to claim 2, the monoblock zone of protruding pattern will be arranged as the metal finishing face, it is characterized in that: at goods through the application of slip, after burning till, can remove zone of oxidation on this decorative cover metallic coating with pickling, again this coating is carried out antique-imitation or other variable color and handles, then to the protrusion pattern part of coating polish, polished finish, the non-protruding pattern part of coating keeps the state after variable color is handled.
4, the surface decorating method of a kind of ceramic according to claim 1, it is characterized in that: on crude method of preparation on the ceramic surface can be unpainted clay idol surface pottery burns till before, spray one deck grouting mud with spray gun, make evenly absorption last layer mud particle of its surface, again through being fired into crude ceramic surface.
5, the surface decorating method of a kind of ceramic according to claim 2, it is characterized in that: it can be to cut out concavo-convex pattern earlier on unpainted clay idol shaping mould therefor that method of patterning is protruded in preparation, then with this mould slip casting or suppress and have the shaping unpainted clay idol that protrudes pattern, also can make the shaping unpainted clay idol earlier, print off or carve the protrusion pattern in the unpainted clay idol surface pressure again with hand heap.
6, the surface decorating method of a kind of ceramic according to claim 1 is characterized in that: the metal of spraying can be copper, aluminium, iron, stainless steel, gold and silver etc., both can carry out thermospray, again can be at the metal of its surperficial enamel ccating.
CN 93105355 1993-05-08 1993-05-08 A kind of surface decorating method of ceramic Pending CN1095053A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 93105355 CN1095053A (en) 1993-05-08 1993-05-08 A kind of surface decorating method of ceramic

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 93105355 CN1095053A (en) 1993-05-08 1993-05-08 A kind of surface decorating method of ceramic

Publications (1)

Publication Number Publication Date
CN1095053A true CN1095053A (en) 1994-11-16

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CN 93105355 Pending CN1095053A (en) 1993-05-08 1993-05-08 A kind of surface decorating method of ceramic

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CN (1) CN1095053A (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000009306A1 (en) * 1998-08-14 2000-02-24 Seagull Decor Co., Ltd. A method of producing pottery ornament densely covered with tiny edges and corners
EP1780297A3 (en) * 2005-10-18 2007-07-04 T.W.R. Sas Di Mario Doda & C. Process for coating and/or decorating ceramic articles and articles thus obtainable
CN101921139A (en) * 2010-09-21 2010-12-22 上海高诚艺术包装有限公司 Manufacture method of ceramic wine bottle with liquid gold
CN101921138A (en) * 2010-09-14 2010-12-22 上海高诚艺术包装有限公司 Method for making cloisonne patterns on ceramic matrix
CN101921140A (en) * 2010-09-21 2010-12-22 上海高诚艺术包装有限公司 Method for manufacturing blue-and-white gilded pattern on ceramic matrix
CN102040399A (en) * 2009-10-15 2011-05-04 章云树 Method for manufacturing three-dimensional artistic glazed brick
CN101376602B (en) * 2008-09-23 2011-12-21 林敏� Method for forming one layer or multiple layers of metal patterns on surface of ceramic products
CN101652338B (en) * 2007-02-19 2013-06-12 齐尼亚科技有限公司 Method, printing device, and formulations for decorating glass or ceramic items
CN105237023A (en) * 2015-09-28 2016-01-13 深圳市金宝盈科技发展有限公司 Novel ceramic product and processing method thereof
CN109111243A (en) * 2018-09-20 2019-01-01 界首永恩机电科技有限公司 A kind of method that ceramics surface sprays complex copper powder
CN110713392A (en) * 2018-07-13 2020-01-21 江苏扬中印刷有限公司 Printing method of ceramic product

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000009306A1 (en) * 1998-08-14 2000-02-24 Seagull Decor Co., Ltd. A method of producing pottery ornament densely covered with tiny edges and corners
EP1780297A3 (en) * 2005-10-18 2007-07-04 T.W.R. Sas Di Mario Doda & C. Process for coating and/or decorating ceramic articles and articles thus obtainable
CN101652338B (en) * 2007-02-19 2013-06-12 齐尼亚科技有限公司 Method, printing device, and formulations for decorating glass or ceramic items
CN101376602B (en) * 2008-09-23 2011-12-21 林敏� Method for forming one layer or multiple layers of metal patterns on surface of ceramic products
CN102040399A (en) * 2009-10-15 2011-05-04 章云树 Method for manufacturing three-dimensional artistic glazed brick
CN101921138A (en) * 2010-09-14 2010-12-22 上海高诚艺术包装有限公司 Method for making cloisonne patterns on ceramic matrix
CN101921138B (en) * 2010-09-14 2012-06-27 上海高诚艺术包装有限公司 Method for making cloisonne patterns on ceramic matrix
CN101921139B (en) * 2010-09-21 2012-06-27 上海高诚艺术包装有限公司 Manufacture method of ceramic wine bottle with liquid gold
WO2012037865A1 (en) * 2010-09-21 2012-03-29 上海高诚艺术包装有限公司 Method for manufacturing blue and white pattern having gold outline on porcelain clay body
CN101921140A (en) * 2010-09-21 2010-12-22 上海高诚艺术包装有限公司 Method for manufacturing blue-and-white gilded pattern on ceramic matrix
CN101921140B (en) * 2010-09-21 2012-07-04 上海高诚艺术包装有限公司 Method for manufacturing blue-and-white gilded pattern on ceramic matrix
CN101921139A (en) * 2010-09-21 2010-12-22 上海高诚艺术包装有限公司 Manufacture method of ceramic wine bottle with liquid gold
CN105237023A (en) * 2015-09-28 2016-01-13 深圳市金宝盈科技发展有限公司 Novel ceramic product and processing method thereof
CN110713392A (en) * 2018-07-13 2020-01-21 江苏扬中印刷有限公司 Printing method of ceramic product
CN109111243A (en) * 2018-09-20 2019-01-01 界首永恩机电科技有限公司 A kind of method that ceramics surface sprays complex copper powder
CN109111243B (en) * 2018-09-20 2020-12-11 界首永恩机电科技有限公司 Method for spraying composite copper powder on surface of ceramic artwork

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