CN109504516A - A kind of micro emulsion cutting fluid and preparation method thereof suitable for heavy load intermetallic composite coating - Google Patents
A kind of micro emulsion cutting fluid and preparation method thereof suitable for heavy load intermetallic composite coating Download PDFInfo
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- CN109504516A CN109504516A CN201910060102.5A CN201910060102A CN109504516A CN 109504516 A CN109504516 A CN 109504516A CN 201910060102 A CN201910060102 A CN 201910060102A CN 109504516 A CN109504516 A CN 109504516A
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- cutting fluid
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
- C10M2207/2815—Esters of (cyclo)aliphatic monocarboxylic acids used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
- C10M2207/2835—Esters of polyhydroxy compounds used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/284—Esters of aromatic monocarboxylic acids
- C10M2207/2845—Esters of aromatic monocarboxylic acids used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
- C10M2207/289—Partial esters containing free hydroxy groups
- C10M2207/2895—Partial esters containing free hydroxy groups used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/18—Anti-foaming property
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/40—Low content or no content compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/40—Low content or no content compositions
- C10N2030/41—Chlorine free or low chlorine content compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/40—Low content or no content compositions
- C10N2030/43—Sulfur free or low sulfur content compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/245—Soft metals, e.g. aluminum
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/246—Iron or steel
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The micro emulsion cutting fluid and preparation method thereof that the present invention relates to a kind of suitable for heavy load intermetallic composite coating, belongs to technical field of lubricant.Micro emulsion cutting fluid of the invention, including mineral base oil, synthetic ester, extreme pressure anti-wear additives and emulsifier, synthetic ester be one of isooctyl oleate, neopentyl polyol ester, tricarboxymethyl propane oleate, trimellitate, pentaerythritol fatty acid ester or a variety of, emulsifier be fatty acid methyl ester ethoxylate, alkyl phenol polyoxyethylene ether, polyoxyethylene alcohol fatty acid ester and polyol ethers in two kinds and it is two or more.Micro emulsion cutting fluid of the invention is free of sodium nitrite, formaldehyde and all kinds of poisonous and harmful substances, for environmentally friendly machine, unique synthesis Recipe, good lubricating action is played to the intermetallic composite coating under black material heavy load, also there is extraordinary lubricating action to aluminum casting, effectively improves cutter life；Using special emulsifying technology, guarantees the lasting low bubble of emulsion, extend the service life of cutting fluid.
Description
Technical field
The invention belongs to technical field of lubricant, and in particular to a kind of micro emulsion cutting fluid suitable for heavy load intermetallic composite coating
And preparation method thereof.
Background technique
Cutting fluid is a kind of in metal cutting, mill process, for cooling down and lubricating the work of cutter and workpiece
Industry liquid, cutting fluid from a variety of super strong functional auxiliary agents through science it is compound with form, be provided simultaneously with good cooling performance, profit
Slip energy, rustless property, oil removing cleaning function, anti-corrosion function, easily dilutable feature.It is easy to overcome traditional tradition soap base emulsion summer
The difficult dilution of smelly, winter, rust-proof effect difference defect, also have no adverse effects to lathe paint, suitable for ferrous metal cutting and
Mill processing belongs to current most leading abrasive product.For cutting fluid all indicators are better than saponified oil, it has good cooling, clear
Wash, antirust the features such as, and have it is nontoxic, tasteless, non-corrosive to human body, to equipment burn into does not pollute environment the features such as.
Most of cutting fluid is easy blistering when in use, plays soap at present, to influence the stability used, while also dropping
Low service life, many times greasy property is unable to satisfy processing request, needs to use very high concentration, and use cost compares
Greatly, and contain many harmful components, working environment and personnel health are impacted.
Summary of the invention
It is a kind of suitable for weight technical problem to be solved by the present invention lies in view of the above shortcomings of the prior art, providing
The micro emulsion cutting fluid and preparation method thereof of load wire processing.Micro emulsion cutting fluid of the invention is free of formaldehyde, chlorine, sulphur, has clear
Clean, lubrication, cooling and antisepsis, be suitable for metal aluminum casting under heavy load, ironcasting, steel-casting (nickel-containing alloys part) plus
Work is a kind of microemulsion, forms close and stable protective layer around the workpiece to run at high speed, plays very good lubrication and makees
With, while resisting miscellaneous oil.
In order to solve the above technical problems, the technical solution adopted by the present invention is that: it is a kind of suitable for heavy load intermetallic composite coating
Micro emulsion cutting fluid and preparation method thereof, which is characterized in that the micro emulsion cutting fluid and preparation method thereof has the feature that
A kind of micro emulsion cutting fluid suitable for heavy load intermetallic composite coating, including 30~60wt.% of mineral base oil, synthetic ester
10~20wt.% of 10~30wt.%, 10~20wt.% of extreme pressure anti-wear additives and emulsifier, the synthetic ester be isooctyl oleate,
One of neopentyl polyol ester, tricarboxymethyl propane oleate, trimellitate, pentaerythritol fatty acid ester are a variety of.
The mineral base oil is 5# white oil, No. 15 naphthene base crude oils, No. 22 naphthene base crude oils, No. 32 naphthene base crude oils, No. 32 stones
One of cerul oil is a variety of.
The emulsifier is fatty acid methyl ester ethoxylate, alkyl phenol polyoxyethylene ether, neopentyl glycol oleate, oleyl alcohol
Two kinds in ether and erucic acid and two or more.
The fatty acid methyl ester ethoxylate, alkyl phenol polyoxyethylene ether, neopentyl glycol oleate, oleyl alcohol ether and erucic acid
Between mass ratio be 1:(0.1~2): (0.5~1.5): (0.1~0.5): (0.1~0.5).
The extreme pressure anti-wear additives are one of alkene, vegetable and animals oils, phosphorus system extreme pressure anti-wear additives or synthetic sodium sulfonate or more
Kind.
The mass percent of the extreme pressure anti-wear additives each component is as follows: 0~5wt.% of alkene, and vegetable and animals oils 2~
10wt.%, phosphorus system 0~5wt.% of extreme pressure anti-wear additives, 5~10wt.% of synthetic sodium sulfonate.
A kind of preparation method of the micro emulsion cutting fluid suitable for heavy load intermetallic composite coating, comprising the following steps:
(1) synthetic ester is added into mineral base oil, stirs, is kept for 20 DEG C~40 DEG C of temperature；
(2) surfactant is sequentially added, is stirred, is then cooled to 40 DEG C hereinafter, stopping stirring.
Compared with the prior art, the present invention has the following advantages:
Cutting liquid product prepared by the present invention is free of sodium nitrite, formaldehyde and all kinds of poisonous and harmful substances, produces for environment-friendly type
Product；Unique synthesis Recipe plays good lubricating action to the intermetallic composite coating under black material heavy load, also to aluminum casting
There is extraordinary lubricating action, effectively improves cutter life；Using special emulsifying technology, guarantee lasting low of emulsion
Bubble property, extends the service life of cutting fluid；It rinses well, noresidue；In hard water, almost without foam；With bacteriostasis；
To the cast aluminium alloy containing high silicon (> 5%) without discoloration；There is good antisepsis to cast iron, steel-casting；In the workpiece to run at high speed
Surrounding forms close and stable protective layer, plays very good lubricating action, while resisting miscellaneous oil.
The present invention is described further combined with specific embodiments below.
Specific embodiment
Embodiment 1
A kind of preparation method of the micro emulsion cutting fluid suitable for heavy load intermetallic composite coating, comprising the following steps:
(1) synthetic ester is added into mineral base oil, stirs, is kept for 30 DEG C of temperature；
(2) surfactant is sequentially added, is stirred, is then cooled to 40 DEG C hereinafter, stopping stirring.
The micro emulsion cutting fluid, including mineral base oil 49.2wt.%, synthetic ester 20wt.%, extreme pressure anti-wear additives
15wt.% and emulsifier 15.8wt.%, the synthetic ester are isooctyl oleate.
The mineral base oil is No. 22 naphthene base crude oils.
The emulsifier is fatty acid methyl ester ethoxylate, alkyl phenol polyoxyethylene ether, neopentyl glycol oleate, oleyl alcohol
Ether and erucic acid, wherein fatty acid methyl ester ethoxylate (5wt.%), alkyl phenol polyoxyethylene ether (3wt.%), neopentyl glycol
Mass ratio between oleate (4wt.%), oleyl alcohol ether (3wt.%) and erucic acid (0.8wt.%) is 1:0.6:0.8:0.6:
0.16。
The extreme pressure anti-wear additives are alkene, vegetable and animals oils, phosphorus system extreme pressure anti-wear additives and synthetic sodium sulfonate, wherein each component
Mass percent is as follows: alkene 2wt.%, vegetable and animals oils 6wt.%, phosphorus system extreme pressure anti-wear additives 2wt.%, synthetic sodium sulfonate
5wt.%.
Cutting fluid finished product made from embodiment 1 is carried out to the test of various performances, test result see the table below shown in 1:
The inspection result of the cutting fluid finished product properties of 1 embodiment 1 of table preparation
As can be seen from Table 1, cutting fluid washing power made from preparation method of the present invention is stronger, rinses well, noresidue,
In hard water, almost without foam, there is good antisepsis to cast iron, steel-casting, without sodium nitrite, formaldehyde and all kinds of toxic
Harmful substance is environmentally friendly machine；Unique synthesis Recipe plays well the intermetallic composite coating under black material heavy load
Lubricating action also has extraordinary lubricating action to aluminum casting, effectively improves cutter life, using special emulsification skill
Art guarantees the lasting low bubble of emulsion, extends the service life of cutting fluid.
The above is only presently preferred embodiments of the present invention, is not intended to limit the invention in any way.It is all according to the present invention
Essence any simple modification, change and equivalence change to the above embodiments, still fall within technical solution of the present invention
In protection scope.
Claims (7)
1. a kind of micro emulsion cutting fluid suitable for heavy load intermetallic composite coating, which is characterized in that including mineral base oil 30 ~
60wt.%, 10 ~ 20wt.% of 10 ~ 30wt.% of synthetic ester, 10 ~ 20wt.% of extreme pressure anti-wear additives and emulsifier, the synthetic ester are oleic acid
One of different monooctyl ester, neopentyl polyol ester, tricarboxymethyl propane oleate, trimellitate, pentaerythritol fatty acid ester are more
Kind.
2. a kind of micro emulsion cutting fluid suitable for heavy load intermetallic composite coating according to claim 1, which is characterized in that described
Mineral base oil is 5# white oil, No. 15 naphthene base crude oils, No. 22 naphthene base crude oils, No. 32 naphthene base crude oils, one in No. 32 paraffine base crude oils
Kind is a variety of.
3. a kind of micro emulsion cutting fluid suitable for heavy load intermetallic composite coating according to claim 1, which is characterized in that described
Emulsifier is in fatty acid methyl ester ethoxylate, alkyl phenol polyoxyethylene ether, neopentyl glycol oleate, oleyl alcohol ether and erucic acid
Two kinds and two or more.
4. a kind of micro emulsion cutting fluid suitable for heavy load intermetallic composite coating according to claim 3, which is characterized in that described
Mass ratio between fatty acid methyl ester ethoxylate, alkyl phenol polyoxyethylene ether, neopentyl glycol oleate, oleyl alcohol ether and erucic acid
For .1 ~ 2 1:(0): (.5 of 0 .5 ~ 1): (.5 of 0 .1 ~ 0): (.5 of 0 .1 ~ 0).
5. a kind of micro emulsion cutting fluid suitable for heavy load intermetallic composite coating according to claim 1, which is characterized in that described
Extreme pressure anti-wear additives are one of alkene, vegetable and animals oils, phosphorus system extreme pressure anti-wear additives or synthetic sodium sulfonate or a variety of.
6. a kind of micro emulsion cutting fluid suitable for heavy load intermetallic composite coating according to claim 5, which is characterized in that described
The mass percent of extreme pressure anti-wear additives each component is as follows: 0~5 wt.% of alkene, 2~10 wt.% of vegetable and animals oils, and phosphorus system extreme pressure is anti-
0~5 wt.% of grinding agent, 5~10 wt.% of synthetic sodium sulfonate.
7. a kind of preparation method of micro emulsion cutting fluid suitable for heavy load intermetallic composite coating according to claim 1, special
Sign is, comprising the following steps:
(1) synthetic ester is added into mineral base oil, stirs, is kept for 20 DEG C~40 DEG C of temperature；
(2) surfactant is sequentially added, is stirred；Then 40 DEG C are cooled to hereinafter, stopping stirring.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910060102.5A CN109504516A (en) | 2019-01-22 | 2019-01-22 | A kind of micro emulsion cutting fluid and preparation method thereof suitable for heavy load intermetallic composite coating |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910060102.5A CN109504516A (en) | 2019-01-22 | 2019-01-22 | A kind of micro emulsion cutting fluid and preparation method thereof suitable for heavy load intermetallic composite coating |
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| CN109504516A true CN109504516A (en) | 2019-03-22 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110331028A (en) * | 2019-07-24 | 2019-10-15 | 湖南湘科新材料有限公司 | A kind of long-acting extreme pressure emulsion cutting fluid of multifunctional water-soluble for intermetallic composite coating |
| CN110982598A (en) * | 2019-12-12 | 2020-04-10 | 无锡科捷化学有限公司 | Heavy-duty diesel engine oil and preparation method thereof |
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|---|---|---|---|---|
| CN101575550A (en) * | 2009-05-26 | 2009-11-11 | 上海应用技术学院 | Ternary base oil microemulsified cutting solution and preparation method thereof |
| CN103468382A (en) * | 2013-08-30 | 2013-12-25 | 广州机械科学研究院有限公司 | Boron-free chlorine-free formaldehyde-free microemulsified cutting fluid and application thereof |
| CN105462672A (en) * | 2015-12-07 | 2016-04-06 | 刘方旭 | Extreme pressure type micro-emulsion cutting fluid |
| CN106701296A (en) * | 2016-12-28 | 2017-05-24 | 河南恒润昌环保科技有限公司 | Environment-friendly microemulsion cutting liquid and preparation method thereof |
-
2019
- 2019-01-22 CN CN201910060102.5A patent/CN109504516A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101575550A (en) * | 2009-05-26 | 2009-11-11 | 上海应用技术学院 | Ternary base oil microemulsified cutting solution and preparation method thereof |
| CN103468382A (en) * | 2013-08-30 | 2013-12-25 | 广州机械科学研究院有限公司 | Boron-free chlorine-free formaldehyde-free microemulsified cutting fluid and application thereof |
| CN105462672A (en) * | 2015-12-07 | 2016-04-06 | 刘方旭 | Extreme pressure type micro-emulsion cutting fluid |
| CN106701296A (en) * | 2016-12-28 | 2017-05-24 | 河南恒润昌环保科技有限公司 | Environment-friendly microemulsion cutting liquid and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110331028A (en) * | 2019-07-24 | 2019-10-15 | 湖南湘科新材料有限公司 | A kind of long-acting extreme pressure emulsion cutting fluid of multifunctional water-soluble for intermetallic composite coating |
| CN110982598A (en) * | 2019-12-12 | 2020-04-10 | 无锡科捷化学有限公司 | Heavy-duty diesel engine oil and preparation method thereof |
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