CN109501399B - Three-dimensional silk fur-like fabric - Google Patents

Three-dimensional silk fur-like fabric Download PDF

Info

Publication number
CN109501399B
CN109501399B CN201811351567.8A CN201811351567A CN109501399B CN 109501399 B CN109501399 B CN 109501399B CN 201811351567 A CN201811351567 A CN 201811351567A CN 109501399 B CN109501399 B CN 109501399B
Authority
CN
China
Prior art keywords
silk
layer
rayon
fur
fabric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201811351567.8A
Other languages
Chinese (zh)
Other versions
CN109501399A (en
Inventor
刘科江
王勇
张来源
张雪峰
侯文峰
邓单
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangzhou Panyu Polytechnic
Original Assignee
Guangzhou Panyu Polytechnic
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangzhou Panyu Polytechnic filed Critical Guangzhou Panyu Polytechnic
Priority to CN201811351567.8A priority Critical patent/CN109501399B/en
Priority to PCT/CN2019/070922 priority patent/WO2020098137A1/en
Publication of CN109501399A publication Critical patent/CN109501399A/en
Application granted granted Critical
Publication of CN109501399B publication Critical patent/CN109501399B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/06—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by a fibrous or filamentary layer mechanically connected, e.g. by needling to another layer, e.g. of fibres, of paper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04B—KNITTING
    • D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/02—Pile fabrics or articles having similar surface features
    • D04B1/04—Pile fabrics or articles having similar surface features characterised by thread material
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/20—All layers being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/08—Animal fibres, e.g. hair, wool, silk
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/718—Weight, e.g. weight per square meter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/10—Animal fibres
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00—Protein-based fibres, e.g. animal fibres
    • D10B2211/01—Natural animal fibres, e.g. keratin fibres
    • D10B2211/04—Silk

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Woven Fabrics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Knitting Of Fabric (AREA)

Abstract

The invention discloses a three-dimensional silk-like fur fabric. The fabric comprises a real silk floss layer, a rayon substrate layer, an adhesive layer and a leather-like floss layer, wherein the real silk floss layer is fixedly connected with the upper part of the rayon substrate layer in a knitting mode, and the rayon substrate layer and the leather-like floss layer are adhered through the adhesive layer. The invention takes mulberry silk as a fluff raw material, takes rayon as a substrate layer raw material, adopts a large circular knitting machine to carry out spinning, fixes a silk fluff layer on the rayon substrate layer, and combines a leather-like fluff layer to form the three-dimensional silk and fur-like fabric. The real silk floss layer disclosed by the invention is good in gloss, has a good three-dimensional structure and a good pattern effect, and endows the fabric with a concave-convex three-dimensional effect, smooth lines and good visual sense. The invention adopts the rayon as the material of the base layer, and compared with silk, the weight is light and the cost is lower. The fabric provided by the invention simulates animal fur, and the silk component is protein, so that the touch feeling of the skin is more ideal, the air permeability is good, and the fabric is more environment-friendly.

Description

Three-dimensional silk fur-like fabric
Technical Field
The invention relates to the technical field of textiles, in particular to a three-dimensional silk fur-like fabric.
Background
The artificial fur is a long-wool type fabric similar to animal fur in appearance, is an artificial animal fur, and is manufactured by a common manufacturing method such as knitting, weaving and the like, wherein a knitting weft knitting method is developed fastest and is applied most widely. The acrylic fiber, modified acrylic fiber, polyvinyl chloride fiber and other materials can be used as raw materials of the artificial fur. Although the artificial fur has inferior warmth retention property to real fur, the artificial fur is soft and beautiful, can be made into overcoat, hat, collar, carpet and the like, and has wide application. At present, the imitation fur popular in the market is made by weaving terylene or acrylic fibers into grey cloth through a circular knitting machine, then removing napping and napping, the manufactured product is hard and airtight, the napping can be caused by machine washing, the luster is poor, the hand feeling is poor, and the ratio of chemical raw materials is too large, so that the quality of the imitation fur is poor.
Silk, a textile, is woven from silk or synthetic fibers, rayon, staple, and the like; the term "woven fabric" refers to a fabric made of pure or mixed silk or rayon. The material used by the product is mulberry silk, and the following silk refers to the mulberry silk. The mulberry silk is the only filament fiber which can be produced in large quantity in natural fibers, and has the processing characteristic which is incomparable with other fiber products in the aspects of processing and manufacturing fabrics. However, the existing silk is generally presented by a smooth surface cloth, has no stereoscopic effect, reduces the impact effect of the silk appearance on human vision and the purchase amount of consumers, and is generally constructed by using a single mechanical device, thereby reducing the production efficiency and improving the production cost of the silk. This product makes the breakthrough on traditional silk, lets the silk be more than doing traditional planar fabric, lets the silk become 3D stereoeffect from 2D, and compares with animal fur, and the gas permeability is good, environmental protection more.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide the three-dimensional silk and fur-like fabric.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows:
the three-dimensional silk and fur-like fabric comprises a silk floss layer 1, a rayon substrate layer 2, an adhesive layer 3 and a fur-like floss layer 4, wherein the silk floss layer 1 is fixedly connected with the upper portion of the rayon substrate layer 2 in a knitting mode, and the rayon substrate layer 2 and the fur-like floss layer 4 are adhered through the adhesive layer 3.
The invention takes mulberry silk as a fluff raw material, takes rayon as a substrate layer raw material, adopts a large circular knitting machine to carry out spinning, fixes a silk fluff layer on the rayon substrate layer, and combines a composite imitation leather fluff layer to form the three-dimensional silk imitation fur fabric. The real silk fluff layer has good luster, good three-dimensional structure and pattern effect, and endows the fabric with concave-convex three-dimensional effect, smooth lines and good visual sense. The invention adopts the rayon as the material of the base layer, and compared with silk, the weight is light and the cost is lower. The fabric mainly simulates animal fur, and compared with animal fur, the fabric is made of protein, but is a major breakthrough in visual effect, and has the advantages of low cost, good air permeability, environmental friendliness and humanity.
As a preferred embodiment of the three-dimensional silk-like fur fabric, the silk floss layer 1 takes mulberry silk as a floss raw material; the artificial silk substrate layer 2 is made of artificial silk, the real silk floss layer 1 and the artificial silk substrate layer 2 are formed by spinning through a circular knitting machine, and the method specifically comprises the following steps:
(1a) taking mulberry silk as a fluff raw material and rayon as a basal layer raw material, and putting the mulberry silk and the rayon on a large circular knitting machine;
(2a) the big circular knitting machine forms a coil by utilizing yarns, and the coil is formed into a rayon substrate layer with a real silk floss layer fixed on the surface through longitudinal stringing and transverse connection.
As a preferred embodiment of the three-dimensional silk-like fur fabric, the preparation method of the mulberry silk comprises the following steps:
(1b) soaking the silkworm cocoons in hot water at the temperature of 60-80 ℃, performing silk drawing, and winding the silk cocoons on a silk basket;
(2b) after the step (1b) is finished, screening out excellent raw silk, and then dipping the raw silk to remove sericin;
(3b) after the step (2b) is finished, putting the raw silk without sericin into a drying room for drying for 12 hours;
(4b) and (4) after the step (3b) is finished, winding, doubling, twisting, stopping twisting and twisting the dried raw silk to obtain the mulberry silk.
As a preferred embodiment of the solid silk and fur-like fabric of the present invention, in the step (2b), the raw silk is soaked for 8 hours, and the soaking solution is polyethylene glycol diglycidyl ether solution and is performed under the condition that the pH value is equal to 7.6.
As a preferable embodiment of the three-dimensional silk and fur-like fabric, the fineness of the mulberry silk is 20-128D.
As a preferred embodiment of the three-dimensional silk and fur-like fabric, the mulberry silk is 5-20 mm long.
As a preferred embodiment of the three-dimensional silk-like fur fabric, the process steps of the loop formation are as follows:
(1c) the just formed loop is moved from the hook to the shank, the yarn is then fed to the needle, the yarn is then bent into the shape of a loop, and finally the newly laid yarn or just bent loop is moved into the hook;
(2c) after the step (1c) is finished, closing the needle opening of the knitting needle, and then sleeving the old thread on the needle hook with the closed needle opening.
The invention can effectively save the consumption of raw materials, simplify or cancel the cutting and sewing procedures and improve the wearability of the product by adopting the circular knitting machine for spinning, and the knitting production has short process, strong raw material adaptability, fast variety changing, wide product application range, low noise and low energy consumption.
As a preferred embodiment of the three-dimensional silk and fur-like fabric, before the mulberry silk and rayon are woven, the mulberry silk and rayon are further subjected to antibacterial modification treatment, and the three-dimensional silk and fur-like fabric specifically comprises the following steps:
(1d) crushing rhubarb, adding the crushed rhubarb into an ethanol solution according to the mass ratio of 1: 10-20, extracting for 2-3 hours at 65-70 ℃, centrifuging, and concentrating supernatant to obtain a rhubarb extract;
(2d) crushing madder, adding the crushed madder into an ethanol solution according to the mass ratio of 1: 10-15, extracting at 50-55 ℃ for 3-6 hours, centrifuging, and concentrating the supernatant to obtain a madder extract;
(3d) adding quaternary ammonium salt chitosan into citric acid solution with the mass fraction of 0.5-1%, stirring and dissolving, adding a rhubarb extract and a madder extract, and uniformly stirring to obtain an antibacterial mixed solution, wherein the mass fraction of the quaternary ammonium salt chitosan in the antibacterial mixed solution is 1.2-1.8%, the mass fraction of the rhubarb extract in the antibacterial mixed solution is 2-4%, and the mass fraction of the madder extract in the antibacterial mixed solution is 1-1.5%;
(4d) and immersing the mulberry silk and the rayon into the antibacterial mixed solution, wherein the mass ratio of the total mass of the mulberry silk and the rayon to the antibacterial mixed solution is 1: 5-10, oscillating in a water bath at 45-50 ℃ for 3-4 hours, taking out the mulberry silk and the rayon, and drying.
According to the invention, the mulberry silk and rayon are subjected to antibacterial modification treatment by adopting the quaternary ammonium salt chitosan, the rhubarb extract and the madder extract, so that the antibacterial property of the fabric is obviously improved, and the fabric has good antibacterial durability. Due to the fact that the whiteness of the mulberry silk and the rayon is affected by the addition of the quaternary ammonium salt chitosan, the rhubarb extract and the madder extract, the usage amounts of the quaternary ammonium salt chitosan, the rhubarb extract and the madder extract are further optimized, so that the whiteness of the mulberry silk and the rayon is prevented from being greatly reduced while the antibacterial property of the mulberry silk and the rayon is improved.
As a preferable embodiment of the three-dimensional silk-like fur fabric, the mass fraction of the quaternary ammonium salt chitosan in the antibacterial mixed solution is 1.4%, the mass fraction of the rhubarb extract in the antibacterial mixed solution is 2.4%, and the mass fraction of the madder extract in the antibacterial mixed solution is 1.2%. At the moment, the fabric has high antibacterial property and whiteness.
As a preferable embodiment of the three-dimensional silk and fur-like fabric, the adhesive layer is a thermosetting adhesive layer.
Compared with the prior art, the invention has the beneficial effects that:
the invention takes mulberry silk as a fluff raw material, takes rayon as a substrate layer raw material, adopts a large circular knitting machine to carry out spinning, fixes a silk fluff layer on the rayon substrate layer, and combines a leather-like fluff layer to form the three-dimensional silk and fur-like fabric. The silk floss layer has good gloss, good three-dimensional structure and pattern effect, concave-convex three-dimensional effect is given to the fabric, lines are smooth, visual sense is good, compared with fur, air permeability is better, finished product weight is lighter, the combination with the basal layer is firmer, the basal layer is not easy to tear, cost is lower, production speed is faster, and the fabric is more environment-friendly. The invention adopts the rayon as the material of the base layer, and compared with silk, the weight is light and the cost is lower.
The invention can effectively save the consumption of raw materials, simplify or cancel the cutting and sewing procedures and improve the wearability of the product by adopting the circular knitting machine for spinning, and the knitting production has short process, strong raw material adaptability, fast variety changing, wide product application range, low noise and low energy consumption.
Drawings
Fig. 1 is a schematic structural view of a three-dimensional silk and fur-like fabric, wherein 1 is a real silk floss layer, 2 is a rayon substrate layer, 3 is an adhesive layer, and 4 is a fur-like floss layer.
Detailed Description
To better illustrate the objects, aspects and advantages of the present invention, the present invention will be further described with reference to specific examples. It will be understood by those skilled in the art that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
In the examples, the experimental methods used were all conventional methods unless otherwise specified, and the materials used, etc., were commercially available without otherwise specified.
Example 1
As shown in fig. 1, the three-dimensional silk and fur-like fabric comprises a real silk floss layer 1, a rayon substrate layer 2, an adhesive layer 3 and a fur-like floss layer 4, wherein the real silk floss layer 1 is fixedly connected with the upper part of the rayon substrate layer 2 in a knitting mode, and the rayon substrate layer 2 and the fur-like floss layer 4 are adhered through the adhesive layer 3. Wherein, the bonding layer is a thermosetting adhesive layer.
The real silk floss layer 1 takes mulberry silk as a floss raw material; the artificial silk substrate layer 2 is made of artificial silk, the real silk floss layer 1 and the artificial silk substrate layer 2 are formed by spinning through a circular knitting machine, and the method specifically comprises the following steps:
(1a) taking mulberry silk as a fluff raw material and rayon as a basal layer raw material, and putting the mulberry silk and the rayon on a large circular knitting machine;
(2a) the circular knitting machine forms a coil by using the yarn, and the coil is formed into a rayon substrate layer with a real silk floss layer fixed on the surface through longitudinal stringing and transverse connection.
The preparation method of the mulberry silk comprises the following steps:
(1b) soaking the silkworm cocoons in hot water at the temperature of 60-80 ℃, performing silk drawing, and winding the silk cocoons on a silk basket;
(2b) after the step (1b) is finished, screening out excellent raw silk, and then dipping the raw silk to remove sericin;
(3b) after the step (2b) is finished, putting the raw silk without sericin into a drying room for drying for 12 hours;
(4b) and (4) after the step (3b) is finished, winding, doubling, twisting, stopping twisting and twisting the dried raw silk to obtain the mulberry silk.
In the step (2b), the raw silk is soaked for 8 hours, the soaking solution adopts polyethylene glycol diglycidyl ether solution, and the soaking solution is carried out under the condition that the pH value is equal to 7.6.
The fineness of the mulberry silk is 20D; the length of the mulberry silk is 5 mm.
The process steps for forming the coil are as follows:
(1c) the just formed loop is moved from the hook to the shank, the yarn is then fed to the needle, the yarn is then bent into the shape of a loop, and finally the newly laid yarn or just bent loop is moved into the hook;
(2c) after the step (1c) is finished, closing the needle opening of the knitting needle, and then sleeving the old thread on the needle hook with the closed needle opening.
Example 2
The three-dimensional silk and fur-like fabric comprises a silk floss layer 1, a rayon substrate layer 2, an adhesive layer 3 and a fur-like floss layer 4, wherein the silk floss layer 1 is fixedly connected with the upper portion of the rayon substrate layer 2 in a knitting mode, and the rayon substrate layer 2 and the fur-like floss layer 4 are adhered through the adhesive layer 3. Wherein, the bonding layer is a thermosetting adhesive layer.
The preparation method of mulberry silk is the same as that of example 1. The fineness of the mulberry silk is 50D; the length of the mulberry silk is 10 mm.
Before mulberry silk and rayon are woven, antibacterial modification treatment is further carried out on the mulberry silk and the rayon, and the method specifically comprises the following steps:
(1d) crushing rhubarb, adding the crushed rhubarb into an ethanol solution according to the mass ratio of 1:20, extracting for 2-3 hours at 65-70 ℃, centrifuging, and concentrating supernatant to obtain a rhubarb extract;
(2d) crushing madder, adding the crushed madder into an ethanol solution according to the mass ratio of 1:15, extracting for 3-6 hours at 50-55 ℃, centrifuging, and concentrating supernatant to obtain a madder extract;
(3d) adding quaternary ammonium salt chitosan into a citric acid solution with the mass fraction of 0.5%, stirring for dissolving, adding a rhubarb extract and a madder extract, and uniformly stirring to obtain an antibacterial mixed solution, wherein the mass fraction of the quaternary ammonium salt chitosan in the antibacterial mixed solution is 1.5%, the mass fraction of the rhubarb extract in the antibacterial mixed solution is 2%, and the mass fraction of the madder extract in the antibacterial mixed solution is 1.5%;
(4d) and immersing the mulberry silk and the rayon into the antibacterial mixed solution, wherein the mass ratio of the total mass of the mulberry silk and the rayon to the antibacterial mixed solution is 1:5, oscillating in a water bath at 45-50 ℃ for 3-4 hours, taking out the mulberry silk and the rayon, and drying.
The weaving method of the mulberry silk and the rayon is the same as that of the example 1.
The preparation method of the quaternary ammonium salt chitosan adopted in the embodiment comprises the following steps:
mixing chitosan, isopropanol and glycidyl trimethyl ammonium chloride according to the mass ratio of 1: 30-40: 0.1-0.2, heating in a water bath at 80-90 ℃ for reaction for 15 hours, filtering, washing and drying to obtain the quaternary ammonium salt chitosan.
Example 3
The three-dimensional silk and fur-like fabric comprises a silk floss layer 1, a rayon substrate layer 2, an adhesive layer 3 and a fur-like floss layer 4, wherein the silk floss layer 1 is fixedly connected with the upper portion of the rayon substrate layer 2 in a knitting mode, and the rayon substrate layer 2 and the fur-like floss layer 4 are adhered through the adhesive layer 3. Wherein, the bonding layer is a thermosetting adhesive layer.
The preparation method of mulberry silk is the same as that of example 1. The fineness of the mulberry silk is 100D; the length of the mulberry silk is 20 mm.
Before mulberry silk and rayon are woven, antibacterial modification treatment is carried out on the mulberry silk and the rayon, and the method specifically comprises the following steps:
(1d) crushing rhubarb, adding the crushed rhubarb into an ethanol solution according to the mass ratio of 1:15, extracting for 2-3 hours at 65-70 ℃, centrifuging, and concentrating supernatant to obtain a rhubarb extract;
(2d) crushing madder, adding the crushed madder into an ethanol solution according to the mass ratio of 1:12, extracting for 3-6 hours at 50-55 ℃, centrifuging, and concentrating supernatant to obtain a madder extract;
(3d) adding quaternary ammonium salt chitosan into a citric acid solution with the mass fraction of 0.8%, stirring and dissolving, adding a rhubarb extract and a madder extract, and uniformly stirring to obtain an antibacterial mixed solution, wherein the mass fraction of the quaternary ammonium salt chitosan in the antibacterial mixed solution is 1.2%, the mass fraction of the rhubarb extract in the antibacterial mixed solution is 2.8%, and the mass fraction of the madder extract in the antibacterial mixed solution is 1%;
(4d) and immersing the mulberry silk and the rayon into the antibacterial mixed solution, wherein the mass ratio of the total mass of the mulberry silk and the rayon to the antibacterial mixed solution is 1:8, oscillating in a water bath at 45-50 ℃ for 3-4 hours, taking out the mulberry silk and the rayon, and drying.
The weaving method of the mulberry silk and the rayon is the same as that of the example 1.
Example 4
The three-dimensional silk and fur-like fabric comprises a silk floss layer 1, a rayon substrate layer 2, an adhesive layer 3 and a fur-like floss layer 4, wherein the silk floss layer 1 is fixedly connected with the upper portion of the rayon substrate layer 2 in a knitting mode, and the rayon substrate layer 2 and the fur-like floss layer 4 are adhered through the adhesive layer 3. Wherein, the bonding layer is a thermosetting adhesive layer.
The preparation method of mulberry silk is the same as that of example 1. The fineness of the mulberry silk is 128D; the length of the mulberry silk is 15 mm.
Before mulberry silk and rayon are woven, antibacterial modification treatment is carried out on the mulberry silk and the rayon, and the method specifically comprises the following steps:
(1d) crushing rhubarb, adding the crushed rhubarb into an ethanol solution according to the mass ratio of 1:10, extracting for 2-3 hours at 65-70 ℃, centrifuging, and concentrating supernatant to obtain a rhubarb extract;
(2d) crushing madder, adding the crushed madder into an ethanol solution according to the mass ratio of 1:10, extracting for 3-6 hours at 50-55 ℃, centrifuging, and concentrating supernatant to obtain a madder extract;
(3d) adding quaternary ammonium salt chitosan into a citric acid solution with the mass fraction of 1%, stirring and dissolving, adding a rhubarb extract and a madder extract, and uniformly stirring to obtain an antibacterial mixed solution, wherein the mass fraction of the quaternary ammonium salt chitosan in the antibacterial mixed solution is 1.4%, the mass fraction of the rhubarb extract in the antibacterial mixed solution is 2.4%, and the mass fraction of the madder extract in the antibacterial mixed solution is 1.2%;
(4d) and immersing the mulberry silk and the rayon into the antibacterial mixed solution, wherein the mass ratio of the total mass of the mulberry silk and the rayon to the antibacterial mixed solution is 1:10, oscillating in a water bath at 45-50 ℃ for 3-4 hours, taking out the mulberry silk and the rayon, and drying.
The weaving method of the mulberry silk and the rayon is the same as that of the example 1.
Example 5
The three-dimensional silk and fur-like fabric comprises a silk floss layer 1, a rayon substrate layer 2, an adhesive layer 3 and a fur-like floss layer 4, wherein the silk floss layer 1 is fixedly connected with the upper portion of the rayon substrate layer 2 in a knitting mode, and the rayon substrate layer 2 and the fur-like floss layer 4 are adhered through the adhesive layer 3. Wherein, the bonding layer is a thermosetting adhesive layer.
The preparation method of mulberry silk is the same as that of example 1. The fineness of the mulberry silk is 128D; the length of the mulberry silk is 15 mm.
Before mulberry silk and rayon are woven, antibacterial modification treatment is carried out on the mulberry silk and the rayon, and the method specifically comprises the following steps:
(1d) crushing rhubarb, adding the crushed rhubarb into an ethanol solution according to the mass ratio of 1:10, extracting for 2-3 hours at 65-70 ℃, centrifuging, and concentrating supernatant to obtain a rhubarb extract;
(2d) crushing madder, adding the crushed madder into an ethanol solution according to the mass ratio of 1:10, extracting for 3-6 hours at 50-55 ℃, centrifuging, and concentrating supernatant to obtain a madder extract;
(3d) adding quaternary ammonium salt chitosan into a citric acid solution with the mass fraction of 1%, stirring and dissolving, adding a rhubarb extract and a madder extract, and uniformly stirring to obtain an antibacterial mixed solution, wherein the mass fraction of the quaternary ammonium salt chitosan in the antibacterial mixed solution is 1.8%, the mass fraction of the rhubarb extract in the antibacterial mixed solution is 2%, and the mass fraction of the madder extract in the antibacterial mixed solution is 1.2%;
(4d) and immersing the mulberry silk and the rayon into the antibacterial mixed solution, wherein the mass ratio of the total mass of the mulberry silk and the rayon to the antibacterial mixed solution is 1:10, oscillating in a water bath at 45-50 ℃ for 3-4 hours, taking out the mulberry silk and the rayon, and drying.
The weaving method of the mulberry silk and the rayon is the same as that of the example 1.
Example 6
The three-dimensional silk and fur-like fabric comprises a silk floss layer 1, a rayon substrate layer 2, an adhesive layer 3 and a fur-like floss layer 4, wherein the silk floss layer 1 is fixedly connected with the upper portion of the rayon substrate layer 2 in a knitting mode, and the rayon substrate layer 2 and the fur-like floss layer 4 are adhered through the adhesive layer 3. Wherein, the bonding layer is a thermosetting adhesive layer.
The preparation method of mulberry silk is the same as that of example 1. The fineness of the mulberry silk is 128D; the length of the mulberry silk is 15 mm.
Before mulberry silk and rayon are woven, antibacterial modification treatment is carried out on the mulberry silk and the rayon, and the method specifically comprises the following steps:
(1d) crushing rhubarb, adding the crushed rhubarb into an ethanol solution according to the mass ratio of 1:10, extracting for 2-3 hours at 65-70 ℃, centrifuging, and concentrating supernatant to obtain a rhubarb extract;
(2d) crushing madder, adding the crushed madder into an ethanol solution according to the mass ratio of 1:10, extracting for 3-6 hours at 50-55 ℃, centrifuging, and concentrating supernatant to obtain a madder extract;
(3d) adding quaternary ammonium salt chitosan into a citric acid solution with the mass fraction of 1%, stirring and dissolving, adding a rhubarb extract and a madder extract, and uniformly stirring to obtain an antibacterial mixed solution, wherein the mass fraction of the quaternary ammonium salt chitosan in the antibacterial mixed solution is 1.8%, the mass fraction of the rhubarb extract in the antibacterial mixed solution is 1.5%, and the mass fraction of the madder extract in the antibacterial mixed solution is 5%;
(4d) and immersing the mulberry silk and the rayon into the antibacterial mixed solution, wherein the mass ratio of the total mass of the mulberry silk and the rayon to the antibacterial mixed solution is 1:10, oscillating in a water bath at 45-50 ℃ for 3-4 hours, taking out the mulberry silk and the rayon, and drying.
The weaving method of the mulberry silk and the rayon is the same as that of the example 1.
Comparative example 1
The three-dimensional silk and fur-like fabric comprises a silk floss layer 1, a rayon substrate layer 2, an adhesive layer 3 and a fur-like floss layer 4, wherein the silk floss layer 1 is fixedly connected with the upper portion of the rayon substrate layer 2 in a knitting mode, and the rayon substrate layer 2 and the fur-like floss layer 4 are adhered through the adhesive layer 3. Wherein the bonding layer is a thermosetting adhesive layer; the fineness of the mulberry silk is 20D; the length of the mulberry silk is 15 mm.
The preparation method of mulberry silk is the same as that of example 1.
Before mulberry silk and rayon are woven, antibacterial modification treatment is carried out on the mulberry silk and the rayon, and the method specifically comprises the following steps:
(1d) crushing rhubarb, adding the crushed rhubarb into an ethanol solution according to the mass ratio of 1:10, extracting for 2-3 hours at 65-70 ℃, centrifuging, and concentrating supernatant to obtain a rhubarb extract;
(2d) crushing madder, adding the crushed madder into an ethanol solution according to the mass ratio of 1:10, extracting for 3-6 hours at 50-55 ℃, centrifuging, and concentrating supernatant to obtain a madder extract;
(3d) adding a rheum officinale extract and a madder root extract into a citric acid solution with the mass fraction of 1%, and uniformly stirring to obtain an antibacterial mixed solution, wherein the rheum officinale extract accounts for 4% in the antibacterial mixed solution, and the madder root extract accounts for 1% in the antibacterial mixed solution;
(4d) and immersing the mulberry silk and the rayon into the antibacterial mixed solution, wherein the mass ratio of the total mass of the mulberry silk and the rayon to the antibacterial mixed solution is 1:10, oscillating in a water bath at 45-50 ℃ for 3-4 hours, taking out the mulberry silk and the rayon, and drying.
The weaving method of the mulberry silk and the rayon is the same as that of the example 1.
Comparative example 2
The three-dimensional silk and fur-like fabric comprises a silk floss layer 1, a rayon substrate layer 2, an adhesive layer 3 and a fur-like floss layer 4, wherein the silk floss layer 1 is fixedly connected with the upper portion of the rayon substrate layer 2 in a knitting mode, and the rayon substrate layer 2 and the fur-like floss layer 4 are adhered through the adhesive layer 3. Wherein the bonding layer is a thermosetting adhesive layer; the fineness of the mulberry silk is 20D; the length of the mulberry silk is 15 mm.
The preparation method of mulberry silk is the same as that of example 1.
Before mulberry silk and rayon are woven, antibacterial modification treatment is carried out on the mulberry silk and the rayon, and the method specifically comprises the following steps:
(1d) adding quaternary ammonium salt chitosan into a citric acid solution with the mass fraction of 1%, stirring and dissolving to obtain an antibacterial mixed solution, wherein the mass fraction of the quaternary ammonium salt chitosan in the antibacterial mixed solution is 5%;
(2d) and immersing the mulberry silk and the rayon into the antibacterial mixed solution, wherein the mass ratio of the total mass of the mulberry silk and the rayon to the antibacterial mixed solution is 1:10, oscillating in a water bath at 45-50 ℃ for 3-4 hours, taking out the mulberry silk and the rayon, and drying.
The weaving method of the mulberry silk and the rayon is the same as that of the example 1.
Test for antibacterial Properties
The prepared fabrics of examples 1 to 6 and comparative examples 1 to 2 were respectively placed for 1 day and 6 months, cut into 0.3g square small pieces, numbered, placed in a test tube, plugged with medical absorbent cotton, and sterilized in an autoclave with 0.1MPa high pressure steam for 30 min. The culture medium is subpackaged in test tubes, 2mL of bacterial liquid and 0.3g of fabric are added, the test tubes are placed in a water bath at 37 ℃ for shaking culture, and the bacteria inhibition rate of each group of fabric is detected by sampling at regular time, and the results are shown in Table 1.
TABLE 1
Figure GDA0002725903790000101
Figure GDA0002725903790000111
The results in table 1 show that the mulberry silk and rayon are subjected to antibacterial modification treatment by adopting the quaternary ammonium salt chitosan, the rhubarb extract and the madder extract, the antibacterial property of the fabric is remarkably improved by reasonably adjusting the proportion of the quaternary ammonium salt chitosan, the rhubarb extract and the madder extract, and the quaternary ammonium salt chitosan, the rhubarb extract and the madder extract have a synergistic antibacterial effect and good antibacterial durability.
Whiteness measurement
The mulberry silk and rayon of examples 1 to 6 and comparative examples 1 to 2 were uniformly put into a kit, and whiteness measurement was performed using a standard whiteness board calibration WSB-3A whiteness meter, and the results are shown in table 2.
TABLE 2
Whiteness (%)
Example 1 83.6
Example 2 82.8
Example 3 82.4
Example 4 82.6
Example 5 80.9
Example 6 72.5
Comparative example 1 70.8
Comparative example 2 74.2
As can be seen from the results in table 2, due to the fact that the addition of the quaternary ammonium salt chitosan, the rhubarb extract and the madder extract causes the reduction of the whiteness of the mulberry silk and the rayon, the invention further optimizes the use amounts of the quaternary ammonium salt chitosan, the rhubarb extract and the madder extract, so that the antibacterial property of the mulberry silk and the rayon is improved, and the reduction of the whiteness of the mulberry silk and the rayon is avoided.
In summary, the invention uses mulberry silk as the fluff raw material, uses rayon as the substrate layer raw material, and adopts a circular knitting machine to weave, the silk fluff layer is fixed on the rayon substrate layer, and the composite leather-like fluff layer is combined to form the three-dimensional silk and fur-like fabric. The real silk fluff layer has good gloss, good three-dimensional structure and pattern effect, concave-convex three-dimensional effect is given to the fabric, lines are smooth, visual sense is good, compared with fur, the finished product is lighter in weight, is more firmly combined with the basal layer, is not easy to tear the basal layer, and is lower in cost, faster in production speed and more environment-friendly. The invention adopts the rayon as the material of the base layer, and compared with silk, the weight is light and the cost is lower.
The invention can effectively save the consumption of raw materials, simplify or cancel the cutting and sewing procedures and improve the wearability of the product by adopting the circular knitting machine for spinning, and the knitting production has short process, strong raw material adaptability, fast variety changing, wide product application range, low noise and low energy consumption. Compared with animal fur, the imitation animal fur disclosed by the invention is made of protein, but is a great breakthrough in visual effect, and is low in cost, good in air permeability, more environment-friendly and more humanized.
Finally, it should be noted that the above embodiments are only used for illustrating the technical solutions of the present invention and not for limiting the protection scope of the present invention, and although the present invention is described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions can be made on the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention.

Claims (9)

1. The three-dimensional silk and fur-like fabric is characterized by comprising a silk floss layer (1), a rayon substrate layer (2), an adhesive layer (3) and a fur-like floss layer (4), wherein the silk floss layer (1) is fixedly connected with the upper part of the rayon substrate layer (2) in a knitting mode, and the rayon substrate layer (2) and the fur-like floss layer (4) are adhered through the adhesive layer (3); the real silk floss layer (1) takes mulberry silk as a floss raw material; the artificial silk base layer (2) uses artificial silk as a raw material, before mulberry silk and artificial silk are woven, the mulberry silk and the artificial silk are further subjected to antibacterial modification treatment, and the method specifically comprises the following steps:
(1d) crushing rhubarb, adding the crushed rhubarb into an ethanol solution according to the mass ratio of 1: 10-20, extracting for 2-3 hours at 65-70 ℃, centrifuging, and concentrating supernatant to obtain a rhubarb extract;
(2d) crushing madder, adding the crushed madder into an ethanol solution according to the mass ratio of 1: 10-15, extracting at 50-55 ℃ for 3-6 hours, centrifuging, and concentrating the supernatant to obtain a madder extract;
(3d) adding quaternary ammonium salt chitosan into citric acid solution with the mass fraction of 0.5-1%, stirring and dissolving, adding a rhubarb extract and a madder extract, and uniformly stirring to obtain an antibacterial mixed solution, wherein the mass fraction of the quaternary ammonium salt chitosan in the antibacterial mixed solution is 1.2-1.8%, the mass fraction of the rhubarb extract in the antibacterial mixed solution is 2-4%, and the mass fraction of the madder extract in the antibacterial mixed solution is 1-1.5%;
(4d) and immersing the mulberry silk and the rayon into the antibacterial mixed solution, wherein the mass ratio of the total mass of the mulberry silk and the rayon to the antibacterial mixed solution is 1: 5-10, oscillating in a water bath at 45-50 ℃ for 3-4 hours, taking out the mulberry silk and the rayon, and drying.
2. The solid silk wool-like fabric according to claim 1, wherein the real silk floss layer (1) and the rayon substrate layer (2) are formed by spinning with a circular knitting machine, and the method specifically comprises the following steps:
(1a) taking mulberry silk as a fluff raw material and rayon as a basal layer raw material, and putting the mulberry silk and the rayon on a large circular knitting machine;
(2a) the big circular knitting machine forms a coil by utilizing yarns, and the coil is formed into a rayon substrate layer with a real silk floss layer fixed on the surface through longitudinal stringing and transverse connection.
3. The stereoscopic silk and fur-like fabric according to claim 2, wherein the fineness of the mulberry silk is 20-128D.
4. The three-dimensional silk and fur-like fabric according to claim 3, wherein the length of the mulberry silk is 5-20 mm.
5. The stereoscopic silk fur-like fabric according to claim 2, wherein the preparation method of the mulberry silk comprises the following steps:
(1b) soaking the silkworm cocoons in hot water at the temperature of 60-80 ℃, performing silk drawing, and winding the silk cocoons on a silk basket;
(2b) after the step (1b) is finished, screening out excellent raw silk, and then dipping the raw silk to remove sericin;
(3b) after the step (2b) is finished, putting the raw silk without sericin into a drying room for drying for 12 hours;
(4b) and (4) after the step (3b) is finished, winding, doubling, twisting, stopping twisting and twisting the dried raw silk to obtain the mulberry silk.
6. The solid silk wool-like fabric according to claim 5, wherein in the step (2b), the raw silk is soaked for 8 hours, the soaking solution is polyethylene glycol diglycidyl ether solution, and the soaking is carried out under the condition that the pH value is equal to 7.6.
7. The solid silk wool-like fabric of claim 2, wherein the process steps of forming the loops are:
(1c) moving the just formed loop from the hook to the needle bar, then feeding the yarn to the needle, then bending the yarn into the shape of a loop, and finally moving the newly laid yarn or just bent loop into the hook;
(2c) after the step (1c) is finished, closing the needle opening of the knitting needle, and then sleeving the old thread on the needle hook with the closed needle opening.
8. The solid silk fur-like fabric according to claim 1, wherein the antibacterial mixed solution contains chitosan quaternary ammonium salt in an amount of 1.4% by mass, the antibacterial mixed solution contains rhubarb extract in an amount of 2.4% by mass, and the antibacterial mixed solution contains madder extract in an amount of 1.2% by mass.
9. The three-dimensional silk wool-like fabric according to any one of claims 1 to 8, wherein the bonding layer (3) is a thermosetting adhesive layer.
CN201811351567.8A 2018-11-13 2018-11-13 Three-dimensional silk fur-like fabric Active CN109501399B (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201811351567.8A CN109501399B (en) 2018-11-13 2018-11-13 Three-dimensional silk fur-like fabric
PCT/CN2019/070922 WO2020098137A1 (en) 2018-11-13 2019-01-09 Stereoscopic silk imitation fur fabric

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811351567.8A CN109501399B (en) 2018-11-13 2018-11-13 Three-dimensional silk fur-like fabric

Publications (2)

Publication Number Publication Date
CN109501399A CN109501399A (en) 2019-03-22
CN109501399B true CN109501399B (en) 2021-02-09

Family

ID=65748408

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811351567.8A Active CN109501399B (en) 2018-11-13 2018-11-13 Three-dimensional silk fur-like fabric

Country Status (2)

Country Link
CN (1) CN109501399B (en)
WO (1) WO2020098137A1 (en)

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6040239A (en) * 1983-08-15 1985-03-02 カネボウ株式会社 Integrally molded body
JP2969372B2 (en) * 1990-10-25 1999-11-02 東洋クロス株式会社 Manufacturing method of synthetic leather
CN1296098A (en) * 1999-11-11 2001-05-23 余兴宝 Silk velvet
WO2011036786A1 (en) * 2009-09-28 2011-03-31 東洋紡績株式会社 Stress-alleviating agent comprising plant-derived polyamine-containing extract as active ingredient
CN102485477A (en) * 2010-12-06 2012-06-06 常熟市卓辉针纺织有限公司 Man-made leather material
CN102486010A (en) * 2010-12-06 2012-06-06 常熟市卓辉针纺织有限公司 Method for processing imitation leather fabric
US11141371B2 (en) * 2014-08-19 2021-10-12 Symrise Ag Extracts of Nannochloropsis sp. and their applications
CN104432590B (en) * 2014-10-31 2016-06-01 湖州吴兴道场城乡建设发展有限公司 A kind of antibacterial underwear fabric and its preparation method
CN105538806A (en) * 2016-02-04 2016-05-04 江阴泽万贸易有限公司 Three-dimensional woven and knitted composite flannel
CN108660518A (en) * 2018-04-10 2018-10-16 湖州金玺丝绸有限公司 A kind of solid 3D fur silks

Also Published As

Publication number Publication date
CN109501399A (en) 2019-03-22
WO2020098137A1 (en) 2020-05-22

Similar Documents

Publication Publication Date Title
CN104404705B (en) A kind of Pilus Caprae seu Ovis and the preparation method of the blended knitted sweater of functional fiber
CN104389087B (en) A kind of anti pilling, the Super-soft cotton wool cloth with peach face feel and preparation method thereof
CN106435920B (en) The preparation method for the big jacquard home textile that polynary mixed yarn interweaves with silk
CN104790092B (en) Silk wool fabric and manufacturing method thereof
CN102418225B (en) Preparation method of bamboo fiber knitted terry fabric
CN104223382A (en) Purl high-density functional knitted fabric and manufacturing method thereof
CN103898645A (en) Production method of worsted shell fabric containing polyolefin elastic fibers
CN106480577A (en) The production technology of worsted fabric
CN103898765A (en) Production method of polylactic-acid-fiber-containing spun wool fabric
CN103898646A (en) Production method of worsted shell fabric containing stainless steel fibers
CN107650448A (en) A kind of underwear antibiotic facing material and preparation method thereof
CN104233572B (en) A kind of silk like fabric fabric
CN104109940A (en) Jutecell fiber Raschel blanket and technology for manufacturing Jutecell fiber Raschel blanket
CN104164731B (en) The preparation method of low-carbon health care cashmere-like fabric
CN106480576A (en) The technique of anti pilling worsted fabric
CN103898745A (en) Production method of Newdal-fiber-containing spun wool fabric
CN101165246A (en) Ultra-soft high water absorption hollow cotton towel and manufacturing method thereof
CN109501399B (en) Three-dimensional silk fur-like fabric
CN106661824B (en) Method for producing spinning fibrilia and spinning fibrilia
CN103266406A (en) Manufacturing technique of pupa protein silk fiber Raschel blanket
CN104294473A (en) Production process of health care type wool elastic knitted fabric
CN106480564A (en) The production method of the worsted fabric containing polyolefin elastic fiber
CN106987970A (en) The manufacture craft of cuprammonium Silk antistatic spinning fancy suiting
CN103088540B (en) Method for manufacture method antibiosis and anti-electromagnetic-radiation silk flannelette blanket
CN106498727A (en) The production method of anti-shrinkage worsted fabric

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant