CN109498510A - A kind of grapefruit essential oil gel and preparation method thereof - Google Patents
A kind of grapefruit essential oil gel and preparation method thereof Download PDFInfo
- Publication number
- CN109498510A CN109498510A CN201811419124.8A CN201811419124A CN109498510A CN 109498510 A CN109498510 A CN 109498510A CN 201811419124 A CN201811419124 A CN 201811419124A CN 109498510 A CN109498510 A CN 109498510A
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- water
- essential oil
- grapefruit essential
- phase
- oil gel
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- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 231100000765 toxin Toxicity 0.000 description 1
- 229920006163 vinyl copolymer Polymers 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 230000003442 weekly effect Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- XKMZOFXGLBYJLS-UHFFFAOYSA-L zinc;prop-2-enoate Chemical compound [Zn+2].[O-]C(=O)C=C.[O-]C(=O)C=C XKMZOFXGLBYJLS-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/02—Preparations for care of the skin for chemically bleaching or whitening the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
- A61K2800/5922—At least two compounds being classified in the same subclass of A61K8/18
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Dermatology (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Medicinal Preparation (AREA)
Abstract
The invention discloses a kind of grapefruit essential oil gels and preparation method thereof, including following components: 1,3 propylene glycol；G260；Glycerol；SEPIMAX ZEN；Acritamer 940；Methylparaben；Water；HA；Beta glucan；Tridermol Hydrant；PC2000；De Minshu；BN；Decoyl hydroximic acid；Menthanol lactic acid ester；CO40；Grapefruit essential oil and brilliant blue；Grapefruit essential oil gel appearance transparent of the invention, present it is light blue, it is beautiful and stylish, simultaneously containing largely moist greases, it is clearly not sticky using rear face, whitening, moistening effect are good, promote skin metabolism, and long-acting moisturizing, keep skin water profit smooth, it is flexible, while allergic phenomena occurs in non-someone in whole subject, do not occur yet dermatoma itch, shouting pain, the situations such as redness.
Description
Technical field
The present invention relates to cosmetic field, specifically a kind of grapefruit essential oil gel and preparation method thereof.
Background technique
For cosmetics as a kind of trendy product, developing direction is to tend to natural sex, health giving quality and multifunctionality increasingly.
It is with the forerunner of technology, it adopts new technology, new equipment puts out a new product rapidly, is that the one of international cosmetic industrial development in recent years is big
Trend.
Since many cosmetics are influenced by temperature, pH value, viscosity etc., therefore the production technology of product is proposed higher
It is required that.But, Cosmetic Manufacture technique is fairly simple in Cosmetics Production.Its production process is mainly each component
Mixture, the generation of few chemical reactions, and mostly use intermittent batch production needn't use the company that investment is big, control is difficult
Continuous metaplasia producing line.
In Cosmetic Manufacture technique, emulsifying technology is most important, most complicated technology.In cosmetic material, existing parent
Oil component has hydrophilic component again.It is uniformly mixed it, it is necessary to use good mixing and emulsifying technology.Emulsified body is in actual production
In the process, although sometimes using identical formula, temperature, emulsification times, charging rate and stirring condition when due to operation
Etc. differences, the stability and its physical property of product obtained also can be different, differ greatly sometimes.Therefore according to different formulas
Higher product can just be obtained using suitable production technology with different requirements.
And aqua class cosmetics, since such product has to keep as clear as crystal, so in process of production, to temperature
What the requirement of degree (filtration temperature, cryogenic temperature) and digestion time was also strict.General powder class
The production process of cosmetics mainly has the processes such as powder sterilizing, mixing, levigate, sieving, flavoring, stuffing, packaging.
With the raising of cosmetics scientific and technological content, production equipment also tends to computerized management, such as vacuum Homogenized emulsifier
Developed to from single emulsifying computer program controlled, when production need to only input entire process conditions, and computer will be controlled automatically
Process flow processed is automatically performed the overall processes such as weighing, charging accurately, safely.And it can automatically record and entirely produce
The variation of viscosity, conductivity and temperature etc. in journey.Filling apparatus also achieves computer control, make to send bottle, it is filling plus
Lid, screw capping, mounted box are once completed.
Therefore, the following Cosmetic Market competition will be growing more intense, in order to establish oneself in an unassailable position in competition, it is necessary to continuous
While ground improves the quality of product, improves packing and decorating, expands product influence, the moment holds market situation, utilizes modern section
And technology, constantly bring forth new ideas, development of keeping pace with the times is met customer need.
Summary of the invention
The purpose of the present invention is to provide a kind of grapefruit essential oil gels and preparation method thereof, to solve above-mentioned background technique
The problem of middle proposition.
To achieve the above object, the invention provides the following technical scheme:
A kind of grapefruit essential oil gel, including following components: 1,3 propylene glycol；G260；Glycerol；SEPIMAX ZEN；Card wave
Nurse 940；Methylparaben；Water；HA；Beta glucan；Tridermol Hydrant；PC2000；De Minshu；BN；Decoyl hydroxyl oxime
Acid；Menthanol lactic acid ester；CO40；Grapefruit essential oil and brilliant blue.
Further, a kind of grapefruit essential oil gel, by weight percentage, specific formula component is as follows: 1,3 the third two
Alcohol: 8%；G260:5%；Glycerol: 5%；SEPIMAX ZEN:0.4%；Acritamer 940: 0.33%；Methylparaben: 0.2%；
Water: 73.3997%；HA:0.02%；Beta glucan: 2%；Tridermol Hydrant:3%；PC2000:0.2%；Moral is quick
It relaxes: 0.2%；BN:0.6%；Decoyl hydroximic acid: 0.6%；Menthanol lactic acid ester: 0.1%；CO40:0.9%；Grapefruit essential oil:
0.05%；Brilliant blue: 0.0003%.
Further, a kind of grapefruit essential oil gel, by weight percentage, specific formula component is as follows: 1,3 the third two
Alcohol: 8%；G260:4%；Glycerol: 6%；SEPIMAX ZEN:0.4%；Acritamer 940: 0.33%；Methylparaben: 0.2%；
Water: 73.3997%；HA:0.02%；Beta glucan: 2%；Tridermol Hydrant:3%；PC2000:0.2%；Moral is quick
It relaxes: 0.2%；BN:0.6%；Decoyl hydroximic acid: 0.6%；Menthanol lactic acid ester: 0.1%；CO40:0.9%；Grapefruit essential oil:
0.05%；Brilliant blue: 0.0003%.
Further, a kind of grapefruit essential oil gel, by weight percentage, specific formula component is as follows: 1,3 the third two
Alcohol: 1%；G260:6%；Glycerol: 8%；SEPIMAX ZEN:0.4%；Acritamer 940: 0.33%；Methylparaben: 0.2%；
Water: 76.3997%；HA:0.02%；Beta glucan: 2%；Tridermol Hydrant:3%；PC2000:0.2%；Moral is quick
It relaxes: 0.2%；BN:0.6%；Decoyl hydroximic acid: 0.6%；Menthanol lactic acid ester: 0.1%；CO40:0.9%；Grapefruit essential oil:
0.05%；Brilliant blue: 0.0003%.
Further, the water in the present invention is deionized water；It is when consideration in the present invention is heated to ionized water and stirred
Evaporation in journey, aggregate losses about 2%-3%, to accomplish stoste recovery rate 100%, recipe ingredient by weight percentage
2% moisture for needing additionally to add in water, for supplementing the loss of water.
A kind of preparation method of grapefruit essential oil gel, comprising the following steps:
S1. first portions of de-ionized water is added in collet dissolving pan, by 1,3 propylene glycol；G260；Glycerol；SEPIMAX
ZEN；Acritamer 940；Methylparaben adds people wherein, and 90-100 DEG C is heated under stirring, maintains 20min sterilizing, dissolving pan dress
There is simple turbine stirrer, raw material is made to accelerate dissolution, accelerates heat transfer, so that water is heated up, be heated to 90 DEG C of water phase and be cooled to 72-75
It is stand-by DEG C to obtain A water phase；Long-time heating should be avoided, in order to avoid cause viscosity change；
S2. the preparation of oily phase:
By decoyl hydroximic acid；Menthanol lactic acid ester；Grapefruit essential oil；Brilliant blue；It is added in collet dissolving pan, opens steam and add
Heat is heated to 70-75 DEG C under constant agitation, it is made sufficiently to melt or be uniformly dissolved to obtain oily mutually stand-by；It avoided
Degree heating and long-time heating are to prevent material composition oxidation deterioration；
S3. it emulsifies:
A water phase is slowly added into oily phase, while homogenizer, HA is added at the same time；Beta glucan；
TridermolHydrant；PC2000；De Minshu；BN；After water adds, homogeneous blender is stirred for 5 minutes, is then added through purple
(water of the part is B water phase, and B water phase+A water phase=whole is gone for outside line sterilizing and not heated another part deionized water
Ionized water)；The weight of B water phase can be measured in sunset phase pot or with metering pump-metered；
S4. it cools down:
The cooling procedure of emulsion is realized by the stirring of scraper plate blender and the reflux of collet cooling water, and 1000L emulsification is stirred
The scraper plate blender revolving speed 20-30r/min for mixing pot can generate many bubbles, slowly when homogeneous blender starts emulsification stirring
The purpose of stirring is that the bubble risen is made gradually to disappear；
S5. it is aged and filling:
It is filling with bottle placer again after storage and aging three days, it needs to carry out performance rating, up-to-standard rear to product before filling
It can carry out filling.
Further, currently preferred that A phase is compressed to lower value, A=0.2-0.3, B phase can be improved to 0.7-0.8.
Further, the present invention is advantageous to emulsifying using higher speed stirring when starting emulsification, terminates in emulsification and enters
After cooling stage, then with medium speed or mixes slowly advantageous, stir always to room temperature, can reduce be mixed into bubble in this way
Compared with prior art, the beneficial effects of the present invention are: the sample of invention is without obvious lamination, without clearly visible
Sediment, excellent in stability；Grapefruit essential oil gel appearance transparent of the invention, presentation is light blue, beautiful and stylish, contains simultaneously
Grease is largely moistened, there is synergistic effect, whitening grapefruit essential oil gel permeability of the present invention between inventive formulation each component
It is good, it easily absorbs, clearly not sticky using rear face, whitening, moistening effect are good, promote skin metabolism, and long-acting moisturizing, make
Skin water profit is smooth, flexible, while allergic phenomena occurs in non-someone in whole subjects, does not also occur dermatoma and itches, pierces
Bitterly, the situations such as redness.
Specific embodiment
The technical solution of the patent is explained in further detail With reference to embodiment.
Embodiment one, a kind of grapefruit essential oil gel, by weight percentage, specific formula component is as follows:
1,3 propylene glycol: 8%；
G260:5%；
Glycerol: 5%；
SEPIMAX ZEN:0.4%；
Acritamer 940: 0.33%；
Methylparaben: 0.2%；
Water: 73.3997%；
HA:0.02%；
Beta glucan: 2%；
Tridermol Hydrant:3%；
PC2000:0.2%；
De Minshu: 0.2%；
BN:0.6%；
Decoyl hydroximic acid: 0.6%；
Menthanol lactic acid ester: 0.1%；
CO40:0.9%；
Grapefruit essential oil: 0.05%；
Brilliant blue: 0.0003%；
Embodiment two, a kind of grapefruit essential oil gel, by weight percentage, specific formula component is as follows:
1,3 propylene glycol: 8%；
G260:4%；
Glycerol: 6%；
SEPIMAX ZEN:0.4%；
Acritamer 940: 0.33%；
Methylparaben: 0.2%；
Water: 73.3997%；
HA:0.02%；
Beta glucan: 2%；
Tridermol Hydrant:3%；
PC2000:0.2%；
De Minshu: 0.2%；
BN:0.6%；
Decoyl hydroximic acid: 0.6%；
Menthanol lactic acid ester: 0.1%；
CO40:0.9%；
Grapefruit essential oil: 0.05%；
Brilliant blue: 0.0003%；
A kind of grapefruit essential oil gel, by weight percentage, specific formula component is as follows:
1,3 propylene glycol: 1%；
G260:6%；
Glycerol: 8%；
SEPIMAX ZEN:0.4%；
Acritamer 940: 0.33%；
Methylparaben: 0.2%；
Water: 76.3997%；
HA:0.02%；
Beta glucan: 2%；
Tridermol Hydrant:3%；
PC2000:0.2%；
De Minshu: 0.2%；
BN:0.6%；
Decoyl hydroximic acid: 0.6%；
Menthanol lactic acid ester: 0.1%；
CO40:0.9%；
Grapefruit essential oil: 0.05%；
Brilliant blue: 0.0003%；
G260 full name in the present invention is Genapol G260, the entitled glycerin polyether -26 of INCI；It is 26 moles of epoxy second
The glycerol addition product of alkene has smooth, fine and smooth sense of touch as moisturizer and lubricant, it, which can be used as skin conditioning agent, makes
With having good compatibility with cation, nonionic and anionic surfactant, and stablize within the scope of extensive PH.
The entitled polyacrylate cross-linked polymer -6 of the INCI of SEPIMAX ZEN in the present invention；With very high
The polyelectrolyte polymers of association can utmostly resist electrolyte and destroy to formula bring, while have well
Suspending stabilized ability is suitble to the various formulas such as the transparent system containing particle, superflow and white shape gel.
Acritamer 940 in the present invention, Chinese nickname: polyacrylic acid；Carboxy vinyl copolymer, short rheological characteristic, high viscosity,
High clarity, low resistance to ionic and endurance of cutting have the important uses such as thickening suspension, and simple process, stability is good, is widely applied
In lotion, cream, gel, it is used as thickener in the present invention.
Water in the present invention is deionized water；If using tap water, because containing Ca2+, Mg2+ ion, in alkaline condition
Under, the oxyhydroxide of calcium, magnesium is generated, is that a kind of cotton-shaped cohesion suspended matter often blocks pipe when being put into emulsification agitated kettle
The screen cloth of road filter causes dilute light buck to be unable to Channel Group；When consideration in the present invention is heated to ionized water and in whipping process
Evaporation, aggregate losses about 2%-3% needs in the water of the recipe ingredient of weight percent meter to accomplish stoste recovery rate 100%
2% moisture additionally to add, for supplementing the loss of water.
HA in the present invention is sodium hyaluronate, Chinese name hyaluronic acid, the entitled HYALURONIC ACID of INCI, in this hair
It is bright middle as moisturizer.
Beta glucan in the present invention can promote the generation of internal IgM antibody, to improve the immunocompetence of body fluid.In addition,
Beta glucan, which still has, removes free radical, anti-radiation, dissolving cholesterol, prevents hyperlipidemia and resists filterable virus, fungi, thin
The effects of being infected caused by bacterium etc., therefore it is widely used in the industries such as medicine, food, cosmetics.Research in recent years discovery, β -1, the Portugal 3- are poly-
Sugar can be used as the inhereditary material to play the role of a nucleus in vital movement, can control cell division and differentiation, adjust cell growth,
Treat tumour, hepatitis, angiocarpy, diabetes and reducing blood lipid, in terms of have unique bioactivity.The world is each at present
State, especially in states such as Japan, the U.S., Russia, β -1, the Portugal 3- is poly- to be widely used in health care of food, beauty and skin care etc.
Industry.
Tridermol Hydrant, INCI title in the present invention: water, Chondrus crispus (CHONDRUS CRISPUS)
Extract, Sodium Hyaluronate, Phenoxyethanol, gluconolactone, sodium benzoate；Primary efficacy: moisturizing is moistened, and is improved, lubrication,
Adjust viscosity.
PC2000 in the present invention is specially sarin resin PC2000, and sarin resin is that Du Pont utilizes unique production technology
It is polymerized, is ethylene-(methyl) acrylic acid zinc salt, sodium salt, lithium salts plasma key condensate, Du Pont is unique one in the world
Ionic polymerization resin producer is done in the present invention with the characteristic transparent, limpid, soft glossy is luxurious as toner
It uses.
De Minshu full name in the present invention are as follows:De Minshu 143535；INCI title are as follows: Butylene
Glycol, Pentylene Glycol, Hydroxyphenyl Propamidobenzoic Acid butanediol, 1,2- pentanediol,
Hydroxyphenyl propyl amides benzoic acid；Properties of product and application: there is antihistamine, anti-irritant, the itching-relieving action (scabies as caused by dry
Itch, the nursing of skin after the elderly's pruitus and bite by mosquitos)；Effectively inhibit erythema, itch and mistake caused by histamine
Quick reaction；It is good with other material combinations.
BN full name in the present invention isELITE BN；The entitled starch ocentyl succinic aluminium of an INCI/nitrogen
Change boron；Properties of product and application: skin sense modifying agent combines boron nitride powder on the basis of DRY-FLO PC improves skin sense
Good characteristics.The sliding sense of fabulous children and coverage effect are imparted, also there is better adhesiveness compared to DRY-FLO PC starch.
CO40 Chinese name in the present invention: rilanit special is a kind of good solubilizer and emulsifier, can make for days
So and chemically synthesized organic oil-soluble ingredients dissolve the property and smell for forming stablizing solution, and not changing substance in water,
Improve product and function, performance and sense organ.In Cosmetic Manufacture manufacturing field especially in opaque products, CO40 has it solely
Special attraction, it can reduce or eliminate the organic solvent in product, cheap water instead of, not only safety but also reduce organic
The detrimental effect of solvent and influence, while making that the fragrance of product is purer, feels more natural.
The main chemical component of grapefruit essential oil in the present invention: sobrerone or firpene, sabinene, laurene, limonene, perfume (or spice)
Leaf-alcohol, linalool, citronellal, acetic acid certain herbaceous plants with big flowers ester and terpinenes or terpinene；Effect: grapefruit essential oil has the effect of excitation mood,
Pressure and dejected can be mitigated；Grapefruit essential oil can help Oily to keep cleaning, can improve skin and tissue, to controlling
Treatment acne is also helpful, and grapefruit essential oil is often used in hair nursing, and natural on-off cycles of hair growth can be promoted；Grapefruit essential oil contains highly concentrated
The vitamin C of degree, thus to the highly beneficial value of immune system.It can effectively preventing cold and influenza；Grapefruit essential oil
Be most suitable for for the group of reducing fat (fat woman's stern, leg), for lose weight with diuresis also play the role of it is positive, moreover it is possible to help
Body excludes excessive moisture, by stimulating the circulation of lymph glandular system, can also exclude intracorporal toxin；For treating muscle
It is tired and stiff significant in efficacy.
Brilliant blue in the present invention, also known as edible blue 1 (Japan), edible blue 2 belong to water-soluble non-azo coloring
Agent.Molecular formula C37H34N2Na2O9S3, relative molecular mass 792.86.Brilliant blue is edible blue pigment, belongs to artificial synthesized color
Element, be condensed as benzaldehyde-o-sulfonic acid and N- ethyl-N- (3- sulfobenzyl)-aniline, aoxidize prepared by.Belong to azo
Compound.It can be used as colorant in the industries such as food, drug, cosmetics.
A kind of preparation method of grapefruit essential oil gel, comprising the following steps:
S1. first portions of de-ionized water is added in collet dissolving pan, by 1,3 propylene glycol；G260；Glycerol；SEPIMAX
ZEN；Acritamer 940；Methylparaben adds people wherein, and 90-100 DEG C is heated under stirring, maintains 20min sterilizing, dissolving pan dress
There is simple turbine stirrer, raw material is made to accelerate dissolution, accelerates heat transfer, so that water is heated up, be heated to 90 DEG C of water phase and be cooled to 72-75
It is stand-by DEG C to obtain A water phase；Long-time heating should be avoided, in order to avoid cause viscosity change；
S2. the preparation of oily phase:
By decoyl hydroximic acid；Menthanol lactic acid ester；Grapefruit essential oil；Brilliant blue；It is added in collet dissolving pan, opens steam and add
Heat is heated to 70-75 DEG C under constant agitation, it is made sufficiently to melt or be uniformly dissolved to obtain oily mutually stand-by；It avoided
Degree heating and long-time heating are to prevent material composition oxidation deterioration；
S3. it emulsifies:
A water phase is slowly added into oily phase, while homogenizer, HA is added at the same time；Beta glucan；
TridermolHydrant；PC2000；De Minshu；BN；After water adds, homogeneous blender is stirred for 5 minutes, is then added through purple
(water of the part is B water phase, and B water phase+A water phase=whole is gone for outside line sterilizing and not heated another part deionized water
Ionized water)；The weight of B water phase can be measured in sunset phase pot or with metering pump-metered；
S4. it cools down:
The cooling procedure of emulsion is realized by the stirring of scraper plate blender and the reflux of collet cooling water, and 1000L emulsification is stirred
The scraper plate blender revolving speed 20-30r/min for mixing pot can generate many bubbles, slowly when homogeneous blender starts emulsification stirring
The purpose of stirring is that the bubble risen is made gradually to disappear；
S5. it is aged and filling:
It is filling with bottle placer again after storage and aging three days, it needs to carry out performance rating, up-to-standard rear to product before filling
It can carry out filling.
Further, the ratio (see the table below -1) of the A phase water in the present invention and B phase water has to selection suitably, generally, low
The condensed emulsified cognition of viscosity makes the addition of next step B phase water be easy to carry out.
The ratio of table -1A phase and B phase water
| Emulsifier hlb value | Grease ratio | Stirring condition | Select A value | Select B value |
| 10-12 | 20-25 | By force | 0.2-0.3 | 0.7-0.8 |
| 6-8 | 25-35 | It is weak | 0.4-0.5 | 0.5-0.7 |
Currently preferred that A phase is compressed to lower value, A=0.2-0.3, B phase can be improved to 0.7-0.8.
Further, stirring is stronger when emulsification, and emulsifier can be lower, but emulsified body granular size and stirring are strong
Degree and emulsifier have relationship, and universal law is as shown in table -2.
The relationship of -2 stirring intensity of table and granular size and emulsifier
| Stirring intensity | Granular size | Emulsifier |
| Difference (craft or paddle stirring) | Greatly (emulsification is poor) | On a small quantity |
| Difference | It is medium | Middle amount |
| (colloid mill) by force | It is medium | Amount in as little as |
| (homogenizer) by force | It is small | Amount in as little as |
| Medium (craft or rotary propeller type) | It is small | In to a large amount |
| Difference | It is superfine (clear) | Very high amount |
Excessive strong stirring might not be effective to reduction granular size, and is easily mixed into air, using medium
When stirring intensity, with the available thin particle of phase inversion method, when being stirred using paddle or rotary propeller type, it should be noted that do not make air
It stirs into emulsified body.
It is currently preferred, it is advantageous to emulsifying using higher speed stirring when starting emulsification, terminate in emulsification and enters cold
But it after the stage, then with medium speed or mixes slowly advantageous, stirs always to room temperature, can reduce be mixed into bubble in this way.
Performance rating
1. the Detection of Stability of product
When studying and the stability of emulsified body system being discussed, there is famous Stokes (Stokes) equation:
V=2rr (p2-p1) × g/9 η
In formula: the sinking speed of particle (drop) in v- system
Medium viscosity in η-system
The radius (2 powers that the rr in this formula represents r) of particle (drop) in r- system
G- acceleration of gravity,
P1, p2 are respectively interior phase, the density of foreign minister.
Sinking speed v in formula is exactly the aggregation velocity of the particle (drop) in system, it is clear that if aggregation velocity η is big,
The interior phase (oil mutually or water phase) of system is just easily accumulated on causes water-oil separating and unstable together, so, sinking speed
Smaller, cream or emulsion system are just more stable；By formula it follows that working as interior phase and the foreign minister of system, i.e., oily phase and water phase
Density difference (p2-p1) is cured hour, and system is more stable；When the particle (drop) of system is smaller, i.e., v is smaller, that is, oil droplet or water
Drop is dispersed thinner, and v is just smaller, and system is more stable.So efficient emulsifying device, revolving speed should be made when preparing emulsified body
There is a 3000rpm or more, the dispersion degree of system is high, and the stability of product is good and the glossy exquisiteness of appearance；But in formula system is situated between
The viscosity of matter (i.e. foreign minister), sinking speed v are inversely proportional with η, i.e. the viscosity η of foreign minister is bigger, and v is smaller, and system is just more stable.Such as
When preparing O/W type cream, it can be thickened by the way that hydrophilic macromolecular compounds are added in foreign minister (water phase) to improve the stabilization of cream
Property.
Method specifically: five groups of samples are randomly selected in aging tank, determine certain time interval (6h or for 24 hours, preferably
For for 24 hours), product is first stirred into high temperature (50 DEG C) insulating box, taken out after the time of above-mentioned determination, restores room temperature, then stir
Enter in refrigerator (- 15 DEG C), and pass through the same time, take out after restoring room temperature, place into high-temperature incubator, so passes through
After recycling twice or thrice, the stability of product is observed, shows that the formula design of the embodiment one of the product is the most reasonable, respectively
The stability of embodiment as shown in following table -3 (wherein first and second group be embodiment 1, wherein third and fourth group be embodiment 2, wherein
Five, the six groups are embodiment 3).
The stability of each embodiment of table -3
| Sample | First group | Second group | Third group | 4th group | 5th group | 6th group |
| Stability | Stablize | Stablize | Stablize | Stablize | Stablize | Stablize |
Wherein stably expressed sample of the invention is without obvious lamination, without clearly visible sediment.
2. the irritation test of product
Irritation test uses skin patch test method
Patch test is used clinically for detecting potential anaphylactogen or stimulant, is chiefly used in clinical diagnosis allergy
Disease, such as contact dermatitis, eczema, easy to operate, inspection Check is safer, adverse reaction is few, and test result it is accurate, can
It leans on.Bending side skin because of back, upper arm and forearm has more Dendritic Cells, frequently as the position of patch test, wherein the above back
Portion is optimal site.
(1) subject: totally 20 people, male 10 people, 10 people of female the age 20-30 year old, are averaged 25 years old, meet subject volunteer into
Standard is selected, subject is equally divided into 5 groups, every group two male two female；
(2) tested material: the grapefruit essential oil gel of the embodiment of the present invention one:
(3) test method(s):
1) experiment position: the normal skin of upper back backbone two sides.
2) it removes the protection sheet of spot tester, ready grapefruit essential oil gel is placed in aluminum spot tester, spot tries object
It puts in order from top to bottom, from left to right and to mark, grapefruit essential oil gel is dripped with 25ul microsyringe is being put into spot
(wherein first row filter paper instills the grapefruit essential oil gel of embodiment one, and wherein third arranges filter paper on filter paper in examination device
Piece instills the grapefruit essential oil gel of embodiment two, wherein the 5th row's filter paper instills the grapefruit essential oil gel of embodiment three),
Pay attention to plus spot tries to try not to be stained with spot tester edge when object.
3) by added with the spot tester adhesive tape of grapefruit essential oil gel bottom-up patch jail, develop and gently pressed with palm several
Under, so that air is discharged.
4) the patch test time: 48 hours.
5) observe the result time: stick after 48 hours, first removal spot tester, by avoid spot tester oppress skin possibility
Caused by react, removal spot tester at least 30 minutes after observe result.
6) skin adverse reaction grading standard is as shown in following table -4.
- 4 skin adverse reaction grading standard of table
| Reaction result | Score | Reaction result |
| - | 0 | It is reactionless |
| + | 1 | Weak (no blister) positive reaction: erythema, may have small erythema at infiltration |
| ++ | 2 | (blister) positive reaction by force: erythema, infiltration, the non-phlysis of papule |
| +++ | 3 | Extreme positive reaction (reaction of amalgamation bleb): erythema simultaneously has dozen blister |
7) result interpretation.
As a result interpretation is as shown in table -5
- 5 test result of table
| Reaction result | First group | Second group | Third group | 4th group | 5th group |
| Integral | 0 | 0 | 0 | 0 | 0 |
20 subjects skins are all negative (grading system: 0 grade), according to " cosmetics health specification " (2015
Year version) human skin class patch test judgment criteria, sample is to human body without skin adverse reaction.
3. product effect test
1) subject: totally 200 people, the age 20-30 years old, 25 years old average, the colour of skin of subject's face was obscure, no skin disease mistake
Quick history meets subject and volunteers inclusion criteria, meets subject and volunteers inclusion criteria, subject is equally divided into 10 groups, every group
20 people, wherein the grapefruit essential oil gel that 1-3 group uses as embodiment one, wherein 4-6 group uses the Portugal for being embodiment one
Grape shaddock oil gel, wherein 7-9 group, using the grapefruit essential oil gel for being embodiment one, the 10th group is control group；
2) tested material: the grapefruit essential oil gel of 1-3 of the embodiment of the present invention:
3) test method: the grapefruit essential oil gel of embodiment 1-3 is used respectively, observes and experience using effect.
Application method: it after subject cleans face, takes appropriate above-mentioned grapefruit essential oil gel in the centre of the palm, is uniformly applied to
Face, and be gently massaged into absorption, it is each using primary daily morning and evening, adhere to using one month, at least check weekly once with
Whether there is or not whole body and local adverse reactions for solution, and record result in detail is as shown in following table -6.
Table -6 feeds back conclusive table
The grapefruit essential oil gel of the embodiment of the present invention 1 and embodiment 3 liking and approving by subject, illustrates
There is synergistic effect between inventive formulation each component, meanwhile, the formula of the cost of the formula of embodiment 1 compared to embodiment 3
Cost is relatively low, and preferred embodiment 1 is most preferred embodiment, and subject indicates whitening grapefruit essential oil gel permeability of the present invention
It is good, it easily absorbs, clearly not sticky using rear face, whitening, moistening effect are good, promote skin metabolism, and long-acting moisturizing, make
Skin water profit is smooth, flexible, while allergic phenomena occurs in non-someone in whole subjects, does not also occur dermatoma and itches, pierces
Bitterly, the situations such as redness.
By the above test result as it can be seen that grapefruit essential oil gel appearance transparent of the invention, presentation is light blue, when beautiful
Still, simultaneously containing largely moist grease, in conjunction with efficient moisture-retention ingredient, performance of keeping humidity is excellent.
The preferred embodiment of the patent is described in detail above, but this patent is not limited to above-mentioned embodiment party
Formula within the knowledge of one of ordinary skill in the art can also be under the premise of not departing from this patent objective
It makes a variety of changes.
Claims (8)
1. a kind of grapefruit essential oil gel, which is characterized in that including following components: 1,3 propylene glycol；G260；Glycerol；SEPIMAX
ZEN；Acritamer 940；Methylparaben；Water；HA；Beta glucan；Tridermol Hydrant；PC2000；De Minshu；BN；It is pungent
Acyl hydroximic acid；Menthanol lactic acid ester；CO40；Grapefruit essential oil and brilliant blue.
2. grapefruit essential oil gel according to claim 1, which is characterized in that by weight percentage, specific formula group
Divide as follows: 1,3 propylene glycol: 8%；G260:5%；Glycerol: 5%；SEPIMAX ZEN:0.4%；Acritamer 940: 0.33%；Buddhist nun
Pool tortoise beetle ester: 0.2%；Water: 73.3997%；HA:0.02%；Beta glucan: 2%；Tridermol Hydrant:3%；
PC2000:0.2%；De Minshu: 0.2%；BN:0.6%；Decoyl hydroximic acid: 0.6%；Menthanol lactic acid ester: 0.1%；CO40:
0.9%；Grapefruit essential oil: 0.05%；Brilliant blue: 0.0003%.
3. grapefruit essential oil gel according to claim 1, which is characterized in that by weight percentage, specific formula group
Divide as follows: 1,3 propylene glycol: 8%；G260:4%；Glycerol: 6%；SEPIMAX ZEN:0.4%；Acritamer 940: 0.33%；Buddhist nun
Pool tortoise beetle ester: 0.2%；Water: 73.3997%；HA:0.02%；Beta glucan: 2%；Tridermol Hydrant:3%；
PC2000:0.2%；De Minshu: 0.2%；BN:0.6%；Decoyl hydroximic acid: 0.6%；Menthanol lactic acid ester: 0.1%；CO40:
0.9%；Grapefruit essential oil: 0.05%；Brilliant blue: 0.0003%.
4. grapefruit essential oil gel according to claim 1, which is characterized in that by weight percentage, specific formula group
Divide as follows: 1,3 propylene glycol: 1%；G260:6%；Glycerol: 8%；SEPIMAX ZEN:0.4%；Acritamer 940: 0.33%；Buddhist nun
Pool tortoise beetle ester: 0.2%；Water: 76.3997%；HA:0.02%；Beta glucan: 2%；Tridermol Hydrant:3%；
PC2000:0.2%；De Minshu: 0.2%；BN:0.6%；Decoyl hydroximic acid: 0.6%；Menthanol lactic acid ester: 0.1%；CO40:
0.9%；Grapefruit essential oil: 0.05%；Brilliant blue: 0.0003%.
5. grapefruit essential oil gel according to claim 1 and preparation method thereof, which is characterized in that the present invention in water be
Deionized water；Evaporation when consideration in the present invention is heated to ionized water and in whipping process, aggregate losses about 2%-3% are
Accomplish stoste recovery rate 100%, 2% moisture for needing additionally to add in the water of recipe ingredient by weight percentage is used for
Supplement the loss of water.
6. a kind of preparation method of grapefruit essential oil gel, comprising the following steps:
S1. first portions of de-ionized water is added in collet dissolving pan, by 1,3 propylene glycol；G260；Glycerol；SEPIMAX ZEN；Card
Wave nurse 940；Methylparaben adds people wherein, and 90-100 DEG C is heated under stirring, maintains 20min sterilizing, dissolving pan is equipped with simple
Turbine stirrer makes raw material accelerate dissolution, accelerates heat transfer, water is made to heat up, and is heated to 90 DEG C of water phase and is cooled to 72-75 DEG C obtaining
A water phase is stand-by；Long-time heating should be avoided, in order to avoid cause viscosity change；
S2. the preparation of oily phase:
By decoyl hydroximic acid；Menthanol lactic acid ester；Grapefruit essential oil；Brilliant blue；It is added in collet dissolving pan, opens steam heating,
It is heated to 70-75 DEG C under constant agitation, it is made sufficiently to melt or be uniformly dissolved to obtain oily mutually stand-by；It avoids excessively
Heating and long-time heating are to prevent material composition oxidation deterioration；
S3. it emulsifies:
A water phase is slowly added into oily phase, while homogenizer, HA is added at the same time；Beta glucan；Tridermol
Hydrant；PC2000；De Minshu；BN；After water adds, homogeneous blender is stirred for 5 minutes, is then added through ultraviolet disinfection
And not heated another part deionized water (water of the part is B water phase, B water phase+A water phase=whole deionized water)；B
The weight of water phase can be measured in sunset phase pot or with metering pump-metered；
S4. it cools down:
The cooling procedure of emulsion is to be slowly stirred to flow back with collet cooling water by scraper plate blender to realize；
S5. it is aged and filling:
It is filling with bottle placer again after storage and aging three days, it needs to carry out product performance rating before filling, it can be into after up-to-standard
Row is filling.
7. the preparation method of grapefruit essential oil gel according to claim 6, which is characterized in that currently preferred by A
It is mutually compressed to lower value, A=0.2-0.3, B phase can be improved to 0.7-0.8.
8. the preparation method of grapefruit essential oil gel according to claim 6, which is characterized in that the present invention is starting to emulsify
The stirring of Shi Caiyong higher speed is advantageous to emulsifying, and terminates after entering cooling stage in emulsification, then with medium speed or mixes slowly
Favorably, it stirs always to room temperature, can reduce be mixed into bubble in this way.
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| CN201811419124.8A CN109498510A (en) | 2018-11-26 | 2018-11-26 | A kind of grapefruit essential oil gel and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110227034A (en) * | 2019-06-05 | 2019-09-13 | 甘亮 | Method for applying phase inversion emulsification technology to cosmetics |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108066183A (en) * | 2017-12-27 | 2018-05-25 | 广州市澳键丰泽生物科技股份有限公司 | Eye glue preparation containing plants essential oil and its preparation method and application |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108066183A (en) * | 2017-12-27 | 2018-05-25 | 广州市澳键丰泽生物科技股份有限公司 | Eye glue preparation containing plants essential oil and its preparation method and application |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110227034A (en) * | 2019-06-05 | 2019-09-13 | 甘亮 | Method for applying phase inversion emulsification technology to cosmetics |
| CN110227034B (en) * | 2019-06-05 | 2022-05-13 | 甘亮 | Application method of phase inversion emulsification technology in cosmetics |
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