CN109481713B - A kind of liquid deodorant and preparation method thereof - Google Patents
A kind of liquid deodorant and preparation method thereof Download PDFInfo
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- CN109481713B CN109481713B CN201811150799.7A CN201811150799A CN109481713B CN 109481713 B CN109481713 B CN 109481713B CN 201811150799 A CN201811150799 A CN 201811150799A CN 109481713 B CN109481713 B CN 109481713B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
- A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/013—Deodorant compositions containing animal or plant extracts, or vegetable material
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/20—Method-related aspects
- A61L2209/21—Use of chemical compounds for treating air or the like
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- Dentistry (AREA)
- Engineering & Computer Science (AREA)
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Abstract
The invention belongs to deodorant preparation technical fields, and in particular to a kind of liquid deodorant and preparation method thereof.The liquid deodorant includes the ingredient of following mass fraction: beta-cyclodextrin 0.5~2.5%, malic acid 1~4%, citric acid 1~4%, salicylic acid 0.1~2%, sodium bicarbonate 0.5~4%, polyoxyethylene non-ionic surfactant 0.5~2%, essence 0.5~2% and water 80~95%.Fluid present invention deodorant eliminates the malodor molecules in former existing environment in such a way that physical absorption and chemistry neutralize, and it joined sterilizing ingredient, it restrained effectively microbial reproduction, fundamentally prevent the generation again of malodor molecules, it joined essence simultaneously, the experience for substantially increasing the deodorant is enjoyed.
Description
Technical field
The invention belongs to deodorant preparation technical fields, and in particular to a kind of liquid deodorant and preparation method thereof.
Background technique
The extremely strong substance of a kind of volatility in sordes matter, with a variety of chemical characteristics, such as acid, alkalinity, polarity and
Nonpolarity is primarily present in the places such as soot, sewer, lavatory, slaughterhouse and mortuary.In the main component packet of sordes matter
Include hydrogen sulfide, low molecular weight organic acid, ammonia and amine substance, indoles and aldehyde material, propyl alcohol and butanol etc., wherein hydrogen sulfide and
Low molecular weight organic acid belongs to acid in sordes matter；Ammonia and amine substance belong to alkalinity in sordes matter；Indoles and aldehyde material category
In nonpolarity in sordes matter；Propyl alcohol and butanol belong to polarity in sordes matter.Currently, usually used deodorization approach mainly have it is following
Three kinds: the first is to feel deodorization process, feels that deodorization process is also referred to as encapsulation method, i.e., by using with more strong aroma smell
Substance cover offset offensive odour, this substance be also referred to as be in sordes matter masking agent；Second is physical absorption
Method adsorbs malodor molecules using porous material or high molecular polymer, transfers them to and be not easy contact stimulus to the ground of nasal cavity
Side, thus achieve the purpose that smelly eliminating, but absorbing cannot eliminate in the droplet of sordes matter in sordes matter, the latter can be again
It is volatized into air, deodorizing effect is poor；The third is chemical neutralisation, neutralizes deodorant using therein acid and alkalinity
Substance respectively with alkalinity and it is acid be in sordes qualitative response, to achieve the purpose that elimination stink, but they are for polarity and non-
It is polar not have neutralization then in sordes matter.
100551446 C of Chinese patent literature CN discloses a kind of deodorant spray and preparation method thereof, the deodorization spraying
Agent is based on sodium bicarbonate and saleratus and zinc sulfate, plant surface activating agent, starch derivatives, plant aroma-producing substance and water
Ingredient is wanted, wherein the starch derivatives is any one of alpha-cyclodextrin, beta-cyclodextrin and gamma-cyclodextrin, two kinds or three
The mixing of kind, plant surface activating agent are lauroyl sodium sulfate, polyoxyethylenesorbitans palmitic acid lipid, cocoa both sexes acetate
With any one of polyoxyethylene laurel ether, two or more mixing, the deodorant is easy to use, at low cost, deodorization
Effect is comprehensive, safe to the human body harmless.Chinese patent literature CN 103800928B discloses a kind of antibacterial deodorant, the deodorization
Agent using weak acid regulator, dipotassium hydrogen phosphate, solubilizer, metal-chelating salt, cyclodextrin, active constituent and essence as main component,
Active constituent therein is one of one of cryptolepine, new cryptolepine or derivatives thereof, in eliminating cloth products
While peculiar smell, it can be effectively removed bacterium and the virus bred or be attached in cloth products in cloth products, give user
Bring a good cleaning ambient.Deodorant currently on the market is usually using feeling deodorization process, physisorphtion and chemistry
One or both of neutralisation method carries out deodorization, and smelly eliminating inefficiency, application range is narrow, and can not fundamentally solve
The regeneration of malodor molecule, and certain raw materials in being formulated due to itself property and cause using limitation functionally, because
This, needs to overcome the current generally existing smelly eliminating of deodorant on the market ineffective or can not be efficiently applied to different peculiar smell environment etc.
Deficiency, as people provide it is a kind of it is novel from many aspects eliminate stink and at the same time effectively inhibiting microbial reproduction,
The regeneration of malodor molecule is prevented, the liquid deodorant in stink source is fundamentally solved.
Summary of the invention
The purpose of the present invention is intended to overcome the shortcomings of the prior art, provides a kind of liquid deodorant and its preparation side
Method, the liquid deodorant neutralize a variety of smelly eliminating means using effective physical absorption and chemistry, effectively reduce air or article
On malodor molecule, while being aided with disinfection and sterilization ingredient, prevent the regeneration of malodor molecule, fundamentally solve stink source.
To achieve the goals above, technical scheme is as follows:
A kind of liquid deodorant, the ingredient including following mass fraction: beta-cyclodextrin 0.5~2.5%, malic acid 1~
4%, citric acid 1~4%, salicylic acid 0.1~2%, sodium bicarbonate 0.5~4%, polyoxyethylene non-ionic surfactant
0.5~2%, essence 0.5~2% and water 80~95%.
Further, the liquid deodorant, the ingredient including following mass fraction: beta-cyclodextrin 1%, malic acid 2%,
Citric acid 2%, salicylic acid 0.6%, sodium bicarbonate 2%, polyoxyethylene non-ionic surfactant 0.6%, 1.2% and of essence
Water 85~91%.
Further, the liquid deodorant further includes the ingredient of following mass fraction: sodium cumene sulfonate 1~
3%.
Further, the polyoxyethylene non-ionic surfactant is Crodaret or polyoxyethylene
Laurel ether.
The preparation method of aforesaid liquid deodorant, specifically includes the following steps:
S1, the beta-cyclodextrin of formula ratio, malic acid, citric acid and salicylic acid are dissolved in the water of formula ratio, then with matching
Mixed liquor A is made to 4.5~6.0 in the pH value for the manganese hydrogen sodium regulating solution just measured；
S2, according to formula ratio, essence is pre-dissolved using polyoxyethylene non-ionic surfactant, then will be pre- solvent
Essence is added in the mixed liquor A, and mixed liquid B is made；
S3, the mixed liquid B is loaded in spraying plastic bottle, liquid deodorant is made.
Further, the ingredient of following mass fraction: sodium cumene sulfonate 1~3% is also added into the step S1.
Further, the polyoxyethylene non-ionic surfactant is Crodaret or polyoxyethylene
Laurel ether.
In the inventive solutions, physical absorption main body of the beta-cyclodextrin as malodor molecule has excellent suction
Attached performance；The chemical neutralizer of malic acid and citric acid as malodor molecule, for alkalinity in sordes matter ammonia and trimethylamine etc.
With good deodorizing effect, and add sodium bicarbonate formed buffer system, physical absorption and chemistry neutralize both combine for
Sulfide and nitrogenous compound in air have good deodorizing effect；Salicylic acid can effectively press down as disinfectant
Microbial reproduction processed prevents the regeneration of malodor molecule, solves stink source from basic；Essence imparts the perfume (or spice) of pleasant
Taste achievees the purpose that smelly eliminating flavouring.Crodaret is nontoxic nonirritant as a kind of nonionic surfactant
And it is environmentally protective, it on the one hand can be significantly reduced the surface tension of spray liquid, promote polarity and nonpolar in sordes matter
Droplet is dissolved in, the droplet formed it into is smaller, and increases and be in the contact area of sordes matter, and then effectively improves spraying
The deodorizing effect of agent；Still further aspect, Crodaret have to a certain degree essence as a kind of emulsifier
Solubilization, so that essence is preferably played fragrant effect, finally obtaining one kind can effectively smelly eliminating and bring pleased
The liquid deodorant of happy perfume atmosphere experience sense.
But the solubility of beta-cyclodextrin and salicylic acid in water is all relatively low, limits the present invention to a certain extent
Liquid deodorant plays the function of absorption malodor molecule and bactericidal effect, and also results in the stabilization of fluid present invention deodorant
Property decline.Sodium cumene sulfonate also known as cumene sodium sulfonate are a kind of anionic surfactants, have good water solubility,
It is usually used in preparing various detergent, and it can be used as solubilizer under alkaline condition, the molten of some water-insoluble matter can be improved
Xie Du and the stability for keeping system.And fluid present invention deodorant is faintly acid system (pH value 4.5~6.0), but invent
People is surprised to find that add sodium cumene sulfonate in formula, can promote beta-cyclodextrin and salicylic dissolution well,
The stability of system is improved, to effectively improve the deodorizing sterilizing effect of the liquid deodorant.
Compared with prior art, the invention has the following advantages:
(1) fluid present invention deodorant uses a variety of deodorization means, is both disappeared using the mode that physical absorption and chemistry neutralize
Except the malodor molecules in former existing environment, and sterilizing composition is added in the base, restrained effectively the numerous of microorganism
The bacterium for growing and generating penetrating odor continues to decompose the organic matter in pollution sources, fundamentally prevents the production again of malodor molecules
It is raw.
(2) fluid present invention deodorant is added to polyoxyethylene non-ionic surfactant, can be significantly reduced spray
The surface tension of spray film promotes polarity and the nonpolar contact surface for dissolving in droplet in sordes matter and increase and be in sordes matter
Product, and then the deodorizing effect of spray is effectively improved, there is certain solubilization simultaneously for essence, keeps essence better
Play fragrant effect.
(3) fluid present invention deodorant is added to sodium cumene sulfonate, in faintly acid system (pH value 4.5~6.0)
Good solubilization-aid effect is played, to effectively improve the stability and deodorizing sterilizing effect of the liquid deodorant.
Specific embodiment
The following describes the present invention further through the description of specific embodiments, but it is to limit of the invention that this, which is not,
System, those skilled in the art's basic thought according to the present invention can make various modifications or improvements, but without departing from this
The basic thought of invention, is all within the scope of the present invention.
Embodiment 1, fluid present invention deodorant and preparation method thereof
1 liquid deodorant of the embodiment of the present invention, by following quality at being grouped as: beta-cyclodextrin 0.5kg, malic acid 2kg,
Citric acid 1kg, salicylic acid 0.1kg, sodium bicarbonate 0.5kg, Crodaret 0.5kg, essence 0.5kg and distilled water
94.9kg。
The preparation method of 1 liquid deodorant of the embodiment of the present invention, specifically includes the following steps:
S1, the beta-cyclodextrin of formula ratio, malic acid, citric acid and salicylic acid are dissolved in the distilled water of formula ratio, then
With the pH value of the manganese hydrogen sodium regulating solution of formula ratio to 4.5, mixed liquor A is made；
S2, according to formula ratio, essence is pre-dissolved using Crodaret, then pre- solvent essence is added
Into the mixed liquor A, mixed liquid B is made；
S3, the mixed liquid B is loaded in spraying plastic bottle, liquid deodorant is made.
Embodiment 2, fluid present invention deodorant and preparation method thereof
2 liquid deodorant of the embodiment of the present invention, by following quality at being grouped as: beta-cyclodextrin 1.5kg, malic acid 3kg,
Citric acid 3kg, salicylic acid 1kg, sodium bicarbonate 4kg, Crodaret 1kg, essence 2kg and distilled water 84.5kg.
The preparation method of 2 liquid deodorant of the embodiment of the present invention, specifically includes the following steps:
S1, the beta-cyclodextrin of formula ratio, malic acid, citric acid and salicylic acid are dissolved in the distilled water of formula ratio, then
With the pH value of the manganese hydrogen sodium regulating solution of formula ratio to 5, mixed liquor A is made；
S2, according to formula ratio, essence is pre-dissolved using Crodaret, then pre- solvent essence is added
Into the mixed liquor A, mixed liquid B is made；
S3, the mixed liquid B is loaded in spraying plastic bottle, liquid deodorant is made.
Embodiment 3, fluid present invention deodorant and preparation method thereof
3 liquid deodorant of the embodiment of the present invention, by following quality at being grouped as: beta-cyclodextrin 1kg, malic acid 2kg, lemon
Lemon acid 2kg, salicylic acid 0.6kg, sodium bicarbonate 2kg, Crodaret 0.6kg, essence 1.2kg and distilled water
90.6kg。
The preparation method of 3 liquid deodorant of the embodiment of the present invention, specifically includes the following steps:
S1, the beta-cyclodextrin of formula ratio, malic acid, citric acid and salicylic acid are dissolved in the distilled water of formula ratio, then
With the pH value of the manganese hydrogen sodium regulating solution of formula ratio to 4.7, mixed liquor A is made；
S2, according to formula ratio, essence is pre-dissolved using Crodaret, then pre- solvent essence is added
Into the mixed liquor A, mixed liquid B is made；
S3, the mixed liquid B is loaded in spraying plastic bottle, liquid deodorant is made.
Embodiment 4, fluid present invention deodorant and preparation method thereof
4 liquid deodorant of the embodiment of the present invention, by following quality at being grouped as: beta-cyclodextrin 1kg, malic acid 2kg, lemon
Lemon acid 2kg, salicylic acid 0.6kg, sodium bicarbonate 2kg, polyoxyethylene laurel ether 0.6kg, essence 1.2kg and distilled water 90.6kg.
The preparation method of 4 liquid deodorant of the embodiment of the present invention, specifically includes the following steps:
S1, the beta-cyclodextrin of formula ratio, malic acid, citric acid and salicylic acid are dissolved in the distilled water of formula ratio, then
With the pH value of the manganese hydrogen sodium regulating solution of formula ratio to 4.8, mixed liquor A is made；
S2, according to formula ratio, essence is pre-dissolved using polyoxyethylene laurel ether, pre- solvent essence is then added to institute
It states in mixed liquor A, mixed liquid B is made；
S3, the mixed liquid B is loaded in spraying plastic bottle, liquid deodorant is made.
Embodiment 5, fluid present invention deodorant and preparation method thereof
5 liquid deodorant of the embodiment of the present invention, by following quality at being grouped as: beta-cyclodextrin 0.5kg, malic acid 2kg,
Citric acid 1kg, sodium cumene sulfonate 1kg, salicylic acid 0.1kg, sodium bicarbonate 0.5kg, Crodaret
0.5kg, essence 0.5kg and distilled water 93.9kg.
The preparation method of 5 liquid deodorant of the embodiment of the present invention, specifically includes the following steps:
S1, the beta-cyclodextrin of formula ratio, malic acid, citric acid, sodium cumene sulfonate and salicylic acid are dissolved in formula ratio
Distilled water in, then with the pH value of the manganese hydrogen sodium regulating solution of formula ratio to 4.5, mixed liquor A is made；
S2, according to formula ratio, essence is pre-dissolved using Crodaret, then pre- solvent essence is added
Into the mixed liquor A, mixed liquid B is made；
S3, the mixed liquid B is loaded in spraying plastic bottle, liquid deodorant is made.
Embodiment 6, fluid present invention deodorant and preparation method thereof
6 liquid deodorant of the embodiment of the present invention, by following quality at being grouped as: beta-cyclodextrin 1.5kg, malic acid 3kg,
Citric acid 3kg, sodium cumene sulfonate 3kg, salicylic acid 1kg, sodium bicarbonate 4kg, Crodaret 1kg, essence
2kg and distilled water 81.5kg.
The preparation method of 6 liquid deodorant of the embodiment of the present invention, specifically includes the following steps:
S1, the beta-cyclodextrin of formula ratio, malic acid, citric acid, sodium cumene sulfonate and salicylic acid are dissolved in formula ratio
Distilled water in, then with the pH value of the manganese hydrogen sodium regulating solution of formula ratio to 5.0, mixed liquor A is made；
S2, according to formula ratio, essence is pre-dissolved using Crodaret, then pre- solvent essence is added
Into the mixed liquor A, mixed liquid B is made；
S3, the mixed liquid B is loaded in spraying plastic bottle, liquid deodorant is made.
Embodiment 7, fluid present invention deodorant and preparation method thereof
7 liquid deodorant of the embodiment of the present invention, by following quality at being grouped as: beta-cyclodextrin 1kg, malic acid 2kg, lemon
Lemon acid 2kg, sodium cumene sulfonate 2.6kg, salicylic acid 0.6kg, sodium bicarbonate 2kg, Crodaret 0.6kg,
Essence 1.2kg and distilled water 88kg.
The preparation method of 7 liquid deodorant of the embodiment of the present invention, specifically includes the following steps:
S1, the beta-cyclodextrin of formula ratio, malic acid, citric acid, sodium cumene sulfonate and salicylic acid are dissolved in formula ratio
Distilled water in, then with the pH value of the manganese hydrogen sodium regulating solution of formula ratio to 4.7, mixed liquor A is made；
S2, according to formula ratio, essence is pre-dissolved using Crodaret, then pre- solvent essence is added
Into the mixed liquor A, mixed liquid B is made；
S3, the mixed liquid B is loaded in spraying plastic bottle, liquid deodorant is made.
Comparative example 1
Compared with Example 3, the difference of this comparative example is only that: not adding beta-cyclodextrin.
Comparative example 2
Compared with Example 3, the difference of this comparative example is only that: not adding malic acid and citric acid.
Comparative example 3
Compared with Example 3, the difference of this comparative example is only that: not adding salicylic acid.
Comparative example 4
Compared with Example 3, the difference of this comparative example is only that: not adding Crodaret.
Comparative example 5
Compared with Example 7, the difference of this comparative example is only that: replacing polyethylene glycol hydrogenated castor-oil plant using alkyl glycosides
Oil.
Comparative example 6
Compared with Example 7, the difference of this comparative example is only that: replacing cumene sulphur using neopelex
Sour sodium.
Test example one, the test of fluid present invention deodorant deodoriging properties
According to QB/T 2761 " indoor air purification product clean-up effect measuring method ", the embodiment of the present invention 1~7 is used
The liquid deodorant prepared with comparative example 1~6 detects most of foul smell in environment, including ammonia, hydrogen sulfide, front three
Amine and methyl mercaptan, and then fluid present invention deodorant is assessed to the removal ability of foul smell.
1 fluid present invention deodorant deodoriging properties test result of table
| Project | Ammonia removal rate (%) | Hydrogen sulfide removal rate (%) | Trimethylamine removal rate (%) | Methyl mercaptan removal rate (%) |
| Embodiment 1 | 85.4 | 76.8 | 84.8 | 75.7 |
| Embodiment 2 | 85.9 | 76.2 | 85.5 | 74.3 |
| Embodiment 3 | 86.8 | 78.2 | 86.5 | 76.8 |
| Embodiment 4 | 86.3 | 76.5 | 85.2 | 75.1 |
| Embodiment 5 | 98.9 | 86.2 | 95.5 | 84.3 |
| Embodiment 6 | 99.8 | 88.2 | 96.5 | 86.8 |
| Embodiment 7 | 99.9 | 89.3 | 97.2 | 87.6 |
| Comparative example 1 | 70.2 | 62.3 | 71.4 | 63.5 |
| Comparative example 2 | 71.6 | 75.4 | 72.4 | 75.7 |
| Comparative example 3 | 85.8 | 77.5 | 86.1 | 75.9 |
| Comparative example 4 | 75.6 | 68.2 | 76.8 | 69.2 |
| Comparative example 5 | 88.2 | 79.3 | 88.3 | 78.2 |
| Comparative example 6 | 86.3 | 79.5 | 87.2 | 77.5 |
As shown in Table 1:
(1) compared with comparative example, liquid deodorant prepared by the embodiment of the present invention 5~7 is in sordes matter ammonia, vulcanization
Hydrogen, trimethylamine and methyl mercaptan all have good deodorizing effect, wherein most with the liquid deodorant deodorizing effect of the preparation of embodiment 7
It is good, it is highly preferred embodiment of the present invention.
(2) compared with embodiment 5~7, liquid deodorant prepared by the embodiment of the present invention 1~4 does not add cumene
Sodium sulfonate does not play beta-cyclodextrin good solubilization-aid effect, plays the function limitation of absorption malodor molecule, causes to prepare
The deodorizing effect of liquid deodorant declined.Compared with Example 3, comparative example 1 does not add beta-cyclodextrin, the liquid of preparation
Body deodorant is decreased obviously the deodorizing effect in sordes matter ammonia, hydrogen sulfide, trimethylamine and methyl mercaptan；Comparative example 2 does not add
Add malic acid and citric acid, the liquid deodorant of preparation is obvious in the deodorizing effect of sordes matter ammonia and trimethylamine for alkalinity
Decline, this is because malic acid and citric acid have the alkalinity such as ammonia and trimethylamine in sordes matter as acidic chemical neutralizer
Good deodorizing effect, for acidic materials such as hydrogen sulfide and methyl mercaptans then without obvious effect；Comparative example 4 does not add polyoxyethylene
The surface tension of rilanit special, the spray liquid of the liquid deodorant of preparation significantly increases, with the contact area for being in sordes matter
It is substantially reduced, deodorizing effect is decreased obviously.
(3) compared with Example 7, comparative example 5 replaces Crodaret using alkyl glycosides, and deodorizing effect has
Declined；Comparative example 6 replaces sodium cumene sulfonate using neopelex, and deodorizing effect is made relative to embodiment 3
Standby liquid deodorant is without significant change, and illustrating sodium cumene sulfonate of the present invention, (pH value 4.5~6.0) very in acid system
Solubilization-aid effect has been played well, has increased the stability and deodorizing effect of liquid deodorant.
Test example two, the test of fluid present invention deodorant bacteriostasis property
According to the test method of fungistatic effect in 2017 editions " disinfection technology standard " to the embodiment of the present invention 1~7 and comparison
Liquid deodorant prepared by example 3~6 carries out bacteriostasis property test, and test strain is staphylococcus aureus ATCC6538 and large intestine
Bacillus 8099, action time 1min.
2 fluid present invention deodorant bacteriostasis property test result of table
As shown in Table 2:
(1) compared with comparative example, liquid deodorant prepared by the embodiment of the present invention 1~7 for staphylococcus aureus and
The inhibiting rate of Escherichia coli is up to 95% or more, wherein the liquid deodorant prepared with embodiment 7 is for staphylococcus aureus
It is highly preferred embodiment of the present invention with the inhibiting rate highest of Escherichia coli.
(2) compared with embodiment 5~7, liquid deodorant prepared by the embodiment of the present invention 1~4 does not add cumene
Sodium sulfonate does not play salicylic acid good solubilization-aid effect, cause preparation liquid deodorant bactericidal property under
Drop；Compared with Example 3, comparative example 3 does not add salicylic acid, and the liquid deodorant of preparation is for staphylococcus aureus and greatly
The inhibiting rate of enterobacteria substantially reduces；Comparative example 4 does not add Crodaret, the spray of the liquid deodorant of preparation
The surface tension of spray film significantly increases, and is substantially reduced with the contact area of microbes in air, bactericidal effect is decreased obviously；Comparison
Example 5 replaces Crodaret using alkyl glycosides, and bactericidal effect is declined；Comparative example 6 uses detergent alkylate
Sodium sulfonate replaces sodium cumene sulfonate, and the liquid deodorant that bactericidal effect is prepared relative to embodiment 3 is without significant change, explanation
Sodium cumene sulfonate of the present invention (pH value 4.5~6.0) in acid system has played solubilization-aid effect well, increases liquid
The bactericidal effect of deodorant.
Test example three, the test of fluid present invention deodorant skin irritation
The liquid deodorant prepared respectively to embodiment 3 and embodiment 7 carries out skin irritation test, is surveyed by HET VAM
Examination measurement dermoreaction classification (opposite values be classified), intense stimulus > 2.0, stimulation 1.2~2.0, medium stimulation 0.8~
1.2, minimal irritation 0.0~0.8.
3 fluid present invention deodorant skin irritation test result of table
| Project | Opposite values (%) |
| Embodiment 3 | 0.07 |
| Embodiment 7 | 0.09 |
As seen from table, the liquid deodorant property that prepared by the embodiment of the present invention 3 and embodiment 7 is mild, for the thorn of skin
It is lower to swash property.
The above-described embodiments merely illustrate the principles and effects of the present invention, and is not intended to limit the present invention.It is any ripe
The personage for knowing this technology all without departing from the spirit and scope of the present invention, carries out modifications and changes to above-described embodiment.Cause
This, institute is complete without departing from the spirit and technical ideas disclosed in the present invention by those of ordinary skill in the art such as
At all equivalent modifications or change, should be covered by the claims of the present invention.
Claims (5)
1. a kind of liquid deodorant, which is characterized in that the ingredient including following mass fraction: beta-cyclodextrin 0.5~2.5%, apple
Tartaric acid 1~4%, citric acid 1~4%, salicylic acid 0.1~2%, sodium bicarbonate 0.5~4%, polyoxyethylene-type non-ionic surface
Activating agent 0.5~2%, essence 0.5~2%, water 80~95% and sodium cumene sulfonate 1~3%.
2. liquid deodorant as described in claim 1, which is characterized in that the ingredient including following mass fraction: beta-cyclodextrin
1%, malic acid 2%, citric acid 2%, salicylic acid 0.6%, sodium bicarbonate 2%, polyoxyethylene non-ionic surfactant
0.6%, essence 1.2%, water 85~91% and sodium cumene sulfonate 1~3%.
3. liquid deodorant as claimed in claim 1 or 2, which is characterized in that the polyoxyethylene non-ionic surfactant
For Crodaret or polyoxyethylene laurel ether.
4. a kind of preparation method of liquid deodorant as claimed in claim 1 or 2, which is characterized in that specifically includes the following steps:
S1, the water that the beta-cyclodextrin of formula ratio, malic acid, citric acid, salicylic acid and sodium cumene sulfonate are dissolved in formula ratio
In, then with the pH value of the manganese hydrogen sodium regulating solution of formula ratio to 4.5~6.0, mixed liquor A is made；
S2, according to formula ratio, essence is pre-dissolved using polyoxyethylene non-ionic surfactant, then by pre- solvent essence
It is added in the mixed liquor A, mixed liquid B is made；
S3, the mixed liquid B is loaded in spraying plastic bottle, liquid deodorant is made.
5. the preparation method of liquid deodorant as claimed in claim 4, which is characterized in that the polyoxyethylene-type non-ionic surface
Activating agent is Crodaret or polyoxyethylene laurel ether.
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| CN110844985A (en) * | 2019-11-14 | 2020-02-28 | 浙江理工大学 | Deodorant for paper mill and preparation method thereof |
| CN111991597A (en) * | 2020-08-05 | 2020-11-27 | 河南蓝图环保科技有限公司 | Liquid deodorant for toilet and preparation method thereof |
| CN112191076A (en) * | 2020-09-30 | 2021-01-08 | 内蒙古信度科技发展有限公司 | Absorption deodorant and application thereof |
| CN113426272A (en) * | 2021-07-14 | 2021-09-24 | 上海泓济环保科技股份有限公司 | Deodorant for treating malodorous gas of sewage plants of pharmaceutical enterprises and preparation method thereof |
| CN114225619A (en) * | 2021-12-24 | 2022-03-25 | 汉宁化学(上海)有限公司 | Long-acting deodorant |
| CN115650794A (en) * | 2022-10-30 | 2023-01-31 | 上海野马环保设备工程有限公司 | Method for preparing compost deodorant |
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| EP0601057B1 (en) * | 1991-08-28 | 1996-05-15 | The Procter & Gamble Company | Process for preparing protected particles of water sensitive material |
| EP0601065B1 (en) * | 1991-08-28 | 1998-02-04 | The Procter & Gamble Company | Liquid fabric softener with insoluble pefume-containing particles stably suspended by soil release polymer |
| CN101831361A (en) * | 2010-05-13 | 2010-09-15 | 台州绿岛化妆品有限公司 | Deodorizing and dirt-removing agent of fabrics |
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| US7550416B2 (en) * | 2007-06-27 | 2009-06-23 | The Procter & Gamble Company | Perfumed household products and methods for preserving perfume integrity and extending fragrance life |
| CN114870057A (en) * | 2014-04-28 | 2022-08-09 | 株式会社Lg生活健康 | Composition for removing unwanted molecules and method for removing unwanted molecules |
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|---|---|---|---|---|
| EP0601057B1 (en) * | 1991-08-28 | 1996-05-15 | The Procter & Gamble Company | Process for preparing protected particles of water sensitive material |
| EP0601065B1 (en) * | 1991-08-28 | 1998-02-04 | The Procter & Gamble Company | Liquid fabric softener with insoluble pefume-containing particles stably suspended by soil release polymer |
| CN101831361A (en) * | 2010-05-13 | 2010-09-15 | 台州绿岛化妆品有限公司 | Deodorizing and dirt-removing agent of fabrics |
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