CN109467046B - The method for composite material of particle three-dimensional micro-nano structureization arrangement based on micro-nano-scale - Google Patents
The method for composite material of particle three-dimensional micro-nano structureization arrangement based on micro-nano-scale Download PDFInfo
- Publication number
- CN109467046B CN109467046B CN201811141344.9A CN201811141344A CN109467046B CN 109467046 B CN109467046 B CN 109467046B CN 201811141344 A CN201811141344 A CN 201811141344A CN 109467046 B CN109467046 B CN 109467046B
- Authority
- CN
- China
- Prior art keywords
- nano
- particle
- micro
- scale
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
- B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
- B82B3/0061—Methods for manipulating nanostructures
- B82B3/0066—Orienting nanostructures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
- B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
- B82B3/0009—Forming specific nanostructures
- B82B3/0014—Array or network of similar nanostructural elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
Abstract
The particle of micro-nano-scale, is now placed in mother liquor, obtains the solution containing microcosmic particle by a kind of method for composite material based on the arrangement of nanoparticle three-dimensional micro-nano structureization；Part solution is placed in levelling in container, first structure field is imposed on into the solution in container, pair solution in particle manipulate, realize solution in particle controllable patterned arrangement；Again by solution curing molding in container, container is moved down, and the solution containing microcosmic particle is supplemented in container, change structure field parameters, the longitudinal controllable arrangement for realizing particle in solution realizes the different patternization arrangement of particle in the solution containing microcosmic particle using different structure field；First structure field is changed to the second structure field, particle is made to be arranged into respective shapes；It is repeated up to the composite material for obtaining the arrangement of function nano particle three-dimensional micro-nano structureization；The present invention has many advantages, such as orientable localization adjusting, high efficiency, the molding that Arbitrary 3 D shape and structure can be achieved.
Description
Technical field
The invention belongs to minute manufacturing nanostructure technology field, in particular to a kind of particle three based on micro-nano-scale
Tie up the method for composite material of micro-nano structureization arrangement.
Background technique
The restrained space dimensionality of nanostructure can be divided into 4 kinds: (1) the nano atomic group race of zero dimension；(2) one dimension fibre shape
Nanostructure, length are noticeably greater than width, such as carbon nanotube；(3) two-dimensional layer nanostructure, length and width size is at least
More much bigger than thickness, crystallite dimension is nanoscale in one direction, such as graphene；(4) three-dimensional nano-solid, Ren Menyi
Through being prepared for different nano materials with a variety of different methods, and to numerous preparation methods, the medium according to preparation is gas
Body, liquid or solid can totally be divided into three classes vapor phase method, liquid phase method and solid phase method；Wherein vapor phase method mainly includes chemistry
Vapor phase method, sublimation recrystallization method, molten reactant metal method, high pressure gas atomization；Liquid phase method mainly include hydro-thermal method, the precipitation method,
Radiation Synthesis Method, emulsion method；Solid phase method mainly includes high-energy ball milling method, Amorphous Crystallization method, depth plastic deformation method.And these sides
Method is the preparation that three-dimensional manometer solid is realized by the growth of control nanoparticle mostly, and nanoparticle is in functional material
In distribution mostly be dispersion, it is structureless, cannot achieve with three-dimensional micro-nano structure function nano particle orientation localization
Arrangement.
How to realize the Arbitrary 3 D structuring arrangement of low-dimension nano material in the composite, makes the difference of composite material
Position shows different physicochemical characteristics, is always one so that composite material be made to meet more complicated working environment
Problem.
Summary of the invention
In order to overcome the disadvantages of the above prior art, the purpose of the present invention is to provide a kind of grains based on micro-nano-scale
The method for composite material of sub- three-dimensional micro-nano structureization arrangement is, it can be achieved that function nano particle is controllable fixed in composite material
To arrangement, the different location of composite material is made to show different physicochemical characteristics, there is orientable localization to adjust, efficiently
The advantages that molding of Arbitrary 3 D shape and structure can be achieved in rate.
To achieve the goals above, the technical solution adopted by the present invention is as follows:
A kind of method for composite material of the particle three-dimensional micro-nano structureization arrangement based on micro-nano-scale, including it is following
Step:
1) particle of micro-nano-scale is placed in mother liquor, stirring is distributed the uniform particle of micro-nano-scale, is contained
There is the solution of the particle of micro-nano-scale；
2) solution of the particle by a part containing micro-nano-scale is placed in container, and a part contains micro-nano-scale
The solution of particle is at any time as supplement；
3) by the solution levelling of the particle in container containing micro-nano-scale；
4) solution that first structure field is imposed on to the particle in container containing micro-nano-scale, to containing micro-nano-scale
Particle solution in the particle of micro-nano-scale manipulated, realize micro-nano in the solution of the particle containing micro-nano-scale
The controllable patterned arrangement of the particle of metrical scale；
5) by the solution curing molding of the particle in container containing micro-nano-scale；
6) container is moved down；
7) solution of the particle containing micro-nano-scale is supplemented in container；
8) change structure field parameters, the particle of micro-nano-scale is vertical in the solution of particle of the realization containing micro-nano-scale
To controllable arrangement；
9) different structure field is used, realizes the particle of micro-nano-scale in the solution of the particle containing micro-nano-scale not
Same patterned configuration；
10) first structure field is changed to the second structure field, the particle of micro-nano-scale is made to be arranged into respective shapes；
11) step 2) -10 is repeated) until obtaining answering for the particle three-dimensional micro-nano structureization arrangement of function micro-nano-scale
Condensation material.
The particle of micro-nano-scale in the step 1) is the metallic particles or nonmetallic that partial size is 30 μm of 100nm-
Particle, mother liquor are photo curable resinous material or heat-setting organic polymer material, and mother liquor viscosity is 1 × 10- 3Pa·s—2×101Pa·s。
Levelling mode in the step 3) is to strike off.
Structuring field in the step 4) is structuring AC field, and voltage 50V-50KV, frequency is 1KHz-
200KHz；The electrode structure of structuring AC field is interdigital electrode, combined electrode or inserting electrode；Interdigital electrode is interdigital
Width be 5 μm -1mm, it is interdigital between spacing be 5 μm -1mm.
Controllable patterned arrangement in the step 4) is that particle neatly aligns the type of being in line, triangle, circle
Or rectangular patterns.
Curing molding mode in the step 5) is ultraviolet light solidification, blue light solidification or heat cure.
Dropping distance in the step 6) is 5 μm -100 μm.
The amount of make-up solution in the step 7) makes the liquid level after having supplemented rise 5 μm -100 μm.
Change structure field parameters in the step 8) are the voltage and frequency of height-regulating structure electric field, are realized micro-nano
The particle of scale is in longitudinal arrangement.
The second structure field is used to change interdigital electrode into snakelike electrode structure in the step 10), realizes micro-nano
The different patternization of the particle of metrical scale is arranged.
Compared with prior art, the invention has the following advantages:
(1) present invention can carry out the structure of design structure field by the arrangement mode of the particle of expected micro-nano-scale, and
And after structure field completes, it can be used continuously, the particle that function micro-nano-scale truly may be implemented is fixed
It is manipulated to localization, realizes the three dimensional patterned arrangement of the particle of function micro-nano-scale.
(2) present invention controllably orients manipulation from the particle for realizing function micro-nano-scale and starts with, and has designed and prepared out not
With the structure field of structuring, and the particle of function micro-nano-scale can be realized by adjusting the voltage and frequency of structure field
The different in width and depth of patterned configuration.
(3) relative to traditional manufacture technology of composite material, the present invention can be by for different layers micro-nano-scale
The space three-dimensional arrangement that the different patternization of particle arranges to realize the truly particle of function micro-nano-scale, so that multiple
The number of the particle of function micro-nano-scale and arrangement contained by different zones are different from condensation material, so that composite material is different
Region shows different mechanical characteristics.It is worth with promotion and application, is expected to be applied to become functionally gradient material (FGM), novel intelligent material
Material, the fields such as functional composite material manufacture.
Detailed description of the invention
Fig. 1 is manufacturing method schematic diagram of the embodiment of the present invention.
Fig. 2 is the schematic diagram for the particle single layer oriented alignment that the embodiment of the present invention realizes function micro-nano-scale.
Fig. 3 is the different row of the particle of function micro-nano-scale after the embodiment of the present invention realizes change structure field parameters
Column width schematic diagram.
Fig. 4 is the different patterning row of the particle of function micro-nano-scale after the embodiment of the present invention realizes change structure field
Cloth schematic diagram.
Specific embodiment
Below with reference to embodiment and attached drawing, the present invention is further illustrated, but protection of the invention should not be limited with this
Range.
Referring to Fig.1, a kind of method for composite material of the particle three-dimensional micro-nano structureization arrangement based on micro-nano-scale,
The following steps are included:
1) particle 1 of the micro-nano-scale for the polystyrene sphere for being 5 μm by diameter is placed in PDMS solution, stirs five points
Clock is distributed the uniform particle of micro-nano-scale, is evenly distributed the PDMS solution 4 of granules of polystyrene；
2) the PDMS solution 4 of a part of granules of polystyrene is poured into container 3, is then struck off, keep liquid level in container high
Degree is 60 μm；
3) by 4 levelling of PDMS solution of granules of polystyrene in container；
4) by 50 μm of interdigital finger beam, 50 microns of span of first structure electric field imposes on granules of polystyrene in container 3
PDMS solution 4 manipulates the particle 1 of the micro-nano-scale in solution, is arranged into the particle 1 of micro-nano-scale such as Fig. 2
Shown in linear type；Wherein, structuring electric field both end voltage is 30V, and frequency 50KHz, waveform is sinusoidal pattern；
5) by the ultraviolet light 8s of PDMS solution 4 of granules of polystyrene in container 3, it is solidified；
6) 3 height of container is adjusted, container 3 is made to move down 60 μm；
7) the PDMS solution 4 that granules of polystyrene is supplemented into container 3 makes the liquid level of container 3 rise 60 μm；
8) as shown in figure 3, adjustment structured electrodes both end voltage is 50V, 50KHz, micro-nano-scale in solution is realized
The multirow linearization(-sation) of particle 1 is arranged, and realizes the control of the particle 1 of longitudinal direction micro-nano-scale；
9) as shown in figure 4, first structure field is changed to the second structure field 5, the particle of micro-nano-scale is made to be arranged into circle,
Wherein, 50 μm of 6 line width of pole plate, connects anode；50 μm of 7 line width of pole plate, connects cathode；Spacing between pole plate 6 and pole plate 7 is 80 μm；
Institute's making alive is 50V, frequency 50KHz；
10) repeat the above steps 2) -9), realize the particle three-dimensional micro-nano structureization arrangement containing functional micro-nano-scale
Composite material production.
For the present invention, available structure field is not limited only to tell two kinds.Although referring to previous examples to this hair
It is bright to be described in detail, it for those skilled in the art, still can be to technology documented by previous examples
Scheme is modified or equivalent replacement of some of the technical features.All within the spirits and principles of the present invention, institute
Any modification, equivalent substitution, improvement and etc. of work, should all be included in the protection scope of the present invention.
Claims (5)
1. a kind of method for composite material of the particle three-dimensional micro-nano structureization arrangement based on micro-nano-scale, feature exist
In, comprising the following steps:
1) particle of micro-nano-scale is placed in mother liquor, stirring is distributed the uniform particle of micro-nano-scale, obtains containing micro-
The solution of the particle of nanoscale；
2) solution of the particle by a part containing micro-nano-scale is placed in container, a part of particle containing micro-nano-scale
Solution at any time as supplement；
3) by the solution levelling of the particle in container containing micro-nano-scale；
4) solution that first structure field is imposed on to the particle in container containing micro-nano-scale, to the grain containing micro-nano-scale
Particle in the solution of son is manipulated, and nanoparticle is controllable patterned in the solution of particle of the realization containing micro-nano-scale
Arrangement；
5) by the solution curing molding of the particle in container containing micro-nano-scale；
6) container is moved down；
7) solution of the particle containing micro-nano-scale is supplemented in container；
8) change structure field parameters, realize that the longitudinal direction of the particle of micro-nano-scale in the solution of the particle containing micro-nano-scale can
Control arrangement；
9) different structure field is used, realizes the different figures of the particle of micro-nano-scale in the solution of the particle containing micro-nano-scale
Caseization arrangement；
10) first structure field is changed to the second structure field, the particle of micro-nano-scale is made to be arranged into respective shapes；
11) step 2) -10 is repeated) until obtaining the composite wood of the particle three-dimensional micro-nano structureization arrangement of function micro-nano-scale
Material,
The particle of micro-nano-scale in the step 1) is the metallic particles that partial size is 30 μm of 100nm-or nonmetallic
Grain, mother liquor are photo curable resinous material or heat-setting organic polymer material, and mother liquor viscosity is 1 × 10-3Pa·
s—2×101Pa·s；
Structuring field in the step 4) is structuring AC field, and voltage 50V-50KV, frequency is 1KHz-
200KHz；The electrode structure of structuring AC field is interdigital electrode；The interdigital width of interdigital electrode be 5 μm -1mm, it is interdigital between
Spacing is 5 μm -1mm；
Dropping distance in the step 6) is 5 μm -100 μm；
The amount of make-up solution in the step 7) makes the liquid level after having supplemented rise 5 μm -100 μm；
The second structure field is used to change interdigital electrode into snakelike electrode structure in the step 10), realizes micro-nano meter ruler
The different patternization of the particle of degree is arranged.
2. a kind of composite material of particle three-dimensional micro-nano structureization arrangement based on micro-nano-scale according to claim 1
Manufacturing method, it is characterised in that: the levelling mode in the step 3) is to strike off.
3. a kind of composite material of particle three-dimensional micro-nano structureization arrangement based on micro-nano-scale according to claim 1
Manufacturing method, it is characterised in that: the controllable patterned arrangement in the step 4) is that the particle of micro-nano-scale neatly orients
Be arranged in a straight line type, triangle, circle or rectangular patterns.
4. a kind of composite material of particle three-dimensional micro-nano structureization arrangement based on micro-nano-scale according to claim 1
Manufacturing method, it is characterised in that: the curing molding mode in the step 5) is ultraviolet light solidification, blue light solidification or thermosetting
Change.
5. a kind of composite material of particle three-dimensional micro-nano structureization arrangement based on micro-nano-scale according to claim 1
Manufacturing method, it is characterised in that: the change structure field parameters in the step 8) are the voltage and frequency of height-regulating structure electric field
Rate realizes the particle of micro-nano-scale in longitudinal arrangement.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811141344.9A CN109467046B (en) | 2018-09-28 | 2018-09-28 | The method for composite material of particle three-dimensional micro-nano structureization arrangement based on micro-nano-scale |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811141344.9A CN109467046B (en) | 2018-09-28 | 2018-09-28 | The method for composite material of particle three-dimensional micro-nano structureization arrangement based on micro-nano-scale |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109467046A CN109467046A (en) | 2019-03-15 |
| CN109467046B true CN109467046B (en) | 2019-11-26 |
Family
ID=65664399
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811141344.9A Active CN109467046B (en) | 2018-09-28 | 2018-09-28 | The method for composite material of particle three-dimensional micro-nano structureization arrangement based on micro-nano-scale |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109467046B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109901250B (en) * | 2019-04-04 | 2020-03-24 | 西安交通大学 | Optical element containing structured nanoparticles inside and manufacturing method thereof |
| CN112736212A (en) * | 2019-10-28 | 2021-04-30 | Tcl华星光电技术有限公司 | Nanoparticle patterning device and nanoparticle patterning method |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7455757B2 (en) * | 2001-11-30 | 2008-11-25 | The University Of North Carolina At Chapel Hill | Deposition method for nanostructure materials |
| WO2005100541A2 (en) * | 2004-04-12 | 2005-10-27 | The Regents Of The University Of California | Optoelectronic tweezers for microparticle and cell manipulation |
| JP2008287163A (en) * | 2007-05-21 | 2008-11-27 | Ricoh Co Ltd | Electrophoretic dispersion liquid |
| FI122014B (en) * | 2007-06-08 | 2011-07-15 | Teknologian Tutkimuskeskus Vtt | Method and apparatus for the functionalization of nanoparticle systems |
| JP2010091718A (en) * | 2008-10-07 | 2010-04-22 | Nikon Corp | Method of manufacturing optical element, and the optical element |
| CN101446762B (en) * | 2008-12-31 | 2011-07-27 | 西安交通大学 | Micro-complex type method for inducing electric field under the restrict of non-contact moulding board |
| JP4903907B1 (en) * | 2011-05-13 | 2012-03-28 | 株式会社サクラクレパス | Electret particulate and method for producing the same |
| CN102253435A (en) * | 2011-07-11 | 2011-11-23 | 西安交通大学 | Micromachining method for manufacturing polymer cylindrical microlens by electric field induction |
| CN106430079B (en) * | 2016-09-28 | 2017-12-26 | 西安交通大学 | A kind of manufacture method of the compound micron post of electric field induced polymer base functionally gradient |
| CN106924804B (en) * | 2017-02-17 | 2020-08-14 | 江汉大学 | Nano-hydroxyapatite/polycaprolactone gradient functional material prepared by high-voltage electric field induction and preparation method thereof |
| US10722887B2 (en) * | 2017-03-21 | 2020-07-28 | International Business Machines Corporation | Device and method for flow and bead speed characterization in microfluidic devices |
-
2018
- 2018-09-28 CN CN201811141344.9A patent/CN109467046B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN109467046A (en) | 2019-03-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Kim et al. | Three-dimensional printing of highly conductive carbon nanotube microarchitectures with fluid ink | |
| Mao et al. | The emerging frontiers and applications of high-resolution 3D printing | |
| Li et al. | Smart materials by nanoscale magnetic assembly | |
| Ai et al. | Advanced colloidal lithography beyond surface patterning | |
| Tawfick et al. | Engineering of micro‐and nanostructured surfaces with anisotropic geometries and properties | |
| He et al. | Pattern and feature designed growth of ZnO nanowire arrays for vertical devices | |
| Masuda et al. | Low-dimensional arrangement of SiO2 particles | |
| US10138120B2 (en) | Shaping nanostructure arrays | |
| CN103219476B (en) | A kind of organic electroluminescent LED and preparation method thereof | |
| Shi et al. | Synthesis and applications of silver nanowires for transparent conductive films | |
| CN109467046B (en) | The method for composite material of particle three-dimensional micro-nano structureization arrangement based on micro-nano-scale | |
| Paik et al. | Hierarchical materials design by pattern transfer printing of self-assembled binary nanocrystal superlattices | |
| Xu et al. | Evaporative self-assembly of nanowires on superhydrophobic surfaces of nanotip latching structures | |
| Jambhulkar et al. | Aligned Ti3C2T x MXene for 3D Micropatterning via Additive Manufacturing | |
| Xiong et al. | Magnetic-field-driven ultra-small 3D hydrogel microstructures: Preparation of gel photoresist and two-photon polymerization microfabrication | |
| CN106904002B (en) | The extensive inkjet printing methods of three-dimensional metamaterial array | |
| EP2704990A1 (en) | Hierarchical carbon nano and micro structures | |
| Ahn et al. | Atomic layer deposition of inorganic thin films on 3D polymer nanonetworks | |
| Cai et al. | Mechanisms, influencing factors, and applications of electrohydrodynamic jet printing | |
| CN102383102B (en) | Magnetic nano anti-dot array film and preparation method thereof | |
| Park et al. | Fabrication and applications of stimuli‐responsive micro/nanopillar arrays | |
| Li et al. | A review on fabrication and application of tunable hybrid micro–nano array surfaces | |
| Handrea-Dragan et al. | Multifunctional structured platforms: from patterning of polymer-based films to their subsequent filling with various nanomaterials | |
| Słoma | 3D printed electronics with nanomaterials | |
| Sola et al. | Self-assembly meets additive manufacturing: Bridging the gap between nanoscale arrangement of matter and macroscale fabrication |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |