CN109467046A - Method for composite material based on the arrangement of nanoparticle three-dimensional micro-nano structureization - Google Patents

Method for composite material based on the arrangement of nanoparticle three-dimensional micro-nano structureization Download PDF

Info

Publication number
CN109467046A
CN109467046A CN201811141344.9A CN201811141344A CN109467046A CN 109467046 A CN109467046 A CN 109467046A CN 201811141344 A CN201811141344 A CN 201811141344A CN 109467046 A CN109467046 A CN 109467046A
Authority
CN
China
Prior art keywords
particle
arrangement
nano
composite material
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201811141344.9A
Other languages
Chinese (zh)
Other versions
CN109467046B (en
Inventor
蒋维涛
刘红忠
郑祥文
张雅君
韩捷
牛东
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xian Jiaotong University
Original Assignee
Xian Jiaotong University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xian Jiaotong University filed Critical Xian Jiaotong University
Priority to CN201811141344.9A priority Critical patent/CN109467046B/en
Publication of CN109467046A publication Critical patent/CN109467046A/en
Application granted granted Critical
Publication of CN109467046B publication Critical patent/CN109467046B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • B82B3/0061—Methods for manipulating nanostructures
    • B82B3/0066—Orienting nanostructures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • B82B3/0009—Forming specific nanostructures
    • B82B3/0014—Array or network of similar nanostructural elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes

Abstract

The particle of micro-nano-scale, is now placed in mother liquor, obtains the solution containing microcosmic particle by a kind of method for composite material based on the arrangement of nanoparticle three-dimensional micro-nano structureization；Part solution is placed in levelling in container, first structure field is imposed on into the solution in container, pair solution in particle manipulate, realize solution in particle controllable patterned arrangement；Again by solution curing molding in container, container is moved down, and the solution containing microcosmic particle is supplemented in container, change structure field parameters, the longitudinal controllable arrangement for realizing particle in solution realizes the different patternization arrangement of particle in the solution containing microcosmic particle using different structure field；First structure field is changed to the second structure field, particle is made to be arranged into respective shapes；It is repeated up to the composite material for obtaining the arrangement of function nano particle three-dimensional micro-nano structureization；The present invention has many advantages, such as orientable localization adjusting, high efficiency, the molding that Arbitrary 3 D shape and structure can be achieved.

Description

Method for composite material based on the arrangement of nanoparticle three-dimensional micro-nano structureization
Technical field
The invention belongs to minute manufacturing nanostructure technology fields, in particular to a kind of to be based on nanoparticle three-D micro-nano knot The method for composite material of structureization arrangement.
Background technique
The restrained space dimensionality of nanostructure can be divided into 4 kinds: (1) the nano atomic group race of zero dimension；(2) one dimension fibre shape Nanostructure, length are noticeably greater than width, such as carbon nanotube；(3) two-dimensional layer nanostructure, length and width size is extremely More much bigger than thickness less, crystallite dimension is nanoscale in one direction, such as graphene；(4) three-dimensional nano-solid, people Different nano materials is prepared for a variety of different methods, and to numerous preparation methods, it is according to the medium of preparation Gas, liquid or solid can totally be divided into three classes vapor phase method, liquid phase method and solid phase method；Wherein main the including of vapor phase method Learn vapor phase method, sublimation recrystallization method, molten reactant metal method, high pressure gas atomization；Liquid phase method mainly includes hydro-thermal method, precipitating Method, Radiation Synthesis Method, emulsion method；Solid phase method mainly includes high-energy ball milling method, Amorphous Crystallization method, depth plastic deformation method.And this A little methods are the preparation that three-dimensional manometer solid is realized by the growth of control nanoparticle mostly, and nanoparticle is in function Distribution in material is to disperse, is structureless mostly, cannot achieve the function nano particle orientation with three-dimensional micro-nano structure Localization arrangement.
How to realize the Arbitrary 3 D structuring arrangement of low-dimension nano material in the composite, makes the difference of composite material Position shows different physicochemical characteristics, is always one so that composite material be made to meet more complicated working environment Problem.
Summary of the invention
In order to overcome the disadvantages of the above prior art, it is micro- based on nanoparticle three-dimensional that the purpose of the present invention is to provide one kind The method for composite material of nanostructured arrangement, it can be achieved that controllable oriented alignment of the function nano particle in composite material, So that the different location of composite material is shown different physicochemical characteristics, there is orientable localization adjusting, high efficiency, can be achieved The advantages that molding of Arbitrary 3 D shape and structure.
To achieve the goals above, the technical solution adopted by the present invention is as follows:
A kind of method for composite material based on the arrangement of nanoparticle three-dimensional micro-nano structureization, comprising the following steps:
1) particle of micro-nano-scale is placed in mother liquor, stirring is distributed uniform particle, obtains containing microcosmic particle Solution；
2) a part is placed in container containing the solution of microcosmic particle, a part of solution containing microcosmic particle is made at any time For supplement；
3) by the solution levelling in container containing microcosmic particle；
4) first structure field is imposed on into the solution in container containing microcosmic particle, in the solution containing microcosmic particle Particle is manipulated, and realizes the controllable patterned arrangement of particle in the solution containing microcosmic particle；
5) by the solution curing molding in container containing microcosmic particle；
6) container is moved down；
7) solution containing microcosmic particle is supplemented in container；
8) change structure field parameters, realize longitudinal controllable arrangement of particle in the solution containing microcosmic particle；
9) different structure field is used, realizes the different patternization arrangement of particle in the solution containing microcosmic particle；
10) first structure field is changed to the second structure field, particle is made to be arranged into respective shapes；
11) step 2) -10 is repeated) until obtaining the composite material of function nano particle three-dimensional micro-nano structureization arrangement.
Particle in the step 1) is the metallic particles or non-metallic particle that partial size is 30 μm of 100nm-, and mother liquor is Photo curable resinous material or heat-setting organic polymer material, mother liquor viscosity are 1 × 10-3Pa·s—2× 101Pa·s。
Levelling mode in the step 3) is to strike off.
Structuring field in the step 4) is structuring AC field, and voltage 50V-50KV, frequency is 1KHz- 200KHz；The electrode structure of structuring AC field is interdigitated electrodes, combined electrode or inserting electrode；Interdigital electrode fork Finger widths be 5 μm -1mm, it is interdigital between spacing be 5 μm -1mm.
Controllable patterned arrangement in the step 4) is that particle neatly aligns the type of being in line, triangle, circle Or rectangular patterns.
Curing molding mode in the step 5) is ultraviolet light solidification, blue light solidification or heat cure.
Dropping distance in the step 6) is 5 μm -100 μm.
The amount of make-up solution in the step 7) makes the liquid level after having supplemented rise 5 μm -100 μm.
Change structure field parameters in the step 8) are the voltage and frequency of height-regulating structure electric field, realize micro-nano grain Son is in longitudinal arrangement.
The second structure field is used to change interdigital electrode into snakelike electrode structure in the step 10), realizes micro-nano The different patternization of particle is arranged.
Compared with prior art, the invention has the following advantages:
(1) present invention can come the structure of design structure field, and structure field by the arrangement mode of expected microcosmic particle It after completing, can be used continuously, function nano particle orientation localization manipulation truly may be implemented, realize function The three dimensional patterned arrangement of energy nanoparticle.
(2) present invention controllably orients manipulation from realization function nano particle and starts with, and has designed and prepared out differently structured Structure field, and can by adjusting the voltage and frequency of structure field, realize the particle patterned arrangement of function nano difference Width and depth.
(3) relative to traditional manufacture technology of composite material, the present invention can be schemed by the difference for different layers particle The space three-dimensional arrangement that caseization arranges to realize truly function nano particle, so that in composite material contained by different zones The number of function nano particle and arrangement are different from, so that composite material different zones show different mechanical characteristics.Tool There is promotion and application value, is expected to be applied to become functionally gradient material (FGM), novel intelligent material, the fields such as functional composite material manufacture.
Detailed description of the invention
Fig. 1 is manufacturing method schematic diagram of the embodiment of the present invention.
Fig. 2 is the schematic diagram that the embodiment of the present invention realizes function nano particle single layer oriented alignment.
Fig. 3 is after the embodiment of the present invention realizes change structure field parameters, and the different arrangement width of function nano particle shows It is intended to.
Fig. 4 is the different patterned configuration schematic diagram of function nano particle after the embodiment of the present invention realizes change structure field.
Specific embodiment
Below with reference to embodiment and attached drawing, the present invention is further illustrated, but protection of the invention should not be limited with this Range.
Referring to Fig.1, a kind of method for composite material based on the arrangement of nanoparticle three-dimensional micro-nano structureization, including it is following Step:
1) particle for the polystyrene sphere 1 for being 5 μm by diameter is placed in PDMS solution, is stirred five minutes, is kept particle equal Even distribution is evenly distributed the PDMS solution 4 of granules of polystyrene；
2) the PDMS solution 4 of a part of granules of polystyrene is poured into container 3, is then struck off, keep liquid level in container high Degree is 60 μm；
3) by 4 levelling of PDMS solution of granules of polystyrene in container；
4) by 50 μm of interdigital finger beam, 50 microns of span of first structure electric field imposes on granules of polystyrene in container 3 PDMS solution 4 manipulates the particle 1 in solution, particle 1 is made to be arranged into linear type as shown in Figure 2；Wherein, structuring Electric field both end voltage is 30V, and frequency 50KHz, waveform is sinusoidal pattern；
5) by the ultraviolet light 8s of PDMS solution 4 of granules of polystyrene in container 3, it is solidified；
6) 3 height of container is adjusted, container 3 is made to move down 60 μm；
7) the PDMS solution 4 that granules of polystyrene is supplemented into container 3 makes the liquid level of container 3 rise 60 μm；
8) as shown in figure 3, adjustment structured electrodes both end voltage is 50V, 50KHz, realize that the multirow of particle 1 in solution is straight Lineization arrangement, realizes the control of longitudinal direction particle 1；
9) as shown in figure 4, first structure field is changed to the second structure field 5, particle is made to be arranged into circle, wherein 6 line of pole plate It is 50 μm wide, connect anode；50 μm of 7 line width of pole plate, connects cathode；Spacing between pole plate 6 and pole plate 7 is 80 μm；Institute's making alive is 50V, frequency 50KHz；
10) repeat the above steps 2) -9), realize the composite wood arranged containing function nano particle three-dimensional micro-nano structureization The production of material.
For the present invention, available structure field is not limited only to tell two kinds.Although referring to previous examples to this hair It is bright to be described in detail, it for those skilled in the art, still can be to technology documented by previous examples Scheme is modified or equivalent replacement of some of the technical features.All within the spirits and principles of the present invention, institute Any modification, equivalent substitution, improvement and etc. of work, should all be included in the protection scope of the present invention.

Claims (10)

1. it is a kind of based on nanoparticle three-dimensional micro-nano structureization arrangement method for composite material, which is characterized in that including with Lower step:
1) particle of micro-nano-scale is placed in mother liquor, stirring is distributed uniform particle, obtains the solution containing microcosmic particle；
2) a part is placed in container containing the solution of microcosmic particle, a part of solution containing microcosmic particle is at any time as benefit It fills；
3) by the solution levelling in container containing microcosmic particle；
4) first structure field is imposed on into the solution in container containing microcosmic particle, to the particle in the solution containing microcosmic particle It is manipulated, realizes the controllable patterned arrangement of particle in the solution containing microcosmic particle；
5) by the solution curing molding in container containing microcosmic particle；
6) container is moved down；
7) solution containing microcosmic particle is supplemented in container；
8) change structure field parameters, realize longitudinal controllable arrangement of particle in the solution containing microcosmic particle；
9) different structure field is used, realizes the different patternization arrangement of particle in the solution containing microcosmic particle；
10) first structure field is changed to the second structure field, particle is made to be arranged into respective shapes；
11) step 2) -10 is repeated) until obtaining the composite material of function nano particle three-dimensional micro-nano structureization arrangement.
2. a kind of composite material manufacturer based on the arrangement of nanoparticle three-dimensional micro-nano structureization according to claim 1 Method, it is characterised in that: the particle in the step 1) is the metallic particles or non-metallic particle that partial size is 30 μm of 100nm-, Mother liquor is photo curable resinous material or heat-setting organic polymer material, and mother liquor viscosity is 1 × 10-3Pa·s—2 ×101Pa·s。
3. a kind of composite material manufacturer based on the arrangement of nanoparticle three-dimensional micro-nano structureization according to claim 1 Method, it is characterised in that: the levelling mode in the step 3) is to strike off.
4. a kind of composite material manufacturer based on the arrangement of nanoparticle three-dimensional micro-nano structureization according to claim 1 Method, it is characterised in that: structuring field in the step 4) is structuring AC field, voltage 50V-50KV, and frequency is 1KHz—200KHz；The electrode structure of structuring AC field is interdigitated electrodes, combined electrode or inserting electrode；It is interdigital The interdigital width of electrode be 5 μm -1mm, it is interdigital between spacing be 5 μm -1mm.
5. a kind of composite material manufacturer based on the arrangement of nanoparticle three-dimensional micro-nano structureization according to claim 1 Method, it is characterised in that: the controllable patterned arrangement in the step 4) is that particle neatly aligns the type of being in line, triangle Shape, circle or rectangular patterns.
6. a kind of composite material manufacturer based on the arrangement of nanoparticle three-dimensional micro-nano structureization according to claim 1 Method, it is characterised in that: the curing molding mode in the step 5) is ultraviolet light solidification, blue light solidification or heat cure.
7. a kind of composite material manufacturer based on the arrangement of nanoparticle three-dimensional micro-nano structureization according to claim 1 Method, it is characterised in that: the dropping distance in the step 6) is 5 μm -100 μm.
8. a kind of composite material manufacturer based on the arrangement of nanoparticle three-dimensional micro-nano structureization according to claim 1 Method, it is characterised in that: the amount of the make-up solution in the step 7) makes the liquid level after having supplemented rise 5 μm -100 μm.
9. a kind of composite material manufacturer based on the arrangement of nanoparticle three-dimensional micro-nano structureization according to claim 1 Method, it is characterised in that: the change structure field parameters in the step 8) are the voltage and frequency of height-regulating structure electric field, are realized Micro-nano particle is in longitudinal arrangement.
10. a kind of composite material manufacturer based on the arrangement of nanoparticle three-dimensional micro-nano structureization according to claim 1 Method, it is characterised in that: use the second structure field to change interdigital electrode into snakelike electrode structure in the step 10), it is real The different patternization arrangement of existing micro-nano particle.
CN201811141344.9A 2018-09-28 2018-09-28 The method for composite material of particle three-dimensional micro-nano structureization arrangement based on micro-nano-scale Active CN109467046B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811141344.9A CN109467046B (en) 2018-09-28 2018-09-28 The method for composite material of particle three-dimensional micro-nano structureization arrangement based on micro-nano-scale

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811141344.9A CN109467046B (en) 2018-09-28 2018-09-28 The method for composite material of particle three-dimensional micro-nano structureization arrangement based on micro-nano-scale

Publications (2)

Publication Number Publication Date
CN109467046A true CN109467046A (en) 2019-03-15
CN109467046B CN109467046B (en) 2019-11-26

Family

ID=65664399

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811141344.9A Active CN109467046B (en) 2018-09-28 2018-09-28 The method for composite material of particle three-dimensional micro-nano structureization arrangement based on micro-nano-scale

Country Status (1)

Country Link
CN (1) CN109467046B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109901250A (en) * 2019-04-04 2019-06-18 西安交通大学 A kind of optical element and its manufacturing method of the inside containing structured nano scale particle
CN112736212A (en) * 2019-10-28 2021-04-30 Tcl华星光电技术有限公司 Nanoparticle patterning device and nanoparticle patterning method

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1871378A (en) * 2003-07-10 2006-11-29 北卡罗来纳-查佩尔山大学 Deposition method for nanostructure materials
JP2008287163A (en) * 2007-05-21 2008-11-27 Ricoh Co Ltd Electrophoretic dispersion liquid
CN101325151A (en) * 2007-06-08 2008-12-17 芬兰国立技术研究中心 Method and apparatus related to nanoparticle systems
WO2005100541A3 (en) * 2004-04-12 2009-04-09 Univ California Optoelectronic tweezers for microparticle and cell manipulation
CN101446762A (en) * 2008-12-31 2009-06-03 西安交通大学 Micro-complex type method for inducing electric field under the restrict of non-contact moulding board
JP2010091718A (en) * 2008-10-07 2010-04-22 Nikon Corp Method of manufacturing optical element, and the optical element
CN102253435A (en) * 2011-07-11 2011-11-23 西安交通大学 Micromachining method for manufacturing polymer cylindrical microlens by electric field induction
CN103518159A (en) * 2011-05-13 2014-01-15 株式会社櫻花彩色笔 Fine electret particles and process for producing same
CN106430079A (en) * 2016-09-28 2017-02-22 西安交通大学 Manufacturing method of electric field-induced polymer-based function gradient composite micron column
CN106924804A (en) * 2017-02-17 2017-07-07 江汉大学 Nanometer hydroxyapatite/polycaprolactone function-graded material prepared using high voltage electric field induction and preparation method thereof
US20180272348A1 (en) * 2017-03-21 2018-09-27 International Business Machines Corporation Device and Method for Flow and Bead Speed Characterization in Microfluidic Devices

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1871378A (en) * 2003-07-10 2006-11-29 北卡罗来纳-查佩尔山大学 Deposition method for nanostructure materials
WO2005100541A3 (en) * 2004-04-12 2009-04-09 Univ California Optoelectronic tweezers for microparticle and cell manipulation
JP2008287163A (en) * 2007-05-21 2008-11-27 Ricoh Co Ltd Electrophoretic dispersion liquid
CN101325151A (en) * 2007-06-08 2008-12-17 芬兰国立技术研究中心 Method and apparatus related to nanoparticle systems
JP2010091718A (en) * 2008-10-07 2010-04-22 Nikon Corp Method of manufacturing optical element, and the optical element
CN101446762A (en) * 2008-12-31 2009-06-03 西安交通大学 Micro-complex type method for inducing electric field under the restrict of non-contact moulding board
CN103518159A (en) * 2011-05-13 2014-01-15 株式会社櫻花彩色笔 Fine electret particles and process for producing same
CN102253435A (en) * 2011-07-11 2011-11-23 西安交通大学 Micromachining method for manufacturing polymer cylindrical microlens by electric field induction
CN106430079A (en) * 2016-09-28 2017-02-22 西安交通大学 Manufacturing method of electric field-induced polymer-based function gradient composite micron column
CN106924804A (en) * 2017-02-17 2017-07-07 江汉大学 Nanometer hydroxyapatite/polycaprolactone function-graded material prepared using high voltage electric field induction and preparation method thereof
US20180272348A1 (en) * 2017-03-21 2018-09-27 International Business Machines Corporation Device and Method for Flow and Bead Speed Characterization in Microfluidic Devices

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
DANIEL MORALES ET AL.: "Bending of Responsive Hydrogel Sheets Guided by Field-Assembled Microparticle Endoskeleton Structures.", 《SMALL》 *
NING WU ET AL.: "Toward Large-Scale Alignment of Electrohydrodynamic Patterning of Thin Polymer Films.", 《ADVANCED FUNCTIONAL MATERIALS》 *
XIANGMING LI ET AL.: "Fabrication of Microlens Arrays with Well-controlled Curvature by Liquid Trapping and Electrohydrodynamic Deformation in Microholes.", 《ADVANCED MATERIALS》 *
YAJUN ZHANG ET AL.: "Formation of highly ordered microfillers in polymeric matrix by electro-field-assisted aligning.", 《RSC ADVANCES》 *
李欣等.: "电场诱导微结构图形化形成机理及常温制备工艺.", 《纳米技术与精密工程》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109901250A (en) * 2019-04-04 2019-06-18 西安交通大学 A kind of optical element and its manufacturing method of the inside containing structured nano scale particle
CN112736212A (en) * 2019-10-28 2021-04-30 Tcl华星光电技术有限公司 Nanoparticle patterning device and nanoparticle patterning method

Also Published As

Publication number Publication date
CN109467046B (en) 2019-11-26

Similar Documents

Publication Publication Date Title
Li et al. Smart materials by nanoscale magnetic assembly
Kim et al. Three-dimensional printing of highly conductive carbon nanotube microarchitectures with fluid ink
Tawfick et al. Engineering of micro‐and nanostructured surfaces with anisotropic geometries and properties
Ai et al. Advanced colloidal lithography beyond surface patterning
Miao et al. Bioinspired superspreading surface: from essential mechanism to application
Bae et al. 25th anniversary article: scalable multiscale patterned structures inspired by nature: the role of hierarchy
Gao et al. Characterisation of surface wettability based on nanoparticles
Yin et al. Self-assembly of spherical colloids into helical chains with well-controlled handedness
Masuda et al. Low-dimensional arrangement of SiO2 particles
Leng et al. Multifunctional polymer nanocomposites
Cooperstein et al. Hybrid materials for functional 3D printing
Xiong et al. Magnetic-field-driven ultra-small 3D hydrogel microstructures: Preparation of gel photoresist and two-photon polymerization microfabrication
WO2012150278A1 (en) Hierarchical carbon nano and micro structures
Jambhulkar et al. Aligned Ti3C2T x MXene for 3D Micropatterning via Additive Manufacturing
CN109467046B (en) The method for composite material of particle three-dimensional micro-nano structureization arrangement based on micro-nano-scale
Li et al. A review on fabrication and application of tunable hybrid micro–nano array surfaces
Park et al. Fabrication and applications of stimuli‐responsive micro/nanopillar arrays
CN102383102A (en) Magnetic nano anti-dot array film and preparation method thereof
Sola et al. Self-assembly meets additive manufacturing: Bridging the gap between nanoscale arrangement of matter and macroscale fabrication
Handrea-Dragan et al. Multifunctional structured platforms: from patterning of polymer-based films to their subsequent filling with various nanomaterials
Wan et al. A review of superhydrophobic shape-memory polymers: Preparation, activation, and applications
Kuang et al. Materials, design, and fabrication of shape programmable polymers
Cho et al. Focused electric-field polymer writing: toward ultralarge, multistimuli-responsive membranes
Carrola et al. Best of both worlds: Synergistically derived material properties via additive manufacturing of nanocomposites
Du et al. Self-formation of polymer nanostructures in plasma etching: Mechanisms and applications

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant