CN109439074A - A kind of non-skid coating - Google Patents

A kind of non-skid coating Download PDF

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Publication number
CN109439074A
CN109439074A CN201811113630.4A CN201811113630A CN109439074A CN 109439074 A CN109439074 A CN 109439074A CN 201811113630 A CN201811113630 A CN 201811113630A CN 109439074 A CN109439074 A CN 109439074A
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China
Prior art keywords
skid coating
skid
coating
water
elastomer powder
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Pending
Application number
CN201811113630.4A
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Chinese (zh)
Inventor
张忠峰
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Ningbo Hong Kong Long Packing Materials Co Ltd
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Ningbo Hong Kong Long Packing Materials Co Ltd
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Priority to CN201811113630.4A priority Critical patent/CN109439074A/en
Publication of CN109439074A publication Critical patent/CN109439074A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D109/00Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
    • C09D109/02Copolymers with acrylonitrile
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D107/00Coating compositions based on natural rubber
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D109/00Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
    • C09D109/06Copolymers with styrene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/16Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/45Anti-settling agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/66Additives characterised by particle size
    • C09D7/67Particle size smaller than 100 nm
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/38Coatings with pigments characterised by the pigments
    • D21H19/40Coatings with pigments characterised by the pigments siliceous, e.g. clays
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/58Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/60Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/62Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nanotechnology (AREA)
  • Dispersion Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of non-skid coatings, including water-and acrylate lotion or aqueous polyurethane emulsion, elastomer powder, water, film forming agent, nano silica and adhesion promoter.Non-skid coating of the invention is suitable for spraying or being coated in a variety of substrate surfaces, such as paper, plastics, steel;After non-skid coating of the invention is sprayed or is coated on substrate, it can form a film at room temperature, considerably increase the use scope of non-skid coating;Non-skid coating of the invention is water paint, and environmental-protecting performance is excellent.

Description

A kind of non-skid coating
Technical field
The present invention relates to technical field of coatings more particularly to a kind of non-skid coatings.
Background technique
In cargo transport, need to avoid cargo that opposite slide occurs due to inertia etc..Common method is to pass through Attaching means constrains cargo, and cargo is avoided to slide between each other, at present there is a method in which being exactly the frictional force increased between cargo, To avoid cargo that opposite sliding occurs.
In the patent of Patent No. CN201720972847.5, a kind of gum antiskid paper is disclosed, by paper Coat anti-slip layer, the frictional force of Lai Zengjia antiskid paper in side.The gum antiskid paper is attached on cargo or cargo pallet, Ke Yizeng Add the frictional force of cargo surfaces, to play the effect of anti-sliding stop.
But existing non-skid coating needs to place a period of time at a higher temperature after being coated on substrate surface Afterwards, nonskid coating could be obtained, which limits the applications of non-skid coating.For example, in some cases, cargo has been completed to wrap Dress, also there is no antiskid effects for the packaging bag of cargo, at this point, traditional non-skid coating can not be coated in outside packaging bag, make to wrap Pack obtains nonskid coating.
Summary of the invention
For overcome the deficiencies in the prior art, the purpose of the present invention is to provide a kind of non-skid coating, be suitable for spraying or Coated in substrate surface, to quickly and easily form nonskid coating in substrate surface.
The purpose of the present invention adopts the following technical scheme that realization:
A kind of non-skid coating, comprising: water-and acrylate lotion or aqueous polyurethane emulsion, elastomer powder, water, film forming Agent, nano silica and adhesion promoter.
Further, the granularity of the elastomer powder is 100 mesh~400 mesh.
Further, the elastomer powder is selected from one or more of: rubber powder, elastic polyurethane powder, elasticity are poly- Ethylene powder.
Further, the non-skid coating includes water-and acrylate lotion, and the water-and acrylate lotion is non-anti- Answer type acrylic acid ester emulsion.
Further, the non-skid coating includes aqueous polyurethane emulsion, and the aqueous polyurethane emulsion is poly- for one pack system Urethane lotion.
Further, the mass fraction of each component in the non-skid coating is respectively as follows:
Compared with prior art, it is suitable for spraying the beneficial effects of the present invention are: non-skid coating of the invention or is coated in more Kind substrate surface, such as paper, plastics, steel;Non-skid coating spraying of the invention or after being coated on substrate, can at room temperature at Film considerably increases the use scope of non-skid coating;Non-skid coating of the invention is water paint, and environmental-protecting performance is excellent.
Specific embodiment
In the following, being described further in conjunction with specific embodiment to the present invention, it should be noted that is do not collided Under the premise of, new embodiment can be formed between various embodiments described below or between each technical characteristic in any combination.
First preferred embodiment according to the present invention, non-skid coating of the invention include: water-and acrylate lotion, Elastomer powder, water, film forming agent, nano silica and adhesion promoter.
Water-and acrylate lotion is used in coating more and more because of its feature of environmental protection, but water-and acrylate The non-skid property of itself is poor, in the prior art mainly by carrying out graft modification to acrylate, to improve acrylate The skid resistance of coating.And the present invention is formed anti-mainly by directly mixing elastomer powder with water-and acrylate lotion Sliding coating, preparation method is simple, at low cost.
In some embodiments, water-and acrylate lotion of the invention is non-reactive acrylic acid ester emulsion, film forming When rely primarily on the coalescence of interparticle physics to improve the performance of film, it is of the invention due to not needing to crosslink reaction Non-skid coating can form a film at room temperature.The preparation method of non-reactive acrylic acid ester emulsion can refer to the prior art, the present invention No longer it is described in detail.
Nano silica is to improve the important channel of aqueous polymer emulsion performance, and nano silica is of the invention In formula, it can also play the role of preventing elastomer powder from depositing, the uniformity of elastomer powder distribution be improved, thus favorably In the coefficient of friction for the nonskid coating for improving non-skid coating preparation of the present invention.
Elastomer powder main function is the frictional force of increase non-skid coating, and granularity is preferably 100 mesh~400 mesh. Elastomer powder be selected from one or more of: rubber powder, TPU, TPE, wherein rubber powder include but is not limited to acrylonitrile-butadiene rubber powder, Styrene butadiene rubber powder, EP rubbers, natural rubber.
Adhesion promoter can be aqueous or oiliness.In some embodiments, adhesion promoter is aqueous, adhesive force Promotor includes but is not limited to BYK-4500, BYK-4510, and BYK-4500, BYK-4510 are the attached of German Bi Ke company exploitation Adhesion promoter, is the prior art, and the present invention is no longer described in detail.
Preferably, the mass fraction of each component in non-skid coating is respectively as follows:
Second preferred embodiment according to the present invention, non-skid coating of the invention include: aqueous polyurethane emulsion, bullet Property body powder, water, film forming agent, nano silica and adhesion promoter.
Aqueous polyurethane emulsion is not only environmentally friendly material, and function admirable, is widely used in paint field. In some embodiments, aqueous polyurethane emulsion of the invention is monocomponent waterborne polyurethane lotion, using water as dispersing agent, The crosslinking reaction may not occur in film forming procedure, and due to not needing to crosslink reaction, non-skid coating of the invention can be in room temperature Lower film forming.The type and preparation method of monocomponent waterborne polyurethane lotion can refer to the prior art, and the present invention is no longer described in detail.
Nano silica is to improve the important channel of aqueous polymer emulsion performance, and nano silica is of the invention In formula, it can also play the role of preventing elastomer powder from depositing, the uniformity of elastomer powder distribution be improved, thus favorably The coefficient of friction of nonskid coating is prepared in raising non-skid coating of the present invention.
Elastomer powder main function is the frictional force of increase non-skid coating, and granularity is preferably 100 mesh~400 mesh. Elastomer powder be selected from one or more of: rubber powder, TPU, TPE, wherein rubber powder include but is not limited to acrylonitrile-butadiene rubber powder, Styrene butadiene rubber powder, EP rubbers, natural rubber.
Adhesion promoter can be aqueous or oiliness.In some embodiments, adhesion promoter is aqueous, attachment Power promotor includes but is not limited to BYK-4500, BYK-4510.BYK-4500, BYK-4510 are that German Bi Ke company develops Adhesion promoter, is the prior art, and the present invention is no longer described in detail.
Preferably, the mass fraction of each component in non-skid coating is respectively as follows:
[embodiment 1]
Non-skid coating includes the component of following mass percent:
At 25 DEG C~45 DEG C, the above components are uniformly mixed, non-skid coating is obtained.
[embodiment 2]
Non-skid coating includes the component of following mass percent:
At 25 DEG C~45 DEG C, the above components are uniformly mixed, non-skid coating is obtained.
[embodiment 3]
Non-skid coating includes the component of following mass percent:
At 25 DEG C~45 DEG C, the above components are uniformly mixed, non-skid coating is obtained.
[embodiment 4]
Non-skid coating includes the component of following mass percent:
At 25 DEG C~45 DEG C, the above components are uniformly mixed, non-skid coating is obtained.
[embodiment 5]
Non-skid coating includes the component of following mass percent:
At 25 DEG C~45 DEG C, the above components are uniformly mixed, non-skid coating is obtained.
[embodiment 6]
Non-skid coating includes the component of following mass percent:
At 25 DEG C~45 DEG C, the above components are uniformly mixed, non-skid coating is obtained.
[comparative example 1]
Coating includes the component of following mass percent:
At 25 DEG C~45 DEG C, the above components are uniformly mixed, obtain the coating of comparative example 1.
[comparative example 2]
Coating includes the component of following mass percent:
At 25 DEG C~45 DEG C, the above components are uniformly mixed, obtain the coating of comparative example 2.
[comparative example 3]
Coating includes the component of following mass percent:
At 25 DEG C~45 DEG C, the above components are uniformly mixed, obtain the coating of comparative example 3.
[comparative example 4]
Non-skid coating includes the component of following mass percent:
At 25 DEG C~45 DEG C, the above components are uniformly mixed, obtain the coating of comparative example 4.
The coating of each embodiment and comparative example is sprayed on to brown paper, PP plastic knitting band, surface of steel plate respectively, then The confficient of static friction and dynamic friction coefficient of each sample are tested, experimental result is shown in Table 1.
Table 1
The above embodiment is only the preferred embodiment of the present invention, and the scope of protection of the present invention is not limited thereto, The variation and replacement for any unsubstantiality that those skilled in the art is done on the basis of the present invention belong to institute of the present invention Claimed range.

Claims (6)

1. a kind of non-skid coating characterized by comprising water-and acrylate lotion or aqueous polyurethane emulsion, elastomer powder End, water, film forming agent, nano silica and adhesion promoter.
2. non-skid coating according to claim 1, which is characterized in that the granularity of the elastomer powder is 100 mesh~400 Mesh.
3. non-skid coating according to claim 1, which is characterized in that the elastomer powder is selected from following a kind of or more Kind: rubber powder, TPU, TPE.
4. non-skid coating according to claim 1, which is characterized in that the non-skid coating includes water-and acrylate cream Liquid, the water-and acrylate lotion are non-reactive acrylic acid ester emulsion.
5. non-skid coating according to claim 1, which is characterized in that the non-skid coating includes aqueous polyurethane emulsion, The aqueous polyurethane emulsion is mono-component polyurethane lotion.
6. -5 any non-skid coating according to claim 1, which is characterized in that the quality of each component in the non-skid coating Number is respectively as follows:
CN201811113630.4A 2018-09-25 2018-09-25 A kind of non-skid coating Pending CN109439074A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111073088A (en) * 2019-09-29 2020-04-28 大茂环保新材料股份有限公司 Water-based elastic floor block and production process thereof
CN112708322A (en) * 2020-12-11 2021-04-27 广东西敦千江粉漆科学研究有限公司 Anti-skid powder coating and preparation method and spraying process thereof
CN113174777A (en) * 2021-03-31 2021-07-27 美盈森集团股份有限公司 Bi-component coating type anti-slip coating and preparation method thereof
CN116179068A (en) * 2023-03-17 2023-05-30 天津科技大学 Anti-friction polyurethane super-hydrophobic coating prepared based on organic/inorganic particle composite, coating, method and application

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CN104119759A (en) * 2014-07-10 2014-10-29 广东柏胜新材料科技有限公司 Wear-resistant weather-proof antiskid sports ground silicone-acrylic coating
CN104194601A (en) * 2014-08-27 2014-12-10 句容市石狮冲压件厂 Antiskid paint for bicycle court tracks and preparation method thereof
CN105803896A (en) * 2016-04-11 2016-07-27 上海台安实业集团有限公司 High-performance and environment-friendly waterborne plastic track
CN107266998A (en) * 2016-12-23 2017-10-20 惠州兴鑫涂料化工有限公司 A kind of environment-friendly type pavement antiskid paint

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CN104119759A (en) * 2014-07-10 2014-10-29 广东柏胜新材料科技有限公司 Wear-resistant weather-proof antiskid sports ground silicone-acrylic coating
CN104194601A (en) * 2014-08-27 2014-12-10 句容市石狮冲压件厂 Antiskid paint for bicycle court tracks and preparation method thereof
CN105803896A (en) * 2016-04-11 2016-07-27 上海台安实业集团有限公司 High-performance and environment-friendly waterborne plastic track
CN107266998A (en) * 2016-12-23 2017-10-20 惠州兴鑫涂料化工有限公司 A kind of environment-friendly type pavement antiskid paint

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111073088A (en) * 2019-09-29 2020-04-28 大茂环保新材料股份有限公司 Water-based elastic floor block and production process thereof
CN111073088B (en) * 2019-09-29 2022-03-25 大茂环保新材料股份有限公司 Water-based elastic floor block and production process thereof
CN112708322A (en) * 2020-12-11 2021-04-27 广东西敦千江粉漆科学研究有限公司 Anti-skid powder coating and preparation method and spraying process thereof
CN113174777A (en) * 2021-03-31 2021-07-27 美盈森集团股份有限公司 Bi-component coating type anti-slip coating and preparation method thereof
CN116179068A (en) * 2023-03-17 2023-05-30 天津科技大学 Anti-friction polyurethane super-hydrophobic coating prepared based on organic/inorganic particle composite, coating, method and application

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