CN109438981A - 一种聚苯胺复合氢氧化镁阻燃剂的制备方法 - Google Patents
一种聚苯胺复合氢氧化镁阻燃剂的制备方法 Download PDFInfo
- Publication number
- CN109438981A CN109438981A CN201811344659.3A CN201811344659A CN109438981A CN 109438981 A CN109438981 A CN 109438981A CN 201811344659 A CN201811344659 A CN 201811344659A CN 109438981 A CN109438981 A CN 109438981A
- Authority
- CN
- China
- Prior art keywords
- magnesium hydroxide
- flame retardant
- polyaniline
- aniline
- compound flame
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 52
- 239000000347 magnesium hydroxide Substances 0.000 title claims abstract description 44
- 229910001862 magnesium hydroxide Inorganic materials 0.000 title claims abstract description 44
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 title claims abstract description 41
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 229920000767 polyaniline Polymers 0.000 title claims abstract description 38
- 150000001875 compounds Chemical class 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims abstract description 72
- 239000003999 initiator Substances 0.000 claims abstract description 19
- 238000005406 washing Methods 0.000 claims abstract description 19
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000908 ammonium hydroxide Substances 0.000 claims abstract description 11
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 8
- 239000011777 magnesium Substances 0.000 claims abstract description 8
- 238000001914 filtration Methods 0.000 claims abstract description 4
- 239000000843 powder Substances 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 239000000654 additive Substances 0.000 claims description 14
- 230000000996 additive effect Effects 0.000 claims description 14
- 239000008367 deionised water Substances 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 14
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L magnesium chloride Substances [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 10
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 8
- 229910021641 deionized water Inorganic materials 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 8
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 229910001868 water Inorganic materials 0.000 claims description 8
- 229910001641 magnesium iodide Inorganic materials 0.000 claims description 6
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 6
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Inorganic materials O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims description 3
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 claims description 2
- 238000002242 deionisation method Methods 0.000 claims 1
- 238000002604 ultrasonography Methods 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 6
- 239000002994 raw material Substances 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 238000003912 environmental pollution Methods 0.000 abstract 1
- 229920002521 macromolecule Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 230000001376 precipitating effect Effects 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 description 17
- 239000001301 oxygen Substances 0.000 description 9
- 229910052760 oxygen Inorganic materials 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 239000002002 slurry Substances 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 238000012512 characterization method Methods 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- -1 compound magnesium hydroxide Chemical class 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 235000019504 cigarettes Nutrition 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 2
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 125000001841 imino group Chemical group [H]N=* 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
- C08L79/02—Polyamines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/026—Wholly aromatic polyamines
- C08G73/0266—Polyanilines or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
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CN201811344659.3A CN109438981B (zh) | 2018-11-13 | 2018-11-13 | 一种聚苯胺复合氢氧化镁阻燃剂的制备方法 |
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CN201811344659.3A CN109438981B (zh) | 2018-11-13 | 2018-11-13 | 一种聚苯胺复合氢氧化镁阻燃剂的制备方法 |
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Publication Number | Publication Date |
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CN109438981A true CN109438981A (zh) | 2019-03-08 |
CN109438981B CN109438981B (zh) | 2021-01-01 |
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Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101210111A (zh) * | 2006-12-29 | 2008-07-02 | 财团法人工业技术研究院 | 有机/无机复合材料与包含该复合材料的防火板材 |
CN102010619A (zh) * | 2010-11-24 | 2011-04-13 | 沈阳工业大学 | 一种氢氧化镁阻燃剂制备方法及所制备的氢氧化镁阻燃剂 |
CN102432876A (zh) * | 2011-11-04 | 2012-05-02 | 无锡中科光远生物材料有限公司 | 一种杂化二氧化钛-聚苯胺纳米粒子及其制备方法 |
WO2012144608A1 (ja) * | 2011-04-20 | 2012-10-26 | 三菱レイヨン株式会社 | 導電性組成物及び前記導電性組成物を用いた導電体、並びに固体電解コンデンサ |
CN103803602A (zh) * | 2012-11-15 | 2014-05-21 | 毛其伟 | 一种氢氧化镁阻燃剂的制备方法 |
CN104804474A (zh) * | 2015-05-19 | 2015-07-29 | 山东航通工贸有限公司 | 一种双包覆氢氧化镁阻燃剂及其制备方法 |
WO2018157400A1 (zh) * | 2017-03-03 | 2018-09-07 | 深圳市佩成科技有限责任公司 | PANI/Fe3O4/MWCNTs-石蜡复合材料的制备方法 |
-
2018
- 2018-11-13 CN CN201811344659.3A patent/CN109438981B/zh active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101210111A (zh) * | 2006-12-29 | 2008-07-02 | 财团法人工业技术研究院 | 有机/无机复合材料与包含该复合材料的防火板材 |
CN102010619A (zh) * | 2010-11-24 | 2011-04-13 | 沈阳工业大学 | 一种氢氧化镁阻燃剂制备方法及所制备的氢氧化镁阻燃剂 |
WO2012144608A1 (ja) * | 2011-04-20 | 2012-10-26 | 三菱レイヨン株式会社 | 導電性組成物及び前記導電性組成物を用いた導電体、並びに固体電解コンデンサ |
CN102432876A (zh) * | 2011-11-04 | 2012-05-02 | 无锡中科光远生物材料有限公司 | 一种杂化二氧化钛-聚苯胺纳米粒子及其制备方法 |
CN103803602A (zh) * | 2012-11-15 | 2014-05-21 | 毛其伟 | 一种氢氧化镁阻燃剂的制备方法 |
CN104804474A (zh) * | 2015-05-19 | 2015-07-29 | 山东航通工贸有限公司 | 一种双包覆氢氧化镁阻燃剂及其制备方法 |
WO2018157400A1 (zh) * | 2017-03-03 | 2018-09-07 | 深圳市佩成科技有限责任公司 | PANI/Fe3O4/MWCNTs-石蜡复合材料的制备方法 |
Non-Patent Citations (2)
Title |
---|
戴焰林等: ""氢氧化镁阻燃剂在聚合物材料中的应用"", 《应用化工》 * |
王国祥等: ""复合引发剂合成氢氧化镁/聚丙烯酰胺"", 《当代化工》 * |
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Effective date of registration: 20240411 Address after: No. 2 Yunjing Road, Information Industry Base, Luoyang Street Office, Economic Development Zone, Kunming Area, China (Yunnan) Pilot Free Trade Zone, Kunming City, Yunnan Province, 650501 Patentee after: YUNNAN TIN NEW MATERIAL Co.,Ltd. Country or region after: China Address before: No. 650000, Changyuan Road, Kunming, Yunnan Province Patentee before: R & D Center of Yunnan Tin Industry Group (Holdings) Co.,Ltd. Country or region before: China |