CN109437532A - A kind of glass tempering furnace and its application method modified for surface - Google Patents

A kind of glass tempering furnace and its application method modified for surface Download PDF

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Publication number
CN109437532A
CN109437532A CN201811617501.9A CN201811617501A CN109437532A CN 109437532 A CN109437532 A CN 109437532A CN 201811617501 A CN201811617501 A CN 201811617501A CN 109437532 A CN109437532 A CN 109437532A
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China
Prior art keywords
heating furnace
furnace
nitrogen
valve
glass
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CN201811617501.9A
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Chinese (zh)
Inventor
王东
金良茂
鲍田
汤永康
甘治平
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CNBM Bengbu Design and Research Institute for Glass Industry Co Ltd
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CNBM Bengbu Design and Research Institute for Glass Industry Co Ltd
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Priority to CN201811617501.9A priority Critical patent/CN109437532A/en
Publication of CN109437532A publication Critical patent/CN109437532A/en
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B27/00Tempering or quenching glass products
    • C03B27/012Tempering or quenching glass products by heat treatment, e.g. for crystallisation; Heat treatment of glass products before tempering by cooling

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Photovoltaic Devices (AREA)

Abstract

The present invention provides a kind of glass tempering furnace and its application method for surface modification, it includes upper piece platform (1), the first heating furnace (2) are equipped with upper platform (1) side, it is characterized by: being equipped with the second heating furnace (3) in the first heating furnace (2) side, air grid (4) are equipped in the second heating furnace (3) side, are equipped with bottom sheet platform (5) in air grid (4) side.Photovoltaic glass successively after the activation modification of the first and second heating furnace, is waiting until modified photovoltaic glass in bottom sheet platform into hot wind grid chilling.It is the configuration of the present invention is simple, easy to operate, the problem of effectively avoiding the generated output decaying of photovoltaic glass in the prior art after a period of use.

Description

A kind of glass tempering furnace and its application method modified for surface
Technical field:
The present invention relates to glass tempering technology fields, specifically exactly a kind of glass tempering furnace modified for surface and its make Use method.
Background technique:
In order to improve the generating efficiency of photovoltaic cell, people coat antireflective film in photovoltaic glass surface, and antireflective film can increase too Sunlight transmittance rate, to improve the generating efficiency of photovoltaic cell.Now widely used antireflective film is a kind of The film of main component, in order to meet the requirement of photovoltaic glass high intensity and film adhesion, the prior art is first to plate silicon substrate Film liquid is coated in photovoltaic glass surface, then utilizes annealing furnace, the heat treatment of the tempering of glass and film layer is carried out simultaneously, tempering Furnace is mainly made of heating furnace and air grid, and the photovoltaic glass after film is heated to close to after softening temperature in heating furnace, into Enter air grid by chilling, obtain tempered glass, meets the requirement of photovoltaic glass high intensity, while the high temperature of heating furnace is also by silicon substrate Antireflective film sintering makes film layer have high adhesive force in glass surface.
But this antireflective film just will appear transmitance reduction after coming into operation 1 ~ 2 year, and photovoltaic power is caused to decay. There are many reason of causing transmitance to reduce, and one of major reason is: there are great amount of hydroxy group, hydroxyl poles for silicon substrate anti-reflection film surface Water and dirt easily in absorption environment, scatter incident sunlight, by the accumulation of certain time, will seriously reduce photovoltaic electric The generating efficiency in pond.The annealing furnace of the prior art can only carry out glass tempering and film layer sintering, can not eliminate surface hydroxyl.Also have It by the modified method to reduce hydroxyl in surface, but carries out heating and modification again to the anti-reflection film glass after tempering, is It is time-consuming, laborious, uneconomic, it is done so currently without manufacturer, also without the suitable equipment for handling again.
Summary of the invention:
The present invention is exactly in order to overcome the shortcomings in the prior art, to provide a kind of glass tempering furnace modified for surface and its make Use method.
The present invention the following technical schemes are provided:
A kind of glass tempering furnace modified for surface, it includes upper piece platform, is equipped with the first heating furnace upper platform side, special Sign is: being equipped with the second heating furnace in the first heating furnace side, is equipped with air grid in the second heating furnace side, is equipped in air grid side Bottom sheet platform;The first nitrogen inlet duct, the second nitrogen inlet duct and exhaust pipe are communicated on the second heating furnace, the first nitrogen into Tracheae be equipped with the first valve, on the second nitrogen inlet duct be equipped with the second valve, on exhaust pipe be equipped with exhaust valve, first It is additionally provided with branch pipe on nitrogen inlet duct, manifold valve, first nitrogen inlet duct one end and the first source nitrogen are equipped on branch pipe Connection, second nitrogen inlet duct one end are connected to the second source nitrogen, input modifying agent in described branch pipe one end.
Based on the above technical solution, there can also be technical solution further below:
First source nitrogen provides the low-pressure nitrogen that pressure is 0.03 ~ 0.04Mp.
Second source nitrogen provides the high pressure nitrogen that pressure is 0.4 ~ 0.6Mp.
The temperature for the nitrogen that first source nitrogen and the second gas source provide is 580 ~ 680 DEG C.
The branch pipe is connected on the tube body of the first nitrogen inlet duct between the first valve and the second heating furnace.
The modifying agent is trim,ethylchlorosilane or dimethyldichlorosilane or hexamethyldisiloxane or hexamethyl second Alkenyl siloxane or vinylethoxysilane or phenyl tri-chlorination silane or butanol or amylalcohol or polyvinyl alcohol or n-octyl alcohol or Straight chain lauryl alcohol or hexamethyldisilazane etc..
A kind of application method of the glass tempering furnace modified for surface, it is characterised in that it the following steps are included:
1, nitrogen charging: opening the first valve, low-pressure nitrogen be passed through the second heating furnace, makes the second heating furnace nitrogen atmosphere, adjusts The aperture of first valve makes the second heating nitrogen pressure in furnace be maintained at 50 ~ 1000Pa;
2, it activates: the photovoltaic glass after film being placed on the rollgang of upper piece platform, then open the first heating furnace close to upper Photovoltaic glass is sent into the first heating furnace by rollgang, glass is heated to 300 by the first feeding furnace door of piece platform side ~ 450 DEG C, the impurity such as moisture for activating antireflective film surface hydroxyl sufficiently, while removing adsorption;
3, it is protected into furnace gas: opening the first discharging door of the first heating furnace other side and the second feed furnace of the second heating furnace side Photovoltaic glass in first heating furnace, is then input in the second heating furnace by rollgang, in the second feeding furnace door by door While opening, opening the second valve so that high pressure nitrogen is quickly passed through the second heating furnace, to maintain positive pressure in furnace, prevents sky Gas enters, and after photovoltaic glass enters the second heating furnace, the second feeding furnace door and the second valve is closed, to guarantee the second heating furnace Nitrogen pressure is stablized;
4, modified: after photovoltaic glass enters the second heating furnace, to open manifold valve and modifying agent is made to enter the first nitrogen inlet duct, change Property agent gasified by high-temperature low-pressure nitrogen, and be entrained into the second heating furnace of people, then modifying agent and antireflective film surface hydroxyl occur Chemical reaction achievees the purpose that reduce surface hydroxyl, opens exhaust valve and reaction end gas is discharged, when glass is heated to approach softening temperature After degree, manifold valve and exhaust valve are closed, photovoltaic glass preparation is come out of the stove;
5, go out furnace gas to protect;Second discharging door of the second heating furnace other side is opened, and the photovoltaic glass in furnace passes through rollgang Be transported into the air grid of the second heating furnace other side, the second discharging door open while open the second valve so that High pressure nitrogen, which enters, is quickly passed through the second heating furnace, to maintain positive pressure in furnace, prevents air from entering, is turned completely to photovoltaic glass After transporting the second heating furnace, the second discharging door and the second valve are closed, to guarantee that the second heating furnace nitrogen pressure is stablized;
6, it quenching: after photovoltaic glass is transported into air grid by rollgang, is transported into down by rapid cooling, then by rollgang Piece platform, to obtain the modified antireflective film photovoltaic glass in surface.
Invention advantage:
Annealing furnace of the invention can carry out surface modification treatment to antireflective film in photovoltaic glass tempering process, directly come out Be exactly surface modified version product, treatment effeciency is high, and equipment is simple, and operation is easy, at low cost.
Detailed description of the invention:
Fig. 1 is structural schematic diagram of the invention.
Specific embodiment:
As shown in Figure 1, a kind of glass tempering furnace modified for surface, it includes upper piece platform 1, is equipped with the upper 1 side of platform One heating furnace 2 is equipped with the first feeding furnace door 2a, on the furnace body of upper 1 other side of platform on the furnace body close to upper piece 1 side of platform Equipped with the first discharging door 2b.
It is equipped with the second heating furnace 3 in the first side discharging door 2b, is added close to the second of the first side discharging door 2b The furnace body of hot stove 3 is equipped with the second feeding furnace door 3a, and the second discharging door is equipped on the furnace body of 3 other side of the second heating furnace 3b。
It is equipped with air grid 4 in the second side discharging door 3b, is equipped with bottom sheet platform 5, upper piece platform 1, first in 4 side of air grid Rollgang on heating furnace 2, the second heating furnace 3, air grid 4 and bottom sheet platform 5, in same level, and upper piece platform 1, It is additionally provided with excessive roller-way between one heating furnace 2, the second heating furnace 3, air grid 4 and bottom sheet platform 5, so that glass plate can be from upper piece platform Rollgang be moved on the rollgang of bottom sheet platform.Described upper piece platform, the first and second heating furnace, air grid, bottom sheet platform are Existing equipment, wherein included rollgang, specific structure is no longer superfluous here to be chatted, and excessive roller-way is also existing equipment, therefore Here also no longer superfluous to chat.
The first nitrogen inlet duct 6, the second nitrogen inlet duct 7 and exhaust pipe 8 are communicated on the furnace roof of the second heating furnace 3, The vertical distribution of first nitrogen inlet duct 6, the second nitrogen inlet duct 7 and exhaust pipe 8, and be separated between being gone back between each pipe certain Spacing.
It is equipped with the first valve 6a on the first nitrogen inlet duct 6, the second valve 7a is equipped on the second nitrogen inlet duct 7, Exhaust valve 8a is equipped on exhaust pipe 8.Described first nitrogen inlet duct, 6 one end is connected to the first source nitrogen, second nitrogen 7 one end of air inlet pipe is connected to the second source nitrogen.First source nitrogen provides the low-pressure nitrogen that pressure is 0.03 ~ 0.04Mp, the Two source nitrogens provide the high pressure nitrogen that pressure is 0.4 ~ 0.6Mp.The nitrogen that first source nitrogen and the second gas source provide Temperature be 580 ~ 680 DEG C.
It is additionally provided with branch pipe 9 on the first nitrogen inlet duct 6 between the first valve 6a and the furnace roof of the second heating furnace 3, On branch pipe 9 be equipped with manifold valve 9a, described 9 one end of branch pipe input modifying agent, the modifying agent be trim,ethylchlorosilane or Dimethyldichlorosilane or hexamethyldisiloxane or hexamethyl vinylsiloxane or vinylethoxysilane or phenyl three Chlorinated silane or butanol or amylalcohol or polyvinyl alcohol or n-octyl alcohol or straight chain lauryl alcohol or hexamethyldisilazane etc..
A kind of application method of the glass tempering furnace modified for surface, it is characterised in that it the following steps are included:
1, nitrogen charging: opening the first valve, low-pressure nitrogen be passed through the second heating furnace, makes the second heating furnace nitrogen atmosphere, adjusts The aperture of first valve makes the second heating nitrogen pressure in furnace be maintained at 50 ~ 1000Pa;
2, it activates: the photovoltaic glass after film being placed on the rollgang of upper piece platform, then open the first heating furnace close to upper Photovoltaic glass is sent into the first heating furnace by rollgang, glass is heated to 300 by the first feeding furnace door of piece platform side ~ 450 DEG C, the impurity such as moisture for activating antireflective film surface hydroxyl sufficiently, while removing adsorption;
3, it is protected into furnace gas: opening the first discharging door of the first heating furnace other side and the second feed furnace of the second heating furnace side Photovoltaic glass in first heating furnace, is then input in the second heating furnace by rollgang, in the second feeding furnace door by door While opening, opening the second valve so that high pressure nitrogen is quickly passed through the second heating furnace, to maintain positive pressure in furnace, prevents sky Gas enters, and after photovoltaic glass enters the second heating furnace, the second feeding furnace door and the second valve is closed, to guarantee the second heating furnace Nitrogen pressure is stablized;
4, modified: after photovoltaic glass enters the second heating furnace, to open manifold valve and make the hexamethyldisilazane as modifying agent Into the first nitrogen inlet duct, hexamethyldisilazane is gasified by high-temperature low-pressure nitrogen, and is entrained into the second heating furnace of people, and Modifying agent is chemically reacted with antireflective film surface hydroxyl afterwards, achievees the purpose that reduce surface hydroxyl, and it is anti-to open exhaust valve discharge Tail gas is answered, after glass is heated to close to softening temperature, closes manifold valve and exhaust valve, photovoltaic glass preparation is come out of the stove;
5, go out furnace gas to protect;Second discharging door of the second heating furnace other side is opened, and the photovoltaic glass in furnace passes through rollgang Be transported into the air grid of the second heating furnace other side, the second discharging door open while open the second valve so that High pressure nitrogen, which enters, is quickly passed through the second heating furnace, to maintain positive pressure in furnace, prevents air from entering, is turned completely to photovoltaic glass After transporting the second heating furnace, the second discharging door and the second valve are closed, to guarantee that the second heating furnace nitrogen pressure is stablized;
6, it quenching: after photovoltaic glass is transported into air grid by rollgang, is transported into down by rapid cooling, then by rollgang Piece platform, to obtain the modified antireflective film photovoltaic glass in surface.

Claims (7)

1. a kind of glass tempering furnace modified for surface, it includes upper piece platform (1), upper platform (1) side be equipped with first plus Hot stove (2), it is characterised in that: be equipped with the second heating furnace (3) in the first heating furnace (2) side, set in the second heating furnace (3) side There are air grid (4), is equipped with bottom sheet platform (5) in air grid (4) side;The first nitrogen inlet duct is communicated on the second heating furnace (3) (6), the second nitrogen inlet duct (7) and exhaust pipe (8) are equipped with the first valve (6a) on the first nitrogen inlet duct (6), second Nitrogen inlet duct (7) is equipped with the second valve (7a), is equipped with exhaust valve (8a) on exhaust pipe (8), the first nitrogen inlet duct (6) it is additionally provided with branch pipe (9) on, is equipped with manifold valve (9a) on branch pipe (9), described first nitrogen inlet duct (6) one end and first Source nitrogen connection, described second nitrogen inlet duct (7) one end are connected to the second source nitrogen, and in the branch pipe (9) one end, input changes Property agent.
2. a kind of glass tempering furnace modified for surface according to claim 1, it is characterised in that: described first Source nitrogen provides the low-pressure nitrogen that pressure is 0.03 ~ 0.04Mp.
3. a kind of glass tempering furnace modified for surface according to claim 1, it is characterised in that: described second Source nitrogen provides the high pressure nitrogen that pressure is 0.4 ~ 0.6Mp.
4. a kind of glass tempering furnace modified for surface according to claim 1, it is characterised in that: first nitrogen The temperature for the nitrogen that gas source and the second gas source provide is 580 ~ 680 DEG C.
5. a kind of glass tempering furnace modified for surface according to claim 1, it is characterised in that: the branch pipe (9) it is connected on the tube body of the first nitrogen inlet duct (6) between the first valve (6a) and the second heating furnace (3).
6. a kind of glass tempering furnace modified for surface according to claim 1, it is characterised in that: the modification Agent is trim,ethylchlorosilane or dimethyldichlorosilane or hexamethyldisiloxane or hexamethyl vinylsiloxane or vinyl Ethoxysilane or phenyl tri-chlorination silane or butanol or amylalcohol or polyvinyl alcohol or n-octyl alcohol or straight chain lauryl alcohol or hexamethyl Disilazane etc..
7. a kind of application method of the glass tempering furnace modified for surface, it is characterised in that it the following steps are included:
1, it nitrogen charging: opens the first valve (6a), low-pressure nitrogen is passed through the second heating furnace (3), makes the second heating furnace nitrogen gas Atmosphere adjusts the aperture of the first valve (6a), the second heating nitrogen pressure in furnace is made to be maintained at 50 ~ 1000Pa;
2, it activates: the photovoltaic glass (10) after film being placed on the rollgang of upper piece platform (1), then open the first heating furnace Photovoltaic glass (10) are sent into the first heating furnace by rollgang by the first feeding furnace door (2a) close to upper piece platform (1) side (2) in, glass is heated to 300 ~ 450 DEG C, activates antireflective film surface hydroxyl sufficiently, while removing the moisture etc. of adsorption Impurity;
3, it is protected into furnace gas: opening the first discharging door (2b) and the second heating furnace (3) side of the first heating furnace (2) other side Photovoltaic glass (10) in first heating furnace (2) is then input to second by rollgang and added by the second feeding furnace door (3a) In hot stove, while the second feeding furnace door (3a) is opened, open the second valve (7a), so that high pressure nitrogen is quickly passed through second Heating furnace prevents air from entering to maintain positive pressure in furnace, after photovoltaic glass (10) enter the second heating furnace (3), closes second Feeding furnace door (3a) and the second valve (7a), to guarantee that the second heating furnace (3) nitrogen pressure is stablized;
4, modified: after photovoltaic glass (10) enters the second heating furnace, to open manifold valve (9a) and modifying agent is made to enter the first nitrogen Air inlet pipe (6), modifying agent is gasified by high-temperature low-pressure nitrogen, and is entrained into the second heating furnace of people (3), then modifying agent and anti-reflection Film surface hydroxyl chemically reacts, and achievees the purpose that reduce surface hydroxyl, opens exhaust valve (8a) and reaction end gas is discharged, work as glass Glass is heated to close to after softening temperature, closes manifold valve (9a) and exhaust valve (8a), and photovoltaic glass (10) preparation is come out of the stove;
5, go out furnace gas to protect;Second discharging door (3b) of the second heating furnace (3) other side is opened, and the photovoltaic glass (10) in furnace is logical It crosses in the air grid (4) for being transported into the second heating furnace (3) other side of rollgang, is opened at the second discharging door (3b) same When open the second valve (7a) so that high pressure nitrogen is quickly passed through the second heating furnace, to maintain positive pressure in furnace, prevent air into Enter, after photovoltaic glass (10) is transported out the second heating furnace (3) completely, closes the second discharging door (3b) and the second valve (7a), to guarantee that the second heating furnace (3) nitrogen pressure is stablized;
6, quenching: after photovoltaic glass (10) is transported into air grid (4) by rollgang, turn by rapid cooling, then by rollgang It transports into bottom sheet platform (5), to obtain the modified antireflective film photovoltaic glass in surface.
CN201811617501.9A 2018-12-28 2018-12-28 A kind of glass tempering furnace and its application method modified for surface Pending CN109437532A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110981210A (en) * 2019-12-25 2020-04-10 中建材蚌埠玻璃工业设计研究院有限公司 Photovoltaic glass anti-reflection strengthening continuous production device and method

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US20090104369A1 (en) * 2006-03-27 2009-04-23 Beneq Oy Method for producing functional glass surfaces by changing the composition of the original surface
CN201634569U (en) * 2010-02-01 2010-11-17 浙江鼎玻自动化设备有限公司 Glass tempering furnace with inert gas protection system
US20140072811A1 (en) * 2012-09-13 2014-03-13 Hiroyuki Watanabe Black synthetic quartz glass with transparent layer and method for producing the same
CN103833200A (en) * 2012-11-20 2014-06-04 虞建忠 Preparation method of high-strength fireproof glass
CN105948472A (en) * 2016-06-20 2016-09-21 河南环宇玻璃科技股份有限公司 Tempered glass processing technology
CN208104223U (en) * 2018-02-06 2018-11-16 广东索奥斯玻璃技术有限公司 A kind of novel tempered glass air curtain device
CN209352776U (en) * 2018-12-28 2019-09-06 中建材蚌埠玻璃工业设计研究院有限公司 A kind of glass tempering furnace modified for surface

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090104369A1 (en) * 2006-03-27 2009-04-23 Beneq Oy Method for producing functional glass surfaces by changing the composition of the original surface
CN201634569U (en) * 2010-02-01 2010-11-17 浙江鼎玻自动化设备有限公司 Glass tempering furnace with inert gas protection system
US20140072811A1 (en) * 2012-09-13 2014-03-13 Hiroyuki Watanabe Black synthetic quartz glass with transparent layer and method for producing the same
CN103833200A (en) * 2012-11-20 2014-06-04 虞建忠 Preparation method of high-strength fireproof glass
CN105948472A (en) * 2016-06-20 2016-09-21 河南环宇玻璃科技股份有限公司 Tempered glass processing technology
CN208104223U (en) * 2018-02-06 2018-11-16 广东索奥斯玻璃技术有限公司 A kind of novel tempered glass air curtain device
CN209352776U (en) * 2018-12-28 2019-09-06 中建材蚌埠玻璃工业设计研究院有限公司 A kind of glass tempering furnace modified for surface

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110981210A (en) * 2019-12-25 2020-04-10 中建材蚌埠玻璃工业设计研究院有限公司 Photovoltaic glass anti-reflection strengthening continuous production device and method

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Application publication date: 20190308