CN109370810A - A kind of heavy oil greasy dirt detergent and preparation method thereof - Google Patents
A kind of heavy oil greasy dirt detergent and preparation method thereof Download PDFInfo
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- CN109370810A CN109370810A CN201811419393.4A CN201811419393A CN109370810A CN 109370810 A CN109370810 A CN 109370810A CN 201811419393 A CN201811419393 A CN 201811419393A CN 109370810 A CN109370810 A CN 109370810A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
- C11D1/945—Mixtures with anionic, cationic or non-ionic compounds containing a combination of non-ionic compounds differently alcoxylised or with different alkylated chains
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/886—Ampholytes containing P
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Abstract
The present invention relates to the technical fields of greasy dirt detergent auxiliary equipment, more particularly to a kind of heavy oil greasy dirt detergent and preparation method thereof, a kind of heavy oil greasy dirt detergent of the invention, it is measured with 100 parts of weight, including 2-5 parts of potassium carbonate, 3-6 parts of sodium carbonate, 2-4 parts of potassium silicate, tetrapotassium pyrophosphate 3-6,10-30 parts of surfactant, 5-10 parts of solubilizer, 1-4 parts of sterilization antiseptic, 4-8 parts of lipase, deionized water: 27-70 parts, preparation method includes the following steps: (1) before prepared by mixed solution；(2) addition of surfactant；(3) addition of solubilizer；(4) addition of lipase and sterilization antiseptic.
Description
Technical field
The present invention relates to the technical field of greasy dirt detergent auxiliary equipment, more particularly to a kind of heavy oil greasy dirt detergent and
Preparation method.
Background technique
It is well known that heavy oil greasy dirt detergent and preparation method thereof is a kind of for removing automobile, machinery, electronics, metallurgy
With workpiece surface and the internal obstinate greasy dirt accumulated in various aspects process of manufacture such as building, with guarantee operation it is normal into
Row.
Heavy oil greasy dirt, which accumulates in workpiece surface, will affect the normal use of workpiece, and the heavy oil greasy dirt of working as that do not clear up for a long time accumulates
Position is transported in fuel oil transportation inner wall of the pipe and fuel nozzle etc., petroleum transported obstacle is easily caused, causes in fuel oil transportation pipeline
Local pressure increased dramatically, and workpiece part is chronically at high pressure conditions and transport pipeline explosion easily occurs, and cause equipment fault
It even paralyses, causes unnecessary loss, it is more serious to lead to safety accident, irremediable loss is left, thus it is periodically right
Equipment carry out heavy oil greasy dirt cleaning be very it is necessary to.
Early stage carries out the cleaning of heavy oil greasy dirt using organic solvent fuels such as gasoline, kerosene, but this method causes to provide
Source largely wastes, and sustainability and safety are poor.
In recent years, greasy dirt detergent mostly uses heavy oil greasy dirt preparation side of the surfactant in conjunction with alkali electroless reagent
Method, although the greasy dirt detergent that this method is prepared is higher to the removal rate of greasy dirt, common surfactant is adopted mostly
With chlorinated hydrocarbon and phosphorus containg substances, chlorinated hydrocarbon substance has certain toxicity, and safety in utilization is poor, and after cleaning agent cleaning
Wastewater treatment get up to be more troublesome, higher cost is poor using reasonability, and processing be not thorough, it is toxic containing chlorohydrocarbon etc.
The discharge of wastewater of substance easily causes water resource pollution into environment, generates threat to human body and environment, safety in utilization is poor；This
The alkaline matter that the greasy dirt detergent that method is prepared contains selects sodium hydroxide mostly, and sodium hydroxide has strong basicity,
Equally there is when degreasing to workpiece certain corrosiveness, cause workpiece surface damage, there is some potential safety problems, simultaneously
Workpiece service life is reduced, cost is caused to increase；The cleaning agent retention cycle that this method is prepared is shorter, needs in certain time
Interior use, it is poor using reasonability.
Summary of the invention
In order to solve the above technical problems, the present invention provides a kind of pollution for being free of chlorinated hydrocarbon substance, reducing to environment；No
Containing strong alkaline substance, the damage to workpiece is reduced, extends workpiece service life, reduces cost；Extend the holding time of cleaning agent,
It improves using rational heavy oil greasy dirt detergent and preparation method thereof.
A kind of heavy oil greasy dirt detergent of the invention, including following components:
It is measured with 100 parts of weight: 2-5 parts of potassium carbonate, 3-6 parts of sodium carbonate, 2-4 parts of potassium silicate, tetrapotassium pyrophosphate 3-6, table
Activating agent 10-30 parts of face, 5-10 parts of solubilizer, 1-4 parts of sterilization antiseptic, 4-8 parts of lipase, 27-70 parts of deionized water.
A kind of heavy oil greasy dirt detergent of the invention, it is preferred that potassium carbonate is 2 parts, and sodium carbonate is 3 parts, potassium silicate 2
Part, tetrapotassium pyrophosphate is 4 parts, and surfactant is 26 parts, and solubilizer is 8 parts, and sterilization antiseptic is 2 parts, and lipase is 5 parts,
Deionized water is 48 parts.
A kind of heavy oil greasy dirt detergent of the invention, it is preferred that surfactant is composed of the following components: detergent alkylate
10 parts of sodium sulfonate, 3 parts of lecithin, 5 parts of alkyl polyglucoside, 4 parts of cocoanut fatty acid diethanolamide, fatty acid sorbitan 4
Part.
A kind of heavy oil greasy dirt detergent of the invention, it is preferred that solubilizer is composed of the following components；Polyglyceryl fatty acid ester
5 parts, 3 parts of castor oil dimly of polyoxy.
A kind of heavy oil greasy dirt detergent of the invention, it is preferred that sterilization antiseptic is selected as Kathon CG.
A kind of heavy oil greasy dirt detergent preparation method of the invention, comprising the following steps:
(1) before prepared by mixed solution: by within the scope of temperature of reaction kettle adjusting again 20-30 DEG C, 48 parts of deionized waters being added
To reaction kettle, then by 2 parts of potassium carbonate, 3 parts of sodium carbonate, 2 parts of potassium silicate, 4 parts of tetrapotassium pyrophosphate are successively added to reaction kettle
It is interior, it stirs at 10-15 minutes.
(2) addition of surfactant: adjusting temperature of reaction kettle is 50-65 DEG C, by 10 parts of neopelex, ovum
Phosphatidase 3 part, 5 parts of alkyl polyglucoside, 4 parts of cocoanut fatty acid diethanolamide, 4 parts of fatty acid sorbitan are successively added to instead
It answers in kettle, in addition, reaction kettle is constantly in stirring, stirs 60-90 minutes.
(3) addition of solubilizer: maintaining temperature of reaction kettle within the scope of 50-65 DEG C, and 5 parts of polyglyceryl fatty acid ester are gathered
3 parts of castor oil dimly of oxygen are successively added in reaction kettle, and stirring 30 minutes spare.
(4) addition of lipase and sterilization antiseptic: temperature of reaction kettle is cooled within the scope of 30-40 DEG C, by lipase 5
Part is successively added in reaction kettle with 2 parts of sterilization antiseptic, and constant temperature stirs 10 minutes to get greasy dirt detergent mixed liquor is arrived.
A kind of heavy oil greasy dirt detergent preparation method of the invention, it is preferred that step (1) speed of agitator into (4)
It is 200rpm.
A kind of heavy oil greasy dirt detergent preparation method of the invention, it is preferred that the step (1) reacts kettle temperature into (3)
Degree control is within the scope of 55-60 DEG C.
Compared with prior art the invention has the benefit that when sodium dodecyl benzene sulfonate content is constant, with alkane
The raising of base polyglucoside content, oily waste degradation rate gradually rise, when alkyl polyglucoside content is constant, with dodecyl
The raising of benzene sulfonic acid sodium salt content, oily waste degradation rate equally increase, and when the alkyl polyglucoside of increase phase homogenous quantities, oily waste degradation
The raised amplitude of rate, which is higher than, increases phase homogenous quantities neopelex, illustrates that the ability of cleaning greasy dirt of alkyl polyglucoside is wanted
Higher than neopelex, but gradually rising with alkyl polyglucoside content, when alkyl polyglucoside content reaches
When to 6 parts, the raised amplitude reduction of oily waste degradation rate, in order to reduce cost, selecting alkyl polyglucoside is 5 parts, dodecyl
Benzene sulfonic acid sodium salt is 10 parts, is free of chlorinated hydrocarbon substance, reduces the pollution to environment, is free of strong alkaline substance, is reduced to workpiece
Damage extends workpiece service life, reduces cost, while extending the holding time of cleaning agent, improves and uses reasonability.
Specific embodiment
With reference to embodiment, the embodiment of the present invention is furthur described in detail.Following embodiment is used for
Illustrate the present invention, but is not intended to limit the scope of the invention.
Embodiment 1
Under the conditions of 20-30 DEG C, 48 parts of deionized waters are added in reaction kettle, then by 2 parts of potassium carbonate, sodium carbonate 3
Part, 2 parts of potassium silicate, 4 parts of tetrapotassium pyrophosphate are successively added in reaction kettle, and stirring was at 10-15 minutes under the conditions of 200rpm, when stirring
After mixing uniformly, temperature of reaction kettle is adjusted within the scope of 55-60 DEG C, and by 9 parts of neopelex, 3 parts of lecithin, alkyl is poly-
4 parts of glucoside, 4 parts of cocoanut fatty acid diethanolamide, 4 parts of fatty acid sorbitan are successively added in reaction kettle, are adding
When reaction kettle be constantly in stirring, stir 60-90 minutes under the conditions of 200rpm, after mixing evenly, keep temperature of reaction kettle
Under the conditions of 55-60 DEG C, by 5 parts of polyglyceryl fatty acid ester, 3 parts of castor oil dimly of polyoxy are successively added in reaction kettle,
It stirs 30 minutes under the conditions of 200rpm, after mixing evenly, temperature of reaction kettle is cooled within the scope of 30-40 DEG C, it then will be fatty
5 parts and 2 parts of sterilization antiseptic of enzyme are successively added in reaction kettle, are maintained within the scope of 30-40 DEG C, 10 are stirred under the conditions of 200rpm
Minute, solution after mixing is heavy oil greasy dirt detergent.
Embodiment 2
Under the conditions of 20-30 DEG C, 48 parts of deionized waters are added in reaction kettle, then by 2 parts of potassium carbonate, sodium carbonate 3
Part, 2 parts of potassium silicate, 4 parts of tetrapotassium pyrophosphate are successively added in reaction kettle, and stirring was at 10-15 minutes under the conditions of 200rpm, when stirring
After mixing uniformly, temperature of reaction kettle is adjusted within the scope of 55-60 DEG C, by 10 parts of neopelex, 3 parts of lecithin, alkyl
4 parts of polyglucoside, 4 parts of cocoanut fatty acid diethanolamide, 4 parts of fatty acid sorbitan are successively added in reaction kettle, are adding
Added-time reaction kettle is constantly in stirring, stirs 60-90 minutes under the conditions of 200rpm, after mixing evenly, keeps reaction kettle temperature
Under the conditions of 55-60 DEG C, by 5 parts of polyglyceryl fatty acid ester, 3 parts of castor oil dimly of polyoxy are successively added in reaction kettle degree,
It stirs 30 minutes under the conditions of 200rpm, after mixing evenly, temperature of reaction kettle is cooled within the scope of 30-40 DEG C, it then will be fatty
5 parts and 2 parts of sterilization antiseptic of enzyme are successively added in reaction kettle, are maintained within the scope of 30-40 DEG C, 10 are stirred under the conditions of 200rpm
Minute, solution after mixing is heavy oil greasy dirt detergent.
Embodiment 3
Under the conditions of 20-30 DEG C, 48 parts of deionized waters are added in reaction kettle, then by 2 parts of potassium carbonate, sodium carbonate 3
Part, 2 parts of potassium silicate, 4 parts of tetrapotassium pyrophosphate are successively added in reaction kettle, and stirring was at 10-15 minutes under the conditions of 200rpm, when stirring
After mixing uniformly, temperature of reaction kettle is adjusted within the scope of 55-60 DEG C, by 11 parts of neopelex, 3 parts of lecithin, alkyl
4 parts of polyglucoside, 4 parts of cocoanut fatty acid diethanolamide, 4 parts of fatty acid sorbitan are successively added in reaction kettle, are adding
Added-time reaction kettle is constantly in stirring, stirs 60-90 minutes under the conditions of 200rpm, after mixing evenly, keeps reaction kettle temperature
Under the conditions of 55-60 DEG C, by 5 parts of polyglyceryl fatty acid ester, 3 parts of castor oil dimly of polyoxy are successively added in reaction kettle degree,
It stirs 30 minutes under the conditions of 200rpm, after mixing evenly, temperature of reaction kettle is cooled within the scope of 30-40 DEG C, it then will be fatty
5 parts and 2 parts of sterilization antiseptic of enzyme are successively added in reaction kettle, are maintained within the scope of 30-40 DEG C, 10 are stirred under the conditions of 200rpm
Minute, solution after mixing is heavy oil greasy dirt detergent.
Embodiment 4
Under the conditions of 20-30 DEG C, 48 parts of deionized waters are added in reaction kettle, then by 2 parts of potassium carbonate, sodium carbonate 3
Part, 2 parts of potassium silicate, 4 parts of tetrapotassium pyrophosphate are successively added in reaction kettle, and stirring was at 10-15 minutes under the conditions of 200rpm, when stirring
After mixing uniformly, temperature of reaction kettle is adjusted within the scope of 55-60 DEG C, and by 9 parts of neopelex, 3 parts of lecithin, alkyl is poly-
5 parts of glucoside, 4 parts of cocoanut fatty acid diethanolamide, 4 parts of fatty acid sorbitan are successively added in reaction kettle, are adding
When reaction kettle be constantly in stirring, stir 60-90 minutes under the conditions of 200rpm, after mixing evenly, keep temperature of reaction kettle
Under the conditions of 55-60 DEG C, by 5 parts of polyglyceryl fatty acid ester, 3 parts of castor oil dimly of polyoxy are successively added in reaction kettle,
It stirs 30 minutes under the conditions of 200rpm, after mixing evenly, temperature of reaction kettle is cooled within the scope of 30-40 DEG C, it then will be fatty
5 parts and 2 parts of sterilization antiseptic of enzyme are successively added in reaction kettle, are maintained within the scope of 30-40 DEG C, 10 are stirred under the conditions of 200rpm
Minute, solution after mixing is heavy oil greasy dirt detergent.
Embodiment 5
Under the conditions of 20-30 DEG C, 48 parts of deionized waters are added in reaction kettle, then by 2 parts of potassium carbonate, sodium carbonate 3
Part, 2 parts of potassium silicate, 4 parts of tetrapotassium pyrophosphate are successively added in reaction kettle, and stirring was at 10-15 minutes under the conditions of 200rpm, when stirring
After mixing uniformly, temperature of reaction kettle is adjusted within the scope of 55-60 DEG C, by 10 parts of neopelex, 3 parts of lecithin, alkyl
5 parts of polyglucoside, 4 parts of cocoanut fatty acid diethanolamide, 4 parts of fatty acid sorbitan are successively added in reaction kettle, are adding
Added-time reaction kettle is constantly in stirring, stirs 60-90 minutes under the conditions of 200rpm, after mixing evenly, keeps reaction kettle temperature
Under the conditions of 55-60 DEG C, by 5 parts of polyglyceryl fatty acid ester, 3 parts of castor oil dimly of polyoxy are successively added in reaction kettle degree,
It stirs 30 minutes under the conditions of 200rpm, after mixing evenly, temperature of reaction kettle is cooled within the scope of 30-40 DEG C, it then will be fatty
5 parts and 2 parts of sterilization antiseptic of enzyme are successively added in reaction kettle, are maintained within the scope of 30-40 DEG C, 10 are stirred under the conditions of 200rpm
Minute, solution after mixing is heavy oil greasy dirt detergent.
Embodiment 6
Under the conditions of 20-30 DEG C, 48 parts of deionized waters are added in reaction kettle, then by 2 parts of potassium carbonate, sodium carbonate 3
Part, 2 parts of potassium silicate, 4 parts of tetrapotassium pyrophosphate are successively added in reaction kettle, and stirring was at 10-15 minutes under the conditions of 200rpm, when stirring
After mixing uniformly, temperature of reaction kettle is adjusted within the scope of 55-60 DEG C, by 11 parts of neopelex, 3 parts of lecithin, alkyl
5 parts of polyglucoside, 4 parts of cocoanut fatty acid diethanolamide, 4 parts of fatty acid sorbitan are successively added in reaction kettle, are adding
Added-time reaction kettle is constantly in stirring, stirs 60-90 minutes under the conditions of 200rpm, after mixing evenly, keeps reaction kettle temperature
Under the conditions of 55-60 DEG C, by 5 parts of polyglyceryl fatty acid ester, 3 parts of castor oil dimly of polyoxy are successively added in reaction kettle degree,
It stirs 30 minutes under the conditions of 200rpm, after mixing evenly, temperature of reaction kettle is cooled within the scope of 30-40 DEG C, it then will be fatty
5 parts and 2 parts of sterilization antiseptic of enzyme are successively added in reaction kettle, are maintained within the scope of 30-40 DEG C, 10 are stirred under the conditions of 200rpm
Minute, solution after mixing is heavy oil greasy dirt detergent.
Embodiment 7
Under the conditions of 20-30 DEG C, 48 parts of deionized waters are added in reaction kettle, then by 2 parts of potassium carbonate, sodium carbonate 3
Part, 2 parts of potassium silicate, 4 parts of tetrapotassium pyrophosphate are successively added in reaction kettle, and stirring was at 10-15 minutes under the conditions of 200rpm, when stirring
After mixing uniformly, temperature of reaction kettle is adjusted within the scope of 55-60 DEG C, and by 9 parts of neopelex, 3 parts of lecithin, alkyl is poly-
6 parts of glucoside, 4 parts of cocoanut fatty acid diethanolamide, 4 parts of fatty acid sorbitan are successively added in reaction kettle, are adding
When reaction kettle be constantly in stirring, stir 60-90 minutes under the conditions of 200rpm, after mixing evenly, keep temperature of reaction kettle
Under the conditions of 55-60 DEG C, by 5 parts of polyglyceryl fatty acid ester, 3 parts of castor oil dimly of polyoxy are successively added in reaction kettle,
It stirs 30 minutes under the conditions of 200rpm, after mixing evenly, temperature of reaction kettle is cooled within the scope of 30-40 DEG C, it then will be fatty
5 parts and 2 parts of sterilization antiseptic of enzyme are successively added in reaction kettle, are maintained within the scope of 30-40 DEG C, 10 are stirred under the conditions of 200rpm
Minute, solution after mixing is heavy oil greasy dirt detergent.
Embodiment 8
Under the conditions of 20-30 DEG C, 48 parts of deionized waters are added in reaction kettle, then by 2 parts of potassium carbonate, sodium carbonate 3
Part, 2 parts of potassium silicate, 4 parts of tetrapotassium pyrophosphate are successively added in reaction kettle, and stirring was at 10-15 minutes under the conditions of 200rpm, when stirring
After mixing uniformly, temperature of reaction kettle is adjusted within the scope of 55-60 DEG C, by 10 parts of neopelex, 3 parts of lecithin, alkyl
6 parts of polyglucoside, 4 parts of cocoanut fatty acid diethanolamide, 4 parts of fatty acid sorbitan are successively added in reaction kettle, are adding
Added-time reaction kettle is constantly in stirring, stirs 60-90 minutes under the conditions of 200rpm, after mixing evenly, keeps reaction kettle temperature
Under the conditions of 55-60 DEG C, by 5 parts of polyglyceryl fatty acid ester, 3 parts of castor oil dimly of polyoxy are successively added in reaction kettle degree,
It stirs 30 minutes under the conditions of 200rpm, after mixing evenly, temperature of reaction kettle is cooled within the scope of 30-40 DEG C, it then will be fatty
5 parts and 2 parts of sterilization antiseptic of enzyme are successively added in reaction kettle, are maintained within the scope of 30-40 DEG C, 10 are stirred under the conditions of 200rpm
Minute, solution after mixing is heavy oil greasy dirt detergent.
Embodiment 9
Under the conditions of 20-30 DEG C, 48 parts of deionized waters are added in reaction kettle, then by 2 parts of potassium carbonate, sodium carbonate 3
Part, 2 parts of potassium silicate, 4 parts of tetrapotassium pyrophosphate are successively added in reaction kettle, and stirring was at 10-15 minutes under the conditions of 200rpm, when stirring
After mixing uniformly, temperature of reaction kettle is adjusted within the scope of 55-60 DEG C, by 11 parts of neopelex, 3 parts of lecithin, alkyl
6 parts of polyglucoside, 4 parts of cocoanut fatty acid diethanolamide, 4 parts of fatty acid sorbitan are successively added in reaction kettle, are adding
Added-time reaction kettle is constantly in stirring, stirs 60-90 minutes under the conditions of 200rpm, after mixing evenly, keeps reaction kettle temperature
Under the conditions of 55-60 DEG C, by 5 parts of polyglyceryl fatty acid ester, 3 parts of castor oil dimly of polyoxy are successively added in reaction kettle degree,
It stirs 30 minutes under the conditions of 200rpm, after mixing evenly, temperature of reaction kettle is cooled within the scope of 30-40 DEG C, it then will be fatty
5 parts and 2 parts of sterilization antiseptic of enzyme are successively added in reaction kettle, are maintained within the scope of 30-40 DEG C, 10 are stirred under the conditions of 200rpm
Minute, solution after mixing is heavy oil greasy dirt detergent
Heavy oil greasy dirt detergent and the organo-silicic oil made from the prior art being prepared through the foregoing embodiment are shown in
Following table.
It can be seen that by upper table when sodium dodecyl benzene sulfonate content is constant, with alkyl polyglucoside content
It increases, oily waste degradation rate gradually rises, when alkyl polyglucoside content is constant, with the liter of sodium dodecyl benzene sulfonate content
Height, oily waste degradation rate equally increase, and when the alkyl polyglucoside of increase phase homogenous quantities, the raised amplitude of oily waste degradation rate wants high
In increasing phase homogenous quantities neopelex, illustrate that the ability of cleaning greasy dirt of alkyl polyglucoside is higher than detergent alkylate sulphur
Sour sodium, but gradually rising with alkyl polyglucoside content, when alkyl polyglucoside content reaches 6 parts, oily waste degradation
The raised amplitude reduction of rate, in order to reduce cost, selecting alkyl polyglucoside is 5 parts, and neopelex is 10 parts.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, without departing from the technical principles of the invention, several improvements and modifications, these improvements and modifications can also be made
Also it should be regarded as protection scope of the present invention.
Claims (8)
1. a kind of heavy oil greasy dirt detergent, which is characterized in that including following components:
Measured with 100 parts of weight: 2-5 parts of potassium carbonate, 3-6 parts of sodium carbonate, 2-4 parts of potassium silicate, tetrapotassium pyrophosphate 3-6, surface is living
10-30 parts of agent, 5-10 parts of solubilizer, 1-4 parts of sterilization antiseptic, 4-8 parts of lipase, 27-70 parts of deionized water of property.
2. a kind of heavy oil greasy dirt detergent as described in claim 1, which is characterized in that preferred, potassium carbonate is 2 parts, carbonic acid
Sodium is 3 parts, and potassium silicate is 2 parts, and tetrapotassium pyrophosphate is 4 parts, and surfactant is 26 parts, and solubilizer is 8 parts, and sterilization antiseptic is
2 parts, lipase is 5 parts, and deionized water is 48 parts.
3. a kind of heavy oil greasy dirt detergent as claimed in claim 2, which is characterized in that preferred, surfactant is by following
Group is grouped as: 10 parts of neopelex, 3 parts of lecithin, and 5 parts of alkyl polyglucoside, coco-nut oil fatty acid diethanol acyl
4 parts of amine, 4 parts of fatty acid sorbitan.
4. a kind of heavy oil greasy dirt detergent as claimed in claim 3, which is characterized in that preferred, solubilizer is by following components
Composition；5 parts of polyglyceryl fatty acid ester, 3 parts of castor oil dimly of polyoxy.
5. a kind of heavy oil greasy dirt detergent as claimed in claim 4, which is characterized in that preferred, sterilization antiseptic is selected as card
Pine.
6. a kind of heavy oil greasy dirt detergent preparation method, comprising the following steps:
(1) before prepared by mixed solution: by within the scope of temperature of reaction kettle adjusting again 20-30 DEG C, 48 parts of deionized waters being added to instead
It answers in kettle, then by 2 parts of potassium carbonate, 3 parts of sodium carbonate, 2 parts of potassium silicate, 4 parts of tetrapotassium pyrophosphate are successively added in reaction kettle, are stirred
It mixes at 10-15 minutes.
(2) addition of surfactant: adjusting temperature of reaction kettle is 50-65 DEG C, by 10 parts of neopelex, lecithin
3 parts, 5 parts of alkyl polyglucoside, 4 parts of cocoanut fatty acid diethanolamide, 4 parts of fatty acid sorbitan are successively added to reaction kettle
Interior, in addition, reaction kettle is constantly in stirring, stirs 60-90 minutes.
(3) addition of solubilizer: maintaining temperature of reaction kettle within the scope of 50-65 DEG C, by 5 parts of polyglyceryl fatty acid ester, polyoxy according to
3 parts of dilute castor oil is successively added in reaction kettle, and stirring 30 minutes spare.
(4) addition of lipase and sterilization antiseptic: temperature of reaction kettle is cooled within the scope of 30-40 DEG C, by 5 parts of lipase and
2 parts of sterilization antiseptic are successively added in reaction kettle, and constant temperature stirs 10 minutes to get greasy dirt detergent mixed liquor is arrived.
7. a kind of heavy oil greasy dirt detergent preparation method as claimed in claim 6, which is characterized in that preferred, the step
(1) into (4), speed of agitator is 200rpm.
8. a kind of heavy oil greasy dirt detergent preparation method as claimed in claim 7, which is characterized in that preferred, the step
(1) into (3), temperature of reaction kettle is controlled within the scope of 55-60 DEG C.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811419393.4A CN109370810A (en) | 2018-11-26 | 2018-11-26 | A kind of heavy oil greasy dirt detergent and preparation method thereof |
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| CN201811419393.4A CN109370810A (en) | 2018-11-26 | 2018-11-26 | A kind of heavy oil greasy dirt detergent and preparation method thereof |
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Citations (3)
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|---|---|---|---|---|
| CN103710161A (en) * | 2013-12-31 | 2014-04-09 | 上海交通大学 | Cleaning agent for removing heavy dirt and greasy dirt |
| CN104893833A (en) * | 2015-05-25 | 2015-09-09 | 时修官 | Industrial heavy oil contamination cleaning agent |
| CN106833937A (en) * | 2015-12-04 | 2017-06-13 | 深圳市芭格美生物科技有限公司 | Kitchen heavy oil biology enzyme cleaning fluid and preparation method thereof |
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2018
- 2018-11-26 CN CN201811419393.4A patent/CN109370810A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103710161A (en) * | 2013-12-31 | 2014-04-09 | 上海交通大学 | Cleaning agent for removing heavy dirt and greasy dirt |
| CN104893833A (en) * | 2015-05-25 | 2015-09-09 | 时修官 | Industrial heavy oil contamination cleaning agent |
| CN106833937A (en) * | 2015-12-04 | 2017-06-13 | 深圳市芭格美生物科技有限公司 | Kitchen heavy oil biology enzyme cleaning fluid and preparation method thereof |
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| 徐宝财 编: "《洗涤剂概论》", 31 October 2000, 化学工业出版社 * |
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