CN109370795B - 涤/氨及锦/氨混纺针织面料连续加工用除油剂及其制备方法 - Google Patents

涤/氨及锦/氨混纺针织面料连续加工用除油剂及其制备方法 Download PDF

Info

Publication number
CN109370795B
CN109370795B CN201811520271.4A CN201811520271A CN109370795B CN 109370795 B CN109370795 B CN 109370795B CN 201811520271 A CN201811520271 A CN 201811520271A CN 109370795 B CN109370795 B CN 109370795B
Authority
CN
China
Prior art keywords
ammonia
agent
nylon
polyester
oil removing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201811520271.4A
Other languages
English (en)
Other versions
CN109370795A (zh
Inventor
杨伟
李正雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TAICANG BAONI INDUSTRIAL Co.,Ltd.
Original Assignee
Taicang Baoni Industrial Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Taicang Baoni Industrial Co ltd filed Critical Taicang Baoni Industrial Co ltd
Priority to CN201811520271.4A priority Critical patent/CN109370795B/zh
Publication of CN109370795A publication Critical patent/CN109370795A/zh
Application granted granted Critical
Publication of CN109370795B publication Critical patent/CN109370795B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/201—Monohydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/2034—Monohydric alcohols aromatic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/364—Organic compounds containing phosphorus containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/332—Di- or polyamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/44—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing nitrogen and phosphorus
    • D06M13/453—Phosphates or phosphites containing nitrogen atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008—Polymeric surface-active agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/12—Soft surfaces, e.g. textile
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/38—Polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/01—Stain or soil resistance

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

本发明提供了一种涤/氨及锦/氨混纺针织面料连续加工用除油剂及其制备方法。该除油剂包括50‑70重量％聚氧化烯型非离子表面活性剂、2‑15重量％螯合剂、1‑5重量％氟碳表面活性剂、0.2‑3重量％有机氟整理剂、1‑10重量％有机溶剂和15‑35重量％水，以涤/氨及锦/氨混纺针织面料连续加工用除油剂的总重量为基准。本发明除油剂具有良好的油去除性，乳化分散性，防反沾性和快速渗透性，解决涤/氨或锦/氨混纺针织面料连续前处理过程中，由于油去除不良引起的各种染整加工问题。

Description

涤/氨及锦/氨混纺针织面料连续加工用除油剂及其制备方法
技术领域
本发明涉及纺织印染平幅连续加工用除油剂及其制备方法，特别涉及涤/氨及锦/氨混纺针织面料连续加工用除油剂及其制备方法。
背景技术
氨纶纤维由于其出色的服用性，在化纤混纺面料中的应用不断的扩大，而且氨纶的含量不断提升，由最初的2-5％提升到30-50％不等。这类面料在织造过程中，除了要添加各类矿物油，针织油等纺织油剂外，氨纶本身还含有大量有机硅类的润滑剂。这些油剂的存在，在进行染色加工处理前必须去除，否则会导致各种染色色斑，色花等染色问题。
平幅连续前处理相对于间歇式绳状加工，能显著提高加工品质：减少擦伤，皱印，不易起毛，织物表面更洁净；同时生产效率更高，能耗能减少一半左右。因而，平幅连续加工已经成为行业的发展趋势。但是，连续除油水洗相对于缸内除油而言，存在布液接触时间短，除油不易充分，同时由于杂质的不断积累，处理后期容易反沾，造成头尾差，品质不均一的问题。
目前市场上常用的去油剂大部分是基于氨纶含量低，绳状缸内加工工艺的基础上开发的，不能完全适合平幅连续除油的需求。首先，矿物油，针织油等纺织油剂的表面张力一般30mN/m左右，氨纶纺丝用的有机硅类润滑剂的表面张力一般在20mN/m左右；传统用去油表面张力一般低于30mN/m，不能满足对氨纶丝的除油要求。再次，缸内除油不存在油剂不断积累的问题，连续处理随着时间的推移，油剂不断增多，反沾问题严重，要求除油剂有更强的乳化分散能力；最后，平幅连续加工布液接触时间短，要求去油剂渗透力更好，除油效率更高。
本领域中迫切需要一种去油剂，它不仅可以满足高含量氨纶混纺织物的去油要求，同时满足平幅连续前处理的高渗透性，高乳化分散力的要求，满足市场行业的发展需求；同时不含有APEO，NPEO，等非环保类成分。
发明内容
本发明解决了现用传统去油剂，在平幅连续前处理工艺中，存在的渗透性不足，乳化分散力不够，纺织用硅油油剂去除力不够引起的各种前处理问题，满足后期染整加工要求，达到提高效率，节能减排的目的。
本发明的一方面提供了一种涤/氨及锦/氨混纺针织面料连续加工用除油剂，它包括如下组分：
Figure BDA0001903055270000021
以涤/氨及锦/氨混纺针织面料连续加工用除油剂的总重量为基准。
本发明的另一方面提供了上述涤/氨及锦/氨混纺针织面料连续加工用除油剂的制备方法，它包括如下步骤：
a)将聚氧化烯型非离子表面活性剂、螯合剂、氟碳表面活性剂、有机氟整理剂、有机溶剂和水在50－100℃的温度和在50－100r/min的速度下搅拌均匀，和
b)降温出料。
本发明的另一个方面提供了一种除油剂在涤/氨或锦/氨混纺针织面料在中性或碱性条件下平幅连续除油工艺上的应用。
本发明具有良好的油去除力，防沾污性，加工稳定性，不含有APEO，NPEO等非环保类成分。
具体实施方式
在一个优选的实施方式中，本发明的涤/氨及锦/氨混纺针织面料连续加工用除油剂它包括如下组分：
Figure BDA0001903055270000031
以涤/氨及锦/氨混纺针织面料连续加工用除油剂的总重量为基准。
在一个优选的实施方式中，所述的聚氧化烯型非离子表面活性剂例如包括脂肪醇聚氧乙烯聚氧丙烯型非离子表面活性剂、酚类聚氧乙烯型非离子表面活性剂、或它们的混合物。
在一个特别优选的实施方式中，脂肪醇聚氧乙烯聚氧丙烯型非离子表面活性剂例如可用如下通式表示：
R6-O-(EO)x'-(PO)y'-H (I)
其中R6为C10～20烷基，优选C12～18烷基；所述EO结构单元的个数x'＝1～20，优选为5～12，PO结构单元个数y'＝0～8，优选为1－5。
在一个特别优选的实施方式中，酚类聚氧乙烯型非离子表面活性剂例如是可用如下通式表示的烷基酚类聚氧乙烯型非离子表面活性剂：
Figure BDA0001903055270000032
式中，-R7为C10～20直链或支链烷基，优选为C12～18直链或支链烷基；m'＝1－20，优选为5-15。
在一个特别优选的实施方式中，所述脂肪醇聚氧乙烯聚氧丙烯型非离子表面活性剂与酚类聚氧乙烯聚氧丙烯型非离子表面活性剂的重量比为30－70：30－70，优选为35－65：35－65。
在一个优选的实施方式中，所述的螯合剂例如包括多羧酸盐型螯合剂、多磷酸盐型螯合剂、羟基羧酸盐型螯合剂、羟基磷酸盐型螯合剂、或它们的混合物。
在一个更优选的实施方式中，所述的螯合剂例如包括马来酸-丙烯酸聚合物、乙二胺四乙酸(EDTA)、二乙基三胺五乙酸(DTPA)、羟基乙叉二磷酸(HEDP)、二乙烯三胺五甲叉磷酸(DTPMPA)中的一种或多种。
在一个特别优选的实施方式中，马来酸-丙烯酸聚合物的分子量例如为3000－15000，优选为5000-12000。
在一个优选的实施方式中，所述的氟碳表面活性剂包括非离子型氟碳表面活性剂、两性离子型氟碳表面活性剂、阴离子型氟碳表面活性剂、或它们的混合物。
在一个更优选的实施方式，所述的非离子型氟碳表面活性例如可用如下通式表示：
Rf1CH2CH2O(CH2CH2O)n'H, (III)
式中Rf1＝F(CF2CF2)p1，n'＝0～50,优选为10-35,p1＝1～9,优选为1～5。
在一个更加优选的实施方式，所述的两性离子型氟碳表面活性剂可用如下通式表示：
Rf2CH2CH2O(CH2CH2O)sN+(CH3)3CH2SO3-M (IV)
式中，Rf2＝F(CF2CF2)p2其中s＝0～10,优选为1-5,p2＝1～9,优选为1～5,M为钠、钾或铵离子。，
在一个更加优选的实施方式，所述的阴离子型氟碳表面活性剂可用如下通式表示：
Rf3COO-M (V)
式中，Rf3＝F(CF2CF2)p3其中p3＝1～9,优选为1～5,M为钠、钾或铵离子。
在一个优选的实施方式中，所述的有机氟整理剂是易去污功能的有机氟整理剂。
在一个更优选的实施方式中，所述易去污功能的含氟聚合物包含用下式表示的结构单元：
Figure BDA0001903055270000051
其中：Rf＝CnF2n+1(n＝6-12),X＝-(CH2)tNHSO2-(t＝2-4)、-CH2CH2NOH-、-(CH2)m-(m＝1-10)、或-CH2CHOHCH2-；R3、R4、R5为H、-CH2CH3、或-CH3；R1＝CrH2r+1(r＝8-18)、-(CH2CH2O)WH(w＝1-18)；Y＝H或Cl；R2＝-CH2OH、-C(CH3)2CH2COCH3；a＝1-10000,b＝1-10000,c＝1-10000,d＝1-10000。
在一个更加优选的实施方式，所述含氟聚合物为TG-9131(大金氟化工),TG-9011(大金氟化工)，Nuva N4118(昂高化工),Nuva N4547(昂高化工),AG-E100(旭硝子化学)中的任意一种或两种以上的组合。
在一个优选的实施方式，所述的有机溶剂例如包括有机醇、有机醚或它们的混合物，例如可以为本行业中常用的醇或醚，特别是可与水任意混溶的醇或醚，例如，甲醇，乙醇、异丙醇，二乙二醇单丁醚，苯甲醇中任意一种或两种以上的组合。
在一个优选的实施方式，本发明中所用的水可以为本行业中所用的任何洁净的水，如去离子水。
本发明的另一个方面提供了一种涤/氨及锦/氨混纺针织面料连续加工用除油剂的制备方法，它包括：
将聚氧化烯型非离子表面活性剂、螯合剂、氟碳表面活性剂、有机氟整理剂、有机溶剂和水在50－100℃的温度和在50－100r/min的速度搅拌0.5-3小时，降温至40℃以下，出料。
本发明的除油剂可在涤/氨或锦/氨混纺针织面料在中性或碱性条件下平幅连续除油工艺上的应用。
本发明适用于涤纶/氨纶混纺，锦纶/氨纶混纺面料，素材形态方面，可用于针织布。
本发明的涤/氨及锦/氨混纺针织面料连续加工用除油剂的使用量可根据纤维素材，以及目标性能等适宜调整。
本发明具有良好的油去除力，防沾污性，加工稳定性，不含有APEO，NPEO等非环保类成分。
实施例
下面结合具体实施例的性能对比，进一步阐述本发明。
如下各实施例中的性能测试指标通过如下方法测定：
1，去油性评价
1)油污布制作：
织物：涤纶氨纶去油针织布(预先用氯仿萃取干净)
Figure BDA0001903055270000061
上油工艺：两浸两轧油污溶液(3kgf)→室温晾干。
织物：锦纶氨纶针织去油布(预先用氯仿萃取干净)
Figure BDA0001903055270000062
上油工艺：两浸两轧油污溶液(3kgf)→室温晾干。
评价标准：
2)去油率测定
仪器：纤维油脂快速抽取器
溶剂：***
操作工艺：精确称取2g左右的测试布和铝盘的重量(精确至0.0001g)，将布样装入抽取器的钢筒中，并用压杆压紧，油剂烘干温度设定为120℃，温度到达后，在钢筒下方放置称量过的干净铝盘，往钢筒中加入10ml***，堵住出口，保持1min，放开出口，待溶剂滴完后，再加入10ml***，同样保持1min，待溶剂滴完后，恒重铝箔盘，计算萃取得到的油剂量，计算织物含油率，每块布样测二个值，取平均值，计算去油率。
Figure BDA0001903055270000071
去油率(％)＝处理前油污布含油率(％)-处理后油污布含油率(％)
3)除油操作方法
去油工艺过程：精练槽(90℃*3min)→精练槽(90℃*3min)→水洗槽(90℃*3min)→水洗槽(70℃*3min)→水洗槽(40℃*3min)→脱水→烘干
将0.5g实施例和对比例(还需一组不加除油剂的空白样)分别加入100ml精练槽，待各槽温度升至设定温度后，加入待处理油污布10g，按照设定工艺时间，依次通过各槽，完成前处理工艺流程。
4)评判标准：
去油率越高，去油性能越好。
2，乳化分散力评价
油和染料的混合液制备：
将矿物油40g，针织油20g，机油5g,二甲基硅油35g,油溶红0.02g，混合后，搅拌均匀。
评价方法：将0.2g的实施例和对比列(还需一组不加除油剂的空白样)分别加入250ml烧瓶中，配制成100ml溶液，然后向溶液中滴加油和染料的混合液0.03g.配置好的溶液放置在恒温震荡染色机(震荡频率900rpm)，按照3℃/分的速度升温至90℃，该温度下保持30分钟；结束后取出，降至室温后，采用4A滤纸过滤。
评价标准：
滤纸颜色越浅，乳化分散效果越好。
3，渗透力评价
将2g的实施例和对比列(还需一组不加除油剂的空白样)分别加入1000ml的水溶液中，采用3*3cm的涤氨坯布进行沉降实验，将待测液放置在1L量筒中(内径约为70mm)，记录涤氨坯布的从放入液面到下沉至量筒底部的时间t作为助剂的渗透时间。
评价标准：
渗透时间越短，渗透力越好。
实施例1
将30重量份的脂肪醇聚氧乙烯聚氧丙烯型非离子表面活性剂(式I中，脂肪醇的C数为13，其中EO数为9，PO数为1),30重量份的烷基酚聚氧乙烯型非离子表面活性剂(式II中，R7为-C15H25，其中EO数为10)，5重量份的马来酸-丙烯酸聚合物(聚合度1万)，2重量份的非离子氟碳表面活性剂(式III中，Rf1＝F(CF2CF2)3其中n'＝30)，1重量份的易去污整理剂TG-9131(大金氟化工)和3重量份的异丙醇以及29重量份的去离子水，然后升温至90－100℃，在60－70r/min速度搅拌2小时，搅拌均匀后，降温至40℃以下，出料，制得产品。
实施例2
将40重量份的脂肪醇聚氧乙烯聚氧丙烯型非离子表面活性剂(式I中，脂肪醇的C数为12，其中EO数为6，PO数为1),25重量份的烷基酚聚氧乙烯型非离子表面活性剂(式II中，R7为-C15H27，其中EO数为5)，5重量份的二乙基三胺五乙酸，3重量份的非离子氟碳表面活性剂(式III中，Rf1＝F(CF2CF2)3其中n'＝15)，和0.5重量份的易去污整理剂Nuva N4118(昂高化工),2重量份的异丙醇，4重量份的二乙二醇单丁醚，以及20.5重量份的去离子水，然后升温至70－80℃，在60－70r/min速度搅拌1-2小时，搅拌均匀后，降温至40℃以下，出料，制得产品。
实施例3
将25重量份的脂肪醇聚氧乙烯聚氧丙烯型非离子表面活性剂(式I中，脂肪醇的C数为18，其中EO数为9，PO数为3),35重量份的烷基酚聚氧乙烯型非离子表面活性剂(式II中，R7为-C15H29，其中EO数为10)，2重量份的马来酸-聚丙烯酸聚合物(聚合度8000)，4重量份羟基乙叉二磷酸，3重量份的两性离子型氟碳表面活性剂(式IV中，Rf2＝F(CF2CF2)4,其中s＝1)，和2重量份的易去污整理剂AG-E100(旭硝子化学),4重量份的苯丙醇，1重量份的甲醇，以及24重量份的去离子水，然后升温至90－100℃，在70－80r/min速度搅拌2-3小时，搅拌均匀后，降温至40℃以下，出料，制得产品。
实施例4
将30重量份的脂肪醇聚氧乙烯聚氧丙烯型非离子表面活性剂(式I中，脂肪醇的C数为13，其中EO数为8，PO数为2),28重量份的烷基酚聚氧乙烯聚氧丙烯型非离子表面活性剂(式II中，R7为-C15H31，其中EO数为6)，12重量份二乙烯三胺五甲叉磷酸，1重量份的阴离子型氟碳表面活性剂(式V中，Rf3＝F(CF2CF2)3,M＝Na+)和2重量份非离子氟碳表面活性剂(式III中，Rf1＝F(CF2CF2)3,其中n'＝15),1重量份的易去污整理剂TG-9011(大金氟化工)，5重量份的二乙二醇单丁醚，以及21重量份的去离子水，然后升温至80－90℃，在70－90r/min速度搅拌2-3小时，搅拌均匀后，降温至40℃以下，出料，制得产品。
对比例
国产品T:去油剂TF-115D(浙江传化化工)
国产品D:专利公开号CN106978727A实施例三(40重量份的脂肪醇聚氧乙烯醚AEO-7和30重量份的异构十三醇聚氧乙烯醚1307,10重量份的甲醇，20重量份的水)
进口品L:去油剂LYS(科莱恩化工)
应用效果表1
Figure BDA0001903055270000101
应用效果附表2
乳化分散性过滤 渗透性
外观 时间(s)
实施例1 颜色浅，残留物少 5s
实施例2 颜色浅，残留物少 4s
实施例3 颜色浅，残留物少 4s
实施例4 颜色浅，残留物少 7s
国产品T 颜色深，残留物多 50s
国产品D 颜色稍深，残留物稍多 20s
进口品L 颜色浅，残留物稍少 15s
空白 颜色深，残留多 ＞180s
由以上数据可知，本发明各实施例的连续去油性均优于市场对比例，不仅适用于低氨纶含量的混纺面料，对高氨纶含量的混纺面料也具有极佳的去油效果；各实施例的油的乳化分散性均好于市场对比例，可以极大提升布面的防沾污性，同时渗透性相对于市场对比例也有明显的优势，满足长车连续处理的速度要求，提高生产效率。

Claims (10)

1.一种涤/氨及锦/氨混纺针织面料连续加工用除油剂，它由如下组分组成：
Figure FDA0002545217220000011
以涤/氨及锦/氨混纺针织面料连续加工用除油剂的总重量为基准。
2.如权利要求1所述的涤/氨及锦/氨混纺针织面料连续加工用除油剂，其特征在于，它由如下组分组成：
Figure FDA0002545217220000012
以涤/氨及锦/氨混纺针织面料连续加工用除油剂的总重量为基准。
3.如权利要求1或2所述的涤/氨及锦/氨混纺针织面料连续加工用除油剂，其特征在于，所述的聚氧化烯型非离子表面活性剂是脂肪醇聚氧乙烯聚氧丙烯型非离子表面活性剂、酚类聚氧乙烯型非离子表面活性剂、或它们的混合物。
4.如权利要求1或2所述的涤/氨及锦/氨混纺针织面料连续加工用除油剂，其特征在于，所述的螯合剂包括多羧酸盐型螯合剂、多磷酸盐型螯合剂、羟基羧酸盐型螯合剂、羟基磷酸盐型螯合剂、或它们的混合物。
5.如权利要求1或2所述的涤/氨及锦/氨混纺针织面料连续加工用除油剂，其特征在于，所述的螯合剂包括马来酸-丙烯酸聚合物、乙二胺四乙酸(EDTA)、二乙基三胺五乙酸(DTPA)、羟基乙叉二磷酸(HEDP)、二乙烯三胺五甲叉磷酸(DTPMPA)中的一种或多种。
6.如权利要求1或2所述的涤/氨及锦/氨混纺针织面料连续加工用除油剂，其特征在于，所述的氟碳表面活性剂包括非离子型氟碳表面活性剂、两性离子型氟碳表面活性剂、阴离子型氟碳表面活性剂、或它们的混合物。
7.如权利要求1或2所述的涤/氨及锦/氨混纺针织面料连续加工用除油剂，其特征在于，所述的有机氟整理剂是易去污功能的有机氟整理剂。
8.如权利要求7所述的涤/氨及锦/氨混纺针织面料连续加工用除油剂，其特征在于，所述易去污功能的含氟聚合物包含用下式表示的结构单元：
Figure FDA0002545217220000021
其中：Rf＝CnF2n+1(n＝6-12),X＝-(CH2)tNHSO2-(t＝2-4)、-CH2CH2NOH-、-(CH2)m-(m＝1-10)、或-CH2CHOHCH2-；R3、R4、R5为H、-CH2CH3、或-CH3；R1＝CrH2r+1(r＝8-18)、-(CH2CH2O)WH(w＝1-18)；Y＝H或Cl；R2＝-CH2OH、-C(CH3)2CH2COCH3；a＝1-10000,b＝1-10000,c＝1-10000,d＝1-10000。
9.如权利要求1或2所述的涤/氨及锦/氨混纺针织面料连续加工用除油剂，其特征在于，所述的有机溶剂包括有机醇、有机醚或它们的混合物；所述的水包括去离子水。
10.如权利要求1－9中任一项所述的涤/氨及锦/氨混纺针织面料连续加工用除油剂的制备方法，它包括如下步骤：
a)将聚氧化烯型非离子表面活性剂、螯合剂、氟碳表面活性剂、有机氟整理剂、有机溶剂和水在50－100℃的温度和在50－100r/min的速度下搅拌均匀，和
b)降温出料。
CN201811520271.4A 2018-12-12 2018-12-12 涤/氨及锦/氨混纺针织面料连续加工用除油剂及其制备方法 Active CN109370795B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811520271.4A CN109370795B (zh) 2018-12-12 2018-12-12 涤/氨及锦/氨混纺针织面料连续加工用除油剂及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811520271.4A CN109370795B (zh) 2018-12-12 2018-12-12 涤/氨及锦/氨混纺针织面料连续加工用除油剂及其制备方法

Publications (2)

Publication Number Publication Date
CN109370795A CN109370795A (zh) 2019-02-22
CN109370795B true CN109370795B (zh) 2020-10-02

Family

ID=65373426

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811520271.4A Active CN109370795B (zh) 2018-12-12 2018-12-12 涤/氨及锦/氨混纺针织面料连续加工用除油剂及其制备方法

Country Status (1)

Country Link
CN (1) CN109370795B (zh)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111206443A (zh) * 2020-01-10 2020-05-29 绍兴市途锦化工有限公司 一种涤纶染色剂及其退浆染色工艺流程
CN113293622B (zh) * 2021-06-15 2022-02-18 杭州美高华颐化工有限公司 一种用于锦氨织物的快速除油剂
CN115058296A (zh) * 2022-04-18 2022-09-16 广东丽臣奥威实业有限公司 一种低泡杀菌的表面活性剂组合物

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001316691A (ja) * 2000-02-29 2001-11-16 Showa Denko Kk 洗浄剤組成物、洗浄方法及びその用途
US7728064B2 (en) * 2003-11-13 2010-06-01 Daikin Industries, Ltd. Aqueous liquid dispersion of water and oil repellent agent containing nonionic surfactant
CN102071110A (zh) * 2011-01-06 2011-05-25 建德市白沙化工有限公司 一种除油剂的配方及制备方法
CN102352561A (zh) * 2011-07-29 2012-02-15 苏州卡奇特纺织有限公司 一种尼龙氨纶混纺织物的精炼工艺
CN104233878A (zh) * 2014-09-04 2014-12-24 绍兴中纺院江南分院有限公司 一种聚丁二酸丁二醇酯针织物的染整加工方法
CN107446725A (zh) * 2017-07-04 2017-12-08 传化智联股份有限公司 一种水包油微乳液去油剂及其制备方法和应用
CN107794763A (zh) * 2017-11-13 2018-03-13 东莞市古川纺织助剂有限公司 一种织物除油剂

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001316691A (ja) * 2000-02-29 2001-11-16 Showa Denko Kk 洗浄剤組成物、洗浄方法及びその用途
US7728064B2 (en) * 2003-11-13 2010-06-01 Daikin Industries, Ltd. Aqueous liquid dispersion of water and oil repellent agent containing nonionic surfactant
CN102071110A (zh) * 2011-01-06 2011-05-25 建德市白沙化工有限公司 一种除油剂的配方及制备方法
CN102352561A (zh) * 2011-07-29 2012-02-15 苏州卡奇特纺织有限公司 一种尼龙氨纶混纺织物的精炼工艺
CN104233878A (zh) * 2014-09-04 2014-12-24 绍兴中纺院江南分院有限公司 一种聚丁二酸丁二醇酯针织物的染整加工方法
CN107446725A (zh) * 2017-07-04 2017-12-08 传化智联股份有限公司 一种水包油微乳液去油剂及其制备方法和应用
CN107794763A (zh) * 2017-11-13 2018-03-13 东莞市古川纺织助剂有限公司 一种织物除油剂

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
含氟表面活性剂的特性和用途;蔡继权;《杭州化工》;20100331;10-14页 *

Also Published As

Publication number Publication date
CN109370795A (zh) 2019-02-22

Similar Documents

Publication Publication Date Title
CN109370795B (zh) 涤/氨及锦/氨混纺针织面料连续加工用除油剂及其制备方法
EP0436470B1 (de) Verfahren zum photochemischen Stabilisieren von gefärbten Polyamid-Fasermaterialien
US6007584A (en) Scouring agent composition for fiber
CN105696386B (zh) 一种涤纶面料练漂染工艺
US4123378A (en) Stain removing agents and process for cleaning and optionally dyeing textile material
SE440027B (sv) Skumdempningsmedel for vattenhaltiga system
CN111910451B (zh) 一种宽温去油精炼剂及其制备方法
CN107794763A (zh) 一种织物除油剂
DE2153366C3 (de) Polyglykolätherverbindungen, Verfahren zu deren Herstellung und deren Verwendung
CN107630370A (zh) 集多功能的染色同浴用除油剂
CN104480718A (zh) 一种新型人造棉低温精炼剂
JP2015522721A (ja) ポリエステル繊維用染色助剤、並びにこれを用いたポリエステル繊維の染色方法及び染色物の製造方法
CN114318903A (zh) 一种低泡同浴染色除油匀染剂
JP2013155470A (ja) 繊維用精練剤及び非イオン界面活性剤
CN110564517A (zh) 低泡除油精练剂及其制备方法和使用方法
EP0235080A1 (de) Färbereihilfsmittel und seine Verwendung beim Färben oder optischen Aufhellen von synthetischen stickstoffhaltigen Fasermaterialien
JP5666146B2 (ja) 繊維用精練剤組成物
CN111910437B (zh) 一种三防整理用润湿剂及其制备方法
TW201733971A (zh) 染色助劑及染色纖維製品之製造方法
JP2003528988A (ja) 織物繊維の処理におけるポリアルコキシ化したテルペン誘導体の使用方法
CN113583763A (zh) 一种高效织物除油剂的制备方法
CN112553907A (zh) 染色同浴用多功能除油剂及其制备方法
JPH0617379A (ja) 天然由来又は合成ポリアミド繊維の染色法
JP2020033667A (ja) 繊維用精練剤及び精練方法
DE3119518A1 (de) Verfahren zum faerben oder ausruesten von textilen fasermaterialien

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right

Effective date of registration: 20200909

Address after: No.11 Binzhou Road, petrochemical District, taicanggang Port Development Zone, Suzhou City, Jiangsu Province

Applicant after: TAICANG BAONI INDUSTRIAL Co.,Ltd.

Address before: 201812 No. 388, Jinyuan Sixth Road, Jiangqiao Town, Jiading District, Shanghai

Applicant before: ARGUS (SHANGHAI) TEXTILE AUXILIARY Co.,Ltd.

TA01 Transfer of patent application right
GR01 Patent grant
GR01 Patent grant