CN109370795B - 涤/氨及锦/氨混纺针织面料连续加工用除油剂及其制备方法 - Google Patents
涤/氨及锦/氨混纺针织面料连续加工用除油剂及其制备方法 Download PDFInfo
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- CN109370795B CN109370795B CN201811520271.4A CN201811520271A CN109370795B CN 109370795 B CN109370795 B CN 109370795B CN 201811520271 A CN201811520271 A CN 201811520271A CN 109370795 B CN109370795 B CN 109370795B
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- Prior art keywords
- ammonia
- agent
- nylon
- polyester
- oil removing
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- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title claims abstract description 80
- 239000004744 fabric Substances 0.000 title claims abstract description 52
- 229910021529 ammonia Inorganic materials 0.000 title claims abstract description 42
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 38
- 238000012545 processing Methods 0.000 title claims abstract description 34
- 229920000728 polyester Polymers 0.000 title claims abstract description 27
- 239000004677 Nylon Substances 0.000 title claims abstract description 25
- 229920001778 nylon Polymers 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title abstract description 7
- 238000004519 manufacturing process Methods 0.000 title description 5
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 22
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000004094 surface-active agent Substances 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000002738 chelating agent Substances 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 15
- 239000013527 degreasing agent Substances 0.000 claims abstract description 14
- 239000004814 polyurethane Substances 0.000 claims abstract description 14
- 229920002635 polyurethane Polymers 0.000 claims abstract description 14
- 238000005237 degreasing agent Methods 0.000 claims abstract description 10
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 7
- 239000011737 fluorine Substances 0.000 claims abstract description 7
- 239000003960 organic solvent Substances 0.000 claims abstract description 6
- 239000004952 Polyamide Substances 0.000 claims abstract 3
- 229920002647 polyamide Polymers 0.000 claims abstract 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 7
- 238000007599 discharging Methods 0.000 claims description 7
- -1 polyoxyethylene Polymers 0.000 claims description 7
- 239000002689 soil Substances 0.000 claims description 7
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 4
- 229920002125 Sokalan® Polymers 0.000 claims description 4
- 125000000129 anionic group Chemical group 0.000 claims description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
- BAERPNBPLZWCES-UHFFFAOYSA-N (2-hydroxy-1-phosphonoethyl)phosphonic acid Chemical compound OCC(P(O)(O)=O)P(O)(O)=O BAERPNBPLZWCES-UHFFFAOYSA-N 0.000 claims description 3
- JSYPRLVDJYQMAI-ODZAUARKSA-N (z)-but-2-enedioic acid;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)\C=C/C(O)=O JSYPRLVDJYQMAI-ODZAUARKSA-N 0.000 claims description 3
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 2
- CBOIHMRHGLHBPB-UHFFFAOYSA-N hydroxymethyl Chemical group O[CH2] CBOIHMRHGLHBPB-UHFFFAOYSA-N 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 2
- 229960001484 edetic acid Drugs 0.000 claims 2
- 229920000388 Polyphosphate Polymers 0.000 claims 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims 1
- 238000005202 decontamination Methods 0.000 claims 1
- 230000003588 decontaminative effect Effects 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 125000000373 fatty alcohol group Chemical group 0.000 claims 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims 1
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims 1
- MPNNOLHYOHFJKL-UHFFFAOYSA-N peroxyphosphoric acid Chemical compound OOP(O)(O)=O MPNNOLHYOHFJKL-UHFFFAOYSA-N 0.000 claims 1
- 229920005646 polycarboxylate Polymers 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 239000001205 polyphosphate Substances 0.000 claims 1
- 235000011176 polyphosphates Nutrition 0.000 claims 1
- 238000004043 dyeing Methods 0.000 abstract description 6
- 230000001804 emulsifying effect Effects 0.000 abstract description 5
- 230000035699 permeability Effects 0.000 abstract description 5
- 239000003921 oil Substances 0.000 description 45
- 229920002334 Spandex Polymers 0.000 description 13
- 239000004759 spandex Substances 0.000 description 13
- 150000002191 fatty alcohols Chemical class 0.000 description 12
- 239000000126 substance Substances 0.000 description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 238000011156 evaluation Methods 0.000 description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000009940 knitting Methods 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 239000012496 blank sample Substances 0.000 description 3
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 3
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000010186 staining Methods 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- DMOXNIKYXJYCFQ-UHFFFAOYSA-N (2-hydroxy-1-phosphonooxyethyl) dihydrogen phosphate Chemical compound OP(=O)(O)OC(CO)OP(O)(O)=O DMOXNIKYXJYCFQ-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 229920004933 Terylene® Polymers 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 238000007605 air drying Methods 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000004148 curcumin Substances 0.000 description 2
- 238000005238 degreasing Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 238000003682 fluorination reaction Methods 0.000 description 2
- 229920002313 fluoropolymer Polymers 0.000 description 2
- 239000004811 fluoropolymer Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000008676 import Effects 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000008041 oiling agent Substances 0.000 description 2
- 150000004812 organic fluorine compounds Chemical class 0.000 description 2
- 230000010355 oscillation Effects 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 description 2
- 239000011591 potassium Chemical group 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 1
- VAJVDSVGBWFCLW-UHFFFAOYSA-N 3-Phenyl-1-propanol Chemical compound OCCCC1=CC=CC=C1 VAJVDSVGBWFCLW-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 238000012935 Averaging Methods 0.000 description 1
- 229920006052 Chinlon® Polymers 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- DYUQAZSOFZSPHD-UHFFFAOYSA-N Phenylpropyl alcohol Natural products CCC(O)C1=CC=CC=C1 DYUQAZSOFZSPHD-UHFFFAOYSA-N 0.000 description 1
- 229910006067 SO3−M Inorganic materials 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- KZKGLGIVGQYOTG-UHFFFAOYSA-N [F].[Au] Chemical compound [F].[Au] KZKGLGIVGQYOTG-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000010727 cylinder oil Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- AMTWCFIAVKBGOD-UHFFFAOYSA-N dioxosilane;methoxy-dimethyl-trimethylsilyloxysilane Chemical compound O=[Si]=O.CO[Si](C)(C)O[Si](C)(C)C AMTWCFIAVKBGOD-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 210000004177 elastic tissue Anatomy 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- NIXONLGLPJQPCW-UHFFFAOYSA-K gold trifluoride Chemical compound F[Au](F)F NIXONLGLPJQPCW-UHFFFAOYSA-K 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229940083037 simethicone Drugs 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2034—Monohydric alcohols aromatic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/364—Organic compounds containing phosphorus containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/332—Di- or polyamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/44—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing nitrogen and phosphorus
- D06M13/453—Phosphates or phosphites containing nitrogen atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
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Abstract
本发明提供了一种涤/氨及锦/氨混纺针织面料连续加工用除油剂及其制备方法。该除油剂包括50‑70重量%聚氧化烯型非离子表面活性剂、2‑15重量%螯合剂、1‑5重量%氟碳表面活性剂、0.2‑3重量%有机氟整理剂、1‑10重量%有机溶剂和15‑35重量%水,以涤/氨及锦/氨混纺针织面料连续加工用除油剂的总重量为基准。本发明除油剂具有良好的油去除性,乳化分散性,防反沾性和快速渗透性,解决涤/氨或锦/氨混纺针织面料连续前处理过程中,由于油去除不良引起的各种染整加工问题。
Description
技术领域
本发明涉及纺织印染平幅连续加工用除油剂及其制备方法,特别涉及涤/氨及锦/氨混纺针织面料连续加工用除油剂及其制备方法。
背景技术
氨纶纤维由于其出色的服用性,在化纤混纺面料中的应用不断的扩大,而且氨纶的含量不断提升,由最初的2-5%提升到30-50%不等。这类面料在织造过程中,除了要添加各类矿物油,针织油等纺织油剂外,氨纶本身还含有大量有机硅类的润滑剂。这些油剂的存在,在进行染色加工处理前必须去除,否则会导致各种染色色斑,色花等染色问题。
平幅连续前处理相对于间歇式绳状加工,能显著提高加工品质:减少擦伤,皱印,不易起毛,织物表面更洁净;同时生产效率更高,能耗能减少一半左右。因而,平幅连续加工已经成为行业的发展趋势。但是,连续除油水洗相对于缸内除油而言,存在布液接触时间短,除油不易充分,同时由于杂质的不断积累,处理后期容易反沾,造成头尾差,品质不均一的问题。
目前市场上常用的去油剂大部分是基于氨纶含量低,绳状缸内加工工艺的基础上开发的,不能完全适合平幅连续除油的需求。首先,矿物油,针织油等纺织油剂的表面张力一般30mN/m左右,氨纶纺丝用的有机硅类润滑剂的表面张力一般在20mN/m左右;传统用去油表面张力一般低于30mN/m,不能满足对氨纶丝的除油要求。再次,缸内除油不存在油剂不断积累的问题,连续处理随着时间的推移,油剂不断增多,反沾问题严重,要求除油剂有更强的乳化分散能力;最后,平幅连续加工布液接触时间短,要求去油剂渗透力更好,除油效率更高。
本领域中迫切需要一种去油剂,它不仅可以满足高含量氨纶混纺织物的去油要求,同时满足平幅连续前处理的高渗透性,高乳化分散力的要求,满足市场行业的发展需求;同时不含有APEO,NPEO,等非环保类成分。
发明内容
本发明解决了现用传统去油剂,在平幅连续前处理工艺中,存在的渗透性不足,乳化分散力不够,纺织用硅油油剂去除力不够引起的各种前处理问题,满足后期染整加工要求,达到提高效率,节能减排的目的。
本发明的一方面提供了一种涤/氨及锦/氨混纺针织面料连续加工用除油剂,它包括如下组分:
以涤/氨及锦/氨混纺针织面料连续加工用除油剂的总重量为基准。
本发明的另一方面提供了上述涤/氨及锦/氨混纺针织面料连续加工用除油剂的制备方法,它包括如下步骤:
a)将聚氧化烯型非离子表面活性剂、螯合剂、氟碳表面活性剂、有机氟整理剂、有机溶剂和水在50-100℃的温度和在50-100r/min的速度下搅拌均匀,和
b)降温出料。
本发明的另一个方面提供了一种除油剂在涤/氨或锦/氨混纺针织面料在中性或碱性条件下平幅连续除油工艺上的应用。
本发明具有良好的油去除力,防沾污性,加工稳定性,不含有APEO,NPEO等非环保类成分。
具体实施方式
在一个优选的实施方式中,本发明的涤/氨及锦/氨混纺针织面料连续加工用除油剂它包括如下组分:
以涤/氨及锦/氨混纺针织面料连续加工用除油剂的总重量为基准。
在一个优选的实施方式中,所述的聚氧化烯型非离子表面活性剂例如包括脂肪醇聚氧乙烯聚氧丙烯型非离子表面活性剂、酚类聚氧乙烯型非离子表面活性剂、或它们的混合物。
在一个特别优选的实施方式中,脂肪醇聚氧乙烯聚氧丙烯型非离子表面活性剂例如可用如下通式表示:
R6-O-(EO)x'-(PO)y'-H (I)
其中R6为C10~20烷基,优选C12~18烷基;所述EO结构单元的个数x'=1~20,优选为5~12,PO结构单元个数y'=0~8,优选为1-5。
在一个特别优选的实施方式中,酚类聚氧乙烯型非离子表面活性剂例如是可用如下通式表示的烷基酚类聚氧乙烯型非离子表面活性剂:
式中,-R7为C10~20直链或支链烷基,优选为C12~18直链或支链烷基;m'=1-20,优选为5-15。
在一个特别优选的实施方式中,所述脂肪醇聚氧乙烯聚氧丙烯型非离子表面活性剂与酚类聚氧乙烯聚氧丙烯型非离子表面活性剂的重量比为30-70:30-70,优选为35-65:35-65。
在一个优选的实施方式中,所述的螯合剂例如包括多羧酸盐型螯合剂、多磷酸盐型螯合剂、羟基羧酸盐型螯合剂、羟基磷酸盐型螯合剂、或它们的混合物。
在一个更优选的实施方式中,所述的螯合剂例如包括马来酸-丙烯酸聚合物、乙二胺四乙酸(EDTA)、二乙基三胺五乙酸(DTPA)、羟基乙叉二磷酸(HEDP)、二乙烯三胺五甲叉磷酸(DTPMPA)中的一种或多种。
在一个特别优选的实施方式中,马来酸-丙烯酸聚合物的分子量例如为3000-15000,优选为5000-12000。
在一个优选的实施方式中,所述的氟碳表面活性剂包括非离子型氟碳表面活性剂、两性离子型氟碳表面活性剂、阴离子型氟碳表面活性剂、或它们的混合物。
在一个更优选的实施方式,所述的非离子型氟碳表面活性例如可用如下通式表示:
Rf1CH2CH2O(CH2CH2O)n'H, (III)
式中Rf1=F(CF2CF2)p1,n'=0~50,优选为10-35,p1=1~9,优选为1~5。
在一个更加优选的实施方式,所述的两性离子型氟碳表面活性剂可用如下通式表示:
Rf2CH2CH2O(CH2CH2O)sN+(CH3)3CH2SO3-M (IV)
式中,Rf2=F(CF2CF2)p2其中s=0~10,优选为1-5,p2=1~9,优选为1~5,M为钠、钾或铵离子。,
在一个更加优选的实施方式,所述的阴离子型氟碳表面活性剂可用如下通式表示:
Rf3COO-M (V)
式中,Rf3=F(CF2CF2)p3其中p3=1~9,优选为1~5,M为钠、钾或铵离子。
在一个优选的实施方式中,所述的有机氟整理剂是易去污功能的有机氟整理剂。
在一个更优选的实施方式中,所述易去污功能的含氟聚合物包含用下式表示的结构单元:
其中:Rf=CnF2n+1(n=6-12),X=-(CH2)tNHSO2-(t=2-4)、-CH2CH2NOH-、-(CH2)m-(m=1-10)、或-CH2CHOHCH2-;R3、R4、R5为H、-CH2CH3、或-CH3;R1=CrH2r+1(r=8-18)、-(CH2CH2O)WH(w=1-18);Y=H或Cl;R2=-CH2OH、-C(CH3)2CH2COCH3;a=1-10000,b=1-10000,c=1-10000,d=1-10000。
在一个更加优选的实施方式,所述含氟聚合物为TG-9131(大金氟化工),TG-9011(大金氟化工),Nuva N4118(昂高化工),Nuva N4547(昂高化工),AG-E100(旭硝子化学)中的任意一种或两种以上的组合。
在一个优选的实施方式,所述的有机溶剂例如包括有机醇、有机醚或它们的混合物,例如可以为本行业中常用的醇或醚,特别是可与水任意混溶的醇或醚,例如,甲醇,乙醇、异丙醇,二乙二醇单丁醚,苯甲醇中任意一种或两种以上的组合。
在一个优选的实施方式,本发明中所用的水可以为本行业中所用的任何洁净的水,如去离子水。
本发明的另一个方面提供了一种涤/氨及锦/氨混纺针织面料连续加工用除油剂的制备方法,它包括:
将聚氧化烯型非离子表面活性剂、螯合剂、氟碳表面活性剂、有机氟整理剂、有机溶剂和水在50-100℃的温度和在50-100r/min的速度搅拌0.5-3小时,降温至40℃以下,出料。
本发明的除油剂可在涤/氨或锦/氨混纺针织面料在中性或碱性条件下平幅连续除油工艺上的应用。
本发明适用于涤纶/氨纶混纺,锦纶/氨纶混纺面料,素材形态方面,可用于针织布。
本发明的涤/氨及锦/氨混纺针织面料连续加工用除油剂的使用量可根据纤维素材,以及目标性能等适宜调整。
本发明具有良好的油去除力,防沾污性,加工稳定性,不含有APEO,NPEO等非环保类成分。
实施例
下面结合具体实施例的性能对比,进一步阐述本发明。
如下各实施例中的性能测试指标通过如下方法测定:
1,去油性评价
1)油污布制作:
织物:涤纶氨纶去油针织布(预先用氯仿萃取干净)
上油工艺:两浸两轧油污溶液(3kgf)→室温晾干。
织物:锦纶氨纶针织去油布(预先用氯仿萃取干净)
上油工艺:两浸两轧油污溶液(3kgf)→室温晾干。
评价标准:
2)去油率测定
仪器:纤维油脂快速抽取器
溶剂:***
操作工艺:精确称取2g左右的测试布和铝盘的重量(精确至0.0001g),将布样装入抽取器的钢筒中,并用压杆压紧,油剂烘干温度设定为120℃,温度到达后,在钢筒下方放置称量过的干净铝盘,往钢筒中加入10ml***,堵住出口,保持1min,放开出口,待溶剂滴完后,再加入10ml***,同样保持1min,待溶剂滴完后,恒重铝箔盘,计算萃取得到的油剂量,计算织物含油率,每块布样测二个值,取平均值,计算去油率。
去油率(%)=处理前油污布含油率(%)-处理后油污布含油率(%)
3)除油操作方法
去油工艺过程:精练槽(90℃*3min)→精练槽(90℃*3min)→水洗槽(90℃*3min)→水洗槽(70℃*3min)→水洗槽(40℃*3min)→脱水→烘干
将0.5g实施例和对比例(还需一组不加除油剂的空白样)分别加入100ml精练槽,待各槽温度升至设定温度后,加入待处理油污布10g,按照设定工艺时间,依次通过各槽,完成前处理工艺流程。
4)评判标准:
去油率越高,去油性能越好。
2,乳化分散力评价
油和染料的混合液制备:
将矿物油40g,针织油20g,机油5g,二甲基硅油35g,油溶红0.02g,混合后,搅拌均匀。
评价方法:将0.2g的实施例和对比列(还需一组不加除油剂的空白样)分别加入250ml烧瓶中,配制成100ml溶液,然后向溶液中滴加油和染料的混合液0.03g.配置好的溶液放置在恒温震荡染色机(震荡频率900rpm),按照3℃/分的速度升温至90℃,该温度下保持30分钟;结束后取出,降至室温后,采用4A滤纸过滤。
评价标准:
滤纸颜色越浅,乳化分散效果越好。
3,渗透力评价
将2g的实施例和对比列(还需一组不加除油剂的空白样)分别加入1000ml的水溶液中,采用3*3cm的涤氨坯布进行沉降实验,将待测液放置在1L量筒中(内径约为70mm),记录涤氨坯布的从放入液面到下沉至量筒底部的时间t作为助剂的渗透时间。
评价标准:
渗透时间越短,渗透力越好。
实施例1
将30重量份的脂肪醇聚氧乙烯聚氧丙烯型非离子表面活性剂(式I中,脂肪醇的C数为13,其中EO数为9,PO数为1),30重量份的烷基酚聚氧乙烯型非离子表面活性剂(式II中,R7为-C15H25,其中EO数为10),5重量份的马来酸-丙烯酸聚合物(聚合度1万),2重量份的非离子氟碳表面活性剂(式III中,Rf1=F(CF2CF2)3其中n'=30),1重量份的易去污整理剂TG-9131(大金氟化工)和3重量份的异丙醇以及29重量份的去离子水,然后升温至90-100℃,在60-70r/min速度搅拌2小时,搅拌均匀后,降温至40℃以下,出料,制得产品。
实施例2
将40重量份的脂肪醇聚氧乙烯聚氧丙烯型非离子表面活性剂(式I中,脂肪醇的C数为12,其中EO数为6,PO数为1),25重量份的烷基酚聚氧乙烯型非离子表面活性剂(式II中,R7为-C15H27,其中EO数为5),5重量份的二乙基三胺五乙酸,3重量份的非离子氟碳表面活性剂(式III中,Rf1=F(CF2CF2)3其中n'=15),和0.5重量份的易去污整理剂Nuva N4118(昂高化工),2重量份的异丙醇,4重量份的二乙二醇单丁醚,以及20.5重量份的去离子水,然后升温至70-80℃,在60-70r/min速度搅拌1-2小时,搅拌均匀后,降温至40℃以下,出料,制得产品。
实施例3
将25重量份的脂肪醇聚氧乙烯聚氧丙烯型非离子表面活性剂(式I中,脂肪醇的C数为18,其中EO数为9,PO数为3),35重量份的烷基酚聚氧乙烯型非离子表面活性剂(式II中,R7为-C15H29,其中EO数为10),2重量份的马来酸-聚丙烯酸聚合物(聚合度8000),4重量份羟基乙叉二磷酸,3重量份的两性离子型氟碳表面活性剂(式IV中,Rf2=F(CF2CF2)4,其中s=1),和2重量份的易去污整理剂AG-E100(旭硝子化学),4重量份的苯丙醇,1重量份的甲醇,以及24重量份的去离子水,然后升温至90-100℃,在70-80r/min速度搅拌2-3小时,搅拌均匀后,降温至40℃以下,出料,制得产品。
实施例4
将30重量份的脂肪醇聚氧乙烯聚氧丙烯型非离子表面活性剂(式I中,脂肪醇的C数为13,其中EO数为8,PO数为2),28重量份的烷基酚聚氧乙烯聚氧丙烯型非离子表面活性剂(式II中,R7为-C15H31,其中EO数为6),12重量份二乙烯三胺五甲叉磷酸,1重量份的阴离子型氟碳表面活性剂(式V中,Rf3=F(CF2CF2)3,M=Na+)和2重量份非离子氟碳表面活性剂(式III中,Rf1=F(CF2CF2)3,其中n'=15),1重量份的易去污整理剂TG-9011(大金氟化工),5重量份的二乙二醇单丁醚,以及21重量份的去离子水,然后升温至80-90℃,在70-90r/min速度搅拌2-3小时,搅拌均匀后,降温至40℃以下,出料,制得产品。
对比例
国产品T:去油剂TF-115D(浙江传化化工)
国产品D:专利公开号CN106978727A实施例三(40重量份的脂肪醇聚氧乙烯醚AEO-7和30重量份的异构十三醇聚氧乙烯醚1307,10重量份的甲醇,20重量份的水)
进口品L:去油剂LYS(科莱恩化工)
应用效果表1
应用效果附表2
乳化分散性过滤 | 渗透性 | |
外观 | 时间(s) | |
实施例1 | 颜色浅,残留物少 | 5s |
实施例2 | 颜色浅,残留物少 | 4s |
实施例3 | 颜色浅,残留物少 | 4s |
实施例4 | 颜色浅,残留物少 | 7s |
国产品T | 颜色深,残留物多 | 50s |
国产品D | 颜色稍深,残留物稍多 | 20s |
进口品L | 颜色浅,残留物稍少 | 15s |
空白 | 颜色深,残留多 | >180s |
由以上数据可知,本发明各实施例的连续去油性均优于市场对比例,不仅适用于低氨纶含量的混纺面料,对高氨纶含量的混纺面料也具有极佳的去油效果;各实施例的油的乳化分散性均好于市场对比例,可以极大提升布面的防沾污性,同时渗透性相对于市场对比例也有明显的优势,满足长车连续处理的速度要求,提高生产效率。
Claims (10)
3.如权利要求1或2所述的涤/氨及锦/氨混纺针织面料连续加工用除油剂,其特征在于,所述的聚氧化烯型非离子表面活性剂是脂肪醇聚氧乙烯聚氧丙烯型非离子表面活性剂、酚类聚氧乙烯型非离子表面活性剂、或它们的混合物。
4.如权利要求1或2所述的涤/氨及锦/氨混纺针织面料连续加工用除油剂,其特征在于,所述的螯合剂包括多羧酸盐型螯合剂、多磷酸盐型螯合剂、羟基羧酸盐型螯合剂、羟基磷酸盐型螯合剂、或它们的混合物。
5.如权利要求1或2所述的涤/氨及锦/氨混纺针织面料连续加工用除油剂,其特征在于,所述的螯合剂包括马来酸-丙烯酸聚合物、乙二胺四乙酸(EDTA)、二乙基三胺五乙酸(DTPA)、羟基乙叉二磷酸(HEDP)、二乙烯三胺五甲叉磷酸(DTPMPA)中的一种或多种。
6.如权利要求1或2所述的涤/氨及锦/氨混纺针织面料连续加工用除油剂,其特征在于,所述的氟碳表面活性剂包括非离子型氟碳表面活性剂、两性离子型氟碳表面活性剂、阴离子型氟碳表面活性剂、或它们的混合物。
7.如权利要求1或2所述的涤/氨及锦/氨混纺针织面料连续加工用除油剂,其特征在于,所述的有机氟整理剂是易去污功能的有机氟整理剂。
9.如权利要求1或2所述的涤/氨及锦/氨混纺针织面料连续加工用除油剂,其特征在于,所述的有机溶剂包括有机醇、有机醚或它们的混合物;所述的水包括去离子水。
10.如权利要求1-9中任一项所述的涤/氨及锦/氨混纺针织面料连续加工用除油剂的制备方法,它包括如下步骤:
a)将聚氧化烯型非离子表面活性剂、螯合剂、氟碳表面活性剂、有机氟整理剂、有机溶剂和水在50-100℃的温度和在50-100r/min的速度下搅拌均匀,和
b)降温出料。
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