CN109369942A - It is a kind of intelligently to indicate edible film and preparation method thereof, purposes - Google Patents

It is a kind of intelligently to indicate edible film and preparation method thereof, purposes Download PDF

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Publication number
CN109369942A
CN109369942A CN201811275214.4A CN201811275214A CN109369942A CN 109369942 A CN109369942 A CN 109369942A CN 201811275214 A CN201811275214 A CN 201811275214A CN 109369942 A CN109369942 A CN 109369942A
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starch
film
based material
edible film
quality
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CN201811275214.4A
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CN109369942B (en
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何芸
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Shunde Vocational and Technical College
Shunde Polytechnic
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Shunde Vocational and Technical College
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Priority to CN202110019093.2A priority Critical patent/CN112661997A/en
Priority to CN201811275214.4A priority patent/CN109369942B/en
Priority to CN202110019075.4A priority patent/CN112552542A/en
Publication of CN109369942A publication Critical patent/CN109369942A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/0427Coating with only one layer of a composition containing a polymer binder
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38Packaging materials of special type or form
    • B65D65/46Applications of disintegrable, dissolvable or edible materials
    • B65D65/463Edible packaging materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2303/00Characterised by the use of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08J2303/02Starch; Degradation products thereof, e.g. dextrin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2389/00Characterised by the use of proteins; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2401/00Characterised by the use of cellulose, modified cellulose or cellulose derivatives
    • C08J2401/08Cellulose derivatives
    • C08J2401/26Cellulose ethers
    • C08J2401/28Alkyl ethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2403/00Characterised by the use of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08J2403/02Starch; Degradation products thereof, e.g. dextrin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2405/00Characterised by the use of polysaccharides or of their derivatives not provided for in groups C08J2401/00 or C08J2403/00
    • C08J2405/04Alginic acid; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2471/00Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
    • C08J2471/02Polyalkylene oxides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/092Polycarboxylic acids
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/90Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in food processing or handling, e.g. food conservation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W90/00Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
    • Y02W90/10Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • General Preparation And Processing Of Foods (AREA)
  • Jellies, Jams, And Syrups (AREA)

Abstract

The present invention discloses a kind of intelligently instruction edible film and its preparation, purposes.Intelligence instruction edible film is starch/albumen bilayer edible film that one layer of protein film is added on dry starch film, wherein, starch film is using starch as substrate, add the natural acid-base indicators of the crosslinking agent of starch based material quality 2.5%, the reinforcing agent of starch based material quality 1.4%, the plasticizer of starch based material quality 0.6% and starch based material quality 1.5%, protein film adds the plasticizer of protein basis quality 0.3% and the moisturizer of protein basis quality 0.15% using albumen as substrate.Resulting starch/albumen bilayer edible film is made using safe, physical property is good, and has the function of intelligence instruction.

Description

It is a kind of intelligently to indicate edible film and preparation method thereof, purposes
Technical field
The present invention relates to functional food membrane preparation technology field, more particularly, to a kind of intelligence instruction edible film and its Preparation method, purposes.
Background technique
Dairy products and vegetable protein beverage are rich in nutritive value and have been increasingly becoming public drink by liking for people.? Production is transported, in storing process, and for other drinks, dairy products and vegetable protein beverage are apt to deteriorate, in this process In, it is usually associated with the variation of pH value, therefore can judge whether drink goes bad by pH value determination.But in life can not It is detected by instrument, however contains toxic substance in pH test paper, if being detected using pH test paper, there are using security issues. Under the overall situation for paying high attention to food safety and environmental protection, edible film has become current development instead of traditional plastic foil and becomes Therefore gesture develops a kind of edible film with intelligence instruction function and is of great immediate significance.
Summary of the invention
The purpose of the present invention is to provide a kind of intelligence instruction edible films and preparation method thereof, purposes.Utilize starch film With the characteristic of protein film, pass through the suitable substrate of screening and edible natural acid-base indicators, optimization technique, to improve material The physical property of material, and the function that material intelligently indicates is assigned, to overcome the shortcomings of the prior art.
The present invention the technical solution to solve the technical problem is that: it is a kind of intelligence instruction edible film, it is characterised in that: it is described Intelligence instruction edible film is starch/albumen bilayer edible film that one layer of protein film is added on dry starch film, described Starch film adds the crosslinking agent of starch based material quality 2.5%, the reinforcing agent of starch based material quality 1.4%, forms sediment using starch as substrate The plasticizer of powder substrate mass 0.6% and the natural acid-base indicators of starch based material quality 1.5%, the protein film are with albumen Substrate, adds the plasticizer of protein basis quality 0.3% and the moisturizer of protein basis quality 0.15%, and the natural soda acid refers to Show that agent is purple potato pigment.
The starch based material is oxidised maize starch and wheaten starch, and the protein basis is zeins.
The crosslinking agent is citric acid.
The reinforcing agent is sodium carboxymethylcellulose and sodium alginate.
The plasticizer is one of sorbierite, glycerol.
The moisturizer is polyethylene glycol-400.
The intelligence instruction edible film is coated on colorless and transparent suction pipe inner wall, and drink is quickly detected when drink flows through Freshness, the drink includes dairy products and vegetable protein beverage, the dairy products include pasteurization milk, sterile milk, Cream etc. is modulated, the vegetable protein beverage includes almond milk, coconut milk, Walnut Milk etc..
A kind of intelligence instruction edible film, preparation method follow the steps below:
1) preparation of purple potato pigment
Be sliced after purple sweet potato is cleaned, drying to constant weight at 60 DEG C, after with pulverizer high speed be polished into powder, sieving for standby; Obtained powder is extracted under conditions of 60 DEG C with the ethyl alcohol that volume fraction is 75%, and raw material and solvent press solid-to-liquid ratio 1: 10g/mL mixing, water-bath extract 3h, filter to obtained extracting solution, remove the ethyl alcohol in filtrate under the conditions of being protected from light, Last vacuum freeze drying processing, obtains purple potato pigment powder.
2) corn-wheat starch at film liquid preparation
Oxidised maize starch, wheaten starch are sieved respectively, are configured to 60g/L than deionized water is added by certain mass Solution, the sorbierite of starch based material quality 0.6% is added, carboxymethyl that the mass ratio of starch based material quality 1.4% is 1:1 it is fine The citric acid homogenate of plain sodium and sodium alginate, starch based material quality 2.5% is tieed up, revolving speed 550r/min is gelatinized at 75 DEG C 30min obtains corn-wheat starch into film liquid.
3) natural acid-base indicator is added
1.5% purple potato pigment powder of starch based material quality is added in solution obtained above and uses pH=after mixing evenly PH is adjusted to 7-9 by the sodium hydroxide solution of 13-14, the deaeration 10min in ultrasonic device.
4) zeins at film liquid preparation
The zeins for weighing certain mass prepares albumen quality point by solvent of the ethyl alcohol that volume fraction is 95% The solution of number about 6%, stirs 3min, after completely dissolution to it, the glycerol and protein basis of protein basis quality 0.3% is added The polyethylene glycol-400 of quality 0.15%, continue stir 20min, after be statically placed in 85 DEG C water-bath heat treatment 15min, obtain corn Alcohol soluble protein is at film liquid.
5) on suction pipe inner wall, intelligence indicates the production of edible film
The corn-wheat starch for being added to purple potato pigment is coated on the inner wall of suction pipe at film liquid, is formed a film at 45 DEG C And dry, then zeins is coated on corn-wheat starch film at film liquid, after standing 30min, in 60 DEG C of air blast Dry 2h, obtains intelligent suction pipe finished product.
The beneficial effects of the present invention are:
The present invention utilizes the characteristic of starch film and protein film, by the obtained starch that has complementary functions/albumen bilayer edible film, Good physical property is made it have, and natural acid-base indicator is added, assigns the function that edible film intelligently indicates.It is used It is safety, edible material, and biodegradable.
Specific embodiment
The embodiments described below is exemplary, and for explaining only the invention, and should not be understood as to limit of the invention System.
1) preparation of purple potato pigment
Be sliced after purple sweet potato is cleaned, drying to constant weight at 60 DEG C, after with pulverizer high speed be polished into powder, sieving for standby; Obtained powder is extracted under conditions of 60 DEG C with the ethyl alcohol that volume fraction is 75%, and raw material and solvent press solid-to-liquid ratio 1: 10g/mL mixing, water-bath extract 3h, filter to obtained extracting solution, remove the ethyl alcohol in filtrate under the conditions of being protected from light, Last vacuum freeze drying processing, obtains purple potato pigment powder.
2) corn-wheat starch at film liquid preparation
Oxidised maize starch, wheaten starch are sieved respectively, are configured to 60g/L than deionized water is added by certain mass Solution, the sorbierite of starch based material quality 0.6% is added, carboxymethyl that the mass ratio of starch based material quality 1.4% is 1:1 it is fine The citric acid homogenate of plain sodium and sodium alginate, starch based material quality 2.5% is tieed up, revolving speed 550r/min is gelatinized at 75 DEG C 30min obtains corn-wheat starch into film liquid.
3) natural acid-base indicator is added
1.5% purple potato pigment powder of starch based material quality is added in solution obtained above and uses pH=after mixing evenly PH is adjusted to 7-9 by the sodium hydroxide solution of 13-14, the deaeration 10min in ultrasonic device.
4) zeins at film liquid preparation
The zeins for weighing certain mass prepares albumen quality point by solvent of the ethyl alcohol that volume fraction is 95% The solution of number about 6%, stirs 3min, after completely dissolution to it, the glycerol and protein basis of protein basis quality 0.3% is added The polyethylene glycol-400 of quality 0.15%, continue stir 20min, after be statically placed in 85 DEG C water-bath heat treatment 15min, obtain corn Alcohol soluble protein is at film liquid.
5) on suction pipe inner wall, intelligence indicates the production of edible film
The corn-wheat starch for being added to purple potato pigment is coated on the inner wall of suction pipe at film liquid, is formed a film at 45 DEG C And dry, then zeins is coated on corn-wheat starch film at film liquid, after standing 30min, in 80 DEG C of air blast Dry 1.5h, obtains intelligent suction pipe finished product.
The following are the explanations of oxidised maize starch and wheaten starch mass ratio:
The surface of intelligence instruction edible film is smooth, uniform, and by test, intelligence indicates that the average tensile of edible film is strong Degree is 9.60MPa, average elongation at break 75.15%.
Although an embodiment of the present invention has been shown and described, those skilled in the art should understand that: not A variety of change, modification, replacement and modification can be carried out to these embodiments in the case where being detached from the principle of the present invention and objective, this The range of invention is limited by claim and its equivalent replacement, without creative work improvements introduced etc., should all include Within protection scope of the present invention.

Claims (8)

1. a kind of intelligence instruction edible film, it is characterised in that: the intelligence instruction edible film is on dry starch film Starch/albumen bilayer the edible film of one layer of protein film is added, the starch film adds starch based material quality using starch as substrate 2.5% crosslinking agent, the reinforcing agent of starch based material quality 1.4%, the plasticizer of starch based material quality 0.6% and starch base material The natural acid-base indicators of amount 1.5%, the protein film add the plasticizer of protein basis quality 0.3% using albumen as substrate With the moisturizer of protein basis quality 0.15%, the natural acid-base indicators are purple potato pigment.
2. intelligence instruction edible film according to claim 1, it is characterised in that: the starch based material is oxidised maize starch And wheaten starch, the protein basis are zeins.
3. intelligence instruction edible film according to claim 2, it is characterised in that: the crosslinking agent is citric acid.
4. intelligence instruction edible film according to claim 3, it is characterised in that: the reinforcing agent is sodium carboxymethylcellulose And sodium alginate.
5. intelligence instruction edible film according to claim 4, it is characterised in that: the plasticizer is sorbierite, in glycerol One kind.
6. intelligence instruction edible film according to claim 5, it is characterised in that: the moisturizer is polyethylene glycol-400.
7. the purposes of intelligence instruction edible film according to claim 1, it is characterised in that: the intelligence instruction edible film Coated in the freshness of drink on colorless and transparent suction pipe inner wall, is quickly detected when drink flows through, the drink includes cream system Product and vegetable protein beverage, the dairy products include pasteurization milk, sterile milk, modulation cream etc., the vegetable protein beverage packet Include almond milk, coconut milk, Walnut Milk etc..
8. the preparation method of intelligence instruction edible film according to claim 1, it is characterised in that the following steps are included:
1) be sliced after cleaning purple sweet potato, drying to constant weight at 60 DEG C, after with pulverizer high speed be polished into powder, sieving for standby;? The powder arrived is extracted under conditions of 60 DEG C with the ethyl alcohol that volume fraction is 75%, and raw material and solvent press solid-to-liquid ratio 1: 10g/mL mixing, water-bath extract 3h, filter to obtained extracting solution, remove the ethyl alcohol in filtrate under the conditions of being protected from light, Last vacuum freeze drying processing, obtains purple potato pigment powder;
2) oxidised maize starch, wheaten starch are sieved respectively, are configured to the molten of 60g/L than deionized water is added by certain mass The mass ratio of liquid, sorbierite, starch based material quality 1.4% that starch based material quality 0.6% is added is the carboxymethyl cellulose of 1:1 The citric acid homogenate of sodium and sodium alginate, starch based material quality 2.5%, revolving speed 550r/min are gelatinized 30min at 75 DEG C, obtain To corn-wheat starch at film liquid;
3) 1.5% purple potato pigment powder of starch based material quality is added in solution obtained above and uses pH=after mixing evenly PH is adjusted to 7-9 by the sodium hydroxide solution of 13-14, the deaeration 10min in ultrasonic device;
4) zeins for weighing certain mass prepares albumen quality score by solvent of the ethyl alcohol that volume fraction is 95% About 6% solution stirs 3min, after completely dissolution to it, the glycerol and protein basis matter of protein basis quality 0.3% is added Amount 0.15% polyethylene glycol-400, continue stir 20min, after be statically placed in 85 DEG C water-bath heat treatment 15min, obtain corn alcohol Molten albumen is at film liquid;
5) the corn-wheat starch for being added to purple potato pigment is coated on the inner wall of suction pipe at film liquid, is formed a film simultaneously at 45 DEG C Drying, then zeins is coated on corn-wheat starch film at film liquid, after standing 30min, in 60 DEG C of forced air dryings 2h obtains intelligent suction pipe finished product.
CN201811275214.4A 2018-10-30 2018-10-30 Intelligent indicating edible film and preparation method and application thereof Active CN109369942B (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN202110019093.2A CN112661997A (en) 2018-10-30 2018-10-30 Application of intelligent indicating edible film
CN201811275214.4A CN109369942B (en) 2018-10-30 2018-10-30 Intelligent indicating edible film and preparation method and application thereof
CN202110019075.4A CN112552542A (en) 2018-10-30 2018-10-30 Preparation method of intelligent indicating edible film

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CN202110019093.2A Division CN112661997A (en) 2018-10-30 2018-10-30 Application of intelligent indicating edible film

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Cited By (1)

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Publication number Priority date Publication date Assignee Title
CN111011874A (en) * 2020-01-03 2020-04-17 广州绿徽新材料研究院有限公司 Natural biodegradable composite edible tubular product and preparation method thereof

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CN114989465A (en) * 2022-06-09 2022-09-02 东北农业大学 Preparation method of sodium alginate-purple sweet potato peel anthocyanin intelligent indicating film for monitoring freshness of chicken

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US20080044434A1 (en) * 1999-02-26 2008-02-21 Kirin Beer Kabushiki Kaisha Coated material and process for producing the coated material
CN105885113A (en) * 2016-06-16 2016-08-24 河南省***(集团)有限公司 Double-layer edible film and preparation method and application thereof
CN106496646A (en) * 2016-10-20 2017-03-15 河南工业大学 A kind of corn starch is combined edible flavoring agent packaging film and preparation method thereof with wheaten starch
CN107936311A (en) * 2017-12-21 2018-04-20 天津农学院 It is a kind of to praise cross-linking modified edible film of glue and its preparation method and application based on three

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111011874A (en) * 2020-01-03 2020-04-17 广州绿徽新材料研究院有限公司 Natural biodegradable composite edible tubular product and preparation method thereof

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