CN106496646A - A kind of corn starch is combined edible flavoring agent packaging film and preparation method thereof with wheaten starch - Google Patents
A kind of corn starch is combined edible flavoring agent packaging film and preparation method thereof with wheaten starch Download PDFInfo
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/02—Starch; Degradation products thereof, e.g. dextrin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/38—Packaging materials of special type or form
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/04—Starch derivatives, e.g. crosslinked derivatives
- C08L3/06—Esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/04—Starch derivatives, e.g. crosslinked derivatives
- C08L3/10—Oxidised starch
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2303/00—Characterised by the use of starch, amylose or amylopectin or of their derivatives or degradation products
- C08J2303/02—Starch; Degradation products thereof, e.g. dextrin
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2403/00—Characterised by the use of starch, amylose or amylopectin or of their derivatives or degradation products
- C08J2403/02—Starch; Degradation products thereof, e.g. dextrin
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08L2203/00—Applications
- C08L2203/16—Applications used for films
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/90—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in food processing or handling, e.g. food conservation
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W90/00—Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
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Abstract
The invention belongs to instant food flavouring packaging processing technique field, is related to a kind of citric acid and Fructus Citri Limoniae quintessence oil replaces the corn starch of plasticizer and wheaten starch to be combined edible flavoring agent packaging film and preparation method thereof.A kind of citric acid and Fructus Citri Limoniae quintessence oil replace the corn starch of plasticizer and wheaten starch to be combined edible film and preparation method thereof：(1) Feedstock treating：Configure 57 parts of corn starchs and wheaten starch (m: m=2: 3), 46 parts of citric acids, 1.2 1.6 parts of sodium carboxymethyl cellulose and sodium alginate (m: m=3: 2)；(2) mixed processing：80 120 parts of distilled water, 0.5 1.5 parts of Fructus Citri Limoniae quintessence oil, 0.05 0.15 parts of emulsifier tween 80 or sorbester p17, mixing 15 25min of vibration is added to stir 30 50min with agitator, obtain the homogeneous film liquid being completely dissolved；(3) film forming is dried：To carrying out casting film-forming into film liquid, then at a temperature of 35 55 DEG C, forced air drying obtains compound edible flavoring agent packaging film.
Description
Technical field
The invention belongs to flavoring agent packaging film processing technique field, is related to a kind of citric acid and Fructus Citri Limoniae quintessence oil replaces plasticizer
Corn starch is combined edible flavoring agent packaging film and preparation method thereof with wheaten starch.
Background technology
Starch has source wide, low price, biodegradable, and starch film is that edible film research and development are earliest
Type.In polysaccharide membrane, corn starch is widely used in food packaging applications with wheaten starch, as they have preferably life
The thing compatibility and film forming characteristicss.Corn starch is pure white compared with ative starch color, easy gelatinizing, viscosity is low, stability is high, mobility
Good, permeability is strong, transparency is high, good film-forming property, adhesive tension strong, with corn starch as base material processing edible degradative membrane not
But environment and safety problem that packaging is brought in itself can be solved, moreover it is possible to improve the added value of large agricultural byproducts such as Semen Maydiss.So
And, corn starch film draw high intensity and fracture elongation is unsatisfactory.
Semen Tritici aestivi is staple food crop of the China in addition to rice, as grain ration, is seldom used for producing starch；But Semen Tritici aestivi forms sediment
Paste mixing has that viscosity is low, gelatinization point is low, heat stability good, and long-time heating and stirring viscosity reduce few, form solidifying after cooling
The advantages of gel strength is high, however, single selection wheaten starch is used as into film base material, the poor fluidity of film liquid, smoothness are poor, crisp
Property increase.
Currently, in order to improve the processing characteristics and mechanical performance of plastic package material, it usually needs add appropriate plasticising
Agent, plasticizer can reduce the fragility of starch film.The plasticizer for being usually used in improving film properties mainly has Sorbitol, glycerol, xylose
Alcohol etc..Although above-mentioned several plasticizers have clear and definite consumption standard after all in state food additive catalogue, because long
Phase is taken body is had potentially hazardous.Such as：Sorbitol, calls Sorbitol, be white hygroscopic powder or crystalline powder,
Lamellar or granule, odorless.But toxicity test shows, excess for oral administration can cause diarrhoea and digestive disorders；Glycerol has good water conservation
Effect, it can increase blood volume, so that causing the symptoms such as dizziness, nausea.These symptoms are in gestation, hypertension, diabetes, kidney
The blood volumes such as disease or blood pressure inherently compare high in the case of, just become apparent from.Additionally, glycerol is can be converted in human body
Fat, if so the substantial amounts of glycerol of intake may can cause obesity, these health to people are all potential threats；Wood
Sugar alcohol is a kind of sweet substance with nutritive value, and the normal intermediate of human body carbohydate metabolism.But edible xylitol mistake
Amount can be got fat, and from for physicochemical property, xylitol is cooler, and it is not decomposed by gastric enzyme, is directly entered intestinal, overeats
There is certain stimulation to gastrointestinal, abdominal discomfort, flatulence, borborygmus may be caused.Due to xylitol in intestinal internal absorption factor less than 20%,
Easily accumulate in intestinal wall, easily cause osmotic diarrhea.Explanation presented above, the starch film for adding conventional plasticizers can not be realized
" edible " truly, these chemical addition agents need the sufficiently long time to the harm of human body and environment to assess,
Can not briefly edible.For example fat-soluble phthalic acid ester (content in the plastic is up to 20--30%), in the storage of food
During Tibetan, these plasticizers may be moved in food, and then threaten consumer health, therefore, how to ensure food
On the premise of product packaging film combination property, it is to avoid using similar plasticizer, become current study hotspot and emphasis.
Plants essential oil has natural antibacterial functions.For example, from Citrus extract Fructus Citri Limoniae quintessence oil with its good local flavor,
The advantages of relatively low price, antibacterial action, receive the extensive concern of people.Relative to directly applying to food surface, antioxygen
Agent or antibacterial isoreactivity material are added in packaging for foodstuff, it is to avoid be directly exposed in air, have reached slow release anti-
Oxidant or the purpose of antibacterial isoreactivity material, improve its utilization ratio, and during film forming, plants essential oil with
Starch can internally produce crosslinked action, improve the mechanical performance of packaging film.The interpolation of emulsifier tween 80, sorbester p17, no
Can only help quintessence oil to be preferably soluble in the aqueous phase in system, and cause composite membrane finer and close, uniform.
Content of the invention
For disadvantages mentioned above present in prior art and deficiency, problem to be solved by this invention is：A kind of nothing is provided
The cheap of plasticizer, environmental pollution are less, the tensile strength of material and elongation at break is larger, biocidal property is strong jade
Rice starch is combined edible flavoring agent packaging film and preparation method thereof with wheaten starch.
The purpose of the present invention is achieved through the following technical solutions：
According to the one side of invention, there is provided a kind of corn starch and the compound edible flavoring agent packaging film of wheaten starch, its
It is characterised by, each raw material components of the edible flavoring agent packaging film are according to following weight portion mixing composition：5-7 parts oxidation Semen Maydiss form sediment
(m: m=2: 3, oxidised maize starch color is pure white, flowing with wheaten starch for powder or the double starch adipate corn starchs of acetylation
Property good, film property high and containing substantial amounts of carboxyl and carbonyl, wheaten starch gelatinization point is low, forms gel strength after cooling
Height, both add, and not only can reduce gelatinization point, improve packaging film outward appearance, and define many models due to molecule interchain
The crosslinking of moral China, packaging film mechanical strength are improved well, but when wheaten starch content is more than 60%, are flowed into film liquid
Property be deteriorated, packaging film fragility increase), 4-6 part citric acids, dialdehyde starch or ferulic acid, 1.2-1.6 parts sodium carboxymethyl cellulose and
Sodium alginate (m: m=3: 2, the mechanical performance that both compound packaging film is preferable with block-water performance), 80-120 part distilled water, 0.5-
After 1.5 parts of Fructus Citri Limoniae quintessence oil, the emulsifier tween 80 of 0.05-0.15 parts or sorbester p17, Fructus Citri Limoniae quintessence oil and emulsifying agent add, composite membrane
Compactness is improved, and vapor transmission coefficient reduces.
According to a further aspect in the invention, there is provided a kind of edible corn starch without plasticizer is multiple with wheaten starch
The preparation method of flavoring agent packaging film is closed, is comprised the following steps that：
A, Feedstock treating：Configuration 5-7 parts corn starch and wheaten starch or the double starch adipate corn starchs of acetylation
With wheaten starch (m: m=2: 3), 4-6 part citric acids, dialdehyde starch or ferulic acid, 1.2-1.6 parts sodium carboxymethyl cellulose and sea
Sodium alginate (m: m=3: 2)；
B, mixed processing：Add the emulsifying agent of 80-120 part distilled water, 0.5-1.5 parts Fructus Citri Limoniae quintessence oil and 0.05-0.15 parts
Tween 80 or sorbester p17, mixing vibration 15-25min, stir 30-50min with agitator, obtain the homogeneous film being completely dissolved
Liquid；
C, film forming are dried：To carrying out casting film-forming into film liquid, then at a temperature of 35-55 DEG C forced air drying obtain compound can
Edible-flavouring packaging film.
Compared with the existing technology, the present invention has significant technique effect：
(1) present invention is into film base material by choosing corn starch and wheaten starch, and by process optimization, composite membrane resists
Tensile strength and fracture elongation have reached the requirement of inner packing.
(2), after adding Fructus Citri Limoniae quintessence oil in composite membrane, the fracture elongation of film increases, and color burn, barrier property increase,
And antibacterial ability strengthens, film liquid has good inhibition to staphylococcus aureuses and escherichia coli.
(3), when citric acid addition is 4-6%, the mechanical property of film and barrier property reach most preferably, add Fructus Citri Limoniae quintessence oil
Afterwards, the barrier property of film is further improved, and causes the change of composite membrane mechanical performance.
(4) add the roughness that Fructus Citri Limoniae quintessence oil increased film surface, promote the compactness of cross section structure, but cavity is got over
Carry out bigger, and the interpolation of emulsifying agent, be conducive to the dissolubility for improving Fructus Citri Limoniae quintessence oil, and then cause film finer and close, uniform.
(6) the composite flavouring packaging film that the present invention is developed is mainly by oxidised maize starch, wheaten starch, carboxymethyl cellulose
Prepared by plain sodium, sodium alginate, citric acid, Fructus Citri Limoniae quintessence oil, water, with edibility, nutritive value is higher.
Specific embodiment
For making the objects, technical solutions and advantages of the present invention become more apparent, the present invention is described in more detail.Need
It is noted that described below is only presently preferred embodiments of the present invention, it is not intended to limit the scope of the present invention.Generally
The simple equivalence changes that is made according to claims of the present invention and content of the invention and modification, all still fall within the guarantor of the present patent application
Shield scope.
Embodiment 1
Raw material is from commercially available oxidised maize starch and wheaten starch.First carry out Feedstock treating, 6 parts of corn starchs of configuration with little
Wheat starch, 0.6 part of Sorbitol, 2.5 parts of citric acids, 1.4 parts of sodium carboxymethyl cellulose and sodium alginate；By raw material mix homogeneously
Afterwards, 100 parts of distilled water, mixing vibration 20min are added to stir 40min with 550r/min agitators, obtain being completely dissolved is homogeneous
Film liquid；To carrying out casting film-forming into film liquid, then at a temperature of 45 DEG C, forced air drying obtains compound edible flavoring agent packaging film,
It is put into 48h in 85% constant humidity exsiccator standby.
Embodiment 2
Raw material is from commercially available oxidised maize starch and wheaten starch.First carry out Feedstock treating, 6 parts of corn starchs of configuration with little
Wheat starch, 5 parts of citric acids, 1.4 parts of sodium carboxymethyl cellulose and sodium alginate；After by raw material mix homogeneously, 100 parts of distillations are added
Water, mixing vibration 20min, stirs 40min with 550r/min agitators, obtains the homogeneous film liquid being completely dissolved；To into film liquid
Casting film-forming is carried out, then forced air drying obtains compound edible flavoring agent packaging film at a temperature of 45 DEG C, be put into 85% constant humidity and do
In dry device, 48h is standby.
Embodiment 3
Raw material is from commercially available oxidised maize starch and wheaten starch.First carry out Feedstock treating, 6 parts of corn starchs of configuration with little
Wheat starch, 5 parts of citric acids, 1.4 parts of sodium carboxymethyl cellulose and sodium alginate；After by raw material mix homogeneously, 100 parts of distillations are added
Water, 1 part of Fructus Citri Limoniae quintessence oil, mixing vibration 20min stir 40min with 550r/min agitators, obtain the homogeneous film being completely dissolved
Liquid；To carrying out casting film-forming into film liquid, then at a temperature of 45 DEG C, forced air drying obtains compound edible flavoring agent packaging film, is put into
In 85% constant humidity exsiccator, 48h is standby.
Embodiment 4
Raw material is from commercially available oxidised maize starch and wheaten starch.First carry out Feedstock treating, 6 parts of corn starchs of configuration with little
Wheat starch, 5 parts of citric acids, 1.4 parts of sodium carboxymethyl cellulose and sodium alginate；After by raw material mix homogeneously, 100 parts of distillations are added
Water, 1 part of Fructus Citri Limoniae quintessence oil, 0.1 part of emulsifier span 80, mixing vibration 20min stir 40min with 550r/min agitators, obtain
The homogeneous film liquid being completely dissolved；To carrying out casting film-forming into film liquid, then at a temperature of 45 DEG C forced air drying obtain compound can
Edible-flavouring packaging film, is put into 48h in 85% constant humidity exsiccator standby.
Embodiment 5
Raw material is from commercially available oxidised maize starch and wheaten starch.First carry out Feedstock treating, 6 parts of corn starchs of configuration with little
Wheat starch, 0.6 part of Sorbitol, 2.5 parts of citric acids, 1.4 parts of sodium carboxymethyl cellulose and sodium alginate；By raw material mix homogeneously
Afterwards, emulsifier tween 80 or the sorbester p17 of 100 parts of distilled water, 1 part of Fructus Citri Limoniae quintessence oil and 0.1 part, mixing vibration 20min is added to use
550r/min agitators stir 40min, obtain the homogeneous film liquid being completely dissolved；To carrying out casting film-forming, Ran Hou into film liquid
At a temperature of 45 DEG C, forced air drying obtains compound edible flavoring agent packaging film, is put into 48h in 85% constant humidity exsiccator standby.
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Tensile strength (MPa) | 15.45 | 11.80 | 9.21 | 7.60 | 11.16/11.81 |
| Elongation at break (%) | 29.87 | 38.05 | 46.84 | 33.86 | 25.43/31.79 |
By above-described embodiment, the purpose of the present invention is completely effectively achieved.Person skilled in art is appreciated that
The present invention includes but is not limited to the content described in above specific embodiment.Although the present invention just it is now recognized that the most practical and
Preferred embodiment is illustrated, it should be understood that the present invention is not limited to the disclosed embodiments, any without departing from the present invention's
The modification of function and structure principle is intended to be included in the scope of claims.
Claims (3)
1. a kind of corn starch is combined edible flavoring agent packaging film with wheaten starch, it is characterised in that the edible flavor pack
The each raw material components of dress film are according to following weight portion mixing composition：5-7 parts oxidised maize starch or the double starch adipates of acetylation
Corn starch and wheaten starch (m: m=2: 3), 4-6 part citric acids, dialdehyde starch or ferulic acid, 1.2-1.6 part carboxymethyl celluloses
Plain sodium and sodium alginate (m: m=3: 2), 80-120 part distilled water, 0.5-1.5 part Fructus Citri Limoniae quintessence oil, the emulsifying agent of 0.05-0.15 parts
Tween 80 or sorbester p17, after citric acid, Fructus Citri Limoniae quintessence oil and emulsifying agent add, composite membrane compactness is improved, vapor transmission coefficient
Reduce.
2. edible flavoring agent packaging film according to claim 1, it is characterised in that the emulsifying agent includes span, tween
Deng.
3. the preparation method of edible flavoring agent packaging film according to claim 1, it is characterised in that the preparation method bag
Include following steps：
A, Feedstock treating：Configuration 5-7 parts corn starch and wheaten starch or acetylation pair starch adipate corn starch with little
Wheat starch (m: m=2: 3), 4-6 part citric acids, dialdehyde starch or ferulic acid, 1.2-1.6 parts sodium carboxymethyl cellulose and alginic acid
Sodium (m: m=3: 2)；
B, mixed processing：Add the emulsifier tween of 80-120 part distilled water, 0.5-1.5 parts Fructus Citri Limoniae quintessence oil and 0.05-0.15 parts
80 or sorbester p17, mixing vibration 15-25min, stir 30-50min with agitator, obtain the homogeneous film liquid being completely dissolved；
C, film forming are dried：To carrying out casting film-forming into film liquid, then at a temperature of 35-55 DEG C, forced air drying obtains compound edible
Flavoring agent packaging film.
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| CN108440796A (en) * | 2018-03-07 | 2018-08-24 | 福建师范大学福清分校 | A kind of preparation method of edible multifunctional compound package material |
| CN109369942A (en) * | 2018-10-30 | 2019-02-22 | 顺德职业技术学院 | It is a kind of intelligently to indicate edible film and preparation method thereof, purposes |
| CN110684240A (en) * | 2019-10-11 | 2020-01-14 | 徐铖伟 | Preparation method of easily-degradable edible multi-taste tableware |
| CN112795057A (en) * | 2021-02-05 | 2021-05-14 | 齐鲁工业大学 | Corn starch/sodium carboxymethylcellulose/fatty acid composite membrane and preparation method and application thereof |
| CN113930082A (en) * | 2021-10-20 | 2022-01-14 | 厦门子恒环保科技有限公司 | Environment-friendly paper tableware processing film-coated material and preparation method thereof |
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| CN106832015A (en) * | 2017-03-17 | 2017-06-13 | 广西大学 | A kind of preparation method of starch octadecyl forulic acid compound |
| CN108440796A (en) * | 2018-03-07 | 2018-08-24 | 福建师范大学福清分校 | A kind of preparation method of edible multifunctional compound package material |
| CN109369942A (en) * | 2018-10-30 | 2019-02-22 | 顺德职业技术学院 | It is a kind of intelligently to indicate edible film and preparation method thereof, purposes |
| CN112552542A (en) * | 2018-10-30 | 2021-03-26 | 顺德职业技术学院 | Preparation method of intelligent indicating edible film |
| CN112661997A (en) * | 2018-10-30 | 2021-04-16 | 顺德职业技术学院 | Application of intelligent indicating edible film |
| CN110684240A (en) * | 2019-10-11 | 2020-01-14 | 徐铖伟 | Preparation method of easily-degradable edible multi-taste tableware |
| CN112795057A (en) * | 2021-02-05 | 2021-05-14 | 齐鲁工业大学 | Corn starch/sodium carboxymethylcellulose/fatty acid composite membrane and preparation method and application thereof |
| CN113930082A (en) * | 2021-10-20 | 2022-01-14 | 厦门子恒环保科技有限公司 | Environment-friendly paper tableware processing film-coated material and preparation method thereof |
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