CN109365138B - 一种用于硫化铜镍矿浮选的新型复合浮选剂 - Google Patents
一种用于硫化铜镍矿浮选的新型复合浮选剂 Download PDFInfo
- Publication number
- CN109365138B CN109365138B CN201811449530.9A CN201811449530A CN109365138B CN 109365138 B CN109365138 B CN 109365138B CN 201811449530 A CN201811449530 A CN 201811449530A CN 109365138 B CN109365138 B CN 109365138B
- Authority
- CN
- China
- Prior art keywords
- agent
- flotation
- xanthate
- collecting
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000005188 flotation Methods 0.000 title claims abstract description 29
- YFLLTMUVNFGTIW-UHFFFAOYSA-N nickel;sulfanylidenecopper Chemical compound [Ni].[Cu]=S YFLLTMUVNFGTIW-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 239000002131 composite material Substances 0.000 title claims abstract description 14
- 239000008396 flotation agent Substances 0.000 title claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 27
- 239000012991 xanthate Substances 0.000 claims abstract description 27
- 239000004088 foaming agent Substances 0.000 claims abstract description 11
- IRDQNLLVRXMERV-UHFFFAOYSA-N CCCC[Na] Chemical compound CCCC[Na] IRDQNLLVRXMERV-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims abstract description 5
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 5
- 239000011734 sodium Substances 0.000 claims abstract description 5
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims abstract description 4
- KJGPAEUTPOVBIL-UHFFFAOYSA-N CC(C)CC[K] Chemical compound CC(C)CC[K] KJGPAEUTPOVBIL-UHFFFAOYSA-N 0.000 claims abstract description 3
- XLJYGTUUQWFFGT-UHFFFAOYSA-N CC(C)CC[Na] Chemical compound CC(C)CC[Na] XLJYGTUUQWFFGT-UHFFFAOYSA-N 0.000 claims abstract description 3
- ISZKKWKBYKPCSI-UHFFFAOYSA-N CC(C)C[Na] Chemical compound CC(C)C[Na] ISZKKWKBYKPCSI-UHFFFAOYSA-N 0.000 claims abstract description 3
- HQPSKTOGFFYYKN-UHFFFAOYSA-N CC(C)[Na] Chemical compound CC(C)[Na] HQPSKTOGFFYYKN-UHFFFAOYSA-N 0.000 claims abstract description 3
- KCMZYCFSSYXEQR-UHFFFAOYSA-N CCCC[K] Chemical compound CCCC[K] KCMZYCFSSYXEQR-UHFFFAOYSA-N 0.000 claims abstract description 3
- NTZRDKVFLPLTPU-UHFFFAOYSA-N CC[Na] Chemical compound CC[Na] NTZRDKVFLPLTPU-UHFFFAOYSA-N 0.000 claims abstract description 3
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims abstract description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 3
- CRAXZMAICBMTCW-UHFFFAOYSA-M potassium;2-methylpropoxymethanedithioate Chemical compound [K+].CC(C)COC([S-])=S CRAXZMAICBMTCW-UHFFFAOYSA-M 0.000 claims abstract description 3
- ZMWBGRXFDPJFGC-UHFFFAOYSA-M potassium;propan-2-yloxymethanedithioate Chemical compound [K+].CC(C)OC([S-])=S ZMWBGRXFDPJFGC-UHFFFAOYSA-M 0.000 claims abstract description 3
- WVYWICLMDOOCFB-UHFFFAOYSA-N 4-methyl-2-pentanol Chemical compound CC(C)CC(C)O WVYWICLMDOOCFB-UHFFFAOYSA-N 0.000 claims description 7
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 4
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 claims description 4
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 claims description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 4
- WAEVWDZKMBQDEJ-UHFFFAOYSA-N 2-[2-(2-methoxypropoxy)propoxy]propan-1-ol Chemical compound COC(C)COC(C)COC(C)CO WAEVWDZKMBQDEJ-UHFFFAOYSA-N 0.000 claims description 2
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 claims description 2
- 150000008378 aryl ethers Chemical class 0.000 claims description 2
- 229930003836 cresol Natural products 0.000 claims description 2
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920001451 polypropylene glycol Polymers 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 229940116411 terpineol Drugs 0.000 claims description 2
- 239000010949 copper Substances 0.000 description 13
- 238000011084 recovery Methods 0.000 description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 9
- 229910052802 copper Inorganic materials 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 230000003213 activating effect Effects 0.000 description 4
- 238000013329 compounding Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 229910000365 copper sulfate Inorganic materials 0.000 description 3
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 239000004604 Blowing Agent Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- AAJRIJBGDLLRAE-UHFFFAOYSA-M sodium;butoxymethanedithioate Chemical compound [Na+].CCCCOC([S-])=S AAJRIJBGDLLRAE-UHFFFAOYSA-M 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/012—Organic compounds containing sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/008—Organic compounds containing oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/04—Frothers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; specified applications
- B03D2203/02—Ores
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201811449530.9A CN109365138B (zh) | 2018-11-30 | 2018-11-30 | 一种用于硫化铜镍矿浮选的新型复合浮选剂 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201811449530.9A CN109365138B (zh) | 2018-11-30 | 2018-11-30 | 一种用于硫化铜镍矿浮选的新型复合浮选剂 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN109365138A CN109365138A (zh) | 2019-02-22 |
CN109365138B true CN109365138B (zh) | 2021-03-05 |
Family
ID=65374973
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201811449530.9A Active CN109365138B (zh) | 2018-11-30 | 2018-11-30 | 一种用于硫化铜镍矿浮选的新型复合浮选剂 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN109365138B (zh) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110369143B (zh) * | 2019-07-10 | 2021-02-09 | 青海省地质矿产测试应用中心 | 一种耐低温复合捕收剂及其制备方法和应用 |
CN111298979A (zh) * | 2020-03-27 | 2020-06-19 | 云南铁峰矿业化工新技术有限公司 | 一种起泡剂 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN85107378A (zh) * | 1984-09-13 | 1987-03-18 | 陶氏化学公司 | 从原煤中回收有用煤的起泡剂组合物和泡沫浮选方法 |
CA1270076A (en) * | 1985-05-31 | 1990-06-05 | The Dow Chemical Company | Collectors for the selective froth flotation of mineral sulfides |
WO2008019451A1 (en) * | 2006-08-17 | 2008-02-21 | Ab Tall (Holdings) Pty Ltd | Collectors and flotation methods |
CN102806148A (zh) * | 2012-09-07 | 2012-12-05 | 西北矿冶研究院 | 一种高硫铜矿捕收剂 |
CN104759354A (zh) * | 2015-03-11 | 2015-07-08 | 铜陵鑫腾矿业科技有限公司 | 一种复合型铜矿浮选剂 |
CN106269274A (zh) * | 2016-06-20 | 2017-01-04 | 兰州大学 | 一种用于硫化铜镍矿酸性浮选的药剂 |
CN107971140B (zh) * | 2017-11-27 | 2023-04-28 | 湖南华麒资源环境科技发展有限公司 | 二硫代非金属酸盐及其低聚物浮选抑制剂及配制使用方法 |
-
2018
- 2018-11-30 CN CN201811449530.9A patent/CN109365138B/zh active Active
Also Published As
Publication number | Publication date |
---|---|
CN109365138A (zh) | 2019-02-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN106170343B (zh) | 一种黄铜矿的选矿方法 | |
US20210402414A1 (en) | Wide-size-fraction flotation system and process | |
CN109365138B (zh) | 一种用于硫化铜镍矿浮选的新型复合浮选剂 | |
CN102218377B (zh) | 一种高效氧化铜钴矿组合捕收剂及氧化铜矿选矿方法 | |
CN109290062B (zh) | 一种氧化矿浮选混溶捕收剂及其使用方法 | |
CN110000008B (zh) | 一种硫化铅锌矿复合捕收剂、复合浮选药剂及其制备和应用 | |
CN107694762A (zh) | 一种从矿石中浮选捕收金红石的组合物及浮选方法 | |
CN106694235B (zh) | 一种镍多金属矿选矿工艺 | |
CN112973968B (zh) | 一种黄铁矿-黄铜矿的浮选药剂和浮选分离方法 | |
CN110328046A (zh) | 一种矽卡岩型低品位铜锌矿的分选方法 | |
CN109647628A (zh) | 1,3,4-噻二唑类化合物在硫化矿浮选中的应用 | |
CN113102113B (zh) | 一种方铅矿与含锌脉石选择性浮选分离药剂和方法 | |
CN110369143A (zh) | 一种耐低温复合捕收剂及其制备方法和应用 | |
CN113102114A (zh) | 一种用于高含硫细粒级浮选金矿的高效捕收剂 | |
CN105413855A (zh) | 一种钨粗精矿精选提纯的方法 | |
CN107899753A (zh) | 一种无氟浮选分离石英和长石的阴离子组合捕收剂及其制备方法与应用 | |
CN103817016A (zh) | 低品位多金属硫化矿铜铅分离选矿组合抑制剂及其使用方法 | |
CN103433142B (zh) | 微细粒复杂脆硫锑铅矿的浮选方法 | |
CN206924887U (zh) | 一种铁铜硫矿选矿*** | |
CN109158218A (zh) | 一种方铅矿的复合抑制剂及其使用方法 | |
CN106975574B (zh) | 一种用于金红石矿浮选的捕收剂组合物 | |
CN110665645A (zh) | 一种细粒级闪锌矿选别的高效浮选药剂及其制备方法与应用 | |
CN114405657B (zh) | 通过重浮联合分离辉钼矿与方铅矿的方法 | |
CN107413531B (zh) | 一种云母捕收剂的制备方法 | |
CN112808463B (zh) | 一种将铁钛矿与含铁脉石浮选分离的药剂和方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20220901 Address after: 230000 Room 203, building 2, phase I, e-commerce Park, Jinggang Road, Shushan Economic Development Zone, Hefei City, Anhui Province Patentee after: Hefei Jiuzhou Longteng scientific and technological achievement transformation Co.,Ltd. Address before: 467036 Henan province Pingdingshan city new city Longxiang Road Patentee before: Henan University of Urban Construction |
|
TR01 | Transfer of patent right |
Effective date of registration: 20240522 Address after: 016000 Mechanical Processing Park on the northwest side of Moergou, Haibowan District, Wuhai City, Inner Mongolia Autonomous Region (within the yard of Wuhai Deping Stone Sales Co., Ltd.) Patentee after: Inner Mongolia Zhengjiehao Environmental Protection Technology Co.,Ltd. Country or region after: China Address before: 230000 Room 203, building 2, phase I, e-commerce Park, Jinggang Road, Shushan Economic Development Zone, Hefei City, Anhui Province Patentee before: Hefei Jiuzhou Longteng scientific and technological achievement transformation Co.,Ltd. Country or region before: China |