CN109362768B - Mineral salt-containing disinfection spray - Google Patents

Mineral salt-containing disinfection spray Download PDF

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Publication number
CN109362768B
CN109362768B CN201811555381.4A CN201811555381A CN109362768B CN 109362768 B CN109362768 B CN 109362768B CN 201811555381 A CN201811555381 A CN 201811555381A CN 109362768 B CN109362768 B CN 109362768B
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parts
mineral salt
disinfection spray
disinfection
spray
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CN109362768A (en
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傅云峥
古嘉俊
冯小婕
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Zigong Innovation Center of Zhejiang University
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Zigong Innovation Center of Zhejiang University
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
    • A01N47/44—Guanidine; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A01N25/06—Aerosols
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/12—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
    • A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
    • A01N39/04—Aryloxy-acetic acids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00—Medicinal preparations containing organic active ingredients
    • A61K31/075—Ethers or acetals
    • A61K31/085—Ethers or acetals having an ether linkage to aromatic ring nuclear carbon
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00—Medicinal preparations containing organic active ingredients
    • A61K31/13—Amines
    • A61K31/14—Quaternary ammonium compounds, e.g. edrophonium, choline
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00—Medicinal preparations containing organic active ingredients
    • A61K31/13—Amines
    • A61K31/155—Amidines (), e.g. guanidine (H2N—C(=NH)—NH2), isourea (N=C(OH)—NH2), isothiourea (—N=C(SH)—NH2)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00—Medicinal preparations containing organic active ingredients
    • A61K31/185—Acids; Anhydrides, halides or salts thereof, e.g. sulfur acids, imidic, hydrazonic or hydroximic acids
    • A61K31/19—Carboxylic acids, e.g. valproic acid
    • A61K31/195—Carboxylic acids, e.g. valproic acid having an amino group
    • A61K31/197—Carboxylic acids, e.g. valproic acid having an amino group the amino and the carboxyl groups being attached to the same acyclic carbon chain, e.g. gamma-aminobutyric acid [GABA], beta-alanine, epsilon-aminocaproic acid or pantothenic acid
    • A61K31/198—Alpha-amino acids, e.g. alanine or edetic acid [EDTA]
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00—Medicinal preparations containing organic active ingredients
    • A61K31/33—Heterocyclic compounds
    • A61K31/395—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins
    • A61K31/435—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins having six-membered rings with one nitrogen as the only ring hetero atom
    • A61K31/44—Non condensed pyridines; Hydrogenated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00—Medicinal preparations containing organic active ingredients
    • A61K31/74—Synthetic polymeric materials
    • A61K31/785—Polymers containing nitrogen
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K33/00—Medicinal preparations containing inorganic active ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/43—Guanidines
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
    • A61K8/4926—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having six membered rings
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/965—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of inanimate origin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P31/00—Antiinfectives, i.e. antibiotics, antiseptics, chemotherapeutics
    • A61P31/02—Local antiseptics
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/005—Antimicrobial preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

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  • Pest Control & Pesticides (AREA)
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Abstract

The invention provides a mineral salt-containing disinfection spray which is characterized by comprising the following components in parts by weight: 0.5-5 parts of guanidine disinfectant, 0.5-5 parts of auxiliary bactericide and 0.01-2 parts of mineral salt. The disinfection spray is colorless and tasteless, has no stimulation, can be matched with essence to form a product with required smell, effectively kills pathogenic bacteria such as escherichia coli, staphylococcus aureus and the like, achieves the disinfection technical specification level, and has high repeatability. The disinfection spray does not contain ethanol, does not cause object damage and secondary pollution due to dissolving of some substances dissolved in organic liquid on the surface of an object, and does not cause damage to skin.

Description

Mineral salt-containing disinfection spray
Technical Field
The invention relates to the field of daily chemical articles, in particular to a mineral salt-containing disinfection spray.
Background
With the decrease of modern air quality, the air contains more bacteria, such as pathogenic bacteria like escherichia coli, staphylococcus aureus and the like, and people live in unhealthy environments for a long time, so that a lot of adverse effects are generated, and various diseases are caused. Air is generally sterilized by a sterile spray.
Most of the existing cleaning agents or disinfectants in the market at present are synthesized by chemical agents, so that certain harm is caused to human bodies after long-time use, but the problems cannot be solved fundamentally by common cleaning agents, the problems can be relieved only by means of smell covering, and the disinfectants generally have pungent smell and are not beneficial to human health. The current commercially available disinfection sprays for the surfaces of common objects have sterilization performance which does not reach or cannot always reach the disinfection level required by the disinfection specification, and contain ethanol, which may cause certain damage or injury to the surfaces of the objects or the skin surfaces. Therefore, the search for a healthy non-irritating disinfecting spray is an urgent problem to be solved.
Disclosure of Invention
In order to solve the problems, the invention provides a mineral salt-containing disinfection spray, which is a water-based spray formula and adopts non-toxic raw materials without ethanol. Can be applied to the surface of common objects, and also can be applied to human skin (excluding mucosa, wound, etc.) such as hand sterilization and cleaning for children.
In order to realize the purpose of the invention, the technical scheme adopted by the invention is as follows: a mineral salt-containing disinfection spray comprises the following components in parts by weight: 0.5-5 parts of guanidine disinfectant, 0.5-5 parts of auxiliary bactericide and 0.01-2 parts of mineral salt.
Preferably, the guanidine disinfectant is polyhexamethylene biguanide hydrochloride or polyaminopropyl biguanide.
More preferably, the guanidine disinfectant is polyhexamethylene biguanide hydrochloride.
Preferably, the auxiliary bactericide is one or any combination of phenoxyethanol, cetylpyridinium chloride, cetrimide and lauroyl arginine ethyl ester.
More preferably, the auxiliary bactericide is a combination of cetylpyridinium chloride and phenoxyethanol.
Preferably, the mineral salt is one or any combination of deep well salt, sea salt, lake salt and rock salt.
More preferably, the mineral salt is a deep well salt.
Preferably, the disinfection spray comprises the following components in parts by weight: 5 parts of polyhexamethylene biguanide hydrochloride, 0.5 part of cetylpyridinium chloride, 3 parts of phenoxyethanol, 1 part of cetrimide, 0.5 part of lauroyl arginine ethyl ester and 2 parts of deep well salt.
The invention has the beneficial effects that: the mineral salt adopted by the invention has the advantages of low cost, cleaning and disinfecting, anti-inflammation and bacteriostasis effects, skin care effect, certain treatment and improvement effects on common dermatitis, and daily chemical products containing the mineral salt are more and more favored by consumers. The disinfection spray is colorless and tasteless, has no stimulation, can be matched with essence to form a product with required smell, effectively kills pathogenic bacteria such as escherichia coli, staphylococcus aureus and the like, achieves the disinfection technical specification level, and has high repeatability. The disinfection spray does not contain ethanol, does not cause object damage and secondary pollution due to dissolving of some substances dissolved in organic liquid on the surface of an object, and does not cause damage to skin.
Detailed Description
In order to more concisely and clearly demonstrate technical solutions, objects and advantages of the present invention, the present invention will be further described in detail with reference to specific embodiments.
Table 1: EXAMPLES 1-10 Disinfection spray formulations
Figure BDA0001911722850000021
Figure BDA0001911722850000031
The sprays of examples 1 to 10 were evaluated for efficacy, and the bactericidal effect was examined, according to the regulations of GB 15979-; the results are shown in Table 2, wherein a certain brand of disinfecting spray sold in China is used as a comparative example, and deionized water is used as a blank example. The standard specifies that the killing log value of the blank case is 0, so the blank case is not described in the table.
Table 2: EXAMPLES 1 to 10 Disinfection spray Sterilization Effect
Figure BDA0001911722850000032
As can be seen from Table 2, examples 1-10 all had a strong bactericidal effect, a strong inhibitory effect against the pathogenic bacteria Escherichia coli and Staphylococcus aureus, and a better bactericidal effect than the comparative examples. In examples 1-5, the guanidine disinfectant in examples 2-5 is polyhexamethylene biguanide hydrochloride, which has better bactericidal effect than the polyaminopropyl biguanide in example 1, and examples 4 and 5 have better bactericidal effect than examples 1-3, because the mineral salts selected in examples 4 and 5 are deep well salts; the sterilization effects of the examples 1 to 5 are not as good as those of the examples 6 to 10, because the auxiliary bactericides are all single bactericides, and the examples 6 to 10 all adopt composite auxiliary bactericides, wherein the combination of cetylpyridinium chloride and phenoxyethanol has the best sterilization effect; therefore, the best combination obtained by the invention is polyhexamethylene biguanide hydrochloride, cetylpyridinium chloride, phenoxyethanol and deep well salt, and simultaneously cetroronium chloride and lauroyl arginine ethyl ester are added, the sterilization effect is the best like the formula of the embodiment 10, so the embodiment 10 is the best embodiment of the invention.
The above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.

Claims (1)

1. The mineral salt-containing disinfection spray is characterized by comprising the following components in parts by weight: 5 parts of polyhexamethylene biguanide hydrochloride, 3 parts of cetylpyridinium chloride, 0.5 part of phenoxyethanol, 1 part of cetrimide, 0.5 part of lauroyl arginine ethyl ester and 2 parts of deep well salt.
CN201811555381.4A 2018-12-19 2018-12-19 Mineral salt-containing disinfection spray Active CN109362768B (en)

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AU2021240358A1 (en) * 2020-03-26 2022-09-22 Arch Uk Biocides Ltd Disinfectant compositions

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CN1947687A (en) * 2006-03-29 2007-04-18 成都死海盐疗健康馆服务有限公司 Salt solution with sterilization function
CN106212551B (en) * 2016-07-29 2018-11-30 腾科宝迪（厦门）生物科技有限公司 Daily non-stimulated disinfectant of one kind and preparation method thereof
CN106176570A (en) * 2016-08-31 2016-12-07 广东芭薇生物科技股份有限公司 A kind of spraying for skin surface temperature drop and preparation method thereof
CN106581148A (en) * 2017-02-28 2017-04-26 四川艾医生医疗科技有限公司 Nasal irrigation care solution
CN108887289A (en) * 2018-07-26 2018-11-27 上海沃必盛生物科技有限公司 A kind of daily high effect disinfectants of family and its application method

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