CN109355121A - A kind of high-efficiency desulfurization system of liquefied gas and device in Gas - Google Patents

A kind of high-efficiency desulfurization system of liquefied gas and device in Gas Download PDF

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Publication number
CN109355121A
CN109355121A CN201811551698.0A CN201811551698A CN109355121A CN 109355121 A CN109355121 A CN 109355121A CN 201811551698 A CN201811551698 A CN 201811551698A CN 109355121 A CN109355121 A CN 109355121A
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gas
tower
liquefied gas
import
outlet
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CN109355121B (en
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焦金锋
赵杰
何帅帅
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Nanjing Tesp Chemical Engineering Technology Co Ltd
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Nanjing Tesp Chemical Engineering Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • C10L3/101Removal of contaminants
    • C10L3/102Removal of contaminants of acid contaminants
    • C10L3/103Sulfur containing contaminants

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

The present invention provides the high-efficiency desulfurization system of a kind of liquefied gas and device in Gas, belong to technical field of desulfurization, including desulfuration of liquefied gas tower, device in Gas desulfurizing tower and solvent regeneration tower, desulfuration of liquefied gas tower top and bottom are respectively equipped with the first desulfurizing agent import and liquefied gas inlet, and desulfuration of liquefied gas top of tower and bottom are respectively equipped with liquefied gas outlet and semi lean solution outlet;Device in Gas desulfurizing tower top and bottom are respectively equipped with the second desulfurizing agent import and device in Gas import, and device in Gas outlet and rich solution outlet are respectively equipped at the top and bottom of device in Gas desulfurizing tower, is equipped with semi lean solution import in the middle part of device in Gas desulfurizing tower;In the middle part of solvent regeneration tower and bottom is respectively equipped with rich solution import and the outlet of lean solution desulfurizing agent;Semi lean solution import is connected by semi lean solution pipe with semi lean solution outlet, and rich solution import is connected by rich solution pipe with rich solution outlet.Equipment cost in the present invention is low, and the desulfuration efficiency of liquefied gas and device in Gas is high, and doctor solution consumption is few, helps to economize on resources, reduces energy consumption.

Description

A kind of high-efficiency desulfurization system of liquefied gas and device in Gas
Technical field
The invention belongs to technical field of desulfurization, and in particular to the high-efficiency desulfurization system of a kind of liquefied gas and device in Gas.
Background technique
In recent years, with the enhancing of energy conservation and environmental awareness, the country also increasingly payes attention to desulfurization technology.Currently, liquefied gas And device in Gas needs desulfurization, the main sulfur removal technology of use as shown in Figure 1, liquefied gas enters from the tower bottom of desulfuration of liquefied gas tower 1, Liquefied gas is inversely contacted with the desulfurizing agent solution that 1 tower top of desulfuration of liquefied gas tower enters, and the sulphur in liquefied gas is removed, similarly, Device in Gas enters from the tower bottom of device in Gas desulfurizing tower 2, and device in Gas and the desulfurizing agent solution that 2 tower top of device in Gas desulfurizing tower enters are reverse Contact removes the sulphur in device in Gas.Desulfuration of liquefied gas tower 1 and the rich solution of 2 tower bottom of device in Gas desulfurizing tower outflow have respectively entered Solvent regeneration tower 3 is regenerated, and the lean solution desulfurizing agent after regeneration is respectively from the tower of desulfuration of liquefied gas tower 1 and device in Gas desulfurizing tower 2 Top top proceeds in corresponding tower, to promote desulfurizing agent to be recycled.But desulfuration of liquefied gas tower 1 and device in Gas desulfurizing tower 2 Rich solution after desulfurization enters directly into solvent regeneration tower 3, so that desulfurizing agent usage amount is big, increases energy consumption, and desulfuration of liquefied gas Tower 1, device in Gas desulfurizing tower 2, the tower internals in solvent regeneration tower 3 generally select filler, but because liquefied gas and device in Gas Property leads to the cost that equipment is increased to the more demanding of metal packing, needs to clear up all fillers in scale removal process It just can be carried out cleaning maintenance out, the cost of labor and time cost of maintenance are also higher.In addition, the system of liquefied gas and device in Gas Dirtier, containing solid granule, and these particles are easy to blocking filler, cause bias current and influence flux, reduce the de- of tower Sulphur efficiency.In minute quantity, tower internals can also select valve plate, and solid particle easily blocks the sky between float valve valve leg Gap causes float valve to fail to open and influences flux, to also reduce the desulfuration efficiency of tower.Desulfurizing agent used in sulfur removal technology Easily foaming, easily causes liquid phase back-mixing, influences the efficiency of tower.Therefore, it is badly in need of a kind of liquefied gas for being able to solve existing issue And the high-efficiency desulfurization system of device in Gas.
Summary of the invention
In view of the deficiencies of the prior art, it is an object of the present invention to provide a kind of liquefied gas and the high-efficiency desulfurization systems of device in Gas System has the advantages that economize on resources, desulfurization effect is good, desulfuration efficiency is high, convenient to overhaul.
The present invention provides the following technical solutions:
The high-efficiency desulfurization system of a kind of liquefied gas and device in Gas, including desulfuration of liquefied gas tower, device in Gas desulfurizing tower and solvent Regenerator, desulfuration of liquefied gas tower top and bottom are respectively equipped with the first desulfurizing agent import and liquefied gas inlet, the liquefaction Desulfurization top of tower and bottom are respectively equipped with liquefied gas outlet and semi lean solution outlet, device in Gas desulfurizing tower top and bottom point It She You not the second desulfurizing agent import and device in Gas import;Device in Gas outlet is respectively equipped at the top and bottom of the device in Gas desulfurizing tower And rich solution outlet, the device in Gas desulfurizing tower middle part are equipped with semi lean solution import;It is set respectively at the top and bottom of the solvent regeneration tower There are exhaust outlet and the outlet of lean solution desulfurizing agent, is equipped with rich solution import in the middle part of the solvent regeneration tower;The semi lean solution import passes through half Lean solution pipe is connected with semi lean solution outlet, and the rich solution import is connected by rich solution pipe with the rich solution outlet, to promote Into the recycling of desulfurizing agent, lean solution desulfurizing agent outlet also by pipeline respectively with the first desulfurizing agent import and described Second desulfurizing agent import is connected.
Preferably, the height of the semi lean solution import is greater than the height of the device in Gas import, is less than second desulfurization The height of agent import.
Preferably, the desulfuration of liquefied gas tower is plate column, uses sieve tray in the desulfuration of liquefied gas tower.
Preferably, the device in Gas desulfurizing tower and the solvent regeneration tower are plate column, the device in Gas desulfurizing tower and institute It states in solvent regeneration tower using Glitsch V-O tray.
Preferably, the Glitsch V-O tray includes cambered plate, and the cambered plate side is equipped with seal pot, the cambered plate The other side is equipped with inclination down-flow plate.
Preferably, several fixed valves are equipped with the seal pot on the cambered plate.
Preferably, the angle between the inclination down-flow plate and the cambered plate is 40-90 °.
Preferably, what the sulfur content for the liquefied gas being passed through at the liquefied gas inlet was passed through lower than the device in Gas entrance The sulfur content of device in Gas.
The beneficial effects of the present invention are:
(1) present invention liquefied gas and reverse gas-liquid contact of desulfurizing agent in desulfuration of liquefied gas tower, the semi lean solution that tower bottom comes out Into the middle part of device in Gas desulfurizing tower, at the same with together with the desulfurizing agent that device in Gas desulfurizing tower top is got off in device in Gas desulfurizing tower Interior lower part carries out preliminary desulfurization to device in Gas, the then lean solution desulfurization with device in Gas desulfurizing tower top of the device in Gas after preliminary desulfurization Agent carries out reverse contact to remove remaining sulphur in device in Gas, and this set not only takes full advantage of the outflow of desulfuration of liquefied gas tower Semi lean solution but also the dosage for the lean solution desulfurizing agent that device in Gas desulfurizing tower need to use is greatly decreased, and reduces pump load, section The about circulation losses of a large amount of energy consumptions and desulfurizing agent;
(2) sulfur content is relatively low in the liquefied gas in the present invention, and sulfur content is relatively high in device in Gas, desulfuration of liquefied gas tower Throughput requirements are big, therefore select the biggish sieve tray of flux, and the throughput requirements of device in Gas desulfurizing tower are small, therefore select tray efficiency Higher Glitsch V-O tray, opposite packed tower, the selection of sieve tray and Glitsch V-O tray not only can effectively prevent solid particle The case where blocking, extends the operation cycle under the premise of guaranteeing that column efficiency is stablized, it helps reduces cost of equipment, easy access Cleaning reduces the cost of overhaul;
(3) present invention selects Glitsch V-O tray in device in Gas desulfurizing tower and solvent regeneration tower, selects on Glitsch V-O tray Down-flow plate is tilted, so that gas-liquid two-phase is easy defoaming on inclination down-flow plate, reduces two-phase entrainment and influences tray efficiency.
Detailed description of the invention
Attached drawing is used to provide further understanding of the present invention, and constitutes part of specification, with reality of the invention It applies example to be used to explain the present invention together, not be construed as limiting the invention.In the accompanying drawings:
Fig. 1 is the structural schematic diagram of the prior art;
Fig. 2 is structural schematic diagram of the invention;
Fig. 3 is the overlooking structure diagram of Glitsch V-O tray of the invention;
Fig. 4 is Glitsch V-O tray of the invention in the scheme of installation in tower.
In the figure, it is marked as 1, desulfuration of liquefied gas tower;2, device in Gas desulfurizing tower;3, solvent regeneration tower;4, the first desulfurizing agent into Mouthful;5, liquefied gas inlet;6, liquefied gas exports;7, semi lean solution exports;8, the second desulfurizing agent import;9, device in Gas import;Watt 10, The outlet of this gas;11, rich solution outlet;12, semi lean solution import;13, exhaust outlet;14, lean solution desulfurizing agent exports;15, rich solution import; 16, semi lean solution pipe;17, rich solution pipe;18, Glitsch V-O tray;19, cambered plate;20, seal pot;21, down-flow plate is tilted;22, fixed Valve.
Specific embodiment
As shown in Figures 2 to 4, the high-efficiency desulfurization system of a kind of liquefied gas and device in Gas, including desulfuration of liquefied gas tower 1, watt This desulfurization tower 2 and solvent regeneration tower 3,1 top and bottom of desulfuration of liquefied gas tower are respectively equipped with the first desulfurizing agent import 4 and liquefaction Gas import 5 is respectively equipped with liquefied gas outlet 6 and semi lean solution outlet 7 at the top and bottom of desulfuration of liquefied gas tower 1;Device in Gas desulfurizing tower 2 Top and bottom are respectively equipped with the second desulfurizing agent import 8 and device in Gas import 9, and 2 top and bottom of device in Gas desulfurizing tower are set respectively There are device in Gas outlet 10 and rich solution outlet 11, is equipped with semi lean solution import 12, the height of semi lean solution import 12 in the middle part of device in Gas desulfurizing tower 2 Degree is greater than the height of device in Gas import 9, less than the height of the second desulfurizing agent import 8;3 top and bottom of solvent regeneration tower are set respectively There are exhaust outlet 13 and lean solution desulfurizing agent outlet 14, is equipped with rich solution import 15 in the middle part of solvent regeneration tower 3;Semi lean solution import 12 passes through half Lean solution pipe 16 is connected with semi lean solution outlet 7, and rich solution import 15 is connected by rich solution pipe 17 with rich solution outlet 11, de- to promote The recycling of sulphur agent, lean solution desulfurizing agent outlet 14 also by pipeline respectively with the first desulfurizing agent import 4 and the second desulfurizing agent into Mouth 8 is connected.
Wherein, desulfuration of liquefied gas tower 1 is plate column, uses sieve tray, device in Gas desulfurizing tower 2 in desulfuration of liquefied gas tower 1 Also be plate column with solvent regeneration tower 3, use Glitsch V-O tray 18 in device in Gas desulfurizing tower 2 and solvent regeneration tower 3, such as Fig. 3 and Shown in Fig. 4, Glitsch V-O tray 18 includes cambered plate 19, and 19 side of cambered plate is equipped with seal pot 20, and the other side of cambered plate 19 is set Have and tilt down-flow plate 21, on cambered plate 19 and seal pot 20 is equipped with several fixed valves 22, inclination down-flow plate 21 and cambered plate 19 Between angle be 40-90 °.
In use, the lean solution desulfurizing agent after solvent regeneration tower 3 regenerates can be by pipeline respectively from liquefaction by the present invention The tower top of desulfurization tower 1 and device in Gas desulfurizing tower 2 enters, and in desulfuration of liquefied gas tower 1, liquefied gas enters from liquefied gas inlet 5, Liquefied gas inversely contacts on efficient sieve plate tower tray with desulfurizing agent, and the sulphur in liquefied gas is removed, and liquefied gas after desulfurization is from tower The liquefied gas on top exports 6 bleeders, and the sulfur content in liquefied gas is lower, and the semi lean solution after absorbing sulphur goes out from the semi lean solution of tower bottom Mouth 7 flows out, and the middle part of device in Gas desulfurizing tower 2 is entered by semi lean solution pipe 16;In device in Gas desulfurizing tower 2, from semi lean solution Import 12 enter device in Gas desulfurizing tower 2 in semi lean solution with together with the desulfurizing agent that 2 top of device in Gas desulfurizing tower is got off in gas Lower part carries out gas-liquid contact tentatively to remove the sulphur in device in Gas in 2 tower of desulfurization tower, device in Gas after preliminary desulfurization then with The lean solution desulfurizing agent on 2 top of device in Gas desulfurizing tower inversely contact to remove remaining sulphur in device in Gas, the gas after desulfurization Gas exports 10 bleeders from the device in Gas of tower top, and the sulfur content in device in Gas is higher, richness of the rich solution after absorbing sulphur from tower bottom 11 outflow of liquid outlet, and entered in solvent regeneration tower 3 by rich solution pipe 17;In solvent regeneration tower 3, rich solution desulfurizing agent is molten Regeneration, the desulfurizing agent after regeneration have respectively entered in desulfuration of liquefied gas tower 1 and device in Gas desulfurizing tower 2 and are followed in agent regenerator 3 Ring uses.
In the present embodiment, sulfur content is relatively low in liquefied gas, and sulfur content is relatively high in device in Gas, desulfuration of liquefied gas tower 1 Throughput requirements are big, therefore select the biggish sieve tray of flux, and the throughput requirements of device in Gas desulfurizing tower 2 are small, therefore select tower tray effect The higher Glitsch V-O tray 18 of rate, opposite packed tower, the selection of sieve tray and Glitsch V-O tray 18 not only can effectively prevent solid The case where body particle blocks extends the operation cycle under the premise of guaranteeing that column efficiency is stablized, it helps reduces cost of equipment, just It is cleaned in maintenance, reduces the cost of overhaul;The present invention liquefied gas and the reverse gas-liquid contact of desulfurizing agent, tower in desulfuration of liquefied gas tower 1 The semi lean solution that bottom comes out enters the middle part of device in Gas desulfurizing tower 2, at the same with the desulfurizing agent one that gets off from 2 top of device in Gas desulfurizing tower Play lower part in device in Gas desulfurizing tower 2 and desulfurization carried out to device in Gas, the device in Gas after preliminary desulfurization then with gas desulfurization The lean solution desulfurizing agent on 2 top of tower carries out reverse contact and is not only taken full advantage of with removing remaining sulphur, this set in device in Gas The semi lean solution that desulfuration of liquefied gas tower 1 flows out, but also the dosage for the lean solution desulfurizing agent that device in Gas desulfurizing tower 2 need to use substantially subtracts It is few, and reduce pump load, save a large amount of energy consumptions and desulfurizing agent circulation losses;The present invention is in device in Gas desulfurizing tower 2 and molten Glitsch V-O tray 18 is selected in agent regenerator 3, inclination down-flow plate 21 is selected on Glitsch V-O tray 18, so that in inclination down-flow plate 21 Upper gas-liquid two-phase is easy defoaming, reduces two-phase entrainment and influences tray efficiency.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although referring to aforementioned reality Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation Technical solution documented by example is modified or equivalent replacement of some of the technical features.It is all in essence of the invention Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (8)

1. the high-efficiency desulfurization system of a kind of liquefied gas and device in Gas, which is characterized in that including desulfuration of liquefied gas tower, gas desulfurization Tower and solvent regeneration tower, desulfuration of liquefied gas tower top and bottom are respectively equipped with the first desulfurizing agent import and liquefied gas inlet, The desulfuration of liquefied gas top of tower and bottom are respectively equipped with liquefied gas outlet and semi lean solution outlet;Device in Gas desulfurizing tower upper end The second desulfurizing agent import and device in Gas import are respectively equipped with lower end, are respectively equipped at the top and bottom of the device in Gas desulfurizing tower watt The outlet of this gas and rich solution outlet, the device in Gas desulfurizing tower middle part are equipped with semi lean solution import;The solvent reclamation top of tower and bottom Portion is respectively equipped with exhaust outlet and the outlet of lean solution desulfurizing agent, is equipped with rich solution import in the middle part of the solvent regeneration tower;The semi lean solution into Mouth is connected by semi lean solution pipe with semi lean solution outlet, and the rich solution import is connected by rich solution pipe with the rich solution outlet It is logical, the lean solution desulfurizing agent outlet also by pipeline respectively with the first desulfurizing agent import and the second desulfurizing agent import phase Connection.
2. the high-efficiency desulfurization system of a kind of liquefied gas according to claim 1 and device in Gas, which is characterized in that described half is poor The height of liquid import is greater than the height of the device in Gas import, less than the height of the second desulfurizing agent import.
3. the high-efficiency desulfurization system of a kind of liquefied gas according to claim 1 and device in Gas, which is characterized in that the liquefaction Desulfurization tower is plate column, uses sieve tray in the desulfuration of liquefied gas tower.
4. the high-efficiency desulfurization system of a kind of liquefied gas according to claim 1 or 3 and device in Gas, which is characterized in that described Device in Gas desulfurizing tower and the solvent regeneration tower are plate column, are used in the device in Gas desulfurizing tower and the solvent regeneration tower solid Determine valve tower disk.
5. the high-efficiency desulfurization system of a kind of liquefied gas according to claim 4 and device in Gas, which is characterized in that the fixation Valve tower disk includes cambered plate, and the cambered plate side is equipped with seal pot, and the other side of the cambered plate is equipped with inclination down-flow plate.
6. the high-efficiency desulfurization system of a kind of liquefied gas according to claim 5 and device in Gas, which is characterized in that the arch On plate and the seal pot is equipped with several fixed valves.
7. the high-efficiency desulfurization system of a kind of liquefied gas according to claim 5 and device in Gas, which is characterized in that the inclination Angle between down-flow plate and the cambered plate is 40-90 °.
8. the high-efficiency desulfurization system of a kind of liquefied gas and device in Gas described in any one of -7, feature exist according to claim 1 In the sulfur content for the liquefied gas being passed through at the liquefied gas inlet contains lower than the sulphur for the device in Gas that the device in Gas entrance is passed through Amount.
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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10314535A (en) * 1997-05-15 1998-12-02 Ishikawajima Harima Heavy Ind Co Ltd High temperature dry desulfurization device
JPH11276847A (en) * 1998-03-27 1999-10-12 Ishikawajima Harima Heavy Ind Co Ltd Desulfurizing equipment
CN102977932A (en) * 2012-12-13 2013-03-20 济南冶金化工设备有限公司 Coke oven gas desulfurization equipment
CN202844827U (en) * 2012-09-26 2013-04-03 中国恩菲工程技术有限公司 Smoke gas desulfurization system
CN203360406U (en) * 2013-07-31 2013-12-25 林吉萍 Efficient regeneration desulfurizing tower
CN105195018A (en) * 2015-10-22 2015-12-30 华东理工大学 Method for reducing loss of liquefied gas in desulfurization process
CN107243242A (en) * 2017-05-23 2017-10-13 武汉理工大学 Refinery's amine liquid desulphurization system and its sulfur method
CN206940816U (en) * 2017-06-21 2018-01-30 临沂恒昌焦化股份有限公司 Coking industry desulphurization system
CN209508174U (en) * 2018-12-19 2019-10-18 南京泰斯普化工工程技术有限公司 A kind of high-efficiency desulfurization system of liquefied gas and device in Gas

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10314535A (en) * 1997-05-15 1998-12-02 Ishikawajima Harima Heavy Ind Co Ltd High temperature dry desulfurization device
JPH11276847A (en) * 1998-03-27 1999-10-12 Ishikawajima Harima Heavy Ind Co Ltd Desulfurizing equipment
CN202844827U (en) * 2012-09-26 2013-04-03 中国恩菲工程技术有限公司 Smoke gas desulfurization system
CN102977932A (en) * 2012-12-13 2013-03-20 济南冶金化工设备有限公司 Coke oven gas desulfurization equipment
CN203360406U (en) * 2013-07-31 2013-12-25 林吉萍 Efficient regeneration desulfurizing tower
CN105195018A (en) * 2015-10-22 2015-12-30 华东理工大学 Method for reducing loss of liquefied gas in desulfurization process
CN107243242A (en) * 2017-05-23 2017-10-13 武汉理工大学 Refinery's amine liquid desulphurization system and its sulfur method
CN206940816U (en) * 2017-06-21 2018-01-30 临沂恒昌焦化股份有限公司 Coking industry desulphurization system
CN209508174U (en) * 2018-12-19 2019-10-18 南京泰斯普化工工程技术有限公司 A kind of high-efficiency desulfurization system of liquefied gas and device in Gas

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